JPH0438762B2 - - Google Patents
Info
- Publication number
- JPH0438762B2 JPH0438762B2 JP57502349A JP50234982A JPH0438762B2 JP H0438762 B2 JPH0438762 B2 JP H0438762B2 JP 57502349 A JP57502349 A JP 57502349A JP 50234982 A JP50234982 A JP 50234982A JP H0438762 B2 JPH0438762 B2 JP H0438762B2
- Authority
- JP
- Japan
- Prior art keywords
- functional
- monomers
- monomer
- grafting
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 description 56
- 238000000034 method Methods 0.000 description 52
- 239000002904 solvent Substances 0.000 description 17
- 230000005855 radiation Effects 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 229920005989 resin Polymers 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- 229910052731 fluorine Inorganic materials 0.000 description 13
- 239000011737 fluorine Substances 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- -1 cyano, hydroxysulfonyl Chemical group 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical group [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 10
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 239000012986 chain transfer agent Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 238000007334 copolymerization reaction Methods 0.000 description 8
- 239000012528 membrane Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical group O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000002221 fluorine Chemical class 0.000 description 6
- 239000003014 ion exchange membrane Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000005341 cation exchange Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000003729 cation exchange resin Substances 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 4
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 4
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 3
- VAJGLWNYOMVAOX-UHFFFAOYSA-N 2,3,4,4,4-pentafluorobut-2-enoic acid Chemical compound OC(=O)C(F)=C(F)C(F)(F)F VAJGLWNYOMVAOX-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 3
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical class FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 2
- QARLOMBMXGVKNV-UHFFFAOYSA-N 1,2,2-trifluoroethenesulfonyl fluoride Chemical compound FC(F)=C(F)S(F)(=O)=O QARLOMBMXGVKNV-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- KMEUSKGEUADGET-UHFFFAOYSA-N 1-hydroxy-2,2,6,6-tetramethylpiperidin-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)N1O KMEUSKGEUADGET-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 229940023913 cation exchange resins Drugs 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 150000002791 naphthoquinones Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- YPJUNDFVDDCYIH-UHFFFAOYSA-N perfluorobutyric acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)F YPJUNDFVDDCYIH-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- SEOJLEWUZIGEMA-UHFFFAOYSA-N 1-hydroxy-2,2,6,6-tetramethylpiperazine Chemical compound CC1(C)CNCC(C)(C)N1O SEOJLEWUZIGEMA-UHFFFAOYSA-N 0.000 description 1
- JUQWFONZRDXAAB-UHFFFAOYSA-N 1-methyl-1-oxidopiperazin-1-ium Chemical compound C[N+]1([O-])CCNCC1 JUQWFONZRDXAAB-UHFFFAOYSA-N 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- IWYWFRZTVHUEGY-UHFFFAOYSA-N ethyl 2,3,4,4,4-pentafluorobut-2-enoate Chemical compound CCOC(=O)C(F)=C(F)C(F)(F)F IWYWFRZTVHUEGY-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- XGZOSJVPXJTPEB-UHFFFAOYSA-N methyl 2,3,4,4,4-pentafluorobut-2-enoate Chemical group COC(=O)C(F)=C(F)C(F)(F)F XGZOSJVPXJTPEB-UHFFFAOYSA-N 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920006009 resin backbone Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Fuel Cell (AREA)
Description
è«æ±ã®ç¯å²
ïŒ ã«ããªã³äº€ææš¹èã補é ããæ¹æ³ã§ãã€ãŠã
åŒïŒ CF2ïŒCFïŒCF2ïŒo åã³åŒ CF2ïŒCFââïŒCFXâCFXïŒn ïŒåŒäžïŒ¡ã¯ã«ã«ããã·ã«ãC1ãC6ã¢ã«ã³ãã·
ã«ã«ããã«ãããããã·C1ãC6ã¢ã«ã³ãã·âã«
ã«ããã«ãã·ã¢ããããããã·ã¹ã«ããã«ããã«
ãªãã¹ã«ããã«ããŸãã¯R1åã³R2ãæ°ŽçŽ åã³C1
ãC6ã¢ã«ãã«ããç¬ç«ã«éžã°ããâCOâNR1R2
åºã§ãããäžæ¹ã®ïŒžã¯åŒçŽ ã§ãããä»æ¹ã®ïŒžã¯å¡©
çŽ ãåŒçŽ åã³ããªãã«ãªãã¡ãã«åºããéžã°ãã
ïœã¯ïŒã12ã®æŽæ°ã§ãããïœã¯ïŒãïŒã®æŽæ°ã§ã
ããïŒ ã®ååç©ãããªã矀ããéžã°ããå°ãªããšãïŒçš®
ã®å®èœã¢ãããŒãåŒïŒ CF2ïŒCFY ïŒåŒäžïŒ¹ã¯å¡©çŽ ãåŒçŽ ãåã¯ããªãã«ãªãã¡ã
ã«åºã§ãããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒçš®ã®éå®èœçµåã¢ãããŒãšå ±ã«ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹äžã«å ±é
åããã€ãŠæŸå°ç·ã°ã©ããããããšãå«ã¿ãå®èœ
ã¢ãããŒãšéå®èœã¢ãããŒãšã®ã¢ã«æ¯ãïŒïŒïŒã
ïŒïŒ20ã®ç¯å²ã«ããæ¹æ³ã ïŒ åŒçŽ å«æããªããŒéªšæ Œåºå¹¹ãåŒçŽ åãšãã¬ã³
ã®ãã¢ããªããŒåã¯ã³ããªããŒã§ããè«æ±ã®ç¯å²
第ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ åãšãã¬ã³ãããã©ãã«ãªããšãã¬ã³ã§
ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ åãšãã¬ã³ãã¯ããããªãã«ãªããšãã¬
ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ã³ããªããŒããããµãã«ãªããããã¬ã³åäœ
ãå«ãã§ãªãè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ å«æããªããŒéªšæ Œåºå¹¹ãããªããã©ãã«
ãªããšãã¬ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ åŒçŽ å«æããªããŒåºå¹¹ãããªã¯ããããªãã«
ãªããšãã¬ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ åŒçŽ å«æããªããŒåºå¹¹ãããã©ãã«ãªããšã
ã¬ã³ãšåèšã³ããªããŒã«ãããŠçµã¿èŸŒãŸãããã
ãµãã«ãªããããã¬ã³ã3.5ã12.5ïŒ ïœïŒïœã®æ¿
