JPH0449214A - Transparent cosmetic of solubilization type - Google Patents
Transparent cosmetic of solubilization typeInfo
- Publication number
- JPH0449214A JPH0449214A JP15834890A JP15834890A JPH0449214A JP H0449214 A JPH0449214 A JP H0449214A JP 15834890 A JP15834890 A JP 15834890A JP 15834890 A JP15834890 A JP 15834890A JP H0449214 A JPH0449214 A JP H0449214A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- transparent
- cosmetic
- transparent cosmetic
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title abstract description 23
- 230000007928 solubilization Effects 0.000 title abstract description 8
- 238000005063 solubilization Methods 0.000 title abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 20
- 150000003904 phospholipids Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000008777 Glycerylphosphorylcholine Substances 0.000 abstract description 6
- 229960004956 glycerylphosphorylcholine Drugs 0.000 abstract description 6
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 abstract description 3
- 239000006210 lotion Substances 0.000 description 23
- 239000000203 mixture Substances 0.000 description 21
- -1 alkyl glycoside Chemical class 0.000 description 18
- 229930182470 glycoside Natural products 0.000 description 14
- 230000003750 conditioning effect Effects 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- LXNHXLLTXMVWPM-UHFFFAOYSA-N pyridoxine Chemical compound CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 description 4
- 229940088594 vitamin Drugs 0.000 description 4
- 239000011782 vitamin Substances 0.000 description 4
- 229930003231 vitamin Natural products 0.000 description 4
- 235000013343 vitamin Nutrition 0.000 description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003722 vitamin derivatives Chemical class 0.000 description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- NLEBIOOXCVAHBD-QKMCSOCLSA-N dodecyl beta-D-maltoside Chemical compound O[C@@H]1[C@@H](O)[C@H](OCCCCCCCCCCCC)O[C@H](CO)[C@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 NLEBIOOXCVAHBD-QKMCSOCLSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002772 monosaccharides Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000008160 pyridoxine Nutrition 0.000 description 2
- 239000011677 pyridoxine Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229940011671 vitamin b6 Drugs 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- DNXHEGUUPJUMQT-UHFFFAOYSA-N (+)-estrone Natural products OC1=CC=C2C3CCC(C)(C(CC4)=O)C4C3CCC2=C1 DNXHEGUUPJUMQT-UHFFFAOYSA-N 0.000 description 1
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- CSTRPYAGFNTOEQ-MGMRMFRLSA-N (2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one;octadecanoic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O.CCCCCCCCCCCCCCCCCC(O)=O CSTRPYAGFNTOEQ-MGMRMFRLSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- LGQKSQQRKHFMLI-SJYYZXOBSA-N (2s,3r,4s,5r)-2-[(3r,4r,5r,6r)-4,5,6-trihydroxyoxan-3-yl]oxyoxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@H](O)CO[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)OC1 LGQKSQQRKHFMLI-SJYYZXOBSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- BFPYWIDHMRZLRN-UHFFFAOYSA-N 17alpha-ethynyl estradiol Natural products OC1=CC=C2C3CCC(C)(C(CC4)(O)C#C)C4C3CCC2=C1 BFPYWIDHMRZLRN-UHFFFAOYSA-N 0.000 description 1
- VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- LGQKSQQRKHFMLI-UHFFFAOYSA-N 4-O-beta-D-xylopyranosyl-beta-D-xylopyranose Natural products OC1C(O)C(O)COC1OC1C(O)C(O)C(O)OC1 LGQKSQQRKHFMLI-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- SQNRKWHRVIAKLP-UHFFFAOYSA-N D-xylobiose Natural products O=CC(O)C(O)C(CO)OC1OCC(O)C(O)C1O SQNRKWHRVIAKLP-UHFFFAOYSA-N 0.000 description 1
- 239000011627 DL-alpha-tocopherol Substances 0.000 description 1
- 235000001815 DL-alpha-tocopherol Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 description 1
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- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
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- 238000005194 fractionation Methods 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 210000000496 pancreas Anatomy 0.000 description 1
- 229940055695 pancreatin Drugs 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 150000003905 phosphatidylinositols Chemical class 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は可溶化型透明化粧料に関し、更に詳しくは、特
定のモノアシル型リン脂質、特定のアルキルグリコシド
、油性物質及び水とを組合せて含有せしめることによっ
て外観が透明で、経日安定性が良好で、優れた官能特性
(Hlち塗布使用時には皮膚に良好な感触を与えながら
肌に馴染み、しっとりと且つ滑らかに仕上がりべたつき
感の無い事)を有する可溶化型透明化粧料に関する。Detailed Description of the Invention [Industrial Field of Application] The present invention relates to a solubilized transparent cosmetic composition, and more specifically, a cosmetic composition containing a combination of a specific monoacyl phospholipid, a specific alkyl glycoside, an oily substance, and water. By applying it, it has a transparent appearance, good stability over time, and excellent organoleptic properties (when applied as a coating, it blends into the skin while giving a good feel to the skin, leaving a moist and smooth finish without a sticky feeling). The present invention relates to a solubilized transparent cosmetic having the following properties.
