JPH04301000A - Nonionic powdery detergent composition - Google Patents
Nonionic powdery detergent compositionInfo
- Publication number
- JPH04301000A JPH04301000A JP6649991A JP6649991A JPH04301000A JP H04301000 A JPH04301000 A JP H04301000A JP 6649991 A JP6649991 A JP 6649991A JP 6649991 A JP6649991 A JP 6649991A JP H04301000 A JPH04301000 A JP H04301000A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- nonionic
- detergent composition
- present
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000003599 detergent Substances 0.000 title claims abstract description 19
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 7
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 7
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- -1 Fatty acid salt Chemical class 0.000 claims description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 150000005215 alkyl ethers Chemical class 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000008237 rinsing water Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 10
- 238000005406 washing Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000010457 zeolite Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical group C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- OOOLSJAKRPYLSA-UHFFFAOYSA-N 2-ethyl-2-phosphonobutanedioic acid Chemical compound CCC(P(O)(O)=O)(C(O)=O)CC(O)=O OOOLSJAKRPYLSA-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical class OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 125000004436 sodium atom Chemical group 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は洗浄剤組成物に関する。
更に詳しくは非イオン界面活性剤が主基剤の粉末洗浄剤
組成物、特にすすぎ時の泡切れが良く、すすぎ水中の濁
りが早く消える粉末洗浄剤組成物に関する。FIELD OF THE INVENTION This invention relates to cleaning compositions. More specifically, the present invention relates to a powder detergent composition containing a nonionic surfactant as a main base, and particularly to a powder detergent composition that has good foam removal during rinsing and quickly eliminates turbidity in the rinse water.
【０００２】0002
【従来の技術及び発明が解決しようとする課題】非イオ
ン界面活性剤は、耐硬水性が良好であるうえ、洗浄力、
汚れ分散力が際立っており、且つ生分解性が非常に良好
であるなどの特徴を有しており、洗浄用界面活性剤とし
て重要視されている。[Prior Art and Problems to be Solved by the Invention] Nonionic surfactants have good hard water resistance, detergency,
It has characteristics such as outstanding dirt dispersion ability and very good biodegradability, and is considered important as a cleaning surfactant.
【０００３】しかしながら、通常、洗浄用に用いられる
非イオン界面活性剤は、常温で液体のものが多いため、
粉末洗剤の製造に当たって非イオン界面活性剤を液体状
態のまま多量に配合した粉末洗剤は、経日により非イオ
ン界面活性剤が徐々にしみ出してきて紙製容器の内面に
しみ込んだり、粉末洗剤の流動性が著しく損なわれたり
、更にはケーキングを起こして洗剤が固まってしまい商
品価値を損ねるという問題点を有している。[0003] However, most nonionic surfactants used for cleaning are liquid at room temperature;
Powdered detergents are manufactured by blending a large amount of nonionic surfactants in liquid state, and over time, the nonionic surfactants gradually ooze out and seep into the inner surface of paper containers, or the powdered detergent's There are problems in that fluidity is significantly impaired, and furthermore, caking occurs, causing the detergent to solidify, thereby impairing its commercial value.
【０００４】この問題点については、種々検討がなされ
ている。例えば、特開昭５０−１１９８１３号公報には
ゼオライト、又はゼオライトと水中で過酸化水素を生じ
る無機過酸化物との混合物上に非イオン界面活性剤を微
細に分配した予備混合物（予備混合物中には４％以下の
高分散性珪酸を使用してもよい）３０〜１００ ％と噴
霧乾燥洗剤０〜７０％を含有する流動性洗剤が開示され
ている。特開昭６１−８９３００ 号公報には水不溶性
粒体とシリカ粉末とを混合した後、非イオン界面活性剤
を噴霧し次いでゼオライト粉末を添加して造粒物を調製
し、この造粒物と陰イオン界面活性剤を含む粒状洗剤を
配合した非イオン界面活性剤含有粒状洗剤は流動性が良
好でケーキングも防止できることが開示されている。こ
のような技術により、上述の問題点はほとんど解決され
ている。[0004] Various studies have been made regarding this problem. For example, JP-A-50-119813 discloses a premix in which a nonionic surfactant is finely distributed on a zeolite or a mixture of a zeolite and an inorganic peroxide that produces hydrogen peroxide in water. Fluid detergents containing 30-100% (up to 4% of highly dispersed silicic acid may be used) and 0-70% of spray-dried detergent are disclosed. JP-A-61-89300 discloses that after mixing water-insoluble granules and silica powder, a nonionic surfactant is sprayed, and then zeolite powder is added to prepare a granulated product. It is disclosed that a nonionic surfactant-containing granular detergent blended with an anionic surfactant-containing granular detergent has good fluidity and can prevent caking. With this technique, most of the above-mentioned problems have been solved.