床ç¯å²ã«ãããããµãã«ãªããããã¬ã³ãšã®ã³ã
ãªããŒã§ããè«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé èšèŒ
ã®æ¹æ³ã ïŒ åŒåã³ã®ååç©ããã³ã¿ãã«ãªãããã³
é žãC1ãC6ã¢ã«ãã«ãã³ã¿ãã«ãªãããããšãŒ
ãåã³ããªãã«ãªãããã«ã¹ã«ããã«ãã«ãªãªã
ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããããã«èš
èŒã®æ¹æ³ã ïŒïŒ åèšC1ãC6ã¢ã«ãã«ãã³ã¿ãã«ãªããã
ããšãŒããã¡ãã«ãã³ã¿ãã«ãªãããããšãŒãå
ã³ãšãã«ãã³ã¿ãã«ãªãããããšãŒãã§ããè«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åŒã®éå®èœã¢ãããŒãããã©ãã«ãªããš
ãã¬ã³åã³ã¯ããããªãã«ãªããšãã¬ã³ã§ããè«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹
æ³ã ïŒïŒ åèšã¢ã«æ¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²ã«ãã
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åèšã¢ã«æ¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²ã«ãã
è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æŸå°ç·ã°ã©ãããγâç·ãâç·åã³é»å
ããŒã ãããªã矀ããéžã°ããæŸå°ç·ã®ãããã
ã®åœ¢ã«ããç §å°ã«ãããã®ã§ããè«æ±ã®ç¯å²ç¬¬ïŒ
é ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ··åç©ãåºå¹¹ãèšæœ€ããèœåã
ãã溶å€äžã«æº¶è§£ãããŠããè«æ±ã®ç¯å²ç¬¬ïŒé ã
第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ·»å åã«ãã€ã€ãã©ã ããã€ã€
ãã©ã ãèšæœ€ããèœåã®ãã溶å€ã§åŠçãããè«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹
æ³ã ïŒïŒ 溶å€ããã«ãšã³ããã·ã¬ã³ãããªã¯ããã
ãªãã«ãªããšã¿ã³åã³ããã©ãã«ãªããšãã¬ã³ã®
ãªãªãŽããŒãããªã矀ããéžã°ããè«æ±ã®ç¯å²ç¬¬
ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ··åç©ãè¿œå çã«å°ãªããšãïŒ
çš®ã®éåæå¶å€åã³å°ãªããšãïŒçš®ã®é£é移åå€
ãå«ãã§ãªãè«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ãã
ããã«èšèŒã®æ¹æ³ã ïŒïŒ éåæå¶å€ãé žçŽ ã®ååšã«ãããïœâãã³
ãŸããã³ãããã¿ããã³ããããããã³ãé ¢é ž
é ãïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãªããœ
ãããªãžã³âïŒâãªãã·ããïŒïŒïŒïŒïŒïŒïŒâã
ãã©âã¡ãã«ããã©ãžã³ââãªãã·ããåã³ã¯
ãã©ãã«ãããªã矀ããéžã°ããè«æ±ã®ç¯å²ç¬¬ïŒ
ïŒé èšèŒã®æ¹æ³ã ïŒïŒ éåæå¶å€ãã¢ãããŒãšé£é移åå€ã®å šæ··
åç©ã®0.001ãïŒïŒ ïœïŒïœã®æ¿åºŠç¯å²ã«ããè«æ±
ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æ¿åºŠç¯å²ã0.01ã0.5ïŒ ïœïŒïœã§ããè«æ±
ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ é£é移åå€ãã¯ãããã«ã ãåå¡©åççŽ ã
ãžã¡ãã«ãã«ã ã¢ããåã³ãããã®æ··åç©ãããª
ã矀ããéžã°ãã溶å€ã§ããè«æ±ã®ç¯å²ç¬¬ïŒïŒé
ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ é£é移åå€ã«ãããã¢ãããŒã®æ¿åºŠã10ã
60ïŒ ïœïŒïœã®ç¯å²ã«ããè«æ±ã®ç¯å²ç¬¬ïŒïŒé ã第
ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ åèšç¯å²ã30ã50ïŒ ïœïŒïœã§ããè«æ±ã®ç¯
å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã æè¡åé æ¬çºæã¯ãæ°èŠãªã«ããªã³äº€ææš¹èãç¹ã«ã¢ã«
ã«ãªéå±ã®æ°Žé žåç©ã®æº¶æ¶²åã³å¡©çŽ ã®è£œé ã«çšã
ããããããªé»è§£æ§œäžã®ã€ãªã³äº€æèãšããŠäœ¿çš
ããã®ã«é©ããã«ããªã³äº€æææã®è£œæ³ã«é¢ã
ãã èæ¯æè¡ ã¢ã«ã«ãªéå±æ°Žé žåç©æº¶æ¶²åã³å¡©çŽ ã¯ãäžè¬
ã«ãæ°Žéã»ã«åã¯ãã€ã€ãã©ã ã»ã«äžã§è£œé ãã
ããæ°Žéã»ã«ã¯ãæ¿åãªã¢ã«ã«ãªéå±æ°Žé žåç©æº¶
液ãçæãããšããå©ç¹ãæãããããããæ°Žé
ãå«ãæµåºæ¶²ã®å»æ£ã«äŒŽãåé¡ãçãããäžæ¹ã
éœæ¥µåã³é°æ¥µãéœã€ãªã³åã³é°ã€ãªã³äžŠã³ã«é»è§£
質ãééããããå€å質ãã€ã€ãã©ã ã«ãã€ãŠå
é¢ãããŠãããã€ã€ãã©ã ã»ã«ã¯ãäžèšæµåºæ¶²ã®
åé¡ãçããªãããã©ãã (1) æ¯èŒç匱ããäžçŽãã¢ã«ã«ãªéå±æ°Žé žåç©æº¶
液ãçæãããèžçºã®ããã®ã³ã¹ããå¢å ã
ãããŸã (2) çæã¬ã¹ããªãã¡æ°ŽçŽ åã³å¡©çŽ ãæ··åãããŠ
ããŸãå¯èœæ§ãããã ãšããæ¬ ç¹ãæããã éœæ¥µåã³é°æ¥µãã«ããªã³æŽ»æ§ã€ãªã³äº€æèã«ã
ã€ãŠåé¢ãããŠããã»ã«ã®äœ¿çšã«ãã€ãŠæ°Žéã»ã«
åã³ãã€ã€ãã©ã ã»ã«ã®äž¡è ã®æ¬ ç¹ã解決ããè©Š
ã¿ããªãããŠããããããã¯ãæ£ã«åž¯é»ãããã€
ãªã³ã®ã¿ãééãããé»è§£è³ªãééãããªããã
ãªãéžæééæ§ã®èã§ãããå¡©çŽ ã»ã«ã«ãããã
ã®çšéã«é©åœãªã«ããªã³æŽ»æ§ã€ãªã³äº€æèã¯ãäŸ
ãã°ãã«ããªã³äº€æåºãäŸãã°ãã¹ã«ãããŒãã
ã«ã«ããã·ã¬ãŒãåã³ãã¹ãããŒããå«ãåææ
æ©ã³ããªããŒææãããªããã®ãå«ãã ç¹ã«ãé·æéã®ã»ã«æ¡ä»¶ã«èããåæãã«ãªã
ããªããŒãäŸãã°ãåæšãNAFIONãã®ããšã§
EIããŠãã³ç€Ÿã«ãã€ãŠè£œé åã³è²©å£²ãããŠããã
å æ°Žå解ããããéåŒçŽ åçåæ°ŽçŽ ïŒäŸãã°ããª
ããã©ãã«ãªããšãã¬ã³ïŒãšãã«ãªãã¹ã«ãã³å
ãã«ãã«ãªãããã«ãšãŒãã«ãšã®ã³ããªããŒã«åº
ã¥ãããã«ãã«ãªãã¹ã«ãã³é žèãæçšã§ããã ãããã®èã補é ãããæš¹èã®ååæ§é äžã®æŽ»
æ§éšäœã¯ããã«ãªãã¹ã«ãã³åãã«ãã«ãªããã
ã«ãšãŒãã«æåã«ãã€ãŠäžããããããããã®éš
äœã¯ãæš¹èã®éªšæ Œæ§é ã«å¯ŸãããšãŒãã«çµåã«ã
ã€ãŠçµåãããåŽéäžã«ååšããããã®ãããªè
ã¯ãäŸãã°ãç±³åœç¹èš±ç¬¬2636851å·ã第3017338
å·ã第3496077å·ã第3560568å·ã第2967807å·ã
ãã³ç¬¬3282875å·åã³è±åœç¹èš±ç¬¬1184321å·ã«èšèŒ
ãããŠããã äžè¬ã«ãããã®ãã«ãªãããªããŒã¯ã©ãžã«ã«é
å觊åªãå«ããšãã«ãžãšã³åã¯ãµã¹ãã³ãžãšã³äž
ã«ãããŠãã«ãªãã«ãŒãã³ã¢ãããŒã®éååã¯å ±
éåã«ãã€ãŠè£œé ããããåŸãããããªããŒã¯æº¶
èæ圢å å·¥ã®ãããªéåžžã®æ圢æ¹æ³ã«ãã€ãŠèã«
æ圢ãããã çºæã®é瀺 æã ã¯ã«ããªã³æŽ»æ§ã€ãªã³äº€æèã«äœ¿çšããã®
ã«é©ãããã«ãªãããªããŒã®æ°èŠãªè£œé æ¹æ³ãèŠ
ãåºããããã®æ¹æ³ã¯ã掻æ§éšäœãåã¯æŽ»æ§éšäœ
ã«è»¢åããåŸãå®èœåºãå«ãã¢ãããŒãæŸå°ç·ã°
ã©ããåæ³ã«ãã€ãŠéããã²ã³åããªããŒã®éªšæ Œ
åºå¹¹äžã«çŽæ¥ã°ã©ãããããç¹ã§åŸæ¥æè¡ã®æ¹æ³
ãšç°ã€ãŠãããããªããŒã®éªšæ Œåºå¹¹ãç²æ«åã¯ã
ã€ã«ã 圢ç¶ã§ãã€ãŠããããšããããšãæã ã®æ¹
æ³ã®èããç¹åŸŽã§ããã ããã«ç¹ã«ã以åŸèŠå®ããããããªå®èœã¢ãã
ãŒã以åŸèŠå®ããããããªéå®èœçµåã¢ãããŒå
ã³éããã²ã³ååŒçŽ å«æçåæ°ŽçŽ ããªããŒéªšæ Œåº
å¹¹ãæŸå°ç·ã°ã©ããæ¹æ³ã«å ±ã«ä»ãããå Žåãå®
èœã¢ãããŒåã³éå®èœçµåã¢ãããŒãåæã«ããª
ããŒã«å ±éåãåã³ã°ã©ããããå®èœåºãå«ãåŽ
éãæããåŒçŽ å«æçåæ°ŽçŽ ããªããŒåºå¹¹ãæã
ãã«ããªã³äº€ææš¹èã圢æããããšãããã€ãã
ãããã®å®èœåºã¯ããèªäœã«ããªã³äº€æã®ããã®
掻æ§éšäœã§ãããåã¯å æ°Žå解ã®ãããªéåžžã®æ¹
æ³ã«ãã掻æ§éšäœã«å®¹æã«çµåãããã åŸã€ãŠæã ã¯ã«ããªã³äº€ææš¹èã補é ããæ¹æ³
ã§ãã€ãŠã åŒïŒ CF2ïŒCFïŒCF2ïŒo åã³ åŒïŒ CF2ïŒCFââïŒCFXâCFXïŒn ïŒåŒäžïŒ¡ã¯ã«ã«ããã·ã«ãC1ãC6âã¢ã«ã³ã
ã·ã«ã«ããã«ãããããã·C1ãC6ã¢ã«ã³ãã·ã«
ã«ããã«ãã·ã¢ããããããã·ã¹ã«ããã«ããã«
ãªãã¹ã«ããã«ãåã¯R1åã³R2ãæ°ŽçŽ åã³C1ã
C6ã¢ã«ãã«ããç¬ç«ã«éžã°ããåºâCOâNR1R2
