JPH04174771A - Coated polyester web and preparation thereof - Google Patents
Coated polyester web and preparation thereofInfo
- Publication number
- JPH04174771A JPH04174771A JP29859190A JP29859190A JPH04174771A JP H04174771 A JPH04174771 A JP H04174771A JP 29859190 A JP29859190 A JP 29859190A JP 29859190 A JP29859190 A JP 29859190A JP H04174771 A JPH04174771 A JP H04174771A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- polyester fiber
- coated
- coated fabric
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title description 5
- 239000004744 fabric Substances 0.000 claims abstract description 37
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000000835 fiber Substances 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 239000011342 resin composition Substances 0.000 claims abstract description 10
- 125000002524 organometallic group Chemical group 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 150000002899 organoaluminium compounds Chemical class 0.000 claims 1
- 239000000975 dye Substances 0.000 abstract description 10
- 238000013508 migration Methods 0.000 abstract description 9
- 230000005012 migration Effects 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000986 disperse dye Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- PBHKZGYWHVXIRY-UHFFFAOYSA-K aluminum 2,2-diacetyl-3-oxobutanoate Chemical compound [Al+3].CC(=O)C(C(C)=O)(C(C)=O)C([O-])=O.CC(=O)C(C(C)=O)(C(C)=O)C([O-])=O.CC(=O)C(C(C)=O)(C(C)=O)C([O-])=O PBHKZGYWHVXIRY-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- -1 dimethyl fluorite Chemical compound 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000002370 organoaluminium group Chemical group 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- JTQPTNQXCUMDRK-UHFFFAOYSA-N propan-2-olate;titanium(2+) Chemical compound CC(C)O[Ti]OC(C)C JTQPTNQXCUMDRK-UHFFFAOYSA-N 0.000 description 1
- UZXWWAFGEOYBQG-UHFFFAOYSA-N propan-2-olate;zirconium(2+) Chemical compound CC(C)O[Zr]OC(C)C UZXWWAFGEOYBQG-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明はポリエステル繊維コーティング布帛およびその
製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a polyester fiber coated fabric and a method for producing the same.
［従来の技術］
従来よりナイロン繊維やポリエステル繊維等の合成繊維
の織物や編物等にポリアクリル系樹脂、ポリ塩化ビニル
系樹脂、ポリウレタン系樹脂等の樹脂をコーティング加
工したコーティング布帛があり、衣料、傘、帆布、テン
ト等の用途に使用されている。[Prior Art] There have been coated fabrics in which woven or knitted fabrics made of synthetic fibers such as nylon fibers and polyester fibers are coated with resins such as polyacrylic resins, polyvinyl chloride resins, and polyurethane resins. It is used for umbrellas, canvas, tents, etc.
［発明が解決しようとする課題］
しかし、ナイロン繊維の樹脂コーティング布帛では特に
問題はないが、分散染料で染色したポリエステル繊維の
場合、繊維内の染料がコーティング樹脂層へ移行し、さ
らに濃色のコーティング布帛と淡色または白色のコーテ
ィング布帛のコーテイング面が接触すると濃色側の染料
が淡色または白色のコーテイング面へ移行し、著しく汚
染するという問題がある。[Problems to be solved by the invention] However, while there is no particular problem with resin-coated fabrics made of nylon fibers, in the case of polyester fibers dyed with disperse dyes, the dye in the fibers migrates to the coating resin layer, resulting in an even darker color. When the coated fabric and the coated surface of a light-colored or white coated fabric come into contact, there is a problem in that the dye on the dark-colored side migrates to the light-colored or white coated surface, resulting in significant staining.
口課題を解決するための手段］
本発明者らは染料移行性のない、かつ製造方法の容易な
ポリエステル繊維コーティング布帛およびその製造方法
を鋭意検討した結果本発明に到達した。[Means for Solving the Problems] The present inventors have arrived at the present invention as a result of intensive studies on a polyester fiber coated fabric that does not have dye migration and is easy to manufacture, and a method for manufacturing the same.
すなわち本発明はポリエステル繊維基材に樹脂と有機金
属配位化合物を含有する樹脂組成物をコーティングして
なることを特徴とするポリエステエステル繊維コーティ
ング布帛の製造方法である。That is, the present invention is a method for producing a polyester fiber coated fabric, which is characterized by coating a polyester fiber base material with a resin composition containing a resin and an organometallic coordination compound.
本発明において使用するポリエステル繊維基材としては
ポリエステル繊維単一の織物、編物、不織布はもとより
、ポリニス、チル繊維を必須とする混紡、混繊、混繊、
混編等いずれに対しても可能であり、特に限定されるも
のではない。The polyester fiber base materials used in the present invention include not only woven fabrics, knitted fabrics, and non-woven fabrics made of polyester fibers, but also polyvarnish, blended fabrics, blended fibers, and blended fabrics that require chilled fibers.
Mixed knitting and the like are also possible, and are not particularly limited.
また本発明においてポリエステル繊維基材の染色は、特
に限定された分散染料、または特別な染色条件を必要と
するものではなく、通常の分散染料でキャリヤー染色や
高温染色等通常に染色されたものを使用できる。Furthermore, in the present invention, dyeing of the polyester fiber base material does not require particularly limited disperse dyes or special dyeing conditions, but rather dyeing of polyester fiber base materials that are normally dyed with ordinary disperse dyes such as carrier dyeing or high temperature dyeing. Can be used.
また本発明において使用されるポリエステル繊維基材は
予めカレンダーロールで熱処理したものやシリコーン系
あるいは弗素系のはっ油はっ水剤で処理したもの等も使
用できる。Furthermore, the polyester fiber base material used in the present invention may be one that has been heat-treated with a calendar roll, or one that has been treated with a silicone-based or fluorine-based oil- and water-repellent agent.
本発明において使用する該樹脂としてはポリウレタン系
樹脂、ポリアクリル系樹脂、ポリ塩化ビニル系樹脂、ポ
リ酢酸ビニル系樹脂、シリコーン系樹脂およびこれらの
２種以上の混合物、共重合物等が挙げられる。このうち
好いものはポリウレタン系樹脂、ポリアクリル系樹脂お
よびこれらの混合物あるいは共重合物である。Examples of the resin used in the present invention include polyurethane resins, polyacrylic resins, polyvinyl chloride resins, polyvinyl acetate resins, silicone resins, and mixtures and copolymers of two or more of these resins. Among these, preferred are polyurethane resins, polyacrylic resins, and mixtures or copolymers thereof.
ポリウレタン系樹脂としては高分子ジオールと有機ジイ
ソシアネートと低分子量の鎖伸長剤（例エバエチレング
リコール、エチレンジアミン等）からのポリウレタン樹
脂等が挙げられるポリアクリル系樹脂としてはメタアク
リル酸、メチルメタアク７ル−ト、ｎ−ブチルメタアク
リレート等メタアクリル系モノマーの１種もしくは２種
以上の重合体もしくはこれらとメタアクリル系モノマー
と他の共重合可能なビニル系モノマーとの共重合体が挙
げられる。Examples of polyurethane resins include polyurethane resins made from polymeric diols, organic diisocyanates, and low molecular weight chain extenders (e.g., evaporated ethylene glycol, ethylene diamine, etc.) Examples of polyacrylic resins include methacrylic acid, methyl methacrylate, etc. , a polymer of one or more methacrylic monomers such as n-butyl methacrylate, or a copolymer of these, a methacrylic monomer, and another copolymerizable vinyl monomer.
また、コーティング樹脂層が単一層であっても、多層構
造であってもよい、多層構造の場合は少なくとも一層が
本発明の樹脂組成物コーティング層であればよい。この
多層構造のものを例示するとポリエステルｍ維とポリウ
レタン樹脂層との間にポリウレタン樹脂の含浸を抑制す
る目止め効果を目的としたアクリル樹脂層を有する多層
構造としたものが挙げられる。Further, the coating resin layer may be a single layer or may have a multilayer structure, and in the case of a multilayer structure, at least one layer may be a coating layer of the resin composition of the present invention. An example of this multilayer structure is one having an acrylic resin layer between the polyester m fibers and the polyurethane resin layer for the purpose of sealing effect to suppress impregnation of the polyurethane resin.
を機金属配位化合物としてはアルミニウムトリスアセチ
ルアセトネート、アルミニウムトリイソプロポキシドな
どのを機アルミニウム配位化合物、ジルコニウムテトラ
キスアセチルアセトネート、ジイソプロポキシジルコニ
ウムビスアセチルアセトネートなどの有機ジルコニウム
配位化合物、チタンテトラキスアセチルアセトネート、
ジイソプロポキシチタンビスアセチルアセトネートなど
の有機チタン配位化合物； これらの２種以上の混合物
等が挙げられる。これらのうち好ましいのは有機アルミ
ニウム配位化合物および有機ジルコニウム配位化合物で
ある。The metal coordination compounds include aluminum coordination compounds such as aluminum trisacetylacetonate, aluminum triisopropoxide, organic zirconium coordination compounds such as zirconium tetrakisacetylacetonate, diisopropoxyzirconium bisacetylacetonate, titanium tetrakis acetylacetonate,
Organic titanium coordination compounds such as diisopropoxytitanium bisacetylacetonate; mixtures of two or more of these, and the like. Among these, preferred are organoaluminium coordination compounds and organozirconium coordination compounds.
本発明における有機金属配位化合物の該樹脂組成物中の
含有量は樹脂固形分重量に対して通常０゜５〜３０％、
好ましくは１〜２０％である。０．５％未満では染料移
行の抑制効果が乏しい。３０％を越えると被膜表面に析
出して外観が悪くなる。The content of the organometallic coordination compound in the resin composition in the present invention is usually 0.5 to 30% based on the solid weight of the resin.
Preferably it is 1 to 20%. If it is less than 0.5%, the effect of suppressing dye migration is poor. If it exceeds 30%, it will precipitate on the surface of the coating, resulting in poor appearance.
本発明における樹脂組成物中へは必要により耐候性、耐
熱劣化向上のための各種安定剤や多官能インシアネート
等の架橋剤、着色剤、無機充填剤、有機改質剤、その他
の添加剤等を含有させることができる。In the resin composition of the present invention, various stabilizers and crosslinking agents such as polyfunctional incyanate, colorants, inorganic fillers, organic modifiers, and other additives may be added to improve weather resistance and heat deterioration resistance, if necessary. can be contained.
本発明において該樹脂組成物は以上例示した各成分を含
有する溶剤溶液または水分散液である。In the present invention, the resin composition is a solvent solution or an aqueous dispersion containing the components listed above.
この溶剤としてはケトン（アセトン、メチルエチルケト
ン、メチルイソブチルケトン等）、エステル（酢酸エチ
ル、酢酸ブチル等）、エーテル（テトラハイドロフラン
等）、芳香族炭化水素（トルエン、キシレン等）アミド
（ジメチルホルムアミド、ジメチルアセトアミド等）、
スルホキサイド（ジメチルスルホキサイド等）、アルコ
ール（エタノール、イソプロピルアルコール等）および
これらの２ｍ以上の混合溶剤が挙げられる。Examples of this solvent include ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, etc.), esters (ethyl acetate, butyl acetate, etc.), ethers (tetrahydrofuran, etc.), aromatic hydrocarbons (toluene, xylene, etc.), amides (dimethylformamide, dimethyl acetamide, etc.),
Examples include sulfoxide (dimethyl sulfoxide, etc.), alcohol (ethanol, isopropyl alcohol, etc.), and a mixed solvent of 2 m or more of these.
また樹脂組成物の濃度は通常５〜５０％、好ましくは１
０〜４５％である。Further, the concentration of the resin composition is usually 5 to 50%, preferably 1
It is 0-45%.
次に本発明のコーティング布帛の製造方法を例示する。Next, a method for manufacturing the coated fabric of the present invention will be illustrated.
前記に例示した樹脂組成物を前記ポリエステル繊維基材
に通常の方法でコーティング加工することができる。The resin composition exemplified above can be coated onto the polyester fiber base material by a conventional method.
コーティング方法としては特に限定されるものではなく
通常の方法で加工することができる。The coating method is not particularly limited, and any conventional method can be used.
例えば、ポリエステル繊維基材に直接コーティングし、
乾燥させる直接コーティング方法や離型紙に樹脂被膜を
形成させた後、接着剤を塗布し、ポリエステル繊維基祠
と貼合わせ、乾燥後、離型紙より剥す転写コーティング
方法等が挙げられる。For example, by directly coating a polyester fiber base material,
Examples include a direct coating method in which the film is dried, and a transfer coating method in which a resin film is formed on a release paper, an adhesive is applied, the adhesive is bonded to a polyester fiber base, and after drying, it is peeled off from the release paper.
本発明におけるコーティング樹脂の被膜厚みは通常１〜
２００μｍ１ 好ましくは１０〜１００μｍである。The film thickness of the coating resin in the present invention is usually 1~
200 μm 1 Preferably 10 to 100 μm.
被膜の厚みカ月μｍ未満では染料移行の抑制効果が少な
いことや防水性が不十分である、また２００μｍを越え
るとコーティング布帛の風合いが硬くなり好ましくない
。If the thickness of the coating is less than 1 μm, the effect of suppressing dye migration will be small and the waterproofness will be insufficient, and if it exceeds 200 μm, the texture of the coated fabric will become hard, which is undesirable.
（実施例）
以下、実施例により本発明を説明するが、本発明はこれ
に限定されるものではない。実施例および比較例中の部
は重量部、％は重量％を表す。(Example) The present invention will be described below with reference to Examples, but the present invention is not limited thereto. In Examples and Comparative Examples, parts represent parts by weight, and % represents weight %.
実施例および比較例で使用したを機金属配位化合物およ
び樹脂は次のとおりである。The metal coordination compounds and resins used in Examples and Comparative Examples are as follows.
（１）有機金属配位化合物
ＡＩ−ＡＡ： アルミニウムトリスアセチルアセテート
Ｚｒ−ＡＡ： ジルコニウムテトラキスアセチルアセ
トネート
（２）樹脂
ポリウレタン樹脂
（ｔンブレンＬＱ−３１９０： 三洋化成工業（株）社
製ポリエステル系ホ“リウレタン樹脂溶液）樹脂固形分
＝３０％
シ゛メチルホルムアミド° ： ４０％トルエン
＝ ３０％ポリアクリル樹脂
（バラ’＋Ｄ：／ＳＳ〜２５００＋ 机上工業（株）社
製ボリフ゛チルメタアクリレート系樹脂溶液）樹脂固形
分＝１９％
トルエン ＝ ８１％
また、実施例中の染料移行汚染堅牢性の評価は次の方法
にしたがって行った。(1) Organometallic coordination compound AI-AA: Aluminum trisacetylacetate Zr-AA: Zirconium tetrakisacetylacetonate (2) Resin polyurethane resin (tombrene LQ-3190: Polyester resin manufactured by Sanyo Chemical Industries, Ltd.) Urethane resin solution) Resin solid content = 30% Methylformamide: 40% toluene
= 30% polyacrylic resin (Bara'+D:/SS~2500+ polybutyl methacrylate resin solution manufactured by Kekko Kogyo Co., Ltd.) Resin solid content = 19% Toluene = 81% Also, fastness to dye migration staining in Examples Evaluation of gender was performed according to the following method.
試験片（５ｃｍＸ ５ｃｍ）のコーテイング面とポリエ
ステル添付白布（試験片と同一の生地にホ゛リウレタン
樹脂１５重量％とジメチルホＩｌｌムアニト°８５重量
％からの溶剤溶液をコーティング゛し、水中に浸漬し、
凝固させ、のち水洗、乾燥したもの、５ｃｍ Ｘ ５ｃ
ｍ）のコーテイング面が接触するように、ガラス板２枚
の間にはさみ、１ｋｇの荷重をかけて恒温乾燥機８０°
Ｃ±３°Ｃ中で２時間、工００°Ｃ±３°Ｃ中で２時間
、各々放置し、放冷後、試験片から添付白布への染料移
行状態を汚染用グレースケールで等級判定を行った。
なお、実施例、比較例の結果は第１表にまとめ示した
。The coated surface of a test piece (5 cm x 5 cm) and a polyester-attached white cloth (the same fabric as the test piece were coated with a solvent solution of 15% by weight of polyurethane resin and 85% by weight of dimethyl fluorite, immersed in water,
Solidified, washed with water and dried, 5cm x 5c
Place the plate between two glass plates so that the coated surfaces of (m) are in contact with each other, and place in a constant temperature dryer at 80° with a load of 1 kg.
The samples were left for 2 hours at ℃±3℃ and 2 hours at 00℃±3℃, and after cooling, the state of dye transfer from the test piece to the attached white cloth was graded using a gray scale for contamination. went.
The results of Examples and Comparative Examples are summarized in Table 1.
実施例ま
たて糸５０デニール、よこ糸７５デニールのポリエステ
ルフィラメント糸使い平織物を分散染料Ｒｅｓ。Example: A plain woven fabric using polyester filament yarn with a warp yarn of 50 denier and a weft yarn of 75 denier was dyed with Res.
１１ｎｅＢｌｕｅＦ Ｂ Ｌ ３％０ 、 Ｗ 、ｆ
、 温度１３０℃で８０分間染色し、通常の洗浄を行
い、乾燥後１８０ ’Ｃのヒートセットを行ってコーテ
ィング用染色布を得た。11neBlueF B L 3%0, W, f
, dyed at a temperature of 130°C for 80 minutes, washed normally, and after drying, heat set at 180'C to obtain a dyed fabric for coating.
次にポリウレタン樹脂１００部とトルエン２５部とＡＩ
−ＡＡ １．８部（樹脂固形分に対して６％）を均一に
混合した調整液をナイフコーターで厚さ約７０μｍコー
ティングし、Ｉ００’Ｃで５分乾燥し、コーティング布
帛を得た。得られたコーティング布帛の樹脂層の膜厚み
は１５μｍであった。これを用いて試験片とした。Next, 100 parts of polyurethane resin, 25 parts of toluene and AI
A preparation solution in which 1.8 parts of -AA (6% based on resin solid content) was uniformly mixed was coated with a knife coater to a thickness of about 70 μm, and dried at I00'C for 5 minutes to obtain a coated fabric. The thickness of the resin layer of the obtained coated fabric was 15 μm. This was used as a test piece.
比較例１
実施例１で得た染色布にポリウレタン樹脂ｉｏｏ部とト
ルエン２５部を均一に混合した調整液を実施例１と同様
の方法でコーティング、乾燥し、コーティング布帛を得
た。Comparative Example 1 The dyed fabric obtained in Example 1 was coated with a conditioning solution prepared by uniformly mixing ioo parts of polyurethane resin and 25 parts of toluene, and dried in the same manner as in Example 1 to obtain a coated fabric.
実施例２
実施例１と同様に、ポリウレタン樹脂１００部とトルエ
ン２５部とメチルエチルケトン２５部とＺｒ−ＡＡ １
．２部（樹脂固形分に対して４％）を均一に混合した調
整液をナイフコーターで厚さ約１００μｍコーティング
し、１００°Ｃで５分乾燥し、コーティング布帛を得た
。得られたコーティング布帛の樹脂層の膜厚みは２０μ
ｍであった。Example 2 As in Example 1, 100 parts of polyurethane resin, 25 parts of toluene, 25 parts of methyl ethyl ketone, and 1 part of Zr-AA were added.
．． A mixture of 2 parts (4% based on the resin solid content) of the preparation solution was coated with a knife coater to a thickness of about 100 μm, and dried at 100° C. for 5 minutes to obtain a coated fabric. The thickness of the resin layer of the obtained coated fabric was 20μ.
It was m.
比較例２
実施例２と同様の方法で、ポリウレタン樹脂１００部と
トルエン２５部とメチルエチルケトン２５部を均一に混
合した調整液を実施例２と同様の方法で、コーティング
、乾燥しコーティング布帛を得た。Comparative Example 2 In the same manner as in Example 2, a preparation solution prepared by uniformly mixing 100 parts of polyurethane resin, 25 parts of toluene, and 25 parts of methyl ethyl ketone was coated and dried in the same manner as in Example 2 to obtain a coated fabric. .
１１一
実施例３
実施例２と同様の方法で、ポリアクリル樹脂１００部と
トルエン１０部とメチルエチルケトン１ｏ部とＡ Ｉ
−ＡＡ ０．５７部（樹脂固形分に対して３％）と脂肪
族系多官能イソシアネート（住友ハ゛イエＩ′ｙ社製ヌ
ミジユールＮ−７５） １部とを均一に混合した調整液
をナイフコーターで約１００μｍコーティングし、１０
０℃で５分乾燥し、コーティング布帛を得た。得られた
コーティング布帛の樹脂層の膜厚みは１５μｍであった
。11-Example 3 In the same manner as in Example 2, 100 parts of polyacrylic resin, 10 parts of toluene, 1 part of methyl ethyl ketone, and A
- A preparation solution made by uniformly mixing 0.57 parts of AA (3% based on the resin solid content) and 1 part of an aliphatic polyfunctional isocyanate (Numiyur N-75 manufactured by Sumitomo Hygiene Co., Ltd.) was prepared using a knife coater. Approximately 100 μm coating, 10
It was dried at 0°C for 5 minutes to obtain a coated fabric. The thickness of the resin layer of the obtained coated fabric was 15 μm.
比較例３
Ａ Ｉ−ＡＡを使わないこと以外は実施例３と同様の方
法でコーティング布帛を得た。Comparative Example 3 A coated fabric was obtained in the same manner as in Example 3 except that AI-AA was not used.
表−１
を機金属 使用樹脂 移行汚染
配位 堅牢度（級）
化合物 □
８０℃ １００ ’Ｃ
実施例 １／ ＡＩ−ＡＡ ホ“リウ
レタン ４−５ ４樹脂
比較例１ − 同上 ２１実施例２ Ｚ
ｒ−ＡＡ 同上 ４３−４比較例２ −
同上 ２１実施例 ３ Ａｔ−ＡＡ
ポリアクリル ４３樹脂
比較例３ − 同上 ２１表−１から明ら
かなように、本発明は高い移行汚染堅牢度を示した。こ
れに対して比較例は移行汚染堅牢性が劣り実用性に乏し
いものであった。Table-1 Metal used Resin Migration contamination coordination Fastness (grade) Compound □ 80℃ 100'C Example 1/ AI-AA Polyurethane 4-5 4 Resin Comparative Example 1 - Same as above 21 Example 2 Z
r-AA Same as above 43-4 Comparative Example 2 -
Same as above 21 Example 3 At-AA
Polyacrylic 43 Resin Comparative Example 3 - Same as above 21 As is clear from Table 1, the present invention exhibited high migration stain fastness. On the other hand, the comparative example had poor transfer stain fastness and was poor in practical use.
［発明の効果コ
本発明のポリエステル繊維コーティング布帛は従来のも
のに比べ染料移行が抑制され、汚染防止が著しく向上す
る。[Effects of the Invention] The polyester fiber coated fabric of the present invention suppresses dye migration and significantly improves stain prevention compared to conventional fabrics.
また、本発明のポリエステル繊維コーティング布帛は風
合いが柔らかく、良好な耐水性を示す。Furthermore, the polyester fiber coated fabric of the present invention has a soft feel and exhibits good water resistance.
上記効果を奏することから本発明のポリエステル繊維コ
ーティング布帛は衣料用、車用、帆布用テント用等に好
適である。Because of the above effects, the polyester fiber coated fabric of the present invention is suitable for use in clothing, cars, canvas tents, and the like.
一方製造方法においても、通常の方法で製造でき有用で
ある。On the other hand, as for the manufacturing method, it can be manufactured by a normal method and is useful.
Claims (1)
を含有する樹脂組成物をコーティングしてなることを特
徴とするポリエステル繊維コーティング布帛。 ２、有機金属配位化合物の量が該樹脂の重量に対して０
．５〜３０％である請求項１記載のポリエステル繊維コ
ーティング布帛。 ３、有機金属配位化合物が有機アルミニウム化合物およ
び／または有機ジルコニウム化合物である請求項１また
は２記載のポリエステル繊維コーティング布帛。 ４、樹脂がポリウレタン系樹脂および／またはポリアク
リル系樹脂である請求項１〜３の何れか記載のポリエス
テル繊維コーティング布帛。 ５、請求項１〜４のいずれか記載の樹脂組成物によりポ
リエステル繊維基材をコーティング加工することを特徴
とするポリエステル繊維コーティング布帛の製造方法。[Scope of Claims] 1. A polyester fiber coated fabric characterized by coating a polyester fiber base material with a resin composition containing a resin and an organometallic coordination compound. 2. The amount of organometallic coordination compound is 0 relative to the weight of the resin.
．． The polyester fiber coated fabric according to claim 1, which has a content of 5 to 30%. 3. The polyester fiber coated fabric according to claim 1 or 2, wherein the organometallic coordination compound is an organoaluminium compound and/or an organozirconium compound. 4. The polyester fiber coated fabric according to any one of claims 1 to 3, wherein the resin is a polyurethane resin and/or a polyacrylic resin. 5. A method for producing a polyester fiber coated fabric, which comprises coating a polyester fiber base material with the resin composition according to any one of claims 1 to 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2298591A JPH0830305B2 (en) | 1990-11-01 | 1990-11-01 | Polyester fiber coated fabric and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2298591A JPH0830305B2 (en) | 1990-11-01 | 1990-11-01 | Polyester fiber coated fabric and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04174771A true JPH04174771A (en) | 1992-06-22 |
| JPH0830305B2 JPH0830305B2 (en) | 1996-03-27 |
Family
ID=17861723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2298591A Expired - Lifetime JPH0830305B2 (en) | 1990-11-01 | 1990-11-01 | Polyester fiber coated fabric and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0830305B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07316982A (en) * | 1994-05-24 | 1995-12-05 | Kanebo Ltd | Coating-processed fabric without dye migrating property |
| US5773372A (en) * | 1993-02-15 | 1998-06-30 | Toray Industries, Inc. | Coated polyester fiber fabric and a production process therefor |
| US20110132538A1 (en) * | 2008-05-09 | 2011-06-09 | Robert Graham Bonney | Label |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491893A (en) * | 1972-04-26 | 1974-01-09 |
-
1990
- 1990-11-01 JP JP2298591A patent/JPH0830305B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491893A (en) * | 1972-04-26 | 1974-01-09 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5773372A (en) * | 1993-02-15 | 1998-06-30 | Toray Industries, Inc. | Coated polyester fiber fabric and a production process therefor |
| JPH07316982A (en) * | 1994-05-24 | 1995-12-05 | Kanebo Ltd | Coating-processed fabric without dye migrating property |
| US20110132538A1 (en) * | 2008-05-09 | 2011-06-09 | Robert Graham Bonney | Label |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0830305B2 (en) | 1996-03-27 |
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