JPH0354144B2 - - Google Patents
Info
- Publication number
- JPH0354144B2 JPH0354144B2 JP57088901A JP8890182A JPH0354144B2 JP H0354144 B2 JPH0354144 B2 JP H0354144B2 JP 57088901 A JP57088901 A JP 57088901A JP 8890182 A JP8890182 A JP 8890182A JP H0354144 B2 JPH0354144 B2 JP H0354144B2
- Authority
- JP
- Japan
- Prior art keywords
- pastel
- pigment
- fatty acid
- higher fatty
- metal salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000049 pigment Substances 0.000 claims description 29
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 150000004665 fatty acids Chemical class 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000004606 Fillers/Extenders Substances 0.000 claims description 13
- 239000008187 granular material Substances 0.000 claims description 11
- 238000004898 kneading Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 238000005469 granulation Methods 0.000 description 13
- 230000003179 granulation Effects 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 238000000465 moulding Methods 0.000 description 9
- -1 fatty acid salts Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 241000416162 Astragalus gummifer Species 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- QTSNFLIDNYOATQ-UHFFFAOYSA-N 2-[(4-chloro-2-nitrophenyl)diazenyl]-n-(2-chlorophenyl)-3-oxobutanamide Chemical compound C=1C=CC=C(Cl)C=1NC(=O)C(C(=O)C)N=NC1=CC=C(Cl)C=C1[N+]([O-])=O QTSNFLIDNYOATQ-UHFFFAOYSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- LVOJOIBIVGEQBP-UHFFFAOYSA-N 4-[[2-chloro-4-[3-chloro-4-[(5-hydroxy-3-methyl-1-phenylpyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-methyl-2-phenylpyrazol-3-ol Chemical compound CC1=NN(C(O)=C1N=NC1=CC=C(C=C1Cl)C1=CC(Cl)=C(C=C1)N=NC1=C(O)N(N=C1C)C1=CC=CC=C1)C1=CC=CC=C1 LVOJOIBIVGEQBP-UHFFFAOYSA-N 0.000 description 1
- AQSOTOUQTVJNMY-UHFFFAOYSA-N 7-(dimethylamino)-4-hydroxy-3-oxophenoxazin-10-ium-1-carboxylic acid;chloride Chemical compound [Cl-].OC(=O)C1=CC(=O)C(O)=C2OC3=CC(N(C)C)=CC=C3[NH+]=C21 AQSOTOUQTVJNMY-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- HBHZKFOUIUMKHV-UHFFFAOYSA-N chembl1982121 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HBHZKFOUIUMKHV-UHFFFAOYSA-N 0.000 description 1
- YOCIQNIEQYCORH-UHFFFAOYSA-M chembl2028361 Chemical compound [Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=CC=C1 YOCIQNIEQYCORH-UHFFFAOYSA-M 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
【発明の詳細な説明】
本発明は、パステル及びその製造方法に関する
もので、より詳細にはソフトな書き味と書き味の
均一性とに優れ、しかも形状及び寸法の一様性と
安定性とを有するパステル及びその製造方法に関
する。尚、ここで、パステルとは、オイルパス或
いはパス等の描画材を意味するものではなく、実
質的に硬化油、パラフイン、蝋等を含まない描画
材である。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a pastel and a method for producing the same, and more specifically, the present invention relates to a pastel and a method for producing the same. The present invention relates to a pastel and a method for producing the same. Note that pastel here does not mean a drawing material such as an oil pass or a pastel, but a drawing material that does not substantially contain hardened oil, paraffin, wax, or the like.
従来、パステルとしては、顔料及び体質顔料
に、トラガカントゴム、アラビアゴムなどの薄い
水溶液を固着剤として加え、よく練つて棒状に固
め、乾燥したものが使用されている。この固着材
は棒状にしたものが崩れないように顔料や体質顔
料を固めておくためのもので定着力はなく、描写
は繊維の固い紙にこれをこすりつけて顔料を付着
させることにより行われ、パステル画が完成した
のちは定着液をかけて定着する。 Conventionally, pastels have been made by adding a thin aqueous solution of gum tragacanth, gum arabic, etc. to pigments and extenders as a fixing agent, kneading the mixture thoroughly to harden it into a rod shape, and drying it. This fixing material is used to solidify pigments and extender pigments so that they do not fall apart in the form of a stick, and does not have any fixing power.Drawing is done by rubbing it against paper with stiff fibers to make the pigment adhere. After the pastel drawing is completed, a fixing solution is applied to fix it.
