JPH04364114A - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- JPH04364114A JPH04364114A JP3139873A JP13987391A JPH04364114A JP H04364114 A JPH04364114 A JP H04364114A JP 3139873 A JP3139873 A JP 3139873A JP 13987391 A JP13987391 A JP 13987391A JP H04364114 A JPH04364114 A JP H04364114A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- dye
- hair
- limonene
- linalool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000118 hair dye Substances 0.000 title claims abstract description 39
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 84
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 claims abstract description 64
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000000341 volatile oil Substances 0.000 claims abstract description 50
- 238000004043 dyeing Methods 0.000 claims abstract description 44
- 239000000975 dye Substances 0.000 claims abstract description 43
- 229940087305 limonene Drugs 0.000 claims abstract description 41
- 235000001510 limonene Nutrition 0.000 claims abstract description 41
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims abstract description 30
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims abstract description 29
- 229930007744 linalool Natural products 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 230000001590 oxidative effect Effects 0.000 claims description 9
- 230000000694 effects Effects 0.000 abstract description 38
- 230000003647 oxidation Effects 0.000 abstract description 17
- 238000007254 oxidation reaction Methods 0.000 abstract description 17
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 25
- 239000000203 mixture Substances 0.000 description 25
- 239000008213 purified water Substances 0.000 description 23
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- -1 3'-iminodiphenol Chemical class 0.000 description 6
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 239000012192 staining solution Substances 0.000 description 6
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 5
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 5
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 5
- 241000207199 Citrus Species 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 3
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000283707 Capra Species 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 description 2
- 229940075861 ammonium thioglycolate Drugs 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- 229940075894 denatured ethanol Drugs 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 229940126534 drug product Drugs 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- HLUCICHZHWJHLL-UHFFFAOYSA-N hematein Chemical compound C12=CC=C(O)C(O)=C2OCC2(O)C1=C1C=C(O)C(=O)C=C1C2 HLUCICHZHWJHLL-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 125000000396 limonene group Chemical group 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- ZTQDYDIRBKMMQB-UHFFFAOYSA-N n-(4-aminophenyl)nitramide Chemical compound NC1=CC=C(N[N+]([O-])=O)C=C1 ZTQDYDIRBKMMQB-UHFFFAOYSA-N 0.000 description 2
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- NPNUFJAVOOONJE-ZIAGYGMSSA-N β-(E)-Caryophyllene Chemical compound C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- RFFOTVCVTJUTAD-AOOOYVTPSA-N 1,4-cineole Chemical compound CC(C)[C@]12CC[C@](C)(CC1)O2 RFFOTVCVTJUTAD-AOOOYVTPSA-N 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- DBMWNANFZQEHDV-UHFFFAOYSA-N 1-aminocyclohexa-2,4-dien-1-ol Chemical compound NC1(O)CC=CC=C1 DBMWNANFZQEHDV-UHFFFAOYSA-N 0.000 description 1
- VPMMJSPGZSFEAH-UHFFFAOYSA-N 2,4-diaminophenol;hydrochloride Chemical compound [Cl-].NC1=CC=C(O)C([NH3+])=C1 VPMMJSPGZSFEAH-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- DGRGLKZMKWPMOH-UHFFFAOYSA-N 4-methylbenzene-1,2-diamine Chemical compound CC1=CC=C(N)C(N)=C1 DGRGLKZMKWPMOH-UHFFFAOYSA-N 0.000 description 1
- QZHXKQKKEBXYRG-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 QZHXKQKKEBXYRG-UHFFFAOYSA-N 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- NVEQFIOZRFFVFW-UHFFFAOYSA-N 9-epi-beta-caryophyllene oxide Natural products C=C1CCC2OC2(C)CCC2C(C)(C)CC21 NVEQFIOZRFFVFW-UHFFFAOYSA-N 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 235000005976 Citrus sinensis Nutrition 0.000 description 1
- 240000002319 Citrus sinensis Species 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 241000134874 Geraniales Species 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- FAMPSKZZVDUYOS-UHFFFAOYSA-N alpha-Caryophyllene Natural products CC1=CCC(C)(C)C=CCC(C)=CCC1 FAMPSKZZVDUYOS-UHFFFAOYSA-N 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QKWNIOMGXBERHJ-RXSVEWSESA-N azane;(2r)-2-[(1s)-1,2-dihydroxyethyl]-3,4-dihydroxy-2h-furan-5-one Chemical compound N.OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QKWNIOMGXBERHJ-RXSVEWSESA-N 0.000 description 1
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 description 1
- CNYFJCCVJNARLE-UHFFFAOYSA-L calcium;2-sulfanylacetic acid;2-sulfidoacetate Chemical compound [Ca+2].[O-]C(=O)CS.[O-]C(=O)CS CNYFJCCVJNARLE-UHFFFAOYSA-L 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229940117948 caryophyllene Drugs 0.000 description 1
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 description 1
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 1
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 description 1
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- SVTDYSXXLJYUTM-UHFFFAOYSA-N disperse red 9 Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC SVTDYSXXLJYUTM-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- UENNEPPWFZYINW-UHFFFAOYSA-M sodium;2-amino-4,6-dinitrophenolate Chemical compound [Na+].NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1[O-] UENNEPPWFZYINW-UHFFFAOYSA-M 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229930006978 terpinene Natural products 0.000 description 1
- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、酸化染料を用いる染毛
剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to hair dyes using oxidative dyes.
【０００２】0002
【従来の技術】酸化染毛剤（以下、単に染毛剤という。
）には、第１剤に酸化染料を、第２剤に過酸化水素を各
々必須成分として含有する２剤式の染毛剤、水の添加で
過酸化水素を発生する過酸化物及び酸化染料を必須成分
とする乾燥粉末状の１剤式の染毛剤、同様な成分を炭化
水素（ワセリン、パラフィンワックス等）で非水系のま
ま練り込んだ１剤式の練り状染毛剤等が知られている。
この内２剤式のものは、使用時に１、２剤を混合して使
う。一方、１剤式のものは、使用時に適当量の水と混合
して使用する。そして、これら染毛剤の染毛効果は主に
ｐＨ、染毛時間及び染色剤中の酸化染料の濃度に依存す
る。即ち、十分な染毛効果を得るためにはｐＨを高くす
るか、染料濃度を高くするか、或いは染毛時間を長くす
ることが必要である。[Prior Art] Oxidative hair dyes (hereinafter simply referred to as hair dyes) are two-part hair dyes in which the first part contains an oxidation dye and the second part contains hydrogen peroxide as essential ingredients. Dry powder one-part hair dye that contains peroxide and oxidation dye as essential ingredients, which generate hydrogen peroxide when water is added, and similar ingredients that are mixed with hydrocarbons (Vaseline, paraffin wax, etc.). One-component hair dyes kneaded in water-based formulations are known. Among these, two-drug products are used by mixing one and two drugs together. On the other hand, single-drug products are mixed with an appropriate amount of water before use. The hair dyeing effects of these hair dyes mainly depend on the pH, hair dyeing time, and the concentration of oxidation dye in the dye. That is, in order to obtain a sufficient hair dyeing effect, it is necessary to increase the pH, increase the dye concentration, or lengthen the hair dyeing time.
