JP2001288068A - Skin cosmetic - Google Patents
Skin cosmeticInfo
- Publication number
- JP2001288068A JP2001288068A JP2000104616A JP2000104616A JP2001288068A JP 2001288068 A JP2001288068 A JP 2001288068A JP 2000104616 A JP2000104616 A JP 2000104616A JP 2000104616 A JP2000104616 A JP 2000104616A JP 2001288068 A JP2001288068 A JP 2001288068A
- Authority
- JP
- Japan
- Prior art keywords
- skin
- metal soap
- effect
- particle diameter
- extract
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は化粧水、乳液、クリ
ーム、パック、頭皮ローション等の皮膚用の化粧料に関
し、さらに詳しくは使用時の感触が軽く使用後もべたつ
かず、保湿効果の持続性に優れ、しわ抑制効果、肌荒れ
改善効果に優れ、肌にはりを与えるとともに、テカリや
化粧崩れを生じ難く、経時安定性にも優れる皮膚化粧料
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to skin cosmetics such as lotions, emulsions, creams, packs, scalp lotions and the like, and more particularly, has a light touch when used, and is non-greasy even after use, and has a long-lasting moisturizing effect. The present invention relates to a skin cosmetic composition which is excellent in wrinkles, has an effect of suppressing wrinkles, improves skin roughness, gives a skin appetit, hardly causes shininess and makeup collapse, and has excellent stability over time.
【０００２】[0002]
【従来の技術】通常、人の皮膚表面は皮脂膜に覆われて
いて水分の蒸散が適度に抑制されている。そして、皮膚
の水分を適切な範囲に保つことは皮膚の健康の面から見
て非常に大切なことであり、水分が不足すると肌荒れ等
を生じやすくなる。洗顔や入浴を行うと一時的に皮脂膜
が取り除かれてしまい肌の水分が失われやすくなること
から化粧水、乳液、クリーム、美容液等の保湿化粧料を
使用して水分を補う必要がある。ここで、一般に化粧料
には保湿剤としてグリセリン、１，３−ブチレングリコ
ール、ソルビトール等の多価アルコールやピロリドンカ
ルボン酸塩等が配合されているが、これらは高湿度下に
おける水分保持力には優れているものの低湿度下におけ
る水分保持力に難があり、保湿効果の持続性が保てなか
った。そこで近年、低湿度下での水分保持力の高い保湿
成分としてキチン、キトサンおよびそれらの誘導体、蛋
白加水分解物、ヒアルロン酸等の酸性ムコ多糖類、植物
抽出物等様々な物質が研究されているが、これら保湿力
の高い保湿成分は不快なベタツキを有しており感触が重
くなるという欠点があった。2. Description of the Related Art Normally, the surface of human skin is covered with a sebum film, and the evaporation of water is appropriately suppressed. It is very important to keep skin moisture in an appropriate range from the viewpoint of skin health, and lack of moisture easily causes skin roughness and the like. If you wash your face or take a bath, the sebum film will be temporarily removed and the skin will easily lose its moisture.Therefore, it is necessary to use a moisturizing cosmetic such as a lotion, milky lotion, cream, or serum to supplement the moisture. . Here, in general, polyhydric alcohols such as glycerin, 1,3-butylene glycol, and sorbitol, pyrrolidone carboxylate, and the like are blended in the cosmetics as moisturizers. Although excellent, the water retention ability under low humidity was difficult, and the sustainability of the moisturizing effect could not be maintained. Therefore, in recent years, various substances such as chitin, chitosan and derivatives thereof, protein hydrolysates, acidic mucopolysaccharides such as hyaluronic acid, and plant extracts have been studied as moisturizing components having a high water retention ability under low humidity. However, these moisturizing components having a high moisturizing power have a disadvantage that they have unpleasant stickiness and feel heavy.
【０００３】ここで、木通（モクツウ）はアケビまたは
その他同属植物であり、蔓性の茎を採取し、輪切りにし
て乾燥させたもの等を古来より漢方薬の成分として用い
られてきた生薬である。この生薬はストレス胃潰瘍発生
予防効果｛薬第９５巻１１７９頁（１９７５年）｝、利
尿作用｛Ｃｈｅｍ．Ｐｈａｒ．Ｂｕｌｌ．第２７巻１４
６４頁（１９７９年）｝、抗炎症作用｛日本薬学会第９
０年発表会要旨集（１９７０年）｝を有することが公知
である。また、特開昭６４−４２４１１号公報、特開平
８−１３３９５６号公報においてその抽出エキスが高い
美白効果を有することが示されており、その抽出エキス
を使用した美白効果の高い化粧料や皮膚外用剤が提案さ
れている。さらに、特開平１０−７５８１号公報におい
て木通（モクツウ）の抽出エキスが皮膚保湿能力を高め
る作用を有することが示されており、その抽出エキスを
含有した保湿効果の高い皮膚外用剤が提案されている。
一方、レンゲソウはマメ科の２年草であり、この抽出エ
キスにおいても高い保湿作用、美白作用、細胞腑活作用
等を有することが判っており、特開平１−１１７８１４
号公報においてレンゲソウエキスを使用した化粧料が提
案されている。しかし、これら木通抽出エキスやレンゲ
ソウ抽出エキスを配合した化粧料や皮膚外用剤は、経時
で着色や沈殿を生じたりして安定性に問題を生じたり、
すくなからずべたつきを有して感触が悪くなり易く、ま
た、肌荒れ改善効果、しわ抑制効果が弱く、さらに、使
用後時間が経過すると分泌された皮脂等により「テカ
リ」を生じたり、化粧崩れを起こし易かった。そこで、
酸化チタンやカオリン等の無機粉末、ナイロンパウダー
やセルロース粉末等の有機樹脂粉末を配合することによ
りべたつきや化粧崩れを抑える化粧料が提案されている
（特開昭６１−２７１２０８号公報、特開平４−１８７
６１１号公報）が、これらの粉末を配合した化粧料は使
用時ののびが悪くなったり、塗布時に皮膜感や粉っぽさ
を感じたりしていた。[0003] Here, Kindori (mokutsu) is a plant of the genus Akebi or other congeners, and is a crude drug that has been used as a component of a Chinese herb since ancient times, for example, obtained by collecting vine stems, cutting them into rings, and drying them. . This crude drug has an effect of preventing stress gastric ulcer occurrence {Drug 95, 1179 (1975)}, diuretic effect {Chem. Phar. Bull. Volume 27 14
64 pages (1979), anti-inflammatory action, 9
It is publicly known to have a 0 year presentation abstract (1970). Further, JP-A-64-42411 and JP-A-8-133965 show that the extracted extract has a high whitening effect, and cosmetics and external skin with a high whitening effect using the extracted extract are disclosed. Agents have been proposed. Furthermore, Japanese Patent Application Laid-Open No. 10-7581 discloses that an extract of Mokutsu (mokutsu) has an effect of enhancing the skin moisturizing ability, and a skin external preparation containing the extract and having a high moisturizing effect has been proposed. ing.
On the other hand, astragalus is a two-year grass of the legume family, and it has been found that this extract also has a high moisturizing effect, whitening effect, cell activating effect and the like.
Japanese Patent Application Laid-Open Publication No. HEI 9-202, proposes a cosmetic using the Astragalus extract. However, cosmetics and skin external preparations containing these Kindori extract or Astragalus extract may cause stability problems such as coloring or precipitation over time,
It has a sticky appearance and is easily tacky. It was easy. Therefore,
Cosmetics that suppress stickiness and makeup loss by blending inorganic powders such as titanium oxide and kaolin, and organic resin powders such as nylon powder and cellulose powder have been proposed (JP-A-61-271208, JP-A-Hei. -187
No. 611), however, cosmetics containing these powders had poor spread during use and felt a feeling of film or powder when applied.