[従来の技術及び発明が解決しようとする課題]近年、
可溶化に関する研究が数多くなされた。[Problems to be solved by conventional techniques and inventions] In recent years,
A lot of research has been done on solubilization.
その結果、可溶化剤並びに可溶化技術が進歩し、非常に
安定な可溶化物が多くの分野で利用されている。As a result, advances in solubilizers and solubilization technology have resulted in highly stable solubilized products being utilized in many fields.
それらの可溶化剤は非イオン型界面活性剤、アニオン型
界面活性剤、カチオン型界面活性剤及び両性型界面活性
剤に分類することができる。These solubilizers can be classified into nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants.
しかし、通常用いられているこれら可溶化剤は、一般に
皮膚や毛髪に刺激を起こさせ易い難点がある。最も刺激
が少ないと言われている非イオン型界面活性剤であって
も、その多くは合成物質であるポリオキシエチレン鎖を
有することによって、肌馴染みが悪い等の問題点があっ
た。However, these commonly used solubilizers generally have the disadvantage that they tend to irritate the skin and hair. Even nonionic surfactants, which are said to be the least irritating, have many problems such as poor skin affinity due to their polyoxyethylene chains, which are synthetic substances.
このような背景のもとポリオキシエチレン鎖等を持たな
い非イオン型界面活性剤である天然由来物質のモノアシ
ル型リン脂質とフルキルグリコシドが近年注目されてい
る。Against this background, naturally occurring monoacyl phospholipids and furkyl glycosides, which are nonionic surfactants that do not have polyoxyethylene chains, have attracted attention in recent years.
特開昭61−112007号公報及び特開昭61−17
6511号公報には、透明化粧料としてモノアシル型リ
ン脂質を配合した化粧料が開示されている。しかしなが
らモノアシル型リン脂質は水やアルコール等の溶媒に対
し溶解度が小さく、又これを単独で配合した可溶化型透
明化粧料は低温条件の経日安定性ム二問題がある。即ち
低温で長期間保存を行うと、化粧料が白濁したり、沈澱
が生じる等の問題点がある。JP-A-61-112007 and JP-A-61-17
Publication No. 6511 discloses a cosmetic containing a monoacyl phospholipid as a transparent cosmetic. However, monoacyl phospholipids have low solubility in solvents such as water and alcohol, and solubilized transparent cosmetics containing monoacyl phospholipids alone have problems with their stability over time at low temperatures. That is, when stored at low temperatures for a long period of time, there are problems such as the cosmetic becoming cloudy or forming a precipitate.
また特開昭59−130210号公報には穏和な清浄組
成物として、特開昭64−25709号公報にはクリー
ンルーム用皮膚化粧料として、特開平01−20303
6号公報には乳化組成物及び乳化組成物としてそれぞれ
アルキルグリコシドを配合した化粧料が開示されている
。しかしこれらの組成物であっては、本発明の目的とす
る、外観特性(i!明)、経日安定性、官能特性の全て
に亘って優れた可溶化型透明化粧料を得ることは困難で
あった。In addition, JP-A-59-130210 discloses a mild cleaning composition, JP-A-64-25709 discloses a skin cosmetic for clean rooms, JP-A-01-20303
Publication No. 6 discloses an emulsified composition and a cosmetic composition containing alkyl glycosides as the emulsified composition. However, with these compositions, it is difficult to obtain a solubilized transparent cosmetic that is excellent in all of appearance characteristics (i! brightness), stability over time, and sensory characteristics, which are the objectives of the present invention. Met.
また、可溶化剤として前記のごとくアルキルグリコシド
のみを用いた可溶化型透明化粧料にあっては、一般に可
溶化能に乏しく、特に油性物質としてエステル油のよう
な極性物質を用いた場合、低温条件(5℃以下)あるい
は高温条件(40’C以上)下に保存すると沈澱を生し
るかまたは、濁りやすく、経日安定性に問題があった。In addition, solubilized transparent cosmetics that use only alkyl glycosides as solubilizers, as described above, generally have poor solubilization ability, and especially when polar substances such as ester oils are used as oily substances, they cannot be used at low temperatures. When stored under conditions (below 5° C.) or under high temperature conditions (above 40° C.), it tends to form precipitates or become cloudy, resulting in problems in stability over time.
