JPH04105787A - Filler metal for surface reforming of aluminum material - Google Patents

Filler metal for surface reforming of aluminum material

Info

Publication number
JPH04105787A
JPH04105787A JP22081690A JP22081690A JPH04105787A JP H04105787 A JPH04105787 A JP H04105787A JP 22081690 A JP22081690 A JP 22081690A JP 22081690 A JP22081690 A JP 22081690A JP H04105787 A JPH04105787 A JP H04105787A
Authority
JP
Japan
Prior art keywords
aluminum
filler metal
aluminum material
wear resistance
welding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22081690A
Other languages
Japanese (ja)
Inventor
Shigetoshi Jogan
茂利 成願
Ichizo Tsukuda
市三 佃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Altemira Co Ltd
Original Assignee
Showa Aluminum Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Aluminum Corp filed Critical Showa Aluminum Corp
Priority to JP22081690A priority Critical patent/JPH04105787A/en
Publication of JPH04105787A publication Critical patent/JPH04105787A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To form a surface reformed layer having excellent wear resistance on an aluminum material by using an aluminum alloy filler metal contg. prescribed ratios of Si, Cu and Ni and build-up welding this filler metal to the desired section of an aluminum base metal. CONSTITUTION:The filler metal for surface reforming of the aluminum consisting of 1 to 30w.% Si, 1 to 30wt.% Cu and 1 to 5wt.% Ni and consisting of the balance aluminum and unavoidable impurities is welded to the surface of the aluminum material to form the surface reformed layer. The surface reformed layer having excellent wear resistance and adhesive property is formed, by which the application range of the aluminum material to wear resistant parts is widened.

Description

【発明の詳細な説明】 産業上の利用分野 この発明は溶加材、特にアルミニウム材の表面を硬化さ
せて耐摩耗性に優れたアルミニウム合金材となすのに用
いられる溶加材に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention relates to a filler metal, particularly a filler metal used to harden the surface of an aluminum material to form an aluminum alloy material with excellent wear resistance.

なお、この明細書においてアルミニウムの語はその合金
を含む意味で用いる。
In this specification, the term aluminum is used to include its alloys.

従来の技術 周知のように、アルミニウムは汎用されている鉄系材料
等と比較して格段に軽量であるのに加え、熱伝導特性に
優れ、また耐食性も優れるところから、最近では自動車
等の各種機械部品として広く使用されるようになってき
ている。
As is well known in the art, aluminum is much lighter than commonly used iron-based materials, has excellent thermal conductivity, and has excellent corrosion resistance. It is becoming widely used as a mechanical part.

しかしながら、一般にアルミニウムは鉄系材料と比較し
て耐摩耗性に劣り、このことが自動車等における軽量化
等を目的として鉄系部材をAρ合金部材に代える際の大
きな障害となっていた。
However, aluminum generally has inferior wear resistance compared to iron-based materials, and this has been a major obstacle when replacing iron-based members with Aρ alloy members for the purpose of reducing weight in automobiles and the like.

そこで従来より、耐摩耗性が要求される部位に適用され
るアルミニウム材の耐摩耗性向上策として、アルミニウ
ム材の表面に耐摩耗性に優れた表面硬化層を形成する試
みがなされている。
Therefore, attempts have been made to form a hardened surface layer with excellent wear resistance on the surface of the aluminum material as a measure to improve the wear resistance of the aluminum material used in areas where wear resistance is required.

このような表面改質層の形成法として、従来、アルミニ
ウム材料表面にN1等の耐摩耗性に優れた金属をメツキ
法、陽極酸化処理法、溶射法等で被覆する方法か知られ
ている。
Conventionally known methods for forming such a surface-modified layer include coating the surface of an aluminum material with a metal having excellent wear resistance, such as N1, by plating, anodizing, thermal spraying, or the like.

発明が解決しようとする課題 しかしこの方法では、アルミニウム材料と表面改質層と
の密着性が不十分なため、その後の研磨加工や切削加工
において、表面改質層の剥れ、クラック等が発生し、こ
のためアルミニウム材料の加工や使用条件に制約を受け
るというような欠点があった。
Problems to be Solved by the Invention However, with this method, the adhesion between the aluminum material and the surface modified layer is insufficient, resulting in peeling and cracking of the surface modified layer during subsequent polishing and cutting. However, this has the disadvantage that there are restrictions on the processing and usage conditions of the aluminum material.

