JPH04342775A - Ethanol-based metallic color ink composition - Google Patents
Ethanol-based metallic color ink compositionInfo
- Publication number
- JPH04342775A JPH04342775A JP3144093A JP14409391A JPH04342775A JP H04342775 A JPH04342775 A JP H04342775A JP 3144093 A JP3144093 A JP 3144093A JP 14409391 A JP14409391 A JP 14409391A JP H04342775 A JPH04342775 A JP H04342775A
- Authority
- JP
- Japan
- Prior art keywords
- ethanol
- ink composition
- color ink
- aluminum
- metallic color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 150000002688 maleic acid derivatives Chemical class 0.000 claims abstract 2
- 239000003086 colorant Substances 0.000 claims description 5
- 230000006866 deterioration Effects 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000000976 ink Substances 0.000 description 28
- 229910052782 aluminium Inorganic materials 0.000 description 18
- 239000002904 solvent Substances 0.000 description 10
- 150000002689 maleic acids Chemical class 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- LMZURCXQQZLYNR-UHFFFAOYSA-N ethanol;silver Chemical compound [Ag].CCO LMZURCXQQZLYNR-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、マーキングペン、筆、
***などに適用されて、金属光沢のある色調を与えるメ
タリックカラー用インキ組成物に関するものである。[Industrial Application Field] The present invention is applicable to marking pens, brushes,
The present invention relates to a metallic color ink composition that is applied to seals and the like and gives a metallic luster tone.
【０００２】0002
【従来の技術】アルミニウムなどの金属粉をキシレンな
どの有機溶剤ベースのビヒクル中に分散したメタリック
調の油性インキはよく知られている。しかし、使用して
いる有機溶剤がキシレンなどの刺激性が強い溶剤のため
に、その臭気や溶剤蒸発による害、また樹脂板の種類に
よって筆記表面を侵し易いなどの点が問題となっている
。一方、その有機溶剤による悪作用のないインキとして
水性インキが研究されているが、金属と水との反応によ
る水素ガスの発生により経時的に劣化してしまうことや
、水の蒸発が遅いため特に非吸収性の筆記面に描いた場
合乾燥して描線が定着するまでに時間がかかるという欠
点がある。BACKGROUND OF THE INVENTION Metallic oil-based inks in which metal powder such as aluminum is dispersed in a vehicle based on an organic solvent such as xylene are well known. However, since the organic solvent used is a highly irritating solvent such as xylene, there are problems such as its odor, harm caused by solvent evaporation, and the tendency to corrode the writing surface depending on the type of resin board. On the other hand, water-based inks are being researched as inks that do not have the negative effects of organic solvents, but they deteriorate over time due to the generation of hydrogen gas from the reaction between metal and water, and water evaporates slowly. The drawback is that when drawn on a non-absorbent writing surface, it takes time for the drawn lines to dry and become fixed.
【０００３】0003
【発明が解決しようとする課題】本発明は、従来のメタ
リック調インキに対する上記問題点を解決するためのも
ので、いやな臭いや毒性が少なく、多くの筆記面に対す
る筆記性が良好で、着色剤として混入するアルミニウム
粉などと反応してガスの発生による劣化の起こらないメ
タリックカラー用インキ組成物を提供することを目的と
する。[Problems to be Solved by the Invention] The present invention is intended to solve the above-mentioned problems with conventional metallic inks. An object of the present invention is to provide an ink composition for metallic colors that does not react with aluminum powder or the like mixed as an agent and undergoes no deterioration due to the generation of gas.
【０００４】0004
【課題を解決するための手段】本発明者は、上記の課題
を解決するため種々検討を重ねた結果、着色剤としてア
ルミニウム粉、主溶剤としてエタノール、分散剤として
エタノール溶性ロジン変性マレイン酸樹脂を用いること
により、上記の目的を達成することを見出し、本発明を
完成するに至った。[Means for Solving the Problems] As a result of various studies in order to solve the above problems, the present inventor has developed the following methods using aluminum powder as a coloring agent, ethanol as a main solvent, and an ethanol-soluble rosin-modified maleic acid resin as a dispersant. It has been found that the above object can be achieved by using the present invention, and the present invention has been completed.
【０００５】本発明のメタリックカラー用インキ組成物
は、アルミニウム粉、エタノール、およびエタノール溶
性ロジン変性マレイン酸樹脂を含有してなるエタノール
性であることを特徴とする。The metallic color ink composition of the present invention is characterized by being ethanolic and containing aluminum powder, ethanol, and an ethanol-soluble rosin-modified maleic acid resin.