【０００３】0003
【発明が解決しようとする課題】しかし、染毛剤のｐＨ
を高くすると毛髪を傷める危険性が高くなり、染料濃度
を高くすると皮膚のかぶれが発生しやすくなり、また、
染毛時間を長くすると、染色剤と皮膚及び毛髪との接触
時間が長くなるため同様な副作用が発生し易い。従来の
染毛剤では、これらの副作用を回避しながら十分な染毛
効果を得ることは必ずしも容易でなかった。[Problem to be solved by the invention] However, the pH of hair dye
A high dye concentration increases the risk of damaging the hair, and a high dye concentration increases the likelihood of skin irritation.
If the hair dyeing time is prolonged, the contact time between the dye and the skin and hair becomes longer, and similar side effects are likely to occur. With conventional hair dyes, it has not always been easy to obtain sufficient hair dyeing effects while avoiding these side effects.
【０００４】本発明の目的は、酸化染料の染毛効果を高
めることにより、より緩和な条件、即ち、より低いｐＨ
、より低い染料濃度、或いは、より短い染毛時間で十分
な染毛効果が得られ、従って副作用の少ない染毛剤を提
供することにある。The purpose of the present invention is to improve the hair dyeing effect of oxidative dyes under milder conditions, ie, lower pH.
The object of the present invention is to provide a hair dye that can provide a sufficient hair dyeing effect with a lower dye concentration or a shorter hair dyeing time, and therefore has fewer side effects.
【０００５】[0005]
【課題を解決するための手段】本発明者は、上記目的を
達成するため鋭意検討を重ねた結果、酸化染毛剤にある
種の精油を配合することで、染毛効果を高め得ることを
見出し、本発明を完成した。[Means for Solving the Problems] As a result of intensive studies to achieve the above object, the present inventor has discovered that the hair dyeing effect can be enhanced by blending certain essential oils into oxidative hair dyes. The present invention has been completed.
【０００６】即ち、本発明は、酸化染料を用いた染毛剤
であって、使用時の染色液中の濃度が、リモネンに換算
して０．２５〜５．０重量％のリモネンまたは該割合の
リモネンを含む精油類、リナリルアセテートに換算して
０．２５〜５．０重量％のリナリルアセテートまたは該
割合のリナリルアセテートを含む精油類、及び、リナロ
ールに換算して０．２５〜５．０重量％のリナロールま
たは該割合のリナロールを含む精油類のうち少くとも１
種を含む染毛剤を提供するものである。That is, the present invention provides a hair dye using an oxidative dye, wherein the concentration of limonene in the dyeing solution at the time of use is 0.25 to 5.0% by weight calculated as limonene, or the proportion thereof. essential oils containing limonene, essential oils containing 0.25 to 5.0% by weight of linalyl acetate in terms of linalyl acetate, or essential oils containing linalyl acetate in this proportion, and 0.25 to 5.0% in terms of linalool At least 1% by weight of linalool or essential oils containing this proportion of linalool
A hair dye containing seeds is provided.
【０００７】本発明の組成物に使用されるリモネンとは
、１−メチル−４−（１−メチルエテニル）シクロヘキ
センである。また、本発明でいう“リモネンを含む精油
類”とは、シトルス オーラオティウム（Ｃｉｔｒｕ
ｓ ａｕｒａｕｔｉｕｍ）， シトルス シネンシス
（Ｃｉｔｒｕｓ ｓｉｎｅｎｓｉｓ）等多くの柑橘類植
物の精油を始め、九年母（くねんぼ）油、セロリ油など
、リモネンを６０％以上含む精油類をいう。柑橘類植物
の種類により、例えばレモンオイルではゲラニアール、
ネラール等が含まれ、オレンジオイルではｎ−オクタナ
ール、ｎ−デカナール等が含まれ、ライムオイルでは１
，４−シネオール、α−テルピネオール等が含まれてい
るが、精油中にリモネンが６０％以上含まれる限り、こ
れらの成分は本発明の効果を阻害するものではない。本
発明において、リモネンまたはリモネンを含む精油類の
染色液中の濃度は、好ましくは０．５〜５．０重量％で
あるのが良い。The limonene used in the composition of the present invention is 1-methyl-4-(1-methylethenyl)cyclohexene. In addition, "essential oils containing limonene" as used in the present invention refers to Citrus auraotium (Citrus auraotium).
It refers to essential oils containing 60% or more of limonene, such as essential oils of many citrus plants such as Citrus sauratium and Citrus sinensis, as well as Kunenbo oil and celery oil. Depending on the type of citrus plant, for example, lemon oil contains geranial,
Contains neral, orange oil contains n-octanal, n-decanal, etc., and lime oil contains 1
, 4-cineole, α-terpineol, etc., but as long as 60% or more of limonene is contained in the essential oil, these components do not inhibit the effects of the present invention. In the present invention, the concentration of limonene or essential oils containing limonene in the dyeing solution is preferably 0.5 to 5.0% by weight.
【０００８】本発明の組成物に使用されるリナリルアセ
テートとは、３，７−ジメチル−１，６−オクタジエン
−３−イル アセテートである。また、本発明の組成
物に使用されるリナロールとは、３，７−ジメチル−１
，６−オクタジエン−３−オールである。The linalyl acetate used in the composition of the present invention is 3,7-dimethyl-1,6-octadien-3-yl acetate. In addition, linalool used in the composition of the present invention is 3,7-dimethyl-1
, 6-octadien-3-ol.
【０００９】本発明でいう“リナリルアセテートを含む
精油類”及び“リナロールを含む精油類”とは、通常各
々リナリルアセテートを７０％以上含む精油類及びリナ
ロールを７０％以上含む精油類を意味するが、リナリル
アセテートとリナロールの含有率の合計が７０％以上で
ある精油類であっても良い。例えば、ラベンダーオイル
は、カンファー、カリオフィレン、テルピネオール、γ
−テルピネンなど約３００種の成分が判明しているが、
リナリルアセテートとリナロールの含有率の合計が７０
％以上である限り本発明の効果を発揮する。[0009] In the present invention, "essential oils containing linalyl acetate" and "essential oils containing linalool" usually mean essential oils containing 70% or more of linalyl acetate and essential oils containing 70% or more of linalool, respectively. , essential oils may have a total content of linalyl acetate and linalool of 70% or more. For example, lavender oil contains camphor, caryophyllene, terpineol, gamma
- Approximately 300 types of ingredients have been identified, including terpinene.
The total content of linalyl acetate and linalool is 70
% or more, the effects of the present invention are exhibited.
