JPH0449564B2 - - Google Patents

Info

Publication number: JPH0449564B2
Authority: JP; Japan
Prior art keywords: methylstyrene; poly; polymer; monomer; ion exchange
Prior art date: 1983-08-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP14961083A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6042406A (ja

Inventor

Tadashi Asanuma

Ryuichi Sugimoto

Shinryu Uchikawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsui Toatsu Chemicals Inc

Original Assignee

Mitsui Toatsu Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-08-18

Filing date

1983-08-18

Publication date

1992-08-11

1983-08-18 Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc

1983-08-18 Priority to JP14961083A priority Critical patent/JPS6042406A/ja

1985-03-06 Publication of JPS6042406A publication Critical patent/JPS6042406A/ja

1992-08-11 Publication of JPH0449564B2 publication Critical patent/JPH0449564B2/ja

Status Granted legal-status Critical Current

Links

XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 26
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 13
239000003456 ion exchange resin Substances 0.000 claims description 13
229920003303 ion-exchange polymer Polymers 0.000 claims description 13
230000002378 acidificating effect Effects 0.000 claims description 8
238000000034 method Methods 0.000 claims description 6
238000001704 evaporation Methods 0.000 claims description 4
230000008020 evaporation Effects 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
230000000379 polymerizing effect Effects 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 3
229920000642 polymer Polymers 0.000 description 17
239000000178 monomer Substances 0.000 description 14
238000010539 anionic addition polymerization reaction Methods 0.000 description 11
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
-1 amyllithium Chemical compound 0.000 description 2
MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
229920006237 degradable polymer Polymers 0.000 description 1
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
UBJFKNSINUCEAL-UHFFFAOYSA-N lithium;2-methylpropane Chemical compound [Li+].C[C-](C)C UBJFKNSINUCEAL-UHFFFAOYSA-N 0.000 description 1
WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
125000001979 organolithium group Chemical group 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
ODBSOAATZFAZCB-UHFFFAOYSA-N prop-1-en-2-ylbenzene;sodium Chemical compound [Na].CC(=C)C1=CC=CC=C1 ODBSOAATZFAZCB-UHFFFAOYSA-N 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP14961083A 1983-08-18 1983-08-18 ポリ−α−メチルスチレンの製造方法 Granted JPS6042406A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP14961083A JPS6042406A (ja)	1983-08-18	1983-08-18	ポリ−α−メチルスチレンの製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP14961083A JPS6042406A (ja)	1983-08-18	1983-08-18	ポリ−α−メチルスチレンの製造方法

Publications (2)

Publication Number	Publication Date
JPS6042406A JPS6042406A (ja)	1985-03-06
JPH0449564B2 true JPH0449564B2 (ko)	1992-08-11

Family

ID=15478965

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP14961083A Granted JPS6042406A (ja)	1983-08-18	1983-08-18	ポリ−α−メチルスチレンの製造方法

Country Status (1)

Country	Link
JP (1)	JPS6042406A (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS63238112A (ja) *	1987-03-20	1988-10-04	インターナシヨナル・ビジネス・マシーンズ・コーポレーシヨン	解重合可能な重合体

1983
- 1983-08-18 JP JP14961083A patent/JPS6042406A/ja active Granted

Also Published As

Publication number	Publication date
JPS6042406A (ja)	1985-03-06

Publication	Publication Date	Title
US3891721A (en)	1975-06-24	Block polymers of styrene-butadiene-2-vinylpyridine
Foss et al.	1977	A new difunctional anionic initiator
US3424822A (en)	1969-01-28	Alkali metal catalyzed styrene depolymerization
US3956419A (en)	1976-05-11	Organic reinforcing fillers for silicone rubber
JPH0338590A (ja)	1991-02-19	アルカリ金属有機化合物及びポリマー製造用の開始剤
JPH0449564B2 (ko)	1992-08-11
JP2850432B2 (ja)	1999-01-27	共重合体及びその製造方法
JPS6264806A (ja)	1987-03-23	重合方法及びその開始剤
JPH06298881A (ja)	1994-10-25	ブロツクコポリマー類の製造方法
JPS6072907A (ja)	1985-04-25	１，３−ブタジエンの重合または共重合方法
JPS6335659B2 (ko)	1988-07-15
US6291604B1 (en)	2001-09-18	Method for producing poly(p-t-butoxystyrene)
US4104455A (en)	1978-08-01	Polymerization of monomer
US5073621A (en)	1991-12-17	Removal of group VIII metal catalyst from polymer cements by extraction with aqueous dicarboxylic acid
US3798281A (en)	1974-03-19	Process for production of polyarylenes
JPS6028408A (ja)	1985-02-13	ポリ−α−メチルスチレンの製造方法
JPH0551612B2 (ko)	1993-08-03
JP3711851B2 (ja)	2005-11-02	ポリ（ｐ−ｔｅｒｔ−ブトキシスチレン）の製法
KR100529720B1 (ko)	2005-11-17	폴리(ｐ-ｔ-부톡시스티렌)의 제조방법
JPH0742344B2 (ja)	1995-05-10	オキシメチレン共重合体の製造方法
JPH1180220A (ja)	1999-03-26	共役ジエン系重合体の製造方法
US3814738A (en)	1974-06-04	Methylstyrene/styrene/isobutene terpolymer resins and process for their manufacture
KR20020016554A (ko)	2002-03-04	폴리(ｐ－ｔ－부톡시스티렌)의 제조 방법
JPH02202501A (ja)	1990-08-10	フエノール性ヒドロキシル末端基を有する重合体の製造方法
SU639175A1 (ru)	1981-09-07	Способ приготовлени катализатора дл полимеризации и сополимеризации винильных и диеновых мономеров