JPH0374319A - Hair cosmetic - Google Patents
Hair cosmeticInfo
- Publication number
- JPH0374319A JPH0374319A JP20987389A JP20987389A JPH0374319A JP H0374319 A JPH0374319 A JP H0374319A JP 20987389 A JP20987389 A JP 20987389A JP 20987389 A JP20987389 A JP 20987389A JP H0374319 A JPH0374319 A JP H0374319A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- formula
- component
- manufactured
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 16
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 16
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 15
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 26
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- MUZDXNQOSGWMJJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=C)C(O)=O MUZDXNQOSGWMJJ-UHFFFAOYSA-N 0.000 claims description 4
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- YFTOMFXWAGCYKR-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCNCCOC(=O)C(C)=C YFTOMFXWAGCYKR-UHFFFAOYSA-N 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 238000013329 compounding Methods 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract description 2
- 229920001971 elastomer Polymers 0.000 abstract 2
- 239000005060 rubber Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000499 gel Substances 0.000 description 4
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 3
- 241000195940 Bryophyta Species 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 235000011929 mousse Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- -1 Polyoxyethylene Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008266 hair spray Substances 0.000 description 2
- 229940053080 isosol Drugs 0.000 description 2
- 241000894007 species Species 0.000 description 2
- UOFRJXGVFHUJER-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;hydrate Chemical compound [OH-].OCC[NH+](CCO)CCO UOFRJXGVFHUJER-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- XGZDAGGOXCSMHJ-UHFFFAOYSA-N C(C(=C)C)(=O)OCCN.C(C=C)(=O)O Chemical compound C(C(=C)C)(=O)OCCN.C(C=C)(=O)O XGZDAGGOXCSMHJ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000861 blow drying Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- JCYIWGHPBOTEDG-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(=O)C(C)=C JCYIWGHPBOTEDG-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 229920003146 methacrylic ester copolymer Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は毛髪に刻し優れたクン通り性およびなめらかな
感触をイ・ｊ与し、かつ適度なセット力を＜ｊする頭髪
用化粧料に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a hair cosmetic that imparts excellent runability and a smooth feel when cut into the hair, and has an appropriate setting power.
従来の技術およびその課題
ジメチルシリコーンガム（超高分子ノリコーン）は毛髪
に対し優れた光沢およびクシ通り性、なめらかな感触を
与えるため、頭髪用化粧料に広く配合されている。しか
しながら、これらの頭髪用化粧料はストレートヘアに対
して用いられるものであって、ウェーブヘアやパーマヘ
アの髪形をまとめる作用はなく、さらにジメチルシリコ
ーンカム、の配合量が多いとへたつくという欠点もある
。BACKGROUND ART Dimethyl silicone gum (ultra-polymer silicone) is widely used in hair cosmetics because it provides excellent gloss, combability, and smooth feel to hair. However, these hair cosmetics are used for straight hair, and do not have the effect of shaping wavy or permed hair.Additionally, they also have the disadvantage of becoming untidy if they contain a large amount of dimethyl silicone cam. be.
また、ムース、ジェルなどのスタイリング剤には毛髪セ
ットの目的でポリビニルピロリドン系ポリマー、酸性ポ
リビニルエーテル系ポリマー、酸性アクリル系ポリマー
、あるいはカチオン性ポリマー等の高分子化合物が用い
られている。これらは毛髪のセット力には優れるものの
、べたつき、ひっかかり、ごわっきなど使用時の感触」
二の欠点がある。Further, styling agents such as mousses and gels use polymeric compounds such as polyvinylpyrrolidone polymers, acidic polyvinyl ether polymers, acidic acrylic polymers, or cationic polymers for the purpose of setting hair. Although these products have excellent hair-setting power, they feel sticky, sticky, and stiff when used.
There are two drawbacks.
