JPH0350289A - Non-emulsion type foam aerosol composition - Google Patents
Non-emulsion type foam aerosol compositionInfo
- Publication number
- JPH0350289A JPH0350289A JP18405389A JP18405389A JPH0350289A JP H0350289 A JPH0350289 A JP H0350289A JP 18405389 A JP18405389 A JP 18405389A JP 18405389 A JP18405389 A JP 18405389A JP H0350289 A JPH0350289 A JP H0350289A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- component
- propellant
- liquid
- aerosol composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 22
- 239000006260 foam Substances 0.000 title claims abstract description 19
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 239000000839 emulsion Substances 0.000 title description 4
- 239000003380 propellant Substances 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 239000003921 oil Substances 0.000 abstract description 33
- 235000019198 oils Nutrition 0.000 abstract description 33
- -1 liquid paraffin) Chemical class 0.000 abstract description 12
- 239000001993 wax Substances 0.000 abstract description 7
- 239000011550 stock solution Substances 0.000 abstract description 5
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 4
- 239000000194 fatty acid Substances 0.000 abstract description 4
- 229930195729 fatty acid Natural products 0.000 abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract description 3
- 229940057995 liquid paraffin Drugs 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 229920001296 polysiloxane Polymers 0.000 abstract description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005642 Oleic acid Substances 0.000 abstract description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004203 carnauba wax Substances 0.000 abstract description 2
- 235000013869 carnauba wax Nutrition 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- 150000004665 fatty acids Chemical class 0.000 abstract description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 abstract description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 2
- 235000012424 soybean oil Nutrition 0.000 abstract description 2
- 239000003549 soybean oil Substances 0.000 abstract description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- 239000010495 camellia oil Substances 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
- 229940029284 trichlorofluoromethane Drugs 0.000 description 3
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 2
- 229940099364 dichlorofluoromethane Drugs 0.000 description 2
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229940100463 hexyl laurate Drugs 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 2
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229940042585 tocopherol acetate Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- ZXUJWPHOPHHZLR-UHFFFAOYSA-N 1,1,1-trichloro-2-fluoroethane Chemical compound FCC(Cl)(Cl)Cl ZXUJWPHOPHHZLR-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 235000006732 Torreya nucifera Nutrition 0.000 description 1
- 244000111306 Torreya nucifera Species 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- GQXQIRNPJBUEGY-UHFFFAOYSA-N hexadecan-7-yl 2,2-dimethyloctanoate Chemical compound CCCCCCCCCC(CCCCCC)OC(=O)C(C)(C)CCCCCC GQXQIRNPJBUEGY-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- WNIFXKPDILJURQ-JKPOUOEOSA-N octadecyl (2s,4as,6ar,6as,6br,8ar,10s,12as,14br)-10-hydroxy-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-3,4,5,6,6a,7,8,8a,10,11,12,14b-dodecahydro-1h-picene-2-carboxylate Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CC[C@@](C(=O)OCCCCCCCCCCCCCCCCCC)(C)C[C@H]5C4=CC(=O)[C@@H]3[C@]21C WNIFXKPDILJURQ-JKPOUOEOSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- WNIFXKPDILJURQ-UHFFFAOYSA-N stearyl glycyrrhizinate Natural products C1CC(O)C(C)(C)C2CCC3(C)C4(C)CCC5(C)CCC(C(=O)OCCCCCCCCCCCCCCCCCC)(C)CC5C4=CC(=O)C3C21C WNIFXKPDILJURQ-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000003871 white petrolatum Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、油性化粧料のクレンジング剤等として有用な
非乳化型泡沫エアゾール組成物に関し、ざらに詳しくは
、液状油分と、固型油分と、噴射剤とを含有する洗浄力
、使用性に優れ、安定性良好な非乳化型泡沫エアゾール
組成物に関する。Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a non-emulsifying foam aerosol composition useful as a cleansing agent for oil-based cosmetics, etc. The present invention relates to a non-emulsifying foam aerosol composition containing a propellant and a propellant, which has excellent detergency, usability, and stability.
