JPH0352495B2 - - Google Patents

Info

Publication number: JPH0352495B2
Authority: JP; Japan
Prior art keywords: resin; weather resistance; tert; weight; pmma
Prior art date: 1983-01-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP791983A

Other languages

English (en)

Japanese (ja)

Other versions

JPS59133240A (ja

Inventor

Tetsuya Niimura

Masao Atsumi

Hidehiko Takizawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Denka Co Ltd

Original Assignee

Denki Kagaku Kogyo KK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-01-20

Filing date

1983-01-20

Publication date

1991-08-12

1983-01-20 Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK

1983-01-20 Priority to JP791983A priority Critical patent/JPS59133240A/ja

1984-07-31 Publication of JPS59133240A publication Critical patent/JPS59133240A/ja

1991-08-12 Publication of JPH0352495B2 publication Critical patent/JPH0352495B2/ja

Status Granted legal-status Critical Current

Links

PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
239000003505 polymerization initiator Substances 0.000 claims description 10
239000012986 chain transfer agent Substances 0.000 claims description 7
YWDBZVIHZORXHG-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-1-yl) decanedioate Chemical compound CC1(C)CCCC(C)(C)N1OC(=O)CCCCCCCCC(=O)ON1C(C)(C)CCCC1(C)C YWDBZVIHZORXHG-UHFFFAOYSA-N 0.000 claims description 6
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 5
239000000539 dimer Substances 0.000 claims description 5
239000011342 resin composition Substances 0.000 claims description 5
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 3
229920006026 co-polymeric resin Polymers 0.000 claims description 3
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 claims 1
239000011347 resin Substances 0.000 description 27
229920005989 resin Polymers 0.000 description 27
230000000052 comparative effect Effects 0.000 description 14
229920003229 poly(methyl methacrylate) Polymers 0.000 description 14
239000004926 polymethyl methacrylate Substances 0.000 description 14
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
239000008188 pellet Substances 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 6
YEYCMBWKTZNPDH-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) benzoate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)C1=CC=CC=C1 YEYCMBWKTZNPDH-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
230000000694 effects Effects 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
-1 tert-butyl peroxy esters Chemical class 0.000 description 5
QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
230000007423 decrease Effects 0.000 description 3
230000006866 deterioration Effects 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
239000004342 Benzoyl peroxide Substances 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
239000012965 benzophenone Substances 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
229940116351 sebacate Drugs 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
238000012546 transfer Methods 0.000 description 2
ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 1
HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
MAZSRFDGMAAKBY-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethylpiperidin-1-yl)oxydecanoic acid Chemical compound CC1(C)CCCC(C)(C)N1OC(=O)CCCCCCCCC(O)=O MAZSRFDGMAAKBY-UHFFFAOYSA-N 0.000 description 1
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 1
CARSMBZECAABMO-UHFFFAOYSA-N 3-chloro-2,6-dimethylbenzoic acid Chemical compound CC1=CC=C(Cl)C(C)=C1C(O)=O CARSMBZECAABMO-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
VOOVDZMAQQVAEW-PFONDFGASA-N [(z)-2-methyl-4-phenylpent-3-en-2-yl]benzene Chemical compound C=1C=CC=CC=1C(/C)=C\C(C)(C)C1=CC=CC=C1 VOOVDZMAQQVAEW-PFONDFGASA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
229940067597 azelate Drugs 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
UPIWXMRIPODGLE-UHFFFAOYSA-N butyl benzenecarboperoxoate Chemical compound CCCCOOC(=O)C1=CC=CC=C1 UPIWXMRIPODGLE-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
YCWQBZCTYWZZAX-UHFFFAOYSA-N ditert-butyl 7,8-dioxabicyclo[4.2.0]octane-3,6-dicarboxylate Chemical compound C1C(C(=O)OC(C)(C)C)CCC2(C(=O)OC(C)(C)C)OOC21 YCWQBZCTYWZZAX-UHFFFAOYSA-N 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000113 methacrylic resin Substances 0.000 description 1
238000000034 method Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000002954 polymerization reaction product Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
238000012719 thermal polymerization Methods 0.000 description 1
239000006097 ultraviolet radiation absorber Substances 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP791983A 1983-01-20 1983-01-20 樹脂組成物 Granted JPS59133240A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP791983A JPS59133240A (ja)	1983-01-20	1983-01-20	樹脂組成物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP791983A JPS59133240A (ja)	1983-01-20	1983-01-20	樹脂組成物

Publications (2)

Publication Number	Publication Date
JPS59133240A JPS59133240A (ja)	1984-07-31
JPH0352495B2 true JPH0352495B2 (hu)	1991-08-12

Family

ID=11678932

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP791983A Granted JPS59133240A (ja)	1983-01-20	1983-01-20	樹脂組成物

Country Status (1)

Country	Link
JP (1)	JPS59133240A (hu)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH064740B2 (ja) *	1985-07-04	1994-01-19	電気化学工業株式会社	樹脂組成物
JPH0619615U (ja) *	1992-05-08	1994-03-15	弘光上村	背中を冷やす冷房器具

1983
- 1983-01-20 JP JP791983A patent/JPS59133240A/ja active Granted

Also Published As

Publication number	Publication date
JPS59133240A (ja)	1984-07-31

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