この発明は、かかる技術的背景のもとになされたもので
あって、耐摩耗性、密着性に優れた表面改質層を形成し
、もってアルミニウム材料の耐摩耗性部品への適用範囲
を拡大することを目的とし、そのための表面改質層形成
用の材料を提供せんとするものである。
This invention was made based on this technical background, and forms a surface-modified layer with excellent wear resistance and adhesion, thereby expanding the scope of application of aluminum materials to wear-resistant parts. The purpose is to provide a material for forming a surface-modified layer for that purpose.

課題を解決するための手段 上記目的を達成する材料として、この発明は、Si:1
〜30wt%、Cu:1〜30wt%、Ni:1〜5w
t%を含有し、あるいはさらにMg;0.05−6wt
%、Mn:0.01〜10wt%、Cr : 0. 0
1〜10wt%、Fe:0.05〜10νt%、Ti:
0.005〜]0νt%、BO,001〜5wt%、Z
 r : 0. 005〜5wt%、V : 0. 0
5+−5wt%、P:Q、001〜0.02wt%、S
 r : 0. 001〜0. 2wt%、Na : 
0.001〜0.2wt%の1種または2種以上を含有
し、残部アルミニウム及び不可避不純物からなるアルミ
ニウム材の表面改質用溶加材を提供するものである。そ
して、該溶加材をアルミニウム材料の表面に溶接して表
面改質層を形成することで上記目的を達成せんとするも
のである。
Means for Solving the Problems This invention uses Si:1 as a material to achieve the above object.
~30wt%, Cu: 1~30wt%, Ni: 1~5w
t% or further contains Mg; 0.05-6wt
%, Mn: 0.01 to 10 wt%, Cr: 0. 0
1 to 10 wt%, Fe: 0.05 to 10 νt%, Ti:
0.005~]0νt%, BO, 001~5wt%, Z
r: 0. 005-5wt%, V: 0. 0
5+-5wt%, P:Q, 001-0.02wt%, S
r: 0. 001~0. 2wt%, Na:
The object of the present invention is to provide a filler material for surface modification of an aluminum material containing 0.001 to 0.2 wt% of one or more kinds, with the remainder consisting of aluminum and unavoidable impurities. The above object is achieved by welding the filler metal to the surface of the aluminum material to form a surface-modified layer.

この発明に係る溶加材の各元素の添加意義と限定理由に
ついて説明すると、必須元素としてのSiは溶融によっ
てアルミニウム母材のAΩマトリックスにSi粒子とし
て晶出することにより、またCuSNiはAρマトリッ
クスにAΩ−Cu系、Aρ−Ni系金属間化合物として
晶出することにより、極めて硬度の高い合金化層を形成
する役割を果たす。しかし、5iSCu、Niのいずれ
かが1νt%未満ではその効果に乏しい。一方5iSC
uが30wt%を超えあるいはNiが5wt%を超える
と溶加材の加工が困難となる。特に好ましい含有範囲は
Si:3〜20wt%、Cu:3〜10wt%、Ni:
2〜3wt%である。
To explain the significance and reasons for adding each element in the filler metal according to the present invention, Si as an essential element crystallizes as Si particles in the AΩ matrix of the aluminum base material by melting, and CuSNi crystallizes in the Aρ matrix by melting. By crystallizing as an AΩ-Cu-based or Aρ-Ni-based intermetallic compound, it plays the role of forming an extremely hard alloyed layer. However, if either 5iSCu or Ni is less than 1vt%, the effect is poor. On the other hand, 5iSC
If u exceeds 30 wt% or Ni exceeds 5 wt%, processing of the filler metal becomes difficult. Particularly preferable content ranges are Si: 3 to 20 wt%, Cu: 3 to 10 wt%, Ni:
It is 2 to 3 wt%.

溶加材に任意的に添加されるMg、Mn5Crs Fe
、”riSB% Zr5Vs PSSr、Naはいずれ
も溶加材ひいては表面改質層の機械的性質の改善に寄与
するものである。なかでも特にMgは強度向上に、Mn
、Cr、Feは強度及び耐食性の向上に、Ti5BSZ
rSVは結晶粒の微細化にそれぞれ寄与するものである
Mg, Mn5Crs Fe optionally added to filler metal
, "riSB% Zr5Vs PSSr, and Na all contribute to improving the mechanical properties of the filler metal and eventually the surface modification layer. Among them, Mg in particular contributes to improving the strength, and Mn
, Cr, Fe to improve strength and corrosion resistance, Ti5BSZ
Each rSV contributes to the refinement of crystal grains.

