JPH04156854A - Deodorizing device for toilet - Google Patents
Deodorizing device for toiletInfo
- Publication number
- JPH04156854A JPH04156854A JP2278975A JP27897590A JPH04156854A JP H04156854 A JPH04156854 A JP H04156854A JP 2278975 A JP2278975 A JP 2278975A JP 27897590 A JP27897590 A JP 27897590A JP H04156854 A JPH04156854 A JP H04156854A
- Authority
- JP
- Japan
- Prior art keywords
- deodorizing
- toilet
- deodorant
- porous material
- person
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 26
- 238000009423 ventilation Methods 0.000 claims abstract description 24
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011148 porous material Substances 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000005751 Copper oxide Substances 0.000 claims abstract 4
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract 4
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 238000001514 detection method Methods 0.000 abstract description 4
- 238000004332 deodorization Methods 0.000 abstract description 3
- 238000011045 prefiltration Methods 0.000 abstract description 3
- 239000002781 deodorant agent Substances 0.000 abstract 4
- 239000000470 constituent Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 16
- 235000019645 odor Nutrition 0.000 description 13
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 241000264877 Hippospongia communis Species 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 230000001149 cognitive effect Effects 0.000 description 3
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- -1 dust particles Chemical compound 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 210000001215 vagina Anatomy 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はトイレ、特に水洗式トイレの脱臭装置に関する
。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a deodorizing device for toilets, particularly flush toilets.
従来のトイレの脱臭方法としては、窓を島いての自然換
気、わるいは換気扇による強制換気によるか、または、
特開昭58−158428号公報のように、洋式水洗ト
イレの便座に臭気吸入口を設けて、用便後の臭気を送風
装置により強制的に吸入して戸外に排出する方法力;お
る。Conventional methods of deodorizing toilets include natural ventilation by closing windows, forced ventilation with ventilation fans, or
As disclosed in Japanese Patent Application Laid-Open No. 58-158428, a method is provided in which an odor intake port is provided on the toilet seat of a Western-style flush toilet, and the odor after defecation is forcibly inhaled by an air blower and discharged to the outside.
上記従来技術に8いて、脱臭を自然換気、あるいは強制
換気で行なう場合1戸外の気温が低い場合はトイレ内の
温度が低下し、不快となる。また便座に吸込口を設ける
方法でに便座O交換、表よび排気パイプを戸外に出すた
め壁に穴をめける叫の工事を必要とする。According to the above-mentioned prior art, when deodorization is performed by natural ventilation or forced ventilation, the temperature inside the toilet decreases when the outdoor temperature is low, causing discomfort. In addition, installing a suction port on the toilet seat requires replacing the toilet seat and drilling a hole in the wall to allow the front and exhaust pipes to go outside.
本発明の目的は、手軽で効果O高いトイレ用脱臭装置V
提供することにある。The purpose of the present invention is to provide a toilet deodorizing device that is simple and highly effective.
It is about providing.
上E目的を達成するために、本発明は脱臭剤として二酸
化マンガン、酸化鋼、酸化亜鉛の本体または複合体を主
成分とするか、わるいに多孔質物質の表面に前記徽化物
を担持して脱臭剤を形成し、通風用ファンを用いて強制
通風し、トイレ内な脱臭する構造とし、通風用ファンの
運転は赤外線センサによシ人の立入りを検出して任意に
設定した一定時間行なうようにすることに工夛、簡便で
効果的な脱臭を行なうことができる。In order to achieve the above object, the present invention uses a deodorizer mainly consisting of a body or a composite of manganese dioxide, steel oxide, or zinc oxide, or alternatively, the deodorizing agent is supported on the surface of a porous material. A deodorizing agent is formed and a ventilation fan is used to forcefully circulate the air to deodorize the toilet.The ventilation fan is operated for a predetermined period of time after detecting the entry of a person using an infrared sensor. With this technology, it is possible to perform simple and effective deodorization.
