JPH0428728A - Antistatic polyester film and its production - Google Patents
Antistatic polyester film and its productionInfo
- Publication number
- JPH0428728A JPH0428728A JP2329290A JP2329290A JPH0428728A JP H0428728 A JPH0428728 A JP H0428728A JP 2329290 A JP2329290 A JP 2329290A JP 2329290 A JP2329290 A JP 2329290A JP H0428728 A JPH0428728 A JP H0428728A
- Authority
- JP
- Japan
- Prior art keywords
- film
- polyester film
- antistatic
- ether glycol
- antistatic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006267 polyester film Polymers 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 33
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 239000002216 antistatic agent Substances 0.000 claims abstract description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 238000001125 extrusion Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- -1 alcohol succinic acid esters Chemical class 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- 206010027476 Metastases Diseases 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000009401 metastasis Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- IZKAZYONCIKJID-UHFFFAOYSA-N 2-butoxyethanol;2-ethoxyethanol Chemical compound CCOCCO.CCCCOCCO IZKAZYONCIKJID-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910021514 lead(II) hydroxide Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WLGDAKIJYPIYLR-UHFFFAOYSA-N octane-1-sulfonic acid Chemical compound CCCCCCCCS(O)(=O)=O WLGDAKIJYPIYLR-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、帯電防１１−９性、特に低湿度ドにおける制
電性に優れ、かつ高温高湿度トにおいても、透明性の優
れたフィルムに関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention provides a film that has excellent anti-static properties, especially in low-humidity conditions, and has excellent transparency even in high-temperature and high-humidity conditions. It is related to.
（従来の技術）
周知の如く、ポリエステルフィルムは、高度の結晶性、
優れた透明光沢性、力学的性質、耐薬品性、耐熱性等を
自することから、広範【ｍな用途に年々急速に使用され
ている。(Prior Art) As is well known, polyester film has a high degree of crystallinity,
Due to its excellent transparent gloss, mechanical properties, chemical resistance, heat resistance, etc., it is rapidly being used in a wide range of applications year by year.
しかし、一般のポリエステルフィルムは、高度の電気絶
縁性を有しているｌ）、静電気の発生、蓄積を生じやす
く、静電気障害による神々のトラブルを惹起するという
欠点を有している。例えば、製膜を稈や印刷、接着、製
袋包装、その他２次加■工程等において、ロールへの巻
きつき、人体への／ヨック、取扱い困難のような、作業
能率の低ドや印刷ヒゲの発生、フィルム表面の汚れなと
商品価値の低Ｆをもたらす原因となる。このような静電
気障害防ｌ法として、−・股に帯電防ｌ］−剤を樹脂中
に練込み製膜する方法とフィルム表面に帯′心防正剤を
塗布する方法とがある、ポリエステルフィルムに関して
は、このいわゆる練込型帯′心防止処理法が、フィルム
内部より、帯電防止剤か表面ににしみ出ることによって
、帯電防止効果を発揮するのに対して、ポリエステル樹
脂の高い２次転移温度のためにフィルム製膜後、常温付
近の温度では帯電防止剤の、フィルム表面へのしみ出し
が打なわれず、−・方、製膜温度条件が高いことや、ポ
リエステル自体のもつ極性基の高い反応性のために帯電
防止効果の配合によって、製膜時に重合体の劣化を牛し
たり、着色及び、物理的性質の低下をもたらすなとの問
題かあり、困難であった。特に２軸延伸したポリエステ
ルフィルムの場合、延伸工程でフィルム表面１−にある
、帯電防１１．剤か逃散消失するために全く帯電防＋ｊ
ｔ効製を示さなくなる場合が多（、さらに、帯電防止剤
のうち多くは、ポリエステルフィルムの配合によって、
フィルムの透明性を極度に低−ドさせるものであり、実
用に供し難い。However, general polyester films have the disadvantage that although they have a high degree of electrical insulation, they tend to generate and accumulate static electricity, causing problems due to static electricity. For example, during film forming processes such as culmming, printing, adhesion, bag making and packaging, and other secondary processing processes, there may be problems with low work efficiency such as wrapping around rolls, injury to the human body, and difficulty in handling. The occurrence of dirt and contamination on the film surface result in a low product value. As methods for preventing such electrostatic damage, there are two methods: - A method of kneading an antistatic agent into a resin to form a film, and a method of applying an antistatic agent to the surface of the film. In contrast, this so-called kneading-type band core prevention treatment method achieves the antistatic effect by seeping the antistatic agent from inside the film to the surface, whereas the polyester resin has a high secondary transition. Due to the temperature, the antistatic agent does not ooze out onto the film surface at temperatures around room temperature after film formation. Due to the high reactivity of the polymer, it has been difficult to incorporate antistatic effects into the film to avoid deterioration of the polymer during film formation, coloring, and deterioration of physical properties. In particular, in the case of a biaxially stretched polyester film, the antistatic 11. Completely anti-static due to the dissipation and dissipation of the agent
In many cases, the antistatic agent no longer exhibits any antistatic effect (furthermore, many antistatic agents, depending on the formulation of the polyester film,
This extremely reduces the transparency of the film, making it difficult to put it to practical use.