【０００４】[0004]
【発明が解決しようとする課題】本発明は上記課題を解
決し、使用時の感触が軽く使用後もべたつかず、保湿効
果の持続性に優れ、しわ抑制効果、肌荒れ改善効果に優
れ、肌にはりを与えるとともに、テカリや化粧崩れを生
じ難く、経時安定性にも優れる皮膚化粧料を提供するこ
とを目的とする。DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems, and has a light feel at the time of use, is not sticky even after use, is excellent in sustaining moisturizing effect, is excellent in suppressing wrinkles, is effective in improving rough skin, An object of the present invention is to provide a skin cosmetic which gives a beam, hardly causes shininess and makeup collapse, and has excellent stability over time.
【０００５】[0005]
【課題を解決するための手段】すなわち本発明は、ａ．
木通（モクツウ）またはレンゲソウの抽出エキスを乾燥
残留物として０．００００５〜２重量％、ｂ．３０％粒
径ＲAと７０％粒径ＲCとの差ＲC−ＲAが３μｍ以下また
は５０％粒径ＲBと９５％粒径ＲDとの差ＲD−ＲBが６μ
ｍ以下である金属石鹸微粒子０．１〜２０重量％、ｃ．
Ｌ−アルギニンまたはその誘導体０．０１〜１０重量％
含有することを特徴とする皮膚化粧料である。That is, the present invention provides: a.
0.00005 to 2% by weight of an extract of Mokutsu or Astragalus as a dry residue, b. 30% particle diameter R A and difference R D -R B of the difference R C -R A is 3μm or less, or 50% particle size R B and 95% particle diameter R D of 70% particle diameter R C is 6μ
m to not more than 0.1 to 20% by weight of metal soap fine particles, c.
L-arginine or its derivative 0.01 to 10% by weight
It is a skin cosmetic characterized by containing.
【０００６】[0006]
【発明の実施の形態】本発明に用いられる木通の抽出エ
キスは、木通の蔓性の茎をそのままもしくは乾燥後に炭
化水素、エステル、ケトン、エーテル、ハロゲン化炭化
水素、アルコールおよび水から選ばれる１種または２種
以上の溶媒と共に加熱還流あるいは浸漬して得るが、好
ましくは水またはエタノール、プロピレングリコール、
イソプロピルアルコール、１，３−ブチレングリコール
等の低級アルコールの１種または２種以上の溶媒で抽出
したものであり、更に好ましくは水で抽出したものであ
る。BEST MODE FOR CARRYING OUT THE INVENTION The extract of Kinatsu used in the present invention is selected from hydrocarbons, esters, ketones, ethers, halogenated hydrocarbons, alcohols and water as they are or after drying the vine stems of Kinatsu. It is obtained by heating or refluxing or dipping with one or more kinds of solvents, preferably water or ethanol, propylene glycol,
It is extracted with one or more solvents of lower alcohols such as isopropyl alcohol and 1,3-butylene glycol, and more preferably extracted with water.
【０００７】本発明に用いられるレンゲソウの抽出エキ
スは、マメ科レンゲソウの全草または種子をそのままも
しくは乾燥後に炭化水素、エステル、ケトン、エーテ
ル、ハロゲン化炭化水素、アルコールおよび水から選ば
れる１種または２種以上の溶媒と共に加熱還流あるいは
浸漬して得るが、好ましくは水またはエタノール、プロ
ピレングリコール、イソプロピルアルコール、１，３−
ブチレングリコール等の低級アルコールの１種または２
種以上の溶媒で抽出したものであり、更に好ましくは
水、エタノールおよび１，３−ブチレングリコールの１
種または２種以上溶媒の混合液で抽出したものである。
本発明の木通またはレンゲソウの抽出エキスとは抽出溶
液そのものもしくはその濃縮物を言う。[0007] The extract of Astragalus for use in the present invention is one selected from hydrocarbons, esters, ketones, ethers, halogenated hydrocarbons, alcohols and water, as it is or after drying the whole plant or seed of Astragalus. It is obtained by heating or refluxing or dipping with two or more solvents, preferably water or ethanol, propylene glycol, isopropyl alcohol, 1,3-
One or two of lower alcohols such as butylene glycol
Extracted with one or more solvents, more preferably water, ethanol and 1,3-butylene glycol.
Extracted with a mixture of species or two or more solvents.
The extract of Natsumi or Astragalus in the present invention refers to an extraction solution itself or a concentrate thereof.
【０００８】本発明に用いられる金属石鹸微粒子は炭素
数４〜３０の脂肪酸の多価金属塩であり、脂肪酸として
は例えばラウリン酸、ミリスチン酸、パルミチン酸、ス
テアリン酸、ベヘニン酸等が挙げられ、好ましくはパル
ミチン酸、ステアリン酸である。多価金属原子としては
マグネシウム、カルシウム、亜鉛、アルミニウム、鉄等
が挙げられ、好ましくはマグネシウム、カルシウム、亜
鉛である。金属石鹸微粒子の３０％粒径ＲAと７０％粒
径ＲCとの差ＲC−ＲAが３μｍ以下または５０％粒径ＲB
と９５％粒径ＲDとの差ＲD−ＲBが６μｍ以下であり、
好ましくはＲC−ＲAが２μｍ以下またはＲD−ＲBが３μ
ｍ以下である。ＲC−ＲAが３μｍを超えるかまたはＲD
−ＲBが６μｍを超えると、使用時および使用後の感触
が悪くなるだけでなく、テカリおよび化粧崩れ防止効
果、しわ抑制効果も弱くなり、また、安定性にも悪影響
を与えやすい。The metal soap fine particles used in the present invention are polyvalent metal salts of fatty acids having 4 to 30 carbon atoms. Examples of the fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid and behenic acid. Preferably, palmitic acid and stearic acid are used. Examples of the polyvalent metal atom include magnesium, calcium, zinc, aluminum, iron and the like, and preferably magnesium, calcium and zinc. The difference R C -R A is 3μm or less, or 50% particle diameter R B and 30% particle diameter R A 70% particle diameter R C metallic soap fine particles
When the difference R D -R B of 95% particle diameter R D is at 6μm or less,
Preferably, R C -R A is 2 μm or less or R D -R B is 3 μm.
m or less. If R C -R A exceeds 3 μm or R D
When -R B exceeds 6 [mu] m, not only the feel after use and during use becomes poor, shine and makeup preventing effect, wrinkle suppressing effect becomes weak, and also easy to adversely affect the stability.
【０００９】３０％粒径ＲAとは、金属石鹸粒子全重量
中の３０％の粒子がその粒径以下であることを示し、例
えば図１の一般的な金属石鹸であるステアリン酸亜鉛の
粒度累積グラフ中の累積（％）における３０％での粒径
である３．２μｍをＲAと定義する。ＲB、ＲC、ＲDも同
様に定義され、それぞれ５．３μｍ、８．３μｍ、１
９．６μｍである。従ってＲC−ＲAおよびＲD−ＲBは、
それぞれ５．１μｍ、１４．３μｍとなる。すなわち、
ＲC−ＲAおよびＲD−ＲBの各々の値が低い程、粒度分布
の範囲が狭いことを示す。なお、粒度分布の測定には一
般的な粒度分布測定法を用いる。例えば、フルイ分け
法、沈殿法、顕微鏡法、光走査法、レーザー回折散乱法
等が挙げられるが、本発明に使用する金属石鹸微粒子の
測定法においては、より微細な粒子に対して精度良く測
定が可能な光走査法、レーザー回折散乱法等が好適に使
用される。さらに、本発明に用いられる金属石鹸微粒子
においては１０μｍよりも大きな粒径粒子の全体に対す
る含有率が４％以下であることが好ましく、実質的に１
０μｍよりも大きな粒径粒子を含まないことが更に好ま
しい。The 30% particle size RA indicates that 30% of particles in the total weight of the metal soap particles are equal to or less than the particle size. For example, the particle size of zinc stearate which is a general metal soap shown in FIG. 3.2 μm, which is the particle size at 30% of the cumulative (%) in the cumulative graph, is defined as RA . R B , R C , and R D are similarly defined, and are 5.3 μm, 8.3 μm, 1
9.6 μm. Thus, R C -R A and R D -R B are
They are 5.1 μm and 14.3 μm, respectively. That is,
A lower value of each of R C -R A and R D -R B indicates that the range of the particle size distribution is narrower. Note that a general particle size distribution measuring method is used for measuring the particle size distribution. For example, sieving, sedimentation, microscopy, light scanning, laser diffraction scattering, and the like are mentioned. In the method of measuring metal soap fine particles used in the present invention, measurement is performed on finer particles with high accuracy. An optical scanning method, a laser diffraction scattering method, and the like, which can perform the above, are preferably used. Further, in the metal soap fine particles used in the present invention, the content of the particles having a particle diameter larger than 10 μm is preferably 4% or less, and substantially 1% or less.