【００１０】なお、ある精油中におけるリナリルアセテ
ートとリナロールの含有率の合計を計算する場合、その
精油中にリモネンが含まれる場合には、そのリモネンを
除外してリナリルアセテートとリナロールの含有率の合
計値を計算する。例えば、ベルガモットオイルのように
、リモネン、リナロール及びリナリルアセテートを各々
約３０％、約２０％及び約３０％の割合で含む場合、リ
ナリルアセテートとリナロールの含有率の合計は、（２
０＋３０）／（１００−３０）＝７１．４％であり、含
有率の合計は７０％以上であるため有効である。[0010] When calculating the total content of linalyl acetate and linalool in a certain essential oil, if the essential oil contains limonene, exclude that limonene and calculate the total content of linalyl acetate and linalool. Calculate the value. For example, when bergamot oil contains limonene, linalool, and linalyl acetate in proportions of about 30%, 20%, and 30%, respectively, the total content of linalyl acetate and linalool is (2
0+30)/(100-30)=71.4%, and the total content is 70% or more, so it is effective.
【００１１】本発明において、リナリルアセテートまた
はリナリルアセテートを含む精油類、及び、リナロール
またはリナロールを含む精油類の染色液中の濃度は、好
ましくは各々０．５〜５．０重量％であるのが良い。In the present invention, the concentration of linalyl acetate or essential oils containing linalyl acetate, and linalool or essential oils containing linalool in the dyeing solution is preferably 0.5 to 5.0% by weight each. good.
【００１２】本発明は、剤型を特に限定することなく、
公知の剤型、例えば２剤型（アニオンベース液状、ペー
スト状等）のもの、粉末状のもの、練り状のもの等を任
意に選択できる。また、使用する酸化染料も特に限定す
ることなく、公知の染料を広く使用することができ、具
体的には以下のものが例示できる。[0012] The present invention does not particularly limit the dosage form;
Any known dosage form may be selected, such as a two-dose type (anion-based liquid, paste, etc.), a powdered form, a kneaded form, and the like. Further, the oxidation dye to be used is not particularly limited, and a wide variety of known dyes can be used, and specific examples include the following.
【００１３】■ ２剤式の酸化染毛剤に使用される酸
化染料
５−アミノオルトクレゾール、２−アミノ−４−ニトロ
フェノール、２−アミノ−５−ニトロフェノール、３，
３’ −イミノジフェノール、塩酸２，４−ジアミノフ
ェノール、オルトアミノフェノール、パラアミノフェノ
ール、パラメチルアミノフェノール、メタアミノフェノ
ール、等のアミノフェノール類及びその硫酸、塩酸、酢
酸等の塩、１−アミノ−４−メチルアミノアントラキノ
ン、１，４−ジアミノアントラキノン、ヒドロキノン等
のキノン類及びその硫酸、塩酸、酢酸等の塩、トルエン
２，５−ジアミン、ニトロパラフェニレンジアミン、パ
ラフェニレンジアミン、Ｎ−フェニルパラフェニレンジ
アミン、メタフェニレンジアミン、２，６−ジアミノピ
リジン、トルエン３，４−ジアミン、パラニトロオルト
フェニレンジアミン等のジアミン類及びその硫酸、塩酸
、酢酸等の塩、カテコール、１，５−ジヒドロキシナフ
タレン、ピロガロール等のジフェノールまたはポリフェ
ノール類、その他、ピクラミン酸、ピクラミン酸ナトリ
ウム、ピクリン酸、ジフェニルアミン、α−ナフトール
、パラアミノフェニルスルファミン酸、２−ヒドロキシ
−５−ニトロ−２’ ，４’ −ジアミノアゾベンゼン
−５−スルホン酸ナトリウム、フロログルシン、ヘマテ
イン、没食子酸等が挙げられる。■ Oxidation dyes used in two-part oxidation hair dyes: 5-aminoorthocresol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 3,
Aminophenols such as 3'-iminodiphenol, 2,4-diaminophenol hydrochloride, orthoaminophenol, paraaminophenol, paramethylaminophenol, metaaminophenol, and their salts such as sulfuric acid, hydrochloric acid, acetic acid, 1-aminophenol - Quinones such as 4-methylaminoanthraquinone, 1,4-diaminoanthraquinone, and hydroquinone, and their salts such as sulfuric acid, hydrochloric acid, and acetic acid, toluene 2,5-diamine, nitroparaphenylenediamine, paraphenylenediamine, N-phenylpara Diamines such as phenylenediamine, metaphenylenediamine, 2,6-diaminopyridine, toluene 3,4-diamine, p-nitroorthophenylenediamine, and their salts such as sulfuric acid, hydrochloric acid, acetic acid, catechol, 1,5-dihydroxynaphthalene, Diphenols or polyphenols such as pyrogallol, others, picramic acid, sodium picramate, picric acid, diphenylamine, α-naphthol, para-aminophenylsulfamic acid, 2-hydroxy-5-nitro-2',4'-diaminoazobenzene-5 - Sodium sulfonate, phloroglucin, hematein, gallic acid and the like.
【００１４】■ １剤式の酸化染毛剤に使用される酸
化染料
２−アミノ−５−ニトロフェノール、オルトアミノフェ
ノール、パラアミノフェノール、パラメチルアミノフェ
ノール、メタアミノフェノール等のアミノフェノール類
及びその硫酸、塩酸、酢酸、ナトリウム等の塩、及び、
オルトクロルパラフェニレンジアミン、４，４’ −ジ
アミノジフェニルアミン、トルエン２，５−ジアミン、
ニトロパラフェニレンジアミン、パラニトロオルトフェ
ニレンジアミン、パラニトロメタフェニレンジアミン、
パラフェニレンジアミン、メタフェニレンジアミン等の
ジアミン類及びその硫酸、塩酸、酢酸等の塩、等が挙げ
られる。■ Oxidation dyes used in one-part oxidation hair dyes Aminophenols such as 2-amino-5-nitrophenol, ortho-aminophenol, para-aminophenol, para-methylaminophenol, meta-aminophenol, and their sulfuric acids , salts of hydrochloric acid, acetic acid, sodium, etc., and
orthochlorparaphenylenediamine, 4,4'-diaminodiphenylamine, toluene 2,5-diamine,
Nitroparaphenylenediamine, paranitroorthophenylenediamine, paranitromethphenylenediamine,
Examples include diamines such as para-phenylene diamine and meta-phenylene diamine, and their salts such as sulfuric acid, hydrochloric acid, and acetic acid.
【００１５】一剤中に金属イオンが存在すると、酸化染
料の発色を速めたり、一部の界面活性剤と不溶性の石鹸
を作るため、本発明の染毛剤には、必要に応じて金属封
鎖剤を配合することができる。また、酸化染料が酸化さ
れ、発色することを抑える目的で本発明の染色剤に酸化
防止剤を配合しておくこともできる。[0015] The presence of metal ions in a single agent accelerates the color development of oxidation dyes and creates soaps that are insoluble with some surfactants. Agents can be added. Further, an antioxidant may be added to the dyeing agent of the present invention in order to prevent the oxidation dye from being oxidized and developing color.
【００１６】上記目的で配合される金属封鎖剤としては
、エデト酸、エデト酸二ナトリウム、エデト酸四ナトリ
ウム、クエン酸ナトリウム、メタリン酸ナトリウム、ポ
リリン酸ナトリウム等が挙げられる。[0016] Examples of the sequestering agent blended for the above purpose include edetic acid, disodium edetate, tetrasodium edetate, sodium citrate, sodium metaphosphate, and sodium polyphosphate.