このため、公知のパステルは一般に製品が部分
的に固く、描けない部分があつたり、書き味が不
均一であるという問題がある。また、その製造に
際しては乾燥に長時間を有し、更に乾燥に際して
製品に曲がりを生じ易く、形状及び寸法が一定し
ないという問題もある。 For this reason, known pastels generally have problems in that they are partially hard, have areas that cannot be drawn, and have an uneven writing feel. In addition, there are also problems in that it takes a long time to dry during production, and the product tends to bend during drying, resulting in inconsistent shape and dimensions.
本発明によれば、顔料、体質顔料及び全体当た
り１乃至12重量％の実質上水不溶性で、且つ常温
で固体の高級脂肪酸金属塩から成る均質混合造粒
物を、その造粒物のまま棒柱状に加圧成形して成
ることを特徴とするパステルが提供される。 According to the present invention, a homogeneous mixed granule consisting of a pigment, an extender pigment, and a higher fatty acid metal salt that is substantially water-insoluble and solid at room temperature in an amount of 1 to 12% by weight based on the total, is made into a rod as it is. A pastel is provided that is formed by pressure molding into a columnar shape.
本発明によれば更に、顔料、体質顔料及び常温
で固体で、且つ実質的に水不溶性の高級脂肪酸金
属塩を含む組成物が水の存在化で混練りされ、
該混練りによつて得られる組成物は造粒、乾燥
され、乾燥された造粒組成物は、その造粒物のま
ま型内で棒柱状にプレス成形されることを特徴と
するパステルの製造方法が提供される。 According to the present invention, a composition comprising a pigment, an extender pigment, and a higher fatty acid metal salt that is solid at room temperature and substantially water-insoluble is kneaded in the presence of water, and the composition is obtained by the kneading. There is provided a method for producing pastels, characterized in that the composition is granulated and dried, and the dried granulated composition is press-molded into a rod shape in a mold as it is.
本発明のパステルは公知のパステルには全く認
められない顕著な特徴を有している。即ち、本発
明のパステルにおいては、高級脂肪酸金属塩が加
圧成形時に優れた固着剤としての作用を呈し、形
状及び寸法安定性に優れたパステルが加圧成形に
より容易に得られるという利点がある。従来、パ
ステルの製造に用いられている水溶性樹脂は、加
圧成形に際してはバインダー的作用はほとんどな
く、従つて従来の処方のものを単にプレス成形に
付しただけでは、固結力のないぼろぼろのものし
か得られない傾向がある。これに対して、本発明
に使用する高級脂肪酸金属塩は、加圧下に容易に
軟化して優れた固着作用を示すものである。 The pastels of the present invention have remarkable features that are not found in any known pastels. That is, the pastel of the present invention has the advantage that the higher fatty acid metal salt acts as an excellent fixing agent during pressure molding, and a pastel with excellent shape and dimensional stability can be easily obtained by pressure molding. . The water-soluble resins conventionally used in the production of pastels have almost no binder effect during pressure molding, and therefore, if a conventional formulation is simply press molded, it will become crumbly with no solidifying power. There is a tendency to only get what you want. On the other hand, the higher fatty acid metal salt used in the present invention easily softens under pressure and exhibits an excellent fixing effect.
のみならず、この高級脂肪酸金属塩で顔料粒子及
び体質顔料粒子を固着したものは、紙に描く際少
しの剪断力で崩れて紙面に容易に付着するという
特性を示す。また、この高級脂肪酸金属塩はそれ
自体滑性があり、かくして、このパステルはやわ
らかな書き味を有しており、更に本発明によれ
ば、書き味が一本のパステルのどの部分でも常に
一様であり、従来のパステルに屡々認められたパ
ステル毎に書き味が異なるというトラブルも有効
に解消されることになる。In addition, pigment particles and extender particles fixed with this higher fatty acid metal salt exhibit the characteristic that when drawing on paper, they crumble with a slight shearing force and easily adhere to the paper surface. In addition, this higher fatty acid metal salt itself is slippery, and thus, this pastel has a soft writing feel.Furthermore, according to the present invention, the writing feeling is always the same on any part of a single pastel. This effectively solves the problem of the different writing tastes of each pastel, which is often encountered with conventional pastels.