More preferably, it does not contain particles larger than 0 μm.
【００１０】本発明の金属石鹸微粒子は通常次のように
して調製される。すなわち、炭素数４〜３０の脂肪酸の
アルカリ金属塩またはアンモニウム塩０．００１〜２０
重量％を含有する水溶液と、無機金属塩０．００１〜２
０重量％を含有する水溶液または分散液とを、生成する
金属石鹸の結晶転移開始温度以下の温度で混合して金属
石鹸分散液（スラリー）を調製してから、フィルタープ
レスや加圧濾過等を行って含有する水分をある程度除去
して金属石鹸微粒子のケーキを得る。次に、このケーキ
を水または炭素数１〜４のアルコールもしくはそれらの
混液を用いて数回洗浄して含有される無機塩等の不純物
を除去することにより精製金属石鹸ケーキを得る。さら
に、この精製金属石鹸ケーキを金属石鹸の結晶転移開始
温度以下の温度で乾燥処理することにより金属石鹸微粒
子の粉末を得ることが出来る。そして、本発明において
この金属石鹸微粒子を配合するにあたっては、乾燥前の
金属石鹸ケーキとして用いても乾燥粉末として用いても
どちらでも構わない。[0010] The metal soap fine particles of the present invention are usually prepared as follows. That is, an alkali metal salt or ammonium salt of a fatty acid having 4 to 30 carbon atoms 0.001 to 20
% Aqueous solution containing 0.001 to 2 wt.
An aqueous solution or dispersion containing 0% by weight is mixed at a temperature lower than the crystal transition onset temperature of the produced metal soap to prepare a metal soap dispersion (slurry), and then subjected to a filter press, pressure filtration, or the like. The water content is removed to some extent to obtain a cake of fine metal soap particles. Next, the cake is washed several times with water or an alcohol having 1 to 4 carbon atoms or a mixture thereof to remove impurities such as inorganic salts contained therein, thereby obtaining a purified metal soap cake. Further, by subjecting the purified metal soap cake to a drying treatment at a temperature equal to or lower than a temperature at which crystal transition of the metal soap starts, powder of metal soap fine particles can be obtained. In mixing the metal soap fine particles in the present invention, either of them may be used as a metal soap cake before drying or as a dry powder.
【００１１】ここで、結晶転移開始温度とは、金属石鹸
の結晶構造が変化し始める温度のことであり、例えば図
２のステアリン酸亜鉛の示差熱分析による熱吸収グラフ
において、吸熱開始前の勾配の延長線Ａと吸熱開始後の
勾配の延長線Ｂとの交点Ｃの温度を結晶転移開始温度と
する。例えば、ステアリン酸亜鉛で１００℃、ステアリ
ン酸カルシウムで９４℃、ステアリン酸マグネシウムで
７３℃である。Here, the crystal transition onset temperature is a temperature at which the crystal structure of the metal soap starts to change. For example, in the heat absorption graph obtained by differential thermal analysis of zinc stearate in FIG. The temperature at the intersection C between the extension line A of the above and the extension line B of the gradient after the endothermic start is defined as the crystal transition start temperature. For example, the temperature is 100 ° C. for zinc stearate, 94 ° C. for calcium stearate, and 73 ° C. for magnesium stearate.
【００１２】本発明に用いられるＬ−アルギニンは蛋白
質中に広く存在する塩基性アミノ酸であり、ゼラチン加
水分解物からフラビアン酸塩、ベンジリデン誘導体、ピ
クラート等として沈殿分離したりすることにより得られ
る。さらに、誘導体としては例えば、塩酸、硫酸、硝
酸、クエン酸等の無機または有機酸やグルタミン酸、ア
スパラギン酸等の酸性アミノ酸との塩、アミノ基をアシ
ル化したアミド化合物、ピクラート等が挙げられる。そ
して、本発明においてはこれらの中でもＬ−アルギニン
またはその塩を使用することが好ましい。L-arginine used in the present invention is a basic amino acid widely present in proteins, and can be obtained by precipitation and separation from a hydrolyzate of gelatin as a flavianate, a benzylidene derivative, a picrate or the like. Further, examples of the derivatives include salts with inorganic or organic acids such as hydrochloric acid, sulfuric acid, nitric acid, and citric acid, and salts with acidic amino acids such as glutamic acid and aspartic acid, amide compounds in which amino groups are acylated, and picrates. And in this invention, it is preferable to use L-arginine or its salt among these.
【００１３】本発明のａ．成分である木通またはレンゲ
ソウの抽出エキスは組成物全量中に乾燥残留物として
０．００００５〜２重量％であり、好ましくは０．００
０１〜１．５重量％、更に好ましくは０．０００５〜１
重量％である。０．００００５重量％未満では保湿効果
の持続性、肌にはりを与える効果が弱くなり、２重量％
を超えると経時安定性に問題を生じるだけでなくコスト
的に不利である。ただし、本発明でいう乾燥残留物とは
通常抽出エキスを１０５℃で乾燥して溶媒を除去した時
の残留物である溶質を指すが、抽出溶媒が不揮発性の場
合にはガスクロマトグラフィー、高速液体クロマトグラ
フィー等により溶媒量を定量した値から溶質量を計算値
として求め、乾燥残留物量と見なす。According to the present invention, a. The extract of the wood extract or Astragalus, a component, is 0.00005 to 2% by weight as a dry residue in the total amount of the composition, and is preferably 0.0005 to 2% by weight.
01-1.5% by weight, more preferably 0.0005-1
% By weight. If it is less than 0.00005% by weight, the moisturizing effect lasts, and the effect of giving a skin a weaker effect, and it is 2% by weight.
If it exceeds, not only will there be a problem in stability over time, but it is disadvantageous in terms of cost. However, the dry residue referred to in the present invention usually refers to a solute that is a residue when the extract is dried at 105 ° C. and the solvent is removed. When the extract solvent is non-volatile, gas chromatography, high-speed The dissolved mass is calculated as a calculated value from the value obtained by quantifying the amount of the solvent by liquid chromatography or the like, and is regarded as the amount of the dried residue.
【００１４】本発明のｂ．成分である金属石鹸微粒子は
化粧料全量中に０．１〜２０重量％であり、好ましくは
０．３〜１７重量％、更に好ましくは０．５〜１５重量
％である。０．１重量％未満であるとテカリ抑制効果お
よび化粧崩れ抑制効果が悪くなるとともに、しわ抑制効
果が弱くなり、べたつきを有するため使用後の感触も悪
くなる。２０重量％を超えると使用時の感触が悪くなる
とともに使用後に粉っぽさを感じて感触が悪くなる。な
お、通常ｂ．成分の金属石鹸微粒子は、粉末の状態で用
いる場合には直接系に添加するかもしくはエタノール、
多価アルコール等で湿潤・分散させてから系に添加し、
ケーキの状態で用いる場合にはエタノール、多価アルコ
ール等で分散させてから系に添加する。B. Metal soap fine particles as a component are 0.1 to 20% by weight, preferably 0.3 to 17% by weight, more preferably 0.5 to 15% by weight in the total amount of the cosmetic. If the amount is less than 0.1% by weight, the effect of suppressing shininess and the effect of suppressing makeup collapse are deteriorated, and the effect of suppressing wrinkles is weakened. If the content is more than 20% by weight, the feel at the time of use is deteriorated, and at the same time, the powdery feeling is felt after use and the feel is deteriorated. In addition, usually b. When the metal soap fine particles of the component are used in a powder state, they are directly added to the system or ethanol,
After wetting and dispersing with polyhydric alcohol etc., add to the system,
When used in the form of a cake, it is dispersed in ethanol, polyhydric alcohol or the like and then added to the system.
