JPH04118659A - Electrophotographic sensitive body, electrophotographic device and facsimile having this electrophotographic body - Google Patents
Electrophotographic sensitive body, electrophotographic device and facsimile having this electrophotographic bodyInfo
- Publication number
- JPH04118659A JPH04118659A JP23699990A JP23699990A JPH04118659A JP H04118659 A JPH04118659 A JP H04118659A JP 23699990 A JP23699990 A JP 23699990A JP 23699990 A JP23699990 A JP 23699990A JP H04118659 A JPH04118659 A JP H04118659A
- Authority
- JP
- Japan
- Prior art keywords
- electrophotographic
- pigment
- formula
- electrophotographic photoreceptor
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000049 pigment Substances 0.000 claims abstract description 64
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims abstract description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 108091008695 photoreceptors Proteins 0.000 claims description 54
- 239000000126 substance Substances 0.000 claims description 17
- 238000012546 transfer Methods 0.000 abstract description 16
- 230000035945 sensitivity Effects 0.000 abstract description 8
- 230000003252 repetitive effect Effects 0.000 abstract 1
- -1 3,4- Pyrazolediyl 2,3-pyridinediyl Chemical group 0.000 description 17
- 239000000463 material Substances 0.000 description 13
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920002382 photo conductive polymer Polymers 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- MYKQKWIPLZEVOW-UHFFFAOYSA-N 11h-benzo[a]carbazole Chemical group C1=CC2=CC=CC=C2C2=C1C1=CC=CC=C1N2 MYKQKWIPLZEVOW-UHFFFAOYSA-N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
- 210000003127 knee Anatomy 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 229920005668 polycarbonate resin Polymers 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 description 1
- FKNIDKXOANSRCS-UHFFFAOYSA-N 2,3,4-trinitrofluoren-1-one Chemical compound C1=CC=C2C3=C([N+](=O)[O-])C([N+]([O-])=O)=C([N+]([O-])=O)C(=O)C3=CC2=C1 FKNIDKXOANSRCS-UHFFFAOYSA-N 0.000 description 1
- SCGKCGMVFXMMSF-UHFFFAOYSA-N 2-[(diphenylhydrazinylidene)methyl]-n,n-diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1C=NN(C=1C=CC=CC=1)C1=CC=CC=C1 SCGKCGMVFXMMSF-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 125000005577 anthracene group Chemical group 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
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- 239000011651 chromium Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
- 230000013872 defecation Effects 0.000 description 1
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical group C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
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- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
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- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010147 laser engraving Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical compound C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Photoreceptors In Electrophotography (AREA)
- Fax Reproducing Arrangements (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は電子写真感光体、該電子写真感光体を備えた電
子写真装置並びにファクシミリに関し、詳しくは特定の
構造を有するジスアゾ顔料を含有する感光層を有する電
子写真感光体と該電子写真感光体を備えた電子写真装置
並びにファクシミリに関する。Detailed Description of the Invention [Industrial Field of Application] The present invention relates to an electrophotographic photoreceptor, an electrophotographic device equipped with the electrophotographic photoreceptor, and a facsimile, and more particularly, to a photoreceptor containing a disazo pigment having a specific structure. The present invention relates to an electrophotographic photoreceptor having a layer, an electrophotographic apparatus equipped with the electrophotographic photoreceptor, and a facsimile.
[従来の技術]
従来、電子写真感光体としては、セレン、硫化カドミウ
ム、酸化亜鉛などの無機光導電性物質が広く用いられて
いた。[Prior Art] Conventionally, inorganic photoconductive substances such as selenium, cadmium sulfide, and zinc oxide have been widely used as electrophotographic photoreceptors.
一方、有機光導電性物質からなる電子写真感光体として
はポリ−N−ビニルカルバゾールに代表される光導電性
ポリマーや2.5−ビス(p−ジエチルアミノフェニル
)−1,3,4−オキサジアゾールのような低分子の有
機光導電性物質を用いたもの、さらにはこのような有機
光導電性物質と各種の染料や顔料を組み合わせたものな
どが知られている。On the other hand, electrophotographic photoreceptors made of organic photoconductive substances include photoconductive polymers typified by poly-N-vinylcarbazole and 2,5-bis(p-diethylaminophenyl)-1,3,4-oxadi Those using low-molecular organic photoconductive substances such as azoles, and those in which such organic photoconductive substances are combined with various dyes and pigments are known.
有機光導電性物質を用いた電子写真感光体は成膜性がよ
く、塗工によって生産できるため、極めて生産性が高く
安価な感光体を提供できる利点を有している。また、使
用する染料や顔料の選択により、感色性を自在にコント
ロールできるなどの利点を有し、これまで1幅広い検討
が成されてきた。特に最近では、有機光導電性染料や顔
料を含有した電荷発生層と前述の光導電性ポリマーや低
分子の有機光導電性物質を含有した電荷輸送層を積層し
た機能分離型感光体の開発により、従来の有機電子写真
感光体の欠点とされていた感度や耐久性に著しい改善が
成されてきた。Electrophotographic photoreceptors using organic photoconductive substances have good film-forming properties and can be produced by coating, so they have the advantage of providing extremely highly productive and inexpensive photoreceptors. Furthermore, it has the advantage that color sensitivity can be freely controlled by selecting the dyes and pigments used, and a wide range of studies have been carried out so far. In particular, recent developments have led to the development of functionally separated photoreceptors in which a charge generation layer containing an organic photoconductive dye or pigment is laminated with a charge transport layer containing the aforementioned photoconductive polymer or low-molecular organic photoconductive substance. Significant improvements have been made in the sensitivity and durability, which were considered to be shortcomings of conventional organic electrophotographic photoreceptors.
アゾ顔料は優れた光導電性を示し、しかも、アゾ成分と
カプラー成分の組み合わせ方で様々な特性を持った化合
物が容易に得られることから、これまでに数多くの化合
物が提案されており、例えば特開昭54−22834号
公報、特開昭56−116040号公報、特開昭58−
70232号公報、特開昭60−131539号公報、
特開昭61−215556号公報および特開昭61−2
41763号公報などすでに公知である。Azo pigments exhibit excellent photoconductivity, and because compounds with various properties can be easily obtained by combining the azo component and coupler component, many compounds have been proposed so far, such as JP-A-54-22834, JP-A-56-116040, JP-A-58-
Publication No. 70232, Japanese Unexamined Patent Publication No. 131539/1983,
JP-A-61-215556 and JP-A-61-2
No. 41763 is already known.
しかしながら、従来のジスアゾ顔料を用いた電子写真感
光体は、感度や繰り返し使用時の電位安定性の面で必ず
しも十分なものとは言えず、実用化されているのは掻く
かな材料のみである。However, conventional electrophotographic photoreceptors using disazo pigments are not necessarily satisfactory in terms of sensitivity and potential stability during repeated use, and only katakana materials have been put into practical use.