ã§ãããäžæ¹ã®ïŒžãåŒçŽ ã§ãããä»æ¹ã®ïŒžãå¡©
çŽ ãåŒçŽ åã³ããªãã«ãªãã¡ãã«åºããéžã°ãã
ïœãïŒã12ã®æŽæ°ã§ãããïœãïŒãïŒã®æŽæ°ã§ã
ããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒçš®ã®å®èœã¢ãããŒãåŒïŒ CF2ïŒCFY ïŒåŒäžïŒ¹ã¯å¡©çŽ ãåŒçŽ ãåã¯ããªãã«ãªãã¡ã
ã«åºã§ãããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒåã®éå®èœçµåã¢ãããŒãšå ±ã«ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹äžã«å ±é
åããã€ãŠæŸå°ç·ã°ã©ããããããšãå«ãã§ãªã
æ¹æ³ãæäŸããã éããã²ã³åçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹ã¯é
åŒçŽ åããããåã¯éšåçã«åŒçŽ åãããŠãã
ãã奜ãŸããåŒçŽ å«æçåæ°ŽçŽ åºå¹¹ã¯åŒçŽ åãã
ããšãã¬ã³ã®ãã¢ããªããŒåã¯ã³ããªããŒãç¹ã«
ããã©ãã«ãªããšãã¬ã³ãããã¯ã¯ããããªãã«
ãªããšãã¬ã³ã®ãã¢ããªããŒåã¯ã³ããªããŒã§ã
ãã代衚çãªå¥œãŸããåºå¹¹ã¯ããªããã©ãã«ãªã
ãšãã¬ã³ïŒPTFEïŒãããªã¯ããããªãã«ãªããš
ãã¬ã³ïŒPCTFEïŒã䞊ã³ã«ããã©ãã«ãªããšã
ã¬ã³ãšãããµãã«ãªããããã¬ã³ãšã®ã³ããªããŒ
ã§ãã€ãŠãã®ã³ããªããŒã«æ··å ¥ããããããµãã«
ãªããããã¬ã³ã3.5ã12.5ïŒ ïœïŒïœã®ç¯å²ã«ã
ãã³ããªããŒã«å¯Ÿããäžè¬å称ã§ããFEPã§ã
ãã æã ã®æ¹æ³ã«ãããŠäœ¿çšã®ããã®å¥œãŸããåŒ
ã®å®èœã¢ãããŒã¯ãã³ã¿ãã«ãªãããã³é žãã¡ã
ã«ãã³ã¿ãã«ãªãããããšãŒãåã³ãšãã«ãã³ã¿
ãã«ãªãããããšãŒãã®ãããªã¢ã«ãã«ãã³ã¿ã
ã«ãªãããããšãŒã䞊ã³ã«ããªãã«ãªãããã«ã¹
ã«ããã«ãã«ãªãªããå«ãã奜ãŸããåŒã®éå®
èœçµåã¢ãããŒã¯ããã©ãã«ãªããšãã¬ã³åã³ã¯
ããããªãã«ãªããšãã¬ã³ã§ããã ã¢ãããŒææã®æ··åç©ã¯æ¶²äœåœ¢ç¶ã§ãªããã°ãª
ãããå¿ èŠãªå Žåããããã®æº¶æ¶²ã補é ãããã
ã«éåžžã®æº¶å€ãçšãããéåžžãã®ã¢ãããŒææã®
ãã¡ã®äžã€ã¯ããèªäœä»ã®ã¢ãããŒææã溶解ã
ã液äœçžãäžããã§ãããããã®ä»ã«ãéœåã®ã
ãããšã«ã䜿çšããã溶å€ã¯åºå¹¹ææã«æµžéãã
ããèšæœ€ãããããã®ã§ãããããã«ãã€ãŠã¢ã
ããŒã®æº¶æ¶²ãåºå¹¹ææãéããŠé©åœã«åžåããã
ãã é©åœãªæº¶å€ã¯äŸãã°ãã«ãšã³åã³ãã·ã¬ã³äžŠã³
ã«ããªã¯ããããªãã«ãªããšã¿ã³ã®ãããªå¡©çŽ å
çåæ°ŽçŽ åã³ããã©ãã«ãªããšãã¬ã³ã®ãªãªãŽã
ãŒãäŸãã°ããã©ãã«ãªããšãã¬ã³ã®ããã©ããŒ
åã³ãã³ã¿ããŒãã§ãããåºå¹¹ææãã¢ãããŒã®
æ·»å åã«ãã®ãããªæº¶å€ã§äºåèšæœ€ããã æŸå°ç·ã°ã©ããã®ããããæ¢ç¥ã®æ¹æ³ã䜿çšã
ãŠãããäŸãã°åºå¹¹åã³ã¢ãããŒææãé£ç¶ãã
ãã¯æç¶ç §å°ã«å ±ã«ä»ãããåã¯ãã®åºå¹¹ãã¢ã
ããŒææã«æ¥è§Šãããåã«äºåç §å°ããŠããã奜
ãŸããã¯åºå¹¹åã³ã¢ãããŒææã¯å ±ã«ç §å°ããïŒ
åºäœã§ãã埮ç²å圢ç¶ãåã¯ã·ãŒããããã¯ãã€
ã«ã ãšããŠã§ååšãåŸãåºå¹¹ã¯æ··åãããã¢ãã
ãŒææãå«ã液äœçžäžã«æµžæŒ¬ããããã®å šäœã¯ïŒž
ç·ãé»åããŒã ããããã¯å¥œãŸããã¯Î³ç·ã«ãã
ç §å°ã«ä»ãããã 奜ãŸããã¯ãã®ã°ã©ããæ¹æ³ã¯é žçŽ ã®äžååšäž
ã§è¡ãªãããã 掻æ§ã¢ãããŒã®èªå°äœãäŸãã°ã¡ãã«ãã«ãã«
ãªãããããšãŒãã®ãããªã«ã«ããã·ãšã¹ãã«ã
ãã°ã©ããããã»ã¹ã«ãããŠäœ¿çšãããå Žåã«ã
å æ°Žå解ã®ãããªãã®åŸã®ååŠåŠçããã®èªå°äœ
ã掻æ§ã«ã«ãã³é žåœ¢æ ã«å€ããããã«å¿ èŠãšãã
ãã æ¬çºæã«ãã補é ãããã€ãªã³äº€ææš¹èã¯ç¹ã«
䜿çšã®éæ°Žã®åžåã«ããèå解æ§ã«é¢ããæ§è³ªã
é«ããé»è§£ã»ã«ã«ãããã€ãªã³äº€æèãšããŠãã€
ã«ã 圢ç¶ã§ç¹å®ã®é©çšãèŠãåºãããã ãããã®èã¯æ¬çºæã®æ¹æ³ã«ãã€ãŠè£œé ããã
æš¹èã®ç²åããæ圢å å·¥ãããã奜ãŸããã¯æå
ã«éããã²ã³ååŒçŽ å«æçåæ°ŽçŽ ããªããŒãã€ã«
ã ãäœè£œãã次ãã§ãããæ¬çºæã®æ¹æ³ã«ä»ããŠ
æ¬çºæã®æš¹èãèã®åœ¢ç¶ã«åœ¢æããã åŸã€ãŠæ¬çºæã®ããäžã€ã®æ æ§ã«ãããŠã¯ãã«
ããªã³äº€ææ§ãæããæš¹èãå«ããåèšæš¹èã以
åã«èŠå®ããããããªïŒçš®ãããã¯ãã以äžã®å®
èœã¢ãããŒã以åã«èŠå®ããããããªïŒçš®ããã
ã¯ãã以äžã®éå®èœçµåã¢ãããŒã®ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒãå«ãã§ãªãåºå¹¹ãž
ã®ç §å°èªå°å ±éåã«ãã€ãŠè£œé ãããããã«ãã€
ãŠå®èœã¢ãããŒããèªå°ãããå°ãªããšãïŒåã®
掻æ§åºãå«ãåŽéãæããéããã²ã³ååŒçŽ å«æ
çåæ°ŽçŽ ããªããŒåºå¹¹ãããªãååæ§é ãæãã
æš¹èã圢æãããé»è§£ã»ã«ã«ããã䜿çšã«é©åœãª
ã€ãªã³äº€æèãäžããããã æ¬çºæã«ããèã¯ãŸãäŸãã°ãããããªãŒãç
æã»ã«åã³é»è§£ã»ã«ã«ãããã»ãã¬ãŒã¿ãŒåã³ïŒ
åã¯åºäœé»è§£è³ªã®ãããªä»ã®é»æ°ååŠçç³»ã«ãã
ãŠæå¹ã«äœ¿çšããããšãã§ããã åèšèŠå®ã®ãããªå®èœã¢ãããŒã¯ããèªäœæ¥µã
ãŠãã€ãããã€äœå¹çã§ããªããŒåºå¹¹ã«ã°ã©ãã
ãããæã ã®æ¹æ³ã«ãããŠã¯åŒãæããïŒçš®ã
ããã¯ãã以äžã®éå®èœã¢ãããŒã®æ·»å ã¯å®èœã¢
ãããŒã®ã°ã©ããé床ã倧ãã«å¢å ãããããã
ã®éå®èœã¢ãããŒã¯éåæ¡ä»¶äžã§ããªããŒåºå¹¹å
ã³å®èœã¢ãããŒã®äž¡æ¹ã«ã°ã©ãããããããŠçµå
ããããã«åºãšããŠäœçšããããã®ããã«ããŠ
æã ã®æ¹æ³ã«ãããŠåœ¢æãããã°ã©ããæš¹èã¯å®
èœã¢ãããŒãã圢æãããåºïŒã掻æ§åºãïŒåã³é
å®èœã¢ãããŒãã圢æãããåºïŒãçµåããã«
åºãïŒãå«ãã§ãªãåŽéãå«ãã æã ã®çºæã®æš¹èã®åŽéã«ããã掻æ§åºãšçµå
ããã«åºãšã®å¥œãŸããæ¯ã¯ïŒïŒïŒãïŒïŒ20ã®ç¯å²
ã®ã¢ã«æ¯ã§ããã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®ç¯
å²ã«ãããæš¹èã«ãããŠãããã®å¥œãŸããæ¯ãé
æããããã«ã°ã©ããããã»ã¹ã«ãããå®èœã¢ã
ããŒãšéå®èœã¢ãããŒãšã®æ¯ã®ç¯å²ã¯ïŒïŒïŒã
ïŒïŒ20ã®ç¯å²ã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®ç¯
å²ããããŠããã«å¥œãŸããã¯æ¬çºæã®å¥œãŸããæš¹
èãåŸãããã«çã¢ã«æ¯è¿ãã§ãããªãã¡ïŒïŒïŒ
ãïŒïŒïŒã®ç¯å²ã§æ··åãããã å®èœã¢ãããŒææåã³éå®èœã¢ãããŒææã®äž¡
æ¹ã¯ç §å°ã«ãã€ãŠçºçããããªãŒã©ãžã«ã«ãéå®
èœåºã®åºå¹¹ã«å¯Ÿããã°ã©ããåã³åæã«æ¬çºæã®
æš¹èãç¹æ§ã¥ããéã圢æãããå®èœã¢ãããŒå
ã³éå®èœã¢ãããŒææãšã®å ±éåã®äž¡æ¹ãéå§ã
ãããšãã§ããããã«ãã°ã©ããããã»ã¹ã®éå ±
ã«ååšãããšããããšãæ¬çºæã®æ¹æ³ã«å¯ŸããŠå¿
é ã®ããšã§ããã æ¬çºæãå®æœããæè¯ã®æ¹æ³ ããªããŒåºå¹¹äžãžã®å®èœåã³éå®èœçµåã¢ãã
ãŒã®æŸå°ç·ã°ã©ããïŒå ±éåã¯ïŒã€ã®ç«¶äºåå¿ã«
ãã€ãŠæ¯é ãããŠããããã«æãããããããã®
ãã¡ã®ïŒã€ã¯åæã«ããªããŒåºå¹¹äžã«ã°ã©ããã
ããå®èœã¢ãããŒãšéå®èœçµåã¢ãããŒãšã®ææ
ã®å ±éåã§ããã第ïŒã®ãã®ã¯ã¢ãããŒç¹ã«éå®
èœçµåã¢ãããŒã®å ±éåã§ãããå ±éåã®é床ã
ææã®ã°ã©ããïŒå ±éåããããã倧ããã®ã§ã
åèšã®ãããªåŒçŽ å«æçåæ°ŽçŽ ããªããŒåºå¹¹äžã«
å®èœåã³éå®èœçµåã¢ãããŒãå ±éåã§ãã€ãŠæŸ
å°ç·ã°ã©ããããæ¹æ³ã®å¥œãŸããå®æœæ æ§ã«ãã
ãŠãæã ã¯å°ãªããšãïŒçš®ã®éåæå¶å€ãšå°ãªã
ãšãïŒçš®ã®é£é移åå€ã®æ·»å ãå«ãã§ãªãæ¹è¯ã
æäŸããããã®å®æœæ æ§ã«ãããŠããé«ãã¬ãã«
ã®ã°ã©ãããéæããããšãã§ãã代衚çã«ã¯ã°
ã©ããã®ã¬ãã«ã¯ïŒçš®ãããã¯ãã以äžã®å åã«
ãã€ãŠå¢å ããããæã ã®æ¹è¯ãããæ¹æ³ããã®
æš¹èã¯ããé«ãã€ãªã³äº€æ容éãæãããã®ãã
ãªæš¹èãé»è§£ã»ã«ã«ãããŠäœ¿çšã®ããã®ãã€ã€ã
ã©ã ã®äžãžçµèŸŒãã å Žåãäžå±€è¯å¥œãªæ§èœããã
ãã®ã»ã«ã«ãããŠéããããã æã ã®çºæã®æ¹æ³ã«äœ¿çšããããã®å¥œãŸããé
åæå¶å€ã¯äŸãã°é žçŽ ã®ååšã«ãããïœâãã³ãŸ
ããã³ãããã¿ããã³ãåã³ãããããã³ã®ãã