また、PSSr、Naは鋳造時のSi粒子の微細化に寄
与するが、特にPはSiが12wt%程度以上の過共晶
組成領域に含有される場合に用いるか良く、Sr、Na
はSiが12wt%程度以下の共晶域に含有される場合
に用いるのが良い。しかし、これらの各元素が下限値未
満では該効果に乏しく、逆に上限値を超えて過多に含有
されると加工性の悪化等の不都合を派生する。
In addition, PSSr and Na contribute to the refinement of Si particles during casting, but P is particularly suitable for use when Si is contained in a hypereutectic composition region of about 12 wt% or more, and Sr, Na
is preferably used when Si is contained in the eutectic region of about 12 wt% or less. However, if the content of each of these elements is less than the lower limit, the effect will be poor, and if the content exceeds the upper limit and is excessive, problems such as deterioration of workability will result.

特に好ましい含有量は、Mg:1〜3wt%、Mn:1
〜3wt%、Cr:1〜3wt%、Fe:1〜3wt%
、Ti:1〜5wt%、B:1〜3wt%、Zr:l 
〜3wt%、V:1〜3wt%、P:0゜005〜0.
01wt%、S r : 0. 005〜0゜01wt
%、Na :0.005〜0.01wt%である。
Particularly preferable contents are Mg: 1 to 3 wt%, Mn: 1
~3wt%, Cr: 1-3wt%, Fe: 1-3wt%
, Ti: 1 to 5 wt%, B: 1 to 3 wt%, Zr: l
~3 wt%, V: 1~3 wt%, P: 0°005~0.
01wt%, Sr: 0. 005~0゜01wt
%, Na: 0.005 to 0.01 wt%.

なお、溶加材の残部アルミニウムは母材たるアルミニウ
ム材に対する溶加材の十分な濡れ性を確保する役割を果
たす。
Note that the remaining aluminum of the filler metal serves to ensure sufficient wettability of the filler metal to the aluminum material that is the base material.

この発明に係る溶加材の製造方法は、特に限定されるこ
とはなく、常法に従う展伸材、鋳物材の製造工程の実施
により行えば良い。
The method for manufacturing the filler material according to the present invention is not particularly limited, and may be carried out by carrying out the manufacturing process of wrought material or cast material according to a conventional method.

こうして製作した溶加材は、−船釣には溶接棒あるいは
溶接芯線として用いられ、TIG溶接、MIG溶接等の
溶接手段によりアルミニウム材の表面改質予定部位に肉
盛溶接される。通常、TIG溶接に用いる場合は外径2
,4〜3゜2IRIn程度に設定され、M I G溶接
に用いる場合は外径]、2〜2.4#程度に設定される
。溶接後においてはアルミニウム材の溶融部分は短詩に
凝固し、アルミニウム材のAρマトリックスにSi粒子
、Ac−Cu系、へΩ−Ni系金属間化合物が均一緻密
にあるいは塊状に晶出した合金化層が形成される。而し
て、51粒子、へΩ−Cu系、Ac−Ni系金属間化合
物はそれ自体極めて硬度が高いため、合金化層が全体と
して高い硬度を示し、優れた耐摩耗性を具有する。
The filler metal thus produced is used as a welding rod or welding core wire for boat fishing, and is overlay-welded to a portion of the aluminum material to be surface-modified by welding means such as TIG welding or MIG welding. Normally, when used for TIG welding, the outer diameter is 2
, 4 to 3°2IRIn, and when used for MIG welding, the outer diameter is set to about 2 to 2.4#. After welding, the molten part of the aluminum material solidifies briefly, forming an alloyed layer in which Si particles, Ac-Cu system, and Hemega-Ni system intermetallic compounds crystallize uniformly and densely or in blocks in the Aρ matrix of the aluminum material. is formed. Since the 51 particles, Hemega-Cu type, Ac-Ni type intermetallic compound itself has extremely high hardness, the alloyed layer as a whole exhibits high hardness and has excellent wear resistance.

表面に硬質合金化層を形成したアルミニウム材は、その
後必要に応じて最終製品形状に機械加工し、耐摩耗性部
品として実用に供する。なお、この母材たるアルミニウ
ム材の組成は特に限定されるものではなく、純へΩは勿
論のこと2000系その他のアルミニウム展伸材あるい
はAc8A、AC2B等のアルミニウム鋳物材等を適宜
用いうる。
The aluminum material with a hard alloyed layer formed on its surface is then machined into the final product shape as required, and put into practical use as a wear-resistant part. Note that the composition of the aluminum material as the base material is not particularly limited, and not only pure HΩ but also 2000 series and other wrought aluminum materials, aluminum casting materials such as Ac8A and AC2B, etc. can be used as appropriate.