又、フィルム表面に帯電防止効果を塗布する方法は、例
えば特公昭５０−６８６７号公報では、帯電防止剤を水
溶液として施こす帯電防上仕上方法が、公示されている
が、この方法で、仕上げされたポリエステルフィルムは
、急激な温湿度変化、例えば、２３℃で５０％相対湿度
の雰囲気から、６０℃で８０％相対湿度の雰囲気の急激
な変化によって塗布層が白化し、透明性が低下し、実用
に供し難い状態を惹起する。Furthermore, as a method for applying an antistatic effect to the film surface, for example, Japanese Patent Publication No. 50-6867 discloses an antistatic finishing method in which an antistatic agent is applied as an aqueous solution; The coated layer of polyester film that has been coated will turn white and its transparency will decrease due to a sudden change in temperature and humidity, for example, from an atmosphere of 50% relative humidity at 23°C to an atmosphere of 80% relative humidity at 60°C. , causing a situation that is difficult to put into practical use.
（発明が解決しようとする課題）
本発明は、前記従来技術における課題、即ち、帯電防止
性と透明性、特に、低湿度下における帯電防止性、およ
び、急激な温湿度変化においても、白化せず透明性の優
れたポリエステルフィルムを提供することである。(Problems to be Solved by the Invention) The present invention solves the problems in the prior art described above, namely, antistatic properties and transparency, especially antistatic properties under low humidity, and no whitening even under sudden changes in temperature and humidity. The first object of the present invention is to provide a polyester film with excellent transparency.
（課題を解決するための１段）
すなわち本発明は、ポリエステルフィルムの少なくとも
片面に、
（１） 炭素数ｌＯ〜２０のアルキル基を有するアニ
オン系帯電防止剤
■ 低級エーテルグリコール
（３）水
からなり、低級エーテルグリフールを、１０屯−％以上
含む塗布液を塗布したことを特徴とする帯電防止ポリエ
ステルフィルム及び溶融押出された未延伸ポリエステル
フィルム又は、一軸延伸ポリエステルフィルムの少なく
とも片面に、（１） 炭素数１０〜２０のアルキル基
を有するアニオン系帯電防止剤
■ 低級エーテルグリコール
（３３）水
からなり、低級エーテルグリコールを１０重量％以上含
む塗布液を塗布したのち、この塗布フィルムを史に一軸
延伸、又は、一軸延伸することを特徴とする帯電防１１
−性ポリエステルフイルムの製造方法によって前記課題
を解決することができる。(One Step to Solve the Problems) That is, the present invention comprises, on at least one side of a polyester film, (1) an anionic antistatic agent having an alkyl group having 10 to 20 carbon atoms, lower ether glycol, and (3) water. , on at least one side of an antistatic polyester film, a melt-extruded unstretched polyester film, or a uniaxially stretched polyester film, characterized in that a coating solution containing 10 tons or more of lower ether glyfur is coated, (1) Anionic antistatic agent having an alkyl group having 10 to 20 carbon atoms ■ Lower ether glycol (33) After applying a coating solution consisting of water and containing 10% by weight or more of lower ether glycol, this coated film is uniaxially stretched. , or antistatic 11 characterized by uniaxial stretching.
The above-mentioned problems can be solved by the method for producing a polyester film.
