JPH0388209A - High polymer solid electrolyte - Google Patents
High polymer solid electrolyteInfo
- Publication number
- JPH0388209A JPH0388209A JP1224265A JP22426589A JPH0388209A JP H0388209 A JPH0388209 A JP H0388209A JP 1224265 A JP1224265 A JP 1224265A JP 22426589 A JP22426589 A JP 22426589A JP H0388209 A JPH0388209 A JP H0388209A
- Authority
- JP
- Japan
- Prior art keywords
- crosslinked network
- solid polymer
- polymer electrolyte
- network
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 title abstract description 3
- 239000007784 solid electrolyte Substances 0.000 title abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 230000009257 reactivity Effects 0.000 claims abstract description 5
- 239000005518 polymer electrolyte Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 230000005865 ionizing radiation Effects 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract description 2
- -1 acryl compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 description 8
- 238000010894 electron beam technology Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- JJYNTZGJAAQHKQ-UHFFFAOYSA-N 1,3-dioxolane;2-methyloxolane Chemical compound C1COCO1.CC1CCCO1 JJYNTZGJAAQHKQ-UHFFFAOYSA-N 0.000 description 1
- JRRDISHSXWGFRF-UHFFFAOYSA-N 1-[2-(2-ethoxyethoxy)ethoxy]-2-methoxyethane Chemical compound CCOCCOCCOCCOC JRRDISHSXWGFRF-UHFFFAOYSA-N 0.000 description 1
- YZWVMKLQNYGKLJ-UHFFFAOYSA-N 1-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]-2-methoxyethane Chemical compound CCOCCOCCOCCOCCOC YZWVMKLQNYGKLJ-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 1
- CMJLMPKFQPJDKP-UHFFFAOYSA-N 3-methylthiolane 1,1-dioxide Chemical compound CC1CCS(=O)(=O)C1 CMJLMPKFQPJDKP-UHFFFAOYSA-N 0.000 description 1
- GDKSTFXHMBGCPG-UHFFFAOYSA-N 4,4-dimethyl-1,3-dioxane Chemical compound CC1(C)CCOCO1 GDKSTFXHMBGCPG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- JGNPSJMNGPUQIW-UHFFFAOYSA-N [C].CC=C Chemical compound [C].CC=C JGNPSJMNGPUQIW-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
、本発明は１次電池、２次電池、エレクトロクロ汽りデ
ィスプレイ、電気化学センサーイオントフォレーシス、
及びコンデンサー等の電気化学的デバイスに用いる高分
子固体電解質に関するものである。[Detailed Description of the Invention] The present invention relates to the field of industrial application, primary batteries, secondary batteries, electrochromic displays, electrochemical sensors, iontophoresis,
and solid polymer electrolytes used in electrochemical devices such as capacitors.
従来技術とその問題点
従来、アクリロイル変性ポリアルキレンオキシドとイオ
ン性塩を均一に混和させたものを架橋ネットワークとし
た高分子固体電解質が提案されているが、機械的強度が
小さいという問題点があった。Conventional technologies and their problems Conventionally, solid polymer electrolytes have been proposed in which a crosslinked network is formed by uniformly mixing acryloyl-modified polyalkylene oxide and ionic salts, but this method has the problem of low mechanical strength. Ta.
発明の目的
（４）
本発明は上記従来の問題点に鑑みなされたものであり、
機械的強度に優れた高分子固体電解質を提供することを
目的とするものである。Purpose of the invention (4) The present invention has been made in view of the above-mentioned conventional problems,
The purpose is to provide a solid polymer electrolyte with excellent mechanical strength.