【０００６】本発明のインキ組成物に用いるアルミニウ
ム粉は、市販品のアルミニウム粉、使いやすいアルミペ
ーストタイプを使用できる。アルミニウムの平均粒径は
５〜１５μｍのものが好ましく、１５μｍ以上だと筆記
に用いる繊維芯などの細管を通過しにくく、５μｍ以下
だと描線の光輝性が著しく低下する。また、リーフィン
グタイプのものを使用すると光輝性はさらに向上する。
添加量は、特に制限はなく所望の色相、濃度に適した量
であればよいが、通常、組成物の１〜３０％である。な
お、その他の着色剤として染料や顔料を添加して色調を
変えても構わない。As the aluminum powder used in the ink composition of the present invention, commercially available aluminum powder or an easy-to-use aluminum paste type can be used. The average particle size of aluminum is preferably 5 to 15 μm; if it is 15 μm or more, it will be difficult to pass through a thin tube such as a fiber core used for writing, and if it is less than 5 μm, the brightness of the drawn line will be significantly reduced. Furthermore, if a leafing type material is used, the brightness is further improved. The amount added is not particularly limited as long as it is suitable for the desired hue and concentration, but is usually 1 to 30% of the composition. Note that dyes and pigments may be added as other coloring agents to change the color tone.
【０００７】本発明のインキ組成物に用いるエタノール
は、溶剤の主成分となり、溶剤全体の９５％以上含むの
が好ましく、毒性が少なく、インキの速乾性に効果を示
す。他の溶剤は、白化防止剤、筆記部の乾燥抑制剤、染
料の補助溶剤としてや分散を安定させる目的などで添加
する。具体的な溶剤としては、ベンジルアルコール、プ
ロピルアルコール、乳酸エチルなどの有機溶剤、水など
であるがエタノールに比べてその使用量は著しく少ない
。Ethanol used in the ink composition of the present invention is the main component of the solvent, preferably contains 95% or more of the total solvent, has low toxicity, and is effective in quick drying the ink. Other solvents are added as anti-whitening agents, drying inhibitors for writing areas, auxiliary solvents for dyes, and for the purpose of stabilizing dispersion. Specific solvents include organic solvents such as benzyl alcohol, propyl alcohol, and ethyl lactate, and water, but the amount used is significantly smaller than that of ethanol.
【０００８】本発明のインキ組成物に用いるエタノール
溶性ロジン変性マレイン酸樹脂は、アルミニウムを劣化
させるような反応や、エタノールとアルミニウムの反応
によるガスの発生を抑制し、アルミニウム粉を安定に分
散させるもので、酸価２００〜４００のものが好適に使
用できる。酸価は小さいと分散性が悪く、あまり大きい
とアルミニウムとの相互作用が強くインクの安定性をそ
こなう。該樹脂の添加量は、アルミニウム１００重量部
に対して、１５重量部以上が好ましい。The ethanol-soluble rosin-modified maleic acid resin used in the ink composition of the present invention suppresses reactions that degrade aluminum and gas generation due to reactions between ethanol and aluminum, and stably disperses aluminum powder. So, those having an acid value of 200 to 400 can be suitably used. If the acid value is too low, the dispersibility will be poor, and if it is too high, the interaction with aluminum will be strong, impairing the stability of the ink. The amount of the resin added is preferably 15 parts by weight or more per 100 parts by weight of aluminum.
【０００９】本発明のインキ組成物には、上記のアルミ
ニウム粉、エタノールおよびエタノール溶性ロジン変性
マレイン酸樹脂の必須成分以外に、必要に応じて固着剤
などとして他の樹脂、ケトン樹脂、フェノール樹脂など
を添加してもよい。具体的な固着剤としてはハイラック
１１０Ｈ（日立化成工業製）、タマノルＰＡ、タマノル
５３１（荒川化学工業製）などがあげられる。In addition to the above-mentioned essential components of aluminum powder, ethanol, and ethanol-soluble rosin-modified maleic acid resin, the ink composition of the present invention may optionally contain other resins such as a sticking agent, ketone resin, phenol resin, etc. may be added. Specific examples of the fixing agent include Hilac 110H (manufactured by Hitachi Chemical Co., Ltd.), Tamanol PA, and Tamanol 531 (manufactured by Arakawa Chemical Industries).
【００１０】本発明のインキ組成物において、エタノー
ル溶性ロジン変性マレイン酸樹脂以外のものを分散剤と
して用いると、主溶剤のエタノールが油性溶剤と水との
中間的構造のため分散が困難であると同時にアルミニウ
ムとエタノールあるいはアルミニウムと分散剤との相互
作用により経時劣化の問題が生じてしまう。しかし、本
発明に使用するエタノール可溶性ロジン変性マイレン酸
樹脂を添加するとアルミニウムと樹脂の相互作用などに
よるインキの経時劣化を引き起こすことなしにアルミニ
ウムを安定に分散することが可能となり、要求されるイ
ンキ性能を安定に供給できる。[0010] In the ink composition of the present invention, if a dispersant other than ethanol-soluble rosin-modified maleic acid resin is used, dispersion may be difficult because ethanol, the main solvent, has an intermediate structure between an oily solvent and water. At the same time, the problem of deterioration over time arises due to interaction between aluminum and ethanol or aluminum and dispersant. However, by adding the ethanol-soluble rosin-modified maleic acid resin used in the present invention, it becomes possible to stably disperse aluminum without causing deterioration of the ink over time due to interactions between aluminum and resin, and the required ink performance is achieved. can be stably supplied.