本発明で用いるアニオン系帯電防止剤としては、炭Ｊｆ
ｉｌｏ〜２０のアルキル基を有する高級アルコール疏酸
エステルのＮａの塩、アルキルフェ／−ル酸化エチレン
付加体の硫酸エステル塩、アルキルスルホン酸塩、アル
キルアリルスルホン酸などの硫酸及びスルホン酸誘導体
か好ましい。また、低級エーテルグリコールとしては、
エチレングリコールエチルエーテルエチレングリコール
ブチルエーテルなと、水と任きの割合で混合するものか
好ましいか、高級エーテルグリコールは、塗布液にした
場合、水と層分離を起こし、塗布時に塗布ムラ等の障害
を発生しやすいので好ましくない。As the anionic antistatic agent used in the present invention, carbon Jf
Sulfuric acid and sulfonic acid derivatives such as Na salts of higher alcohol succinic acid esters having an alkyl group of ilo to 20, sulfuric acid ester salts of alkyl phenylene oxide adducts, alkyl sulfonates, and alkylaryl sulfonic acids are preferred. . In addition, as a lower ether glycol,
Ethylene glycol ethyl ether Ethylene glycol butyl ether and ethylene glycol butyl ether are preferable when mixed with water in a given ratio.When made into a coating solution, higher ether glycols cause layer separation from water and cause problems such as uneven coating during coating. This is not desirable as it can easily occur.
但し、層分離を起こさない程度であれば、併用してもよ
い。また、低級アルコールを併用すると史に耐久性が向
トする場合があり、イソプロピルアルコール、エチルア
ルコールが顕著な効果を示す。However, they may be used in combination as long as they do not cause layer separation. Furthermore, if a lower alcohol is used in combination, the durability may be improved, and isopropyl alcohol and ethyl alcohol show remarkable effects.
上記の低級エーテルグリコールは、塗布ＭｊＭの１０Ｓ
＠％以りを占めることが必須である。好ましくは、６０
％〜１０％である。エーテルグリコ−重量が、６０％を
越える場合は、塗布液中の有機溶剤量が増加し、フィル
ム製造玉梓中に塗布する場合、爆発の危険性を生し防爆
対策が必要となる。また、エーテルグリコール凝か１０
％未満の場合には、塗布液の表面張力か大きくなり、フ
ィルムへの濡れ性が低下し、塗布斑を生しやすくなり、
さらに、理由は不明であるが、急激な、温湿度変化が起
った場合に、フィルムの透明性が低下し実用に供し難い
。The above lower ether glycol is 10S of coating MjM.
It is essential to account for @% or more. Preferably 60
% to 10%. When the weight of ether glyco exceeds 60%, the amount of organic solvent in the coating solution increases, and when it is coated during film production, there is a risk of explosion and explosion-proof measures are required. Also, ether glycol 10
If it is less than %, the surface tension of the coating solution increases, the wettability to the film decreases, and coating spots are likely to occur.
Furthermore, for unknown reasons, when a sudden change in temperature and humidity occurs, the transparency of the film decreases, making it difficult to put it to practical use.
本発明に用いられるポリエステルフィルムは、溶融押出
しされた未延伸フィルム、あるいは一軸延伸フィルム、
又は、二軸延伸フィルムのいづれでもよいが、二輪延伸
フィルムに塗布するのは、フィルムが広巾になっており
、かつフィルムの走行速度が速くなっているために、均
一に塗布しにくいため前二者が好ましく、また、前二者
は、塗布後延伸熱処理されるため、帯電防止層とベース
層の密着性が良好である効果が付与される。The polyester film used in the present invention is a melt-extruded unstretched film, a uniaxially stretched film,
Alternatively, either biaxially stretched film may be used, but since the film is wide and the film travels at a high speed, it is difficult to apply it uniformly. In addition, since the former two are subjected to stretching heat treatment after coating, the effect of good adhesion between the antistatic layer and the base layer is imparted.