また外観特性(透明)、官能特性等の面でより一層の改
良の必要があった。Furthermore, there was a need for further improvement in terms of appearance characteristics (transparency), sensory characteristics, etc.
本発明は、経日安定性が良好で優れた官能特性を有する
可溶化型透明化粧料を得ることを目的としている。The object of the present invention is to obtain a solubilized transparent cosmetic that has good stability over time and excellent sensory properties.
[課題を解決する為の手段]
本発明は、下記一般式(1)又は(If)CH2−0−
R
CH−OH・・・・・・(T)
CH2−X
(上記の式中で、R
は
CI7HゴS
又は
C
l5H3
Xは
−〇
CH2−CH2−N” (CHff)ff。[Means for Solving the Problems] The present invention provides the following general formula (1) or (If) CH2-0-
R CH-OH... (T) CH2-X (In the above formula, R is CI7HgoS or C15H3 X is -0CH2-CH2-N'' (CHff)ff.
−〇
H2
CH2−N@H,、又は
e
で表されるモノアシル型リン脂質の少なくとも一種と、
下記一般式(II[)
%式%([)
(式r〕、R2は炭素数8〜22のアルキル基又はアル
ケニル基、Gは炭素数5〜6の1元糖に由来する残基、
nは1〜5の整数を表す、)で表されるアルキルグリコ
シドの少なくとも一種と、油性物質と水とを含有するこ
とを特徴とする可溶化型透明化粧料である。-〇H2 CH2-N@H, or at least one type of monoacyl phospholipid represented by e;
The following general formula (II [) % formula % ([) (formula r], R2 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, G is a residue derived from a monosaccharide having 5 to 6 carbon atoms,
This is a solubilized transparent cosmetic material containing at least one alkyl glycoside represented by (n represents an integer of 1 to 5), an oily substance, and water.
以下、本発明の構成を詳説する。The configuration of the present invention will be explained in detail below.
本発明に於ける前記一般式(1)及び(It)で表され
る化合物、即ちモノー〇−アシルー3−グリセリルホス
ホリルコリン1 モノー〇−アシル3−グリセリルホス
ホリルエタノールアミン、モノー〇−アシルー3−グリ
セリルホスホリルイノシトールとしては、例えば1−バ
ルミトイル−3グリセリルホスホリルコリン、1−ステ
アロイル−3−グリセリルホスホリルコリン、1−バル
ミトイル−3−グリセリルホスホリルエタノールアミン
、1−ステアロイル−3−グリセリルホスホリルエタノ
ールアミン、1−バルミトイル−3−グリセリルホスホ
リルイノシトール、1−ステアロイル−3−グリセリル
ホスホリルイノシトール、2−バルミトイル−3−グリ
セリルホスホリルコリン、2−ステアロイル−3−グリ
セリルホスホリルコリン、2−バルミトイル−3−グリ
セリルホスホリルエタノールアミン、2−ステアロイル
−3−グリセリルホスホリルエタノールアミン 2−バ
ルミトイル−3−グリセリルホスホリルイノシトール、
2−ステアロイル−3−グリセリルホスホリルイノシト
ール等が挙げられる。Compounds represented by the above general formulas (1) and (It) in the present invention, namely mono 0-acyl-3-glycerylphosphorylcholine 1 mono 0-acyl 3-glycerylphosphorylethanolamine, mono 0-acyl 3-glycerylphosphoryl Examples of inositol include 1-valmitoyl-3-glycerylphosphorylcholine, 1-stearoyl-3-glycerylphosphorylcholine, 1-valmitoyl-3-glycerylphosphorylethanolamine, 1-stearoyl-3-glycerylphosphorylethanolamine, and 1-valmitoyl-3-glycerylphosphorylethanolamine. Glycerylphosphorylinositol, 1-stearoyl-3-glycerylphosphorylinositol, 2-valmitoyl-3-glycerylphosphorylcholine, 2-stearoyl-3-glycerylphosphorylcholine, 2-valmitoyl-3-glycerylphosphorylethanolamine, 2-stearoyl-3-glyceryl Phosphorylethanolamine 2-valmitoyl-3-glycerylphosphorylinositol,
Examples include 2-stearoyl-3-glycerylphosphorylinositol.
前記の一般式(1)及び(II)で表される化合物は例
えば、卯黄より得られるホスファチジルコリン、ホスフ
ァチジルエタノールアミンまたは大豆より得られるホス
ファチジルイノシトールを原料として、例えば豚すい臓
抽出酵素のパンクレアチンで処理し、高速液体クロマト
グラフィーにより分画して得られる。あるいは化学的に
合成することによっても得られる。The compounds represented by the above general formulas (1) and (II) can be prepared by using, for example, phosphatidylcholine or phosphatidylethanolamine obtained from Uhuang or phosphatidylinositol obtained from soybean as a raw material, and treating it with, for example, pancreatin, an enzyme extracted from pig pancreas. It is obtained by fractionation using high performance liquid chromatography. Alternatively, it can be obtained by chemical synthesis.
