JPH0421412A - Manufacture of laminated sheet - Google Patents
Manufacture of laminated sheetInfo
- Publication number
- JPH0421412A JPH0421412A JP2127833A JP12783390A JPH0421412A JP H0421412 A JPH0421412 A JP H0421412A JP 2127833 A JP2127833 A JP 2127833A JP 12783390 A JP12783390 A JP 12783390A JP H0421412 A JPH0421412 A JP H0421412A
- Authority
- JP
- Japan
- Prior art keywords
- long
- laminate
- pressure
- laminated sheet
- films
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000011888 foil Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 2
- 238000009751 slip forming Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 9
- 239000010410 layer Substances 0.000 abstract description 8
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011521 glass Substances 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 239000011889 copper foil Substances 0.000 abstract description 3
- 239000012790 adhesive layer Substances 0.000 abstract description 2
- 238000004891 communication Methods 0.000 abstract description 2
- 238000003825 pressing Methods 0.000 abstract description 2
- 229920002313 fluoropolymer Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- -1 polyacrylic Polymers 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920006367 Neoflon Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Moulding By Coating Moulds (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は電子機器・電気機器、コンピューター、通信機
器等に用いられる積層板の製造方法に関するものである
。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for manufacturing a laminate used in electronic/electrical equipment, computers, communication equipment, etc.
従来の弗素樹脂からなる積層板は、弗素樹脂エマルジョ
ンを基材に含浸、乾燥することを反復して得られるプリ
プレグと金属箔とを多段プレスで加熱加圧成形してえら
れるが、基材への樹脂含浸性が悪いのに加え、プレスで
の成形歪が積層板中に残留歪となるため、積層板を印刷
配線板に加工する際や印刷配線板に電子部品を実装する
際の熱によって反りを発生し、自動化工程に支障を招来
する欠点があった。Conventional laminates made of fluororesin are obtained by heating and press-molding metal foil and prepreg obtained by repeatedly impregnating and drying a base material with a fluororesin emulsion in a multistage press. In addition to poor resin impregnation properties, the molding distortion in the press causes residual strain in the laminate, and the heat generated when processing the laminate into a printed wiring board or when mounting electronic components on the printed wiring board This method has the drawback of causing warpage and causing problems in automated processes.
従来の技術で述べたように弗素樹脂エマルジョンを基材
に含浸してなるプリプレグを多段プレスで成形して得ら
れる積層板は反りが大きくなる欠点がある。本発明は従
来の技術における上述の問題点に鑑みてなされたもので
、その目的とするところは反りの少ない積層板の製造方
法、を提供することにある。As described in the prior art section, a laminate obtained by molding a prepreg obtained by impregnating a base material with a fluororesin emulsion using a multi-stage press has the disadvantage of large warpage. The present invention has been made in view of the above-mentioned problems in the prior art, and its object is to provide a method for manufacturing a laminate with less warpage.
本発明は所要枚数の長尺基材の各上面及び又は下面に長
尺弗素樹脂フィルムを配し、更に必要に応じて最外層に
長尺金属箔を配設した長尺積層体を連続的に加熱加圧成
形後、所要寸法に切断することを特徴とする積層板の製
造方法のため、基材に溶融樹脂を圧入でき、且つ加熱加
圧時間を最小限にすることができ、積層板中の残留歪み
を少なくすることができるもので、以下本発明の詳細な
説明する。The present invention continuously forms a long laminate in which a required number of long base materials are provided with a long fluororesin film on each upper surface and/or lower surface, and further, if necessary, a long metal foil is provided on the outermost layer. The laminate manufacturing method is characterized by cutting into the required dimensions after heating and pressure forming, so the molten resin can be press-fitted into the base material and the heating and pressing time can be minimized. The present invention will be described in detail below.
本発明に用いる長尺基材としてはガラス、アスベスト等
の無機繊維やポリエステル、ポリアクリル、ポリビニル
アルコール、ポリアミド、ポリイミド、ポリフェニレン
サルファイド樹脂、ポリウレタン等の有機合成繊維や木
綿等の天然繊維からなる織布、不織布、マット或いは紙
又はこれ等の組合せ基材で、基材は予じめカップリング
剤等で処理しておくこともできる。長尺弗素樹脂フィル
ムとしては、四弗化エチレン樹脂、４弗化エチレンパー
フルオロビニルエーテル共ｆｉ 合体、四弗化エチレン
六弗化プロピレン共重合体、四弗化エチレンエチレン共
重合体、三弗化塩化エチレン樹脂等のように弗素樹脂全
般のフィルムを用いることができる。フィルムの厚みは
Ｏ，ＯＯ５〜０．５〜が好ましく、必要に応して弗素樹
脂には水酸化アルミニウム、タルク、シリカ、アルミナ
、炭酸カルシウム、炭酸マグネシウム等の無機充填剤や
ガラス繊維チップ、アスベスト、木粉、パルプ、綿粉等
の繊維質充填剤を添加することもできる。長尺金属箔と
しては銅、アルミニウム、鉄、ニッケル、亜鉛等の単独
、合金、複合箔が用いられ、必要に応して金属箔の片面
に接着剤層を設けておき、より接着性を向上させること
もできる。長尺積層体はダブルベルト法等によって連続
的に加熱加圧成形することができ、硬化温度は樹脂組成
によって異なるが、加圧は１〜４０ｋｇ／ａｌｌが好ま
しい。The elongated substrate used in the present invention is a woven fabric made of inorganic fibers such as glass and asbestos, organic synthetic fibers such as polyester, polyacrylic, polyvinyl alcohol, polyamide, polyimide, polyphenylene sulfide resin, polyurethane, and natural fibers such as cotton. , nonwoven fabric, mat, paper, or a combination thereof, and the base material may be treated with a coupling agent or the like in advance. Long fluororesin films include tetrafluoroethylene resin, tetrafluoroethylene perfluorovinyl ether cofi, tetrafluoroethylene hexafluoropropylene copolymer, tetrafluoroethylene ethylene copolymer, and trifluorochloride. Films of general fluororesins such as ethylene resins can be used. The thickness of the film is preferably O, OO5~0.5~, and if necessary, the fluororesin may contain inorganic fillers such as aluminum hydroxide, talc, silica, alumina, calcium carbonate, and magnesium carbonate, glass fiber chips, and asbestos. It is also possible to add fibrous fillers such as wood flour, pulp, cotton flour, etc. Single, alloy, or composite foils of copper, aluminum, iron, nickel, zinc, etc. are used as long metal foils, and if necessary, an adhesive layer is provided on one side of the metal foil to further improve adhesion. You can also do so. The elongated laminate can be continuously heated and pressed by a double belt method or the like, and the curing temperature varies depending on the resin composition, but the pressure is preferably 1 to 40 kg/all.
なお長尺積層体は成形直前に予熱することが望ましい。Note that it is desirable to preheat the elongated laminate immediately before molding.
以下本発明を一実施例を図示実施例にもとづいて説明す
れば次のようである。The present invention will be described below based on an illustrated embodiment.
第１図は本発明の積層板の製造方法の一実施例を示す簡
略工程図である。FIG. 1 is a simplified process diagram showing an embodiment of the method for manufacturing a laminate according to the present invention.
第１図に示すように幅１０５Ｃ１＋、厚さ０．１５ｍｍ
０長尺ガラス布ｌの３枚の各層間及び最外層に、厚さ０
．１−〇長尺四弗化エチレン六弗化プロピレン共重合体
フィルム（ダイキン工業株式会社製、ネオフロンフィル
ム）２を配し、更に最外層に厚さ０．０３５＋ａｍＯ長
尺接着剤付銅箔３の接着剤側をフィルム２と対向させて
夫々配設した長尺積層体４をダブルベルトロール装置５
で成形圧力１０ｋｇ／ ｃ４．２８０°Ｃで１０分間加
熱加圧成形後、カンタ−６で１００Ｃ１１毎に切断して
厚さ０．６１１１１の積層板を得た。Width 105C1+, thickness 0.15mm as shown in Figure 1
Between each layer of the 0 long glass cloth l and on the outermost layer, a thickness of 0
．． 1-〇 A long tetrafluoroethylene hexafluoropropylene copolymer film (manufactured by Daikin Industries, Ltd., Neoflon film) 2 is arranged, and the outermost layer is a long adhesive-coated copper foil 3 with a thickness of 0.035+amO. The long laminates 4, each of which is placed with its adhesive side facing the film 2, are transferred to a double belt roll device 5.
After heating and pressure molding at a molding pressure of 10 kg/c at 4.280°C for 10 minutes, the product was cut into pieces of 100 C11 using a counter 6 to obtain a laminate with a thickness of 0.61111 mm.
比較例１
実施例と同じ長尺積層体を１０１０５Ｘ１０５に切断し
、成形圧力２０ｋｇ／ｄ、２８０℃で６０分間プレスで
積層成形して厚さ０．６閣の積層板を得た。Comparative Example 1 The same long laminate as in Example was cut into 10105×105 pieces, and laminated by a press at 280° C. and a molding pressure of 20 kg/d for 60 minutes to obtain a 0.6 mm thick laminate.
比較例２
実施例と同じ四弗化エチレン六弗化プロピレン共重合体
エマルジョンを樹脂量が３０重量％になるように厚さ０
．１５＋ａｍのガラス布に含浸、乾燥したプリプレグ３
枚を重ね、更にその最外層に実施例と同じ銅箔を夫々配
設した積層体を成形圧力２０ ｋｇ／ｃｄ、２８０℃で
６０分間プレスで積層成形して厚さ０．６閣の積層板を
得た。Comparative Example 2 The same tetrafluoroethylene hexafluoropropylene copolymer emulsion as in Example was made to a thickness of 0 so that the resin amount was 30% by weight.
．． 15+am glass cloth impregnated and dried prepreg 3
A laminate with a thickness of 0.6 cm was obtained by stacking the sheets and then placing the same copper foil as in the example on the outermost layer of each layer in a press at a molding pressure of 20 kg/cd and 280°C for 60 minutes. I got it.
実施例及び比較例１と２の積層板の性能は第１表のよう
である。The performances of the laminates of Examples and Comparative Examples 1 and 2 are shown in Table 1.
第 １ 表
〔発明の効果］
本発明は上述した如く構成されている。特許請求の範囲
に記載した構成を有する積層板の製造方法で得られた積
層板の反りは少なく、本発明の優れていることを確認し
た。Table 1 [Effects of the Invention] The present invention is constructed as described above. The laminate obtained by the method for producing a laminate having the configuration described in the claims had little warpage, confirming the superiority of the present invention.
第１図は本発明の積層板の製造方法の一実施例を示す簡
略工程図である。FIG. 1 is a simplified process diagram showing an embodiment of the method for manufacturing a laminate according to the present invention.
Claims (1)
尺弗素樹脂フイルムを配し、更に必要に応じて最外層に
長尺金属箔を配設した長尺積層体を連続的に加熱加圧成
形、所要寸法に切断することを特徴とする積層板の製造
方法。(1) A long laminate in which a long fluororesin film is arranged on the upper and/or lower surface of each of the required number of long base materials, and a long metal foil is further arranged as the outermost layer as necessary, is continuously formed. A method for manufacturing a laminate, which comprises heating and press forming and cutting to required dimensions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2127833A JPH0421412A (en) | 1990-05-16 | 1990-05-16 | Manufacture of laminated sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2127833A JPH0421412A (en) | 1990-05-16 | 1990-05-16 | Manufacture of laminated sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0421412A true JPH0421412A (en) | 1992-01-24 |
Family
ID=14969792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2127833A Pending JPH0421412A (en) | 1990-05-16 | 1990-05-16 | Manufacture of laminated sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0421412A (en) |
-
1990
- 1990-05-16 JP JP2127833A patent/JPH0421412A/en active Pending
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