【０００５】しかしながら、非イオン界面活性剤は泡切
れが悪く、すすぎ水中の濁りがなかなか消えないという
問題がある。[0005] However, nonionic surfactants have a problem in that they do not easily remove bubbles and the turbidity in the rinse water does not disappear easily.
【０００６】[0006]
【課題を解決するための手段】本発明者らは、非イオン
界面活性剤を主洗浄基剤とする洗浄剤について鋭意研究
した結果、特定の分子量のポリエチレングリコールとす
すぎ剤を併用すると、上記の泡切れの問題、すすぎ水中
の濁りの問題が著しく改善されることを見出し、本発明
を完成した。[Means for Solving the Problems] As a result of extensive research into cleaning agents that use nonionic surfactants as the main cleaning base, the present inventors found that when polyethylene glycol of a specific molecular weight is used in combination with a rinsing agent, the above-mentioned The present invention was completed based on the discovery that the problem of foam breakage and the problem of turbidity in rinsing water can be significantly improved.
【０００７】即ち、本発明は次の成分（ａ），（ｂ），
（ｃ）及び（ｄ） を含有してなる非イオン性粉末洗
浄剤組成物を提供するものである。
（ａ） 融点が４０℃以下でかつＨＬＢ が ９．０〜
１６．０の範囲の非イオン界面活性剤
１２〜３５重量％（ｂ） アルミノケイ酸塩
２０〜６０重量％（ｃ） 分子量が
２００〜２０００のポリエチレングリコール
０．０５〜４重量％（ｄ） すすぎ剤
０．０２〜１０重量
％。
本発明に使用される（ａ） 成分の非イオン界面活
性剤は、融点が４０℃以下でかつＨＬＢ が ９．０〜
１６．０の範囲のものが汚れ落ち、泡立ち、泡切れに優
れており、好適である。ここで用いるＨＬＢ はＪ．Ｔ
．Ｄａｖｉｅｓａｎｄ Ｅ．Ｋ．Ｒｉｄｅａｌ，Ｉｎｔ
ｅｒｆａｃｉａｌ Ｐｈｅｎｏｍｅｎａ， Ａｃａｄｅ
ｍｉｃ Ｐｒｅｓｓ， Ｎｅｗ Ｙｏｒｋ １９６３，
ｐ．３７１−３８３により定義されるものである。That is, the present invention comprises the following components (a), (b),
The present invention provides a nonionic powder detergent composition containing (c) and (d). (a) Melting point is 40°C or less and HLB is 9.0~
Nonionic surfactants in the range of 16.0
12-35% by weight (b) aluminosilicate
20-60% by weight (c) Molecular weight is
200-2000 polyethylene glycol
0.05-4% by weight (d) Rinse agent
0.02-10% by weight. The nonionic surfactant as component (a) used in the present invention has a melting point of 40°C or less and an HLB of 9.0 to 9.0.
A value in the range of 16.0 is suitable because it is excellent in stain removal, foaming, and foam removal. The HLB used here is J. T
．． Davies and E. K. Rideal, Int.
erfacial Phenomena, Acade
mic Press, New York 1963,
p. 371-383.