本発明の可溶化型透明化粧料に於ける前記一般式(1)
、(II)で表されるモノアシル型リン脂質は可溶化剤
として一種または2種以上を組み合わせて使用される。The general formula (1) in the solubilized transparent cosmetic of the present invention
The monoacyl phospholipids represented by (II) are used alone or in combination as a solubilizer.
その配合量は組成物の総量を基準として、好ましくはO
,OO1〜5.0重責%、特に好ましくは0.01〜1
.0重量%である。The blending amount is based on the total amount of the composition, preferably O
, OO1 to 5.0%, particularly preferably 0.01 to 1
.. It is 0% by weight.
0、001重量%未満では油性物質の可溶化が悪(なる
傾向があり、50重量%よりも多くなると系中における
溶解性が低下して白濁しやすくなる傾向があり好ましく
ない。If it is less than 0,001% by weight, the solubilization of the oily substance tends to be poor, and if it is more than 50% by weight, the solubility in the system tends to decrease and cloudiness tends to occur, which is not preferable.
本発明における前記一般式(I(1)で表されるアルキ
ルグリコシドとしては、末端に炭素数8〜22のアルキ
ル基又はアルケニル基をもつ、炭素数5〜6の還元糖に
由来する残基1〜5個から構成されたものである。The alkyl glycoside represented by the general formula (I(1)) in the present invention includes a residue 1 derived from a reducing sugar having 5 to 6 carbon atoms and having an alkyl group or alkenyl group having 8 to 22 carbon atoms at the terminal. It is composed of ~5 pieces.
このGの原料としては、単糖ではグルコース。The raw material for this G is glucose among monosaccharides.
ガラクトース、キシロース、フルクトース、マンノース
、リキソース、アブビノース等が、2I!以上ではマル
トース、キシロビオース、イソマルトース、ラクトース
、スクロース、ラフィノース等が挙げられる。これらの
うち、好ましい原料は、入手性及び低コストの点におい
てグルコース、フルクトース、マルトース、スクロース
である。そして、残基2個以上から構成されたアルキル
グリコシドの場合その糖鎖の結合様式は1−2.1−3
1−4.1−6結合、更にα−1β−ビラノンド又はフ
ラノシド結合及びこれらから任意に混合されたものが可
能である。従って、例えばデシルβ−D−77’ルコシ
ド、テトラデシル−α−D−フルクトシト、ドデシル−
β−D−マルトシド、オクタデシル−α−D−スクロシ
ド等が挙げられる。Galactose, xylose, fructose, mannose, lyxose, abbinose, etc. are 2I! Examples of the above include maltose, xylobiose, isomaltose, lactose, sucrose, and raffinose. Among these, preferred raw materials are glucose, fructose, maltose, and sucrose in terms of availability and low cost. In the case of an alkyl glycoside composed of two or more residues, the binding mode of the sugar chain is 1-2.1-3
1-4.1-6 bonds, as well as α-1β-bilanondo or furanoside bonds and any mixtures thereof are possible. Thus, for example, decyl β-D-77' rucoside, tetradecyl-α-D-fructoside, dodecyl-
Examples include β-D-maltoside, octadecyl-α-D-sucroside, and the like.
本発明に於ける前記一般式(IIl)で表されるアルキ
ルグリコシドは可溶化剤として一種または2種以上を組
み合わせて使用される。その配合量は組成物の総量を基
準として、好ましくは0.01t−ti〜5.0重量%
、特に好ましくは0.1〜1.0重量%である。0.0
1重量%未満では油性物質の可溶化が悪くなる傾向があ
り、5.0重量%よりも多くなると使用時の感触が悪く
なる傾向があり好ましくない。In the present invention, the alkyl glycosides represented by the general formula (IIl) are used singly or in combination of two or more as solubilizers. The amount incorporated is preferably 0.01 t-ti to 5.0% by weight based on the total amount of the composition.
, particularly preferably 0.1 to 1.0% by weight. 0.0
If it is less than 1% by weight, the solubilization of the oily substance tends to be poor, and if it is more than 5.0% by weight, the feel during use tends to be poor, which is not preferable.