ãªããã³æå¶å€ïŒé ¢é žé ã®ãããªç¡æ©ã®æå¶å€ïŒ
䞊ã³ã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãªã
ãœâãããªãžã³âïŒâãªãã·ããïŒïŒïŒïŒïŒïŒïŒ
âããã©ã¡ãã«ããã©ãžã³ââãªãã·ãåã³ã¯
ãã©ãã«ã®ãããªååç©ãå«ãã æã ã®çºæã®æ¹æ³ã«ãããŠäœ¿çšãããæå¶å€ã®
æ¿åºŠã¯å®èœåã³çµåã¢ãããŒäžŠã³ã«é£é移åå€ã®
å šæ··åç©ã®0.001ãïŒïŒ ïœïŒïœã®ç¯å²ã«ããã奜
ãŸããã¯0.01ã0.5ïŒ ïœïŒïœã®ç¯å²ã«ããã æŸå°ç·ã°ã©ããã¯å¥œãŸããã¯æ¶²äœåªäœã«ãããŠ
è¡ãªãããã®ã§ãé£é移åå€ã¯ãŸãã¢ãããŒã«å¯Ÿ
ãã溶å€ã§ããããšã奜ãŸããã奜ãŸããé£é移
å溶å€ã¯äŸãã°ã¯ãããã«ã ãåå¡©åççŽ ããžã¡
ãã«ãã«ã ã¢ãããåã³ãããã®æ··åç©ãå«ãã
é©åœãªæ··åç©ã¯äŸãã°ã¯ãããã«ã ãåå¡©åç
çŽ ããžã¡ãã«ãã«ã ã¢ãããåã³ãããã®æ··åç©
ã§ãããé©åœãªæ··åç©ã¯äŸãã°åå¡©åççŽ ïŒã¯ã
ããã«ã ïŒïŒïŒïŒïŒåã³åå¡©åççŽ ïŒãžã¡ãã«ã
ã«ã ã¢ããïŒïŒïŒïŒïŒã§ãããé£é移å溶å€äžã®
ã¢ãããŒã®æ¿åºŠã¯10ã60ïŒ ïœïŒïœã®ç¯å²ã奜ãŸã
ãã¯30ã50ïŒ ïœïŒïœã®ç¯å²ã«ããã åºäœã®é£é移åå€ã¯æŸå°ç·ã°ã©ããçšã®æ¶²äœåª
äœãäžããããè¿œå çãªæº¶å€ãå¿ èŠã§ããã®ã§ã
ãŸã奜ãŸãããªããããåºäœã®é£é移åå€ã䜿çš
ããå Žåããã®é£é移åå€ãšã¢ãããŒãšã®ïœïŒïœ
æ¯ã¯å¥œãŸããé£é移å溶å€ã«å¯ŸããŠã®åèšã®ãã®
ãšåãç¯å²ã«ããã¹ãã§ããã åºå¹¹ãå®èœåºåã³éå®èœåºãå«ãã§ãªãåèšã®
ãããªæš¹èã«ããã«ã«ããªã³äº€æ掻æ§åºãå°å ¥ã
ãããšããŸãæã ã®çºæã®ç¯å²å ã«ãããè¿œå ç
ãªæŽ»æ§åºã¯æ¢åã®åºã®ååŠçæ¹è³ªã«ãã€ãŠå°å ¥ã
ããããããŠäŸãã°åŽéã«ãããéå®èœåºã¯ã¹ã«
ãã³ååã³ïŒåã¯ã«ã«ããã·ã«åãããŠãé«ãã
ããã€ãªã³äº€æ容éåã³æ¹¿æœ€æ§ãæãã掻æ§æš¹è
ãäžããããã ç£æ¥äžã®é©çšæ§ æ¬çºæã«ä¿ã芪氎æ§ãã€ã€ãã©ã ã¯ç¹ã«é»è§£ã»
ã«äžã«ååšãã液äœã«ãã湿最æ§ã«é¢ããŠé«ãã
ããæ§è³ªãæããããæ ã«é»è§£ã»ã«ã«ãããŠç¹å®
ã®é©çšãèŠãåºãããããããã¯ãŸãä»ã®é»æ°å
åŠçç³»ã«ãããŠãäŸãã°ããããªãŒãçæã»ã«å
ã³é»è§£ã»ã«ã«ãããã»ãã¬ãŒã¿ãŒãšããŠæå¹ã«äœ¿
çšããããšãã§ããã æ¬çºæã¯ãã¹ãŠã®ã€ãªã³äº€æ容éãé«åºŠã®ã¢ã«
ã«ãªæ¡ä»¶ã«é¢ãããã®ã§ãããããªãã¡ãã¹ãŠã®
ã«ã«ãã³é žåã³ã¹ã«ãã³é žåºã亀æéšäœãšããŠäœ
çšããŠãã以äžã®äŸã«ãã€ãŠèª¬æããããããã
ããããã«éå®ãããªããä»ã«èšèŒããªããã°ã
ã¹ãŠã®éšåã³ããŒã»ã³ãã¯ééåºæºã«ãããã®ã§
ããã 以äžã®äžè¬çãªæ¹æ³ã«åŸã€ããéåŒçŽ ååºå¹¹ã®
è©Šæãã¬ã©ã¹åå¿å®¹åšã®äžã«çœ®ããã¢ãããŒæ··å
ç©ãæ·»å ãããåå¿å®¹åšã®å 容ç©ã液äœçªçŽ äžã«
ãããŠåçµãããã®ç³»ã«ååšãã空æ°ãé€å»ãã
ããã«ç空äžã«çœ®ããã å®å šãªææ°åŸãç空ãã³ããæã¡ããã®å 容ç©
ãæã宀枩ã«å°éããããã以åŸã¬ã¹æããšããŠ
èšåããããã®ããã»ã¹ãåå¿å®¹åšãã·ãŒã«ãã
åã«ïŒåç¹°ãè¿ããã ãã®æè¡ãçšããŠåå¿å®¹åšã®å 容ç©ãå®è³ªçã«
é žçŽ ã®ãªãé°å²æ°äžã«çœ®ãããããã«ãã®æ¹æ³ã
çšããŠè£œé ãããè©Šæã24æéã®ééžå®æž©åºŠã«å¹³
è¡¡ã«ãªããããã ãã®æéã®åŸãåå¿å®¹åšãç §å°ã»ã«å®€ã«ç§»ãã
ã³ãã«ãâ60æºããåºãγâç·ã«æŽé²ããã ç §å°çµäºåŸãã¬ã©ã¹åå¿å®¹åšã®å 容ç©ãåå¿å®¹
åšãéããåã«æ¶²äœçªçŽ äžã«ãããŠåçµãããã°
ã©ããããåºå¹¹ïŒãã€ã«ã åã¯ç²æ«ïŒãé©åœãªæº¶
å€ã§æªåå¿ã¢ãããŒåã³ãã¢ããªããŒãæŽã€ãŠé€
ãã60âã®ç空ãªãŒãã³äžã§äžå®ééãŸã§ä¹Ÿç¥ã
ãã è¡šåã³èšè¿°ã«ãããŠã次ã®ç¥èªãçšããã TFEïŒããã©ãã«ãªããšãã¬ã³ FEPïŒããã©ãã«ãªããšãã¬ã³ãšãããµãã«
ãªããããã¬ã³ã®ã³ããªã㌠PFBAïŒãã«ãã«ãªãããã³é ž IECïŒã€ãªã³äº€æ äžãããã倧ããã¯ãã¯ãã³ã§ããããã€ã«ã
ã®å Žåã«ã¯åããæå³ããç²æ«ã®å Žåã«ã¯ç²ååŸ
ãæå³ããã ã°ã©ããããŒã»ã³ãïŒãã€ã«ã ã®ééå¢å ãäŸ
ãã°ã°ã©ããããããã€ã«ã ã®ééããŒã»ã³ããš
ããŠè¡šçŸïŒãã°ã©ãããã€ã«ã ã®èµ€å€ã¹ãã¯ãã«
ïŒ1795cm-1ã®æ³¢æ°ã«ãããã«ã«ããã«åžåïŒåã³
ã€ãªã³äº€æ容éïŒmeqïŒïœãšããŠè¡šçŸïŒã¯Î³ç·ç §
å°ã«ãã€ãŠçæãããæ¹è³ªéåŒçŽ ååºå¹¹ãç¹æ§ã¥
ããããã«äœ¿çšãããã ã°ã©ããããŒã»ã³ãã¯åŒïŒ ã°ã©ããïŒ ïŒGiâGoïŒGiÃ100 ïŒåŒäžGoã¯ããªããŒåºå¹¹ã®åæã®ééã§ããã
Giã¯ç §å°åŸã®ã°ã©ããããªããŒã®ééã§ãããïŒ ããèšç®ãããã äŸ ïŒãïŒ ãããã®äŸã¯ã°ã©ããæå¶å€Î±âããã³ã®ååš
äžã§å®èœåã³éå®èœã¢ãããŒã®æ··åç©ã®ã°ã©ãã
ã説æããã ã¬ã©ã¹åå¿å®¹åšäžã«FEPãã€ã«ã ïŒ2.0ïœïŒã
眮ããPFBAïŒÎ±âããã³ïŒ0.12ïœã0.5ïŒ å šæ¿
床ïŒããArkloneããæ°ŽïŒ3.0ïœïŒåã³ã¢ã³ã¢ã
ãŠã ãã«ãã«ãªããªã¯ã¿ããšãŒãïŒ0.025ïœã
0.17ïŒ å šæ¿åºŠïŒã容åšã«æ·»å ãããïŒãArkloneã
ã¯ïŒïŒïŒïŒïŒâããªã¯ããâïŒïŒïŒïŒïŒâããªâ
ãã«ãªããšãã¬ã³ã«å¯Ÿããç»é²åæšã§ããïŒ æ··åç©ã液äœçªçŽ äžã«ãããŠåçµãã空æ°ãæ
æ°ããããŠå 容ç©ã宀枩ãŸã§å°éããããããã®
ã¬ã¹æãã®ããã»ã¹ãïŒåç¹°ãè¿ãã次ãã§
TFEïŒæå¶å€ãå šãå«ãŸãªãïŒã液äœçªçŽ ã®æž©åºŠ
ã§åå¿å®¹åšã®äžãžè£ å¡«ãããå®èœïŒPFBAïŒåã³
éå®èœïŒTFEïŒã¢ãããŒäžŠã³ã«æº¶å€ïŒãArkloneã
ïŒã®å šééã¯21ïœã§ãã€ãã ã¬ã©ã¹åå¿å®¹åšãã·ãŒã«ãã宀枩ã§äžæ©ä¿æã
ãã次ãã§ãããåšå²æž©åºŠã§120æé10KRADïŒ
hrã§ç §å°ããããã®æ··åç©ã¯1.2MRADã®å šç·é
ãåãããããã¬ã©ã¹å®¹åšãéããåã«åã³æ¶²äœ
çªçŽ ãšå ±ã«åçµãããã°ã©ãããããã€ã«ã ãå
éããæŽæµããŠã³ããªããŒåã³æªåå¿ã¢ãããŒã
é€å»ãããããŠ60âã§ç空ãªãŒãã³äžã«ãããŠä¹Ÿ
ç¥ããã çš®ã ã®æ¯ã®å®èœã¢ãããŒãéå®èœã¢ãããŒåã³
溶å€ã䜿çšããã ã°ã©ãããããã€ã«ã ã®èµ€å€ã¹ãã¯ãã«ã¯ã«ã«
ããã«åžåæ³¢æ°ã1795cm-1ã§ããããšã瀺ãã滎
å®ã«ãã€ãŠæž¬å®ãããã€ãªã³äº€æ容éã¯
0.2meqïŒïœã§ãã€ãã䜿çšãããæ¯ãã°ã©ãã
ããŒã»ã³ãåã³ã€ãªã³äº€æ容éãè¡šïŒã«ç€ºãã
åŒïŒ CF2ïŒCFïŒCF2ïŒo åã³åŒ CF2ïŒCFââïŒCFXâCFXïŒn ïŒåŒäžïŒ¡ã¯ã«ã«ããã·ã«ãC1ãC6ã¢ã«ã³ãã·
ã«ã«ããã«ãããããã·C1ãC6ã¢ã«ã³ãã·âã«
ã«ããã«ãã·ã¢ããããããã·ã¹ã«ããã«ããã«
ãªãã¹ã«ããã«ããŸãã¯R1åã³R2ãæ°ŽçŽ åã³C1
ãC6ã¢ã«ãã«ããç¬ç«ã«éžã°ããâCOâNR1R2
åºã§ãããäžæ¹ã®ïŒžã¯åŒçŽ ã§ãããä»æ¹ã®ïŒžã¯å¡©
çŽ ãåŒçŽ åã³ããªãã«ãªãã¡ãã«åºããéžã°ãã
ïœã¯ïŒã12ã®æŽæ°ã§ãããïœã¯ïŒãïŒã®æŽæ°ã§ã
ããïŒ ã®ååç©ãããªã矀ããéžã°ããå°ãªããšãïŒçš®
ã®å®èœã¢ãããŒãåŒïŒ CF2ïŒCFY ïŒåŒäžïŒ¹ã¯å¡©çŽ ãåŒçŽ ãåã¯ããªãã«ãªãã¡ã
ã«åºã§ãããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒçš®ã®éå®èœçµåã¢ãããŒãšå ±ã«ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹äžã«å ±é
åããã€ãŠæŸå°ç·ã°ã©ããããããšãå«ã¿ãå®èœ
ã¢ãããŒãšéå®èœã¢ãããŒãšã®ã¢ã«æ¯ãïŒïŒïŒã
ïŒïŒ20ã®ç¯å²ã«ããæ¹æ³ã ïŒ åŒçŽ å«æããªããŒéªšæ Œåºå¹¹ãåŒçŽ åãšãã¬ã³
ã®ãã¢ããªããŒåã¯ã³ããªããŒã§ããè«æ±ã®ç¯å²
第ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ åãšãã¬ã³ãããã©ãã«ãªããšãã¬ã³ã§
ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ åãšãã¬ã³ãã¯ããããªãã«ãªããšãã¬
ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ã³ããªããŒããããµãã«ãªããããã¬ã³åäœ