実施例 下記第1表に示す組成の各種溶加材を製作した。溶加材
は各組成の合金を鋳造し、多ホー/L押出により直径1
.6#の溶接芯線に製作した。
Examples Various filler metals having the compositions shown in Table 1 below were manufactured. The filler metal is made by casting alloys of various compositions and extruding them into diameters of 1
.. Manufactured with 6# welded core wire.

[以下余白] 一方、表面硬化層を形成すべきアルミニウム材としてA
C8A鋳物合金からなる厚さ7,5m×幅40IrII
n×長さ100711#Iの試験片を用意した。そして
、試験片の中央部長手方向に深さ0゜5#の浅溝を形成
した。
[Left below] On the other hand, as an aluminum material on which a hardened surface layer is to be formed, A
Made of C8A casting alloy, thickness 7.5m x width 40IrII
A test piece of n×length 100711#I was prepared. Then, a shallow groove with a depth of 0°5# was formed in the longitudinal direction of the center of the test piece.

そして、前記溶加材を用いてMIG溶接により試験片の
上記溝の部分に肉盛溶接を行った。
Then, overlay welding was performed on the groove portion of the test piece by MIG welding using the filler metal.

溶接条件は以下のとおりとした。The welding conditions were as follows.

溶接電流210〜22OA。Welding current 210-22OA.

電圧二24V 溶接速度: 60cm/mfn シールドガス流Ji : 25 D /ll1in次に
、上記により得た各溶接品につき、溶接部分の硬さを室
温にて測定したところ、第2表に示すとおりであった。
Voltage 2: 24V Welding speed: 60cm/mfn Shielding gas flow Ji: 25D/11inNext, for each welded product obtained above, the hardness of the welded part was measured at room temperature, and the results were as shown in Table 2. there were.

[以下余白コ 第2表 一方、アルミニウム材単体の硬度を調べたところ、Hv
30 (荷重5Kg)であった。
[Table 2 below: On the other hand, when we investigated the hardness of the aluminum material alone, Hv
30 (load: 5 kg).

以上の試験結果かられかるように、本発明に係る溶加材
を用いると、極めて硬度が高く従って当然に耐摩耗性に
も優れた表面改質層をアルミニウム材の表面に簡単かつ
確実に形成しうろことを確認しえた。
As can be seen from the above test results, when the filler metal according to the present invention is used, a surface-modified layer with extremely high hardness and naturally excellent wear resistance can be easily and reliably formed on the surface of aluminum material. I was able to confirm that it was Shiroko.

発明の効果 この発明は上述の次第で、所定量のSi、Cu、Nfを
含有するアルミニウム合金溶加材を用い、これをアルミ
ニウム母材の所期する部位に肉盛溶接することにより、
アルミニウム材に耐摩耗性に優れた表面改質層を形成す
ることができる。しかもこの改質層はAρマトリックス
とS 1SCuSNiとが合金化した合金化層となって
いるから、アルミニウム材と一体化しえて密着性に優れ
たものとなしうる。その結果、自動車等に要請される耐
摩耗性部品として好適なアルミニウム材の提供が可能と
なる。
Effects of the Invention In accordance with the above, the present invention uses an aluminum alloy filler metal containing a predetermined amount of Si, Cu, and Nf and overlays it on a desired portion of an aluminum base material, thereby achieving the following:
A surface modified layer with excellent wear resistance can be formed on aluminum material. Furthermore, since this modified layer is an alloyed layer in which the Aρ matrix and S1SCuSNi are alloyed, it can be integrated with the aluminum material and has excellent adhesion. As a result, it becomes possible to provide an aluminum material suitable for wear-resistant parts required for automobiles and the like.

また、請求項2に記載の溶加材を用いた場合には、上記
効果に加えて表面改質層の強度等の機械的性質をさらに
改善できる効果がある。
Further, when the filler material according to claim 2 is used, in addition to the above-mentioned effects, the mechanical properties such as the strength of the surface-modified layer can be further improved.

以上that's all

Claims (2)