本発明において使用する高級脂肪酸金属塩は、
パステルの固着剤として使用するためには常温で
固体のものでなければならない。金属塩として
は、ナトリウム塩、カリウム塩等の水溶性塩やカ
ルシウム塩、マグネシウム塩、バリウム塩、亜鉛
塩等の水不溶性塩を挙げることができる。高級脂
肪酸としては、炭素数12乃至29、特に14乃至22の
飽和脂肪酸、例えば、ラウリン酸、ミリスチン
酸、パルミチン酸、ステアリン酸、アラキン酸、
ベヘン酸、ヘプタデシル酸や、牛脂脂肪酸、各種
硬化油脂肪酸等の混合脂肪酸を用いることができ
る。本発明の目的には、高級脂肪酸塩の内でも、
実質上水不溶性の脂肪酸塩、例えばアルカリ土類
金属塩が好適であり、就中ステアリン酸カルシウ
ムを用いた場合に、書き味の点で最良の結果が得
られる。 The higher fatty acid metal salt used in the present invention is
In order to be used as a pastel fixing agent, it must be solid at room temperature. Examples of metal salts include water-soluble salts such as sodium salts and potassium salts, and water-insoluble salts such as calcium salts, magnesium salts, barium salts, and zinc salts. Higher fatty acids include saturated fatty acids having 12 to 29 carbon atoms, especially 14 to 22 carbon atoms, such as lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid,
Mixed fatty acids such as behenic acid, heptadecylic acid, beef tallow fatty acid, and various hydrogenated oil fatty acids can be used. For the purpose of the present invention, among the higher fatty acid salts,
Substantially water-insoluble fatty acid salts, such as alkaline earth metal salts, are preferred, with calcium stearate giving the best results in terms of writing quality.
本発明においては、高級脂肪酸金属塩を全体当
り１乃至12重量％、特に２乃至８重量％の量で用
いることも重要であり、この量が上記範囲よりも
少ないとパステルに必要な固着力やソフトな書き
味が失われることになり、一方上記範囲よりも多
いと、パステルとは異なつた描画材となり、プレ
ス成形も困難となる傾向がある。 In the present invention, it is also important to use the higher fatty acid metal salt in an amount of 1 to 12% by weight, especially 2 to 8% by weight, based on the total weight. On the other hand, if the amount exceeds the above range, the drawing material becomes different from pastel, and press molding tends to be difficult.
本発明において、顔料及び体質顔料としては、
従来パステルに使用されているものが全て制限な
しに使用することができる。顔料及び体質顔料の
適当な例は、これに制限されるものでないが、次
の通りである。 In the present invention, pigments and extender pigments include:
All the materials conventionally used for pastels can be used without restriction. Suitable examples of pigments and extender pigments include, but are not limited to, the following:
黒色顔料
カーボンブラツク、ランプブラツク、ボーンブ
ラツク、鉄黒。Black pigments: carbon black, lamp black, bone black, iron black.
黄色顔料
黄色酸化鉄、ハンザイエロー、ナフトールイエ
ロー、チタンイエロー、ベンジジンイエロー、パ
ーマネントイエロー。Yellow pigments: yellow iron oxide, Hansa yellow, naphthol yellow, titanium yellow, benzidine yellow, permanent yellow.
橙色顔料
パーマネントオレンジ、バルカンオレンジ、ベ
ンジジンオレンジ、インダスレンブリリアントオ
レンジ。Orange pigments Permanent Orange, Vulcan Orange, Benzidine Orange, IndusThrene Brilliant Orange.
赤色顔料
ベンガラ、リソールレツド、ブリリアントカー
ミン、パーマネントレツド。Red pigment Red pigment, Resole Red, Brilliant Carmine, Permanent Red.
紫色顔料
マンガン紫、フアストバイオレツト、メチルバ
イオレツトレーキ、キナクリドンバイオレツト。Violet pigments Manganese violet, fast violet, methyl violet lake, quinacridone violet.