ãå«ãã§ãªãè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ åŒçŽ å«æããªããŒéªšæ Œåºå¹¹ãããªããã©ãã«
ãªããšãã¬ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ åŒçŽ å«æããªããŒåºå¹¹ãããªã¯ããããªãã«
ãªããšãã¬ã³ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹
æ³ã ïŒ åŒçŽ å«æããªããŒåºå¹¹ãããã©ãã«ãªããšã
ã¬ã³ãšåèšã³ããªããŒã«ãããŠçµã¿èŸŒãŸãããã
ãµãã«ãªããããã¬ã³ã3.5ã12.5ïŒ ïœïŒïœã®æ¿
床ç¯å²ã«ãããããµãã«ãªããããã¬ã³ãšã®ã³ã
ãªããŒã§ããè«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé èšèŒ
ã®æ¹æ³ã ïŒ åŒåã³ã®ååç©ããã³ã¿ãã«ãªãããã³
é žãC1ãC6ã¢ã«ãã«ãã³ã¿ãã«ãªãããããšãŒ
ãåã³ããªãã«ãªãããã«ã¹ã«ããã«ãã«ãªãªã
ã§ããè«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããããã«èš
èŒã®æ¹æ³ã ïŒïŒ åèšC1ãC6ã¢ã«ãã«ãã³ã¿ãã«ãªããã
ããšãŒããã¡ãã«ãã³ã¿ãã«ãªãããããšãŒãå
ã³ãšãã«ãã³ã¿ãã«ãªãããããšãŒãã§ããè«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åŒã®éå®èœã¢ãããŒãããã©ãã«ãªããš
ãã¬ã³åã³ã¯ããããªãã«ãªããšãã¬ã³ã§ããè«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹
æ³ã ïŒïŒ åèšã¢ã«æ¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²ã«ãã
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒïŒ åèšã¢ã«æ¯ãïŒïŒïŒãïŒïŒïŒã®ç¯å²ã«ãã
è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æŸå°ç·ã°ã©ãããγâç·ãâç·åã³é»å
ããŒã ãããªã矀ããéžã°ããæŸå°ç·ã®ãããã
ã®åœ¢ã«ããç §å°ã«ãããã®ã§ããè«æ±ã®ç¯å²ç¬¬ïŒ
é ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ··åç©ãåºå¹¹ãèšæœ€ããèœåã
ãã溶å€äžã«æº¶è§£ãããŠããè«æ±ã®ç¯å²ç¬¬ïŒé ã
第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ·»å åã«ãã€ã€ãã©ã ããã€ã€
ãã©ã ãèšæœ€ããèœåã®ãã溶å€ã§åŠçãããè«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹
æ³ã ïŒïŒ 溶å€ããã«ãšã³ããã·ã¬ã³ãããªã¯ããã
ãªãã«ãªããšã¿ã³åã³ããã©ãã«ãªããšãã¬ã³ã®
ãªãªãŽããŒãããªã矀ããéžã°ããè«æ±ã®ç¯å²ç¬¬
ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ ã¢ãããŒã®æ··åç©ãè¿œå çã«å°ãªããšãïŒ
çš®ã®éåæå¶å€åã³å°ãªããšãïŒçš®ã®é£é移åå€
ãå«ãã§ãªãè«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ãã
ããã«èšèŒã®æ¹æ³ã ïŒïŒ éåæå¶å€ãé žçŽ ã®ååšã«ãããïœâãã³
ãŸããã³ãããã¿ããã³ããããããã³ãé ¢é ž
é ãïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãªããœ
ãããªãžã³âïŒâãªãã·ããïŒïŒïŒïŒïŒïŒïŒâã
ãã©âã¡ãã«ããã©ãžã³ââãªãã·ããåã³ã¯
ãã©ãã«ãããªã矀ããéžã°ããè«æ±ã®ç¯å²ç¬¬ïŒ
ïŒé èšèŒã®æ¹æ³ã ïŒïŒ éåæå¶å€ãã¢ãããŒãšé£é移åå€ã®å šæ··
åç©ã®0.001ãïŒïŒ ïœïŒïœã®æ¿åºŠç¯å²ã«ããè«æ±
ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æ¿åºŠç¯å²ã0.01ã0.5ïŒ ïœïŒïœã§ããè«æ±
ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ é£é移åå€ãã¯ãããã«ã ãåå¡©åççŽ ã
ãžã¡ãã«ãã«ã ã¢ããåã³ãããã®æ··åç©ãããª
ã矀ããéžã°ãã溶å€ã§ããè«æ±ã®ç¯å²ç¬¬ïŒïŒé
ã第ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ é£é移åå€ã«ãããã¢ãããŒã®æ¿åºŠã10ã
60ïŒ ïœïŒïœã®ç¯å²ã«ããè«æ±ã®ç¯å²ç¬¬ïŒïŒé ã第
ïŒïŒé ã®ããããã«èšèŒã®æ¹æ³ã ïŒïŒ åèšç¯å²ã30ã50ïŒ ïœïŒïœã§ããè«æ±ã®ç¯
å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã æè¡åé æ¬çºæã¯ãæ°èŠãªã«ããªã³äº€ææš¹èãç¹ã«ã¢ã«
ã«ãªéå±ã®æ°Žé žåç©ã®æº¶æ¶²åã³å¡©çŽ ã®è£œé ã«çšã
ããããããªé»è§£æ§œäžã®ã€ãªã³äº€æèãšããŠäœ¿çš
ããã®ã«é©ããã«ããªã³äº€æææã®è£œæ³ã«é¢ã
ãã èæ¯æè¡ ã¢ã«ã«ãªéå±æ°Žé žåç©æº¶æ¶²åã³å¡©çŽ ã¯ãäžè¬
ã«ãæ°Žéã»ã«åã¯ãã€ã€ãã©ã ã»ã«äžã§è£œé ãã
ããæ°Žéã»ã«ã¯ãæ¿åãªã¢ã«ã«ãªéå±æ°Žé žåç©æº¶
液ãçæãããšããå©ç¹ãæãããããããæ°Žé
ãå«ãæµåºæ¶²ã®å»æ£ã«äŒŽãåé¡ãçãããäžæ¹ã
éœæ¥µåã³é°æ¥µãéœã€ãªã³åã³é°ã€ãªã³äžŠã³ã«é»è§£
質ãééããããå€å質ãã€ã€ãã©ã ã«ãã€ãŠå
é¢ãããŠãããã€ã€ãã©ã ã»ã«ã¯ãäžèšæµåºæ¶²ã®
åé¡ãçããªãããã©ãã (1) æ¯èŒç匱ããäžçŽãã¢ã«ã«ãªéå±æ°Žé žåç©æº¶
液ãçæãããèžçºã®ããã®ã³ã¹ããå¢å ã
ãããŸã (2) çæã¬ã¹ããªãã¡æ°ŽçŽ åã³å¡©çŽ ãæ··åãããŠ
ããŸãå¯èœæ§ãããã ãšããæ¬ ç¹ãæããã éœæ¥µåã³é°æ¥µãã«ããªã³æŽ»æ§ã€ãªã³äº€æèã«ã
ã€ãŠåé¢ãããŠããã»ã«ã®äœ¿çšã«ãã€ãŠæ°Žéã»ã«
åã³ãã€ã€ãã©ã ã»ã«ã®äž¡è ã®æ¬ ç¹ã解決ããè©Š
ã¿ããªãããŠããããããã¯ãæ£ã«åž¯é»ãããã€
ãªã³ã®ã¿ãééãããé»è§£è³ªãééãããªããã
ãªãéžæééæ§ã®èã§ãããå¡©çŽ ã»ã«ã«ãããã
ã®çšéã«é©åœãªã«ããªã³æŽ»æ§ã€ãªã³äº€æèã¯ãäŸ
ãã°ãã«ããªã³äº€æåºãäŸãã°ãã¹ã«ãããŒãã
ã«ã«ããã·ã¬ãŒãåã³ãã¹ãããŒããå«ãåææ
æ©ã³ããªããŒææãããªããã®ãå«ãã ç¹ã«ãé·æéã®ã»ã«æ¡ä»¶ã«èããåæãã«ãªã
ããªããŒãäŸãã°ãåæšãNAFIONãã®ããšã§
EIããŠãã³ç€Ÿã«ãã€ãŠè£œé åã³è²©å£²ãããŠããã
å æ°Žå解ããããéåŒçŽ åçåæ°ŽçŽ ïŒäŸãã°ããª
ããã©ãã«ãªããšãã¬ã³ïŒãšãã«ãªãã¹ã«ãã³å
ãã«ãã«ãªãããã«ãšãŒãã«ãšã®ã³ããªããŒã«åº
ã¥ãããã«ãã«ãªãã¹ã«ãã³é žèãæçšã§ããã ãããã®èã補é ãããæš¹èã®ååæ§é äžã®æŽ»
æ§éšäœã¯ããã«ãªãã¹ã«ãã³åãã«ãã«ãªããã
ã«ãšãŒãã«æåã«ãã€ãŠäžããããããããã®éš
äœã¯ãæš¹èã®éªšæ Œæ§é ã«å¯ŸãããšãŒãã«çµåã«ã
ã€ãŠçµåãããåŽéäžã«ååšããããã®ãããªè
ã¯ãäŸãã°ãç±³åœç¹èš±ç¬¬2636851å·ã第3017338
å·ã第3496077å·ã第3560568å·ã第2967807å·ã
ãã³ç¬¬3282875å·åã³è±åœç¹èš±ç¬¬1184321å·ã«èšèŒ
ãããŠããã äžè¬ã«ãããã®ãã«ãªãããªããŒã¯ã©ãžã«ã«é
å觊åªãå«ããšãã«ãžãšã³åã¯ãµã¹ãã³ãžãšã³äž
ã«ãããŠãã«ãªãã«ãŒãã³ã¢ãããŒã®éååã¯å ±
éåã«ãã€ãŠè£œé ããããåŸãããããªããŒã¯æº¶
èæ圢å å·¥ã®ãããªéåžžã®æ圢æ¹æ³ã«ãã€ãŠèã«
æ圢ãããã çºæã®é瀺 æã ã¯ã«ããªã³æŽ»æ§ã€ãªã³äº€æèã«äœ¿çšããã®
ã«é©ãããã«ãªãããªããŒã®æ°èŠãªè£œé æ¹æ³ãèŠ
ãåºããããã®æ¹æ³ã¯ã掻æ§éšäœãåã¯æŽ»æ§éšäœ
ã«è»¢åããåŸãå®èœåºãå«ãã¢ãããŒãæŸå°ç·ã°
ã©ããåæ³ã«ãã€ãŠéããã²ã³åããªããŒã®éªšæ Œ
åºå¹¹äžã«çŽæ¥ã°ã©ãããããç¹ã§åŸæ¥æè¡ã®æ¹æ³
ãšç°ã€ãŠãããããªããŒã®éªšæ Œåºå¹¹ãç²æ«åã¯ã
ã€ã«ã 圢ç¶ã§ãã€ãŠããããšããããšãæã ã®æ¹
æ³ã®èããç¹åŸŽã§ããã ããã«ç¹ã«ã以åŸèŠå®ããããããªå®èœã¢ãã
ãŒã以åŸèŠå®ããããããªéå®èœçµåã¢ãããŒå
ã³éããã²ã³ååŒçŽ å«æçåæ°ŽçŽ ããªããŒéªšæ Œåº
å¹¹ãæŸå°ç·ã°ã©ããæ¹æ³ã«å ±ã«ä»ãããå Žåãå®
èœã¢ãããŒåã³éå®èœçµåã¢ãããŒãåæã«ããª
ããŒã«å ±éåãåã³ã°ã©ããããå®èœåºãå«ãåŽ
éãæããåŒçŽ å«æçåæ°ŽçŽ ããªããŒåºå¹¹ãæã
ãã«ããªã³äº€ææš¹èã圢æããããšãããã€ãã
ãããã®å®èœåºã¯ããèªäœã«ããªã³äº€æã®ããã®
掻æ§éšäœã§ãããåã¯å æ°Žå解ã®ãããªéåžžã®æ¹