さらに、ジメチルシリコーンガムと特定の両性樹脂とを
配合し、毛髪に光沢となめらかな感触、並びに適度なセ
ット力を付与せんとする毛髪化粧料の開示もなされてい
る（特開昭６３−３１３７１２号）が、かかる毛髪化粧
料はある程度のセット力は有するものの充分に満足なな
めらかさは得られない。Furthermore, a hair cosmetic has been disclosed which is a blend of dimethyl silicone gum and a specific amphoteric resin and is intended to impart shine and smooth feel to the hair as well as appropriate setting power (Japanese Patent Laid-Open No. 63-313712). ) However, although such hair cosmetics have a certain degree of setting power, they do not provide sufficiently satisfactory smoothness.
本発明は、毛髪に優れたクン通り性となめらかな感触を
付与し、かつ好ましい七ノト力を有する頭髪用化粧料を
提供することを目的とする。An object of the present invention is to provide a hair cosmetic that imparts excellent combing properties and smooth feel to the hair, and has desirable strength.
課題を解決するための手段
本発明者らは前記の課題について種々検討を重ねた結果
、ジメチルシリコーンカムと特定の２種のセット樹脂を
組み合わせることによって塗布時のべたつき、乾燥後の
ごわつきがなく、すぐれたなめらかさと適度なセット力
が共に得られることを知り本発明を完成した。Means for Solving the Problems The present inventors have conducted various studies regarding the above-mentioned problems, and have found that by combining a dimethyl silicone cam and two specific set resins, there is no stickiness during application and no stiffness after drying. The present invention was completed after realizing that both excellent smoothness and appropriate setting force can be obtained.
すなわち、本発明は後記の式［１］で示される１種また
は２種以」−のジメチルシリコーンガム、ポリビニルピ
ロリドン、並びに後記の式［１１１］、［ＩＴ［］およ
び［■］で表される構成単位を有するオクチルアクリル
アミド−ブチルアミンエチルメタクリレート−アクリル
酸エステル共重合体を含有することを特徴とする頭髪用
化粧料を提供するものである。That is, the present invention relates to one or more dimethyl silicone gums represented by the following formula [1], polyvinylpyrrolidone, and the following formulas [111], [IT[], and [■]. The present invention provides a hair cosmetic containing an octylacrylamide-butylamine ethyl methacrylate-acrylic acid ester copolymer having a structural unit.
なお、ジメチルシリコーンガム＼とカチオン、アニオン
、ノニオン、両性の各種セット樹脂（例えば、ジエチル
硫酸ヒニルピロリドン・Ｎ、Ｎ −ジメヂルアミノエチ
ルメタクリル酸共重合体、アクリル酸エステル／メタク
リル酸エステル共重合体、ポリビニルピロリドン、ジア
ルキルアミノエチルメタクリレート重合体のモノクロル
酢酸両性化物、オクチルアクリルアミド−ブチルアミノ
エチルメタクリレート−アクリル酸エステル重合物など
）単独との組み合わせでは、塗布時のへたつきのなさ、
なめらかさは向」−するが、良好ななめらかさ、適度な
セット力を共に満足することはできない。In addition, dimethyl silicone gum and various cationic, anionic, nonionic, and amphoteric set resins (e.g., diethyl sulfate-hinylpyrrolidone/N,N-dimedylaminoethyl methacrylic acid copolymer, acrylic ester/methacrylic ester copolymer) Polyvinylpyrrolidone, monochloroacetic acid ampholyte of dialkylaminoethyl methacrylate polymer, octylacrylamide-butylaminoethyl methacrylate-acrylic acid ester polymer, etc.) When used alone, there is no stickiness during application.
Although the smoothness is good, it is not possible to satisfy both good smoothness and appropriate setting force.
本発明の毛髪処理剤に配合されるジメチルシリコーンガ
ムは、下記の構造式［Ｔ］で示される。The dimethyl silicone gum blended into the hair treatment agent of the present invention is represented by the following structural formula [T].