発明の構成
本発明は上記目的を達成するべく、
アクリレート系、メタクリレート系、スチレン系、アリ
ル系化合物よりなる群から２種以上選んだ架橋ネットワ
ーク形成化合物の反応性の反応性が異なり、反応性の速
い化合物を反応させ第１の架橋ネットワークを形成し、
該架橋ネットワークに反応性の遅い化合物によって絡む
ように第２の架橋ネットワークを形成させた構造体がイ
オン性塩を含むことを特徴とする高分子固体電解質であ
る。Structure of the Invention In order to achieve the above-mentioned object, the present invention provides a method in which two or more crosslinked network-forming compounds selected from the group consisting of acrylate-based, methacrylate-based, styrene-based, and allyl-based compounds have different reactivities. reacting a fast compound to form a first crosslinked network;
The solid polymer electrolyte is characterized in that the structure in which a second crosslinked network is formed so as to be entangled with the crosslinked network by a compound with slow reactivity contains an ionic salt.
又、架橋ネットワーク形成化合物がポリエーテル構造を
有する前記の高分子固体電解質である。Moreover, the crosslinked network forming compound is the above-mentioned solid polymer electrolyte having a polyether structure.
又、ポリエーテルがポリエチレンオキシド又はポリプロ
ピレンオキシド又はエチレンオキシドとプロピレンオキ
シドの共重合体である前記の高分子固体電解質である。Further, the above solid polymer electrolyte is one in which the polyether is polyethylene oxide, polypropylene oxide, or a copolymer of ethylene oxide and propylene oxide.
又、反応が電離性放射線、又は可視光線、又は紫外線、
又は熱による前記の高分子固体電解質である。Also, if the reaction is caused by ionizing radiation, visible light, or ultraviolet light,
Or the above-mentioned polymer solid electrolyte by heat.
又、前記の構造体がイオン性塩の他に、イオン性塩を溶
解することができる化合物を含む高分子固体電解質であ
る。Further, the above-mentioned structure is a solid polymer electrolyte containing not only an ionic salt but also a compound capable of dissolving the ionic salt.
作用
第１の架橋ネットワークに第２の架橋ネットワークに絡
み合ったフルインターペネトレイティングネットワーク
構造を形成させることによって、機械的強度が増大する
。Effect Mechanical strength is increased by forming a fully interpenetrating network structure in which the first crosslinked network is intertwined with the second crosslinked network.
実施例 以下、本発明の詳細について実施例により説明する。Example Hereinafter, the details of the present invention will be explained with reference to Examples.
実施例１
ポリエチレンオキシドジアクリレート（平均分子量５２
０）５重量部、ポリエチレンオキシドジメタクリレート
（平均分子量５４０）５重量部、トリフルオロメタンス
ルホン酸リチウム１．３重量部を均一に混合し、溶解し
た。この混合物をガラス板上にキャストし、２．０Ｍｒ
ａｄの電子線を照射した。次に５Ｍ ｒ ａ ｄの電子
線を照射し、５０μｍのフィルムを得た。このフィルム
のイオン伝導度を複素インピーダンス法で測定したとこ
ろ、１ｘ １０’ Ｓ ｃｍ −” （温度２５℃）を
示した。コノ膜の引張強度は３０ｋｇ／ｃ−であった。Example 1 Polyethylene oxide diacrylate (average molecular weight 52
0), 5 parts by weight of polyethylene oxide dimethacrylate (average molecular weight 540), and 1.3 parts by weight of lithium trifluoromethanesulfonate were uniformly mixed and dissolved. This mixture was cast on a glass plate and 2.0 Mr.
irradiated with ad electron beam. Next, an electron beam of 5M rad was irradiated to obtain a 50 μm film. When the ionic conductivity of this film was measured by the complex impedance method, it was found to be 1 x 10' S cm -'' (temperature 25°C). The tensile strength of the Kono membrane was 30 kg/c -.