【０００８】（ａ） 成分の具体例としては、ポリオキ
シエチレンアルキルエーテル、ポリオキシエチレンアル
キルフェニルエーテル、ポリオキシエチレンソルビタン
脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸
エステル、ポリエチレングリコール脂肪酸エステル、ポ
リオキシエチレンヒマシ油、ポリオキシエチレンアルキ
ルアミン、グリセリン脂肪酸エステル、高級脂肪酸アル
カノールアミド、アルキルグリコシド、アルキルアミン
オキサイドなどが挙げられる。就中、主非イオン性界面
活性剤としてポリオキシエチレンアルキルエーテル、特
に炭素数１０〜２０、好ましくは１０〜１５、更に好ま
しくは１２〜１４の直鎖又は分岐鎖、１級又は２級のア
ルコールのエチレンオキサイド平均付加モル数５〜１５
、好ましくは６〜１２、更に好ましくは６〜１０のポリ
オキシエチレンアルキルエーテルを使用するのが望まし
い。（ａ） 成分は、全組成物中に１２〜３５重量％、
好ましくは、１５〜３０重量％配合される。Specific examples of component (a) include polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol fatty acid ester, and polyoxyethylene castor oil. , polyoxyethylene alkylamine, glycerin fatty acid ester, higher fatty acid alkanolamide, alkyl glycoside, alkyl amine oxide, and the like. Among these, polyoxyethylene alkyl ethers, especially linear or branched, primary or secondary alcohols having 10 to 20 carbon atoms, preferably 10 to 15 carbon atoms, more preferably 12 to 14 carbon atoms, are used as the main nonionic surfactant. The average number of moles of ethylene oxide added is 5 to 15.
, preferably 6 to 12, more preferably 6 to 10 polyoxyethylene alkyl ethers. (a) component is 12 to 35% by weight in the total composition;
Preferably, it is blended in an amount of 15 to 30% by weight.
【０００９】本発明の（ｂ） 成分であるアルミノケイ
酸塩は、次式で示されるような結晶性或いは非結晶性ア
ルミノケイ酸塩である。■ 次式で示される結晶性ア
ルミノケイ酸塩（ゼオライト）
ｘ（Ｍ’２Ｏ又はＭ’’Ｏ）・Ａｌ２Ｏ３・ｙ（ＳｉＯ
２）・ｗ（Ｈ２Ｏ）〔式中、Ｍ’はアルカリ金属原子、
Ｍ’’ はカルシウムと交換可能なアルカリ土類金属原
子、ｘ， ｙ， ｗ は各成分のモル数を表し、一般的
には ０．７≧ｘ ≧１．５ 、０．８ ≦ｙ ≦６、
ｗ は任意の正数である。〕■ 次式で示される非結
晶性アルミノケイ酸塩
ｘ（Ｍ２Ｏ）・Ａｌ２Ｏ３・ｙ（ＳｉＯ２）・ｗ（Ｈ２
Ｏ）〔式中、Ｍ はナトリウム原子及び／又はカリウム
原子を表し、ｘ， ｙ， ｗ は ０．７＜ｘ ≦１．
２ 、１．６ ≦ｙ ≦２．８ の範囲内にある各成分
のモル数を表すものである。ｗは任意の正数である。〕
（ｂ） 成分は、全組成物中に２０〜６０重量％、好ま
しくは、３０〜５０重量％配合される。The aluminosilicate which is component (b) of the present invention is a crystalline or non-crystalline aluminosilicate as shown by the following formula. ■ Crystalline aluminosilicate (zeolite) represented by the following formula x(M'2O or M''O)・Al2O3・y(SiO
2)・w(H2O) [In the formula, M' is an alkali metal atom,
M'' is an alkaline earth metal atom exchangeable with calcium, x, y, w represent the number of moles of each component, generally 0.7≧x≧1.5, 0.8≦y≦6 ,
w is any positive number. ]■ Amorphous aluminosilicate x(M2O)・Al2O3・y(SiO2)・w(H2
O) [In the formula, M represents a sodium atom and/or a potassium atom, and x, y, and w satisfy 0.7<x≦1.
2, represents the number of moles of each component within the range of 1.6≦y≦2.8. w is an arbitrary positive number. ] Component (b) is incorporated in the total composition in an amount of 20 to 60% by weight, preferably 30 to 50% by weight.