脱臭剤の成分である二酸化マンガン%酸化鋼、酸化亜鉛
はトイレの臭い、特に、用便直後の残留臭気として考え
られる硫化水素、メルカプタン類に対しては触媒的に作
用し、11.温で脱水累反応を起こして臭いな軽減する
ことができるので長期間、安定した性能を得ることがで
きる。The components of the deodorizer, manganese dioxide% steel oxide and zinc oxide, act catalytically against toilet odors, especially hydrogen sulfide and mercaptans, which are thought to be residual odors immediately after using the toilet.11. Since the dehydration reaction occurs at high temperature and the odor can be reduced, stable performance can be obtained for a long period of time.
また、通風用ファンの運転に赤外線センサによp1人O
立入りを検出して行なうことができ、通風用7アンO作
動時間は使用者が任意に設定できるの?′、使用やる場
所で効果的な時間なそれぞれ選ぶことに=9効果的に脱
臭を行なうことができ机
〔案渡例〕
以下5本発明O−実施例を第1区ないし第5図にエフ説
明する。@1図8よひ第2区に8いて。In addition, an infrared sensor is used to operate the ventilation fan.
Is it possible to detect trespassing and allow the user to set the ventilation operation time at will? ', Selecting an effective time at the place of use = 9 A machine that can effectively deodorize [Delivery example] The following 5 embodiments of the present invention are shown in Sections 1 to 5. explain. @1 Figure 8 Yohi 8 in the 2nd ward.
1にトイレ用脱臭装置本体、2は脱臭剤、5に通風用フ
ァン、4は赤外線センサ、5は制御基板でお心。1 is the toilet deodorizer body, 2 is the deodorizer, 5 is the ventilation fan, 4 is the infrared sensor, and 5 is the control board.
本実施ガにどいて、メインスイッチ11をオンすること
により電源表示灯12が点灯し、赤外線センサ4が検出
動作を開始する。赤外線センサ4の検d範囲に人が立入
るご、人が放出する赤外線を検出して、これを制御基板
5に伝え、通風用ファ/3を作動して脱臭運転をはじめ
、運転表示灯13を点灯する1通風用77ン5が作動す
ると、吸込口14からプレフィルタ15を通してトイレ
内臭気を吸込み、脱臭剤2を通って吐出口16よシ装置
外に第2図の矢印のように排出される。プレフィルタ1
5はほこp等O侵入な防ぐために設置して29%例えば
、アコーディオン状に折シ曲けた不織布等を使用するこ
とができる。In this embodiment, by turning on the main switch 11, the power indicator light 12 lights up and the infrared sensor 4 starts a detection operation. When a person enters the detection range of the infrared sensor 4, it detects the infrared rays emitted by the person, transmits this to the control board 5, activates the ventilation fan 3 to start deodorizing operation, and operates the operation indicator light 13. 1 When the ventilation valve 5 is activated, the odor in the toilet is sucked in from the suction port 14 through the pre-filter 15, passes through the deodorizer 2, and is discharged to the outside of the device through the discharge port 16 as shown by the arrow in Figure 2. be done. Prefilter 1
5 is installed to prevent the intrusion of oxygen such as dust particles, etc. 29% For example, a nonwoven fabric folded into an accordion shape or the like can be used.
脱臭剤2は、ガえFi、多孔質物質としてハニカム状O
アルミナを用いて表面に二酸化マンガン、めるいは、酸
化鋼を添着したものを用いることめ;できる、この作製
方法に硝酸マンカン、おるいは、硝酸鋼の水溶液にアル
ミナハニカムを浸漬して。Deodorizer 2 contains Gae Fi and honeycomb-like O as a porous material.
Alumina honeycombs with manganese dioxide, or oxidized steel attached to the surface can be used; this can be done by immersing an alumina honeycomb in an aqueous solution of manganese nitrate, or steel nitrate.
硝酸マンガン、tDるいは、硝酸鋼を付f−igせた後
に予備乾燥し、さらに、硝酸マンガンあるいは硝酸鋼の
熱分解温度以上まで加熱して、硝酸マンカンは二酸化マ
ンガン(Mn02)に、硝Wk#lは酸化鋼(Cub)
に酸化する。Manganese nitrate, tD Ru, or nitrate steel is pre-dried after being applied with nitric acid steel, and then heated to a temperature higher than the thermal decomposition temperature of manganese nitrate or nitric steel. #l is oxidized steel (Cub)
oxidizes to
トイレ、特に、水洗トイレの臭気として問題になるのは
用便後の残留臭気であり、この臭気として考えられる硫
化水素、メルカプタン類は脱臭剤2を通過すると次のよ
うに脱水業反応を起こすと考えられる。The problem with the odor of toilets, especially flush toilets, is the residual odor after using the toilet, and when hydrogen sulfide and mercaptans, which are thought to be responsible for this odor, pass through deodorizer 2, they cause a dehydration reaction as follows. Conceivable.
この反応をガスクロマトグラフによりfll+定すると
便化水素に生成物が硫黄であり、ガス体ではないので硫
化水素の消失のみが観察芒れるが、メルカプタン類であ
るメチルメルカプタンは、メチルメルカプタンの消失に
あわせてジメチルジサルファイドの生成てれることがw
e−gれる。これよシ、硫化水素を吸込んだ場合、吐出
慟には臭気となる成分は放出しないが、メチルメルカプ
タンの場合は、ジメチルジサルファイドを吸込んだメチ
ルメルカプタンの濃度の半分の濃度で排出することにな
る。ジメチルジサルファイドは無臭ではないが、濃度が
半分になること、8よび、認知闇値の差よル臭いは大き
く軽減される。When this reaction is determined by gas chromatography, the product is sulfur, and since it is not a gas, only the disappearance of hydrogen sulfide can be observed.However, methyl mercaptan, which is a mercaptan, The formation of dimethyl disulfide is possible.
e-greru. In this case, when hydrogen sulfide is inhaled, odor-causing components are not released into the exhaled vagina, but in the case of methyl mercaptan, the concentration of methyl mercaptan is half the concentration of methyl mercaptan when dimethyl disulfide is inhaled. . Although dimethyl disulfide is not odorless, the odor is greatly reduced by halving the concentration and the difference in perceived darkness value.
的えば、メチルメルカプタンがα02 B ppmであ
った場合、ジメチルジサルファイドil[L(N4pp
(1住成するが臭気濃度は40から5と下記のようにへ
分の1に減少させることができる。For example, if methyl mercaptan is α02 B ppm, dimethyl disulfide il[L(N4ppm
(However, the odor concentration can be reduced by a factor of 1 from 40 to 5 as described below.
認知閾値 (PPffi) α0007
α0029臭気a度(jjX濃#/認知閾値)4
05注)認知閾値:臭いを感じはじめるfIk[であp
。Cognitive threshold (PPffi) α0007
α0029 Odor a degree (jjX concentration #/cognitive threshold) 4
05 Note) Cognitive threshold: fIk [deap
.
イ丘し1信のガスp!−アNL%づ」はAμ℃1す入本
実施的の脱臭!!構に活性度等の吸着と異なり触1反応
的のものであるので長期間安定した性能もつことができ
る。さらに、アンモニア、アミン類等のガスは水洗式ト
イレ内ではその濃度は低(・ものと考えるが、本実施的
の脱臭剤2はこれらのカスに対しても吸着作用と思われ
る脱臭性能をもって” D h水洗トイレの用便後の残
留臭気C:対して有効である。Ikushi 1 Shin's gas p! -ANL% is a practical deodorizer that enters Aμ℃1! ! Unlike adsorption, which has a structure such as activity, it is catalytic and reactive, so it can maintain stable performance over a long period of time. Furthermore, although the concentration of gases such as ammonia and amines is thought to be low in flush toilets, this practical deodorizer 2 also has deodorizing performance that is thought to have an adsorption effect on these scum. Dh Residual odor after using flush toilets C: Effective against.
脱臭剤2の成分に他に主成分として酸化亜鉛を使用して
も同様の効果を得られる。また、脱臭剤成分を多孔質物
質に担持して使用する場合、本実施例のアルミナ以外に
豪化チタ/、コージライト等の他の多孔質体でもよい、
形態も本実施的のハニカム状に限らす、ベレット状、球
状、板状等空気との接触面積が大きくなる構造であれば
よい。Similar effects can be obtained by using zinc oxide as the main component in the deodorizer 2. In addition, when the deodorizing agent component is supported on a porous material and used, other porous materials such as alumina and cordierite may be used in addition to the alumina of this example.
The shape is not limited to the honeycomb shape of this embodiment, but may be any structure that increases the contact area with air, such as a pellet shape, a spherical shape, or a plate shape.
本脱臭装置のメチルメルカプタンに対する脱臭性能を@
3図(二示す、Y軸にメチルメルカプタンの残存率、横
軸C:経過時間を示す。トイレの空間体積を五4.?1
’とし、通風用ファン5のitにf15yy//−脱臭
剤20見かけの#:梗に128dである。脱臭剤2の成
分は二酸化マンガン、gよび、酸化鋼を、それぞれ、ア
ルミナハニカムに担持したもの二種を用いたがどちらも
ほとんど同等の性能を示す9通風用7アン6を運転鈍始
彼25〜30分でメチルメルカプタンの残存率は10−
以下となp1急速な脱臭性能をもっていることが判る。The deodorizing performance of this deodorizing device against methyl mercaptan @
Figure 3 (2) shows the residual rate of methyl mercaptan on the Y axis, and the horizontal axis C: shows the elapsed time.
', and the ventilation fan 5 has f15yy//- deodorizer 20 apparent #: 128d. The ingredients of deodorizer 2 were manganese dioxide, g, and oxidized steel, each supported on alumina honeycomb. Two types of deodorizer were used, and both showed almost the same performance. The residual rate of methyl mercaptan in ~30 minutes was 10-
It can be seen that p1 has rapid deodorizing performance as shown below.
な8゜このデータはモデルとしたガスの自然減衰ΣLび
部屋の換気が全くない場合であや、一般のトイレでは自
然減衰8よび換気があるのでさらにモデルとしたガスの
減衰に速くなる。8゜This data is based on the case where there is no natural attenuation ΣL of the modeled gas and no ventilation in the room.In a general toilet, there is natural attenuation 8 and ventilation, so the attenuation of the modeled gas is even faster.
本!l!旅ガのトイレ用脱臭装置1は赤外線センサ4で
人を検知して通風用ファン5を作動して脱臭を行ない、
任意に設定した時間運転して停止するが、七の時間設定
はタイマつまみ17を廻すことにall!整する。$5
図の性能であれば、設定時間は三十分前後に設定すると
良好な結果が得られる。赤外線センサ4で人な検知して
通風用ファ15を作動後、タイマつまみ17で設定した
時間後に通風量ファン5を停止し、その後、待機状態と
なシ、赤外線センサ4の検圧待ちとなる。Book! l! Tabiga's toilet deodorizing device 1 detects a person with an infrared sensor 4 and operates a ventilation fan 5 to deodorize the toilet.
It runs for an arbitrarily set time and then stops, but the seventh time setting is all about turning the timer knob 17! Arrange. $5
If the performance is as shown in the figure, good results can be obtained by setting the setting time to around 30 minutes. After detecting a person with the infrared sensor 4 and activating the ventilation fan 15, the ventilation fan 5 is stopped after the time set with the timer knob 17, and then it is in a standby state, waiting for pressure detection by the infrared sensor 4. .
な8、赤外線センサ4が人を検知して通風用77ン5が
作動中に、赤外線センサ4が再夏人を検知した場合は、
最後に人を検知した時点からタイマつ筐み17で設定し
た時間の間、通風用〕7ン3を作動するようにする。8. If the infrared sensor 4 detects a person and the ventilation 77 is operating, if the infrared sensor 4 detects a person,
The ventilation fan 7 is operated for the time set in the timer box 17 from the time when a person is last detected.
本発明によれば、人がスイッチの操作をすることなく、
効率のよい脱臭運転を長期間安定に行なうことができる
。According to the present invention, there is no need for a person to operate a switch.
Efficient deodorizing operation can be performed stably for a long period of time.
