JPH04168228A - Method for annealing dead soft steel strip - Google Patents

Method for annealing dead soft steel strip

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Publication number
JPH04168228A
JPH04168228A JP29512890A JP29512890A JPH04168228A JP H04168228 A JPH04168228 A JP H04168228A JP 29512890 A JP29512890 A JP 29512890A JP 29512890 A JP29512890 A JP 29512890A JP H04168228 A JPH04168228 A JP H04168228A
Authority
JP
Japan
Prior art keywords
coil
annealing
inner cover
steel strip
hydrogen gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29512890A
Other languages
Japanese (ja)
Inventor
Yasuhiko Shimatani
康彦 嶋谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP29512890A priority Critical patent/JPH04168228A/en
Publication of JPH04168228A publication Critical patent/JPH04168228A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To remarkably reduce the temp. difference of the coil of a dead soft steel strip being annealed in its radial direction and to prevent the burning of the coil periphery due to the over-heating at the time of annealing the coil in a tight annealing furnace by using an almost 100% hydrogen gas atmosphere as the atmosphere in the furnace. CONSTITUTION:The coil 1 of a dead soft steel strip contg. <0.006wt.% C are placed on one another in plural stages in a bell-type tight annealing furnace, the coils are covered with an inner cover 2 and further with a heating bell 3, a 100% hydrogen gas is introduced into the inner cover 2, and the coil 1 is heated by a plural-stage burner 4 through the inner cover 2 and the hydrogen gas in the cover and annealed. Since the hydrogen gas in the inner cover has high heat conductivity, the periphery and inner periphery of the coil 1 are uniformly heated, hence the coil is uniformly annealed with a less temp. difference, the coil periphery close to the inner cover 2 is not overheated, and the coil is never burned or flawed.

Description

【発明の詳細な説明】 産業上の利用分野 この発明は、タイト焼鈍炉において、極低炭素鋼帯をほ
ぼ100%の水素ガス雰囲気下で焼鈍する方法に関する
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for annealing ultra-low carbon steel strip in a tight annealing furnace under a nearly 100% hydrogen gas atmosphere.

従来の技術 冷延鋼板や電気メツキ鋼板で超深絞り鋼板を製造するに
は、炭素含有量0.0060wt%以下の極低炭素鋼材
を熱間圧延したのち、圧下率50〜90%の範囲で冷間
圧延し、その後再結晶温度以上の温度で連続焼鈍し、調
質圧延を施すか、あるいは炭素含有量0.04〜0.0
6%の通常の冷延鋼帯をオーブンコイル焼鈍炉を用いて
脱炭焼鈍して調質圧延するのが一般的な製造方法である
Conventional technology To produce ultra-deep drawn steel sheets using cold-rolled steel sheets or electroplated steel sheets, ultra-low carbon steel with a carbon content of 0.0060 wt% or less is hot-rolled and then rolled at a reduction rate of 50 to 90%. Cold rolled, then continuously annealed at a temperature higher than the recrystallization temperature, and temper rolled, or carbon content 0.04 to 0.0
A common manufacturing method is to decarburize an ordinary 6% cold-rolled steel strip using an oven coil annealing furnace and then temper-roll it.

しかしながら、連続焼鈍炉やオーブンコイル焼鈍炉を使
用することなく、タイト焼鈍炉を用いて超深絞り鋼板を
製造する場合があり得る。この場合、極低炭素鋼帯は、
通常の冷延鋼帯に比較して再結晶温度が高く、変態温度
も高い。このため、通常の冷延鋼帯の最適焼鈍温度であ
る620〜700℃よりも高い温度で焼鈍する必要があ
り、コイル。
However, there may be cases where an ultra-deep drawn steel plate is manufactured using a tight annealing furnace without using a continuous annealing furnace or an oven coil annealing furnace. In this case, the ultra-low carbon steel strip is
It has a higher recrystallization temperature and higher transformation temperature than ordinary cold rolled steel strip. For this reason, it is necessary to anneal the coil at a temperature higher than the optimum annealing temperature of 620-700°C for normal cold-rolled steel strips.

の焼付き疵の発生や雰囲気ガス中の窒素の吸窒等の問題
が生じる。
Problems such as the occurrence of seizure defects and the adsorption of nitrogen in the atmospheric gas occur.

一般的なベル型タイト焼鈍炉は、第3図に示すとおり、
焼鈍する鋼帯コイル(1)にインナーカバー(2)をか
ぶせたのち加熱ベル(3)をかぶせ、インナーカバー(
2)内に還元性ガスを吹込んで空気を追出し、その外側
からバーナー(4)あるいは電気加熱によりコイル(1
)を加熱する。
A typical bell-shaped tight annealing furnace is shown in Figure 3.
After covering the steel strip coil (1) to be annealed with the inner cover (2), the heating bell (3) is placed over the inner cover (
2) Reducing gas is blown into the interior to expel air, and the coil (1) is heated from the outside using a burner (4) or electric heating.
).

還元性ガスとして従来から多く使用されるものは、光輝
度の要求から酸化成分、炭化成分が少ないこと、および
製造方法が容易で安価なことから、アンモニア分解ガス
に窒素を混合し、あるいはプロパンガスなどに窒素を混
合し、水素6〜20%、残部窒素からなる還元性ガスで
ある。
Reducing gases that have traditionally been widely used are ammonia decomposition gas mixed with nitrogen, or propane gas, which is low in oxidizing and carbonizing components due to brightness requirements, and is easy and inexpensive to produce. It is a reducing gas consisting of 6 to 20% hydrogen and the balance nitrogen.

加熱処理終了後、加熱ベル(3)を取除き、冷却ベル(
5)に取替え、冷却したのち、調質圧延等に供している
After the heating process is completed, remove the heating bell (3) and replace the cooling bell (
5), and after cooling, it is subjected to temper rolling, etc.

なお、(6)はインナーカバー(2)内封流ファン、(
7)は対流ファン(6)のモーターである。
In addition, (6) is the inner cover (2) internal flow fan, (
7) is the motor of the convection fan (6).

このベル型タイト焼鈍炉でのバーナーからコイルへの熱
伝達は、インナーカバー(2)および還元性雰囲気ガス
を介して行なわれる。
Heat transfer from the burner to the coil in this bell-shaped tight annealing furnace is performed via the inner cover (2) and the reducing atmosphere gas.

このため、コイル(1)の外周部と内周部では、インナ
ーカバー(2)からの距離に差が生じ、輻射熱の影響が
異なるため、半径方向で温度差が生じる。このコイル(
1)の外周部と内周部の温度差は、外周部が内周部より
10〜20℃高くなり、コイル外周部がオーバーヒート
気味になり、焼付き疵が発生し易くなる。
For this reason, there is a difference in the distance from the inner cover (2) between the outer circumferential portion and the inner circumferential portion of the coil (1), and the effects of radiant heat are different, resulting in a temperature difference in the radial direction. This coil (
Regarding the temperature difference between the outer peripheral part and the inner peripheral part in 1), the outer peripheral part is 10 to 20 degrees Celsius higher than the inner peripheral part, and the outer peripheral part of the coil tends to be overheated, making it easy to cause seizure defects.

また、Tiを添加した極低炭素鋼帯は、T1とNの結合
力が極めて強いため、焼鈍雰囲気中にN2が存在すると
、吸窒現象が生じ、機械試験値特性を劣化させる場合が
ある。
Further, in the ultra-low carbon steel strip to which Ti is added, the bonding force between T1 and N is extremely strong, so if N2 is present in the annealing atmosphere, a nitrification phenomenon occurs, which may deteriorate the mechanical test value characteristics.

発明が解決しようとする課題 前記ベル型タイト焼鈍炉でのコイル外周部と内周部での
温度差の発生を防止する方法としては、コイル外径をイ
ンナーカバー内径に比較して小さくし、あるいはインナ
ーカバーを二重構造にする等によって、インナーカバー
の温度差による輻射熱の影響を緩和している。しかし、
いずれにしても焼鈍炉の能率が著しく低下する。
Problems to be Solved by the Invention As a method for preventing a temperature difference between the outer circumference and the inner circumference of the coil in the bell-shaped tight annealing furnace, the outer diameter of the coil is made smaller than the inner diameter of the inner cover, or By making the inner cover have a double structure, etc., the effects of radiant heat due to temperature differences between the inner covers are alleviated. but,
In either case, the efficiency of the annealing furnace is significantly reduced.

さらに、外部加熱方式の焼鈍炉も考えられたが、外部加
熱のため設備そのものが大きくなり、また、加熱雰囲気
の吹出し口部での温度差が生じる等の問題があった。
Furthermore, an annealing furnace using an external heating method has been considered, but the equipment itself becomes large due to external heating, and there are also problems such as a temperature difference occurring at the outlet of the heated atmosphere.

さらに、Tiを添加した極低炭素鋼帯は、T1とNの結
合力が極めて強いため、焼鈍雰囲気中にN2が存在する
と、鋼中に侵入し機械試験値特性を劣化させる加窒現象
を生じるという欠点がある。
Furthermore, in ultra-low carbon steel strips containing Ti, the bonding force between T1 and N is extremely strong, so if N2 is present in the annealing atmosphere, it will penetrate into the steel and cause a nitriding phenomenon that deteriorates the mechanical test value characteristics. There is a drawback.

この発明の目的は、前記従来方式のタイト焼鈍炉におい
て、コイル外周部と内周部の温度差の発生を防止し、コ
イル外周部における過熱を防止できると共に、焼鈍効率
を向上できる極低炭素鋼帯の焼鈍方法を提供するにある
An object of the present invention is to use an ultra-low carbon steel that can prevent a temperature difference between the outer circumference and the inner circumference of the coil, prevent overheating at the outer circumference of the coil, and improve annealing efficiency in the conventional tight annealing furnace. The present invention provides a method for annealing a strip.

課題を解決するための手段 本発明者らは、前記目的を達成すべく種々検討の結果、
ほぼ100%濃度の水素ガス雰囲気下で焼鈍することに
よって、水素ガスの高熱伝導性により焼鈍雰囲気の熱伝
達が促進され、インナーカバーとの距離の差に基づく輻
射熱の影響が抑制されてコイルの外周部と内周部の温度
差を低減できることを見い出し、この発明に到達した。
Means for Solving the Problems As a result of various studies to achieve the above object, the present inventors have found that
By annealing in a nearly 100% hydrogen gas atmosphere, the high thermal conductivity of hydrogen gas promotes heat transfer in the annealing atmosphere, suppressing the influence of radiant heat due to the difference in distance from the inner cover, and reducing the outer periphery of the coil. The inventors have discovered that it is possible to reduce the temperature difference between the outer circumferential portion and the inner peripheral portion, and have arrived at this invention.

すなわちこの発明は、タイト焼鈍炉において、炭素含有
量0.006wt%以下の極低炭素鋼帯のコイルを、水
素濃度ほぼ100%の水素ガス雰囲気下、焼鈍温度68
0〜750℃で焼鈍するのである。
That is, the present invention anneales a coil of ultra-low carbon steel strip with a carbon content of 0.006 wt% or less in a tight annealing furnace in a hydrogen gas atmosphere with a hydrogen concentration of approximately 100%.
It is annealed at 0 to 750°C.

作    用 この発明においては、タイト焼鈍炉を用い、炭素含有量
0.0060重量%以下の極低炭素鋼帯のコイルを、水
素濃度ほぼ100%の水素ガス雰囲気下、焼鈍温度68
0〜750℃で焼鈍する。このため、インナーカバー内
の焼鈍ガス雰囲気は、水素濃度がほぼ100%の水素雰
囲気となり、従来の水素濃度6〜20%に比較して約5
〜17倍となる。この水素の高熱伝導性(窒素の約7倍
)のため、インナーカバーの円周方向での温度差ならび
に半径方向での熱伝導性に基づくコイル外周部と内周部
の温度差の発生は、ほぼ100%の水素ガス雰囲気によ
る熱伝達の促進により抑制されるのである。
Function In this invention, a coil of ultra-low carbon steel strip with a carbon content of 0.0060% by weight or less is annealed at a temperature of 68% in a hydrogen gas atmosphere with a hydrogen concentration of approximately 100% using a tight annealing furnace.
Anneal at 0-750°C. Therefore, the annealing gas atmosphere inside the inner cover becomes a hydrogen atmosphere with a hydrogen concentration of almost 100%, which is about 5% compared to the conventional hydrogen concentration of 6 to 20%.
~17 times. Due to the high thermal conductivity of hydrogen (approximately 7 times that of nitrogen), the temperature difference between the outer circumference and inner circumference of the coil due to the temperature difference in the circumferential direction of the inner cover and the thermal conductivity in the radial direction is This is suppressed by the promotion of heat transfer by the nearly 100% hydrogen gas atmosphere.

なお、極低炭素鋼帯としては、普通の炭素系、Ti添加
、Nb添加、Ti、Nb複合添加の炭素鋼帯の炭素含有
量を0.006wt%以下としたのは、0、006wt
%を超えると、脱炭焼鈍が必要となり、タイト焼鈍炉で
は焼鈍不可能となるからである。
In addition, as an ultra-low carbon steel strip, the carbon content of ordinary carbon-based, Ti-added, Nb-added, Ti, Nb composite-added carbon steel strip is 0.006 wt% or less.
%, decarburization annealing becomes necessary and annealing becomes impossible in a tight annealing furnace.

焼鈍雰囲気中の水素濃度をほぼ100%としたのは、イ
ンナーカバー内でのより均一な熱伝導性を確保するため
である。このような水素ガスとしては、水を原料とし電
気分解して得た濃度99.8%の未清浄水素あるいは濃
度100%の清浄水素を使用することができる。
The hydrogen concentration in the annealing atmosphere was set to approximately 100% in order to ensure more uniform thermal conductivity within the inner cover. As such hydrogen gas, unpurified hydrogen with a concentration of 99.8% obtained by electrolyzing water as a raw material or clean hydrogen with a concentration of 100% can be used.

焼鈍温度を680〜750℃としたのは、680℃未満
では結晶粒の成長が十分でなく、所望の機械的特性が得
られない。また750℃を超えると焼鈍過程の再結晶時
の異常粒成長が生じ、機械的特性が悪化するからである
The reason why the annealing temperature is 680 to 750°C is that if it is lower than 680°C, the growth of crystal grains is insufficient and desired mechanical properties cannot be obtained. Further, if the temperature exceeds 750°C, abnormal grain growth occurs during recrystallization during the annealing process, resulting in deterioration of mechanical properties.

また、高濃度水素ガス雰囲気下で焼鈍を行うため、水素
の高熱伝導性により焼鈍効率が向上する。
Furthermore, since annealing is performed in a highly concentrated hydrogen gas atmosphere, the annealing efficiency is improved due to the high thermal conductivity of hydrogen.

実   施   例 実施例1 第1表に示す組成からなる極低炭素鋼片を1200℃に
加熱したのち粗圧延し、次いで仕上圧延開始温度900
℃、巻取り温度630℃で仕上圧延して板厚2.3mm
に熱間圧延した。得られたコイルを冷間圧延した0、 
4mmの冷延鋼帯のコイルを、第3図に示すような円周
方向に4個のバーナーが3段に設けられたベル型タイト
焼鈍炉において、炉温900℃、コイル温度735℃、
焼鈍時間16時間、インナーカバー内清浄水素(水素濃
度100%)雰囲気下で焼鈍した。そして焼鈍後のコイ
ルの半径方向の温度差を測定したところ、第1図に示す
とおりであった。焼鈍完了後のコイルは徐々に冷却した
のち伸率0.6%の調質圧延を行い、得られた超深絞り
極低炭素鋼帯からJ IS5号引張試験片を切出し、引
張試験を行い降伏点(以下YPという)、引張強度(以
下TSという)および伸び(以下Elという)を測定し
、ランクフォード値(以下r値という)を求めた。その
結果を第2表に示す。
Examples Example 1 An ultra-low carbon steel billet having the composition shown in Table 1 was heated to 1200°C, rough rolled, and then finished rolled at a starting temperature of 900°C.
Finish rolling at a coiling temperature of 630°C to a plate thickness of 2.3mm.
Hot rolled. The obtained coil was cold rolled 0,
A coil of 4 mm cold-rolled steel strip was heated in a bell-shaped tight annealing furnace equipped with four burners in three stages in the circumferential direction as shown in Fig. 3, at a furnace temperature of 900°C, a coil temperature of 735°C,
The inner cover was annealed in an atmosphere of clean hydrogen (hydrogen concentration 100%) for 16 hours. The temperature difference in the radial direction of the coil after annealing was measured, and the results were as shown in FIG. After completion of annealing, the coil was gradually cooled and then subjected to temper rolling with an elongation rate of 0.6%. JIS No. 5 tensile test pieces were cut from the obtained ultra-deep drawn ultra-low carbon steel strip and subjected to a tensile test to determine yield. Point (hereinafter referred to as YP), tensile strength (hereinafter referred to as TS) and elongation (hereinafter referred to as El) were measured, and the Lankford value (hereinafter referred to as r value) was determined. The results are shown in Table 2.

同様に従来法としてインナーカバー内を水素11%、窒
素89%の雰囲気とした以外は、前記と同一条件で焼鈍
を行った。そして焼鈍後のコイルの半径方向の温度を測
定すると共に、徐々に冷却したのち同じ伸率で調質圧延
を行い、同様に引張試験を実施した。その結果を第2図
および第2表に示す。
Similarly, as a conventional method, annealing was performed under the same conditions as above except that the inside of the inner cover was made into an atmosphere of 11% hydrogen and 89% nitrogen. Then, the temperature in the radial direction of the coil after annealing was measured, and after gradual cooling, skin pass rolling was performed at the same elongation rate, and a tensile test was conducted in the same manner. The results are shown in FIG. 2 and Table 2.

以下余白 第   1   表     (wt2:)(注)単位
: Y P、 T S : kgf/mm”、E l 
: % 水素11%と窒素89%の混合ガスを還元性ガスとして
使用した従来法の場合は、第2図に示すとおりコイルの
半径方向の温度差が10〜20’Cである。
Margin below Table 1 (wt2:) (Note) Unit: Y P, T S: kgf/mm”, E l
:% In the case of the conventional method using a mixed gas of 11% hydrogen and 89% nitrogen as the reducing gas, the temperature difference in the radial direction of the coil is 10 to 20'C, as shown in FIG.

これに対し本発明法の場合は、第1図に示すとおりコイ
ルの半径方向の温度差が5℃以下に低減している。
On the other hand, in the case of the method of the present invention, as shown in FIG. 1, the temperature difference in the radial direction of the coil is reduced to 5° C. or less.

このため、本発明法の場合は、焼鈍時のコイル半径方向
の温度差が軽減され、焼鈍時のコイルの半径方向の温度
差に基づく焼付き疵の発生は見られなかった。
Therefore, in the case of the method of the present invention, the temperature difference in the radial direction of the coil during annealing was reduced, and no seizure defects were observed due to the temperature difference in the radial direction of the coil during annealing.

また、第2表に示すとおり、本発明法の場合は、十分良
好な機械試験値特性を得たが、従来法の場合は、焼鈍時
の吸窒現象の影響からか機械試験値特性が劣化している
In addition, as shown in Table 2, in the case of the method of the present invention, sufficiently good mechanical test value characteristics were obtained, but in the case of the conventional method, the mechanical test value characteristics deteriorated, probably due to the influence of the nitrification phenomenon during annealing. are doing.