【００１０】本発明の（ｃ） 成分である分子量が ２
００〜２０００のポリエチレングリコールは、通常のエ
チレングリコールに酸化エチレンを触媒の存在下で加圧
、加温状態で吹き込み重合させて製造されるものを使用
できる。本発明に用いられる（ｃ） 成分はその分子量
が ２００〜２０００のものであり、特に ２００〜１
０００のものが好ましい。これを越える分子量のものは
（ｃ） 成分と併用することはできるが、単独では本発
明の効果は充分に得ることができない。また、（ｃ）
成分は予想されたよりも少量で本発明の効果を発揮する
ことができ、（ｃ） 成分は本発明の組成物中に０．０
５〜４重量％、好ましくは０．０５〜１重量％配合され
る。Component (c) of the present invention has a molecular weight of 2
00 to 2000 polyethylene glycol can be produced by blowing and polymerizing ethylene oxide into ordinary ethylene glycol in the presence of a catalyst under pressure and heat. The component (c) used in the present invention has a molecular weight of 200 to 2000, particularly 200 to 1
000 is preferred. Those having a molecular weight exceeding this range can be used in combination with component (c), but the effects of the present invention cannot be obtained sufficiently when used alone. Also, (c)
The effect of the present invention can be exerted in a smaller amount than expected, and (c) component is present in the composition of the present invention at 0.0
It is blended in an amount of 5 to 4% by weight, preferably 0.05 to 1% by weight.
【００１１】本発明の（ｄ） 成分であるすすぎ剤は以
下の１）〜３）の中の一種以上を用いるのが好ましい。As the rinsing agent which is component (d) of the present invention, it is preferable to use one or more of the following 1) to 3).
【００１２】１）シリコーン
シリコーンとしてはジメチルシリコーン油、シリコーン
ペースト、シリコーンエマルジョン、有機変性ポリシロ
キサン、フロオロシリコーン油等が使用できるが、特に
これらをシリカの粉末に吸収させたものがより好ましい
。1) Silicone As the silicone, dimethyl silicone oil, silicone paste, silicone emulsion, organically modified polysiloxane, fluorosilicone oil, etc. can be used, but those in which these are absorbed into silica powder are particularly preferred.
【００１３】２）炭素数８〜２０の脂肪酸塩脂肪酸塩と
しては飽和脂肪酸又は不飽和脂肪酸のどちらの塩でもよ
い。このような脂肪酸としてはラウリン酸を主成分とす
る椰子酸、オレイン酸を主成分とする牛脂脂肪酸、パー
ム脂肪酸等が使用できる。かかる脂肪酸塩の配合量が０
．０２重量％未満ではすすぎ性に対する効果がみられず
、また５重量％を越えるとすすぎ性に寄与する効果は変
わらないため、好ましくない。2) Fatty acid salt having 8 to 20 carbon atoms The fatty acid salt may be either a saturated fatty acid or an unsaturated fatty acid salt. As such fatty acids, coconut acid whose main component is lauric acid, beef tallow fatty acid whose main component is oleic acid, palm fatty acid, etc. can be used. The blending amount of such fatty acid salt is 0.
．． If it is less than 0.02% by weight, no effect on rinsability is observed, and if it exceeds 5% by weight, the effect contributing to rinsability remains unchanged, which is not preferable.
【００１４】３）炭素数８〜２０のアルキル基を有しエ
チレンオキサイドの付加モル数が３〜１４であり、プロ
ピレンオキサイドの付加モル数が１〜１４であるポリオ
キシエチレンポリオキシプロピレンアルキルエーテルか
かる化合物は下記の一般式（１） で示されるブロック
型ポリオキシエチレンポリオキシプロピレンアルキルエ
ーテルである。3) Polyoxyethylene polyoxypropylene alkyl ether having an alkyl group having 8 to 20 carbon atoms, the number of moles of ethylene oxide added is 3 to 14, and the number of moles of propylene oxide added is 1 to 14. The compound is a block type polyoxyethylene polyoxypropylene alkyl ether represented by the following general formula (1).
【００１５】[0015]
【化１】[Chemical formula 1]
【００１６】（ここで、Ｒ は炭素数８〜２０の直鎖又
は分枝鎖アルキル基、ｍ 及びｎは付加モル数であり、
ｍ は３〜１４、ｎは１〜１４を表す。）ポリオキシエ
チレンポリオキシプロピレンアルキルエーテルの配合量
が０．０２重量％未満ではすすぎ性に対する効果がみら
れず、また５重量％を越えるとすすぎ性に寄与する効果
は変わらず、逆に濁りを生じてしまうため、好ましくな
い。(Here, R is a straight or branched alkyl group having 8 to 20 carbon atoms, m and n are the number of moles added,
m represents 3-14, and n represents 1-14. ) If the amount of polyoxyethylene polyoxypropylene alkyl ether is less than 0.02% by weight, no effect on rinsability is observed, and if it exceeds 5% by weight, the effect contributing to rinsability remains unchanged, but on the contrary, it reduces turbidity. This is not preferable because it may occur.