青色顔料
紺青、フタロシアニンブルー、群青、フアース
トスカイブルー。Blue pigments: navy blue, phthalocyanine blue, ultramarine blue, first sky blue.
緑色顔料
マラカイトグリーンレーキ、フタロシアニング
リーン、ナフトールグリーン。Green pigments malachite green lake, phthalocyanine green, naphthol green.
白色顔料 チタン白、亜鉛華。white pigment Titanium white, zinc white.
体質顔料
炭酸カルシウム、硫酸バリウム、硫酸カルシウ
ム、炭酸マグネシウム、クレー、シリカ、タル
ク、アルミナホワイト。Extending pigments: calcium carbonate, barium sulfate, calcium sulfate, magnesium carbonate, clay, silica, talc, alumina white.
所謂パステルカラーとしての中間調の色彩を発
現させるためには、全体当り顔料が１乃至50重量
％、特に５乃至40重量％及び体質顔料が48乃至97
重量％、特に58乃至93重量％の量で夫々存在させ
ることが望ましい。 In order to express mid-tone colors as so-called pastel colors, the amount of pigment is 1 to 50% by weight, especially 5 to 40% by weight, and the extender pigment is 48 to 97% by weight.
Preferably, each is present in an amount of 58 to 93% by weight, particularly 58 to 93% by weight.
本発明に用いるパステル描画材中には、上述し
た必須成分に加えて、任意の助剤を配合できる。
例えば、用いる高級脂肪酸金属塩が水不溶性のも
のである場合には、該金属塩或いは更に顔料等の
濡れ性を良くするために、界面活性剤を配合する
ことができる。界面活性剤の代りに勿論水溶性の
脂肪酸金属塩を併用してもよい。また、香料等を
微量配合することもできる。 In addition to the above-mentioned essential components, arbitrary auxiliary agents can be added to the pastel drawing material used in the present invention.
For example, when the higher fatty acid metal salt used is water-insoluble, a surfactant may be added to improve the wettability of the metal salt or pigment. Of course, a water-soluble fatty acid metal salt may also be used in place of the surfactant. In addition, a small amount of fragrance or the like can be added.
本発明によれば、上述した顔料、体質顔料、高
級脂肪酸塩及び他の成分を水の存在下に混練し、
この混練組成物を造粒し、乾燥する。混練は、組
成物の粘稠度に応じて、ヘンシエルミキサー、ニ
ーダー、バンバリミキサー、ロール等を用いて行
うことができ、高級脂肪酸塩が顔料や体質顔料の
粒子と均密に混和するように混練を行う。上記成
分に添加する水分は、各成分の微粒化分散と混和
が一様に行われるようなものであればよく、乾燥
状態の各成分の全体を基準にして、５乃至20重量
％の水分を存在させることが望ましい。混練組成
物の造粒は、それ自体公知の造粒法、例えば噴霧
乾燥造粒法、押出造粒法、鋳型造粒法、流動造粒
法、フレーキング造粒法、解砕造粒法、転動造粒
法、タブレツト造粒法等の任意の手法で行われ
る。粒の形態は、顆粒状、球状、円柱状、不整形
状、タブレツト状等の任意のものであつてよく、
その粒径は取扱いやプレス成形の見地から0.1乃
至1.5mm、特に0.5乃至１mmの範囲にあるのが望ま
しい。上述した造粒法の或るものでは、造粒と同
時に乾燥が行われるが、造粒後の組成物が未だ水
分を保持している場合には、この粒状物を乾燥
し、水分を除去する。 According to the present invention, the pigment, extender pigment, higher fatty acid salt, and other components described above are kneaded in the presence of water,
This kneaded composition is granulated and dried. Kneading can be carried out using a Henschel mixer, kneader, Banbury mixer, roll, etc. depending on the viscosity of the composition, so that the higher fatty acid salt is evenly mixed with the pigment and extender pigment particles. Perform kneading. The amount of water added to the above components may be such as to uniformly atomize, disperse, and mix each component, and add 5 to 20% water by weight based on the total amount of each component in a dry state. It is desirable to have it exist. The kneaded composition can be granulated using a granulation method known per se, such as a spray drying granulation method, an extrusion granulation method, a mold granulation method, a fluidized granulation method, a flaking granulation method, a crushing granulation method, This can be carried out by any method such as rolling granulation method or tablet granulation method. The shape of the particles may be arbitrary, such as granules, spheres, cylinders, irregular shapes, tablets, etc.