[1図は本発明の一実施例のトイレ用脱臭装置の斜視図
、第2図は第1図の部分断面図、第3図はトイレ用脱臭
装置の性能を示すグラフである。
1・・・トイレ用脱臭装置本体、2・・・脱臭剤、3・
・−通風用ファン、4・・・を外線センサ、5・・・制
御基板。
11・・・メインスイッチ、12・・・電源表示灯%
13・・・運転表示灯、14・・・吸入口、15・・・
ブレフィルタ、16・・・吐出口% 17・・・タイマ
ツマミ。[FIG. 1 is a perspective view of a toilet deodorizing device according to an embodiment of the present invention, FIG. 2 is a partial sectional view of FIG. 1, and FIG. 3 is a graph showing the performance of the toilet deodorizing device. 1... Toilet deodorizer main body, 2... Deodorizer, 3...
- Ventilation fan, 4... is an external line sensor, 5... is a control board. 11... Main switch, 12... Power indicator %
13... Operation indicator light, 14... Inlet, 15...
Blur filter, 16...Discharge port % 17...Timer knob.
Claims (1)
おいて、 前記脱臭剤の成分として二酸化マンガン、酸化銅、酸化
亜鉛の単体、あるいは複合体を主成分とするか、または
、多孔質物質の表面に二酸化マンガン、酸化銅、酸化亜
鉛の単体あるいは複合体を保持させて脱臭剤を形成する
ことを特徴とするトイレ用脱臭装置。 2、請求項1において、前記脱臭装置は主電源を投入し
て待機状態とした後、赤外線センサにより人の立入りを
検出し、人を検出すると任意に設定した一定の時間通風
装置を作動して脱臭運転を行なった後に通風装置を停止
し、初期の待機状態に戻るトイレ用脱臭装置。[Scope of Claims] 1. A deodorizing device that obtains a deodorizing effect by forcing air through a deodorizing agent, wherein the deodorizing agent mainly contains manganese dioxide, copper oxide, or zinc oxide alone or in a complex, or Alternatively, a toilet deodorizing device is characterized in that a deodorizing agent is formed by holding manganese dioxide, copper oxide, or zinc oxide alone or in combination on the surface of a porous material. 2. In claim 1, after the deodorizing device turns on the main power and enters a standby state, it detects the entry of a person using an infrared sensor, and when a person is detected, it operates the ventilation device for a predetermined period of time set arbitrarily. A toilet deodorizing device that stops the ventilation device after performing deodorizing operation and returns to the initial standby state.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2278975A JPH04156854A (en) | 1990-10-19 | 1990-10-19 | Deodorizing device for toilet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2278975A JPH04156854A (en) | 1990-10-19 | 1990-10-19 | Deodorizing device for toilet |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04156854A true JPH04156854A (en) | 1992-05-29 |
Family
ID=17604680
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2278975A Pending JPH04156854A (en) | 1990-10-19 | 1990-10-19 | Deodorizing device for toilet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04156854A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996029099A1 (en) * | 1995-03-23 | 1996-09-26 | Toto Ltd. | Deodorizing method, deodorant, process for the preparation of deodorant, and deodorizing equipment |
EP0829299A1 (en) * | 1995-05-26 | 1998-03-18 | Hitachi Chemical Co., Ltd. | Environment purifying material |
-
1990
- 1990-10-19 JP JP2278975A patent/JPH04156854A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996029099A1 (en) * | 1995-03-23 | 1996-09-26 | Toto Ltd. | Deodorizing method, deodorant, process for the preparation of deodorant, and deodorizing equipment |
US6010666A (en) * | 1995-03-23 | 2000-01-04 | Toto, Ltd. | Deodorizing method, deodorizer, method of manufacturing deodorizer, and deodorizing apparatus |
US6207106B1 (en) | 1995-03-23 | 2001-03-27 | Toto, Ltd. | Room temperature deodorizing method based on a polymerization reaction, an oxidation reaction and adsorption |
KR100397384B1 (en) * | 1995-03-23 | 2003-12-24 | 도토기키 가부시키가이샤 | Deodorization method, deodorant manufacturing method and deodorizer |
EP0829299A1 (en) * | 1995-05-26 | 1998-03-18 | Hitachi Chemical Co., Ltd. | Environment purifying material |
EP0829299A4 (en) * | 1995-05-26 | 1999-02-10 | Hitachi Chemical Co Ltd | Environment purifying material |
US5997829A (en) * | 1995-05-26 | 1999-12-07 | Hitachi Chemical Company, Ltd. | Environment purifying material |
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