【００１７】これらの（ｄ）成分は本発明の組成物中に
０．０２〜１０重量％、好ましくは０．１〜２．０重量
％配合される。These components (d) are incorporated in the composition of the present invention in an amount of 0.02 to 10% by weight, preferably 0.1 to 2.0% by weight.
【００１８】本発明の組成物には上記 （ａ）〜（ｄ）
の必須成分に加え、下記の各種界面活性剤を併用する
ことができる。陰イオン界面活性剤としてはアルキルベ
ンゼンスルホン酸塩、アルキル又はアルケニルエーテル
硫酸塩、アルキル又はアルケニル硫酸塩、α−オレフィ
ンスルホン酸塩、α−スルホ脂肪酸塩又はエステル塩、
アルキル又はアルケニルエーテルカルボン酸塩、アミノ
酸型界面活性剤、Ｎ−アシルアミノ酸型界面活性剤、ア
ルキル又はアルケニル燐酸エステル又はその塩等が例示
される。The composition of the present invention includes the above (a) to (d).
In addition to the essential components, the following various surfactants can be used in combination. Examples of anionic surfactants include alkylbenzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, α-olefin sulfonates, α-sulfo fatty acid salts or ester salts,
Examples include alkyl or alkenyl ether carboxylates, amino acid type surfactants, N-acylamino acid type surfactants, alkyl or alkenyl phosphate esters or salts thereof.
【００１９】両性界面活性剤としてはカルボキシ型又は
スルホベタイン型等の両性界面活性剤が、カチオン型界
面活性剤としては第４級アンモニウム塩等が例示される
。Examples of amphoteric surfactants include carboxy-type or sulfobetaine-type amphoteric surfactants, and examples of cationic surfactants include quaternary ammonium salts.
【００２０】その他、本発明の非イオン性粉末洗浄剤組
成物には、慣用の補助添加剤、例えばトリポリ燐酸塩、
ピロ燐酸塩等の燐酸塩、アミノトリ（メチレンホスホン
酸）、１−ヒドロキシエチリデン−１，１ −ジホスホ
ン酸、エチレンジアミンテトラ（メチレンホスホン酸）
、ジエチレントリアミンペンタ（メチレンホスホン酸）
、及びこれらの塩、２−ホスホノブタン−１，２ −ジ
カルボン酸等のホスホノカルボン酸の塩、アスパラギン
酸、グルタミン酸等のアミノ酸の塩、ニトリロ３酢酸塩
、エチレンジアミン４酢酸塩等のアミノポリ酢酸塩、ポ
リアクリル酸塩、ポリアコニット酸塩等の高分子電解質
、ポリビニルアルコール等の非解離高分子、特開昭５０
−５２１９６ 号公報記載のポリアセタールカルボン酸
重合体、特開昭６０−２２７８９５号公報の層状ケイ酸
塩、ジグリコール酸、オキシカルボン酸塩等のビルダー
、二価金属イオン捕捉剤、ケイ酸塩、炭酸塩、硫酸塩等
のアルカリ剤或いは無機電解質、ポリビニルピロリドン
、カルボキシメチルセルロース等の再汚染防止剤、パラ
トルエンスルホン酸塩、スルホコハク酸塩、タルク、カ
ルシウムシリケート等のケーキング防止剤、第３ブチル
ヒドロキシトルエン、ジスチレン化クレゾール等の酸化
防止剤、青味付剤、香料等を含むことができるが、これ
については特に限定されず、目的に応じた配合がなされ
てよい。In addition, the nonionic powder detergent composition of the present invention may contain conventional auxiliary additives such as tripolyphosphate,
Phosphates such as pyrophosphate, aminotri(methylenephosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, ethylenediaminetetra(methylenephosphonic acid)
, diethylenetriaminepenta(methylenephosphonic acid)
, and salts thereof, salts of phosphonocarboxylic acids such as 2-phosphonobutane-1,2-dicarboxylic acid, salts of amino acids such as aspartic acid and glutamic acid, aminopolyacetates such as nitrilotriacetate and ethylenediaminetetraacetate, Polymer electrolytes such as polyacrylates and polyaconitates, non-dissociated polymers such as polyvinyl alcohol, JP-A-1987
Polyacetal carboxylic acid polymers described in JP-A No. 60-227895, builders such as layered silicates, diglycolic acid, and oxycarboxylic acid salts, divalent metal ion scavengers, silicates, and carbonates described in JP-A-60-227895 Alkaline agents or inorganic electrolytes such as salts and sulfates, anti-recontamination agents such as polyvinylpyrrolidone and carboxymethyl cellulose, anti-caking agents such as paratoluene sulfonate, sulfosuccinate, talc and calcium silicate, tertiary butyl hydroxytoluene, It may contain an antioxidant such as a distyrenated cresol, a bluing agent, a flavoring agent, etc., but these are not particularly limited and may be blended according to the purpose.