【００１５】ｃ．成分であるＬ−アルギニンまたはその
誘導体は組成物全量中に０．０１〜１０重量％であり、
好ましくは０．０５〜７重量％、更に好ましくは０．１
〜５重量％である。０．０１重量％未満では肌荒れ改善
効果およびしわ抑制効果が弱くなり、１０重量％を超え
るとべたつきを有して感触が悪くなるだけでなくコスト
的に不利である。C. The component L-arginine or a derivative thereof accounts for 0.01 to 10% by weight based on the total amount of the composition,
Preferably 0.05 to 7% by weight, more preferably 0.1
~ 5% by weight. If the amount is less than 0.01% by weight, the effect of improving skin roughness and the effect of suppressing wrinkles are weakened. If the amount exceeds 10% by weight, not only the stickiness is deteriorated, but also the cost is disadvantageous.
【００１６】なお、本発明の皮膚化粧料には、化粧料に
常用されている添加剤を本発明の性能を損なわない範囲
で配合することも可能である。例えばエタノール、イソ
プロピルアルコール等の揮発性の低級アルコール、プロ
ピレングリコール、ジプロピレングリコール、グリセリ
ン、ジグリセリン、１，３−ブチレングリコール、ポリ
エチレングリコール等の多価アルコール、流動パラフィ
ン、流動イソパラフィン、スクワラン、ワセリン、固形
パラフィン等の炭化水素系油、牛脂、豚脂、魚油等の天
然油脂、トリ２−エチルヘキサン酸グリセリル等の合成
トリグリセリド、ミリスチン酸イソプロピル、パルミチ
ン酸イソプロピル、パルミチン酸ヘキサデシル、オレイ
ン酸エチル、オレイン酸オクタデセニル、ミリスチン酸
オクチルドデシル等のエステル油、ミツロウ、カルナバ
ロウ等のロウ、直鎖および環状のジメチルポリシロキサ
ン、ポリエーテル変性ジメチルポリシロキサン、アミノ
変性ジメチルポリシロキサン等のシリコーン誘導体、セ
ラミド、コレステロール、蛋白誘導体、ラノリン、ラノ
リン誘導体、レシチン等の油性基剤、せっけん、アシル
メチルタウリン塩、アミドエーテル硫酸エステル塩等の
陰イオン性界面活性剤、アミドアミノ酸塩、アミドプロ
ピルジメチルアミノ酢酸ベタイン等の両性界面活性剤、
ポリオキシエチレンアルキルエーテル、ポリエチレング
リコールの脂肪酸エステル、ソルビタン脂肪酸エステ
ル、ポリオキシエチレンソルビタン脂肪酸エステル、ポ
リオキシエチレン硬化ひまし油、ポリグリセリン脂肪酸
エステル、ポリオキシエチレングリセリン脂肪酸エステ
ル、グリセリンモノ脂肪酸エステル、アルキルポリグル
コシド、アルカノールアミド等の非イオン性界面活性
剤、塩化アルキルトリメチルアンモニウム等の陽イオン
性界面活性剤、アルキルジメチルアミンオキシド等の半
極性界面活性剤、アルギン酸、カルボキシビニルポリマ
ー、カルボキシメチルセルロース、ヒドロキシプロピル
メチルセルロース、ヒドロキシエチルセルロース、キサ
ンタンガム等の水溶性高分子、ピロリドンカルボン酸
塩、クエン酸塩、リンゴ酸塩、食塩等の有機または無機
塩、ｐＨ調製剤である酸およびアルカリ、殺菌剤、キレ
ート剤、抗酸化剤、紫外線吸収剤、動植物由来の天然エ
キス、色素、顔料および香料を配合できる。The skin cosmetic of the present invention may contain additives commonly used in cosmetics as long as the performance of the present invention is not impaired. For example, ethanol, volatile lower alcohols such as isopropyl alcohol, propylene glycol, dipropylene glycol, glycerin, diglycerin, 1,3-butylene glycol, polyhydric alcohols such as polyethylene glycol, liquid paraffin, liquid isoparaffin, squalane, petrolatum, Hydrocarbon oils such as solid paraffin, natural fats such as tallow, lard, fish oil, synthetic triglycerides such as glyceryl tri-2-ethylhexanoate, isopropyl myristate, isopropyl palmitate, hexadecyl palmitate, ethyl oleate, oleic acid Ester oils such as octadecenyl and octyldodecyl myristate, waxes such as beeswax and carnauba wax, linear and cyclic dimethylpolysiloxanes, polyether-modified dimethylpolysiloxanes, Silicone derivatives such as mino-modified dimethylpolysiloxane, ceramide, cholesterol, protein derivatives, lanolin, lanolin derivatives, oily bases such as lecithin, soaps, acylmethyltaurine salts, anionic surfactants such as amide ether sulfates, Amidoamino acid salts, amphoteric surfactants such as amidopropyldimethylaminoacetic acid betaine,
Polyoxyethylene alkyl ether, fatty acid ester of polyethylene glycol, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hardened castor oil, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, glycerin mono fatty acid ester, alkyl polyglucoside, Nonionic surfactants such as alkanolamides, cationic surfactants such as alkyltrimethylammonium chloride, semipolar surfactants such as alkyldimethylamine oxide, alginic acid, carboxyvinyl polymer, carboxymethylcellulose, hydroxypropylmethylcellulose, hydroxy Water-soluble polymers such as ethyl cellulose and xanthan gum, pyrrolidone carboxylate, citrate, apple Salts, organic or inorganic salts such as sodium chloride, acid and alkali at a pH adjusting agent, bactericides, chelating agents, antioxidants, ultraviolet absorbers, natural extracts derived from animals and plants, dyes, pigments and perfumes can be blended.
【００１７】[0017]
【実施例】次に実施例によって本発明を更に詳細に説明
する。 実施例１〜７および比較例１〜７ 表１に示す金属石鹸微粒子を使用して表３および表４に
示す皮膚化粧料を調整し、下記の方法により評価を行っ
た。ただし、添加成分として表２に示す３成分を共通添
加成分Ａに使用したが、金属石鹸Ｃは実際には金属石鹸
ケーキとして系に配合している為、エタノール量はケー
キから持ち込まれる量を含めた値として示した。すなわ
ち、配合系内でのエタノール量が総量として１０重量％
であることを示している。なお、配合時には金属石鹸ま
たは金属石鹸ケーキをエタノールに十分分散させてから
系に添加した。そして、表１の金属石鹸微粒子の粒度分
布は以下のようにして測定した。Next, the present invention will be described in more detail by way of examples. Examples 1 to 7 and Comparative Examples 1 to 7 Skin cosmetics shown in Tables 3 and 4 were prepared using metal soap fine particles shown in Table 1, and evaluated by the following methods. However, although the three components shown in Table 2 were used for the common additive component A as the additive components, since the metal soap C is actually blended into the system as a metal soap cake, the ethanol amount includes the amount brought from the cake. Values are shown. That is, the total amount of ethanol in the blending system is 10% by weight.