本発明に使用する油性物質とは、広義の油性物質を意味
し、天然動植物から抽出した油溶性香料(例えばベルガ
モツトオイル)や合成の油溶性香料、油熔類ビタミン類
(例えばビタミンA、ビタミンD、ビタミンE、ビタミ
ンF、ビタミンに群のビタミン、シカプリル酸ピリドキ
シン、シバルミチン酸ピリドキシン、酢酸d1−α−ト
コフェロール、ニコチンa2dl−α−トコフェロール
シバルミチン酸アスコルビル5モノバルミチン酸アスコ
ルビル、モノステアリン酸アスコルビル等のビタミン誘
導体等)、油溶性ホルモン1s(例えば、エストラジオ
ール、エチニルエストラジオール。The oil-based substances used in the present invention refer to oil-based substances in a broad sense, including oil-soluble fragrances extracted from natural animals and plants (e.g. bergamot oil), synthetic oil-soluble fragrances, oil-based vitamins (e.g. vitamin A, vitamin D, vitamin E, vitamin F, vitamins of the vitamin group, pyridoxine caprilate, pyridoxine civalmitate, d1-α-tocopherol acetate, nicotine a2 dl-α-tocopherol ascorbyl civalmitate 5 ascorbyl monobalmitate, ascorbyl monostearate, etc. vitamin derivatives, etc.), oil-soluble hormones (e.g., estradiol, ethinyl estradiol).
エストロン、ジエチルスチルベストロール等)、油溶性
色素fi(例えば、スダン■、テトラフロムフルオレセ
イン ジブロムフルオレセイン、フルオレセイン、キニ
ザリングリーンSS等)、油溶性紫外線吸収剤類(例え
ば、オキシベンゾン、2.5−ジイソプロピル桂皮酸メ
チル等)、動植物油1!(例えば、アボガド油、オリー
ブ油、アーモンド油。estrone, diethylstilbestrol, etc.), oil-soluble pigments fi (e.g., Sudan ■, tetrafluorescein, dibromefluorescein, fluorescein, quinizarin green SS, etc.), oil-soluble ultraviolet absorbers (e.g., oxybenzone, 2.5- Methyl diisopropyl cinnamate, etc.), animal and vegetable oils 1! (For example, avocado oil, olive oil, almond oil.
パーム油等)、高級脂肪族炭化水素類(例えば、流動パ
ラフィン、スクワラン、ワセリン、セレシン等)、高級
脂肪酸類(例えば、ラウリン酸、ミリスチン酸、イソス
テアリン酸、オレイン酸等)、高級アルコール類(例え
ば、ラウリルアルコール、セチルアルコール、イソステ
アリルアルコール、オクチルドデカノール等)、エステ
ル油類(例えば、ブチルステアレート、ヘキシルラウレ
ート、ジイソプロピルアジベート、イソプロピルミリス
テート、オクチルドデシルミリステート等ン等である。palm oil, etc.), higher aliphatic hydrocarbons (e.g. liquid paraffin, squalane, petrolatum, ceresin, etc.), higher fatty acids (e.g. lauric acid, myristic acid, isostearic acid, oleic acid, etc.), higher alcohols (e.g. , lauryl alcohol, cetyl alcohol, isostearyl alcohol, octyl dodecanol, etc.), ester oils (for example, butyl stearate, hexyl laurate, diisopropyl adibate, isopropyl myristate, octyl dodecyl myristate, etc.).
これらの油性物質は一種または二種以上組み合わせて使
用される。その配合量は組成物の総量を基準として、好
ましくはO,OOOl舎1省〜1.0重量%、特に好ま
しくは0.0 O1〜0.3重量%である。0.000
1重量%未満では当該油性物質固有の特性効果が少なく
なり、1.0重量%を越えてはその可溶化が困難になり
易い傾向があり好ましくない。These oily substances may be used alone or in combination of two or more. The blending amount thereof is preferably 1 to 1.0% by weight, particularly preferably 0.0 to 0.3% by weight, based on the total amount of the composition. 0.000
If it is less than 1% by weight, the characteristic effects inherent to the oily substance will be reduced, and if it exceeds 1.0% by weight, it tends to be difficult to solubilize, which is not preferable.
として、好ましくは50〜99.0重量%、特に好まし
くは60〜90重量%である。The amount is preferably 50 to 99.0% by weight, particularly preferably 60 to 90% by weight.
本発明の可溶化型透明化粧料においては、上記必須成分
に加え更にアルコールの適量を添加混合することによっ
て清涼感を与え、乾燥速度を向上し得る。その際のアル
コールの配合量は好ましくは50重量%以下、特に好ま
しくは5〜30重量%である。In the solubilized transparent cosmetic composition of the present invention, by adding and mixing an appropriate amount of alcohol in addition to the above-mentioned essential ingredients, a refreshing feeling can be imparted and the drying rate can be improved. The amount of alcohol blended in this case is preferably 50% by weight or less, particularly preferably 5 to 30% by weight.