【００１１】[0011]
【実施例】本発明の組成物を実施例と比較例にて説明す
る。実施例、比較例で得られたメタリックカラー用イン
キの性能はつぎの方法で評価した。
臭 い：インキをペンに仕立て、使用した時
の臭気を比較評価。
筆 記 性：完全に乾燥した後の描線状態を目視に
て観察。
乾 燥 性：インキを筆記具に仕立て、筆記した描
線の乾燥するまでの時間を比較（２５℃、６５％）。
分 散 性：インキの初期の分散状態を観察。
分散安定性：インキを長時間放置（室温）した後のアル
ミニウム等の沈降状態の観察。
インキ経時劣化：インキを５０℃恒温槽中に放置した時
のガスの発生や色相の変化等の劣化の度合を評価。
それぞれの性能は、特に良好は◎、良好は○、やや劣る
△、劣るは×で示した。[Example] The composition of the present invention will be explained using Examples and Comparative Examples. The performance of the metallic color inks obtained in Examples and Comparative Examples was evaluated by the following method. Odor: Comparatively evaluate the odor when ink is made into a pen and used. Writability: Visually observe the state of drawn lines after completely drying. Drying property: Compare the time it takes for a line drawn using ink to dry (25°C, 65%). Dispersibility: Observe the initial dispersion state of the ink. Dispersion stability: Observation of the sedimentation state of aluminum, etc. after the ink is left to stand for a long time (at room temperature). Ink deterioration over time: Evaluate the degree of deterioration such as gas generation and changes in hue when ink is left in a 50°C constant temperature bath. The respective performances were indicated by ◎ for particularly good, ◯ for good, △ for slightly poor, and × for poor.
【００１２】（実施例１）
・アルミニウムペースト
１５．０（
部） （Ａｌ粉末含有量６５％、平均粒子径１０
μｍ） ・アルコール溶性ロジン変性マレイン酸樹脂
１７．０ （荒川
化学工業（株）製：マルキード３３） ・エタノール
６８．０上記組成
をかくはん型混合機にて６０分間混合分散して、銀色の
エタノール性メタリックカラー用インキを調製した。性
能評価の結果を表１に示す。(Example 1) - Aluminum paste
15.0 (
part) (Al powder content 65%, average particle size 10
μm) - Alcohol-soluble rosin modified maleic acid resin 17.0 (manufactured by Arakawa Chemical Co., Ltd.: Marquid 33) - Ethanol
68.0 The above composition was mixed and dispersed for 60 minutes using a stirring mixer to prepare a silver ethanol-based metallic color ink. The results of the performance evaluation are shown in Table 1.
【００１３】（実施例２）
・アルミニウムペースト（実施例１と同じ）
１５．０（部） ・オイルブ
ルー＃６１３（商品名：オリエント化学工業製）
１．５ ・アルコール溶性ロジン変性マレイン
酸樹脂 ５．０
（荒川化学工業（株）製：マルキード３４） ・ケ
トン樹脂
１３．０
（日立化成工業（株）製：ハイラック１１０Ｈ
） ・エタノール
６２．０ ・ベンジルアルコール
３．５上記組成を実施例１と同様にして、青色の
エタノール性メタリックカラー用インキを調製した。性
能評価の結果を表１に示す。(Example 2) - Aluminum paste (same as Example 1)
15.0 (parts) ・Oil Blue #613 (Product name: Orient Chemical Industry Co., Ltd.)
1.5 ・Alcohol-soluble rosin modified maleic acid resin 5.0
(Manufactured by Arakawa Chemical Industry Co., Ltd.: Marquid 34) - Ketone resin
13.0
(Manufactured by Hitachi Chemical Co., Ltd.: Hilac 110H
) ・Ethanol
62.0 ・Benzyl alcohol
3.5 A blue ethanol-based metallic color ink was prepared using the same composition as in Example 1. The results of the performance evaluation are shown in Table 1.
【００１４】[0014]
【表１】
◎は特に良好、○は良好、△はやや劣る、×は劣るをそ
れぞれ示す。[Table 1] ◎ indicates particularly good, ◯ indicates good, △ indicates slightly poor, and × indicates poor.