Is shown. In addition, at the time of blending, the metal soap or the metal soap cake was sufficiently dispersed in ethanol and then added to the system. And the particle size distribution of the metal soap fine particles of Table 1 was measured as follows.
【００１８】金属石鹸微粒子０．５ｇに１０ｍｌのエタ
ノールを加え、日本精機株式会社製の超音波分散器を用
いて５分間超音波分散を行った。次に測定溶媒としてエ
タノールを循環している日機装株式会社製マイクロトラ
ック粒度分布測定装置（ＳＰＡ型）に得られた金属石鹸
分散液をＤＶ値が０．６〜０．８になるまで添加し、こ
の状態における各サンプルの粒度分布を測定した。な
お、表１中のＣ（２０％ステアリン酸亜鉛ケーキ）は、
前述の方法により調製した金属石鹸ケーキにその含有さ
れる金属石鹸量（理論値）の３倍量の３０％エタノール
水溶液を添加してから濾過するという濾過洗浄工程を３
回行う（計９倍量の３０％エタノール水溶液を使用）こ
とにより得た精製金属石鹸ケーキであり、その組成は金
属石鹸ケーキを１０５℃で２時間乾燥したときの乾燥残
留物の値により金属石鹸量として計算した。10 ml of ethanol was added to 0.5 g of the metal soap fine particles, and ultrasonic dispersion was performed for 5 minutes using an ultrasonic disperser manufactured by Nippon Seiki Co., Ltd. Next, the obtained metal soap dispersion was added to a Nikkiso Co., Ltd. Microtrac particle size distribution analyzer (SPA type) circulating ethanol as a measurement solvent until the DV value became 0.6 to 0.8, The particle size distribution of each sample in this state was measured. In Table 1, C (20% zinc stearate cake)
A filtration and washing step of adding a 30% aqueous ethanol solution in an amount 3 times the amount (theoretical value) of the metal soap contained in the metal soap cake prepared by the above-described method and then filtering is performed.
This is a purified metal soap cake obtained by performing the above operation twice (a total of 9 times the amount of a 30% aqueous ethanol solution). The composition of the metal soap cake is determined by the value of the dried residue obtained when the metal soap cake is dried at 105 ° C. for 2 hours. Calculated as quantity.
【００１９】また、使用した木通抽出エキスは次のよう
にして調製した。木通の茎乾燥粉砕物３０ｇに３００ｍ
ｌの水を加えて７０℃に加熱し、還流しながら３時間温
浸した後濾過して木通抽出エキスを得た。そして、木通
抽出エキスを１０５℃で乾燥させた時の乾燥残留物は
１．３％であった。一方、レンゲソウ抽出エキスは一丸
ファルコス（株）製“ファルコレックスレンゲソウ”を
使用した。そして、レンゲソウ抽出エキスを１０５℃で
乾燥させた時の乾燥残留物は１．１％であった。結果を
表３および表４に示す。In addition, the used Kinatsu extract was prepared as follows. 300m for 30g of dried and crushed stalks of Kodori
The mixture was heated to 70 ° C., digested for 3 hours while refluxing, and then filtered to obtain an extract of Kinatsu. Then, the dried residue obtained by drying the Kodomo extract at 105 ° C. was 1.3%. On the other hand, “Falco Rex Vetchusou” manufactured by Ichimaru Falcos Co., Ltd. was used as the extract of Astragalus. Then, the dried residue when the Astragalus extract was dried at 105 ° C. was 1.1%. The results are shown in Tables 3 and 4.
【００２０】（１）使用時の感触 ２０名の女性（２０才〜３５才）をパネラーとし、洗顔
した後に皮膚化粧料を使用した時の感触について下記の
ように判定し、２０名の平均値を求めて、平均値１．５
点以上を使用時の感触の軽い化粧料であると評価した。 ２点：使用時に肌へのなじみが良くべたつきも無く軽い
感触であると感じた場合 。１点：使用時にややなじみが悪いかもしくはややべた
つきが有り若干重い感触であると感じた場合。 ０点：使用時に肌へのなじみが悪いかもしくはべたつき
が有り重い感触であると感じた場合。(1) Feeling at the time of use Twenty women (20 to 35 years old) were used as panelists, and the feeling at the time of using the skin cosmetic after washing their face was judged as follows. To obtain an average value of 1.5
The above evaluations were evaluated as cosmetics having a light touch when used. 2 points: When the skin feels light and has no stickiness during use. 1 point: When used, it feels slightly uncomfortable or slightly sticky and feels slightly heavy. 0 point: When used, the skin feels bad or sticky and feels heavy.
【００２１】（２）使用後の感触 ２０名の女性（２０才〜３５才）をパネラーとし、洗顔
した後に皮膚化粧料を使用して１０分後の肌の感触につ
いて下記のように判定し、２０名の平均値を求めて、平
均値１．５点以上を使用後にべたつきがない化粧料であ
ると評価した。 ２点：肌に粉っぽさやべたつきが無いと感じた場合。 １点：肌にやや粉っぽさが残るかもしくはややべたつく
と感じた場合。 ０点：肌に粉っぽさが残るかもしくは常にべたつくと感
じた場合。(2) Feeling after use Twenty women (20 to 35 years old) were used as panelists, and after washing their face, the skin feeling after 10 minutes using skin cosmetics was determined as follows. The average value of 20 persons was obtained, and an average value of 1.5 or more was evaluated as a non-sticky cosmetic after use. 2 points: When feeling that there is no powdery or sticky skin. 1 point: Skin feels slightly powdery or slightly sticky. 0 point: If the skin remains powdery or feels always sticky.
【００２２】（３）保湿効果の持続性 ２０名の女性（２０才〜３５才）をパネラーとし、洗顔
した後に皮膚化粧料を使用して２時間後の肌のうるおい
について下記のように判定し、２０名の平均値を求め
て、平均値１．５点以上を保湿効果の持続性の良好な化
粧料であると評価した。 ２点：使用直後と変わらず肌が十分うるおっていると感
じた場合。 １点：使用直後と比べてやや肌のうるおいが足りないと
感じた場合。 ０点：使用直後と比べて明らかに肌のうるおいが足りな
いと感じた場合。(3) Persistence of Moisturizing Effect Twenty women (20 to 35 years old) were used as panelists, and after washing their face, using skin cosmetics, the moisture of the skin after 2 hours was judged as follows. The average value of 20 persons was determined, and an average value of 1.5 or more was evaluated as a cosmetic having good moisturizing effect and good durability. 2 points: When the skin feels sufficiently moist as in immediately after use. 1 point: When feeling that the moisture of the skin is slightly less than immediately after use. 0 point: when the user feels that the skin is clearly less moist than immediately after use.
【００２３】（４）肌荒れ改善効果 肌荒れを生じた１０名の女性（２４才〜３３才）をパネ
ラーとし、皮膚化粧料を一日２回ずつ連続２週間使用し
た時の肌の状態について下記のように判定し、２０名の
平均値を求めて、平均値１．５点以上を肌荒れ改善効果
のある化粧料であると評価した。 ２点：肌荒れが明らかに治ってきたと感じた場合。 １点：肌荒れがやや治ってきたと感じた場合。 ０点：肌荒れ改善効果が全く見られないと感じた場合。(4) Effect of improving skin roughness The skin condition when 10 women (24 to 33 years old) having skin roughness were used as panelists and skin cosmetics were used twice a day for two consecutive weeks is described below. The average value of 20 persons was determined, and an average value of 1.5 or more was evaluated as a cosmetic having an effect of improving skin roughness. 2 points: When the user feels that the rough skin has clearly recovered. 1 point: When the user feels that the rough skin has healed a little. 0 point: When feeling that the effect of improving skin roughness is not seen at all.