［式中、Ｒ’ＳＲ２はメチル基または水酸基、ｎは４０
００〜９０００の整数を意味する］上記式［＋］のジメ
チルシリコーンガムの代表的なものとしては、例えば東
芝ンリコーンＴＳＥ２００、ＴＳＥ−２００Ａ（東芝シ
リコーン（株）製）などが挙げられ、それらの１種また
は２種以上が処理剤全量に対して０．０１〜５０重量％
、好ましくは０５〜２０重量％配合される。配合量がこ
れより少ないと、毛髪のクシ通り性および感触のなめら
かさは充分ではない。一方、配合量かこの範囲を越える
と粘性が強くなり使用感が低下する。[In the formula, R'SR2 is a methyl group or a hydroxyl group, n is 40
means an integer from 00 to 9000] Typical dimethyl silicone gums of the above formula [+] include Toshiba Silicone TSE200 and TSE-200A (manufactured by Toshiba Silicone Co., Ltd.); The species or two or more species are 0.01 to 50% by weight based on the total amount of the treatment agent.
, preferably 05 to 20% by weight. If the amount is less than this, the combability and smooth feel of the hair will not be sufficient. On the other hand, if the blending amount exceeds this range, the viscosity will become strong and the feeling of use will deteriorate.
つぎに、本発明の第二の配合成分であるポリビニルピロ
リドン（ノニオン樹脂）は重合度１００〜１０ ０００
のものが用いられる。Next, polyvinylpyrrolidone (nonionic resin), which is the second compounding component of the present invention, has a polymerization degree of 100 to 10,000.
are used.
かかるポリビニルピロリドンの代表的なものとしては、
例えばＢＡＳＦ’社製ルビ社製−ビスコー０、Ｋ−９０
，ＧＡＦ社製、ＰＶＰ Ｋ−３０゜Ｋ−６０、［−９０
などが拳げられる。Typical examples of such polyvinylpyrrolidone include:
For example, manufactured by BASF', manufactured by Ruby Company - Viscoe 0, K-90
, manufactured by GAF, PVP K-30°K-60, [-90
etc. are punched.
ポリビニルピロリドンの配合量は組成物中、０１〜３重
量％、好ましくは０３〜１５重量％である。ポリビニル
ピロリドンの配合風が０．１重量％よりすくないと七ソ
Ｉ・力が不足する。また３重量％を越えると使用にあた
りへたつきが感じられる。The amount of polyvinylpyrrolidone blended in the composition is 01 to 3% by weight, preferably 03 to 15% by weight. If the amount of polyvinylpyrrolidone in the mixture is less than 0.1% by weight, the strength will be insufficient. Moreover, if it exceeds 3% by weight, it will feel stiff when used.
つぎに本発明の第三の配合酸分であるオクヂルアクリル
アミドープチルアミノエチルメタクリレート−アクリル
酸エステル共重合体（両性樹脂）（Ｊ下式［ＩＩ］
［ｎＩ］ ［ＩＶ］で表される構成単（１７を有する
共重合体である。Next, the third blended acid component of the present invention, octyl acrylamide doptyl aminoethyl methacrylate-acrylic acid ester copolymer (ampholyte resin) (J formula [II]
[nI] A copolymer having the constituent monomer (17) represented by [IV].
かかるオクチルアクリルアミド−ブチルアミノエチルメ
タクリレート−アクリル酸エステル共重合体の市販品と
して代表的なものとしては、例えばＮＳＣ社製アンフォ
マ−２８−４９１０，２８４９６１などが挙げられ、そ
れらの１種または２種以上が処理剤全量に対して０．２
〜４重量％、好ましくは０．４〜２重量％配合される。Typical commercial products of such octylacrylamide-butylaminoethyl methacrylate-acrylic acid ester copolymers include, for example, Amphomer-28-4910 and 284961 manufactured by NSC, and one or more of them may be used. is 0.2 based on the total amount of processing agent.
-4% by weight, preferably 0.4-2% by weight.
配合量がこれより少ないと、セラＩ・ノノが不足する。If the blending amount is less than this, Sera I/Nono will be insufficient.
一方、配合量がこの範囲を越えると頭髪がごわっき滑ら
かさがなくなる。On the other hand, if the amount exceeds this range, the hair will become stiff and lose its smoothness.