The particle size is preferably in the range of 0.1 to 1.5 mm, particularly 0.5 to 1 mm, from the viewpoint of handling and press molding. In some of the above-mentioned granulation methods, drying is carried out simultaneously with granulation, but if the composition after granulation still retains moisture, the granules are dried to remove moisture. .
次いで得られた乾燥粒状物をそのまま型内に充
填し、これをプレスして棒柱状のパステルの形状
に成形し、製品とする。この際のプレス圧力は
200乃至1500Kg／cm2の範囲で変化でき、成形圧力
が小さい場合のソフトタイプのパステルから、成
形圧力が大きい場合のハードタイプのパステル
迄、同じ材料から圧力を変化させることにより描
画特性の異なるパステルが得られることも顕著な
利点である。 Next, the obtained dry granules are filled into a mold as they are, and pressed to form a rod-like pastel shape into a product. The press pressure at this time is
It can be varied in the range of 200 to 1500Kg/ cm2 , from soft type pastels when the molding pressure is low to hard type pastels when the molding pressure is high, pastels with different drawing characteristics from the same material by changing the pressure. Another notable advantage is that
また、本発明によれば、上述した各成分を混
練、造粒、乾燥して粒状物とすることにより、各
成分が均質な混和状態となるばかりでなく、粒状
で乾燥が行われるため、従来の方法に比して乾燥
時間が短かく生産性が高いという利点がある。更
に、高級脂肪酸塩を用いること及び予め混練粒状
物を形成することに関連して、所謂ドライでプレ
ス成形が可能となり、形状や寸法が一定で、書き
味も一様で、不良率の極めて低いパステル製品が
得られるという利点もある。 Furthermore, according to the present invention, by kneading, granulating, and drying the above-mentioned components to form granules, each component not only becomes a homogeneous mixture, but also granules are dried. This method has the advantage of shorter drying time and higher productivity than the method described above. Furthermore, in connection with the use of higher fatty acid salts and the preparation of kneaded granules in advance, so-called dry press molding is possible, resulting in uniform shape and dimensions, uniform writing feel, and an extremely low defect rate. Another advantage is that pastel products can be obtained.
本発明を次の例で説明する。 The invention is illustrated by the following example.
実施例 １
下記処方
硫酸バリウム 80重量部
二酸化チタン 10 〃
ステアリン酸カルシウム ８ 〃
オレイン酸カリウム １ 〃
界面活性剤 １ 〃
（粉末オロミン、ミヨシ油脂製）
の組成物を、14重量部の水の存在下に良く混練
し、この混連組成物を押出造粒法により、平均粒
径１mmの粒状物に成形し、60℃で１時間乾燥し
た。Example 1 The following formulation: Barium sulfate 80 parts by weight Titanium dioxide 10 〃 Calcium stearate 8 〃 Potassium oleate 1 〃 Surfactant 1 〃 (Powdered Oromin, manufactured by Miyoshi Oil & Fat) A composition of the following was added in the presence of 14 parts by weight of water. After thorough kneading, the mixed composition was formed into granules having an average particle size of 1 mm by extrusion granulation, and dried at 60° C. for 1 hour.
この粒状物を、パステル成形用金型内に入れ、
1000Kg／cm2の圧力で成形し、径８mm及び長さ50mm
の角柱状パステルに成形した。 Put this granular material into a pastel mold,
Molded at a pressure of 1000Kg/ cm2 , diameter 8mm and length 50mm
It was molded into a prismatic pastel.
比較のため、トラガカントゴムを固着剤として
使用した従来のパステルと本実施例のパステルと
について、10名のパネラーを使用して実際の紙へ
の描画を行わせたところ、10名とも本実施例の製
品の方がソフトで良好な書き味であるという回答
が得られた。 For comparison, 10 panelists were asked to draw on actual paper using a conventional pastel using rubber tragacanth as a fixing agent and the pastel of this example. Some respondents said that the product was softer and had a better writing quality.