【００１７】また、上記目的で配合される酸化防止剤と
しては、チオグリコール酸、チオグリコール酸カルシウ
ム、チオグリコール酸アンモニウム、亜硫酸ナトリウム
、アスコルビン酸、アスコルビン酸ナトリウム、アスコ
ルビン酸アンモニウム、没食子酸プロピル、トコフェロ
ール等が挙げられる。[0017] Antioxidants to be added for the above purpose include thioglycolic acid, calcium thioglycolate, ammonium thioglycolate, sodium sulfite, ascorbic acid, sodium ascorbate, ammonium ascorbate, propyl gallate, and tocopherol. etc.
【００１８】これらのほか、公知の毛髪保護剤・着香料
なども、染毛剤の性能を損なわない範囲で適宜加えても
良い。[0018] In addition to these, known hair protectants, flavoring agents, etc. may be added as appropriate to the extent that they do not impair the performance of the hair dye.
【００１９】また、実用化の際、１品剤のように非水系
のものでは、有効成分をマイクロカプセル化して配合し
たり、糖質などに吸着させた後、極微量の水分で固めた
ものを粉砕して粉末化したものを用いることもできる。[0019] In addition, for practical use, in the case of non-aqueous products such as single-product preparations, the active ingredient may be blended into microcapsules, or the active ingredient may be adsorbed onto carbohydrates and then hardened with a trace amount of water. It is also possible to use a product obtained by pulverizing and pulverizing.
【００２０】[0020]
【発明の効果】本発明の効果としては、以下のものが挙
げられる。[Effects of the Invention] The effects of the present invention include the following.
【００２１】■ 本発明の染毛剤は、リモネン、リナ
リルアセテート又はリナロール等の精油を所定量含有さ
せることで、これら精油以外は同一成分を含む染毛剤よ
りも染着効果を高くすることができる。従って、染毛条
件の緩和、即ち染毛剤のｐＨの低下、酸化染料の濃度の
低下又は染毛時間の短縮を行っても、従来品と同様な濃
さで染毛を行うことができ、染毛時における毛髪の傷み
、皮膚のかぶれ等の副作用を防止又は軽減することがで
き、より安全な染毛剤を提供できるようになった。■
本発明の染毛剤は、染色の均一性についても所定量の
精油類を含まない従来の染毛剤よりも優れており、より
染色むらの少ない染毛剤を提供できるようになった。■ By containing a predetermined amount of essential oils such as limonene, linalyl acetate, or linalool, the hair dye of the present invention can have a higher dyeing effect than hair dyes containing the same components other than these essential oils. can. Therefore, even if the hair dyeing conditions are relaxed, that is, the pH of the hair dye is lowered, the concentration of the oxidative dye is lowered, or the hair dyeing time is shortened, hair can be dyed to the same density as conventional products. It is now possible to prevent or reduce side effects such as hair damage and skin irritation during hair dyeing, and it has become possible to provide a safer hair dye. ■
The hair dye of the present invention is also superior to conventional hair dyes that do not contain a predetermined amount of essential oils in terms of uniformity of dyeing, making it possible to provide a hair dye with less uneven dyeing.
【００２２】■ 本発明で使用する精油成分は芳香を
有するので、アルカリ剤等として使用するアンモニアな
どの刺激臭やその他の原料臭をマスキングするため、調
合香料を配合する必要性がなくなった。[0022] Since the essential oil component used in the present invention has an aroma, there is no need to add a blended fragrance to mask the irritating odor of ammonia used as an alkaline agent, etc., and the odor of other raw materials.
【００２３】[0023]
【実施例】以下、本発明を実施例を用いて説明するが、
本発明はこれら実施例により限定されるものではない。[Examples] The present invention will be explained below using Examples.
The present invention is not limited to these Examples.
【００２４】尚、以下の実施例１〜３において、本発明
の各染毛剤の効果は、リモネン、リナリルアセテート又
はリナロールを配合する代わりに精製水を配合した染毛
剤との比較により決定した。In Examples 1 to 3 below, the effectiveness of each hair dye of the present invention was determined by comparison with a hair dye containing purified water instead of limonene, linalyl acetate, or linalool. .
【００２５】また、染毛試験は、実施例１〜３において
は脱色山羊毛の一束（約３ｇ）に第１剤及び第２剤の等
量混合液１０ｇを塗り付けて２０分間染毛後、ぬるま湯
で十分にすすぎ、シャンプーをした後、熱風で乾燥した
染色毛について行った。In addition, in Examples 1 to 3, the hair dyeing test was carried out by applying 10 g of a mixed solution of equal amounts of the first and second agents to a bundle of bleached goat hair (approximately 3 g), and dyeing the hair for 20 minutes. After thoroughly rinsing with lukewarm water and shampooing, the dyed hair was dried with hot air.
【００２６】そして、染毛効果は、肉眼観察により決定
した。The hair dyeing effect was determined by visual observation.
【００２７】以下に、本実施例で使用される略号を示す
。The abbreviations used in this example are shown below.
【００２８】＊ＮＰＥ：ポリオキシエチレンノニルフェ
ニルエーテル
＊ＰＰＤ：パラフェニレンジアミン
＊ＭＰＤ：塩酸メタフェニレンジアミン＊ＰＡＰ：パラ
アミノフェノール
＊ＴＧＡＡ：チオグリコール酸アンモニウム＊ＥＤＴＡ
：エデト酸二ナトリウム
＊ＳＬＳ：ポリオキシエチレンラウリル硫酸ナトリウム
＊ＰＴＤ：パラトルイレンジアミン
＊ＯＡＰ：オルトアミノフェノール
＊ＭＡＰ：メタアミノフェノール
＊ＲＥ：レゾルシン
＊ＣＥ１５：ポリオキシエチレンセチルエーテル（エチ
レンの平均重合度１５）
＊ＣＥ２０：ポリオキシエチレンセチルエーテル（エチ
レンの平均重合度２０）
なお、以下の実施例において“部”とは、“重量部”を
表わす。*NPE: Polyoxyethylene nonylphenyl ether *PPD: Paraphenylenediamine *MPD: Metaphenylenediamine hydrochloride *PAP: Paraaminophenol *TGAA: Ammonium thioglycolate *EDTA
: Disodium edetate *SLS: Sodium polyoxyethylene lauryl sulfate *PTD: Paratolylene diamine *OAP: Ortho-aminophenol *MAP: Meta-aminophenol *RE: Resorcinol *CE15: Polyoxyethylene cetyl ether (average polymerization of ethylene Degree of polymerization: 15) *CE20: Polyoxyethylene cetyl ether (average degree of polymerization of ethylene: 20) In the following examples, "parts" refers to "parts by weight."