［従来の技術］
従来、エアゾール組成物には、原液、噴射剤の組合せに
より安定型泡沫、速崩壊型泡沫、噴射型等がある。安定
型泡沫は、噴射剤が溶解している油相からなる内相と噴
射剤との溶解性の悪い水相との２相からなるＯ／Ｗ型エ
マルジョンで形成されている。Ｏ／Ｗ型エマルジョンの
泡沫型エアゾール組成物には、クレンジング用化粧料が
あるが、洗浄力が低く油性のメーキャップの洗浄には不
適当であった。油性のメーキャップを落とすには油分が
最も効果があり、油分と噴射剤の原液で安定型泡沫が得
られれば最も好ましいが、油分と噴射剤は、非常に相溶
性が良く噴射剤の蒸散が早いため、安定型泡沫を得るこ
とが困難であった。[Prior Art] Conventionally, aerosol compositions include stable foam, rapidly disintegrating foam, spray type, etc. depending on the combination of stock solution and propellant. The stable foam is formed of an O/W emulsion consisting of two phases: an internal phase consisting of an oil phase in which a propellant is dissolved, and an aqueous phase in which the propellant has poor solubility. Foam type aerosol compositions of O/W type emulsions are available as cleansing cosmetics, but they have low cleaning power and are unsuitable for cleaning oil-based makeup. Oil is the most effective for removing oil-based makeup, and it is most preferable if a stable foam can be obtained with a undiluted solution of oil and propellant, but oil and propellant are very compatible and the propellant evaporates quickly. Therefore, it was difficult to obtain stable foam.
［発明が解決しようとする課題］
本発明者は上記欠点について検討した結果、固型油分を
用いたならば、安定で洗浄力に優れた組成物が得られる
ことを見出して本発明を完成するに至った。[Problems to be Solved by the Invention] As a result of studying the above-mentioned drawbacks, the present inventor has discovered that a composition that is stable and has excellent detergency can be obtained by using a solid oil component, and has completed the present invention. reached.
［課題を解決するための手段］
すなわち、本発明は、液状油分と、固型油分と、噴射剤
とを含有することを特徴とする非乳化型泡沫エアゾール
組成物に関する。[Means for Solving the Problems] That is, the present invention relates to a non-emulsifying foam aerosol composition characterized by containing a liquid oil component, a solid oil component, and a propellant.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明で用いられる液状油分としては、常温で液状のも
ので、例えば、アボガド油、ツバキ油、タードル油、マ
カデミアナツツ油、トウモロコシ油、ミンク油、オリー
ブ油、ナタネ油、卵黄油、ゴマ油、バーシック油、小麦
胚芽油、サザンカ油、ヒマシ油、アマニ油、サフラワー
油、綿実油、エノ油、大豆油、落花生油、茶実油、カヤ
油、コメヌカ油、シナキリ油、日本キリ油、ホホバ油、
胚芽油、トリグリセリン、トリオクタンサングリセリン
、トリイソパルミチンサングリセリン等の液状油脂、流
動パラフィン、スクワレン、スクワラン、ブリスタン等
の炭化水素、オレイン酸、トール油、イソステアリン酸
等の高級アルコール脂肪酸、ラウリルアルコール、オレ
イルアルコール、イソステアリルアルコール、オクチル
ドデカノール等の高級アルコール、メチルポリシロキサ
ン、メチルフェニルポリシロキサン、メチルハイドロジ
エンポリシロキサン、デカメチルポリシロキサン等のシ
リコーン、ミリスチン酸イソプロピル、パルミチン酸イ
ソプロピル、ラウリン酸ヘキシル、オレイン酸オレイル
、オレイン酸デシルミリスチン酸オクチルドデシル、ジ
メチルオクタン酸へキシルデシル、フタル酸ジエチル、
フタル酸ジブチル等のエステル類等が挙げられる。The liquid oil used in the present invention is one that is liquid at room temperature, such as avocado oil, camellia oil, tardle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, and basic oil. , wheat germ oil, sasanquat oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, sinakiri oil, Japanese tung oil, jojoba oil,
Germ oil, liquid oils and fats such as triglycerin, trioctane sanglycerin, and triisopalmitine sanglycerin, hydrocarbons such as liquid paraffin, squalene, squalane, and bristane, higher alcohol fatty acids such as oleic acid, tall oil, and isostearic acid, and lauryl alcohol. , higher alcohols such as oleyl alcohol, isostearyl alcohol, and octyldodecanol, silicones such as methylpolysiloxane, methylphenylpolysiloxane, methylhydrodiene polysiloxane, and decamethylpolysiloxane, isopropyl myristate, isopropyl palmitate, and hexyl laurate. , oleyl oleate, decyl oleate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate,
Examples include esters such as dibutyl phthalate.