実施例 ２
下記処方
炭酸カルシウム 90重量部
ハンザイエロー10G ６ 〃
ステアリン酸ナトリウム ４ 〃
を用いる以外は、実施例１と同様にして書き味が
ソフトで良好なパステルが得られた。Example 2 A pastel with a soft and good writing feel was obtained in the same manner as in Example 1, except that the following formulation was used: 90 parts by weight of calcium carbonate, 6 parts of Hansa Yellow 10G, and 4 parts of sodium stearate.
Claims (1)
の実質上水不溶性で、且つ常温で固体の高級脂肪
酸金属塩から成る均質混合造粒物を、その造粒物
のまま棒柱状に加圧成形して成ることを特徴とす
るパステル。 ２ 前記高級脂肪酸金属塩がステアリン酸カルシ
ウムである特許請求の範囲第１記載のパステル。 ３ 顔料及び体質顔料が全体当たり１乃至50重量
％及び48乃至97重量％の量で夫々存在する特許請
求の範囲第１項記載のパステル。 ４ 顔料、体質顔料及び常温で固体で、且つ実質
的に水不溶性の高級脂肪酸金属塩を含む組成物が
水の存在下で混練りされ、 該混練りによつて得られる組成物は造粒、乾燥
され、乾燥された造粒組成物は、その造粒物のま
ま型内で棒柱状にプレス成形されることを特徴と
するパステルの製造方法。[Claims] 1. Pigment, extender pigment, and 1 to 12% by weight based on the total amount
A pastel characterized in that a homogeneous mixed granule consisting of a higher fatty acid metal salt that is substantially water-insoluble and solid at room temperature is pressure-molded into a rod shape as the granule. 2. The pastel according to claim 1, wherein the higher fatty acid metal salt is calcium stearate. 3. A pastel according to claim 1, wherein the pigment and the extender pigment are present in an amount of 1 to 50% by weight and 48 to 97% by weight, respectively. 4. A composition containing a pigment, an extender pigment, and a higher fatty acid metal salt that is solid at room temperature and is substantially water-insoluble is kneaded in the presence of water, and the composition obtained by the kneading is granulated, A method for producing pastels, characterized in that the dried granulated composition is press-molded into a rod shape in a mold as it is.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8890182A JPS58206672A (en) | 1982-05-27 | 1982-05-27 | Pastel and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8890182A JPS58206672A (en) | 1982-05-27 | 1982-05-27 | Pastel and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58206672A JPS58206672A (en) | 1983-12-01 |
| JPH0354144B2 true JPH0354144B2 (en) | 1991-08-19 |
Family
ID=13955851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8890182A Granted JPS58206672A (en) | 1982-05-27 | 1982-05-27 | Pastel and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58206672A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6357683A (en) * | 1986-08-29 | 1988-03-12 | Bunchiyou:Kk | Production of crayon |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5117096A (en) * | 1974-08-01 | 1976-02-10 | Tokyo Shibaura Electric Co | |
| JPS5258621A (en) * | 1975-11-07 | 1977-05-14 | Seiyuu Sutoaa Kk | Waterrsoluble crayon |
| JPS52134519A (en) * | 1976-05-06 | 1977-11-10 | Takashi Nagashima | Fluorescent crayon pastel |
| JPS5422137A (en) * | 1977-07-20 | 1979-02-19 | Hitachi Denshi Ltd | Bus line chekcing device |
| JPS5422323A (en) * | 1977-07-21 | 1979-02-20 | Mitsui Toatsu Chem Inc | Preparation of urea for industrial uses |
-
1982
- 1982-05-27 JP JP8890182A patent/JPS58206672A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5117096A (en) * | 1974-08-01 | 1976-02-10 | Tokyo Shibaura Electric Co | |
| JPS5258621A (en) * | 1975-11-07 | 1977-05-14 | Seiyuu Sutoaa Kk | Waterrsoluble crayon |
| JPS52134519A (en) * | 1976-05-06 | 1977-11-10 | Takashi Nagashima | Fluorescent crayon pastel |
| JPS5422137A (en) * | 1977-07-20 | 1979-02-19 | Hitachi Denshi Ltd | Bus line chekcing device |
| JPS5422323A (en) * | 1977-07-21 | 1979-02-20 | Mitsui Toatsu Chem Inc | Preparation of urea for industrial uses |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58206672A (en) | 1983-12-01 |
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