【００２９】[0029]
【実施例１】
（第１剤）
（溶剤）
ＮＰＥ
２０．０部 ９５％エタノール
１０．０部 強アンモニア
水（２８％）
５．０部（酸化染料）
ＰＰＤ
０．３部 ＭＰＤ
０．４部
ＰＡＰ
０．
８部（その他）
ＴＧＡＡ
０．４部 ＥＤＴＡ
０．２部（精油）
精油■（リモネン）
１
．０部 精油■（リモネン）
２．０部 残り精製水で
１００．０部とする（第２剤）
ＳＬＳ
２．０部 セタノール
１．５部 リン酸
０．００
０２部 過酸化水素水（３５％）
１７
．０部 残り精製水で
１００．０部とする尚、比較品は、第１剤中の精油と
してリモネンを加える代わりに精製水を加えた。[Example 1] (First agent) (Solvent) NPE
20.0 parts 95% ethanol
10.0 parts Strong ammonia water (28%)
5.0 parts (oxidation dye) PPD
0.3 part MPD
0.4 parts
P.A.P.
0.
Part 8 (Others) TGAA
0.4 parts EDTA
0.2 parts (essential oil) Essential oil ■ (limonene)
1
．． 0 parts essential oil (limonene)
2.0 parts with remaining purified water
100.0 parts (second agent) SLS
2.0 parts Setanol
1.5 parts phosphoric acid
0.00
02 parts Hydrogen peroxide solution (35%)
17
．． 0 parts with remaining purified water
In the comparative product, purified water was added instead of adding limonene as the essential oil in the first agent.
【００３０】精油■又は精油■を加えた染色液の染毛効
果を比較品との対比で決定した。The hair dyeing effect of the essential oil (1) or the dyeing solution to which essential oil (2) was added was determined in comparison with a comparative product.
【００３１】結果を下記の表１に示す。The results are shown in Table 1 below.
【００３２】[0032]
【表１】[Table 1]
【００３３】尚、 −：効果なし ＋：区別できる程度には効果がある ＋＋：はっきりと効果がある ＋＋＋：更に強く効果がある。[0033] Furthermore, −: No effect +: Effective to the extent that it can be distinguished ++: Clearly effective +++: Even stronger effect.
【００３４】を示す。[0034] is shown.
【００３５】また、表１中において、染色液中のリモネ
ンの濃度は第１剤と第２剤を等量混合するので、第１剤
中の濃度の１／２となっている。Further, in Table 1, the concentration of limonene in the dyeing solution is 1/2 of the concentration in the first agent because equal amounts of the first agent and the second agent are mixed.
【００３６】この表１の結果から、リモネンを配合する
ことにより染毛剤の染毛効果が著しく改善されることが
明らかとなった。From the results shown in Table 1, it is clear that the hair dyeing effect of the hair dye is significantly improved by incorporating limonene.
【００３７】[0037]
【実施例２】
（第１剤）
（溶剤）
ＮＰＥ
２０．０部 ９５％エタノール
５．０部 ヤシ油脂肪
酸ジエタノールアミド
５．０部 強アンモニア水（
２８％）
５．０部（酸化染料）
染料Ａ
ＰＰＤ
０．３部 ＯＡＰ
０．３部 染
料Ｂ
ＰＰＤ
０．３部 ＭＡＰ
０．３部 染
料Ｃ
ＰＰＤ
０．３部 ＰＡＰ
０．３部 染
料Ｄ
ＰＰＤ
０．３部 ＭＰＤ
０．０２部
染料Ｅ
ＰＰＤ
０．３部 ＲＥ
０．５部
染料Ｆ
ＰＴＤ
０．３部 ＯＡＰ
０．３部 染
料Ｇ
ＰＴＤ
０．３部 ＭＡＰ
０．３部 染
料Ｈ
ＰＴＤ
０．３部 ＰＡＰ
０．３部 染
料Ｉ
ＰＴＤ
０．３部 ＭＰＤ
０．０２部
染料Ｊ
ＰＴＤ
０．３部 ＲＥ
０．５部（その他）
ＴＧＡＡ
０．４部 ＥＤＴＡ
０．２部（精油）
精油■（リモネン）
１
．０部 精油■（リナロール）
１．０部 精油■（リナロール）
０．５部 （リナリルア
セテート）
０．５部 精油■（リナリルアセテ
ート）
１．０部 残り精製水で
１００．０部とする（第２剤）
ＳＬＳ
２．０部 セタノール
１．５部 リン酸
０．００
０２部 過酸化水素水（３５％）
１７
．０部 残り精製水で
１００．０部とする尚、比較品は、第１剤中の精油と
してリモネンを加える代わりに精製水を加えた。[Example 2] (First agent) (Solvent) NPE
20.0 parts 95% ethanol
5.0 parts Coconut oil fatty acid diethanolamide
5.0 parts Strong ammonia water (
28%)
5.0 parts (oxidation dye) Dye A PPD
0.3 parts OAP
0.3 parts Dye B PPD
0.3 part MAP
0.3 parts Dye C PPD
0.3 parts PAP
0.3 parts Dye D PPD
0.3 part MPD
0.02 part
Dye E PPD
0.3 part RE
0.5 part
Dye F PTD
0.3 parts OAP
0.3 parts Dye G PTD
0.3 part MAP
0.3 parts Dye H PTD
0.3 parts PAP
0.3 parts Dye I PTD
0.3 part MPD
0.02 part
Dye J PTD
0.3 part RE
0.5 part (other) TGAA
0.4 parts EDTA
0.2 parts (essential oil) Essential oil ■ (limonene)
1
．． 0 parts essential oil (linalool)
1.0 parts essential oil (linalool)
0.5 parts (linalyl acetate)
0.5 parts essential oil (linalyl acetate)
1.0 parts with remaining purified water
100.0 parts (second agent) SLS
2.0 parts Setanol
1.5 parts phosphoric acid
0.00
02 parts Hydrogen peroxide solution (35%)
17
．． 0 parts with remaining purified water
In the comparative product, purified water was added instead of adding limonene as the essential oil in the first agent.
【００３８】また、染料（染料Ａ〜染料Ｊまでの計１０
種類）及び精油（精油■〜精油■までの計４種類）は、
各一種類ずつ選択して第１剤を構成し、合計４０種類の
第１剤を用いて染色効果の試験を行った。In addition, dyes (dye A to dye J, total 10
Types) and essential oils (total of 4 types from essential oil ■ to essential oil ■) are:
One type of each type was selected to constitute the first agent, and a dyeing effect test was conducted using a total of 40 types of the first agent.
【００３９】結果を下記の表２に示す。The results are shown in Table 2 below.
【００４０】[0040]
【表２】[Table 2]
【００４１】尚、表中において、 ○：比較品と対比して効果が優る △：比較品と同程度の効果である ×：比較品と対比して効果が劣る を示す。[0041] In the table, ○: Superior effectiveness compared to comparative products △: Same level of effect as comparative product ×: Less effective compared to comparative product shows.