本発明で用いられる液状油分の配合量は、原液全量中の
３０〜８９．９９重重量が好ましく、ざらに好ましくは
４０〜７５重量％である。The amount of liquid oil used in the present invention is preferably 30 to 89.99% by weight, more preferably 40 to 75% by weight based on the total amount of the stock solution.
本発明に用いられる固型油分としては、常温で固型のも
のであり、例えば、ピースワックス、カルナバワックス
等の蛾類、パラフィンワックス、セレシン、マイクロク
リスタリンワックス等の炭化水素、ラウリン酸、ミリス
チン酸、パルミチン酸、ステアリン酸、ベヘニン酸等の
脂肪酸、ラウリルアルコール、セタノール、ステアリル
アルコール等の脂肪族アルコール、ポーラワックス、固
型トリグリセライド等が挙げられる。The solid oil used in the present invention is one that is solid at room temperature, such as moth wax such as peace wax and carnauba wax, hydrocarbons such as paraffin wax, ceresin, and microcrystalline wax, lauric acid, and myristic acid. , fatty acids such as palmitic acid, stearic acid, and behenic acid, aliphatic alcohols such as lauryl alcohol, cetanol, and stearyl alcohol, polar wax, and solid triglycerides.
本発明で用いられる固型油分の配合量は、原液全量中の
０．１重量％以上、好ましくは０．５重量％以上、ざら
に好ましくは１重量％以上である。０．１重量％未満で
は、安定型泡沫は得られない。The amount of solid oil used in the present invention is 0.1% by weight or more, preferably 0.5% by weight or more, and more preferably 1% by weight or more based on the total amount of the stock solution. If the amount is less than 0.1% by weight, stable foam cannot be obtained.
本発明に用いられる噴射剤は、通常エアゾール製品に用
いられる噴射剤を用いることができる。As the propellant used in the present invention, propellants commonly used in aerosol products can be used.
具体例を挙げるとトリクロロフルオロメタン、ジクロロ
ジフルオロメタン、ジクロロフルオロメタン、トリクロ
ロトリフルオロメタン、ジクロロテトラフルオロエタン
等のクロロフルオロカーボン、プロパン、イソブタン、
ノルマルブタンおよびその混合物である液化石油ガス（
以下ＬＰＧと略す）等の液化ガスである。これらの噴射
剤に加えてジメチルエーテル、炭酸ガス、窒素ガスを用
いてもよい。これらのガスは単独でもまた２種以上を混
合して用いることができる。配合量は３〜９０重量％が
好ましい。３重量％未満では良好な泡沫が得られない。Specific examples include chlorofluorocarbons such as trichlorofluoromethane, dichlorodifluoromethane, dichlorofluoromethane, trichlorotrifluoromethane, and dichlorotetrafluoroethane, propane, isobutane,
Liquefied petroleum gas (normal butane and its mixtures)
It is a liquefied gas such as LPG (hereinafter abbreviated as LPG). In addition to these propellants, dimethyl ether, carbon dioxide, and nitrogen gas may also be used. These gases can be used alone or in combination of two or more. The blending amount is preferably 3 to 90% by weight. If it is less than 3% by weight, good foam cannot be obtained.
本発明の泡沫型エアゾール組成物には、上記の必須成分
の他に防腐剤、色材、粉末、酸化防止剤、香料、紫外線
吸収剤、界面活性剤、薬剤、半固型油分、アルコール、
保湿剤等を加えることができる。また、系の安定性を損
なわない範囲での水の添加は、ざらに消泡時間を長くし
、泡を安定化することができる。In addition to the above-mentioned essential ingredients, the foam-type aerosol composition of the present invention contains preservatives, colorants, powders, antioxidants, fragrances, ultraviolet absorbers, surfactants, drugs, semi-solid oils, alcohol,
Moisturizers etc. can be added. Furthermore, adding water within a range that does not impair the stability of the system can roughly lengthen the defoaming time and stabilize the foam.
［発明の効果］
本発明の非乳化型泡沫エアゾール組成物は、油性化粧料
のクレンジング剤等として有用であり、洗浄力、使用性
、安定性に優れるものである。[Effects of the Invention] The non-emulsifying foam aerosol composition of the present invention is useful as a cleansing agent for oil-based cosmetics, and has excellent detergency, usability, and stability.