æ³ã«ãã掻æ§éšäœã«å®¹æã«çµåãããã åŸã€ãŠæã ã¯ã«ããªã³äº€ææš¹èã補é ããæ¹æ³
ã§ãã€ãŠã åŒïŒ CF2ïŒCFïŒCF2ïŒo åã³ åŒïŒ CF2ïŒCFââïŒCFXâCFXïŒn ïŒåŒäžïŒ¡ã¯ã«ã«ããã·ã«ãC1ãC6âã¢ã«ã³ã
ã·ã«ã«ããã«ãããããã·C1ãC6ã¢ã«ã³ãã·ã«
ã«ããã«ãã·ã¢ããããããã·ã¹ã«ããã«ããã«
ãªãã¹ã«ããã«ãåã¯R1åã³R2ãæ°ŽçŽ åã³C1ã
C6ã¢ã«ãã«ããç¬ç«ã«éžã°ããåºâCOâNR1R2
ã§ãããäžæ¹ã®ïŒžãåŒçŽ ã§ãããä»æ¹ã®ïŒžãå¡©
çŽ ãåŒçŽ åã³ããªãã«ãªãã¡ãã«åºããéžã°ãã
ïœãïŒã12ã®æŽæ°ã§ãããïœãïŒãïŒã®æŽæ°ã§ã
ããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒçš®ã®å®èœã¢ãããŒãåŒïŒ CF2ïŒCFY ïŒåŒäžïŒ¹ã¯å¡©çŽ ãåŒçŽ ãåã¯ããªãã«ãªãã¡ã
ã«åºã§ãããïŒ ãæããååç©ãããªã矀ããéžã°ããå°ãªããš
ãïŒåã®éå®èœçµåã¢ãããŒãšå ±ã«ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹äžã«å ±é
åããã€ãŠæŸå°ç·ã°ã©ããããããšãå«ãã§ãªã
æ¹æ³ãæäŸããã éããã²ã³åçåæ°ŽçŽ ããªããŒã®éªšæ Œåºå¹¹ã¯é
åŒçŽ åããããåã¯éšåçã«åŒçŽ åãããŠãã
ãã奜ãŸããåŒçŽ å«æçåæ°ŽçŽ åºå¹¹ã¯åŒçŽ åãã
ããšãã¬ã³ã®ãã¢ããªããŒåã¯ã³ããªããŒãç¹ã«
ããã©ãã«ãªããšãã¬ã³ãããã¯ã¯ããããªãã«
ãªããšãã¬ã³ã®ãã¢ããªããŒåã¯ã³ããªããŒã§ã
ãã代衚çãªå¥œãŸããåºå¹¹ã¯ããªããã©ãã«ãªã
ãšãã¬ã³ïŒPTFEïŒãããªã¯ããããªãã«ãªããš
ãã¬ã³ïŒPCTFEïŒã䞊ã³ã«ããã©ãã«ãªããšã
ã¬ã³ãšãããµãã«ãªããããã¬ã³ãšã®ã³ããªããŒ
ã§ãã€ãŠãã®ã³ããªããŒã«æ··å ¥ããããããµãã«
ãªããããã¬ã³ã3.5ã12.5ïŒ ïœïŒïœã®ç¯å²ã«ã
ãã³ããªããŒã«å¯Ÿããäžè¬å称ã§ããFEPã§ã
ãã æã ã®æ¹æ³ã«ãããŠäœ¿çšã®ããã®å¥œãŸããåŒ
ã®å®èœã¢ãããŒã¯ãã³ã¿ãã«ãªãããã³é žãã¡ã
ã«ãã³ã¿ãã«ãªãããããšãŒãåã³ãšãã«ãã³ã¿
ãã«ãªãããããšãŒãã®ãããªã¢ã«ãã«ãã³ã¿ã
ã«ãªãããããšãŒã䞊ã³ã«ããªãã«ãªãããã«ã¹
ã«ããã«ãã«ãªãªããå«ãã奜ãŸããåŒã®éå®
èœçµåã¢ãããŒã¯ããã©ãã«ãªããšãã¬ã³åã³ã¯
ããããªãã«ãªããšãã¬ã³ã§ããã ã¢ãããŒææã®æ··åç©ã¯æ¶²äœåœ¢ç¶ã§ãªããã°ãª
ãããå¿ èŠãªå Žåããããã®æº¶æ¶²ã補é ãããã
ã«éåžžã®æº¶å€ãçšãããéåžžãã®ã¢ãããŒææã®
ãã¡ã®äžã€ã¯ããèªäœä»ã®ã¢ãããŒææã溶解ã
ã液äœçžãäžããã§ãããããã®ä»ã«ãéœåã®ã
ãããšã«ã䜿çšããã溶å€ã¯åºå¹¹ææã«æµžéãã
ããèšæœ€ãããããã®ã§ãããããã«ãã€ãŠã¢ã
ããŒã®æº¶æ¶²ãåºå¹¹ææãéããŠé©åœã«åžåããã
ãã é©åœãªæº¶å€ã¯äŸãã°ãã«ãšã³åã³ãã·ã¬ã³äžŠã³
ã«ããªã¯ããããªãã«ãªããšã¿ã³ã®ãããªå¡©çŽ å
çåæ°ŽçŽ åã³ããã©ãã«ãªããšãã¬ã³ã®ãªãªãŽã
ãŒãäŸãã°ããã©ãã«ãªããšãã¬ã³ã®ããã©ããŒ
åã³ãã³ã¿ããŒãã§ãããåºå¹¹ææãã¢ãããŒã®
æ·»å åã«ãã®ãããªæº¶å€ã§äºåèšæœ€ããã æŸå°ç·ã°ã©ããã®ããããæ¢ç¥ã®æ¹æ³ã䜿çšã
ãŠãããäŸãã°åºå¹¹åã³ã¢ãããŒææãé£ç¶ãã
ãã¯æç¶ç §å°ã«å ±ã«ä»ãããåã¯ãã®åºå¹¹ãã¢ã
ããŒææã«æ¥è§Šãããåã«äºåç §å°ããŠããã奜
ãŸããã¯åºå¹¹åã³ã¢ãããŒææã¯å ±ã«ç §å°ããïŒ
åºäœã§ãã埮ç²å圢ç¶ãåã¯ã·ãŒããããã¯ãã€
ã«ã ãšããŠã§ååšãåŸãåºå¹¹ã¯æ··åãããã¢ãã
ãŒææãå«ã液äœçžäžã«æµžæŒ¬ããããã®å šäœã¯ïŒž
ç·ãé»åããŒã ããããã¯å¥œãŸããã¯Î³ç·ã«ãã
ç §å°ã«ä»ãããã 奜ãŸããã¯ãã®ã°ã©ããæ¹æ³ã¯é žçŽ ã®äžååšäž
ã§è¡ãªãããã 掻æ§ã¢ãããŒã®èªå°äœãäŸãã°ã¡ãã«ãã«ãã«
ãªãããããšãŒãã®ãããªã«ã«ããã·ãšã¹ãã«ã
ãã°ã©ããããã»ã¹ã«ãããŠäœ¿çšãããå Žåã«ã
å æ°Žå解ã®ãããªãã®åŸã®ååŠåŠçããã®èªå°äœ
ã掻æ§ã«ã«ãã³é žåœ¢æ ã«å€ããããã«å¿ èŠãšãã
ãã æ¬çºæã«ãã補é ãããã€ãªã³äº€ææš¹èã¯ç¹ã«
䜿çšã®éæ°Žã®åžåã«ããèå解æ§ã«é¢ããæ§è³ªã
é«ããé»è§£ã»ã«ã«ãããã€ãªã³äº€æèãšããŠãã€
ã«ã 圢ç¶ã§ç¹å®ã®é©çšãèŠãåºãããã ãããã®èã¯æ¬çºæã®æ¹æ³ã«ãã€ãŠè£œé ããã
æš¹èã®ç²åããæ圢å å·¥ãããã奜ãŸããã¯æå
ã«éããã²ã³ååŒçŽ å«æçåæ°ŽçŽ ããªããŒãã€ã«
ã ãäœè£œãã次ãã§ãããæ¬çºæã®æ¹æ³ã«ä»ããŠ
æ¬çºæã®æš¹èãèã®åœ¢ç¶ã«åœ¢æããã åŸã€ãŠæ¬çºæã®ããäžã€ã®æ æ§ã«ãããŠã¯ãã«
ããªã³äº€ææ§ãæããæš¹èãå«ããåèšæš¹èã以
åã«èŠå®ããããããªïŒçš®ãããã¯ãã以äžã®å®
èœã¢ãããŒã以åã«èŠå®ããããããªïŒçš®ããã
ã¯ãã以äžã®éå®èœçµåã¢ãããŒã®ãéããã²ã³
ååŒçŽ å«æçåæ°ŽçŽ ããªããŒãå«ãã§ãªãåºå¹¹ãž
ã®ç §å°èªå°å ±éåã«ãã€ãŠè£œé ãããããã«ãã€
ãŠå®èœã¢ãããŒããèªå°ãããå°ãªããšãïŒåã®
掻æ§åºãå«ãåŽéãæããéããã²ã³ååŒçŽ å«æ
çåæ°ŽçŽ ããªããŒåºå¹¹ãããªãååæ§é ãæãã
æš¹èã圢æãããé»è§£ã»ã«ã«ããã䜿çšã«é©åœãª
ã€ãªã³äº€æèãäžããããã æ¬çºæã«ããèã¯ãŸãäŸãã°ãããããªãŒãç
æã»ã«åã³é»è§£ã»ã«ã«ãããã»ãã¬ãŒã¿ãŒåã³ïŒ
åã¯åºäœé»è§£è³ªã®ãããªä»ã®é»æ°ååŠçç³»ã«ãã
ãŠæå¹ã«äœ¿çšããããšãã§ããã åèšèŠå®ã®ãããªå®èœã¢ãããŒã¯ããèªäœæ¥µã
ãŠãã€ãããã€äœå¹çã§ããªããŒåºå¹¹ã«ã°ã©ãã
ãããæã ã®æ¹æ³ã«ãããŠã¯åŒãæããïŒçš®ã
ããã¯ãã以äžã®éå®èœã¢ãããŒã®æ·»å ã¯å®èœã¢
ãããŒã®ã°ã©ããé床ã倧ãã«å¢å ãããããã
ã®éå®èœã¢ãããŒã¯éåæ¡ä»¶äžã§ããªããŒåºå¹¹å
ã³å®èœã¢ãããŒã®äž¡æ¹ã«ã°ã©ãããããããŠçµå
ããããã«åºãšããŠäœçšããããã®ããã«ããŠ
æã ã®æ¹æ³ã«ãããŠåœ¢æãããã°ã©ããæš¹èã¯å®
èœã¢ãããŒãã圢æãããåºïŒã掻æ§åºãïŒåã³é
å®èœã¢ãããŒãã圢æãããåºïŒãçµåããã«
åºãïŒãå«ãã§ãªãåŽéãå«ãã æã ã®çºæã®æš¹èã®åŽéã«ããã掻æ§åºãšçµå
ããã«åºãšã®å¥œãŸããæ¯ã¯ïŒïŒïŒãïŒïŒ20ã®ç¯å²
ã®ã¢ã«æ¯ã§ããã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®ç¯
å²ã«ãããæš¹èã«ãããŠãããã®å¥œãŸããæ¯ãé
æããããã«ã°ã©ããããã»ã¹ã«ãããå®èœã¢ã
ããŒãšéå®èœã¢ãããŒãšã®æ¯ã®ç¯å²ã¯ïŒïŒïŒã
ïŒïŒ20ã®ç¯å²ã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒã®ç¯
å²ããããŠããã«å¥œãŸããã¯æ¬çºæã®å¥œãŸããæš¹
èãåŸãããã«çã¢ã«æ¯è¿ãã§ãããªãã¡ïŒïŒïŒ
ãïŒïŒïŒã®ç¯å²ã§æ··åãããã å®èœã¢ãããŒææåã³éå®èœã¢ãããŒææã®äž¡
æ¹ã¯ç §å°ã«ãã€ãŠçºçããããªãŒã©ãžã«ã«ãéå®
èœåºã®åºå¹¹ã«å¯Ÿããã°ã©ããåã³åæã«æ¬çºæã®
æš¹èãç¹æ§ã¥ããéã圢æãããå®èœã¢ãããŒå
ã³éå®èœã¢ãããŒææãšã®å ±éåã®äž¡æ¹ãéå§ã
ãããšãã§ããããã«ãã°ã©ããããã»ã¹ã®éå ±
ã«ååšãããšããããšãæ¬çºæã®æ¹æ³ã«å¯ŸããŠå¿
é ã®ããšã§ããã æ¬çºæãå®æœããæè¯ã®æ¹æ³ ããªããŒåºå¹¹äžãžã®å®èœåã³éå®èœçµåã¢ãã
ãŒã®æŸå°ç·ã°ã©ããïŒå ±éåã¯ïŒã€ã®ç«¶äºåå¿ã«
ãã€ãŠæ¯é ãããŠããããã«æãããããããã®
ãã¡ã®ïŒã€ã¯åæã«ããªããŒåºå¹¹äžã«ã°ã©ããã
ããå®èœã¢ãããŒãšéå®èœçµåã¢ãããŒãšã®ææ
ã®å ±éåã§ããã第ïŒã®ãã®ã¯ã¢ãããŒç¹ã«éå®
èœçµåã¢ãããŒã®å ±éåã§ãããå ±éåã®é床ã
ææã®ã°ã©ããïŒå ±éåããããã倧ããã®ã§ã
åèšã®ãããªåŒçŽ å«æçåæ°ŽçŽ ããªããŒåºå¹¹äžã«
å®èœåã³éå®èœçµåã¢ãããŒãå ±éåã§ãã€ãŠæŸ
å°ç·ã°ã©ããããæ¹æ³ã®å¥œãŸããå®æœæ æ§ã«ãã
ãŠãæã ã¯å°ãªããšãïŒçš®ã®éåæå¶å€ãšå°ãªã
ãšãïŒçš®ã®é£é移åå€ã®æ·»å ãå«ãã§ãªãæ¹è¯ã
æäŸããããã®å®æœæ æ§ã«ãããŠããé«ãã¬ãã«
ã®ã°ã©ãããéæããããšãã§ãã代衚çã«ã¯ã°
ã©ããã®ã¬ãã«ã¯ïŒçš®ãããã¯ãã以äžã®å åã«
ãã€ãŠå¢å ããããæã ã®æ¹è¯ãããæ¹æ³ããã®