【００１５】（比較例１）
・アルミニウムペースト（実施例１と同じ）
１６．０（部） ・クマロン
樹脂
２０．０
（日鉄化学工業（株）製：日鉄クマロンＧ−９０）
・脂肪族アミド
０
．１ ・キシレン
５０．０ ・メチルイソブチルケトン
１４．０上記組成を実施例１と同様にして、メタリッ
クカラー用インキを調製した。性能評価を表１に示す。(Comparative Example 1) - Aluminum paste (same as Example 1)
16.0 (parts) ・Kumaron resin
20.0
(Manufactured by Nippon Steel Chemical Industry Co., Ltd.: Nippon Steel Kumaron G-90)
・Aliphatic amide
0
．． 1 ・Xylene
50.0 ・Methyl isobutyl ketone
14.0 A metallic color ink was prepared using the same composition as in Example 1. Performance evaluation is shown in Table 1.
【００１６】（比較例２）
・アルミニウムペースト（実施例１と同じ）
１５．０（部） ・アクリル
エマルジョン
２０．０ ・ポリビニル
アルコール
０．５ ・エチレング
リコール
３．０ ・水
６１．
５上記組成を比較例１と同様にして、その結果を表１に
示す。(Comparative Example 2) - Aluminum paste (same as Example 1)
15.0 (parts) ・Acrylic emulsion
20.0 ・Polyvinyl alcohol
0.5 ・Ethylene glycol
3.0 ・Water
61.
5 The above composition was made the same as in Comparative Example 1, and the results are shown in Table 1.
【００１７】（比較例３）
・アルミニウムペースト（実施例１と同じ）
１５．０（部） ・スチレン
・マレイン酸樹脂
１７．０ （積水化成品
：ＳＭＥ５０，０００） ・エタノール
６８．０上記組成を比較例１と
同様にして、その結果を表１に示す。(Comparative Example 3) - Aluminum paste (same as Example 1)
15.0 (parts) ・Styrene/maleic acid resin
17.0 (Sekisui Plastics: SME50,000) ・Ethanol
68.0 The above composition was the same as Comparative Example 1, and the results are shown in Table 1.
【００１８】[0018]
【発明の効果】本発明のエタノール製メタリックカラー
用インキ組成物は、着色剤としてアルミニウム粉、主溶
剤としてエタノール、分散剤としてエタノール溶性ロジ
ン変性マレイン酸樹脂を含むことが特徴である。そのた
め、本発明の組成物によるメタリックカラー用インキは
いやな臭いや毒性が少なく、多くの筆記面に対する筆記
性が良好で、アルミニウムなどと反応性のあるエタノー
ルを使用してもガスの発生などによる劣化は起らない。Effects of the Invention The ethanol-made metallic color ink composition of the present invention is characterized in that it contains aluminum powder as a colorant, ethanol as a main solvent, and an ethanol-soluble rosin-modified maleic acid resin as a dispersant. Therefore, the metallic color ink made from the composition of the present invention has little unpleasant odor and toxicity, has good writing properties on many writing surfaces, and does not cause gas generation even when using ethanol, which is reactive with aluminum etc. No deterioration occurs.
Claims (1)
エタノール溶性ロジン変性マレイン酸樹脂を含有してな
るエタノール性メタリックカラー用インキ組成物。1. An ink composition for ethanolic metallic colors comprising aluminum powder, ethanol, and an ethanol-soluble rosin-modified maleic acid resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14409391A JP2970782B2 (en) | 1991-05-21 | 1991-05-21 | Ink composition for ethanolic metallic color |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14409391A JP2970782B2 (en) | 1991-05-21 | 1991-05-21 | Ink composition for ethanolic metallic color |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04342775A true JPH04342775A (en) | 1992-11-30 |
| JP2970782B2 JP2970782B2 (en) | 1999-11-02 |
Family
ID=15354051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14409391A Expired - Fee Related JP2970782B2 (en) | 1991-05-21 | 1991-05-21 | Ink composition for ethanolic metallic color |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2970782B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160018346A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| KR20160018348A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| KR20160018347A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| JP2017171712A (en) * | 2016-03-18 | 2017-09-28 | シヤチハタ株式会社 | Oiliness metallic color ink |
-
1991
- 1991-05-21 JP JP14409391A patent/JP2970782B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160018346A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| KR20160018348A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| KR20160018347A (en) | 2014-08-07 | 2016-02-17 | 후지모리 고교 가부시키가이샤 | Surface-protective film for transparent conductive film, and transparent conductive film using the same |
| JP2017171712A (en) * | 2016-03-18 | 2017-09-28 | シヤチハタ株式会社 | Oiliness metallic color ink |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2970782B2 (en) | 1999-11-02 |
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