【特許請求の範囲】[Claims] (1)Si:1〜30wt%、Cu:1〜30wt%、
Ni:1〜5wt%を含有し、残部アルミニウム及び不
可避不純物からなるアルミニウム材の表面改質用溶加材
(1) Si: 1 to 30 wt%, Cu: 1 to 30 wt%,
A filler material for surface modification of aluminum materials, containing 1 to 5 wt% of Ni, with the balance being aluminum and unavoidable impurities.
(2)Si:1〜30wt%、Cu:1〜30wt%、
Ni:1〜5wt%を含有し、さらにMg:0.05〜
6wt%、Mn:0.01〜10wt%、Cr:0.0
1〜10wt%、Fe:0.05〜10wt%、Ti:
0.005〜10wt%、B:0.001〜5wt%、
Zr:0.005〜5wt%、V:0.05〜5wt%
、P:0.001〜0.02wt%、Sr:0.001
〜0.2wt%、Na:0.001〜0.2wt%の1
種または2種以上を含有し、残部アルミニウム及び不可
避不純物からなるアルミニウム材の表面改質用溶加材。
(2) Si: 1 to 30 wt%, Cu: 1 to 30 wt%,
Contains Ni: 1 to 5 wt%, and further contains Mg: 0.05 to 5 wt%.
6wt%, Mn: 0.01-10wt%, Cr: 0.0
1 to 10 wt%, Fe: 0.05 to 10 wt%, Ti:
0.005-10wt%, B: 0.001-5wt%,
Zr: 0.005-5wt%, V: 0.05-5wt%
, P: 0.001-0.02wt%, Sr: 0.001
~0.2wt%, Na: 0.001~0.2wt% 1
A filler material for surface modification of aluminum materials containing one or more kinds of aluminum and the remainder consisting of aluminum and unavoidable impurities.
JP22081690A 1990-08-21 1990-08-21 Filler metal for surface reforming of aluminum material Pending JPH04105787A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22081690A JPH04105787A (en) 1990-08-21 1990-08-21 Filler metal for surface reforming of aluminum material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22081690A JPH04105787A (en) 1990-08-21 1990-08-21 Filler metal for surface reforming of aluminum material

Publications (1)

Publication Number Publication Date
JPH04105787A true JPH04105787A (en) 1992-04-07

Family

ID=16757009

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JPH04105787A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374295A (en) * 1992-03-04 1994-12-20 Toyota Jidosha Kabushiki Kaisha Heat resistant aluminum alloy powder, heat resistant aluminum alloy and heat and wear resistant aluminum alloy-based composite material
US5409661A (en) * 1991-10-22 1995-04-25 Toyota Jidosha Kabushiki Kaisha Aluminum alloy
US5464463A (en) * 1992-04-16 1995-11-07 Toyota Jidosha Kabushiki Kaisha Heat resistant aluminum alloy powder heat resistant aluminum alloy and heat and wear resistant aluminum alloy-based composite material
US5614036A (en) * 1992-12-03 1997-03-25 Toyota Jidosha Kabushiki Kaisha High heat resisting and high abrasion resisting aluminum alloy
US6592687B1 (en) * 1998-09-08 2003-07-15 The United States Of America As Represented By The National Aeronautics And Space Administration Aluminum alloy and article cast therefrom
CN102000924A (en) * 2010-10-28 2011-04-06 桂林市庆通有色金属工艺材料开发有限公司 Low-melting-point and high-strength aluminum-based brazing filler metal and preparation method thereof
WO2013050358A1 (en) * 2011-10-04 2013-04-11 Federal-Mogul Nürnberg GmbH Method for producing an engine component and engine component
CN104858566A (en) * 2015-06-09 2015-08-26 中国电子科技集团公司第十四研究所 Aluminum-base low-melting-point vacuum brazing filler and preparation method thereof
CN109434319A (en) * 2018-11-28 2019-03-08 东莞理工学院 A kind of aluminium alloy TIG welding wire and preparation method thereof
CN109504881A (en) * 2018-12-14 2019-03-22 广东省海洋工程装备技术研究所 A kind of Al-Si-Cu-Mg-Ni-Sr alloy material and preparation method thereof and piston
WO2021112155A1 (en) * 2019-12-04 2021-06-10 ヒノデホールディングス株式会社 Aluminum alloy for casting and aluminum cast product made using same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01113199A (en) * 1987-10-23 1989-05-01 Showa Alum Corp Production of aluminum material having excellent wear resistance and conductivity

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01113199A (en) * 1987-10-23 1989-05-01 Showa Alum Corp Production of aluminum material having excellent wear resistance and conductivity

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5409661A (en) * 1991-10-22 1995-04-25 Toyota Jidosha Kabushiki Kaisha Aluminum alloy
US5374295A (en) * 1992-03-04 1994-12-20 Toyota Jidosha Kabushiki Kaisha Heat resistant aluminum alloy powder, heat resistant aluminum alloy and heat and wear resistant aluminum alloy-based composite material
US5464463A (en) * 1992-04-16 1995-11-07 Toyota Jidosha Kabushiki Kaisha Heat resistant aluminum alloy powder heat resistant aluminum alloy and heat and wear resistant aluminum alloy-based composite material
US5614036A (en) * 1992-12-03 1997-03-25 Toyota Jidosha Kabushiki Kaisha High heat resisting and high abrasion resisting aluminum alloy
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