ポリエステルフィルムに、公知のコート法で塗布される
塗布液の晴は、二軸足伸後のフィルム１−に存在する鼠
として、０．００５〜０．５ｇ／ｌ／である。塗布社か
０．００５ｇ／ｊ未ＩＲであると帯電防止効果か弱くな
る。また、塗布賑か０．５ｇ／ｊを越えると、フィルム
の透明性の低ドやブロッキング性か悪くなる。The density of the coating liquid applied to the polyester film by a known coating method is 0.005 to 0.5 g/l/, based on the amount present in the film 1- after biaxial stretching. If the IR is less than 0.005 g/j, the antistatic effect will be weakened. Furthermore, if the coating density exceeds 0.5 g/j, the film will have low transparency and poor blocking properties.
以上述べた方法で得られるポリエステルフィルムは、透
明性帯電防止性にすぐれている。The polyester film obtained by the method described above has excellent transparency and antistatic properties.
（実施例１）
以下にこの発明の詳細な説明するが、本発明は、これに
限定されるものではない。実施例中、部、％は重量基準
を示す。また評価はＦ記に基づいて行なった。(Example 1) The present invention will be described in detail below, but the present invention is not limited thereto. In the examples, parts and % are based on weight. Moreover, the evaluation was performed based on the F description.
（１） 帯電防止性
帯電防止性は、コーティングフィルムの表面抵抗器（Ｋ
ＡＷＡＧＵＣＨＩ ＥＬＥＣＴＲＩＣＷＯＲＫＳ製固有
抵抗測定器）により印加電圧５００Ｖ１２３°Ｃ，４０
％ＲＨの条件で測定した。(1) Antistatic property Antistatic property is determined by the surface resistor (K
Applied voltage 500V 123°C, 40
It was measured under the condition of %RH.
■ ヘイズ
ヘイズＪＩＳ Ｋ６７１４に準し、日本精密機械社製
へイズメーターを用いて、ｓ１定した。■ Haze Haze s1 was determined according to JIS K6714 using a haze meter manufactured by Nippon Seimitsu Machinery Co., Ltd.
Ａ） コートポリエステルフィルムを２３℃で５０％
の相対湿度ドで約１時間以−Ｌ故ｉ！後、ヘイズ測定し
た。A) 50% coated polyester film at 23℃
For about 1 hour or more at a relative humidity of After that, haze was measured.
Ｂ） Ａ）のフィルムを他の雰囲気にさらすことなく
、６０℃で８０％の相対湿度ドに約１０分以Ｉ−放置し
２３℃、５０％の相対湿度）゛で７１１１疋した。B) The film of A) was left at 60 DEG C. and 80% relative humidity for about 10 minutes without being exposed to any other atmosphere, and then heated at 23 DEG C. and 50% relative humidity.
（３）帯電防止層の密着性
帯電防止層のないポリエステルフィルム而さ、本発明フ
ィルムの帯電防止層面を密着させ、１００ｇ／ｃｎｌの
荷重１；４０℃で２４時間放置後剥離し、転移性を肉眼
観察した。全く転移していないものを０１著しく転移し
たものを×、その中間を△とした。(3) Adhesion of antistatic layer A polyester film without an antistatic layer was adhered to the antistatic layer surface of the film of the present invention, and the film was peeled off after being left at 40°C for 24 hours under a load of 100 g/cnl, and the transfer property was confirmed. Observed with the naked eye. Those with no metastasis were rated 0, those with significant metastasis were rated ×, and those in between were rated △.