比較例１
ポリエチレンオキシドジアクリレート（平均分子量５２
０）１０重量部、トリフルオロメタンスルホン酸リチウ
ム１．３重量部を均一に混合し、溶解した。この混合物
をガラス板にキャストし、２．０Ｍｒａｄの電子線を照
射し、５０μｍのフィルムを得た。このフィルムのイオ
ン伝導度を複素インピーダンス法で測定したところ、Ｉ
Ｘ １０−６８ ａａ−１（温度２５℃）を示した。Comparative Example 1 Polyethylene oxide diacrylate (average molecular weight 52
0) and 1.3 parts by weight of lithium trifluoromethanesulfonate were uniformly mixed and dissolved. This mixture was cast on a glass plate and irradiated with an electron beam of 2.0 Mrad to obtain a 50 μm film. When the ionic conductivity of this film was measured using the complex impedance method, it was found that I
X 10-68 aa-1 (temperature 25°C).
この膜の引張強度は１８ｋｇ ／ ｃｊであった。The tensile strength of this membrane was 18 kg/cj.
実施例２
実施例１の組成物にプロピレンカーボネート１０重量部
を加えて、同様の方法で５０μｍのフィルムを得た。こ
の時のイオン伝導度は、複素インピーダンス法で５×１
０→５（７）−１（温度２５℃）で、引張強度は１５ｋ
ｇ／ｄであった。Example 2 10 parts by weight of propylene carbonate was added to the composition of Example 1, and a 50 μm film was obtained in the same manner. The ionic conductivity at this time is 5×1 using the complex impedance method.
0→5(7)-1 (temperature 25℃), tensile strength is 15k
g/d.
比較例２
比較例１の組成物にプロピレンカーボネート１０重量部
を加えて、同様の方法で５０μｍのフィルムを得た。こ
の時のイオン伝導度は、複素インピーダンス法で６Ｘ１
０−’Ｓｃａ＋−１（温度２５℃）で、引張強度は４．
５ｋｇ／ｃｄであった。Comparative Example 2 10 parts by weight of propylene carbonate was added to the composition of Comparative Example 1, and a 50 μm film was obtained in the same manner. The ionic conductivity at this time is 6X1 using the complex impedance method.
At 0-'Sca+-1 (temperature 25°C), the tensile strength is 4.
It was 5 kg/cd.
実施例３
ポリエチレンオキシドジアクリレート（平均分子量５２
０）５重量部、トリアリルエーテル化ポリエチレンオキ
シド（平均分子量３０００）５重量部、トリフルオロメ
タンスルホン酸リチウム１．３重量部、プロピレンカ−
ボネート１０重量部を均一に混合溶解し、ガラス板上に
キャストし、２．９Ｍｒａｄの電子線を照射し、次にｇ
ＱＭｒａｄの電子線を照射し、５０μｍのフィルムを得
た。この膜のイオン伝導度は複素インピーダンス法によ
ると８ Ｘ １０＝Ｓｃｓ−’ （温度２５℃）であっ
た。引張強度は１３ｋｇ／ｃｊであった。Example 3 Polyethylene oxide diacrylate (average molecular weight 52
0) 5 parts by weight, 5 parts by weight of triallyl etherified polyethylene oxide (average molecular weight 3000), 1.3 parts by weight of lithium trifluoromethanesulfonate, propylene carbon
10 parts by weight of carbonate were uniformly mixed and melted, cast on a glass plate, irradiated with an electron beam of 2.9 Mrad, and then g
A 50 μm film was obtained by irradiation with a QMrad electron beam. The ionic conductivity of this membrane was 8 x 10=Scs-' (temperature 25°C) according to the complex impedance method. The tensile strength was 13 kg/cj.
実施例４
実施例３の組成物にベンゾフェノン１重量部を加えて、
ガラス板上にキャストし、１５備の距離からＩＫＷのＵ
Ｖランプで１０秒間紫外線を照射し、次に４０秒間照射
を１０回繰り返した。得られた膜の厚味は５０μｍで、
イオン伝導度は複素インピーダンス法によると８ Ｘ
１０４５ｃｍ−１（温度２５℃）、引張強度は１２ｋｇ
／ｃ−であった。Example 4 1 part by weight of benzophenone was added to the composition of Example 3,
Cast it on a glass plate and use IKW's U from a distance of 15 minutes.