本発明化粧料中、ジメヂルシリコーンガムの配合量と他
の（ｂ）（ｃ）の２威分の合計配合量との重量配合比（
ａ）／［（ｂ）＋（ｃ）〕は１／ｌＯ〜１／１が好まし
く、１／８〜１／２であるのがより好ましい。ジメチル
ンリコーンガムの配合量がこれより少ないと塗布時のべ
たつきがあり頭髪かごわっき滑らかさがなくなる。また
ジメチルノリコーンガムの配合量がこれより多いとセッ
ト力が不足する。In the cosmetic of the present invention, the weight ratio of the amount of dimedyl silicone gum to the total amount of the other two components (b) and (c) (
a)/[(b)+(c)] is preferably 1/1O to 1/1, more preferably 1/8 to 1/2. If the amount of dimethyl silicone gum is less than this, the product will be sticky when applied and the hair will not be smooth. Furthermore, if the amount of dimethyl noricorn gum is more than this, the setting power will be insufficient.
本発明の毛髪処理剤は公知の方法に３１；す、ヘアミル
ク、ブロー剤、ヘアスタイリングムース、ヘアスタイリ
ングジェル、ヘアクリーム、ヘアスプレー等の形態に製
造される。The hair treatment agent of the present invention can be manufactured in the form of hair milk, blow-drying agent, hair styling mousse, hair styling gel, hair cream, hair spray, etc. by a known method.
なお、本発明の化粧料にはその性能を損なわない範囲で
さらに環状シリコーン、ジメチルノリコーン、軽質流動
イソパラフィンなど従来頭髪用化粧料に公知の成分を適
宜配合するのが好ましい。In addition, it is preferable that the cosmetic composition of the present invention further contains ingredients known to conventional hair cosmetic compositions, such as cyclic silicone, dimethyl noricone, and light liquid isoparaffin, as long as their performance is not impaired.
実施例
つぎに本発明を実施例および比較例に乱づきさらに具体
的に説明する。なお、実施例、比較例中の配合量【３重
量％で示した。EXAMPLES Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples. In addition, the blending amount in Examples and Comparative Examples is shown as 3% by weight.
実施例］−１０および比較例１〜１０
後記第１表に示す組成により常法にてンメチルシリコー
ンガムおよび環状シリコーン等を混合した後、各樹脂、
エタノールを混合、撹拌して乳液状の組成物を得た。Example]-10 and Comparative Examples 1 to 10 After mixing methyl silicone gum, cyclic silicone, etc. in a conventional manner according to the composition shown in Table 1 below, each resin,
Ethanol was mixed and stirred to obtain an emulsion-like composition.
これらを用いてつぎの項目について評価した。Using these, the following items were evaluated.
結果を第１表に合わせ示す。The results are also shown in Table 1.
（評価方法）
試験ザンプルについて、塗布時のべたつきのなさ、なめ
らかさ、セット力はっぎのとおり評価した。(Evaluation method) The test samples were evaluated for non-stickiness, smoothness, and setting power during application.