実施例１
（１） ポリエチレンテレフタレートの製＆エチレン
グリコール２００ ｍ［！中に水酸化鉛ｐｂＯ，Ｐｂ
（ＯＨ）２２．２ｇ （Ｐｂ０．９５ｘｌＯ−２モル）
を溶解し、この溶液にＧｅｍ２２、Ｏｇ （１，９Ｘ１
０−２モル）を添加して、１９７℃のエチレングリコー
ルの沸点で、Ｆ：２′ｒｋ加熱すると約３０分で透明な
溶液が得られた。次にこの溶液を重縮合触媒とするポリ
エチレンテレフタレートの製造を社なうた。ジメチルテ
レフタレート６２０部、エチレングリコール４８０部、
エステル交換触媒として、酢酸管側Ｚ ｎ （ＯＡｃ
１２８２００．０３６部をエステル交換反応器にとり、
エステル交換反応は、１５０℃より２３０℃に徐々に昇
温しつつ行ない、１２０分を要してメタノールの溜出を
終った。次いで、内容物を小縮合装置に移し、重縮合触
媒としてＦ記、触媒溶液２．７部を加え、徐々に昇温す
ると共に減圧し、１時間を要して２８０℃として０．５
＋ｓｍＨｇの高減圧Ｆの重縮合反応を２５分間打なって
得られたポリマーは極限粘度０．６３、融点２８２℃で
あった。Example 1 (1) Made of polyethylene terephthalate & ethylene glycol 200 m [! Lead hydroxide pbO, Pb
(OH) 22.2g (Pb0.95xlO-2 mol)
Gem22, Og (1,9X1
0-2 mol) was added and heated at F:2'rk at the boiling point of ethylene glycol at 197 DEG C., a clear solution was obtained in about 30 minutes. Next, they began producing polyethylene terephthalate using this solution as a polycondensation catalyst. 620 parts of dimethyl terephthalate, 480 parts of ethylene glycol,
As a transesterification catalyst, acetic acid tube side Z n (OAc
128200.036 parts were placed in a transesterification reactor,
The transesterification reaction was carried out while gradually raising the temperature from 150°C to 230°C, and distillation of methanol was completed in 120 minutes. Next, the contents were transferred to a small condensation apparatus, 2.7 parts of the catalyst solution of item F was added as a polycondensation catalyst, the temperature was gradually raised and the pressure was reduced, and it took 1 hour to reach 0.5 at 280°C.
The polymer obtained by carrying out the polycondensation reaction at a high vacuum F of +smHg for 25 minutes had an intrinsic viscosity of 0.63 and a melting point of 282°C.
■ アニオン系帯電防止塗布液の調合
ドデ／ルスルホネート２００部に水、６３００部を加え
て希釈し、さらに、エチレングリコールブチルエーテル
３５００部を加えて固形分膿度２％の塗布液を得た。(2) Preparation of anionic antistatic coating solution 200 parts of dode/rusulfonate was diluted by adding 6,300 parts of water, and further 3,500 parts of ethylene glycol butyl ether was added to obtain a coating solution with a solid content of 2%.
（：り） インラインコートフィルムの製造（１）で
製造した、ポリエチレンテレフタレートを２８０℃〜３
００℃で溶融押出し、１５℃の冷却ロールで冷却して、
厚さ１２０ミクロンの未延伸フィルムを得、この未延伸
フィルムを周速の異なる８５℃のロール間で、縦方向に
３．５倍延伸し、前記の塗布液をエアナイフ方式で塗布
し、７０℃の熱風で乾燥し、次いでテンターで９８℃で
横方向に３．５倍延伸し、さらに２００〜２１０℃で熱
固定し、厚さ１２２ミフロンコートｉｏ、０ｇ／ ｒｊ
の二軸延伸コーティングポリエステルフィルムを得た。(:ri) Polyethylene terephthalate produced in step (1) of manufacturing inline coated film was heated to 280°C to 3°C.
Melt extrusion at 00°C, cooled with a cooling roll at 15°C,
An unstretched film with a thickness of 120 microns was obtained, this unstretched film was stretched 3.5 times in the longitudinal direction between rolls at different circumferential speeds at 85°C, and the above coating solution was applied using an air knife method, and the unstretched film was stretched at 70°C. It was dried with hot air of
A biaxially stretched coated polyester film was obtained.
得られたフィルムの物性を第１表に示した。第１表から
れかるように、得られたフィルムは、透明性に優れ低湿
度下における帯電防１１−も優れている。The physical properties of the obtained film are shown in Table 1. As can be seen from Table 1, the obtained film has excellent transparency and antistatic resistance under low humidity (11-).
（実施例２）
実施例１において帯電防１Ｌ剤のドデンルスルホネート
ヲドデ／ルベンゼ／スルホネートに変えた以外は、実施
例１と同様にして二軸延伸フィルムを得た。得られたフ
ィルムの物性を第１表に小した。(Example 2) A biaxially stretched film was obtained in the same manner as in Example 1, except that the antistatic 1L agent in Example 1 was changed to dodode/rubenze/sulfonate. The physical properties of the obtained film are shown in Table 1.
