JPH0439474B2 - - Google Patents

Info

Publication number: JPH0439474B2
Authority: JP; Japan
Prior art keywords: reaction; catalyst; keto; sorbose; gulonic acid
Prior art date: 1983-09-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP58161888A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6054338A (ja

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-09-05

Filing date

1983-09-05

Publication date

1992-06-29

1983-09-05 Application filed filed Critical

1983-09-05 Priority to JP58161888A priority Critical patent/JPS6054338A/ja

1985-03-28 Publication of JPS6054338A publication Critical patent/JPS6054338A/ja

1992-06-29 Publication of JPH0439474B2 publication Critical patent/JPH0439474B2/ja

Status Granted legal-status Critical Current

Links

238000006243 chemical reaction Methods 0.000 claims description 44
239000003054 catalyst Substances 0.000 claims description 31
239000000243 solution Substances 0.000 claims description 18
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
VBUYCZFBVCCYFD-NUNKFHFFSA-N 2-dehydro-L-idonic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)C(=O)C(O)=O VBUYCZFBVCCYFD-NUNKFHFFSA-N 0.000 claims description 11
VBUYCZFBVCCYFD-UHFFFAOYSA-N D-arabino-2-Hexulosonic acid Natural products OCC(O)C(O)C(O)C(=O)C(O)=O VBUYCZFBVCCYFD-UHFFFAOYSA-N 0.000 claims description 11
LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 claims description 11
239000007864 aqueous solution Substances 0.000 claims description 11
229910052793 cadmium Inorganic materials 0.000 claims description 10
229910052697 platinum Inorganic materials 0.000 claims description 9
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
229910052763 palladium Inorganic materials 0.000 claims description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
239000007789 gas Substances 0.000 claims description 6
239000001301 oxygen Substances 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 4
RGHNJXZEOKUKBD-QTBDOELSSA-N L-gulonic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O RGHNJXZEOKUKBD-QTBDOELSSA-N 0.000 claims description 2
230000001590 oxidative effect Effects 0.000 claims description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
238000000034 method Methods 0.000 description 8
238000007254 oxidation reaction Methods 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
-1 organic acid salts Chemical class 0.000 description 4
235000011121 sodium hydroxide Nutrition 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000011521 glass Substances 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
239000002904 solvent Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
GQXSDDHYUVYJCQ-NHRVJRKFSA-N [(3as,4as,8ar,8bs)-2,2,7,7-tetramethyl-4a,5,8a,8b-tetrahydro-[1,3]dioxolo[3,4]furo[1,3-d][1,3]dioxin-3a-yl]methanol Chemical compound O([C@H]12)C(C)(C)OC[C@@H]1O[C@]1(CO)[C@H]2OC(C)(C)O1 GQXSDDHYUVYJCQ-NHRVJRKFSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
229910052797 bismuth Inorganic materials 0.000 description 2
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
238000007664 blowing Methods 0.000 description 2
239000003518 caustics Substances 0.000 description 2
239000012295 chemical reaction liquid Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910052745 lead Inorganic materials 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229930003268 Vitamin C Natural products 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003570 air Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
239000011668 ascorbic acid Substances 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001661 cadmium Chemical class 0.000 description 1
XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
238000003541 multi-stage reaction Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
230000001360 synchronised effect Effects 0.000 description 1
235000019154 vitamin C Nutrition 0.000 description 1
239000011718 vitamin C Substances 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Saccharide Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP58161888A 1983-09-05 1983-09-05 ２−ケト−ｌ−グロン酸の製造法 Granted JPS6054338A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP58161888A JPS6054338A (ja)	1983-09-05	1983-09-05	２−ケト−ｌ−グロン酸の製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP58161888A JPS6054338A (ja)	1983-09-05	1983-09-05	２−ケト−ｌ−グロン酸の製造法

Publications (2)

Publication Number	Publication Date
JPS6054338A JPS6054338A (ja)	1985-03-28
JPH0439474B2 true JPH0439474B2 (ru)	1992-06-29

Family

ID=15743898

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58161888A Granted JPS6054338A (ja)	1983-09-05	1983-09-05	２−ケト−ｌ−グロン酸の製造法

Country Status (1)

Country	Link
JP (1)	JPS6054338A (ru)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3618135A1 (de) *	1986-05-30	1987-12-03	Bayer Ag	Verfahren zur herstellung von oxetan-3-carbonsaeuren
DE4307388A1 (de) *	1993-03-10	1994-09-15	Zuckerindustrie Verein	Verfahren und Vorrichtung zur Herstellung von monooxydierten Produkten aus Kohlenhydraten, Kohlenhydratderivaten und primären Alkoholen

1983
- 1983-09-05 JP JP58161888A patent/JPS6054338A/ja active Granted

Also Published As

Publication number	Publication date
JPS6054338A (ja)	1985-03-28

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US4242525A (en)	1980-12-30	Process for producing salts of pyruvic acid
US4599446A (en)	1986-07-08	Process for the preparation of 2-keto-L-gulonic acid
JPS648638B2 (ru)	1989-02-14
SU641872A3 (ru)	1979-01-05	Способ получени бутендолдиацетатов
JPS6040453B2 (ja)	1985-09-11	ポリエチレングリコ−ル酸の製造方法
JPS6039063B2 (ja)	1985-09-04	ヒドロキシ酢酸の製造方法
JPH0223559B2 (ru)	1990-05-24
JPS6010016B2 (ja)	1985-03-14	ヒドロキシ酢酸の製造方法
JP2552513B2 (ja)	1996-11-13	（ポリ）オキシエチレンアルキルエーテル化合物の酸化方法
JPH10158227A (ja)	1998-06-16	Ｎ，ｎ−ジメチルホルムアミドの製造方法
KR820000822B1 (ko)	1982-05-13	피루빈산염의 제조방법
JPS6041656B2 (ja)	1985-09-18	（ポリ）オキシエチレンエ−テル化合物の酸化方法
NL9302127A (nl)	1995-07-03	Werkwijze voor het bereiden van 2-keto-aldonzuren.
JPS6115863B2 (ru)	1986-04-26
JPS6115862B2 (ru)	1986-04-26