セミロングルロングのウェーブヘアである専門パネラ−
（２０代女性）１０名の実使用による官能評価
（評価基準）
塗布時のべたつきのなさ、なめらかさ
◎；非常に良好
○：良好
△：やや不良
×・不良
セット力
◎：髪をまとめ、ウェーブを保持するのに充分なセット
力
○ｏ 〃 適度なセット力△・やや弱い
セット力
×：弱いセット力
総合評価
◎：なめらかさ、
セットノノが非常に良好
〃 良好
〃 の少なくとも
一方がやや不充分
〃 の少なくとも
一方が不充分
実施例１１（ブロー剤）
戊
分
（成分Ａ）
プロピレングリコール
ＰＯＥ（５）オレイルエーテル
ジメチルシリコーンガム
（車走シリコーン（株）製、ＴＳＥ２０ＯＡ）環状シリ
コーン
（５員環；車走シリコーン（株）製、
ＴＳ）；’４０５）
（酸分Ｂ）
水
（成分Ｃ）
配合量
５
５
残量
ポリビニルピロリドン
（ＢＡＳＦ社製、ルビスコールに
９０）
０．７
両性樹脂
（ＮＳＣ社製、アンフォマー２８−４９１０）９５％エ
タノール
（成分Ｄ）
香料
０
００
■
６０°Ｃに加熱した成分Ａ中に、同じく６０℃に加熱し
た成分Ｂを加え撹拌混合した。ついで、冷却しながら成
分Ｃおよび成分りを加えた。Professional panelist with semi-long wavy hair
(Women in their 20s) Sensory evaluation based on actual use by 10 people (evaluation criteria) No stickiness and smoothness during application ◎; Very good ○: Good △: Slightly poor Sufficient setting force to hold ○o Moderate setting force △ / Slightly weak setting force Insufficient Example 11 (Blowing agent) Bubun (component A) Propylene glycol POE (5) Oleylether dimethyl silicone gum (TSE20OA, manufactured by Shishuhashi Silicone Co., Ltd.) Cyclic silicone (5-membered ring; Shishuhashi) Manufactured by Silicone Co., Ltd., TS);'405) (Acid content B) Water (component C) Blend amount 5 5 Remaining amount polyvinylpyrrolidone (manufactured by BASF, 90% in Rubiscoll) 0.7 Amphoteric resin (manufactured by NSC, Amfomer 28-4910) 95% ethanol (component D) Flavor 0 00 ■ Component B, which was also heated to 60°C, was added to component A, which was heated to 60°C, and mixed with stirring. Then, component C and other ingredients were added while cooling.
実施例１２（ヘアスタイリングジェル）成 分
配合量（成分Ａ）
プロピレングリコール ２．０テト
ラオレイン酸ポリオキシ
エチレンソルビット（４０Ｅ、Ｏ，）
０
ジメチルシリコーンガム
（車走シリコーン（株）製、Ｔ Ｓ Ｅ２Ｑ（ＩＡ）０
．８
軽質流動イソパラフィン
（日本石油化学（株）製、
日石アイソゾール４００）
２
（成分Ｂ）
カルボキシビニルポリマー
（和光純薬（株）製、ハイビスクコ−１０３）水
（成分Ｃ）
４
残量
ポリビニルピロリドン
（ＢＡＳＦ社製、ルビスコールに−９０） １．０両
性樹脂
（ＮＳＣ社製、アンフオマー２８−４９１０）５
＝１３
９５％エタノール
（成分Ｄ）
トリエタノールアミン
水
（成分Ｅ）
香料
５０
４
３．６
Ｉ
成分Ｂを混合して６０℃に保ち、これに別個に成分Ａを
混合して６０℃に保ったものを加えた。Example 12 (hair styling gel) Ingredients
Blend amount (component A) Propylene glycol 2.0 Polyoxyethylene sorbitol tetraoleate (40E, O,) 0 Dimethyl silicone gum (manufactured by Jumaho Silicone Co., Ltd., T S E2Q (IA) 0
．． 8 Light liquid isoparaffin (manufactured by Nippon Petrochemical Co., Ltd., Nisseki Isosol 400) 2 (Component B) Carboxyvinyl polymer (manufactured by Wako Pure Chemical Industries, Ltd., Hibisukuko-103) Water (component C) 4 Residual amount polyvinylpyrrolidone ( 1.0 Amphoteric resin (manufactured by NSC, Amphomer 28-4910) 5 = 13 95% ethanol (component D) Triethanolamine water (component E) Fragrance 50 4 3.6 I Component B was mixed and kept at 60°C, and component A was separately mixed and kept at 60°C.
撹拌して均一化した後、冷却しながら成分Ｃ１Ｄおよび
Ｅを添加してヘアスタイリングジェルを製造した。After stirring to homogenize, ingredients C1D and E were added while cooling to produce a hair styling gel.