（実施例３）
実Ｍ［１において、１千レンゲリコールブチルエーテル
をエチレングリコールエチルエーテルに変えた以外は、
実施例１と同様にして二軸延伸ポリエステルフィルムを
得た。得られたフィルムの物性を第１表に小した。(Example 3) In Actual M [1, except that 1,000 range glycol butyl ether was changed to ethylene glycol ethyl ether,
A biaxially stretched polyester film was obtained in the same manner as in Example 1. The physical properties of the obtained film are shown in Table 1.
（比較例１）
実施例１において、ドデンルスルホネートヲ、アルキル
トリメチルアンモニウム塩に変えた以外は、実施例１と
同様にして二軸延伸ポリエステルフィルムを得た。得ら
れたフィルムの物性を第１表に示した。(Comparative Example 1) A biaxially stretched polyester film was obtained in the same manner as in Example 1, except that dodenyl sulfonate was replaced with alkyltrimethylammonium salt. The physical properties of the obtained film are shown in Table 1.
（比較例２）
実施例１において、ドデ／ルスルホネートを、ポリエチ
レングリコールに変えた以外は、実施例１と同様にして
二軸延伸ポリエステルフィルムを得た。得られたフィル
ムの物性を第１表に示した。(Comparative Example 2) A biaxially stretched polyester film was obtained in the same manner as in Example 1, except that dode/rusulfonate was changed to polyethylene glycol. The physical properties of the obtained film are shown in Table 1.
（比較例３）
実施例１において、ドデ／ルスルホ不一トを、オクチル
スルホネートに変えた以外は、実施例１と同様にして二
軸延伸ポリエステルフィルムを得た。得られたフィルム
の物性を第１表に小した。(Comparative Example 3) A biaxially stretched polyester film was obtained in the same manner as in Example 1, except that octyl sulfonate was used instead of dode/sulfonate. The physical properties of the obtained film are shown in Table 1.
実施例４
実施例１において、二軸延伸後のフィルムに塗布した以
外は実施例１吉同様にしてコートポリエステルフィルム
を得た。得られたフィルムの物性を第１表に小した。Example 4 A coated polyester film was obtained in the same manner as in Example 1 except that the film was coated after biaxial stretching. The physical properties of the obtained film are shown in Table 1.
（比較例４〜５）
実施例１において、低級エーテルグリフールの添加徽を
第１表のごとく変更した以外は、実施例１と同様にして
二軸延伸ポリエステルフィルムを得た。得られたフィル
ムの物性を第１表にホした。(Comparative Examples 4 to 5) A biaxially stretched polyester film was obtained in the same manner as in Example 1, except that the addition level of lower ether glyfur was changed as shown in Table 1. The physical properties of the obtained film are shown in Table 1.
第１表中で、本発明によるポリエステルフィルムはへ−
ズ、帯電防Ｉｌｌ性において、いづれも良好な特性を４
くず。しかしながら帯電防止剤か本発明の範囲から外れ
た場合には帯電防Ｉト効果か、１分には得られない。（
比較例１〜３）
低級エーテルゲリコールの添加か、本発明の範囲を外れ
ると、急激な温湿度変化を受けた場合に、透明性か低ド
することかわかる。（比較例４〜５）以ド余白
（発明の効果）
本発明のポリエステルフィルムは低湿度ドで良好な制電
制を示し、また急激な温湿度変化でもヘイズ変化せず、
包装用、ｆ業用およびその他の用途で極めて有用な制電
性フィルムであるこ占かわかる。In Table 1, the polyester film according to the invention is
All four have good properties in terms of anti-static properties.
Scraps. However, if the antistatic agent is outside the scope of the present invention, the antistatic effect cannot be obtained in one minute. (
Comparative Examples 1 to 3) It can be seen that the addition of lower ether gellicol, which is outside the scope of the present invention, results in a decrease in transparency when subjected to rapid changes in temperature and humidity. (Comparative Examples 4 to 5) Margins (Effects of the Invention) The polyester film of the present invention exhibits good antistatic properties at low humidity, and does not change haze even with sudden changes in temperature and humidity.
It is clear that this antistatic film is extremely useful for packaging, industrial use, and other uses.