発明の効果、 以上述べたとおり、この発明方法によれば、水素濃度ほ
ぼ100%の水素ガス雰囲気中で極低炭素鋼帯をタイト
焼鈍することによって、焼鈍時のコイルの半径方向の温
度差を著しく小さくでき、高温焼鈍時のコイルの焼付き
疵の発生を防止でき、また、吸窒現象を生じることもな
く、機械試験値特性の良好な製品を得ることができる。
Effects of the Invention As described above, according to the method of the present invention, by tightly annealing an ultra-low carbon steel strip in a hydrogen gas atmosphere with a hydrogen concentration of approximately 100%, the temperature difference in the radial direction of the coil during annealing can be reduced. It is possible to significantly reduce the size of the coil, prevent the occurrence of seizure defects in the coil during high-temperature annealing, and obtain a product with good mechanical test value characteristics without causing the nitrification phenomenon.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は実施例1のこの発明におけるコイル半径方向の
温度分布を示す説明図、第2図は実施例1の従来法にお
けるコイル半径方向の温度分布を示す説明図、第3図は
ベル型タイト焼鈍炉の概略説明図である。 1・・・コイル、     2・ インナーカバー、3
・・・加熱ベル、    4・・バーナー、5・・・冷
却ベル、    6・・・対流ファン、7・・モーター
、 出 願 人  住友金属工業株式会社
Figure 1 is an explanatory diagram showing the temperature distribution in the radial direction of the coil in the present invention of Example 1, Figure 2 is an explanatory diagram showing the temperature distribution in the radial direction of the coil in the conventional method of Example 1, and Figure 3 is a bell-shaped diagram. It is a schematic explanatory view of a tight annealing furnace. 1... Coil, 2. Inner cover, 3
... Heating bell, 4. Burner, 5. Cooling bell, 6. Convection fan, 7. Motor, Applicant: Sumitomo Metal Industries, Ltd.

Claims (1)

【特許請求の範囲】[Claims] 1 タイト焼鈍炉において、炭素含有量0.006重量
%以下の極低炭素鋼帯のコイルを、ほぼ100%の水素
ガス雰囲気下、焼鈍温度680〜750℃で焼鈍するこ
とを特徴とする極低炭素鋼帯の焼鈍方法。
1 In a tight annealing furnace, a coil of ultra-low carbon steel strip with a carbon content of 0.006% by weight or less is annealed at an annealing temperature of 680 to 750°C in an almost 100% hydrogen gas atmosphere. Method of annealing carbon steel strip.
JP29512890A 1990-10-30 1990-10-30 Method for annealing dead soft steel strip Pending JPH04168228A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29512890A JPH04168228A (en) 1990-10-30 1990-10-30 Method for annealing dead soft steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29512890A JPH04168228A (en) 1990-10-30 1990-10-30 Method for annealing dead soft steel strip

Publications (1)

Publication Number Publication Date
JPH04168228A true JPH04168228A (en) 1992-06-16

Family

ID=17816651

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29512890A Pending JPH04168228A (en) 1990-10-30 1990-10-30 Method for annealing dead soft steel strip

Country Status (1)

Country Link
JP (1) JPH04168228A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05117757A (en) * 1991-10-25 1993-05-14 Kobe Steel Ltd Manufacture of cold rolled steel sheet excellent in press formability
JP2007092134A (en) * 2005-09-29 2007-04-12 Jfe Steel Kk Cold-rolled steel sheet excellent in chemical conversion treatment, and manufacturing method therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05117757A (en) * 1991-10-25 1993-05-14 Kobe Steel Ltd Manufacture of cold rolled steel sheet excellent in press formability
JP2007092134A (en) * 2005-09-29 2007-04-12 Jfe Steel Kk Cold-rolled steel sheet excellent in chemical conversion treatment, and manufacturing method therefor

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