【００４２】この表の結果から、本願の組成物は、使用
する酸化染料により効果がかなり左右されることが明か
になった。しかし、上記表２は、リモネン等の精油類を
染色液に対し比較的低い量（０．５重量％）加えたとき
の結果であり、リモネン等の精油類をより多く（但し、
リモネン及びリナリルアセテートについては５．０重量
％以下、リナロールについては２．５重量％以下）配合
すると、上記４０種すべての場合において、比較品と対
比して優れた効果を示すことが確認されている。From the results in this table, it is clear that the effects of the composition of the present application are considerably influenced by the oxidation dye used. However, Table 2 above shows the results when a relatively low amount (0.5% by weight) of essential oils such as limonene is added to the dyeing solution, and the results are obtained when essential oils such as limonene are added in a relatively low amount (0.5% by weight).
It has been confirmed that when combined with limonene and linalyl acetate (5.0% by weight or less, and linalool (2.5% by weight or less)), it exhibits superior effects compared to comparative products in all 40 cases above. There is.
【００４３】[0043]
【実施例３】リモネンの濃度の染料組成物の染色効果に
対する影響を調べるため、酸化染料としてＰＰＤ及びＭ
ＡＰを使用し、精油（リモネン）の量を各々０部（比較
品）、０．１０部、０．５０部、１．０部、５．０部、
１０．０部及び１５．０部に変化させた７種類の染料組
成物を調製した。[Example 3] In order to investigate the influence of the concentration of limonene on the dyeing effect of the dye composition, PPD and M were used as oxidation dyes.
Using AP, the amount of essential oil (limonene) was 0 parts (comparative product), 0.10 parts, 0.50 parts, 1.0 parts, 5.0 parts, respectively.
Seven types of dye compositions were prepared with varying amounts of 10.0 parts and 15.0 parts.
【００４４】同様な染料組成物を、リナリルアセテート
（酸化染料：ＰＰＤ、ＰＡＰ及びＲＥ）及びリナロール
（酸化染料：ＰＴＤ、ＰＡＰ及びＲＥ）について各々７
種類ずつ作成した。Similar dye compositions were prepared for linalyl acetate (oxidative dyes: PPD, PAP and RE) and linalool (oxidative dyes: PTD, PAP and RE), respectively.
I created each type.
【００４５】これら２１種類の染料の第１剤の組成を以
下の表３〜表５に示す。なお、表３〜表５において、数
値はすべて重量部を表わす。The compositions of the first agent of these 21 types of dyes are shown in Tables 3 to 5 below. In addition, in Tables 3 to 5, all numerical values represent parts by weight.
【００４６】[0046]
【表３】[Table 3]
【００４７】[0047]
【表４】[Table 4]
【００４８】[0048]
【表５】[Table 5]
【００４９】第２剤は、全ての染料組成物について共通
で、その組成は以下の通りである。
（第２剤）
ＳＬＳ
２．０部 セタノール
１．５部 リン酸
０．００
０２部 過酸化水素水（３５％）
１７
．０部 残り精製水で
１００．０部とする上記２１種類の染毛剤の染毛効果
についての試験結果を以下の表６に示す。The second agent is common to all dye compositions, and its composition is as follows. (Second agent) SLS
2.0 parts Setanol
1.5 parts phosphoric acid
0.00
02 parts Hydrogen peroxide solution (35%)
17
．． 0 parts with remaining purified water
The test results for the hair dyeing effects of the above 21 types of hair dyes at 100.0 parts are shown in Table 6 below.
【００５０】[0050]
【表６】[Table 6]
【００５１】尚、表６中において、 −：効果なし ＋：区別できる程度には効果がある ＋＋：はっきりと効果がある ＋＋＋：更に強く効果がある。[0051] In Table 6, −: No effect +: Effective to the extent that it can be distinguished ++: Clearly effective +++: Even stronger effect.
【００５２】を示す。0052 is shown.
【００５３】上記の結果から、以下の結論が導かれた。
即ち、リモネンは、染色液中の濃度が０．２５％以上で
実用的な効果があり、５．０％を越えて配合しても効果
上の差異はなく、不経済であることが明かになった。リ
ナリルアセテートは、染色液中の濃度が０．２５％以上
で実用的な効果があり、７．５％の濃度では着色が見ら
れたため５．０％以下の濃度で使用することが好ましい
。From the above results, the following conclusions were drawn. In other words, it is clear that limonene has a practical effect when the concentration in the dyeing solution is 0.25% or more, and there is no difference in effectiveness even if it is added in a concentration exceeding 5.0%, which is uneconomical. became. Linalyl acetate has a practical effect when the concentration in the staining solution is 0.25% or more, and since coloring was observed at a concentration of 7.5%, it is preferable to use it at a concentration of 5.0% or less.
【００５４】リナロールも、染色液中の濃度が０．２５
％以上で実用的な効果があり、２．５％を越えて配合し
ても効果上の差異はなく、不経済であることが明かにな
った[0054] Linalool also has a concentration of 0.25 in the staining solution.
It has become clear that there is a practical effect when the amount exceeds 2.5%, and there is no difference in effectiveness even when the amount exceeds 2.5%, making it uneconomical.
【００５５】。[0055]
【実施例４】以下に、アニオンベースで液状の染毛剤の
組成を示す。Example 4 The composition of an anion-based liquid hair dye is shown below.
【００５６】
（第１剤）
ＳＬＳ
２５．０部 オレイン酸
１０．０部
ヤシ油脂肪酸ジエタノールアミド
５．０部 ゲラ
変エタノール
７．０部
ＥＤＴＡ
０．
２部 ＴＧＡＡ
０．４部 強アンモニア水
（２８％）
６．０部 ＰＰＤ
０．４部
ＭＡＰ
０
．３部 リモネン
１．０部 残り精製水で
１００．０部とする（第２剤）
リン酸
０．０００２部 過酸化水素水（
３５％）
１７．０部 残り精製水で
１００．０部とするなお、比較品
としては、リモネンを精製水で置き換えたものを使用し
た。(First agent) SLS
25.0 parts oleic acid
10.0 copies
Coconut oil fatty acid diethanolamide
5.0 parts galley denatured ethanol
7.0 copies
EDTA
0.
Part 2 TGAA
0.4 parts strong ammonia water (28%)
6.0 parts PPD
0.4 parts
MAP
0
．． Part 3 Limonene
1.0 parts with remaining purified water
100.0 parts (second agent) phosphoric acid
0.0002 parts hydrogen peroxide solution (
35%)
17.0 parts with remaining purified water
100.0 parts. As a comparative product, one in which limonene was replaced with purified water was used.
【００５７】また、本剤の第１剤と第２剤の混合液のｐ
Ｈは９．９４（比較品のｐＨは９．９８）であった。[0057] In addition, the p of the mixed solution of the first and second agents of this agent
H was 9.94 (pH of the comparative product was 9.98).
【００５８】[0058]
【実施例５】以下に、もう１つのアニオンベースで液状
の染毛剤の組成を示す。Example 5 The composition of another anion-based liquid hair dye is shown below.
【００５９】
（第１剤）
ＳＬＳ
２５．０部 オレイン酸
１０．０部 ヤシ油
脂肪酸ジエタノールアミド
５．０部 ゲラ変エタノ
ール
７．０部 ＥＤ
ＴＡ
０．２部
ＴＧＡＡ
０．４部 強アンモニア水（２８％
）
６．０部 ＰＴＤ
０．３部 ＯＡ
Ｐ
０．３部
ＲＥ
０．５部 リモネン
１．０部
リナリルアセテート
１．０部
残り精製水で
１００．０部と
する（第２剤）
リン酸
０．０００２部 過酸化水素
水（３５％）
１７．０部 残り精製水
で
１００．０部とするなお、比較品
としては、リモネン及びリナリルアセテートを精製水で
置き換えたものを使用した。(First agent) SLS
25.0 parts oleic acid
10.0 parts Coconut oil fatty acid diethanolamide
5.0 parts galley denatured ethanol
7.0 part ED
T.A.
0.2 parts
TGAA
0.4 parts Strong ammonia water (28%
)
6.0 copies PTD
0.3 copies OA
P
0.3 parts
R.E.
0.5 part limonene
1.0 copy
linalyl acetate
1.0 copy
with remaining purified water
100.0 parts (second agent) phosphoric acid
0.0002 parts hydrogen peroxide solution (35%)
17.0 parts with remaining purified water
100.0 parts.As a comparative product, one in which limonene and linalyl acetate were replaced with purified water was used.
【００６０】また、本剤の第１剤と第２剤の混合液のｐ
Ｈは９．７０（比較品のｐＨは９．６９）であった。[0060] In addition, the p of the mixed solution of the first and second agents of this agent
H was 9.70 (pH of the comparative product was 9.69).
【００６１】[0061]
【実施例６】以下に、ペースト状の染毛剤の組成を示す
。[Example 6] The composition of a paste-like hair dye is shown below.
【００６２】
（第１剤）
ステアリルアルコール
６．
０部 オレイルアルコール
７．０部 流動パラフィン
１０．０部 ＣＥ１５
１０．０部 Ｅ
ＤＴＡ
０．２部
ＴＧＡＡ
０．４部 強アンモニア水（２８
％）
３．０部 ＰＰＤ
０．４部 Ｍ
ＡＰ
０．３部
リモネン
２．０部 残り精製水で
１００．０部とする（第２剤）
ＣＥ２０
４．０部 セタノール
６．０部 リン
酸
０．０００
２部 過酸化水素水（３５％）
１７．
０部 残り精製水で
１００．０部とするなお、比較品としては、リモネンを
精製水で置き換えたものを使用した。(First agent) Stearyl alcohol
6.
0 parts oleyl alcohol
7.0 parts liquid paraffin
10.0 copies CE15
10.0 copies E
D.T.A.
0.2 parts
TGAA
0.4 parts Strong ammonia water (28
%)
3.0 parts PPD
0.4 part M
AP
0.3 parts limonene
2.0 parts with remaining purified water
100.0 parts (second agent) CE20
4.0 parts Setanol
6.0 parts phosphoric acid
0.000
2 parts hydrogen peroxide solution (35%)
17.
0 parts with remaining purified water
100.0 parts. As a comparative product, one in which limonene was replaced with purified water was used.
【００６３】また、本剤の第１剤と第２剤の混合液のｐ
Ｈは９．９６（比較品のｐＨは９．９５）であった。[0063] In addition, the p of the mixed solution of the first and second agents of this agent
H was 9.96 (the pH of the comparative product was 9.95).
【００６４】[0064]
【実施例７】以下に、もう一つのペースト状の染毛剤の
組成を示す。[Example 7] The composition of another paste-like hair dye is shown below.
【００６５】
（第１剤）
ステアリルアルコール
６．
０部 オレイルアルコール
７．０部 流動パラフィン
１０．０部 ＣＥ１５
１０．０部 Ｅ
ＤＴＡ
０．２部
ＴＧＡＡ
０．４部 強アンモニア水（２８
％）
３．０部 ＰＰＤ
０．３部 Ｐ
ＡＰ
０．３部
ＭＡＰ
０．１部 リナロール
２．０部 残
り精製水で
１００．０部とする（第
２剤）
ＣＥ２０
４．０部 セタノール
６．０部 リン
酸
０．０００
２部 過酸化水素水（３５％）
１７．
０部 残り精製水で
１００．０部とするなお、比較品としては、リナロール
を精製水で置き換えたものを使用した。(First agent) Stearyl alcohol
6.
0 parts oleyl alcohol
7.0 parts liquid paraffin
10.0 copies CE15
10.0 copies E
D.T.A.
0.2 parts
TGAA
0.4 parts Strong ammonia water (28
%)
3.0 parts PPD
0.3 part P
AP
0.3 part MAP
0.1 part linalool
2.0 parts with remaining purified water
100.0 parts (second agent) CE20
4.0 parts Setanol
6.0 parts phosphoric acid
0.000
2 parts hydrogen peroxide solution (35%)
17.
0 parts with remaining purified water
100.0 parts. As a comparative product, one in which linalool was replaced with purified water was used.
【００６６】また、本剤の第１剤と第２剤の混合液のｐ
Ｈは９．９０（比較品のｐＨは９．９１）であった。[0066] In addition, the p of the mixed solution of the first and second agents of this agent
H was 9.90 (pH of the comparative product was 9.91).
【００６７】[0067]
【実施例８】以下に、更にもう一つのペースト状の染毛
剤の組成を示す。[Example 8] The composition of yet another paste-like hair dye is shown below.
【００６８】
（第１剤）
ステアリルアルコール
６．
０部 オレイルアルコール
７．０部 流動パラフィン
１０．０部 ＣＥ１５
１０．０部 Ｅ
ＤＴＡ
０．２部
ＴＧＡＡ
０．４部 強アンモニア水（２８
％）
３．０部 ＰＰＤ
０．３部 Ｐ
ＡＰ
０．３部
ＭＡＰ
０．１部 リナリルアセテー
ト
３．０部 残り精製水
で
１００．０部とする（第２剤）
ＣＥ２０
４．０部 セタノール
６．０部 リン
酸
０．０００
２部 過酸化水素水（３５％）
１７．
０部 残り精製水で
１００．０部とするなお、比較品としては、リナリルア
セテートを精製水で置き換えたものを使用した。(First agent) Stearyl alcohol
6.
0 parts oleyl alcohol
7.0 parts liquid paraffin
10.0 copies CE15
10.0 copies E
D.T.A.
0.2 parts
TGAA
0.4 parts Strong ammonia water (28
%)
3.0 parts PPD
0.3 part P
AP
0.3 part MAP
0.1 part linalyl acetate
3.0 parts with remaining purified water
100.0 parts (second agent) CE20
4.0 parts Setanol
6.0 parts phosphoric acid
0.000
2 parts hydrogen peroxide solution (35%)
17.
0 parts with remaining purified water
100.0 parts. As a comparative product, one in which linalyl acetate was replaced with purified water was used.
【００６９】また、本剤の第１剤と第２剤の混合液のｐ
Ｈは９．８２（比較品のｐＨは９．９１）であった。[0069] Also, the p of the mixed solution of the first and second agents of this agent
H was 9.82 (pH of the comparative product was 9.91).