また本発明の可溶化型透明化粧料が二層コンディノヨニ
ングローション等の場合は、公知の所要顔料を更に添加
配合することができる。顔料の配合量は好ましくは10
重量%以下、特に好ましくは0.5〜5重量%である。Further, when the solubilized transparent cosmetic of the present invention is a two-layer conditioner lotion or the like, known required pigments may be further added and blended. The amount of pigment blended is preferably 10
It is preferably 0.5 to 5% by weight or less, particularly preferably 0.5 to 5% by weight.
その際の顔料としてはカオリン、マイカ、ベンガ乞セリ
サイト、タルク、酸化亜鉛、黄酸化鉄、赤酸化鉄等が挙
げられる。Examples of pigments used in this case include kaolin, mica, sericite, talc, zinc oxide, yellow iron oxide, red iron oxide, and the like.
尚、本発明の可溶化型透明化粧料には、必要に応じて更
に、公知の保湿剤、皮膚または毛髪の栄養側、水溶性色
素、紫外線吸収剤、収れん剤、水溶性天然高分子(カゼ
インソーダ、ペクチン、キサンタンガム、カラヤガム、
ローカストビーンガム、カラギーナン等)、白濁剤(ア
クリルスチレン共重合体分散液等)、真珠様光沢付与剤
(魚鱗箔等)等を配合してもよい。The solubilized transparent cosmetic of the present invention may further contain known moisturizers, skin or hair nutrients, water-soluble pigments, ultraviolet absorbers, astringents, and water-soluble natural polymers (casein), if necessary. soda, pectin, xanthan gum, karaya gum,
Locust bean gum, carrageenan, etc.), a clouding agent (acrylic styrene copolymer dispersion, etc.), a pearl-like luster imparting agent (fish scale foil, etc.), etc. may be blended.
本発明の化粧料としては例えば、整肌化粧水拭き取り化
粧水、柔軟化粧水、アクネトリートメントロ一ンヨン、
アフターシェーフローション。Cosmetics of the present invention include, for example, skin conditioning lotion, wiping lotion, softening lotion, acne treatment lotion,
Aftershave lotion.
クレンジングローション、ヘアートニック等が挙げられ
る。Examples include cleansing lotion and hair tonic.
[実施例]
以下実施例及び比較例の記載にて本発明の詳細な説明す
る。配合量は重量%で表す。なお、実施例における外観
特性(透明性)、経日安定性、官能特性の試験方法は次
の通りである。[Examples] The present invention will be described in detail below with reference to Examples and Comparative Examples. The blending amount is expressed in weight%. The test methods for appearance characteristics (transparency), stability over time, and sensory characteristics in Examples are as follows.
(1) 外観特性(透明性)
試料組成物を30℃の恒温槽に6ケ月間放置し、450
nmの波長の光の透過率を測定した。なお、値が80%
以上であると肉眼観察でも透明である。(1) Appearance characteristics (transparency) The sample composition was left in a constant temperature bath at 30°C for 6 months, and
The transmittance of light at a wavelength of nm was measured. In addition, the value is 80%
If it is above, it is transparent even when observed with the naked eye.
(2) 経日安定性
試料組成物を45℃、0℃の恒温槽に最長6ケ月間放置
し、その濁り、沈澱等を肉眼にヱ検査した。(2) Stability over time The sample composition was left in a constant temperature bath at 45° C. and 0° C. for up to 6 months, and was visually inspected for turbidity, precipitation, etc.
(3) 官能特性 塗布使用時の感触(さっばり惑、しっとり怒。(3) Sensory characteristics The feeling when using the application (slightly confusing, moist and angry.
べたつき感、滑らかさ)、塗布後の仕上がりを専門検査
員3人によって調べ、総合評価した。(stickiness, smoothness) and finish after application were examined by three specialized inspectors and comprehensively evaluated.
実施例1〜5及び比較例1〜2 整肌化粧水第1表上段
記載の配合組成中成骨1〜3を混合溶解しく溶液1)、
別途に成分4〜8を混合溶解しく溶液2)、溶液1に溶
液2を混合し、整肌化粧水を調製し、前記諸試験を行っ
た。その結果を第1表下段に示した。Examples 1 to 5 and Comparative Examples 1 to 2 Skin conditioning lotion Solution 1) in which grown bones 1 to 3 were mixed and dissolved in the composition listed in the upper row of Table 1;
Separately, components 4 to 8 were mixed and dissolved in solution 2), and solution 2 was mixed with solution 1 to prepare a skin conditioning lotion, and the various tests described above were conducted. The results are shown in the lower part of Table 1.