Ultraviolet rays were irradiated with a V lamp for 10 seconds, and then irradiation for 40 seconds was repeated 10 times. The thickness of the obtained film was 50 μm,
According to the complex impedance method, the ionic conductivity is 8
1045cm-1 (temperature 25℃), tensile strength is 12kg
/c-.
イオン性塩を溶解することができる化合物は、テトラヒ
ドロフラン、２−メチルテトラヒドロフラン１．３−ジ
オキソラン、４，４−ジメチル−１，３−ジオキサン、
γ−ブチロラクトン、エチレンカーボネート、プロピレ
ンカーボネート、ブチレンカーボネート、スルホラン、
３−メチルスルホラン、ｔｅｒｔ、−ブチルエーテル、
１ｓｏ−ブチルエーテル、１．２ジメトキシエタン、１
．２エトキシメトキシエタン、メチルジグライム、メチ
ルトリグライム、メチルテトラグライム、エチルグライ
ム、エチルジグライムなどがあるが限定はしない。Compounds that can dissolve ionic salts include tetrahydrofuran, 2-methyltetrahydrofuran 1,3-dioxolane, 4,4-dimethyl-1,3-dioxane,
γ-butyrolactone, ethylene carbonate, propylene carbonate, butylene carbonate, sulfolane,
3-methylsulfolane, tert,-butyl ether,
1 so-butyl ether, 1.2 dimethoxyethane, 1
．． Examples include, but are not limited to, 2-ethoxymethoxyethane, methyl diglyme, methyl triglyme, methyltetraglyme, ethyl glyme, and ethyl diglyme.
イオン性塩としては、ＬｉＣｊ！０４．ＬｉＢＦ４．Ｌ
ｉＡｓＦ６．ＬｉＣＦＳＯ３，ＬｉＰＦ６．Ｌｉ Ｉ、
ＬｉＢｒ、Ｌｉ５ＣＮ。As an ionic salt, LiCj! 04. LiBF4. L
iAsF6. LiCFSO3, LiPF6. Li I,
LiBr, Li5CN.
Ｎａ Ｉ、 Ｌ １２Ｂ１ｏ Ｃｆｆ１１ｏ、 Ｌ
ｉ ＣＦ３ Ｃ０２、ＮａＢｒ、Ｎａ５ＣＮ、ＫＳＣ
Ｎ、ＭｇＣｌ２．Ｍｇ（Ｃ之０４ ） ２ 、 （Ｃ
Ｈ３） ４ＮＢＦ４ 、（ＣＨ３）４ ＮＢ ｒ、（Ｃ
２Ｈ５）４ＮＣ１０４，（Ｃ２Ｈ５）４ＮＩ、（Ｃ３Ｈ
７） ４ ＮＢ ｒ、 （ｎ−Ｃ，ｓ Ｈｅ ） ４
ＮＣｆｆ１０４ ｍ （ｎ−Ｃ４Ｈｅ ） ４ Ｎ
Ｉ、 （ｎ−Ｃ５Ｈ１１）４ＮＩが好ましいが、限
定しない。Na I, L 12B1o Cff11o, L
i CF3 C02, NaBr, Na5CN, KSC
N, MgCl2. Mg(C之04)2,(C
H3) 4NBF4, (CH3)4NB r, (C
2H5)4NC104, (C2H5)4NI, (C3H
7) 4 NB r, (n-C,s He ) 4
NCff104 m (n-C4He) 4 N
I, (n-C5H11)4NI is preferred, but not limited.
発明の効果
上述した如く、本発明は機械的強度に優れた高分子固体
電解質を提供することが出来るので、その工業的価値は
極めて大である。Effects of the Invention As described above, the present invention can provide a polymer solid electrolyte with excellent mechanical strength, and therefore has extremely great industrial value.