【００７０】[0070]
【実施例９】以下に、粉末タイプの組成物の組成を示す
。Example 9 The composition of a powder type composition is shown below.
【００７１】
硫酸パラフェニレンジアミン
１０．０ｇ
硫酸メタアミノフェノール
３．０ｇ
カルボキシメチルセルロース
３０．０ｇ
過ほう酸ナトリウム
２５．０ｇ
デキストリン
３２
．０ｇ上記の各化合物を混合し、粉末タイプの染毛剤用
組成物とした。この粉末状組成物６ｇに、リモネン０．
２８ｇ（染液に対して０．５％に相当）、水４９．７２
ｇを加えた液を染色液とし、以下の染毛効果試験に供し
た。Paraphenylene diamine sulfate
10.0g
meta-aminophenol sulfate
3.0g
carboxymethylcellulose
30.0g
sodium perborate
25.0g
dextrin
32
．． 0 g of each of the above compounds were mixed to prepare a powder type hair dye composition. To 6 g of this powder composition, 0.0 g of limonene was added.
28g (equivalent to 0.5% of dye liquor), water 49.72
The solution to which g was added was used as a dyeing solution, and was subjected to the following hair dyeing effect test.
【００７２】なお、比較品は上記粉末６ｇに水５０ｇを
加えて調製した。A comparative product was prepared by adding 50 g of water to 6 g of the above powder.
【００７３】また、本染色液のｐＨは８．４２（比較品
のｐＨは８．４１）であった。[0073] The pH of the main staining solution was 8.42 (the pH of the comparative product was 8.41).
【００７４】[0074]
【実施例１０】以下に、練り状の組成物の組成を示す。Example 10 The composition of a kneaded composition is shown below.
【００７５】
硫酸パラフェニレンジアミン
１０．０ｇ
硫酸メタアミノフェノール
３．０ｇ
カルボキシメチルセルロース
３０．０ｇ
過ほう酸ナトリウム
２５．０ｇ
ワセリン／ＬＰ（１／１）
６４．０ｇ上記の
化合物を混合した練り状の組成物６ｇに、リモネン１．
４０ｇ（染液に対して２．５％に相当）、水４８．６０
ｇを加えた液を染色液とし、以下の染毛効果試験に供し
た。Paraphenylene diamine sulfate
10.0g
meta-aminophenol sulfate
3.0g
carboxymethylcellulose
30.0g
sodium perborate
25.0g
Vaseline/LP (1/1)
64.0g of the above compound was mixed into 6g of a paste-like composition, and 1.
40g (equivalent to 2.5% of dye liquor), water 48.60
The solution to which g was added was used as a dyeing solution, and was subjected to the following hair dyeing effect test.
【００７６】なお、比較品は被検品６ｇに水５０ｇを加
えて調製した。A comparative product was prepared by adding 50 g of water to 6 g of the test product.
【００７７】また、本染色液のｐＨは８．３４（比較品
のｐＨは８．４９）であった。[0077] The pH of the main staining solution was 8.34 (the pH of the comparative product was 8.49).
【００７８】[0078]
【実施例１１】実施例４〜８で得られた被検品について
は、第１剤と第２剤を等量混合したものを染色液として
用い、実施例９及び１０の被検品については、各組成物
を水、リモネンを用いて溶解した上記染色液を使用して
染毛効果試験を行った。[Example 11] For the test items obtained in Examples 4 to 8, a mixture of equal amounts of the first agent and the second agent was used as the staining solution, and for the test items of Examples 9 and 10, each A hair dyeing effect test was conducted using the above dyeing solution in which the composition was dissolved using water and limonene.
【００７９】即ち、本発明の染色液と比較品の各々１０
ｇを、脱色山羊毛１束（約３ｇ）及び人毛１束（約３ｇ
）に各々塗り付け、２０分間染毛後ぬるま湯で十分にす
すぎ、シャンプーした後、熱風で乾燥して目的とする染
毛を得た。得られた染毛について、本発明の染色液と比
較品による染色の濃さと染色の均一性を肉眼で観察した
。結果を、以下の表７に示す。That is, 10% of each of the staining solution of the present invention and the comparative product.
g, 1 bundle of bleached goat hair (approx. 3g) and 1 bundle of human hair (approx. 3g)
) and dyed the hair for 20 minutes, rinsed thoroughly with lukewarm water, shampooed, and dried with hot air to obtain the desired dyed hair. The resulting dyed hair was visually observed for dyeing depth and dyeing uniformity using the dyeing solution of the present invention and a comparative product. The results are shown in Table 7 below.
【００８０】[0080]
【表７】[Table 7]
【００８１】尚、表７中において、 −：効果なし ＋：区別できる程度には効果がある ＋＋：はっきりと効果がある ＋＋＋：更に強く効果がある。[0081] In Table 7, −: No effect +: Effective to the extent that it can be distinguished ++: Clearly effective +++: Even stronger effect.
【００８２】を示す。[0082] is shown.
【００８３】上記表７の結果から、本発明のこれら染色
液は、染色の濃さ及び染色の均一性に関し、リモネン等
の精油類を含まない比較品より優れていることが確認さ
れた。From the results shown in Table 7 above, it was confirmed that these dye solutions of the present invention were superior to comparative products that did not contain essential oils such as limonene in terms of dye depth and dye uniformity.
Claims (1)
の染色液中の濃度が、リモネンに換算して０．２５〜５
．０重量％のリモネンまたは該割合のリモネンを含む精
油類、リナリルアセテートに換算して０．２５〜５．０
重量％のリナリルアセテートまたは該割合のリナリルア
セテートを含む精油類、及び、リナロールに換算して０
．２５〜５．０重量％のリナロールまたは該割合のリナ
ロールを含む精油類のうち少くとも１種を含む染毛剤。Claim 1: A hair dye using an oxidative dye, which has a concentration in the dyeing liquid at the time of use of 0.25 to 5 in terms of limonene.
．． 0% by weight of limonene or essential oils containing this proportion of limonene, converted to linalyl acetate, 0.25 to 5.0
Weight% of linalyl acetate or essential oils containing this proportion of linalyl acetate, and 0 in terms of linalool
．． A hair dye containing 25 to 5.0% by weight of linalool or at least one essential oil containing linalool in this proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3139873A JP3069802B2 (en) | 1991-06-12 | 1991-06-12 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3139873A JP3069802B2 (en) | 1991-06-12 | 1991-06-12 | Hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04364114A true JPH04364114A (en) | 1992-12-16 |
| JP3069802B2 JP3069802B2 (en) | 2000-07-24 |
Family
ID=15255552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3139873A Expired - Lifetime JP3069802B2 (en) | 1991-06-12 | 1991-06-12 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3069802B2 (en) |
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| US11129775B2 (en) | 2017-10-10 | 2021-09-28 | The Procter And Gamble Company | Method of treating hair or skin with a personal care composition in a foam form |
| US11904036B2 (en) | 2017-10-10 | 2024-02-20 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
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| US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
| US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
| US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
| US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
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|---|---|
| JP3069802B2 (en) | 2000-07-24 |
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