［実施例］
次に実施例により、本発明の効果について説明する。本
発明はこれらに限定きれるものではない。配合量は重量
％である。[Example] Next, the effects of the present invention will be explained with reference to Examples. The present invention is not limited to these. The blending amount is in weight%.
実施例１ 洗い流しタイプクレンジング化粧料（１）オ
リーブ油 １５（２）ネオ−ベ
ンチルーグリコール−
ジ−ｎ−デカフェート３５
（３）ポリオキシエチレン（６モル付加）オレイルエー
テル １０
（４）ピースワックス １０（５）
ジクロロテトラフルオロエタン ２５製法
（１）〜（４）を７０〜８０℃で加熱撹拌溶解し、エア
ゾール缶に充填後、バルブをクリンプし、（５）を充填
した。Example 1 Rinse-off type cleansing cosmetic (1) Olive oil 15 (2) Neo-benthyl glycol-di-n-decafate 35 (3) Polyoxyethylene (6 moles added) oleyl ether 10 (4) Peace wax 10 (5) )
Dichlorotetrafluoroethane 25 Production Methods (1) to (4) were heated and stirred to dissolve at 70 to 80°C, filled into an aerosol can, the valve was crimped, and (5) was filled.
実施例１と、従来のＯ／Ｗ乳化型の泡沫型エアゾールク
レンジング化粧料との洗浄力について比較した。表−１
のデータは女性パネル４０名に油性のファンデーション
を塗布してもらい、その落ち具合をテストしたものであ
る。The detergency of Example 1 and a conventional O/W emulsion foam aerosol cleansing cosmetic were compared. Table-1
The data is based on a panel of 40 women who applied oil-based foundation and tested how well it removed.
表−１から明らかなように本発明の実施例は、従来のＯ
／Ｗ乳化型の泡沫型エアゾールクレンジング化粧料に比
べて、洗浄力の非常に高いものであった。また、このエ
アゾールタイプクレンジング化粧料は、従来のポンプ容
器式クレンジング化粧料と比べて以下のような利点があ
る。As is clear from Table 1, the embodiment of the present invention is different from the conventional O
/W The cleaning power was extremely high compared to the emulsified foam type aerosol cleansing cosmetic. Additionally, this aerosol type cleansing cosmetic has the following advantages compared to conventional pump container type cleansing cosmetics.
■手の平にとった時、たれ落ちない。■When you take it in the palm of your hand, it won't drip.
■順に塗布し易い。■Easy to apply in order.
■洗い流し易い。■Easy to wash away.
実施例２ ふき取りタイプクレンジング化粧料（１）ミ
リスチン酸イソプロピル ４１．９９（２）オ
レイルアルコール ５０（３）２−ヒド
ロキシ−４−メトキシ
ベンゾフェノン ３
（４）白色ワセリン ２（５）
ステアリン酸 ０．０１（６）
ジクロロフルオロメタン ２（７） Ｌ Ｐ
Ｇ １製法
（１）〜（５）を７０〜８０℃で加熱撹拌溶解後、エア
ゾール缶に充填後、バルブをクリンプし、（（５） （
７）を充填した。Example 2 Wipe-off type cleansing cosmetic (1) Isopropyl myristate 41.99 (2) Oleyl alcohol 50 (3) 2-hydroxy-4-methoxybenzophenone 3 (4) White petrolatum 2 (5)
Stearic acid 0.01(6)
Dichlorofluoromethane 2(7) L P
After dissolving G1 manufacturing method (1) to (5) with stirring at 70 to 80°C, filling it into an aerosol can, crimping the valve, ((5) (
7) was filled.
実施例３ ふき取りタイプクレンジング化粧料（１）流
動パラフィン ５（２）セチル−２
−エチルヘキサネート３．９（３）ポーラワックス
１（４）ベヘニン酸
０．１（５）トリクロロフルオロメタン
９０製法
（１）〜（４）を７０〜８０℃で加熱撹拌溶解後、エア
ゾール缶に充填後、バルブをクリンプし、（５）を充填
した。Example 3 Wipe-off type cleansing cosmetic (1) Liquid paraffin 5 (2) Cetyl-2
-Ethylhexanate 3.9 (3) Polar wax
1(4) Behenic acid
0.1(5) Trichlorofluoromethane
90 Manufacturing Methods (1) to (4) were heated and stirred to dissolve at 70 to 80° C., and then filled into an aerosol can, the valve was crimped, and (5) was filled.