【００２１】[0021]
【実施例】以下実施例にて本発明を更に説明するが、本
発明はこれらの実施例に限定されるものではない。[Examples] The present invention will be further explained in the following examples, but the present invention is not limited to these examples.
【００２２】実施例１
表１に示す量の粉末原料（牛脂脂肪酸ソーダ、ゼオライ
トＡ、無定形シリカ、炭酸ソーダ、ポリアクリル酸ソー
ダ及び蛍光染料等）を攪拌転動造粒機（レディゲミキサ
ー）に入れ、表１に示す量の液状ノニオン界面活性剤を
徐々に導入し、次いで表１に示す量のポリエチレングリ
コール及びすすぎ剤を添加し、更に酵素、香料及び少量
のゼオライトＡを加えて混合し、表１に示す組成の最終
洗剤製品を得た。この洗剤製品を用いて、消泡性及びす
すぎ性について以下の方法により試験した。表１にその
結果を示した。
■消泡性、すすぎ性試験方法
パルセーター型電気洗濯機（東芝製）に２０℃、３０リ
ットルの水道水を入れ、試料２５ｇを加え、攪拌、溶解
後、木綿肌着とポリエステル／木綿混紡のワイシャツを
合わせて１ｋｇと、下記組成のモデル油性汚れ２ｇを均
一に塗布した汚染布を上記の洗濯液に入れ、１０分間強
反転攪拌する。攪拌停止後、排水し、衣料を１分間脱水
しパルセーターを水道水ですすいだ後、再び水道水３０
リットルを入れ、衣料を加え３分間強反転バッチすすぎ
を行い、攪拌停止後の泡の量にて消泡性を判定し、すす
ぎ水の濁りにてすすぎ性を判定した。Example 1 Powder raw materials (beef tallow fatty acid soda, zeolite A, amorphous silica, soda carbonate, sodium polyacrylate, fluorescent dye, etc.) in the amounts shown in Table 1 were stirred in a rotary granulator (Ledige mixer). , and gradually introduced liquid nonionic surfactant in the amount shown in Table 1, then added polyethylene glycol and rinsing agent in the amounts shown in Table 1, and further added enzyme, fragrance, and a small amount of zeolite A, and mixed. A final detergent product having the composition shown in Table 1 was obtained. Using this detergent product, antifoaming properties and rinsing properties were tested by the following methods. Table 1 shows the results. ■ Defoaming and rinsing test method Pour 30 liters of tap water at 20℃ into a pulsator type electric washing machine (manufactured by Toshiba), add 25 g of sample, stir and dissolve, then add cotton underwear and a polyester/cotton blend dress shirt. A total of 1 kg of stained cloth and 2 g of a model oil-based stain having the composition shown below are placed in the above washing solution and agitated with strong inversion for 10 minutes. After stopping the agitation, drain the water, dehydrate the clothes for 1 minute, rinse the pulsator with tap water, and then rinse it again with tap water for 30 minutes.
liter, clothes were added, and batch rinsing was performed on a strong inversion for 3 minutes. Defoamability was determined by the amount of foam after stirring was stopped, and rinsing performance was determined by the turbidity of the rinse water.
