JPH04242573A - Beverage container - Google Patents
Beverage containerInfo
- Publication number
- JPH04242573A JPH04242573A JP2407830A JP40783090A JPH04242573A JP H04242573 A JPH04242573 A JP H04242573A JP 2407830 A JP2407830 A JP 2407830A JP 40783090 A JP40783090 A JP 40783090A JP H04242573 A JPH04242573 A JP H04242573A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- ion
- bactericidal agent
- metal
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000013361 beverage Nutrition 0.000 title claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 47
- 239000011347 resin Substances 0.000 claims abstract description 47
- 239000003242 anti bacterial agent Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910021645 metal ion Inorganic materials 0.000 abstract description 4
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 abstract description 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- 239000010457 zeolite Substances 0.000 abstract description 3
- 239000004593 Epoxy Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000003899 bactericide agent Substances 0.000 abstract 6
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000013007 heat curing Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000008239 natural water Substances 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011777 magnesium Chemical class 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000005028 tinplate Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 239000011734 sodium Chemical class 0.000 description 1
- 229910052708 sodium Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/12—Cans, casks, barrels, or drums
- B65D1/14—Cans, casks, barrels, or drums characterised by shape
- B65D1/16—Cans, casks, barrels, or drums characterised by shape of curved cross-section, e.g. cylindrical
- B65D1/165—Cylindrical cans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D15/00—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials
- B65D15/02—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums
- B65D15/16—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums with curved, or partially curved, walls made of plastics material
- B65D15/18—Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums with curved, or partially curved, walls made of plastics material with end walls made of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/14—Linings or internal coatings
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Packages (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、自然水やミネルラルウ
ォータ等の飲料液を保存するための容器で、詳しくは、
金属（アルミニウムやブリキ、鉄等）や紙からなる主体
の内面に樹脂コーティングを施したもの、或いは、樹脂
から成るもの等、内面が樹脂から形成されているものに
関する。[Industrial Application Field] The present invention relates to a container for storing drinking liquid such as natural water or mineral water.
It relates to products whose inner surfaces are made of resin, such as those whose inner surfaces are coated with resin on the main body made of metal (aluminum, tinplate, iron, etc.) or paper, or those made of resin.
【０００２】0002
【従来の技術】例えば、自然水やミネラルウォータは、
無菌化保存する必要があり、その手段として、従来では
、自然水やミネラルウォータを容器に充填し密封したの
ち、１２０℃に一定時間保持する加熱殺菌手段が採られ
ていた。[Prior art] For example, natural water and mineral water are
It is necessary to preserve the product in a sterile manner, and the conventional method for this purpose has been to fill a container with natural water or mineral water, seal it, and then heat sterilize it by holding it at 120° C. for a certain period of time.
【０００３】0003
【発明が解決しようとする課題】しかし、前記従来技術
によるときは、殺菌のための加熱によって、水の溶存塩
類の組成、ｐＨが変化して、水の風味が大幅に変化する
。例えば、自然水では、１リットル中に１００〜３００
ｍｇの溶存塩類を含み、その構成は、カルシウムやマグ
ネシウム、ナトリウムの重炭酸塩や硫酸塩、塩化塩であ
る。そして、カルシウムやマグネシウムの重炭酸塩は溶
解度の低い重炭塩に変化し、１２０℃の加熱により、そ
れら重炭塩が水の共存下で一部水酸化物にまで変化する
。また、同時に不溶化したカルシウムやマグネシウムの
塩は、沈澱物やスケールとなる。本発明の目的は、加熱
殺菌することなく無菌化を保持できる飲料容器を提供す
る点にある。[Problems to be Solved by the Invention] However, when using the above-mentioned prior art, heating for sterilization changes the composition of dissolved salts in the water and the pH, resulting in a significant change in the flavor of the water. For example, in natural water, 100 to 300
mg of dissolved salts, which are composed of bicarbonate, sulfate, and chloride salts of calcium, magnesium, and sodium. Then, bicarbonate of calcium and magnesium changes to bicarbonate with low solubility, and by heating at 120° C., a portion of the bicarbonate changes to hydroxide in the coexistence of water. Additionally, calcium and magnesium salts that are insolubilized at the same time become precipitates and scales. An object of the present invention is to provide a beverage container that can maintain sterilization without heat sterilization.
【０００４】0004
【課題を解決するための手段】本発明による飲料容器の
特徴構成は、前記内面を形成する樹脂に抗菌剤を樹脂量
の０．２％以上の量をもって含有させてある点にある。A feature of the beverage container according to the present invention is that the resin forming the inner surface contains an antibacterial agent in an amount of 0.2% or more based on the amount of resin.
【０００５】[0005]
【作用】後述の実験結果からも明らかなように、液と接
する内面を抗菌化でき、液中に菌があっても、それが内
面に接することにより死滅させて、菌の増殖を防止でき
る。[Action] As is clear from the experimental results described below, the inner surface that comes into contact with the liquid can be made antibacterial, and even if there are bacteria in the liquid, they can be killed by coming into contact with the inner surface, and the proliferation of bacteria can be prevented.
【０００６】[0006]
【発明の効果】従って、本発明によれば、加熱殺菌を行
なうことなく無菌状態で保存でき、特に加熱により組成
、ｐＨが変化して風味が大幅に変化する自然水やミネラ
ルウォータの保存に好適な飲料容器を提供できるように
なった。もちろん、飲料を充填するには、除菌フィルタ
ーを通した液を充填することが好ましい。[Effects of the Invention] Therefore, according to the present invention, it can be stored in a sterile state without heat sterilization, and is particularly suitable for preserving natural water and mineral water whose composition and pH change due to heating and whose flavor changes significantly. We are now able to provide beverage containers that are Of course, when filling a beverage, it is preferable to fill the liquid through a sterilizing filter.
【０００７】[0007]
【実施例】図１に示すように、アルミニウムや鉄、ブリ
キ等の金属からなる主体１の内面に樹脂コーティング２
を施してある飲料容器であって、前記樹脂コーティング
２は、抗菌剤を樹脂量の０．２％以上、好ましくは、０
．２〜１０％の量をもって含有するものである。また、
樹脂コーティング２の樹脂は、金属への接着性に勝れた
エポキシなどの熱硬化性樹脂である。なお、樹脂は、ビ
ニール系樹脂などの熱可塑性樹脂であっも良い。
前記抗菌剤は、銀イオン等の金属イオンを、合成ゼオラ
イトやイオン交換樹脂等のイオン交換体の交換基とイオ
ン交換させたもの、或いは、前記の金属イオンを担持さ
せた無機化合物であって、不溶性のものであり、そして
、微粒子として樹脂に混入してある。また、樹脂に混入
する手段としては、樹脂に抗菌剤を、所定の含有量とな
るように直接に混入する手段の他、樹脂に抗菌剤を所定
の含有量以上の設定量で混入して抗菌剤入り樹脂を作り
、その抗菌剤入り樹脂を樹脂に混入して抗菌剤を所定量
含有させる手段を挙げることができる。[Embodiment] As shown in Fig. 1, a resin coating 2 is applied to the inner surface of a main body 1 made of metal such as aluminum, iron, or tinplate.
The resin coating 2 contains an antibacterial agent in an amount of 0.2% or more based on the resin amount, preferably 0.
．． It is contained in an amount of 2 to 10%. Also,
The resin of the resin coating 2 is a thermosetting resin such as epoxy that has excellent adhesion to metal. Note that the resin may be a thermoplastic resin such as a vinyl resin. The antibacterial agent is one in which a metal ion such as a silver ion is ion-exchanged with an exchange group of an ion exchanger such as a synthetic zeolite or an ion exchange resin, or an inorganic compound carrying the metal ion, It is insoluble and is mixed into the resin as fine particles. In addition, as a means of mixing the antibacterial agent into the resin, in addition to directly mixing the antibacterial agent into the resin to a predetermined content, there is also a method of mixing the antibacterial agent into the resin in a set amount higher than the predetermined content. An example of this method is to prepare a resin containing an antibacterial agent and mix the antibacterial agent into the resin to contain a predetermined amount of the antibacterial agent.
【０００８】次に本発明者が行なった抗菌効果を調べる
ための実験を示す。実験には、主体１として１８０ミリ
リットルのアルミニウム缶を、樹脂コーティング２とし
てエポキシ系樹脂を、抗菌剤として合成ゼオライトに銀
イオンをイオン交換させたものの微粒子を夫々用い、抗
菌剤の含有量が夫々０％、０．２％、１．０％、５．０
％、１０％のものを用意し、それら夫々に、大腸菌を含
む脱塩素水道水を収容し、時間経過に伴なう大腸菌の数
を調べた。結果を表１に示す。なお、樹脂コーティング
２については、抗菌剤の分散性を良くするため、２０％
の抗菌剤を加えた高濃度樹脂溶液を作り、これと抗菌剤
の入っていない樹脂溶液とを混合して前述の各濃度の樹
脂溶液を作り、それらに硬化剤を配合した。そして、そ
れらをスプレーにより缶内面に塗布し、１８０℃、２０
分の加熱を行なって硬化させることで形成した。また、
水の充填については、水を充填したのち、上部の蓋をま
きしめて密封化した。Next, an experiment conducted by the present inventor to investigate the antibacterial effect will be described. In the experiment, a 180ml aluminum can was used as the main body 1, an epoxy resin was used as the resin coating 2, and fine particles of silver ion exchanged with synthetic zeolite were used as the antibacterial agent, and the antibacterial agent content was 0. %, 0.2%, 1.0%, 5.0
% and 10% were prepared, each of which contained dechlorinated tap water containing E. coli, and the number of E. coli over time was examined. The results are shown in Table 1. Regarding resin coating 2, in order to improve the dispersibility of the antibacterial agent, 20%
A highly concentrated resin solution containing an antibacterial agent was prepared, and this was mixed with a resin solution containing no antibacterial agent to prepare resin solutions of the various concentrations mentioned above, and a curing agent was added to them. Then, they were applied to the inner surface of the can by spraying, and heated at 180℃ and 20℃.
It was formed by heating for several minutes to harden it. Also,
Regarding filling with water, after filling with water, the upper lid was rolled up to seal it.
【０００９】[0009]
【表１】[Table 1]
【００１０】〔別実施例〕〔１〕 上記実施例では、
主体１として金属製のものを用いたが、主体は紙製であ
っても良い。この場合、樹脂コーティング２の樹脂とし
ては、接着性からみてビニール系樹脂などの熱可塑性樹
脂が望ましい。しかし、熱硬化性樹脂であっても良い。[Another embodiment] [1] In the above embodiment,
Although the main body 1 is made of metal, the main body may be made of paper. In this case, the resin for the resin coating 2 is preferably a thermoplastic resin such as vinyl resin from the viewpoint of adhesiveness. However, a thermosetting resin may also be used.
【００１１】〔２〕 上記実施例では、主体１と樹脂
コーティング２から成るものを示したが、容器としては
、全体が樹脂からなるものであっても良い。[2] In the above embodiment, the container is made up of the main body 1 and the resin coating 2, but the container may be made entirely of resin.
【００１２】〔３〕 本発明は、水以外の飲料液の容
器も対象として含む。[3] The present invention also covers containers for beverages other than water.
【図１】断面図[Figure 1] Cross-sectional view
１ 主体 ２ 樹脂コーティング 1 Subject 2 Resin coating
Claims (1)
器であって、前記内面を形成する樹脂に抗菌剤を樹脂量
の０．２％以上の量をもって含有させてある飲料容器。1. A beverage container whose inner surface is made of resin, wherein the resin forming the inner surface contains an antibacterial agent in an amount of 0.2% or more based on the amount of the resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2407830A JPH04242573A (en) | 1990-12-27 | 1990-12-27 | Beverage container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2407830A JPH04242573A (en) | 1990-12-27 | 1990-12-27 | Beverage container |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04242573A true JPH04242573A (en) | 1992-08-31 |
Family
ID=18517369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2407830A Pending JPH04242573A (en) | 1990-12-27 | 1990-12-27 | Beverage container |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04242573A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020085271A (en) * | 2001-05-07 | 2002-11-16 | 안정오 | Aseptic Storage Method in Beverage Containers |
| KR20020086097A (en) * | 2001-05-11 | 2002-11-18 | 안정오 | Antibacterial treatment method of container |
| IT202100002579A1 (en) * | 2021-02-05 | 2022-08-05 | Alexandria S R L | CONTAINER FOR LIQUIDS |
-
1990
- 1990-12-27 JP JP2407830A patent/JPH04242573A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020085271A (en) * | 2001-05-07 | 2002-11-16 | 안정오 | Aseptic Storage Method in Beverage Containers |
| KR20020086097A (en) * | 2001-05-11 | 2002-11-18 | 안정오 | Antibacterial treatment method of container |
| IT202100002579A1 (en) * | 2021-02-05 | 2022-08-05 | Alexandria S R L | CONTAINER FOR LIQUIDS |
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