【００２４】（５）しわ抑制効果 ２０名の女性（２０才〜３５才）をパネラーとし、皮膚
化粧料を一日２回ずつ連続２週間使用した時の肌の状態
について下記のように判定し、２０名の平均値を求め
て、平均値１．５点以上をしわ抑制効果に優れた化粧料
であると評価した。 ２点：しわが明らかに目立たなくなったと感じた場合。 １点：しわがやや目立たなくなったと感じた場合。 ０点：しわ抑制効果が全く無いと感じた場合。(5) Wrinkle Suppressing Effect Twenty women (aged 20 to 35) were panelists, and the skin condition was evaluated as follows when the skin cosmetics were used twice a day for two consecutive weeks. The average value of 20 persons was evaluated, and an average value of 1.5 or more was evaluated as a cosmetic having an excellent wrinkle suppressing effect. 2 points: When wrinkles are felt to be clearly inconspicuous. 1 point: When wrinkles are felt to be slightly inconspicuous. 0 point: When it is felt that there is no wrinkle suppressing effect.
【００２５】（６）肌のはり ２０名の女性（２０才〜３５才）をパネラーとし、皮膚
化粧料を一日２回ずつ連続２週間使用した時の肌の状態
について下記のように判定し、２０名の平均値を求め
て、平均値１．５点以上を肌にはりを与える効果のある
化粧料であると評価した。 ２点：明らかに肌にはりがでたと感じた場合。 １点：やや肌にはりがでたと感じた場合。 ０点：肌にはりがでないと感じた場合。(6) Skin Beam A panel of 20 women (aged 20 to 35) was evaluated as follows on the condition of the skin when the skin cosmetics were used twice a day for two consecutive weeks. The average value of 20 persons was evaluated, and an average value of 1.5 or more was evaluated as a cosmetic having an effect of giving a skin patch. 2 points: When the user clearly feels that the skin has peeled off. 1 point: When the skin feels slightly peeled. 0 point: When the skin feels no sticking.
【００２６】（７）テカリおよび化粧崩れ防止効果 ２０名の女性（２０才〜３５才）をパネラーとし、朝洗
顔した後に乳液を使用してから市販の固形ファンデーシ
ョンを使用し、５時間後の肌の状態について下記のよう
に判定し、２０名の平均値を求めて、平均値１．５点以
上をテカリおよび化粧崩れ防止効果の良好な化粧料であ
ると評価した。２点：テカリがでていなく化粧もちも良
いと感じた場合。 １点：ややテカリがでてくるかやや化粧崩れを生じてい
ると感じた場合。 ０点：明らかにテカリを生じるかもしくは化粧崩れが生
じていると感じた場合。(7) Effect of Preventing Shininess and Collapse of Makeup Twenty women (20 to 35 years old) were used as panelists. After washing their face in the morning, using an emulsion and then using a commercially available solid foundation, the skin after 5 hours The condition was evaluated as follows, and the average value of 20 persons was obtained. An average value of 1.5 or more was evaluated as a cosmetic having an excellent effect of preventing shine and makeup collapse. 2 points: When you feel that the makeup is good without shine. 1 point: When it is felt that shininess appears slightly or makeup collapse has occurred. 0 point: When it is felt that shininess is apparent or makeup has been lost.
【００２７】（８）経時安定性 化粧料を透明ガラス容器に密封して０℃、２５℃および
４０℃で３ヶ月間保存し、その外観を観察して、下に示
す３段階で評価した。 ○：安定性良好（いずれの温度においても外観の変化が
ない場合。） △：安定性やや不良（いずれかの温度において若干沈
殿、分離を生じるか、または若干着色を生じた場合。） ×：安定性不良（いずれかの温度において沈殿、分離を
生じるか、または着色が著しい場合。）(8) Stability over time The cosmetic was sealed in a transparent glass container and stored at 0 ° C., 25 ° C. and 40 ° C. for 3 months, and its appearance was observed and evaluated according to the following three grades. ：: good stability (when there is no change in appearance at any temperature) △: slightly poor stability (when some precipitation, separation or slight coloring occurs at any temperature) ×: Poor stability (if precipitation, separation occurs or coloring is significant at any temperature)
【００２８】[0028]
【表１】 [Table 1]
【００２９】注）ＲA：３０％粒径 ＲB：５０％粒径 ＲC：７０％粒径 ＲD：９５％粒径 ＊１；ケーキの組成（ステアリン酸亜鉛：２１．６重量
％、エタノール：２３．５２重量％、精製水：５４．８
８重量％）[0029] Note) R A: 30% particle diameter R B: 50% particle diameter R C: 70% particle diameter R D: 95% particle size * 1; composition cake (zinc stearate: 21.6 wt%, Ethanol: 23.52% by weight, purified water: 54.8
8% by weight)
【００３０】[0030]
【表２】 [Table 2]
【００３１】[0031]
【表３】 [Table 3]
【００３２】注１；カーボポール ９４０（ＢＦ−Ｇｏ
ｏｄｒｉｃｈ社）Note 1: Carbopol 940 (BF-Go)
odrich)
【００３３】[0033]
【表４】 [Table 4]
【００３４】注１；ピーチリーフリキッド Ｂ（一丸フ
ァルコス（株）） 注２；アロエエキスベラ（一丸ファルコス（株）） 注３；カーボポール ９４０（ＢＦ−Ｇｏｏｄｒｉｃｈ
社）Note 1: Peach Leaf Liquid B (Ichimaru Falcos Co., Ltd.) Note 2: Aloe Extract Vera (Ichimaru Falcos Co., Ltd.) Note 3: Carbopol 940 (BF-Goodrich)
Company)
【００３５】実施例１〜７より、本発明の成分を用いた
皮膚化粧料はいずれも使用時の感触が軽く使用後もべた
つかず、保湿効果の持続性に優れ、しわ抑制効果、肌荒
れ改善効果に優れ、肌にはりを与えるとともに、テカリ
や化粧崩れを生じ難く、経時安定性にも優れていた。一
方、比較例１〜７では十分な性能が得られていない。つ
まり、比較例１ではａ．成分が配合されていないことか
ら保湿効果の持続性および肌にはりを与える効果が弱く
なっており、比較例２ではｂ．成分が配合されていない
ことから使用後の感触、テカリおよび化粧崩れ防止効果
が悪くなるとともに、しわ抑制効果が弱くなっている。
また、比較例３ではｃ．成分が配合されていないことか
ら肌荒れ改善効果、しわ抑制効果が弱くなっており、比
較例４および比較例５ではａ．成分に変えて他の植物抽
出エキスが配合されていることから、肌荒れ改善効果、
しわ抑制効果、肌にはりを与える効果において十分な性
能が得られていない。比較例６および比較例７ではｂ．
成分に変えて本発明の範囲外の金属石鹸粒子を配合して
いることから使用時および使用後の感触、テカリおよび
化粧崩れ防止効果、しわ抑制効果、経時安定性等が悪く
なっている。From Examples 1 to 7, all skin cosmetics using the components of the present invention have a light feel at the time of use, are not sticky even after use, have an excellent moisturizing effect, an effect of suppressing wrinkles and an effect of improving skin roughness. It was excellent in giving a scalp to the skin, hardly causing shine and makeup collapse, and also excellent in stability over time. On the other hand, in Comparative Examples 1 to 7, sufficient performance was not obtained. That is, in Comparative Example 1, a. Since no component was added, the durability of the moisturizing effect and the effect of giving the skin a weakened skin were weakened. Since the ingredients are not blended, the feeling after use, the shine and the effect of preventing makeup collapse are deteriorated, and the effect of suppressing wrinkles is weakened.
In Comparative Example 3, c. Since no component was blended, the skin roughness improving effect and the wrinkle suppressing effect were weak. In Comparative Examples 4 and 5, a. Because other plant extracts are combined instead of ingredients, skin roughening improvement effect,
Sufficient performance has not been obtained in the effect of suppressing wrinkles and the effect of imparting skin to the skin. In Comparative Examples 6 and 7, b.
