JPH04208246A - Metal soup and thermoplastic resin composition containing the same - Google Patents
Metal soup and thermoplastic resin composition containing the sameInfo
- Publication number
- JPH04208246A JPH04208246A JP33553790A JP33553790A JPH04208246A JP H04208246 A JPH04208246 A JP H04208246A JP 33553790 A JP33553790 A JP 33553790A JP 33553790 A JP33553790 A JP 33553790A JP H04208246 A JPH04208246 A JP H04208246A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic resin
- metal
- metal soap
- acid
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 52
- 239000002184 metal Substances 0.000 title claims abstract description 52
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 24
- 239000011342 resin composition Substances 0.000 title claims abstract description 9
- 235000014347 soups Nutrition 0.000 title 1
- 239000000344 soap Substances 0.000 claims abstract description 46
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- -1 fatty acid carboxylic acid Chemical class 0.000 claims abstract description 10
- 230000000737 periodic effect Effects 0.000 claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 3
- 239000000460 chlorine Substances 0.000 claims abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 3
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 3
- 229910052712 strontium Inorganic materials 0.000 claims abstract 2
- 238000010438 heat treatment Methods 0.000 claims description 5
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229910052728 basic metal Inorganic materials 0.000 abstract description 16
- 150000003818 basic metals Chemical class 0.000 abstract description 16
- 238000000034 method Methods 0.000 abstract description 10
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 6
- 239000000194 fatty acid Substances 0.000 abstract description 6
- 229930195729 fatty acid Natural products 0.000 abstract description 6
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 12
- 238000002844 melting Methods 0.000 description 11
- 230000008018 melting Effects 0.000 description 11
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 239000000395 magnesium oxide Substances 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 150000002484 inorganic compounds Chemical class 0.000 description 6
- 229910010272 inorganic material Inorganic materials 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920002959 polymer blend Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- 235000021357 Behenic acid Nutrition 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229940116226 behenic acid Drugs 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- OBQVOBQZMOXRAL-UHFFFAOYSA-L magnesium;docosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O OBQVOBQZMOXRAL-UHFFFAOYSA-L 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- IMYZYCNQZDBZBQ-UHFFFAOYSA-N (+-)-8-(cis-3-octyl-oxiranyl)-octanoic acid Natural products CCCCCCCCC1OC1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 101100361281 Caenorhabditis elegans rpm-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical group OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- VIALJPAGUCTUBQ-UHFFFAOYSA-L magnesium;12-hydroxyoctadecanoate Chemical compound [Mg+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O VIALJPAGUCTUBQ-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は、脂肪族カルボン酸と周期率表第■族金属の酸
化物又は水酸化物とを加熱直接反応させる、いわゆる乾
式直接法により製造される金属石鹸であって、含有する
金属量を理論量より過剰とした金属石鹸に関するもので
あり、更にこの金属成形物を熱可塑性樹脂に添加するこ
とにより、該熱可塑性樹脂の加工成形性、熱安定性を著
しく改善した熱可塑性樹脂組成物に関するものである。The present invention is a metal soap produced by the so-called dry direct method, in which an aliphatic carboxylic acid and an oxide or hydroxide of a Group I metal of the periodic table are directly reacted by heating. This invention relates to a metal soap in excess of the amount, and further relates to a thermoplastic resin composition in which the processing moldability and thermal stability of the thermoplastic resin are significantly improved by adding this metal molding to the thermoplastic resin. It is.
従来、熱６Ｊ塑性樹脂の成形加工に際し、熱安定−２〜
性、加工性等を向上させるためにフェノール系酸化防止
剤、有機リン酸系酸化防止剤等とともに種々の金属石鹸
が使用されている。
現在使用されている代表的な金属石鹸としては、ステア
リン酸カルシウム、ステアリン酸マグネシウム、ステア
リン酸亜鉛、ステアリン酸アルミニウム、ステアリン酸
リチウム等である。
しかし、これら従来の金属石鹸を使用しても、その成形
加工時に生じる金型での目ヤニ現象、金型壁あるいは加
工機壁へのプレート・アウト現象、スクリーンでの目詰
まり現象、さらには成形製品の表面に発生する添加剤の
吐出（浮き出し）現象等のトラブルに対しては未だ充分
に解決されているとはいえないのが現状である。Conventionally, various metal soaps have been used along with phenolic antioxidants, organic phosphoric acid antioxidants, etc. to improve thermal stability, processability, etc. during the molding process of thermal 6J plastic resins. . Typical metal soaps currently used include calcium stearate, magnesium stearate, zinc stearate, aluminum stearate, lithium stearate, and the like. However, even when using these conventional metal soaps, there are problems such as eye stain in the mold, plate-out phenomenon on the mold wall or processing machine wall, and clogging phenomenon in the screen during molding. At present, problems such as the extrusion (embossment) phenomenon of additives that occur on the surface of products have not yet been sufficiently resolved.