æš¹èã¯ããé«ãã€ãªã³äº€æ容éãæãããã®ãã
ãªæš¹èãé»è§£ã»ã«ã«ãããŠäœ¿çšã®ããã®ãã€ã€ã
ã©ã ã®äžãžçµèŸŒãã å Žåãäžå±€è¯å¥œãªæ§èœããã
ãã®ã»ã«ã«ãããŠéããããã æã ã®çºæã®æ¹æ³ã«äœ¿çšããããã®å¥œãŸããé
åæå¶å€ã¯äŸãã°é žçŽ ã®ååšã«ãããïœâãã³ãŸ
ããã³ãããã¿ããã³ãåã³ãããããã³ã®ãã
ãªããã³æå¶å€ïŒé ¢é žé ã®ãããªç¡æ©ã®æå¶å€ïŒ
䞊ã³ã«ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãªã
ãœâãããªãžã³âïŒâãªãã·ããïŒïŒïŒïŒïŒïŒïŒ
âããã©ã¡ãã«ããã©ãžã³ââãªãã·ãåã³ã¯
ãã©ãã«ã®ãããªååç©ãå«ãã æã ã®çºæã®æ¹æ³ã«ãããŠäœ¿çšãããæå¶å€ã®
æ¿åºŠã¯å®èœåã³çµåã¢ãããŒäžŠã³ã«é£é移åå€ã®
å šæ··åç©ã®0.001ãïŒïŒ ïœïŒïœã®ç¯å²ã«ããã奜
ãŸããã¯0.01ã0.5ïŒ ïœïŒïœã®ç¯å²ã«ããã æŸå°ç·ã°ã©ããã¯å¥œãŸããã¯æ¶²äœåªäœã«ãããŠ
è¡ãªãããã®ã§ãé£é移åå€ã¯ãŸãã¢ãããŒã«å¯Ÿ
ãã溶å€ã§ããããšã奜ãŸããã奜ãŸããé£é移
å溶å€ã¯äŸãã°ã¯ãããã«ã ãåå¡©åççŽ ããžã¡
ãã«ãã«ã ã¢ãããåã³ãããã®æ··åç©ãå«ãã
é©åœãªæ··åç©ã¯äŸãã°ã¯ãããã«ã ãåå¡©åç
çŽ ããžã¡ãã«ãã«ã ã¢ãããåã³ãããã®æ··åç©
ã§ãããé©åœãªæ··åç©ã¯äŸãã°åå¡©åççŽ ïŒã¯ã
ããã«ã ïŒïŒïŒïŒïŒåã³åå¡©åççŽ ïŒãžã¡ãã«ã
ã«ã ã¢ããïŒïŒïŒïŒïŒã§ãããé£é移å溶å€äžã®
ã¢ãããŒã®æ¿åºŠã¯10ã60ïŒ ïœïŒïœã®ç¯å²ã奜ãŸã
ãã¯30ã50ïŒ ïœïŒïœã®ç¯å²ã«ããã åºäœã®é£é移åå€ã¯æŸå°ç·ã°ã©ããçšã®æ¶²äœåª
äœãäžããããè¿œå çãªæº¶å€ãå¿ èŠã§ããã®ã§ã
ãŸã奜ãŸãããªããããåºäœã®é£é移åå€ã䜿çš
ããå Žåããã®é£é移åå€ãšã¢ãããŒãšã®ïœïŒïœ
æ¯ã¯å¥œãŸããé£é移å溶å€ã«å¯ŸããŠã®åèšã®ãã®
ãšåãç¯å²ã«ããã¹ãã§ããã åºå¹¹ãå®èœåºåã³éå®èœåºãå«ãã§ãªãåèšã®
ãããªæš¹èã«ããã«ã«ããªã³äº€æ掻æ§åºãå°å ¥ã
ãããšããŸãæã ã®çºæã®ç¯å²å ã«ãããè¿œå ç
ãªæŽ»æ§åºã¯æ¢åã®åºã®ååŠçæ¹è³ªã«ãã€ãŠå°å ¥ã
ããããããŠäŸãã°åŽéã«ãããéå®èœåºã¯ã¹ã«
ãã³ååã³ïŒåã¯ã«ã«ããã·ã«åãããŠãé«ãã
ããã€ãªã³äº€æ容éåã³æ¹¿æœ€æ§ãæãã掻æ§æš¹è
ãäžããããã ç£æ¥äžã®é©çšæ§ æ¬çºæã«ä¿ã芪氎æ§ãã€ã€ãã©ã ã¯ç¹ã«é»è§£ã»
ã«äžã«ååšãã液äœã«ãã湿最æ§ã«é¢ããŠé«ãã
ããæ§è³ªãæããããæ ã«é»è§£ã»ã«ã«ãããŠç¹å®
ã®é©çšãèŠãåºãããããããã¯ãŸãä»ã®é»æ°å
åŠçç³»ã«ãããŠãäŸãã°ããããªãŒãçæã»ã«å
ã³é»è§£ã»ã«ã«ãããã»ãã¬ãŒã¿ãŒãšããŠæå¹ã«äœ¿
çšããããšãã§ããã æ¬çºæã¯ãã¹ãŠã®ã€ãªã³äº€æ容éãé«åºŠã®ã¢ã«
ã«ãªæ¡ä»¶ã«é¢ãããã®ã§ãããããªãã¡ãã¹ãŠã®
ã«ã«ãã³é žåã³ã¹ã«ãã³é žåºã亀æéšäœãšããŠäœ
çšããŠãã以äžã®äŸã«ãã€ãŠèª¬æããããããã
ããããã«éå®ãããªããä»ã«èšèŒããªããã°ã
ã¹ãŠã®éšåã³ããŒã»ã³ãã¯ééåºæºã«ãããã®ã§
ããã 以äžã®äžè¬çãªæ¹æ³ã«åŸã€ããéåŒçŽ ååºå¹¹ã®
è©Šæãã¬ã©ã¹åå¿å®¹åšã®äžã«çœ®ããã¢ãããŒæ··å
ç©ãæ·»å ãããåå¿å®¹åšã®å 容ç©ã液äœçªçŽ äžã«
ãããŠåçµãããã®ç³»ã«ååšãã空æ°ãé€å»ãã
ããã«ç空äžã«çœ®ããã å®å šãªææ°åŸãç空ãã³ããæã¡ããã®å 容ç©
ãæã宀枩ã«å°éããããã以åŸã¬ã¹æããšããŠ
èšåããããã®ããã»ã¹ãåå¿å®¹åšãã·ãŒã«ãã
åã«ïŒåç¹°ãè¿ããã ãã®æè¡ãçšããŠåå¿å®¹åšã®å 容ç©ãå®è³ªçã«
é žçŽ ã®ãªãé°å²æ°äžã«çœ®ãããããã«ãã®æ¹æ³ã
çšããŠè£œé ãããè©Šæã24æéã®ééžå®æž©åºŠã«å¹³
è¡¡ã«ãªããããã ãã®æéã®åŸãåå¿å®¹åšãç §å°ã»ã«å®€ã«ç§»ãã
ã³ãã«ãâ60æºããåºãγâç·ã«æŽé²ããã ç §å°çµäºåŸãã¬ã©ã¹åå¿å®¹åšã®å 容ç©ãåå¿å®¹
åšãéããåã«æ¶²äœçªçŽ äžã«ãããŠåçµãããã°
ã©ããããåºå¹¹ïŒãã€ã«ã åã¯ç²æ«ïŒãé©åœãªæº¶
å€ã§æªåå¿ã¢ãããŒåã³ãã¢ããªããŒãæŽã€ãŠé€
ãã60âã®ç空ãªãŒãã³äžã§äžå®ééãŸã§ä¹Ÿç¥ã
ãã è¡šåã³èšè¿°ã«ãããŠã次ã®ç¥èªãçšããã TFEïŒããã©ãã«ãªããšãã¬ã³ FEPïŒããã©ãã«ãªããšãã¬ã³ãšãããµãã«
ãªããããã¬ã³ã®ã³ããªã㌠PFBAïŒãã«ãã«ãªãããã³é ž IECïŒã€ãªã³äº€æ äžãããã倧ããã¯ãã¯ãã³ã§ããããã€ã«ã
ã®å Žåã«ã¯åããæå³ããç²æ«ã®å Žåã«ã¯ç²ååŸ
ãæå³ããã ã°ã©ããããŒã»ã³ãïŒãã€ã«ã ã®ééå¢å ãäŸ
ãã°ã°ã©ããããããã€ã«ã ã®ééããŒã»ã³ããš
ããŠè¡šçŸïŒãã°ã©ãããã€ã«ã ã®èµ€å€ã¹ãã¯ãã«
ïŒ1795cm-1ã®æ³¢æ°ã«ãããã«ã«ããã«åžåïŒåã³
ã€ãªã³äº€æ容éïŒmeqïŒïœãšããŠè¡šçŸïŒã¯Î³ç·ç §
å°ã«ãã€ãŠçæãããæ¹è³ªéåŒçŽ ååºå¹¹ãç¹æ§ã¥
ããããã«äœ¿çšãããã ã°ã©ããããŒã»ã³ãã¯åŒïŒ ã°ã©ããïŒ ïŒGiâGoïŒGiÃ100 ïŒåŒäžGoã¯ããªããŒåºå¹¹ã®åæã®ééã§ããã
Giã¯ç §å°åŸã®ã°ã©ããããªããŒã®ééã§ãããïŒ ããèšç®ãããã äŸ ïŒãïŒ ãããã®äŸã¯ã°ã©ããæå¶å€Î±âããã³ã®ååš
äžã§å®èœåã³éå®èœã¢ãããŒã®æ··åç©ã®ã°ã©ãã
ã説æããã ã¬ã©ã¹åå¿å®¹åšäžã«FEPãã€ã«ã ïŒ2.0ïœïŒã
眮ããPFBAïŒÎ±âããã³ïŒ0.12ïœã0.5ïŒ å šæ¿
床ïŒããArkloneããæ°ŽïŒ3.0ïœïŒåã³ã¢ã³ã¢ã
ãŠã ãã«ãã«ãªããªã¯ã¿ããšãŒãïŒ0.025ïœã
0.17ïŒ å šæ¿åºŠïŒã容åšã«æ·»å ãããïŒãArkloneã
ã¯ïŒïŒïŒïŒïŒâããªã¯ããâïŒïŒïŒïŒïŒâããªâ
ãã«ãªããšãã¬ã³ã«å¯Ÿããç»é²åæšã§ããïŒ æ··åç©ã液äœçªçŽ äžã«ãããŠåçµãã空æ°ãæ
æ°ããããŠå 容ç©ã宀枩ãŸã§å°éããããããã®
ã¬ã¹æãã®ããã»ã¹ãïŒåç¹°ãè¿ãã次ãã§
TFEïŒæå¶å€ãå šãå«ãŸãªãïŒã液äœçªçŽ ã®æž©åºŠ
ã§åå¿å®¹åšã®äžãžè£ å¡«ãããå®èœïŒPFBAïŒåã³
éå®èœïŒTFEïŒã¢ãããŒäžŠã³ã«æº¶å€ïŒãArkloneã
ïŒã®å šééã¯21ïœã§ãã€ãã ã¬ã©ã¹åå¿å®¹åšãã·ãŒã«ãã宀枩ã§äžæ©ä¿æã
ãã次ãã§ãããåšå²æž©åºŠã§120æé10KRADïŒ
hrã§ç §å°ããããã®æ··åç©ã¯1.2MRADã®å šç·é
ãåãããããã¬ã©ã¹å®¹åšãéããåã«åã³æ¶²äœ
çªçŽ ãšå ±ã«åçµãããã°ã©ãããããã€ã«ã ãå
éããæŽæµããŠã³ããªããŒåã³æªåå¿ã¢ãããŒã
é€å»ãããããŠ60âã§ç空ãªãŒãã³äžã«ãããŠä¹Ÿ
ç¥ããã çš®ã ã®æ¯ã®å®èœã¢ãããŒãéå®èœã¢ãããŒåã³
溶å€ã䜿çšããã ã°ã©ãããããã€ã«ã ã®èµ€å€ã¹ãã¯ãã«ã¯ã«ã«
ããã«åžåæ³¢æ°ã1795cm-1ã§ããããšã瀺ãã滎
å®ã«ãã€ãŠæž¬å®ãããã€ãªã³äº€æ容éã¯
0.2meqïŒïœã§ãã€ãã䜿çšãããæ¯ãã°ã©ãã
ããŒã»ã³ãåã³ã€ãªã³äº€æ容éãè¡šïŒã«ç€ºãã
ãè¡šã
ïŒ ãããã®è¡šã«ãããæ¿åºŠã¯å®èœåã³éå®
èœã¢ãããŒäžŠã³ã«æº¶å€ã®å šééããŒã»ã³ã
ãšããŠè¡šçŸãããã
äŸ ïŒã13 äŸïŒã®æ¹æ³ãå šåžåæŸå°ç·éãè¡šïŒã«ãããŠç€º
ãããŠããããã«å€åããŠããããšãé€ããŠç¹°ã
è¿ããçµæãè¡šã«ç€ºãã
èœã¢ãããŒäžŠã³ã«æº¶å€ã®å šééããŒã»ã³ã
ãšããŠè¡šçŸãããã
äŸ ïŒã13 äŸïŒã®æ¹æ³ãå šåžåæŸå°ç·éãè¡šïŒã«ãããŠç€º
ãããŠããããã«å€åããŠããããšãé€ããŠç¹°ã
è¿ããçµæãè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
äŸ 14ã20
äŸïŒã®æ¹æ³ãå
šåžåæŸå°ç·éãè¡šïŒã«ãããŠç€º
ãããŠããããã«å€åããŠããããšãé€ããŠç¹°ã
è¿ããçµæãè¡šã«ç€ºãã
ãããŠããããã«å€åããŠããããšãé€ããŠç¹°ã
è¿ããçµæãè¡šã«ç€ºãã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU0111 | 1981-08-07 | ||
| AUPF011181 | 1981-08-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58501232A JPS58501232A (ja) | 1983-07-28 |
| JPH0438762B2 true JPH0438762B2 (ja) | 1992-06-25 |
Family