第1表から判るように、モノアシル型リン脂質とアルキ
ルグリコシドの両者を含む本発明の整肌化粧水は、極性
物質であるイソプロピルミリステートを含むにも関わら
ず、透明性、経日安定性に優れた。一方、モノアシル型
リン脂質、アルキルグリコシドのどちらか一方を欠く比
較例1及び比較例2の整肌化粧水は透明性、経日安定性
が悪く、濁り、油浮きが生じた。また、本発明の整肌化
粧水は、官能特性に於いても比較例よりも優れてい実施
例6〜9.比較例3〜4 アフターシエーブローシヨン
第2表上段記載の配合組成生成分1〜6を混合熔解しく
溶液1)、別途に成分7.8を混合溶解しく溶液2)、
溶液lに溶液2を混合し、アフターシェーブローション
を調製し、前記諸試験を行った。As can be seen from Table 1, the skin conditioning lotion of the present invention containing both monoacyl phospholipids and alkyl glycosides has good transparency and stability over time, even though it contains isopropyl myristate, which is a polar substance. Excellent. On the other hand, the skin lotions of Comparative Examples 1 and 2 lacking either monoacyl phospholipids or alkyl glycosides had poor transparency and stability over time, and were cloudy and oily. Furthermore, the skin conditioning lotion of the present invention was superior to the comparative examples in terms of sensory properties as well. Comparative Examples 3 to 4 Aftershave lotion Mixture composition listed in the upper row of Table 2 Ingredients 1 to 6 were mixed and dissolved in Solution 1), Components 7 and 8 were separately mixed and dissolved in Solution 2),
Aftershave lotion was prepared by mixing Solution 2 with Solution 1, and the various tests described above were conducted.
その結果を第2表下段に示した。The results are shown in the lower part of Table 2.
第2表から判るように、モノアシル型リン脂質とアルキ
ルグリコシドの両者を含む本発明のアフターシエーブロ
ーシヨンは、透明性、経口安定性。As can be seen from Table 2, the aftershave lotion of the present invention containing both monoacyl phospholipids and alkyl glycosides is transparent and orally stable.
官能特性のすべてが良好であった。一方、モノアシル型
リン脂質、アルキルグリコシドのどちらか一方を欠く比
較例3及び4のアフターシェーブローションは、沈澱、
濁り、油浮きが生じる。この様にこれらの透明性、経日
安定性には問題があっ実)I例1o 二層型コンディ
ショニングローション
(組成) (重量%)1、 エタ
ノール 10.02、 香料(ベル
ガモツトオイル)0.13、 硫酸亜鉛
0.34、 酸化亜鉛
1.05、 ベンガラ
0.016、 タルク 1.
07、 オクタデシル−α−D−
スクロシド 0.058、 ドデ
シル−β−D−マルトシド 0.19.2−バルミト
イル−3−グリセリ
ルホスホリルエタノールアミン 0.110、 炭
酸ナトリウム 0.211、 精
製水 87.14上記の配合組
成中成分11の一部に成分3.7.8及び9を混合溶解
し、この水溶液に予め混合撹拌した成分4〜6の混合物
を添加して、撹拌下に均一分散させる。次に成分11の
残部に成分10を溶解した物を撹拌下に徐々に加え、更
に成分1に成分2を溶解した物を均一に混合して、本発
明の二層型コンディショニングローションを調製し前記
諸試験を行った。All organoleptic properties were good. On the other hand, the aftershave lotions of Comparative Examples 3 and 4 lacking either monoacyl phospholipids or alkyl glycosides showed precipitation,
Cloudiness and oil floating occur. As described above, there are problems with their transparency and stability over time) Example 1o Two-layer conditioning lotion (composition) (wt%) 1, ethanol 10.02, fragrance (bergamot oil) 0.13 , zinc sulfate
0.34, zinc oxide
1.05, Bengala
0.016, Talc 1.
07, Octadecyl-α-D-sucroside 0.058, Dodecyl-β-D-maltoside 0.19.2-Valmitoyl-3-glycerylphosphorylethanolamine 0.110, Sodium carbonate 0.211, Purified water 87.14 Above Components 3, 7, 8, and 9 are mixed and dissolved in a part of component 11 in the blended composition, and a mixture of components 4 to 6 that has been mixed and stirred in advance is added to this aqueous solution and uniformly dispersed under stirring. Next, a solution of component 10 is gradually added to the remainder of component 11 while stirring, and a solution of component 2 and component 1 is mixed uniformly to prepare the two-layer conditioning lotion of the present invention. Various tests were conducted.