実施例１３（ヘアスタイリングムース）成分
配合量
（成分Ａ）
プロピレングリコール
１．０
ポリオキシエチレン
硬化ヒマシ油（６０Ｅ、Ｏ，）
２．０
ジメチルシリコーンガム
（車走シリコーン（株）製、ＴＳＥ２００Ａ）０．５
＝１４−
（日本石油化学（株）製、８石アイソゾール）４．５（
酸分Ｂ）
水
残量（成分Ｃ）
ポリビニルピロリドン
（ＢＡＳＦ社製、ルビスコールに−９０）０．５両性樹
脂
（ＮＳＣ社製、アンフォマー２８−４９６１） １
，０９５％エタノール １５．
０（成分Ｄ）
香料 ０．１（酸
分Ｅ）
液化石油ガス ２．０フロ
ン１２ ５．０ジメチルエ
ーテル ２．０６０℃に加熱し
た酸分Ａ中に、同じく６０℃に加熱した成分Ｂを加え撹
拌混合した。ついで、冷却しながら成分Ｃおよび成分り
を加えた。この乳化物をエアゾール容器に入れて弁を取
り付けたのち成分Ｅを充填した。Example 13 (hair styling mousse) Ingredient content (ingredient A) Propylene glycol 1.0 Polyoxyethylene hydrogenated castor oil (60E, O,) 2.0 Dimethyl silicone gum (manufactured by Jumaho Silicone Co., Ltd., TSE200A) 0 .5 = 14- (manufactured by Nippon Petrochemical Co., Ltd., 8-stone isosol) 4.5 (
Acid content B) Water
Remaining amount (component C) Polyvinylpyrrolidone (manufactured by BASF, Rubiscoll -90) 0.5 Amphoteric resin (manufactured by NSC, Amfomer 28-4961) 1
,095% ethanol 15.
0 (Component D) Fragrance 0.1 (Acid content E) Liquefied petroleum gas 2.0 Freon 12 5.0 Dimethyl ether 2. Add component B, which was also heated to 60°C, to acid content A heated to 60°C and stir. Mixed. Then, component C and other ingredients were added while cooling. This emulsion was placed in an aerosol container, a valve was attached, and component E was filled.
軽質流動イソパラフィン
実施例１４（ヘアスプレー）
１戊
分
配合量
（成分Ａ）
ポリビニルピロリドン
（ＢＡ Ｓ Ｆ社製、ルビスコールＩ（−，９０）０両
性樹脂
（Ｎ Ｓ Ｃ社製、アンフォラ−２８−４９１０）９９
％エタノール
番別
（成分Ｂ）
４．０
ジメヂルシリコーンガへ
（車走ノリコーン（株）製、
液化石Ａｉ＋ガス
フ〔１ン１１
′Ｉ゛５Ｅ２００Ａ）
０．２
５０
２０．０
成分Ａをエアゾール容器に入れて弁を取りｆ」けたのち
、成分Ｂを充埴した。Light liquid isoparaffin Example 14 (Hairspray) 1 Amount of ingredients (Component A) Polyvinylpyrrolidone (manufactured by BASF, Rubiscol I (-,90) 0 Ampholytic resin (manufactured by NSC, Amphora-28- 4910)99
% Ethanol number (component B) 4.0 To dimedyl silicone gas (manufactured by Kursumasho Noricone Co., Ltd., liquefied fossil Ai + gas fan [1 fan 11'I゛5E200A) 0.2 50 20.0 Component A to aerosol container After putting it in a container and removing the valve, component B was charged.
発明の効果
本発明の頭髪用化粧料は、頭髪に対してべたつきがなく
滑らかさに優れ、かつ適度なセット力をイ４与する。Effects of the Invention The hair cosmetic of the present invention is non-sticky to hair, has excellent smoothness, and provides appropriate setting power.