そこで、これら諸トラブルを解決するための手段として
、種々の滑剤類の添加が試みられているが、未だ満足す
べき結果は得られていない。
そのため、現状ではこのようなトラブルが発生すると、
成形加工機の運転を一時止め、その箇所を一３＝
クリーニングした後、再運転している。このような処置
を取るため、長時間の連続成形加１ニができず、作業性
が低下するばかりでなく、場合によっては成形製品の品
質低下にもつながるので、これを早期に解決すべき対策
の確立が要望されていた。Therefore, as a means to solve these problems, attempts have been made to add various lubricants, but satisfactory results have not yet been obtained. Therefore, currently, when such a problem occurs,
The operation of the molding machine was temporarily stopped, the area was cleaned, and then restarted. Due to such measures, continuous molding cannot be performed for a long time, which not only reduces work efficiency but also leads to a decline in the quality of the molded product in some cases, so measures should be taken to resolve this issue as soon as possible. It was requested that the establishment of
、 本発明者らは、このような問題点を解決するべく鋭
意研究を進めた結果、乾式直接法で製造した周期率表第
■族の金属石鹸であって、含有する金属量が理論計算量
より過剰な金属石鹸（１種の塩基性金属石鹸で以下塩基
性金属石鹸という）を開発し、この金属石鹸を従来の金
属石鹸に替えて、熱可塑性樹脂に添加使用することによ
り、前記した諸トラブルを解消し、加工成形性を改善す
るとともに、製品の品質低下を防ぐことに成功し本発明
を完成したものである。As a result of intensive research in order to solve these problems, the inventors of the present invention have found that a metal soap of group Ⅰ of the periodic table produced by a dry direct method has a metal content that is equal to the theoretically calculated amount. By developing a metal soap with a higher excess content (a type of basic metal soap, hereinafter referred to as basic metal soap), and adding this metal soap to a thermoplastic resin instead of the conventional metal soap, the above-mentioned problems can be achieved. The present invention has been completed by successfully eliminating the troubles, improving processing and forming properties, and preventing deterioration in product quality.
本発明の塩基性金属石鹸は、脂肪族モノカルボン酸（以
下脂肪酸という）と、周期率表第■族金属の酸化物又は
水酸化物（以下金属無機化合物とい一４＝
う）とを、加熱直接反応させて得られる公知の金属石鹸
の製造法の一種で、いわゆる乾式直接法（別名熔融法）
で製造されるものであるが、公知の金属石鹸と異なる点
は、公知の金属石鹸が脂肪酸と反応当量の金属無機化合
物と反応させるのに対して、本発明の□塩基性金属石鹸
は脂肪酸と反応当量以上の過剰に金属無機化合物を加え
て、反応生成物が透明になるように完全反間させて得ら
れたもので、その生成物の金属含有量、融点、酸価は自
ずから異なるものである。
本発明の塩基性金属石鹸の金属含有量の過剰率は、０．
１〜１．０モルで、好ましくは０．１〜０゜８である。
０．１モル以下では従来の金属石鹸とその性能にあまり
差がなく、又１．０モル以上では生成物の融液が透明に
ならず、未反応の金属無機化合物が残存するので好まし
くない。
本発明の塩基性金属石鹸の原料となる脂肪酸は炭素数１
２〜３０を有する天然又は合成の飽和又は不飽和のモノ
カルボン酸の１種以−Ｌで、構造中に側鎖、水酸基、ケ
トン基、アルデヒド基、エボシキ基等があってもよい。
その代表例としては、ラウリン酸、ミリスチン酸、パル
ミチン酸、ステアリン酸、アラギン酸、ヘプタデシル酸
、ベヘン酸、オレイン酸、エライジン・。
酸、エルカ酸、リノール酸、リルイン酸、リシノール酸
、ヒドロキシステアリン酸、モンタン酸、イソステアリ
ン酸、エポキシステアリン酸等が挙げられる。また、そ
の一部を脂肪族モノカルボン酸以外のカルボン酸又はジ
カルボン酸に置き換えてもよい。
本発明の塩基性金属石鹸を構成する金属は、′周期率表
第■族の金属の１種以上で、具体的には■ａアルカリ土
類金属及びｎｂ亜鉛族金属を言い、好ましくはＭｇ、
Ｃａ、Ｚｎである。
本発明の熱可塑性樹脂組成物は、熱可塑性樹脂に上記塩
基性金属石鹸を添加してなる組成物で、従来の金属石鹸
を添加した熱可塑性樹脂組成物では得られない成形加工
性を発揮する。
即ち、過剰な金属を含有する本発明の金属石鹸は、後記
実施例に示す如く、その融点が従来の金属石、鹸に比し
著しく高くなるので、高温成形の熱可塑性樹脂において
、滑性効果並びに離型効果の向−１〕を期待することが
できるものである。
本発明の乾式直接法の塩基性金属石鹸以外に、湿式沈澱
法によって塩基性金属石鹸を製造することもできるが、
この湿式沈澱法で製造した塩基性金属石鹸は、熱熔解す
ると塩基性部分の金属無機化合物が分離し、沈殿が生じ
る。また、この湿式沈澱法で製造した塩基性金属石鹸を
熱可塑性樹脂に添加して成形加工を行うと、金型での目
ヤニ現象は全く改善で゛きないばかりでなく、逆にスク
リーンへの目詰まり現象が強く生じ、トラブルを助長す
る欠点があり、本発明の塩基性金属石鹸とは性能的に比
較にならない。
本発明に用いる熱可塑性樹脂とは、熱可塑性をイＪ”す
る樹脂で、例えば
塩素含有樹脂として、ポリ塩化ビニル、塩素化ポリ塩化
ビニル、塩素化ポリエチレン、塩化ビニル／酢酸ビニル
共重合体及びそれら樹脂と他樹脂との共重合体並びにポ
リマーブレンド、
＝７−
ポリオレフィン樹脂としては、低密度ポリエチレン、高
密度ポリエチレン、直鎖低密度ポリエチレン、ポリプロ
ピレン及び樹脂相互、α−オレフィン又は他樹脂との共
重合体並びにポリマーブレンド。
各種のポリアミド樹脂及び他樹脂との共重合体並びにポ
リマーブレンド。
各種のポリエステル・樹脂及び他樹脂との共重合体並び
にポリマーブレンド。
各種のＡＢＳ樹脂及び他樹脂共重合体並びにポリマーブ
レンド。
各種のポリアセタール樹脂及び他樹脂との共重合体並び
にポリマーブレンド、その他各種エンジニアリングプラ
スチック類が挙げられる。
本発明組成物における塩基性金属石鹸の使用量は、熱可
塑性樹脂１００重量部に対して、０．０１〜５重量部で
、好ましくは０．０３〜３．０重量部である。
本発明の熱可塑性樹脂組成物には、」二記の塩基性金属
石鹸以外に必要な添加物、例えば可塑剤、充填剤、安定
剤、酸化防止剤（フェノール系、有機リン系等）、紫外
線吸収剤（ベゾトリアゾール系、ベンゾフェノン系、ヒ
ンダードアミン系）、顔料、滑剤、帯電防止剤、防曇剤
、難燃剤、抗菌剤、防黴剤、発泡剤、エポキシ化合物、
加工助剤等を適宜添加してもよい。The basic metal soap of the present invention is produced by heating an aliphatic monocarboxylic acid (hereinafter referred to as fatty acid) and an oxide or hydroxide of a metal of group Ⅰ of the periodic table (hereinafter referred to as metal inorganic compound). A type of known method for producing metal soaps obtained by direct reaction, the so-called dry direct method (also known as the melting method)
The basic metal soap of the present invention differs from known metal soaps in that while known metal soaps react with a fatty acid and a reaction equivalent amount of a metal inorganic compound, the basic metal soap of the present invention reacts with a fatty acid and a reaction equivalent amount of a metal inorganic compound. It is obtained by adding a metal inorganic compound in excess of the reaction equivalent and completely incubating the reaction product so that it becomes transparent, and the metal content, melting point, and acid value of the product are naturally different. be. The excess ratio of the metal content of the basic metal soap of the present invention is 0.
The amount is 1 to 1.0 mol, preferably 0.1 to 0.8. If it is less than 0.1 mol, there is not much difference in performance from conventional metal soaps, and if it is more than 1.0 mol, the melt of the product will not become transparent and unreacted metal inorganic compounds will remain, which is not preferable. The fatty acid that is the raw material for the basic metal soap of the present invention has 1 carbon number.
One or more natural or synthetic saturated or unsaturated monocarboxylic acids having from 2 to 30 L, which may have a side chain, hydroxyl group, ketone group, aldehyde group, eboxy group, etc. in the structure. Typical examples include lauric acid, myristic acid, palmitic acid, stearic acid, alagic acid, heptadecylic acid, behenic acid, oleic acid, and elaidin. Examples include erucic acid, linoleic acid, liluic acid, ricinoleic acid, hydroxystearic acid, montanic acid, isostearic acid, epoxystearic acid, and the like. Further, a part thereof may be replaced with a carboxylic acid or dicarboxylic acid other than the aliphatic monocarboxylic acid. The metal constituting the basic metal soap of the present invention is one or more metals of group Ⅰ of the periodic table, specifically ①a alkaline earth metals and nb zinc group metals, preferably Mg,
They are Ca and Zn. The thermoplastic resin composition of the present invention is a composition obtained by adding the above-mentioned basic metal soap to a thermoplastic resin, and exhibits moldability that cannot be obtained with conventional thermoplastic resin compositions containing metal soap. . That is, the metal soap of the present invention containing an excessive amount of metal has a melting point significantly higher than that of conventional metal soaps and soaps, as shown in the examples below, and therefore has a lubricating effect in thermoplastic resins molded at high temperatures. In addition, it can be expected to improve the mold release effect (1). In addition to the basic metal soaps produced by the direct dry method of the present invention, basic metal soaps can also be produced by the wet precipitation method.
When the basic metal soap produced by this wet precipitation method is thermally melted, the metal inorganic compound in the basic part is separated and a precipitate is formed. Furthermore, if basic metal soap produced by this wet precipitation method is added to a thermoplastic resin and molded, not only will the eye stain phenomenon in the mold not be improved at all, but on the contrary, it will cause problems on the screen. It has the disadvantage that clogging phenomenon occurs strongly and promotes trouble, and it cannot be compared in terms of performance with the basic metal soap of the present invention. The thermoplastic resin used in the present invention refers to a resin having good thermoplasticity, such as chlorine-containing resins such as polyvinyl chloride, chlorinated polyvinyl chloride, chlorinated polyethylene, vinyl chloride/vinyl acetate copolymers, and the like. Copolymers and polymer blends of resins and other resins, =7- Polyolefin resins include low-density polyethylene, high-density polyethylene, linear low-density polyethylene, polypropylene and copolymers with each other, α-olefin, or other resins. Coalescing and polymer blends. Copolymers and polymer blends of various polyamide resins and other resins. Copolymers and polymer blends of various polyester resins and other resins. Various ABS resins and copolymers of other resins, and polymers. Blends. Examples include various polyacetal resins and copolymers with other resins, polymer blends, and other various engineering plastics.The amount of basic metal soap used in the composition of the present invention is based on 100 parts by weight of the thermoplastic resin. , 0.01 to 5 parts by weight, preferably 0.03 to 3.0 parts by weight. For example, plasticizers, fillers, stabilizers, antioxidants (phenol-based, organic phosphorus-based, etc.), ultraviolet absorbers (bezotriazole-based, benzophenone-based, hindered amine-based), pigments, lubricants, antistatic agents, antifogging agents. , flame retardants, antibacterial agents, antifungal agents, foaming agents, epoxy compounds,
Processing aids and the like may be added as appropriate.
以下実施例をあげて本発明をさらに具体的に説明する。
実施例 １
ステアリン酸（ＮＶ−２００）１００ｇを１３０℃に加
熱し、撹拌しながら酸化亜鉛１６．７６ｇを徐々に加え
た後、温度を１５０℃ににげ、２０分間撹拌を続けて熔
解すると、透明な、亜鉛含有量１１．８６重量％、融点
１３０℃の、０．１５モルＺｎＯが過剰な塩基性ステア
リン酸亜鉛を得た。
参考までに、このステアリン酸のＮＶに対応する酸化亜
鉛で当量反応させたステアリン酸亜鉛の亜鉛含有量は１
０．４７重量％、融点は１２３℃であった。
一９＝
実施例 ２
１２−ヒドロキシステアリン酸（ＮＶ−１７９）１００
ｇを１２０℃に加熱後、撹拌しながら酸化マグネシウム
Ｉ Ｏ，０６ｇを徐々に加え、全量加え終わった後温度
を１６５℃に上げ、２０分間撹拌を続けて反応を完結し
、マグネシウム含有量５．８重量％、融点２２．８℃の
、熔解すると透明な、０．４４モルＭｇＯが過剰な塩基
性１２−ヒドロキシステアリン酸マグネシウムを得た。
参考までに、この１２−ヒドロキシステアリン酸のＮＶ
に対応する酸化マグネシウムで当量反応させた１２−ヒ
ドロキシステアリン酸マグネシウムのマグネシウム含有
量は３．７重量％、融点は１２３℃であった。
実施例 ３
ラウリン酸（ＮＶ＝２８０）１００ｇ７ｉｌ−１２５℃
に加熱し、撹拌しながら水酸化カルシウム２１．１０ｇ
を徐々に加え、温度を１７５℃まで上昇させ、２０分間
撹拌を続けて反応を完結させ、カルシウム含有量１０．
０３重槍形、融点１７１℃の、熔解すると透明な、０．
、、Ｉ Ｌ ５モルＣａＯが過剰な塩基性ラウリン酸カ
ルシウムを得た。
参考までに、ごのラウリン酸のＮＶに対応する水酸化カ
ルシウムで当量反応させたラウリン酸カルシウムのカル
シウム含有量は９．１３重量％、融点はＩ、５５℃であ
った。
実施例４
ベヘン酸（ＮＶ−１６７，２６）１００ｇを１３０℃に
加熱後、撹拌しながら酸化マグネシウム１１ｙ４５ｇを
徐々に加えて反応させ、徐々に温度を１−げて１７５℃
とする。熔解液が透明になるまで撹拌して反応を完結さ
せ、マグネシウム含有量６．３４重量％、融点２１０℃
の、０．８モルＭｇＯが過剰な塩基性ベヘン酸マグネシ
ウムを得た。
参考までに１．ごのベヘン酸のＮＶに対応する酸化マグ
ネシウムで当量反応させたベヘン酸マグネシウムのマグ
ネシウム含有量は３．１５重量％、融点は１１９℃であ
った。
実施例 ５
下記配合物を１６０℃に調節した６インチの試験ロール
で５分間混練し、０．３ｍｍ厚のシートを作成した。こ
のシートの一部を１７０℃に調節したギヤーオーブンに
入れ、熱安定性を比較し、残りのシートを１７０℃に調
節した熱プレスで５分間プレスし、１ｍｍ１’ノのシー
トに成形し、そのシートの透明性及び７０℃に調節した
恒温水槽中に２４時間浸漬した後の表面の吐出（浮き出
し）現象を観察した。その結果を表−１の評点で評価し
、表−２に示した。 ・
〈配合〉
ＰｖＣ（Ｐ・１０００） １００ 重量
部ＤＯＩ）（可塑剤） ４０ 〃エポ
キシ化大豆油 ２ 〃有機面リン酸エ
ステル ０．５ 〃ステアリン酸亜鉛
０．４ 〃金属石鹸（表−２）
０．６ ７表−１（評点）
表−２（実施例−５の結果）
実施例 ６
下記配合物を１８０℃に調節した試験ロールで７分間混
練し、０．５ｍｍ厚のシートを作成した。
このシートを２４０℃に調節した熱プレスで表−３に示
す各温度で熱プレスしてＩｎ＋ｎ＋厚のシートに成形し
、そのシートの着色度を東洋精機製ホトボルト反射率測
定器を用いて測定し、自席として表−３に記載した。こ
の数値は大きい程熱安定性が良い）
〈配合〉
ポリプロピレン（ＭＰＲ＝０．３） １００
重量部微粉末タルク ４３ 〃酸
化チタン ２ 〃イルガノック
ス１０１０ ０．０５／／金属石鹸（表−３）
’ ０．２ 〃〜１５一
実施例 ７
下記配合物を２６φｍｍＸＬ／Ｄ−１６．５の単軸押出
機（シリンダー温度：Ｃ，＝１５０℃、Ｃ９＝２１０℃
、ダイス温度：２３０℃、回転数：４０ｒｐｍ１スクリ
ーン：２００メツシュ、金型サイズ＝３０ ｍｍＸ ｌ
ｍｍ）で１２時間連続押出しを行い、金型へのＬ１ヤ
ニの付着量及びスクリーンへの［１詰まり、ｉｌｌを目
測するとともに、押出機のモーター負荷を記録した。そ
の結果を表−４に示す。
く配合〉
ポリプロピＬ／ ン（ＭＦＲ＝０．３） １００
重量部微粉末タルク ４３ 〃
酸化チタン ２ 〃イルガノッ
クス１０１０ ０．１ 〃ウルトラノックス
６２６ ０．０５〃金属石鹸（表−４）
０．３ 〃実施例 ８
下記配合物を１６０℃？こ調節した６インチの試験ロー
ルで８分間混練し、１．２ｍｍ厚のシートを作成した。
この時の試験ロールからの剥離性を観察し、表−５に示
した。このシートを２４０℃に調節した熱プレスで２分
間、５分間、１０分間の各時間で熱プレスし、それぞれ
１ｍｍ厚のシートに調製し、この熱変色したシートの白
色度を東洋精機製ホトポルト反射律測定機で測定し、そ
の結果を表−５に示す。
く配合〉
ＡＢＳ樹脂（ダイヤペット３００１ＭＴ（）１００ 重
量部The present invention will be explained in more detail below by giving examples. Example 1 100g of stearic acid (NV-200) was heated to 130°C, 16.76g of zinc oxide was gradually added while stirring, the temperature was lowered to 150°C, and stirring was continued for 20 minutes to melt. A clear basic zinc stearate with a zinc content of 11.86% by weight and a melting point of 130° C. with an excess of 0.15 mol ZnO was obtained. For reference, the zinc content of zinc stearate reacted equivalently with zinc oxide corresponding to the NV of stearic acid is 1
The content was 0.47% by weight, and the melting point was 123°C. 19 = Example 2 12-hydroxystearic acid (NV-179) 100
After heating 120°C of magnesium oxide to 120°C, 0.6g of magnesium oxide I2O was gradually added with stirring, and after the entire addition was completed, the temperature was raised to 165°C, stirring was continued for 20 minutes to complete the reaction, and the magnesium content was 5. A basic magnesium 12-hydroxystearate of 8% by weight, melting point 22.8 DEG C., transparent when melted, with an excess of 0.44 mol MgO was obtained. For reference, the NV of this 12-hydroxystearic acid
Magnesium 12-hydroxystearate, which was equivalently reacted with magnesium oxide corresponding to the above, had a magnesium content of 3.7% by weight and a melting point of 123°C. Example 3 Lauric acid (NV=280) 100g7il-125°C
21.10g of calcium hydroxide while stirring.
was gradually added, the temperature was increased to 175°C, stirring was continued for 20 minutes to complete the reaction, and the calcium content was 10.
03 double lance shape, melting point 171°C, transparent when melted, 0.
,,IL Basic calcium laurate with 5 mol CaO excess was obtained. For reference, calcium laurate, which was equivalently reacted with calcium hydroxide corresponding to the NV of lauric acid, had a calcium content of 9.13% by weight, a melting point of I, and 55°C. Example 4 After heating 100 g of behenic acid (NV-167,26) to 130°C, 45 g of magnesium oxide 11y was gradually added with stirring to react, and the temperature was gradually increased to 175°C.
shall be. The reaction was completed by stirring until the melt became transparent, and the magnesium content was 6.34% by weight and the melting point was 210°C.
A basic magnesium behenate with a 0.8 mol MgO excess was obtained. For reference 1. Magnesium behenate, which was equivalently reacted with magnesium oxide corresponding to the NV of behenic acid, had a magnesium content of 3.15% by weight and a melting point of 119°C. Example 5 The following formulation was kneaded for 5 minutes using a 6-inch test roll adjusted to 160°C to form a sheet with a thickness of 0.3 mm. A portion of this sheet was placed in a gear oven adjusted to 170°C to compare thermal stability, and the remaining sheet was pressed for 5 minutes in a heat press adjusted to 170°C to form a 1mm x 1' sheet. The transparency of the sheet and the ejection (embossment) phenomenon on the surface after being immersed in a constant temperature water bath adjusted to 70° C. for 24 hours were observed. The results were evaluated using the scores shown in Table-1 and shown in Table-2.・ <Formulation> PvC (P・1000) 100 Part by weight DOI) (plasticizer) 40 Epoxidized soybean oil 2 Organic phosphate ester 0.5 Zinc stearate
0.4 〃Metal soap (Table-2)
0.6 7 Table-1 (Rating) Table-2 (Results of Example-5) Example 6 The following formulation was kneaded for 7 minutes using a test roll adjusted to 180°C to create a 0.5 mm thick sheet. . This sheet was heat-pressed at each temperature shown in Table 3 using a heat press adjusted to 240°C to form a sheet with a thickness of In+n+, and the degree of coloration of the sheet was measured using a photovolt reflectance meter manufactured by Toyo Seiki. , is listed in Table 3 as my own seat. (The higher this value is, the better the thermal stability is.) <Formulation> Polypropylene (MPR=0.3) 100
Part by weight Finely powdered talc 43 Titanium oxide 2 Irganox 1010 0.05 // Metal soap (Table 3)
' 0.2 - 15 Example 7 The following formulation was heated in a 26φmm XL/D-16.5 single-screw extruder (cylinder temperature: C, = 150°C, C9 = 210°C
, die temperature: 230°C, rotation speed: 40 rpm 1 screen: 200 mesh, mold size = 30 mmX l
Continuous extrusion was carried out for 12 hours at 1 mm), and the amount of L1 tar attached to the mold and the amount of clogging and ill on the screen were visually measured, and the motor load of the extruder was recorded. The results are shown in Table-4. Blend> Polypropylene L/N (MFR=0.3) 100
Part by weight Finely powdered talc 43
Titanium oxide 2 Irganox 1010 0.1 Ultranox 626 0.05 Metal soap (Table 4)
0.3 〃Example 8 The following formulation was heated to 160℃? The mixture was kneaded for 8 minutes using a 6-inch test roll adjusted in this manner to form a sheet with a thickness of 1.2 mm. The peelability from the test roll at this time was observed and is shown in Table 5. This sheet was heat-pressed in a heat press adjusted to 240°C for 2 minutes, 5 minutes, and 10 minutes to prepare sheets with a thickness of 1 mm. The results are shown in Table 5. Blend> ABS resin (Diapet 3001MT () 100 parts by weight
Claims (1)
は水酸化物とを加熱直接反応させて得られ、かつ理論計
算量より過剰な金属含有量を有することを特徴とする周
期率表第II族の金属石鹸。 ２、金属含有量の過剰率が、０．１〜１．０モルの範囲
である特許請求の範囲第１項の金属石鹸。 ３、金属石鹸を構成する金属が、Ｍｇ、Ｃａ、Ｓｒ、ま
たはＺｎから選ばれた金属の１種以上である特許請求の
範囲第１項の金属石鹸。 ４、金属石鹸を構成するカルボン酸が、炭素数１２〜３
０の脂肪族モノカルボン酸から選ばれたカルボン酸の１
種以上である特許請求の範囲第１項の金属石鹸。 ５、熱可塑性樹脂１００重量部に対し、特許請求の範囲
第１項〜第４項のいずれかに記載された金属石鹸の１種
以上を０．０１〜５重量部添加した熱可塑性樹脂組成物
。 ６、熱可塑性樹脂が塩素含有樹脂である特許請求の範囲
第５項の熱可塑性樹脂組成物。 ７、熱可塑性樹脂がポリオレフィン樹脂である特許請求
の範囲第５項の熱可塑性樹脂組成物。 ８、熱可塑性樹脂がＡＢＳ樹脂である特許請求の範囲第
５項の熱可塑性樹脂組成物。[Claims] 1. Obtained by directly heating and reacting an aliphatic carboxylic acid with an oxide or hydroxide of a Group II metal in the periodic table, and having a metal content in excess of the theoretically calculated amount. A metal soap from Group II of the periodic table, characterized by: 2. The metal soap according to claim 1, wherein the excess metal content is in the range of 0.1 to 1.0 mol. 3. The metal soap according to claim 1, wherein the metal constituting the metal soap is one or more metals selected from Mg, Ca, Sr, or Zn. 4. The carboxylic acid constituting the metal soap has 12 to 3 carbon atoms.
1 of the carboxylic acids selected from 0 aliphatic monocarboxylic acids
The metal soap according to claim 1, which is more than 100% of the metal soap. 5. A thermoplastic resin composition in which 0.01 to 5 parts by weight of one or more metal soaps described in any of claims 1 to 4 are added to 100 parts by weight of the thermoplastic resin. . 6. The thermoplastic resin composition according to claim 5, wherein the thermoplastic resin is a chlorine-containing resin. 7. The thermoplastic resin composition according to claim 5, wherein the thermoplastic resin is a polyolefin resin. 8. The thermoplastic resin composition according to claim 5, wherein the thermoplastic resin is an ABS resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2335537A JPH0729975B2 (en) | 1990-11-30 | 1990-11-30 | Metal soap and thermoplastic resin composition containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2335537A JPH0729975B2 (en) | 1990-11-30 | 1990-11-30 | Metal soap and thermoplastic resin composition containing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04208246A true JPH04208246A (en) | 1992-07-29 |
| JPH0729975B2 JPH0729975B2 (en) | 1995-04-05 |
Family
ID=18289685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2335537A Expired - Lifetime JPH0729975B2 (en) | 1990-11-30 | 1990-11-30 | Metal soap and thermoplastic resin composition containing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0729975B2 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304980A (en) * | 1991-01-24 | 1994-04-19 | Mitsubishi Denki Kabushiki Kaisha | Distance detecting apparatus for a vehicle |
| JP2000290457A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2000290455A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2000290456A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2008019447A (en) * | 2007-08-31 | 2008-01-31 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2011005770A (en) * | 2009-06-26 | 2011-01-13 | Nippon Synthetic Chem Ind Co Ltd:The | Purging agent and purging method |
| JP2013138724A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138722A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138723A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138726A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Multi-piece golf ball |
| JP2013138725A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Multi-piece golf ball |
| JP2013236878A (en) * | 2012-05-17 | 2013-11-28 | Dunlop Sports Co Ltd | Golf ball |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55136244A (en) * | 1979-04-04 | 1980-10-23 | Chem Ueruke Miyunhen Otsutoo B | Manufacture of metal soap |
| JPS6471836A (en) * | 1987-08-28 | 1989-03-16 | Henkel Kgaa | Continuous manufacture of fatty acid soap |
-
1990
- 1990-11-30 JP JP2335537A patent/JPH0729975B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55136244A (en) * | 1979-04-04 | 1980-10-23 | Chem Ueruke Miyunhen Otsutoo B | Manufacture of metal soap |
| JPS6471836A (en) * | 1987-08-28 | 1989-03-16 | Henkel Kgaa | Continuous manufacture of fatty acid soap |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304980A (en) * | 1991-01-24 | 1994-04-19 | Mitsubishi Denki Kabushiki Kaisha | Distance detecting apparatus for a vehicle |
| JP2000290457A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2000290455A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2000290456A (en) * | 1999-04-06 | 2000-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2008019447A (en) * | 2007-08-31 | 2008-01-31 | Nippon Synthetic Chem Ind Co Ltd:The | Resin composition and laminate |
| JP2011005770A (en) * | 2009-06-26 | 2011-01-13 | Nippon Synthetic Chem Ind Co Ltd:The | Purging agent and purging method |
| JP2013138723A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138722A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138724A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Golf ball resin composition and golf ball |
| JP2013138726A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Multi-piece golf ball |
| JP2013138725A (en) * | 2011-12-28 | 2013-07-18 | Dunlop Sports Co Ltd | Multi-piece golf ball |
| US9221927B2 (en) | 2011-12-28 | 2015-12-29 | Dunlop Sports Co. Ltd. | Golf ball resin composition and golf ball |
| US9345933B2 (en) | 2011-12-28 | 2016-05-24 | Dunlop Sports Co. Ltd. | Multi-piece golf ball |
| US9345932B2 (en) | 2011-12-28 | 2016-05-24 | Dunlop Sports Co. Ltd. | Multi-piece golf ball |
| US9346898B2 (en) | 2011-12-28 | 2016-05-24 | Dunlop Sports Co. Ltd. | Golf ball resin composition and golf ball |
| US9353199B2 (en) | 2011-12-28 | 2016-05-31 | Dunlop Sports Co. Ltd. | Golf ball resin composition and golf ball |
| JP2013236878A (en) * | 2012-05-17 | 2013-11-28 | Dunlop Sports Co Ltd | Golf ball |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0729975B2 (en) | 1995-04-05 |
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