この二層型コンディショニングローションの振とう時の
均一混和性を調べた結果、分離していた粉体層と水層は
所要振とう回数4回にして一体的に混和し、水中に粉体
が均一に分散した懸濁液を生成した。この結果から、こ
の二層型コンディショニングローションは、振とうによ
って容易に均一懸濁状の二層型コンディショニングロー
ションが生成し、且つ適当時間安定に保持し得て、極め
て使用し易いことを認めた。更に静置1時間後、透明無
色の水層部と淡赤色の粉体層部の二層に明瞭に分離した
美しい外観を呈した。As a result of examining the uniform miscibility of this two-layer conditioning lotion when shaking, it was found that the powder layer and water layer, which had been separated, were mixed as one after the required number of shaking four times, and the powder was uniformly mixed in the water. A suspension was produced. From these results, it was confirmed that this two-layer conditioning lotion is extremely easy to use, as it can easily be shaken to form a uniformly suspended two-layer conditioning lotion and can be stably maintained for an appropriate period of time. After being allowed to stand for 1 hour, it had a beautiful appearance that was clearly separated into two layers: a transparent colorless water layer and a pale red powder layer.
この二層型コンディショニングローションは、使用時に
べたつき感がな(、塗布後の仕上がりも良好な感触を有
する、極めて優秀な化粧料を得た。This two-layer conditioning lotion produced an extremely excellent cosmetic product that did not feel sticky during use (and had a good finish after application).
実施例10に於けるドデシル−β−D−マルトシドとオ
クタデシル−α−D−スクロシドに代えて、他のアルキ
ルグリコシドを用いて調製した二層型コンディショニン
グローションモ実施例1゜とほぼ同し挙動を示した。A two-layer conditioning lotion prepared using other alkyl glycosides in place of dodecyl-β-D-maltoside and octadecyl-α-D-sucroside in Example 10 exhibited almost the same behavior as Example 1°. Indicated.
[発明の効果コ
本発明は、特定のモノアシル型リン脂質及び特定のアル
キルグリコシドを含有せしめる事によって、外観が透明
で、経日安定性が良好で、塗布使用時には皮膚に良好な
感触を与えながら肌に馴染み、しっとりと且つ滑らかに
仕上がり、べた付き感のない、優れた有用な可溶化型透
明化粧料を提供し得る。[Effects of the Invention] By containing a specific monoacyl phospholipid and a specific alkyl glycoside, the present invention has a transparent appearance, good stability over time, and provides a good feel to the skin when applied. To provide an excellent and useful solubilized transparent cosmetic that is familiar to the skin, has a moist and smooth finish, and has no sticky feeling.
Claims (1)
ます▼、又は ▲数式、化学式、表等があります▼、Xは ▲数式、化学式、表等があります▼ ▲数式、化学式、表等があります▼、又は ▲数式、化学式、表等があります▼ である) で表されるモノアシル型リン脂質の少なくとも一種と、
下記一般式(III) G_n−R_2・・・・・・(III) (式中、R_2は炭素数8〜22のアルキル基又はアル
ケニル基、Gは炭素数5〜6の還元糖に由来する残基、
nは1〜5の整数を表す。)で表されるアルキルグリコ
シドの少なくとも一種と、油性物質と水とを含有するこ
とを特徴とする可溶化型透明化粧料。[Claims] The following general formula (I) or (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) (In the above formula, R_1 ▲There are mathematical formulas, chemical formulas, tables, etc.▼, or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, , chemical formula, table, etc. ▼) At least one type of monoacyl phospholipid represented by
The following general formula (III) G_n-R_2... (III) (In the formula, R_2 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, and G is a residue derived from a reducing sugar having 5 to 6 carbon atoms. basis,
n represents an integer of 1 to 5. ), an oily substance, and water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15834890A JP2752231B2 (en) | 1990-06-15 | 1990-06-15 | Solubilized transparent cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15834890A JP2752231B2 (en) | 1990-06-15 | 1990-06-15 | Solubilized transparent cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0449214A true JPH0449214A (en) | 1992-02-18 |
JP2752231B2 JP2752231B2 (en) | 1998-05-18 |
Family
ID=15669685
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15834890A Expired - Fee Related JP2752231B2 (en) | 1990-06-15 | 1990-06-15 | Solubilized transparent cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2752231B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0632710A (en) * | 1992-07-13 | 1994-02-08 | Shiseido Co Ltd | Skin external preparation |
WO2011081136A1 (en) | 2009-12-28 | 2011-07-07 | 株式会社資生堂 | Cosmetic preparation |
-
1990
- 1990-06-15 JP JP15834890A patent/JP2752231B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0632710A (en) * | 1992-07-13 | 1994-02-08 | Shiseido Co Ltd | Skin external preparation |
WO2011081136A1 (en) | 2009-12-28 | 2011-07-07 | 株式会社資生堂 | Cosmetic preparation |
Also Published As
Publication number | Publication date |
---|---|
JP2752231B2 (en) | 1998-05-18 |
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