[発明が解決しようとする課題〕
本発明の目的は新規な光導電性材料を提供すること、実
用的な高感度特性と繰り返し使用における安定な電位特
性を有する電子写真感光体を提供すること、該電子写真
感光体を備えた電子写真装置並びにファクシミリを提供
することにある。[Problems to be Solved by the Invention] The objects of the present invention are to provide a novel photoconductive material, an electrophotographic photoreceptor having practical high sensitivity characteristics and stable potential characteristics during repeated use; An object of the present invention is to provide an electrophotographic apparatus and a facsimile equipped with the electrophotographic photoreceptor.
E課題を解決する手段、作用]
本発明は導電性支持体上に下記一般式(1)で示すジス
アゾ顔料を含有する感光層を有することを特徴とする電
子写真感光体から構成される。E Means for Solving Problems and Effects] The present invention comprises an electrophotographic photoreceptor characterized by having a photosensitive layer containing a disazo pigment represented by the following general formula (1) on a conductive support.
一般式
式中、A、およびA1は同一または異なるフェノール性
水酸基を有するカプラー残基を表わす。In the general formula, A and A1 represent coupler residues having the same or different phenolic hydroxyl groups.
好ましい例としては下記一般式(2)〜(7)で示す残
基が挙げられる。Preferred examples include residues represented by the following general formulas (2) to (7).
一般式(2)、(3)、(4)および(5)中のXはベ
ンゼン環と縮合して置換基を有してもよいナフタレン環
、アントラセン環、カルバゾール環、ベンズカルバゾー
ル環、ジベンゾフラン環などの多環芳香環または複素環
を形成するに必要な残基を表わす。In general formulas (2), (3), (4) and (5), X is a naphthalene ring, an anthracene ring, a carbazole ring, a benzcarbazole ring, a dibenzofuran ring, which may be fused with a benzene ring and have a substituent. Represents residues necessary to form a polycyclic aromatic ring or heterocycle such as.
一般式(7)中のYは置換基を有してもよい2価の芳香
族炭化水素基ないしは窒素原子を環内に含む2価の複素
環基を表わし、具体的には0−フェニレン、0−ナフチ
レン、ペリナフチレン、12−アンスリレン、3,4−
ピラゾールジイル2.3−ピリジンジイル、4,5−ピ
リジンジイル、6.7−インダゾールジイル、6.7−
キラリンジイルなどの2価の基が挙げられる。Y in general formula (7) represents a divalent aromatic hydrocarbon group which may have a substituent or a divalent heterocyclic group containing a nitrogen atom in the ring, and specifically, 0-phenylene, 0-naphthylene, perinaphthylene, 12-antrylene, 3,4-
Pyrazolediyl 2,3-pyridinediyl, 4,5-pyridinediyl, 6,7-indazolediyl, 6.7-
Examples include divalent groups such as chiralediyl.
一般式(2)および(3)中のR1およびR2は水素原
子、置換基を有してもよいアルキル基、アリール基、ア
ラルキル基または複素環基を表わし、また、R,、R,
はともに窒素原子と結合して窒素原子を環内に含む環状
アミノ基を形成してもよい。R1 and R2 in general formulas (2) and (3) represent a hydrogen atom, an alkyl group that may have a substituent, an aryl group, an aralkyl group, or a heterocyclic group, and R,, R,
may be combined with a nitrogen atom to form a cyclic amino group containing a nitrogen atom in the ring.
一般式(4)および(5)中のR3は水素原子、置換基
を有してもよいアルキル基、アリール基アラルキル基ま
たは複素環基を表わす。R3 in general formulas (4) and (5) represents a hydrogen atom, an alkyl group which may have a substituent, an aryl group, an aralkyl group, or a heterocyclic group.
数式(6)中のR4は置換基を有してもよいアルキル基
、アリール基、アラルキル基または複素環基を表わす。R4 in formula (6) represents an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group which may have a substituent.
上記表現のアルキル基としてはメチル、エチル、プロピ
ルなどの基、アリール基の具体例としてはフェニル、ナ
フチル、アンスリルなどの基、アラルキル基としてはベ
ンジル、フェネチルなどの基、複素環基としてはピリジ
ル、チエニル、カルバゾリル、ベンゾイミダゾリル、ベ
ンゾチアゾリルなどの基、窒素原子を環内に含む環状ア
ミン基としてはピロール、ピロリン、ピロリジン、ピロ
リドン、インドール、インドリン、カルバゾール、イミ
ダゾール、ピラゾール、ピラゾリン、オキサジン、フェ
ノキサジンなどが挙げられる。Examples of alkyl groups in the above expression include methyl, ethyl, and propyl; specific examples of aryl groups include phenyl, naphthyl, and anthryl; aralkyl groups include benzyl and phenethyl; heterocyclic groups include pyridyl; Groups such as thienyl, carbazolyl, benzimidazolyl, and benzothiazolyl, and cyclic amine groups containing a nitrogen atom in the ring include pyrrole, pyrroline, pyrrolidine, pyrrolidone, indole, indoline, carbazole, imidazole, pyrazole, pyrazoline, oxazine, and phenoxazine. It will be done.
また置換基としては、フッ素、塩素、ヨウ素、臭素など
のハロゲン原子、メチル、エチル、プロピルなどのアル
キル基、メトキシ、エトキシなどのアルコキシ基、ジメ
チルアミノ、ジエチルアミノなどのアルキルアミノ基、
フェニルカルバモイル基、ニトロ基、シアン基、トリフ
ルオロメチルなどのへロメチル基などが挙げられる。Examples of substituents include halogen atoms such as fluorine, chlorine, iodine, and bromine; alkyl groups such as methyl, ethyl, and propyl; alkoxy groups such as methoxy and ethoxy; alkylamino groups such as dimethylamino and diethylamino;
Examples include a phenylcarbamoyl group, a nitro group, a cyanide group, and a helomethyl group such as trifluoromethyl.
−M式(2)および(4)中の2は酸素原子または硫黄
原子を表し、2はOまたは1の整数である。-M In formulas (2) and (4), 2 represents an oxygen atom or a sulfur atom, and 2 is an integer of O or 1.
また、本発明は感光層が一般式(1)で示すジスアゾ顔
料を含有する電荷発生層と電荷輸送層の少なくとも二層
からなる請求項1記載の電子写真感光体から構成される
。Further, the present invention comprises the electrophotographic photoreceptor according to claim 1, wherein the photosensitive layer comprises at least two layers: a charge generation layer containing a disazo pigment represented by general formula (1) and a charge transport layer.
なお、一般式(1)中、A、 、A2が一般式(2)、
(3)、(4)または(5)であり、該式中のXがベン
ゼン環と縮合してベンズカルバゾール環を形成している
カプラー残基である場合の顔料は、その吸収域が近赤外
領域付近まで広がるため、半導体レーザー用の電荷発生
材料としても好適である。In addition, in general formula (1), A, , A2 are general formula (2),
(3), (4) or (5), in which X is a coupler residue condensed with a benzene ring to form a benzcarbazole ring, the pigment has an absorption range near red. Since it spreads to the vicinity of the outer region, it is also suitable as a charge generating material for semiconductor lasers.
また、本発明は前記本発明の電子写真感光体を備えた電
子写真装置から構成される。Further, the present invention comprises an electrophotographic apparatus equipped with the electrophotographic photoreceptor of the present invention.
また、本発明は前記本発明の電子写真感光体を備えた電
子写真装置並びにリモート端末からの画像情報を受信す
る受信手段を有するファクシミリから構成される。Further, the present invention comprises an electrophotographic apparatus equipped with the electrophotographic photoreceptor of the present invention, and a facsimile machine having a receiving means for receiving image information from a remote terminal.
以下に本発明の一般式(1)で示すジスアゾ顔料の代表
的な具体例を列挙するが、本発明において用いる上記ジ
スアゾ顔料はこれらに限定されるものではない。Typical specific examples of the disazo pigment represented by the general formula (1) of the present invention are listed below, but the disazo pigment used in the present invention is not limited to these.
例示顔料は、基本型において、変化する部分のみを記載
することで具体的構造を表わすこととする。The specific structure of the exemplified pigment will be expressed by describing only the parts that change in the basic form.
基本型
例示顔料(1)
例示顔料(2)
例示顔料(3)
例示顔料
例示顔料(5)
例示顔料(6)
例示顔料(7)
例示顔料(8)
例示顔料(9)
例示顔料(lO)
例示顔料(11)
例示顔料(12)
例示顔料
H
例示顔料(14)
例示顔料(15)
例示顔料(16)
例示顔料(17)
例示顔料(18)
例示顔料(19)
例示顔料(20)
例示顔料(21)
例示顔料(22)
例示顔料(23)
例示顔料(24)
一般式(1)で示すジスアゾ顔料は、相当するジアミン
を常法によりテトラゾ化し、アルカリの存在下にカプラ
ーと水系でカップリングするか、テトラゾニウム塩をホ
ウフッ化塩や塩化亜鉛複塩などに変換した後、N、N−
ジメチルポルムアミド、ジメチルスルホキシドなどの有
機溶剤中で酢酸ソーダ、トリエチルアミン、N−メチル
モルボリンなどの塩基の存在下、カプラーとカップリン
グすることによって容易に合成できる。Basic Exemplary Pigment (1) Exemplary Pigment (2) Exemplary Pigment (3) Exemplary Pigment Exemplary Pigment (5) Exemplary Pigment (6) Exemplary Pigment (7) Exemplary Pigment (8) Exemplary Pigment (9) Exemplary Pigment (lO) Exemplary Pigment (11) Exemplary Pigment (12) Exemplary Pigment H Exemplary Pigment (14) Exemplary Pigment (15) Exemplary Pigment (16) Exemplary Pigment (17) Exemplary Pigment (18) Exemplary Pigment (19) Exemplary Pigment (20) Exemplary Pigment ( 21) Exemplary Pigment (22) Exemplary Pigment (23) Exemplary Pigment (24) The disazo pigment represented by the general formula (1) is obtained by tetrazotizing the corresponding diamine by a conventional method and coupling it with a coupler in an aqueous system in the presence of an alkali. Or, after converting the tetrazonium salt to borofluoride salt or zinc chloride double salt, N,N-
It can be easily synthesized by coupling with a coupler in an organic solvent such as dimethylpolamide or dimethyl sulfoxide in the presence of a base such as sodium acetate, triethylamine, or N-methylmorboline.
数式(1)中のA、、A2が相異なるカプラーであるジ
スアゾ顔料を合成する場合は、前述のテトラゾニウム塩
1モルに対し初めに一方のカプラー1モルをカップリン
グさせ、次いでもう一方のカプラー1モルをカップリン
グさせて合成するか、あるいはジアミンの一方のアミン
基をアセチル基などで保護しておき、これをジアゾ化し
一方のカプラーをカップリングさせた後、保護基を塩酸
などで加水分解し、これを再びジアゾ化しもう一方のカ
プラーをカップリングさせて合成することができる。When synthesizing a disazo pigment in which A, A2 in formula (1) are different couplers, first 1 mole of one coupler is coupled to 1 mole of the above-mentioned tetrazonium salt, and then 1 mole of the other coupler is coupled. It can be synthesized by coupling moles, or one amine group of the diamine is protected with an acetyl group, etc., this is diazotized, one coupler is coupled, and the protecting group is hydrolyzed with hydrochloric acid etc. , it can be synthesized by diazotizing it again and coupling it with the other coupler.
本発明の電子写真感光体は、導電性支持体上に一般式(
1)で示すジスアゾ顔料を含有する感光層を有する。感
光層の形態は公知のいかなる形態を取っていてもかまわ
ないが、一般式(1)で示すジスアゾ顔料を含有する感
光層を電荷発生層とし、これに電荷輸送物質を含有する
電荷輸送層を積層した機能分離型の感光層が特に好まし
い。The electrophotographic photoreceptor of the present invention has the general formula (
It has a photosensitive layer containing the disazo pigment shown in 1). The form of the photosensitive layer may be any known form; however, a photosensitive layer containing a disazo pigment represented by general formula (1) is used as a charge generation layer, and a charge transport layer containing a charge transporting substance is added thereto. Laminated functionally separated photosensitive layers are particularly preferred.
電荷発生層は、前記のアゾ顔料を適当な溶剤中でバイン
ダー樹脂と共に分散した塗布液を、導電性支持体上に公
知の方法によって塗布することによって形成することが
でき、その膜厚は例えば5μm以下、好ましくは0.1
=1umの薄膜層とすることが望ましい。The charge generation layer can be formed by coating a coating liquid in which the above-mentioned azo pigment is dispersed together with a binder resin in a suitable solvent on a conductive support by a known method, and the film thickness thereof is, for example, 5 μm. Below, preferably 0.1
A thin film layer of =1 um is desirable.
この際用いられるバインダー樹脂は、広範な絶縁性樹脂
あるいは有機光導電性ポリマーから選択されるが、ポリ
ビニルブチラール、ポリビニルベンザール、ボリアリレ
ート、ポリカーボネート、ポリエステル、フェノキシ樹
脂、セルロース系樹脂、アクリル樹脂、ポリウレタンな
どが好ましく、その使用量は電荷発生層中の含有率で8
0重量%以下、好ましくは40重量%以下である。The binder resin used in this case is selected from a wide range of insulating resins or organic photoconductive polymers, including polyvinyl butyral, polyvinylbenzal, polyarylate, polycarbonate, polyester, phenoxy resin, cellulose resin, acrylic resin, polyurethane. etc., and the amount used is 8% in terms of content in the charge generation layer.
It is 0% by weight or less, preferably 40% by weight or less.
また便用する溶剤は前記の樹脂を溶解し、後述の電荷輸
送層や下引層を溶解しないものから選択することが好ま
しい。The solvent to be used is preferably selected from those that dissolve the resin but do not dissolve the charge transport layer or undercoat layer, which will be described later.
具体的には、テトラヒドロフラン、1,4−ジオキサン
などのエーテル類、シクロヘキサノン、メチルエチルケ
トンなどのケトン類、N、N−ジメチルホルムアミドな
どのアミド類、酢酸メチル、酢酸エチルなどのエステル
類、トルエン、キシレン、クロロベンゼンなどの芳香族
類、メタノール、エタノール、2−プロパツールなどの
アルコール類、クロロホルム、塩化メチレン、ジクロル
エチレン、四塩化炭素、トリクロルエチレンなどの脂肪
族ハロゲン化炭化水素類など挙げられる。Specifically, ethers such as tetrahydrofuran and 1,4-dioxane, ketones such as cyclohexanone and methyl ethyl ketone, amides such as N,N-dimethylformamide, esters such as methyl acetate and ethyl acetate, toluene, xylene, Examples include aromatics such as chlorobenzene, alcohols such as methanol, ethanol, and 2-propanol, and aliphatic halogenated hydrocarbons such as chloroform, methylene chloride, dichloroethylene, carbon tetrachloride, and trichlorethylene.
電荷輸送層は電荷発生層の上または下に積層され、電界
の存在下電荷発生層から電荷キャリアを受取り、これを
輸送する機能を有している。The charge transport layer is laminated above or below the charge generation layer, and has the function of receiving charge carriers from the charge generation layer in the presence of an electric field and transporting them.
電荷輸送層は電荷輸送物質を必要に応じて適当なバイン
ダー樹脂と共に溶剤中に溶解し塗布することによって形
成され、その膜厚は一般的には5〜40μmであるが1
5〜30umが好ましい。The charge transport layer is formed by dissolving a charge transport substance in a solvent together with an appropriate binder resin as necessary and coating the layer, and the film thickness is generally 5 to 40 μm, but 1
5 to 30 um is preferable.
電荷輸送物質は電子輸送性物質と正孔輸送性物質があり
、電子輸送性物質としては、例えば2゜4.7−1−リ
ニトロフルオレノン、2,4,5゜7−チトラニトロフ
ルオレノン、クロラニル、テトラシアノキノジメタンな
どの電子吸引性物質やこれら電子吸引性物質を高分子化
したものなどが挙げられる。Charge transport substances include electron transport substances and hole transport substances. Examples of electron transport substances include 2°4,7-1-linitrofluorenone, 2,4,5°7-titranitrofluorenone, and chloranil. Examples include electron-withdrawing substances such as , tetracyanoquinodimethane, and polymers of these electron-withdrawing substances.
正孔輸送性物質としてはピレン、アントラセンなどの多
環芳香族化合物、カルバゾール系、インドール系、イミ
ダゾール系、オキサゾール系、チアゾール系、オキサジ
アゾール系、ピラゾール系ピラゾリン系、チアジアゾー
ル系、トリアゾール系化合物などの複素環化合物、p−
ジエチルアミノベンズアルデヒド−N、N−ジフェニル
ヒドラゾン、N、N−ジフェニルヒドラジノ−3−メチ
リデン−9−エチルカルバゾールなどのヒドラゾン系化
合物、α−フェニル−4−N、N−ジフェニルアミノス
チルベン、5− [4−(ジ−p−トリルアミノ)ベン
ジリデン] −5H−ジベンゾ[a、d] シクロヘプ
テンなどのスチリル系化合物、ベンジジン系化合物、ト
リアリールメタン系化合物、トリフェニルアミンあるい
は、これらの化合物から成る基を主鎖または側鎖に有す
るポリマー(例えばポリ−N−ビニルカルバゾール、ポ
リビニルアントラセンなど)が挙げられる。Hole-transporting substances include polycyclic aromatic compounds such as pyrene and anthracene, carbazole-based, indole-based, imidazole-based, oxazole-based, thiazole-based, oxadiazole-based, pyrazole-based pyrazoline-based, thiadiazole-based, triazole-based compounds, etc. heterocyclic compound, p-
Hydrazone-based compounds such as diethylaminobenzaldehyde-N,N-diphenylhydrazone, N,N-diphenylhydrazino-3-methylidene-9-ethylcarbazole, α-phenyl-4-N,N-diphenylaminostilbene, 5-[4 -(di-p-tolylamino)benzylidene] -5H-dibenzo[a, d] A styryl compound such as cycloheptene, a benzidine compound, a triarylmethane compound, triphenylamine, or a group consisting of these compounds in the main chain Alternatively, polymers having side chains (eg, poly-N-vinylcarbazole, polyvinylanthracene, etc.) can be mentioned.
これらの有機電荷輸送物質の他にセレン、セレン−テル
ル、アモルファスシリコン、硫化カドミウムなどの無機
材料も用いることができる。In addition to these organic charge transport materials, inorganic materials such as selenium, selenium-tellurium, amorphous silicon, and cadmium sulfide can also be used.
また、これらの電荷輸送物質は1種または2種以上組合
せて用いることができる。Further, these charge transport materials can be used alone or in combination of two or more.
電荷輸送物質が成膜性を有していないときには適当なバ
インダーを用いることができる。具体的には、アクリル
樹脂、ボリアリレート、ポリエステル、ポリカーボネー
ト、ポリスチレン、アクリロニトリル−スチレンコポリ
マー、ポリアクリルアミド、ポリアミド、塩素化ゴムな
どの絶縁性樹脂あるいはポリ−N−ビニルカルバゾール
、ポリビニルアントラセンなどの有機光導電性ポリマー
などが挙げられる。When the charge transport material does not have film-forming properties, a suitable binder can be used. Specifically, insulating resins such as acrylic resin, polyarylate, polyester, polycarbonate, polystyrene, acrylonitrile-styrene copolymer, polyacrylamide, polyamide, and chlorinated rubber, or organic photoconductive resins such as poly-N-vinylcarbazole and polyvinylanthracene. Polymers and the like can be mentioned.
感光層が形成される導電性支持体としては、例えばアル
ミニウム、アルミニウム合金、銅、亜鉛、ステンレス、
バナジウム、モリブデン、クロム、チタン、ニッケル、
インジウム、金や白金などが用いられる。またこうした
金属あるいは合金を、真空蒸着法によって被膜形成した
プラスチック(例えばポリエチレン、ポリプロピレン、
ポリ塩化ビニル、ポリエチレンテレフタレート、アクリ
ル樹脂など)や、導電性粒子(例えばカーボンブラック
、銀粒子など)を適当なバインダー樹脂と共にプラスチ
ックまたは金属基板上に被覆した支持体あるいは導電性
粒子をプラスチックや紙に含浸した支持体などを用いる
ことができる。Examples of the conductive support on which the photosensitive layer is formed include aluminum, aluminum alloy, copper, zinc, stainless steel,
vanadium, molybdenum, chromium, titanium, nickel,
Indium, gold, platinum, etc. are used. Plastics (e.g. polyethylene, polypropylene,
Polyvinyl chloride, polyethylene terephthalate, acrylic resin, etc.) or conductive particles (e.g. carbon black, silver particles, etc.) are coated on a plastic or metal substrate with a suitable binder resin, or conductive particles are coated on plastic or paper. An impregnated support or the like can be used.
導電性支持体と感光層の中間にバリヤー機部と接着機能
をもつ下引き層を設けることもできる。An undercoat layer having a barrier function and an adhesive function can also be provided between the conductive support and the photosensitive layer.
下引き層はカゼイン、ポリビニルアルコール、ニトロセ
ルロース、ポリアミド(ナイロン6、ナイロン66、ナ
イロン610、共重合ナイロン、アルコキシメチル化ナ
イロンなど)、ポリウレタン、酸化アルミニウムなどに
よって形成できる。The undercoat layer can be formed of casein, polyvinyl alcohol, nitrocellulose, polyamide (nylon 6, nylon 66, nylon 610, copolymerized nylon, alkoxymethylated nylon, etc.), polyurethane, aluminum oxide, or the like.
下引き層の膜厚は5μm以下、好ましくは01〜3μm
が適当である。The thickness of the undercoat layer is 5 μm or less, preferably 01 to 3 μm.
is appropriate.
本発明の別の具体例として、航述のジスアゾ顔料と電荷
輸送物質を同一層に含有させた電子写真感光体を挙げる
ことができる。この際、電荷輸送物質としてポリ−N−
ビニルカルバゾールとトリニトロフルオレノンからなる
電荷移動錯体を用いることもできる。Another specific example of the present invention is an electrophotographic photoreceptor containing the aforementioned disazo pigment and charge transport material in the same layer. At this time, poly-N-
Charge transfer complexes consisting of vinyl carbazole and trinitrofluorenone can also be used.
この例の電子写真感光体は、前述のジスアゾ顔料と電荷
移動錯体を適当な樹脂溶液中に分散させた液を塗布乾燥
して形成することができる。The electrophotographic photoreceptor of this example can be formed by coating and drying a solution in which the above-mentioned disazo pigment and charge transfer complex are dispersed in a suitable resin solution.
いずれの電子写真感光体においても用いる顔料は一般式
(1)で示すジスアゾ顔料の結晶形は非晶質であっても
結晶質であってもよく、また必要に応じて一般式(1)
で示すジスアゾ顔料を2種類以上組み合せたり、公知の
電荷発生物質と組み合せて使用することも可能である。The pigment used in any of the electrophotographic photoreceptors is a disazo pigment represented by the general formula (1). The crystal form of the disazo pigment may be amorphous or crystalline.
It is also possible to use a combination of two or more kinds of disazo pigments shown in the following, or to use them in combination with a known charge generating substance.
本発明の電子写真感光体は電子写真複写機に利用するの
みならず、レーザービームプリンタCRTプリンター、
LEDプリンター、液晶プリンター、レーザー製版、フ
ァクシミリのプリンターなどの電子写真応用分野にも広
く用いることができる。The electrophotographic photoreceptor of the present invention can be used not only for electrophotographic copying machines, but also for laser beam printers, CRT printers,
It can also be widely used in electrophotographic applications such as LED printers, liquid crystal printers, laser engravings, and facsimile printers.
次に、本発明の電子写真感光体を備えた電子写真装置並
びにファクシミリについて説明する。Next, an electrophotographic apparatus and a facsimile equipped with the electrophotographic photoreceptor of the present invention will be described.
第1図に本発明のドラム型感光体を用いた一般的な転写
式電子写真装置の概略構成を示した。FIG. 1 shows a schematic configuration of a general transfer type electrophotographic apparatus using the drum type photoreceptor of the present invention.
図において、1は像担持体としてのドラム型感光体であ
り軸1aを中心に矢印方向に所定の周速度で回転駆動さ
れる。該感光体1はその回転過程で帯電手段2によりそ
の周面に正または負の所定電位の均一帯電を受け、次い
で露光部3にて不図示の像露光手段により光像露光しく
スリット露光・レーザービーム走査露光など)を受ける
。In the figure, reference numeral 1 denotes a drum-type photoreceptor as an image carrier, which is rotated at a predetermined circumferential speed in the direction of the arrow around an axis 1a. During the rotation process, the photoreceptor 1 is uniformly charged to a predetermined positive or negative potential on its circumferential surface by the charging means 2, and then exposed to a light image by an image exposure means (not shown) in the exposure section 3, such as slit exposure/laser. beam scanning exposure, etc.).
これにより感光体周面に露光像に対応した静電潜像が順
次形成されていく。As a result, electrostatic latent images corresponding to the exposed images are sequentially formed on the circumferential surface of the photoreceptor.
その静電潜像は、次いで現像手段4でトナー現像され、
そのトナー現像像が転写手段5により不図示の給紙部か
ら感光体lと転写手段5との間に感光体1の回転と同期
取りされて給送された転写材Pの面に順次転写されてい
く。The electrostatic latent image is then developed with toner by the developing means 4,
The toner developed image is sequentially transferred by the transfer means 5 from a paper feeding section (not shown) onto the surface of the transfer material P, which is fed between the photoreceptor l and the transfer means 5 in synchronization with the rotation of the photoreceptor 1. To go.
像転写を受けた転写材Pは感光体面から分離されて像定
着手段8へ導入されて像定着を受けて複写物(コピー)
として機外ヘプリントアウトされる。The transfer material P that has undergone the image transfer is separated from the photoreceptor surface and introduced into the image fixing means 8, where the image is fixed and a copy is produced.
will be printed out on the outside of the aircraft.
像転写後の感光体1の表面はクリーニング手段6にて転
写残りトナーの除去を受けて清浄面化され、前露光手段
7により除電処理がされて繰り返して像形成に使用され
る。After the image has been transferred, the surface of the photoreceptor 1 is cleaned by a cleaning means 6 to remove residual toner, and subjected to a charge removal process by a pre-exposure means 7, and is repeatedly used for image formation.
感光体lの均一帯電手段2としてはコロナ帯電装置が一
般に広く使用されている。As the uniform charging means 2 for the photoreceptor 1, a corona charging device is generally widely used.
また、転写装置5もコロナ転写手段が一般に広く使用さ
れている。Further, as for the transfer device 5, a corona transfer means is generally widely used.
電子写真装置として、上述の感光体や現像手段クリーニ
ング手段などの構成要素のうち、複数のものを装置ユニ
ットとして一体に結合して構成し、このユニットを装置
本体に対して着脱自在に構成しても良い。例えば、感光
体1とクリーニング手段6とを一体化してひとつの装置
ユニットとし、装置本体のレールなどの案内手段を用い
て着脱自在の構成にしても良い。このとき、上記の装置
ユニットのほうに帯電手段および/または現像手段を伴
って構成しても良い。An electrophotographic apparatus is constructed by combining a plurality of components such as the photoreceptor and developing means cleaning means described above into an apparatus unit, and this unit is configured to be detachable from the apparatus main body. Also good. For example, the photoreceptor 1 and the cleaning means 6 may be integrated into one device unit, and configured to be detachable using a guide means such as a rail of the device body. At this time, the above-mentioned device unit may include a charging means and/or a developing means.
また、光像露光しは、電子写真装置を複写機やプリンタ
ーとして使用する場合には、原稿からの反射光や透過光
、あるいは、原稿を読み取り信号化し、この信号により
レーザービームの走査、発光ダイオードアレイの駆動、
または液晶シャッターアレイの駆動などにより行われる
。In addition, when an electrophotographic device is used as a copying machine or a printer, light image exposure involves scanning the reflected light or transmitted light from the document, or by reading the document and converting it into a signal. driving the array,
Alternatively, it is performed by driving a liquid crystal shutter array.
また、ファクシミリのプリンターとして使用する場合に
は、光像露光しは受信データをプリントするための露光
になる。Furthermore, when used as a facsimile printer, the optical image exposure is exposure for printing received data.
第2図は、この場合の1例をブロック図で示したもので
ある。FIG. 2 is a block diagram showing an example of this case.
コントローラ11は画像読取部10とプリンター19を
制御する。The controller 11 controls the image reading section 10 and the printer 19.
コントローラ11の全体はCPU17により制御されて
いる。The entire controller 11 is controlled by a CPU 17.
画像読取部からの読取りデータは、送信回路13を通し
て相手局に送信される。相手局から受けたデータは受信
回路12を通してプリンター19に送られる。画像メモ
リには所定の画像データが記憶される。プリンタコント
ローラ18はプリンター19を制御している。14は電
話である。The read data from the image reading unit is transmitted to the partner station through the transmitting circuit 13. Data received from the partner station is sent to the printer 19 through the receiving circuit 12. Predetermined image data is stored in the image memory. A printer controller 18 controls a printer 19. 14 is a telephone.
回線15から受信された画像(回線を介して接続された
リモート端末からの画像情報)は、受信回路12で復調
された後、CPLI 17は画像情報の信号処理を行い
順次画像メモリ16に格納される。そして、少なくとも
1ページの画像がメモリ16に格納されると、そのペー
ジの画像記憶を行う。CPU17は、メモリ16より1
ページの画像情報を読み出しプリンタコントローラ18
に信号かされた1ページの画像情報を送出する。The image received from the line 15 (image information from a remote terminal connected via the line) is demodulated by the receiving circuit 12, and then the CPLI 17 performs signal processing on the image information and sequentially stores it in the image memory 16. Ru. When at least one page of images is stored in the memory 16, the image of that page is stored. The CPU 17 uses 1 from the memory 16.
Printer controller 18 reads page image information
1 page of image information signaled to is sent out.
プリンタコントローラ18は、CPU 17からの1ペ
ージの画像情報を受は取るとそのページの画像情報記録
を行うべく、プリンタ19を制御する。When the printer controller 18 receives one page of image information from the CPU 17, it controls the printer 19 to record the image information of that page.
なお、CPU17は、プリンタ19による配録中に、次
のページの受信を行っている。Note that the CPU 17 receives the next page while the printer 19 is recording.
以上のように、画像の受信と記録が行われる。As described above, images are received and recorded.
[実施例]
実施例1〜15
アルミ基板上にメトキシメチル化ナイロン(重量平均分
子量3万2千)7gとアルコール可溶性共重合ナイロン
(重量平均分子量5万7千)10gをメタノール95g
に溶解した液をマイヤーパーで塗布し、乾燥後の膜厚が
1μmの下引き層を形成けた。[Example] Examples 1 to 15 7 g of methoxymethylated nylon (weight average molecular weight 32,000) and 10 g of alcohol-soluble copolymerized nylon (weight average molecular weight 57,000) were placed on an aluminum substrate in 95 g of methanol.
A solution dissolved in the above was applied using a Mayer Par to form an undercoat layer having a thickness of 1 μm after drying.
次に例示顔料(2)を5gをシクロへキサノン95gに
ブチラール樹脂(ブチラール化度63モル%)を2gを
溶かした液に加え、サンドミルで13時間分散した。こ
の分散液を先に形成した下引き層の上に乾燥後の膜厚が
0.17μmとなるようにマイヤーバーで塗布し、乾燥
して電荷発生層を形成した。Next, 5 g of Exemplified Pigment (2) was added to a solution prepared by dissolving 2 g of butyral resin (butyralization degree 63 mol %) in 95 g of cyclohexanone, and dispersed in a sand mill for 13 hours. This dispersion was applied onto the previously formed undercoat layer using a Mayer bar so that the film thickness after drying would be 0.17 μm, and dried to form a charge generation layer.
次に、下記構造式で示すフルオレン化合物5gとポリカ
ーボネートZ型樹脂(重量平均分子量7万)5gをクロ
ロベンゼン40gに溶解し、これを電荷発生層の上に乾
燥後の膜厚が18gmとなるようにマイヤーバーで塗布
し、乾燥して電荷輸送層を形成し、実施例1の電子写真
感光体を作成した。Next, 5 g of a fluorene compound represented by the structural formula below and 5 g of polycarbonate Z type resin (weight average molecular weight 70,000) were dissolved in 40 g of chlorobenzene, and this was placed on the charge generation layer so that the film thickness after drying was 18 gm. The electrophotographic photoreceptor of Example 1 was prepared by coating with a Mayer bar and drying to form a charge transport layer.
例示顔料(2)に代えて他の例示顔料を用い、実施例2
〜工5に対応する電子写真感光体を全く同様にして作成
した。Example 2 using other exemplary pigments in place of exemplary pigment (2)
An electrophotographic photoreceptor corresponding to Steps 5 to 5 was prepared in exactly the same manner.
作成した電子写真感光体を川口電機■製、静電複写紙試
験装置Model 5P−428を用いて一5KVのコ
ロナ放電で負に帯電し、暗所で1秒間保持した後、ハロ
ゲンランプを用いて照度10ルツクスで露光し、帯電特
性を評価した。The prepared electrophotographic photoreceptor was negatively charged with a corona discharge of 15 KV using an electrostatic copying paper tester Model 5P-428 manufactured by Kawaguchi Denki ■, held in a dark place for 1 second, and then charged with a halogen lamp. It was exposed to light at an illuminance of 10 lux and the charging characteristics were evaluated.
帯電特性としては、表面電位■。と暗所放置後の表面電
位が172に減衰するに必要な露光量E1/2を測定し
た。結果を示す。As for charging characteristics, surface potential ■. The exposure amount E1/2 required for the surface potential to attenuate to 172 after being left in a dark place was measured. Show the results.
8(l 1
7001゜
700 1゜
69g 1゜
698 l
701 2゜
699 1゜
698 1゜
12 (18) 699 1. 1
213 (19) 698 0.8
914 (22) 698 1.3
315 (23) 699 1.1
7比較例1〜3
実施例1に用いたアゾ顔料を下記構造式で示す比較顔料
(A)〜(C)に代えた他は、実施例1と全(同様にし
て電子写真感光体を作成し、同様に帯電特性を評価した
。結果を示す。8 (l 1 7001°700 1°69g 1°698 l 701 2°699 1°698 1°12 (18) 699 1. 1
213 (19) 698 0.8
914 (22) 698 1.3
315 (23) 699 1.1
7 Comparative Examples 1 to 3 Electrophotographic photoreceptors were prepared in the same manner as in Example 1, except that the azo pigment used in Example 1 was replaced with comparative pigments (A) to (C) shown by the following structural formulas. The charging characteristics were similarly evaluated.The results are shown below.
比較顔料(A)
比較顔料
(B)
比較顔料
(C)
1 (A) 698 6.82
(B) 702 3.53
(C) 699 5.9こ
の結果から、本発明の電子写真感光体は十分な帯電能と
優れた感度を有することが分かる。Comparative pigment (A) Comparative pigment (B) Comparative pigment (C) 1 (A) 698 6.82
(B) 702 3.53
(C) 699 5.9 From these results, it can be seen that the electrophotographic photoreceptor of the present invention has sufficient charging ability and excellent sensitivity.
実施例16〜30
実施例1で作成した電子写真感光体を−6,5KVのコ
ロナ帯電器、露光光学系、現像器、転写帯電器、除電露
光光学系およびクリーナーを備えた電子写真複写機のシ
リンダーに貼り付けた。Examples 16 to 30 The electrophotographic photoreceptor prepared in Example 1 was used in an electrophotographic copying machine equipped with a -6.5 KV corona charger, an exposure optical system, a developer, a transfer charger, a static elimination exposure optical system, and a cleaner. Attached to the cylinder.
初期の暗部電位■。と明部電位VLをそれぞれ−700
■、−200V付近に設定し、5千回繰り返し使用した
際の暗部電位の変動量(Δ■o)と明部電位の変動量(
ΔVL)を測定した。Initial dark potential■. and bright area potential VL are -700 respectively.
■The amount of variation in dark area potential (Δ■o) and the amount of variation in light area potential (Δ■o) when set to around -200V and used repeatedly 5,000 times.
ΔVL) was measured.
実施例2〜15で作成した電子写真感光体についても同
様に評価を行った。結果を示す。The electrophotographic photoreceptors prepared in Examples 2 to 15 were also evaluated in the same manner. Show the results.
なお、電位の変動量における負記号は電位の絶対値の低
下を表わし、正記号は電位の絶対値の増加を表わす。Note that a negative sign in the amount of change in potential represents a decrease in the absolute value of the potential, and a positive sign represents an increase in the absolute value of the potential.
l 6 + 2
17 +5
19 +3
21 + 2
22 +4
23 + 2
24 + 1
25 +2
+ 2
+ 2
+ 3
+4
+1
30 +3
+ 3
l
比較例4〜6
比較例1〜3で作成した電子写真感光体を実施例16と
同じ方法で繰り返し便用時の電位変動量を測定した。結
果を示す。l 6 + 2 17 +5 19 +3 21 + 2 22 +4 23 + 2 24 + 1 25 +2 + 2 + 2 + 3 +4 +1 30 +3 + 3 l Comparative Examples 4 to 6 Electrophotographic photosensitive materials prepared in Comparative Examples 1 to 3 The body was repeatedly subjected to the same method as in Example 16 to measure the amount of potential fluctuation during defecation. Show the results.
5 −52 +386
−80 +58*は感度悪くおよび残留
電位が大きく
初期設定できず
上記の結果から、本発明の電子写真感光体は繰り返し便
用時の電位変動が少ないことが分かる。5 -52 +386
-80 +58* has poor sensitivity and a large residual potential, making it difficult to initialize, and from the above results, it can be seen that the electrophotographic photoreceptor of the present invention has little potential fluctuation during repeated use.
実施例31
アルミ蒸着ポリエチレンテレフタレートフィルムのアル
ミ面上に膜厚0.5μmのポリビニルアルコールの下引
き層を形成した。この上に実施例3で用いたジスアゾ顔
料の分散液をマイヤーバーで塗布乾燥して、膜厚0.2
μmの電荷発生層を形成した。Example 31 A subbing layer of polyvinyl alcohol having a thickness of 0.5 μm was formed on the aluminum surface of an aluminum vapor-deposited polyethylene terephthalate film. On top of this, the dispersion of the disazo pigment used in Example 3 was applied with a Mayer bar and dried, resulting in a film thickness of 0.2
A charge generation layer of .mu.m was formed.
次いで下記構造式のスチリル化合物10gとポリカーボ
ネート樹脂(重量平均分子量6万)85gをテトラヒド
ロフラン70gに溶かした液を電荷発生層の上に塗布乾
燥して、膜厚18umの電荷輸送層を形成した。Next, a solution prepared by dissolving 10 g of a styryl compound having the following structural formula and 85 g of a polycarbonate resin (weight average molecular weight: 60,000) in 70 g of tetrahydrofuran was applied onto the charge generation layer and dried to form a charge transport layer with a thickness of 18 um.
作成した電子写真感光体について帯電特性と耐久特性を
実施例1と実施例16と同じ方法によって測定した。結
果を示す。The charging characteristics and durability characteristics of the produced electrophotographic photoreceptor were measured in the same manner as in Examples 1 and 16. Show the results.
V、ニー700V
El/2:0.88J2ux−sec
ΔVo:+2V
ΔVL ニー3V
実施例32
実施例13で作成した電子写真感光体の電荷発生層と電
荷輸送層を逆の順番で塗布した電子写真感光体を作成し
、実施例1と同じ方法で帯電特性を評価した。ただし、
帯電は正帯電とした。V, knee 700V El/2: 0.88J2ux-sec ΔVo: +2V ΔVL knee 3V Example 32 Electrophotographic photosensitive material in which the charge generation layer and charge transport layer of the electrophotographic photoreceptor prepared in Example 13 were applied in the reverse order. A sample was prepared, and the charging characteristics were evaluated in the same manner as in Example 1. however,
The charging was positive.