Since metal soap particles outside the scope of the present invention are blended in place of the components, the feeling at the time of use and after use, the effect of preventing shine and makeup collapse, the effect of suppressing wrinkles, the stability over time, and the like are deteriorated.
【００３６】実施例８〜１０ 表１に示す金属石鹸微粒子を使用して表６に示す水中油
型乳液である皮膚化粧料を調整し、実施例１〜７と同様
の方法により評価を行った。ただし、添加成分として表
５に示す１４成分を共通添加成分Ｂに使用したが、金属
石鹸Ｃは前述と同様に金属石鹸ケーキとして系に配合し
ている為、エタノール量はケーキから持ち込まれる量を
含めた値として示している。すなわち、配合系内でのエ
タノール量が総量として１０重量％であることを示して
いる。なお、配合時には金属石鹸または金属石鹸ケーキ
をエタノールに十分分散させてから系に添加した。そし
て、木通抽出エキスは実施例１〜７と同じのものを使用
した。結果を表６に示す。Examples 8 to 10 Skin cosmetics as oil-in-water emulsions shown in Table 6 were prepared using the metal soap fine particles shown in Table 1 and evaluated in the same manner as in Examples 1 to 7. . However, the 14 components shown in Table 5 were used for the common additive component B as the additive components. However, since the metal soap C is blended in the system as a metal soap cake as described above, the amount of ethanol is the amount brought in from the cake. It is shown as a value that includes it. That is, it shows that the total amount of ethanol in the blending system is 10% by weight. In addition, at the time of blending, the metal soap or the metal soap cake was sufficiently dispersed in ethanol and then added to the system. The same extract as used in Examples 1 to 7 was used as the extract of Kodori. Table 6 shows the results.
【００３７】[0037]
【表５】 [Table 5]
【００３８】[0038]
【表６】 [Table 6]
【００３９】実施例８〜１０より、本発明の乳液はいず
れも使用時の感触が軽く使用後もべたつかず、保湿効果
の持続性に優れ、しわ抑制効果、肌荒れ改善効果に優
れ、肌にはりを与えるとともに、テカリや化粧崩れを生
じ難く、経時安定性にも優れていた。As can be seen from Examples 8 to 10, the emulsions of the present invention all have a light feel upon use, are not sticky even after use, are excellent in sustaining moisturizing effects, are excellent in suppressing wrinkles, are effective in improving rough skin, and are effective in applying skin. In addition to being less likely to cause shine and makeup collapse, and excellent in stability over time.
【００４０】実施例１１および実施例１２ 表１に示す金属石鹸微粒子を使用して表６に示す水中油
型クリームである皮膚化粧料を調整し、（１）〜（７）
は実施例１〜７の方法により、そして（８）経時安定性
については下記の方法により評価を行った。ただし、添
加成分として表７に示す１３成分を共通添加成分Ｃとし
て使用し、木通抽出エキスは実施例１〜７と同じのもの
を使用した。結果を表６に示す。なお、金属石鹸は乳化
後にそのまま系に添加した。Example 11 and Example 12 Skin cosmetics which are oil-in-water creams shown in Table 6 were prepared using the metal soap fine particles shown in Table 1, and (1) to (7).
Was evaluated by the methods of Examples 1 to 7, and (8) the stability over time was evaluated by the following method. However, the 13 components shown in Table 7 were used as common additional components C as the additional components, and the same kind of extract as used in Examples 1 to 7 was used as the extract of Kindori. Table 6 shows the results. The metal soap was added to the system as it was after emulsification.
【００４１】（８）経時安定性 化粧料を透明ガラス容器に密封して−５℃、２５℃およ
び４５℃で１ヶ月間保存したときの状態を調査し、下に
示す３段階で評価した。 ○：安定性良好（いずれの温度においても外観の変化が
なくブツ等も生じない場合。） △：安定性やや不良（いずれかの温度において僅かに沈
殿を生じるか僅かに分離が見られる場合。または僅かに
ブツ、ダマを生じた場合。） ×：安定性不良（いずれかの温度において明らかに沈殿
を生じるか分離した場合。またはブツやダマを生じた場
合。）(8) Stability over time The cosmetics were sealed in a transparent glass container and stored for 1 month at -5 ° C, 25 ° C and 45 ° C, and evaluated according to the following three grades. ：: Good stability (in the case where there is no change in appearance and no blemishes occur at any temperature) Δ: Slightly poor stability (in the case where slight precipitation occurs or slight separation is observed at any temperature). X: poor streaks or lint.) X: Poor stability (when precipitation or separation clearly occurs at any temperature, or when lump or lump occurs)
【００４２】[0042]
【表７】 [Table 7]
【００４３】実施例１１および実施例１２より、本発明
のクリームはいずれも使用時の感触が軽く使用後もべた
つかず、保湿効果の持続性に優れ、しわ抑制効果、肌荒
れ改善効果に優れ、肌にはりを与えるとともに、テカリ
や化粧崩れを生じ難く、経時安定性にも優れていた。From the results of Examples 11 and 12, the creams of the present invention all have a light feel at the time of use, are not sticky even after use, are excellent in sustaining moisturizing effects, are excellent in suppressing wrinkles, and are effective in improving rough skin. Along with giving a beam, it was hard to cause shininess and makeup collapse and was excellent in stability over time.
【００４４】実施例１３および実施例１４ 表１に示す金属石鹸微粒子を使用して表６に示す油中水
型クリームである皮膚化粧料を調整し、実施例１１およ
び実施例１２の方法により評価を行った。ただし、添加
成分として表８に示す１１成分を共通添加成分Ｄとして
使用し、木通抽出エキスは実施例１〜７と同じのものを
使用した。結果を表６に示す。なお、金属石鹸は乳化後
にそのまま系に添加した。Examples 13 and 14 Skin cosmetics which are water-in-oil creams shown in Table 6 were prepared using the metal soap fine particles shown in Table 1 and evaluated by the methods of Examples 11 and 12. Was done. However, the 11 components shown in Table 8 were used as the common additive components D as the additive components, and the same kind of extract as used in Examples 1 to 7 was used for the extract of Kindori. Table 6 shows the results. The metal soap was added to the system as it was after emulsification.
【００４５】[0045]
【表８】 [Table 8]
【００４６】実施例１３および実施例１４より、本発明
のクリームはいずれも使用時の感触が軽く使用後もべた
つかず、保湿効果の持続性に優れ、しわ抑制効果、肌荒
れ改善効果に優れ、肌にはりを与えるとともに、テカリ
や化粧崩れを生じ難く、経時安定性にも優れていた。From the results of Examples 13 and 14, the creams of the present invention all have a light feel at the time of use, are not sticky even after use, have excellent moisturizing effects, are excellent in suppressing wrinkles and are effective in improving rough skin. Along with giving a beam, it was hard to cause shininess and makeup collapse and was excellent in stability over time.
【００４７】[0047]
【発明の効果】本発明の保湿化粧料は使用時の感触が軽
く使用後もべたつかず、保湿効果の持続性に優れ、しわ
抑制効果、肌荒れ改善効果に優れ、肌にはりを与えると
ともに、テカリや化粧崩れを生じ難く、経時安定性にも
優れていた。EFFECT OF THE INVENTION The moisturizing cosmetic of the present invention has a light feel at the time of use, is not sticky even after use, has excellent durability of moisturizing effect, is excellent in suppressing wrinkles and improving skin roughness, gives skin a shine, And the makeup was hardly disintegrated, and the stability over time was excellent.
【図１】金属石鹸の一般品であるステアリン酸亜鉛の粒
度分布および粒度累積グラフを示す。FIG. 1 is a graph showing a particle size distribution and a particle size accumulation of zinc stearate which is a general product of a metal soap.