Claims (2)
）少なくともＣ＿１＿０〜Ｃ＿２＿０基を有するアニオ
ン系帯電防止剤 （Ｂ）低級エーテルグリコール （Ｃ）水 からなり、低級エーテルグリコールを少なくとも１０％
含む塗布液を塗布したことを特徴とする帯電防止ポリエ
ステルフィルム(1) On at least one side of the polyester film, (A
) Anionic antistatic agent having at least C_1_0 to C_2_0 groups (B) Lower ether glycol (C) Consisting of water and containing at least 10% lower ether glycol
An antistatic polyester film coated with a coating liquid containing
一軸延伸されたポリエステルフィルムの少なくとも片面
に （Ａ）少なくともＣ＿１＿０〜Ｃ＿２＿０基を有するア
ニオン系帯電防止剤 （Ｂ）低級エーテルグリコール （Ｃ）水 からなり、低級エーテルグリコールを少くとも１０％含
む塗布液を塗布したのち乾燥し、更に二軸延伸、又は一
軸延伸することを特徴とする帯電防止ポリエステルフィ
ルムの製造方法。(2) consisting of (A) an anionic antistatic agent having at least C_1_0 to C_2_0 groups (B) lower ether glycol (C) water on at least one side of the melt-extruded unstretched polyester film or uniaxially stretched polyester film; A method for producing an antistatic polyester film, which comprises applying a coating solution containing at least 10% of lower ether glycol, drying, and further biaxially or uniaxially stretching.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2329290A JP2924045B2 (en) | 1990-01-31 | 1990-01-31 | Antistatic polyester film and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2329290A JP2924045B2 (en) | 1990-01-31 | 1990-01-31 | Antistatic polyester film and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0428728A true JPH0428728A (en) | 1992-01-31 |
| JP2924045B2 JP2924045B2 (en) | 1999-07-26 |
Family
ID=12106534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2329290A Expired - Fee Related JP2924045B2 (en) | 1990-01-31 | 1990-01-31 | Antistatic polyester film and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2924045B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103368A (en) * | 1996-07-12 | 2000-08-15 | Teijin Ltd. | Antistatic polyester film and antistatic film laminate |
| US6254996B1 (en) | 1998-06-05 | 2001-07-03 | Teijin Limited | Antistatic polyester film and process for producing the same |
| EP1108741A3 (en) * | 1999-12-14 | 2004-04-21 | Diafoil Hoechst Co., Ltd. | Packaging polyester film |
| JP2005316428A (en) * | 2004-03-31 | 2005-11-10 | Dainippon Printing Co Ltd | Antistatic antireflection film preventing occurrence of interference fringe |
| US7211309B2 (en) | 2003-03-25 | 2007-05-01 | Teijin Dupont Films Japan Limited | Antistatic laminated polyester film |
| US20120088112A1 (en) * | 2009-06-05 | 2012-04-12 | Toyo Boseki Kabushiki Kaisha | Biaxially-oriented polyester film for use as wrap-around container label, and wrap-around container label |
-
1990
- 1990-01-31 JP JP2329290A patent/JP2924045B2/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103368A (en) * | 1996-07-12 | 2000-08-15 | Teijin Ltd. | Antistatic polyester film and antistatic film laminate |
| US6254996B1 (en) | 1998-06-05 | 2001-07-03 | Teijin Limited | Antistatic polyester film and process for producing the same |
| EP1108741A3 (en) * | 1999-12-14 | 2004-04-21 | Diafoil Hoechst Co., Ltd. | Packaging polyester film |
| US7211309B2 (en) | 2003-03-25 | 2007-05-01 | Teijin Dupont Films Japan Limited | Antistatic laminated polyester film |
| JP2005316428A (en) * | 2004-03-31 | 2005-11-10 | Dainippon Printing Co Ltd | Antistatic antireflection film preventing occurrence of interference fringe |
| US20120088112A1 (en) * | 2009-06-05 | 2012-04-12 | Toyo Boseki Kabushiki Kaisha | Biaxially-oriented polyester film for use as wrap-around container label, and wrap-around container label |
| US9005766B2 (en) * | 2009-06-05 | 2015-04-14 | Toyo Boseki Kabushiki Kaisha | Biaxially-oriented polyester film for use as wrap-around container label, and wrap-around container label |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2924045B2 (en) | 1999-07-26 |
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