ID=3769160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57502349A Granted JPS58501232A (ja) | 1981-08-07 | 1982-08-06 | éåæ¹æ³ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4481306A (ja) |
| JP (1) | JPS58501232A (ja) |
| AU (1) | AU551369B2 (ja) |
| DE (1) | DE3248945T1 (ja) |
| WO (1) | WO1983000487A1 (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2485395B1 (fr) * | 1980-06-24 | 1986-04-11 | Commissariat Energie Atomique | Membrane echangeuse de cations, son procede de fabrication et son application en tant qu'electrolyte solide |
| US5232600A (en) * | 1989-05-15 | 1993-08-03 | Pall Corporation | Hydrophobic membranes |
| US4954256A (en) * | 1989-05-15 | 1990-09-04 | Pall Corporation | Hydrophobic membranes |
| US5648400A (en) * | 1992-08-04 | 1997-07-15 | Japan Atomic Energy Research Inst. | Process for producing polymeric electrolyte complex and ion-exchange resin |
| JP3810179B2 (ja) * | 1996-05-10 | 2006-08-16 | ã€ãŒã»ã¢ã€ã»ãã¥ãã³ã»ããŠã»ãã ãŒã«ã»ã¢ã³ãã»ã«ã³ãã㌠| åäžããé»æ°ååŠçç¹æ§ãæããã«ããªã³äº€æèã®è£œé æ¹æ³ |
| WO2005049204A2 (en) * | 2003-09-29 | 2005-06-02 | E.I. Dupont De Nemours And Company | Trifluorostyrene containing compounds grafted to base polymers |
| TW200536869A (en) * | 2004-05-07 | 2005-11-16 | Du Pont | Stable trifluorostyrene containing compounds grafted to base polymers, and their use as polymer electrolyte membranes |
| US9234062B2 (en) * | 2011-12-14 | 2016-01-12 | Honeywell International Inc. | Process, properties, and applications of graft copolymers |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1371843A (fr) * | 1963-06-25 | 1964-09-11 | Centre Nat Rech Scient | Perfectionnements apportés aux membranes semi-perméables |
| GB1295874A (ja) * | 1968-11-26 | 1972-11-08 | ||
| JPS5032289A (ja) * | 1973-07-21 | 1975-03-28 | ||
| GB1435477A (en) * | 1973-11-19 | 1976-05-12 | Hooker Chemicals Plastics Corp | Electrolytic cell and process |
| US4113922A (en) * | 1974-12-23 | 1978-09-12 | Hooker Chemicals & Plastics Corp. | Trifluorostyrene sulfonic acid membranes |
| JPS5284191A (en) * | 1975-12-30 | 1977-07-13 | Asahi Glass Co Ltd | Improved f-contg. cation exchange resin membrane |
| JPS5939453B2 (ja) * | 1976-06-23 | 1984-09-22 | æ ªåŒäŒç€Ÿãã¯ã€ã | éœã€ãªã³äº€æäœã®è£œé æ¹æ³ |
| JPS538692A (en) * | 1976-07-14 | 1978-01-26 | Japan Atom Energy Res Inst | Preparation of graft copolymer for ion-exchange membrane |
| JPS5852700B2 (ja) * | 1976-08-25 | 1983-11-24 | ãã€ãã³å·¥æ¥æ ªåŒäŒç€Ÿ | ã€ãªã³äº€æäœã®è£œæ³ |
| JPS6010538B2 (ja) * | 1977-09-02 | 1985-03-18 | æåææ ªåŒäŒç€Ÿ | éœã€ãªã³äº€æèã®è£œé æ³ |
| JPS5679110A (en) * | 1979-11-30 | 1981-06-29 | Asahi Glass Co Ltd | Preparation of modified polytetrafluoroethylene |
| NZ195570A (en) * | 1979-12-28 | 1983-05-31 | Ici Australia Ltd | Cation exchange resin based on perhalogenated fluorine-containing polymer |
| US4278777A (en) * | 1980-03-27 | 1981-07-14 | Abcor, Inc. | Grafted polymers and method of preparing and using same |
-
1982
- 1982-08-06 DE DE823248945T patent/DE3248945T1/de not_active Ceased
- 1982-08-06 US US06/482,332 patent/US4481306A/en not_active Expired - Fee Related
- 1982-08-06 JP JP57502349A patent/JPS58501232A/ja active Granted
- 1982-08-06 AU AU87399/82A patent/AU551369B2/en not_active Ceased
- 1982-08-06 WO PCT/AU1982/000126 patent/WO1983000487A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| US4481306A (en) | 1984-11-06 |
| WO1983000487A1 (en) | 1983-02-17 |
| AU8739982A (en) | 1983-02-22 |
| DE3248945T1 (de) | 1983-11-03 |
| JPS58501232A (ja) | 1983-07-28 |
| AU551369B2 (en) | 1986-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4506035A (en) | Microporous hydrophilic fluoropolymer membranes and method | |
| FI68067C (fi) | Katjonbytarharts dess framstaellning och anvaendning | |
| EP1806371B1 (en) | Electrolyte membrane and membrane electrode assembly for solid polymer fuel cell | |
| EP1893323B1 (en) | A method of preparing a radiation fuel cell membrane with enhanced chemical stability and a membrane electrode assembly | |
| EP0065547B1 (en) | Permselective fluoropolymeric membrane and method of its production | |
| US4396727A (en) | Cation exchange membrane and process for producing the same | |
| US8263287B2 (en) | Polymer electrolyte membranes comprising alkyl graft chains and a process for producing the same | |
| JPH0438762B2 (ja) | ||
| EP0079157B1 (en) | Process for esterifying fluorinated carboxylic acid polymer | |
| EP1421126B1 (en) | Process for preparing graft copolymer membranes | |
| JP4670074B2 (ja) | èé žæ§ã®åªããçæé»æ± çšé»è§£è³ªè | |
| EP0057065B1 (en) | Production of cation permselective membrane and electrolytic cell containing said membrane | |
| JP2005142014A (ja) | èé žæ§ã«åªããçæé»æ± çšé»è§£è³ªè | |
| JPS61185507A (ja) | é°ã€ãªã³äº€æäœã®è£œé æ¹æ³ | |
| JP6861329B2 (ja) | ç±ååŠæ°ŽçŽ 補é ãšãŠçŽ âç¡«é»ïŒïœïœïŒããã»ã¹ã®èãã³ãŒã³åå¿åšã«äœ¿çšããã«ããªã³äº€æèã®è£œé æ¹æ³ | |
| AU8587682A (en) | Polymers | |
| NO830666L (no) | Polymerer. | |
| CH654318A5 (en) | Cation exchange resin | |
| US20080044710A1 (en) | Electrolyte Membrane Having Excellent Adhesion To Electrodes |