実施例４ 洗い流しタイプクレンジング化粧料（１）ヒ
マシ油 ７．９８（２）オ
レイル酸オレイル １５（３）フタル酸
ジエチル １５（４）酢酸トコフェロ
ール ０．０１（５）香料
０．１（６）マイクロクリスタリ
ンワックス １０（７）ポリオキシエチレン（゛２
０モル付加）硬化ヒマシ油モノイソステアレート１０（
８）精製水 ７（９） Ｌ
Ｐ Ｇ ３５製法
（１）〜（７）を７０〜８０℃で加熱撹拌溶解後、（８
）を添加し撹拌溶解してエアゾール缶に充填後、バルブ
をクリンプし、（９）を充填した。Example 4 Rinse-off type cleansing cosmetic (1) Castor oil 7.98 (2) Oleyl oleate 15 (3) Diethyl phthalate 15 (4) Tocopherol acetate 0.01 (5) Fragrance
0.1 (6) Microcrystalline wax 10 (7) Polyoxyethylene (゛2
0 mol addition) hydrogenated castor oil monoisostearate 10 (
8) Purified water 7 (9) L
After dissolving PG 35 manufacturing methods (1) to (7) with stirring at 70 to 80°C, (8
) was added, dissolved with stirring, and filled into an aerosol can, the valve was crimped, and (9) was filled.
実施例２〜４のクレンジング化粧料は、洗浄力、使用性
、安定性に優れていた。The cleansing cosmetics of Examples 2 to 4 were excellent in detergency, usability, and stability.
実施例５ ベビーオイル
（１）スクワラン ３４．４９
（２）オレイルアルコール ２０（３）
メチルポリシロキサン ５（４）グリチ
ルレチン酸ステアリル ０．０１（５）ピースワ
ックス ０．５（６）バルミチン
酸 １０（７）トリクロロフルオ
ロメタン ２０（８）ジメチルエーテル
１０製法
（１）〜（６）を７０〜８０℃で加熱撹拌溶解後、エア
ゾール缶に充填後、バルブをクリンプし、（７）（８）
を充填した。Example 5 Baby oil (1) Squalane 34.49
(2) Oleyl alcohol 20(3)
Methylpolysiloxane 5(4) Stearyl glycyrrhetinate 0.01(5) Peace wax 0.5(6) Valmitic acid 10(7) Trichlorofluoromethane 20(8) Dimethyl ether
10 Production methods (1) to (6) are heated and stirred to dissolve at 70 to 80°C, then filled into an aerosol can, the valve is crimped, and (7) (8)
filled with.
実施例６ ヘアーオイル
（１）ツバキ油 １９．４９
（２）ラウリン酸ヘキシル ２０（３）
酢酸トコフェロール ０．０１（４）香
料 ０．５（５）セタ
ノール ２０．０（６）トリク
ロロフルオロエタン ３９．９（７）窒素ガス
０．１製法
（１）〜（５）を７０〜８０℃で加熱撹拌溶解後、エア
ゾール缶に充填後、バルブをクリンプし、（６）（７）
を充填した。Example 6 Hair oil (1) Camellia oil 19.49
(2) Hexyl laurate 20(3)
Tocopherol acetate 0.01 (4) Fragrance 0.5 (5) Cetanol 20.0 (6) Trichlorofluoroethane 39.9 (7) Nitrogen gas 0.1 Manufacturing methods (1) to (5) at 70 to 80°C After dissolving with heating and stirring, fill the aerosol can and crimp the valve, (6) (7)
filled with.
実施例５及び６け、安定性、使用性に優れていた。Examples 5 and 6 were excellent in stability and usability.
Claims (1)
とを特徴とする非乳化型泡沫エアゾール組成物。(1) A non-emulsifying foam aerosol composition characterized by containing a liquid oil, a solid oil, and a propellant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18405389A JPH0350289A (en) | 1989-07-17 | 1989-07-17 | Non-emulsion type foam aerosol composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18405389A JPH0350289A (en) | 1989-07-17 | 1989-07-17 | Non-emulsion type foam aerosol composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0350289A true JPH0350289A (en) | 1991-03-04 |
Family
ID=16146553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18405389A Pending JPH0350289A (en) | 1989-07-17 | 1989-07-17 | Non-emulsion type foam aerosol composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0350289A (en) |
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