Claims (5)
、アリル系化合物よりなる群から２種以上選んだ架橋ネ
ットワーク形成化合物の反応性が異なり、反応性の速い
化合物を反応させ第１の架橋ネットワークを形成し、該
架橋ネットワークに反応性の遅い化合物によって絡むよ
うに第２の架橋ネットワークを形成させた構造体がイオ
ン性塩を含むことを特徴とする高分子固体電解質。(1) Two or more crosslinked network-forming compounds selected from the group consisting of acrylates, methacrylates, styrenes, and allyl compounds have different reactivities, and compounds with fast reactivity are reacted to form a first crosslinked network. A solid polymer electrolyte, characterized in that the structure in which a second crosslinked network is formed so as to be entangled with the crosslinked network by a slowly reactive compound contains an ionic salt.
を有する請求項１記載の高分子固体電解質。(2) The solid polymer electrolyte according to claim 1, wherein the crosslinked network-forming compound has a polyether structure.
ロピレンオキシド又はエチレンオキシドとプロピレンオ
キシドの共重合体である請求項２記載の高分子固体電解
質。(3) The solid polymer electrolyte according to claim 2, wherein the polyether is polyethylene oxide, polypropylene oxide, or a copolymer of ethylene oxide and propylene oxide.
、又は熱による請求項１記載の高分子固体電解質。(4) The solid polymer electrolyte according to claim 1, wherein the reaction is caused by ionizing radiation, visible light, ultraviolet rays, or heat.
ン性塩を溶解することができる化合物を含む高分子固体
電解質。(5) A solid polymer electrolyte in which the structure according to claim 1 contains, in addition to an ionic salt, a compound capable of dissolving the ionic salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1224265A JPH0388209A (en) | 1989-08-29 | 1989-08-29 | High polymer solid electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1224265A JPH0388209A (en) | 1989-08-29 | 1989-08-29 | High polymer solid electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0388209A true JPH0388209A (en) | 1991-04-12 |
Family
ID=16811068
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1224265A Pending JPH0388209A (en) | 1989-08-29 | 1989-08-29 | High polymer solid electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0388209A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2246872A (en) * | 1990-07-20 | 1992-02-12 | Dowty Electronic Components | Electrochromic material |
| EP0825619A2 (en) * | 1996-07-23 | 1998-02-25 | Rohm And Haas Company | Solid polymeric electrolyte |
| CN109494411A (en) * | 2018-10-31 | 2019-03-19 | 中南大学 | A kind of low temperature flexibility solid polyelectrolyte and its preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4654279A (en) * | 1986-07-10 | 1987-03-31 | The United States Of America As Represented By The Secretary Of The Navy | Interpenetrating-network polymeric electrolytes |
| JPS6394501A (en) * | 1986-10-09 | 1988-04-25 | 宇部興産株式会社 | Manufacture of ion conducting solid electrolytic shield |
-
1989
- 1989-08-29 JP JP1224265A patent/JPH0388209A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4654279A (en) * | 1986-07-10 | 1987-03-31 | The United States Of America As Represented By The Secretary Of The Navy | Interpenetrating-network polymeric electrolytes |
| JPS6394501A (en) * | 1986-10-09 | 1988-04-25 | 宇部興産株式会社 | Manufacture of ion conducting solid electrolytic shield |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2246872A (en) * | 1990-07-20 | 1992-02-12 | Dowty Electronic Components | Electrochromic material |
| EP0825619A2 (en) * | 1996-07-23 | 1998-02-25 | Rohm And Haas Company | Solid polymeric electrolyte |
| EP0825619A3 (en) * | 1996-07-23 | 1998-08-12 | Rohm And Haas Company | Solid polymeric electrolyte |
| CN109494411A (en) * | 2018-10-31 | 2019-03-19 | 中南大学 | A kind of low temperature flexibility solid polyelectrolyte and its preparation method and application |
| CN109494411B (en) * | 2018-10-31 | 2021-08-31 | 中南大学 | Low-temperature flexible polymer solid electrolyte and preparation method and application thereof |
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