【００２３】
＊モデル油性汚れ組成
綿実油 ６０
重量％コレステロール １０重
量％オレイン酸 １０
重量％パルミチン酸 １０
重量％液体及び固体パラフィン １０重量％＊消
泡性の評価基準
Ａ：洗濯後の液面に泡がほとんど見られないＢ：洗濯後
の液面の約１／４に泡が存在するＣ：洗濯後の液面の約
１／２に泡が存在する＊すすぎ性の評価基準
Ａ：洗濯液が透明である
Ｂ：洗濯液がほぼ透明である
Ｃ：洗濯液に濁りが見られる*Model oily stain composition Cottonseed oil 60
wt% cholesterol 10wt% oleic acid 10
Weight% palmitic acid 10
Weight% Liquid and solid paraffin 10% by weight *Defoaming evaluation criteria A: Almost no foam is seen on the liquid surface after washing B: Foam is present on about 1/4 of the liquid surface after washing C: Washing Bubbles are present on about 1/2 of the liquid surface after cleaning * Rinseability evaluation criteria A: Washing liquid is transparent B: Washing liquid is almost transparent C: Washing liquid is cloudy
【００２４】[0024]
【表１】[Table 1]
【００２５】[0025]
【表２】[Table 2]
【００２６】[0026]
【表３】[Table 3]
Claims (2)
ｄ） を含有してなる非イオン性粉末洗浄剤組成物。 （ａ） 融点が４０℃以下でかつＨＬＢ が ９．０〜
１６．０の範囲の非イオン界面活性剤
１２〜３５重量％（ｂ） アルミノケイ酸塩
２０〜６０重量％（ｃ） 分子量が
２００〜２０００のポリエチレングリコール
０．０５〜４重量％（ｄ） すすぎ剤
０．０２〜１０重量
％Claim 1: The following components (a), (b), (c) and (
d) A nonionic powder cleaning composition comprising: (a) Melting point is 40°C or less and HLB is 9.0~
Nonionic surfactants in the range of 16.0
12-35% by weight (b) aluminosilicate
20-60% by weight (c) Molecular weight is
200-2000 polyethylene glycol
0.05-4% by weight (d) Rinse agent
0.02-10% by weight
〜３）から選ばれた１種以上である請求項１記載の非イ
オン性粉末洗浄剤組成物。 １）シリコーン ２）炭素数８〜２０の脂肪酸塩 ３）炭素数８〜２０のアルキル基を有しエチレンオキサ
イドの付加モル数が３〜１４であり、プロピレンオキサ
イドの付加モル数が１〜１４であるポリオキシエチレン
ポリオキシプロピレンアルキルエーテル[Claim 2] (d) The rinsing agent as the component is the following 1)
The nonionic powder detergent composition according to claim 1, which is one or more selected from 3) to 3). 1) Silicone 2) Fatty acid salt having 8 to 20 carbon atoms 3) Having an alkyl group having 8 to 20 carbon atoms, the number of moles of ethylene oxide added is 3 to 14, and the number of moles of propylene oxide added is 1 to 14. A polyoxyethylene polyoxypropylene alkyl ether
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3066499A JP2714494B2 (en) | 1991-03-29 | 1991-03-29 | Nonionic powder detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3066499A JP2714494B2 (en) | 1991-03-29 | 1991-03-29 | Nonionic powder detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04301000A true JPH04301000A (en) | 1992-10-23 |
| JP2714494B2 JP2714494B2 (en) | 1998-02-16 |
Family
ID=13317574
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3066499A Expired - Fee Related JP2714494B2 (en) | 1991-03-29 | 1991-03-29 | Nonionic powder detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2714494B2 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61272299A (en) * | 1985-05-29 | 1986-12-02 | ライオン株式会社 | Granular detergent composition |
| JPS638496A (en) * | 1986-06-27 | 1988-01-14 | ライオン株式会社 | Water-soluble film-containing pasty detergent |
-
1991
- 1991-03-29 JP JP3066499A patent/JP2714494B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61272299A (en) * | 1985-05-29 | 1986-12-02 | ライオン株式会社 | Granular detergent composition |
| JPS638496A (en) * | 1986-06-27 | 1988-01-14 | ライオン株式会社 | Water-soluble film-containing pasty detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2714494B2 (en) | 1998-02-16 |
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