V、:+699V
El/2:0.8112ux−sec
実施例33
実施例15で作成した電荷発生層上に2.4゜7−ドリ
ニトロー9−フルオレノン5gとポリ−4,4°−ジオ
キシジフェニル−2,2−プロパンカーボネート(分子
量30万)5gをテトラヒドロフラン50gに溶解した
液をマイヤーバーで塗布乾燥して膜厚18μmの電荷輸
送層を形成した。V,: +699V El/2: 0.8112ux-sec Example 33 On the charge generation layer prepared in Example 15, 5 g of 2.4°7-dolinitro-9-fluorenone and poly-4,4°-dioxydiphenyl- A solution prepared by dissolving 5 g of 2,2-propane carbonate (molecular weight: 300,000) in 50 g of tetrahydrofuran was coated with a Mayer bar and dried to form a charge transport layer with a thickness of 18 μm.
作成した電子写真感光体について実施例1と同じ方法で
帯電特性を評価した。ただし、帯電は正帯電とした。The charging characteristics of the produced electrophotographic photoreceptor were evaluated in the same manner as in Example 1. However, the charging was positive.
V、:+696V
E 1/2 : 1.81ux −sec実施例34
例示顔料(8)を0.5gをシクロヘキサノン9.5g
と共にペイントシェイカーで7時間分散した。ここへ実
施例1で用いた電荷輸送材料10gとポリカーボネート
樹脂8.5gをテトラヒドロフラン85gに溶かした液
を加え、さらに1時間振とうした。こうして調製した塗
布液をアルミ基板上にマイヤーバーで塗布乾燥して膜厚
17μmの感光層を形成した。V,: +696V E 1/2: 1.81ux -sec Example 34 0.5g of exemplified pigment (8) and 9.5g of cyclohexanone
It was also dispersed in a paint shaker for 7 hours. A solution prepared by dissolving 10 g of the charge transport material used in Example 1 and 8.5 g of polycarbonate resin in 85 g of tetrahydrofuran was added thereto, and the mixture was further shaken for 1 hour. The coating solution thus prepared was applied onto an aluminum substrate using a Mayer bar and dried to form a photosensitive layer with a thickness of 17 μm.
作成した電子写真感光体を実施例1と同じ方法で帯電特
性を評価した。帯電は正帯電とした。The charging characteristics of the produced electrophotographic photoreceptor were evaluated in the same manner as in Example 1. The charging was positive.
■。:+698V
El/2 : 3.2J2ux−sec[発明の効果]
本発明の電子写真感光体は、感光層に特定構造のジスア
ゾ顔料を用いたことにより、感光層内部における電荷キ
ャリアの発生効率ないしは注入効率のいずれか一方ある
いは双方が改善され、感度や繰り返し使用時の電位安定
性に優れた特性が得られるという顕著な効果を奏し、更
に、電子写真装置並びにファクシミリに用いて同様の優
れた効果を奏する。■. : +698V El/2 : 3.2J2ux-sec [Effects of the Invention] The electrophotographic photoreceptor of the present invention uses a disazo pigment with a specific structure in the photosensitive layer, thereby improving the generation efficiency or injection of charge carriers inside the photosensitive layer. It has the remarkable effect of improving one or both of the efficiency and providing excellent characteristics in sensitivity and potential stability during repeated use, and furthermore, it has the same excellent effect when used in electrophotographic equipment and facsimiles. play.
第1図は一般的な転写式電子写真装置の概略構成図であ
る。
符号lは像担持体としてのドラム型感光体(本発明の電
子写真感光体)、2はコロナ帯電装置、3は露光部、4
は現像手段、5は転写手段、6はクリーニング手段、7
は前露光手段、8は像定着手段、Lは光像露光、Pは像
転写を受けた転写材である。
第2区は電子写真装置をプリンターとして使用したファ
クシミリのブロック図である。
符号10は画像読取部、11はコントローラー12は受
信回路、13は送信回路、14は電話15は回線、16
は画像メモリ、17はCPU18はプリンタコントロー
ラ、19はプリンターである。FIG. 1 is a schematic diagram of a general transfer type electrophotographic apparatus. Symbol 1 is a drum type photoreceptor (electrophotographic photoreceptor of the present invention) as an image carrier, 2 is a corona charging device, 3 is an exposure section, 4
is a developing means, 5 is a transfer means, 6 is a cleaning means, 7
8 is a pre-exposure means, 8 is an image fixing means, L is a light image exposure, and P is a transfer material subjected to image transfer. The second section is a block diagram of a facsimile machine that uses an electrophotographic device as a printer. 10 is an image reading unit, 11 is a controller 12 is a receiving circuit, 13 is a transmitting circuit, 14 is a telephone 15 is a line, 16
17 is an image memory, 17 is a CPU 18 is a printer controller, and 19 is a printer.
Claims (1)
顔料を含有する感光層を有することを特徴とする電子写
真感光体。 一般式 ▲数式、化学式、表等があります▼(1) 式中、A_1およびA_2は同一または異なるフェノー
ル性水酸基を有するカプラー残基を表わす。 2、感光層が一般式(1)で示すジスアゾ顔料を含有す
る電荷発生層と、電荷輸送層の少なくとも二層からなる
請求項1記載の電子写真感光体。 3、請求項1記載の電子写真感光体を備えた電子写真装
置。 4、請求項1記載の電子写真感光体を備えた電子写真装
置およびリモート端末からの画像情報を受信する受信手
段を有するファクシミリ。[Scope of Claims] 1. An electrophotographic photoreceptor comprising a photosensitive layer containing a disazo pigment represented by the following general formula (1) on a conductive support. General formula ▲ Numerical formula, chemical formula, table, etc. ▼ (1) In the formula, A_1 and A_2 represent coupler residues having the same or different phenolic hydroxyl groups. 2. The electrophotographic photoreceptor according to claim 1, wherein the photosensitive layer comprises at least two layers: a charge generation layer containing a disazo pigment represented by general formula (1) and a charge transport layer. 3. An electrophotographic apparatus comprising the electrophotographic photoreceptor according to claim 1. 4. A facsimile machine comprising an electrophotographic apparatus comprising the electrophotographic photoreceptor according to claim 1 and a receiving means for receiving image information from a remote terminal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23699990A JP2811363B2 (en) | 1990-09-10 | 1990-09-10 | Electrophotographic photoreceptor, electrophotographic apparatus provided with the electrophotographic photoreceptor, and facsimile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23699990A JP2811363B2 (en) | 1990-09-10 | 1990-09-10 | Electrophotographic photoreceptor, electrophotographic apparatus provided with the electrophotographic photoreceptor, and facsimile |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04118659A true JPH04118659A (en) | 1992-04-20 |
JP2811363B2 JP2811363B2 (en) | 1998-10-15 |
Family
ID=17008887
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23699990A Expired - Fee Related JP2811363B2 (en) | 1990-09-10 | 1990-09-10 | Electrophotographic photoreceptor, electrophotographic apparatus provided with the electrophotographic photoreceptor, and facsimile |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2811363B2 (en) |
-
1990
- 1990-09-10 JP JP23699990A patent/JP2811363B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2811363B2 (en) | 1998-10-15 |
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