【図２】金属石鹸の一般品であるステアリン酸亜鉛の示
差熱分析結果を示す。FIG. 2 shows the results of differential thermal analysis of zinc stearate, which is a general metal soap.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4C083 AA111 AA112 AA122 AB352 AC022 AC062 AC072 AC102 AC122 AC182 AC241 AC242 AC342 AC392 AC482 AC542 AC581 AC582 AD042 AD092 AD112 AD172 AD352 CC05 DD33 EE06 EE07 EE12 EE13 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4C083 AA111 AA112 AA122 AB352 AC022 AC062 AC072 AC102 AC122 AC182 AC241 AC242 AC342 AC392 AC482 AC542 AC581 AC582 AD042 AD092 AD112 AD172 AD352 CC05 DD33 EE06 EE07 EE12 EE13
Claims (1)
の抽出エキスを乾燥残留物として０．００００５〜２重
量％、ｂ．３０％粒径ＲAと７０％粒径ＲCとの差ＲC−
ＲAが３μｍ以下または５０％粒径ＲBと９５％粒径ＲD
との差ＲD−ＲBが６μｍ以下である金属石鹸微粒子０．
１〜２０重量％、ｃ．Ｌ−アルギニンまたはその誘導体
０．０１〜１０重量％含有することを特徴とする皮膚化
粧料。1. A method comprising: a. 0.00005 to 2% by weight of an extract of Mokutsu or Astragalus as a dry residue, b. The difference between the 30% particle diameter R A 70% particle diameter R C R C -
R A is 3μm or less, or 50% particle size R B and 95% particle diameter R D
The difference R D -R B metal soap particles is 6μm or less 0 between.
1-20% by weight, c. A skin cosmetic comprising 0.01 to 10% by weight of L-arginine or a derivative thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000104616A JP2001288068A (en) | 2000-04-06 | 2000-04-06 | Skin cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000104616A JP2001288068A (en) | 2000-04-06 | 2000-04-06 | Skin cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001288068A true JP2001288068A (en) | 2001-10-16 |
Family
ID=18618127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000104616A Pending JP2001288068A (en) | 2000-04-06 | 2000-04-06 | Skin cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001288068A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007523195A (en) * | 2004-02-23 | 2007-08-16 | ストラテジック サイエンス アンド テクノロジーズ， エルエルシー | Topical delivery of nitric oxide to improve body and skin appearance |
| US8603519B2 (en) | 1997-09-17 | 2013-12-10 | Strategic Science & Technologies, Llc | Topical delivery of L-arginine to cause beneficial effects |
| US8604081B2 (en) | 2009-06-24 | 2013-12-10 | Strategic Science & Technologies, Llc | Topical composition containing ibuprofen |
| US9050365B2 (en) | 2004-04-19 | 2015-06-09 | Strategic Science & Technologies, Llc | Transdermal delivery of beneficial substances effected by a hostile biophysical environment |
| US9072659B2 (en) | 2009-06-24 | 2015-07-07 | Strategic Science & Technologies, Llc | Topical composition containing naproxen |
| US9226909B2 (en) | 2004-04-19 | 2016-01-05 | Strategic Science & Technologies, Llc | Beneficial effects of increasing local blood flow |
| US9289495B2 (en) | 2010-12-29 | 2016-03-22 | Strategic Science & Technologies, Llc | Systems and methods for treatment of allergies and other indications |
| US9463158B2 (en) | 2009-06-24 | 2016-10-11 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US11684624B2 (en) | 2009-06-24 | 2023-06-27 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
-
2000
- 2000-04-06 JP JP2000104616A patent/JP2001288068A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8603519B2 (en) | 1997-09-17 | 2013-12-10 | Strategic Science & Technologies, Llc | Topical delivery of L-arginine to cause beneficial effects |
| JP2007523195A (en) * | 2004-02-23 | 2007-08-16 | ストラテジック サイエンス アンド テクノロジーズ， エルエルシー | Topical delivery of nitric oxide to improve body and skin appearance |
| US9226909B2 (en) | 2004-04-19 | 2016-01-05 | Strategic Science & Technologies, Llc | Beneficial effects of increasing local blood flow |
| US9050365B2 (en) | 2004-04-19 | 2015-06-09 | Strategic Science & Technologies, Llc | Transdermal delivery of beneficial substances effected by a hostile biophysical environment |
| US9463158B2 (en) | 2009-06-24 | 2016-10-11 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9737543B2 (en) | 2009-06-24 | 2017-08-22 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9161915B2 (en) | 2009-06-24 | 2015-10-20 | Strategic Science & Technologies, Llc | Delivery of ibuprofen and other compounds |
| US9072659B2 (en) | 2009-06-24 | 2015-07-07 | Strategic Science & Technologies, Llc | Topical composition containing naproxen |
| US11684624B2 (en) | 2009-06-24 | 2023-06-27 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9457092B2 (en) | 2009-06-24 | 2016-10-04 | Strategic Science & Technologies, Llc | Delivery of ibuprofen and other compounds |
| US8604081B2 (en) | 2009-06-24 | 2013-12-10 | Strategic Science & Technologies, Llc | Topical composition containing ibuprofen |
| US9492458B2 (en) | 2009-06-24 | 2016-11-15 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US10898489B2 (en) | 2009-06-24 | 2021-01-26 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9675619B2 (en) | 2009-06-24 | 2017-06-13 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9155701B2 (en) | 2009-06-24 | 2015-10-13 | Strategic Science & Technologies, Llc | Delivery of ibuprofen and other compounds |
| US10682357B2 (en) | 2009-06-24 | 2020-06-16 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US10172865B2 (en) | 2009-06-24 | 2019-01-08 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9833456B2 (en) | 2010-12-29 | 2017-12-05 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9498482B2 (en) | 2010-12-29 | 2016-11-22 | Strategic Science & Technologies, Llc | Treatment of erectile dysfunction and other indications |
| US9289495B2 (en) | 2010-12-29 | 2016-03-22 | Strategic Science & Technologies, Llc | Systems and methods for treatment of allergies and other indications |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4634768B2 (en) | A skin aging prevention effect improving agent, a production method thereof, a composition for preventing skin aging using the same, and a skin external preparation containing the same. | |
| JP3908126B2 (en) | Epidermal keratinization normalizing agent and skin external preparation containing the same | |
| JP3513872B2 (en) | External preparation for skin | |
| JP2001288068A (en) | Skin cosmetic | |
| JPH10279466A (en) | Preparation for external use | |
| JPH0532556A (en) | Skin agent for external use | |
| JP2000229835A (en) | Cosmetic material for improving dullness | |
| JPH10194947A (en) | Cosmetic composition containing extract of plant of family cannabaceae | |
| JP3342050B2 (en) | Cosmetics | |
| JP2000344697A (en) | Long-chain branched alcohol and cosmetic and external preparation produced by using the alcohol | |
| JP3101090B2 (en) | External preparation for skin | |
| JP4310008B2 (en) | Cosmetics | |
| JP3686394B2 (en) | Anti-aging agent, Maillard reaction inhibitor, collagenase activity inhibitor and cosmetics for preventing skin aging containing these | |
| JP2858257B2 (en) | Cosmetics | |
| JP2001316238A (en) | Skin cosmetic | |
| JP2000109420A (en) | Cosmetic against aging | |
| JP2002060332A (en) | Cosmetic for skin | |
| JP3429939B2 (en) | External preparation for skin | |
| JP2781626B2 (en) | Solubilized transparent cosmetic | |
| JPH08119829A (en) | External medicine for skin | |
| JPH07133208A (en) | Cosmetic | |
| JPH10182409A (en) | Cosmetic | |
| JPS60163806A (en) | Skin pharmaceutical for external use | |
| JP3887596B2 (en) | Skin preparation for moisturizing and skin preparation for improving rough skin | |
| JP3113116B2 (en) | Cosmetics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070316 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20090218 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090303 |
|
| A02 | Decision of refusal |
Effective date: 20090602 Free format text: JAPANESE INTERMEDIATE CODE: A02 |