Claims (2)
４０００〜９０００の整数を意味する］ で示される１種または２種以上のジメチルシリコーンガ
ム、 （ｂ）ポリビニルピロリドン、並びに （ｃ）下式［II］、［III］および［IV］ ▲数式、化学式、表等があります▼［II］ ▲数式、化学式、表等があります▼［III］ ▲数式、化学式、表等があります▼［IV］ で表される構成単位を有するオクチルアクリルアミド−
ブチルアミノエチルメタクリレート−アクリル酸エステ
ル共重合体を含有することを特徴とする頭髪用化粧料。(1) (a) The following formula [I]: ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [I] [In the formula, R^1 and R^2 are methyl groups or hydroxyl groups; n is an integer from 4000 to 9000. (b) polyvinylpyrrolidone, and (c) the following formulas [II], [III] and [IV] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [II] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [III] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [IV] Octylacrylamide having the structural unit represented by -
A hair cosmetic comprising a butylaminoethyl methacrylate-acrylic acid ester copolymer.
ルアクリルアミド−ブチルアミノエチルメタクリレート
−アクリル酸エステル共重合体０．２〜４重量％を含有
し、かつジメチルシリコーンガム（ａ）の配合量に対す
るポリビニルピロリドン（ｂ）とオクチルアクリルアミ
ド−ブチルアミノエチルメタクリレート−アクリル酸エ
ステル共重合体（ｃ）との合計配合量との重量配合比（
ａ）／〔（ｂ）＋（ｃ）〕＝１／１０〜１／１である前
記請求項１記載の頭髪用化粧料。(2) Containing 0.1 to 3% by weight of polyvinylpyrrolidone and 0.2 to 4% by weight of octylacrylamide-butylaminoethyl methacrylate-acrylic acid ester copolymer, and based on the amount of dimethyl silicone gum (a). Weight blending ratio of the total blending amount of pyrrolidone (b) and octylacrylamide-butylaminoethyl methacrylate-acrylic acid ester copolymer (c) (
The hair cosmetic according to claim 1, wherein a)/[(b)+(c)]=1/10 to 1/1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20987389A JPH0621049B2 (en) | 1989-08-14 | 1989-08-14 | Cosmetics for hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20987389A JPH0621049B2 (en) | 1989-08-14 | 1989-08-14 | Cosmetics for hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0374319A true JPH0374319A (en) | 1991-03-28 |
| JPH0621049B2 JPH0621049B2 (en) | 1994-03-23 |
Family
ID=16580055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20987389A Expired - Fee Related JPH0621049B2 (en) | 1989-08-14 | 1989-08-14 | Cosmetics for hair |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0621049B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05139932A (en) * | 1991-11-12 | 1993-06-08 | Kao Corp | Hair cosmetic |
| JP2003081786A (en) * | 2001-09-11 | 2003-03-19 | Hoyu Co Ltd | Hair grooming agent composition |
| EP1666093A1 (en) * | 2004-11-19 | 2006-06-07 | KPSS-Kao Professional Salon Services GmbH | Aerosol hair styling composition comprising amphoteric and non-ionic polymers |
| JP2010189308A (en) * | 2009-02-18 | 2010-09-02 | Kracie Home Products Ltd | Hair cosmetic |
| JP2019112318A (en) * | 2017-12-21 | 2019-07-11 | 株式会社ミルボン | Hairdressing composition and hairdressing method |
-
1989
- 1989-08-14 JP JP20987389A patent/JPH0621049B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05139932A (en) * | 1991-11-12 | 1993-06-08 | Kao Corp | Hair cosmetic |
| JP2003081786A (en) * | 2001-09-11 | 2003-03-19 | Hoyu Co Ltd | Hair grooming agent composition |
| EP1666093A1 (en) * | 2004-11-19 | 2006-06-07 | KPSS-Kao Professional Salon Services GmbH | Aerosol hair styling composition comprising amphoteric and non-ionic polymers |
| JP2010189308A (en) * | 2009-02-18 | 2010-09-02 | Kracie Home Products Ltd | Hair cosmetic |
| JP2019112318A (en) * | 2017-12-21 | 2019-07-11 | 株式会社ミルボン | Hairdressing composition and hairdressing method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0621049B2 (en) | 1994-03-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |