JPH03351B2 - - Google Patents

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Publication number
JPH03351B2
JPH03351B2 JP14184985A JP14184985A JPH03351B2 JP H03351 B2 JPH03351 B2 JP H03351B2 JP 14184985 A JP14184985 A JP 14184985A JP 14184985 A JP14184985 A JP 14184985A JP H03351 B2 JPH03351 B2 JP H03351B2
Authority
JP
Japan
Prior art keywords
glaze
transfer paper
layer
melt viscosity
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP14184985A
Other languages
Japanese (ja)
Other versions
JPS623043A (en
Inventor
Masahiro Takeuchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inax Corp
Original Assignee
Inax Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inax Corp filed Critical Inax Corp
Priority to JP14184985A priority Critical patent/JPS623043A/en
Publication of JPS623043A publication Critical patent/JPS623043A/en
Publication of JPH03351B2 publication Critical patent/JPH03351B2/ja
Granted legal-status Critical Current

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  • Glass Compositions (AREA)
  • Decoration By Transfer Pictures (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

[産業上の利用分野] 本発明はタイルの装飾方法に係り、特にタイル
の施釉面に転写紙を用いて絵具を転写する工程を
有するタイルの装飾方法に関する。 [従来の技術] 陶磁器タイルは、主として外装、内装及び床用
のタイルに分けられているが、これらのうち特に
内装用タイルは表面に釉薬がかけられた施釉タイ
ルが殆んどであり、その外観はタイルの性能評価
の重要な項目となつている。 しかして、タイルの装飾性をより高めるため
に、施釉面にプリント模様等の化粧を施したデザ
インタイルが広く用いられるようになつてきてい
る。 施釉タイルの表面に模様を付す方法として従来
より転写紙を用いる方法が行われている。 この方法は、第2図a〜cに示す如く、タイル
素地11の釉層12の上にイングレース転写紙1
3を載せて焼付けるものであるが、この場合、焼
付けにより転写紙13の絵具14の一部が釉層1
2の釉薬と反応し、釉層12の中へ浸透し、釉層
12の表面は平坦面となる。 このようなことは、タイル素地11に二層釉を
設けたタイルにおいても同様である。即ち、第3
図a〜cに示す如く、タイル素地11に下釉(エ
ンゴーベ)層12a及び上釉(透明釉)層12b
が設けられている場合、上釉層12bの上にイン
グレーズ転写紙13を載せて焼付けると、転写紙
13の絵具14の一部は上釉層12bの釉薬と反
応し、上釉層12bの中へ浸透して上釉層12b
の表面は平坦面となる。 [発明が解決しようとする問題点] このような従来法による転写面は、転写された
絵具が釉中に浸透し、施釉表面が平坦面になる。
そのため、転写された模様は単なる平面模様とな
り、奥行き感が不足し、深み等の趣きに欠けたも
のとなり易い。 なお、このように、転写紙絵具が施釉表面と同
一面となるのは、施釉層の釉薬が、転写紙絵具よ
りも高い溶融粘性を有し、反応性が低いためであ
る。即ち、釉薬が転写紙絵具と反応し、施釉層内
に浸透し得ても、転写紙絵具が施釉表面よりも更
に深く陥没するほどには反応しない。 第3図a〜cに示すような二層釉を設けた場合
においても、一般に下釉(エンゴーベ)層は溶融
粘性の高い薄い層であり、上釉(透明釉)層は溶
融粘性のやや低い、厚い層である。そのため、上
釉層の上に転写紙絵具を転写しても、やはり上釉
層の釉薬の溶融粘性が転写紙絵具の溶融粘性より
高く、転写紙絵具が下釉層表面よりも深く陥没す
ることはない。 なお、これに対し、転写紙絵具の反応性を高め
れば、転写紙絵具との反応により施釉表面を陥没
させ得るが、転写紙絵具の反応性を高めると、転
写紙絵具は施釉層の釉薬と反応して施釉層に広く
拡散してしまう。このため、施釉表面に転写され
たデザインの輪郭がぼけて美麗な化粧面を得るこ
とができず。タイルとしての商品価値が大幅に低
化する。このように、転写紙絵具の反応性を高め
ることにも限界があつた。 [問題点を解決するための手段] 本発明は施釉タイルの施釉面に転写紙絵具を転
写して焼付けることによりタイルの装飾を行う方
法において、施釉層を下釉層と上釉層との二層釉
とし、かつ上釉の溶融粘性A、転写紙絵具の溶融
粘性B及び下釉の溶融粘性Cの間に A>B>C なる関係が成立する上釉、転写紙絵具及び下釉を
用いるものである。 以下に本発明を図面を参照して詳細に説明す
る。 第1図a〜cは本発明のタイルの装飾方法を説
明する断面図である。 本発明の方法においては、タイル素地1にエン
ゴーベ等の下釉層2及び透明釉等の上釉層3を形
成し、その上に転写紙4の絵具5を転写して焼付
ける。、この際に、上釉の溶融粘性A、転写紙絵
具の溶融粘性B及び下釉の溶融粘性Cとの間に A>B>C なる関係が成立するようにする。 具体的には、各々の熔融温度が、上釉:1000〜
1250℃、転写紙絵具:1000〜1200℃、下釉:980
〜1180℃範囲となるように調合された釉及び絵具
が用いるのが好ましい。 転写紙絵具は、通常、融剤(フラツクス)に金
属化合物等の顔料を配合したものであるが、この
融剤の製成を種々変更することにより、転写紙絵
具の溶融粘性を調整するこができる。 上釉薬、転写紙絵具、下釉薬の好ましい組合せ
例は下記の如くである。 組合せ例 1 (組成例等をご記入下さい。) 上釉薬 組成:K2O−CaO−Al2O3−B2O3−SiO2 熔融温度:1100℃ 転写紙絵具 組成:K2O−CaO−Al2O3−B2O3−SiO2 熔融温度:1080℃ 下釉薬 組成:(K、Na)2OZnO−CaO−Li2O−Al2O3
2O3−SiO2 熔融温度:1020℃ 組合せ例 2 上釉薬 組成:K2O−CaO−Al2O3−SiO2−ZnO 熔融温度:1150℃ 転写紙絵具 組成:K2O−CaO−Al2O3−SiO2−ZnO−B2O3 熔融温度:1100℃ 下釉薬 組成:K2O−CaO−Al2O3−SiO2−ZnO−Li2O 熔融温度1050℃ なお、上記の組合せ例は、一例であつて、本発
明がこれらに限定されるものではない。 また、本発明においては、上釉層3の厚さは薄
くする必要があり、一般に転写紙絵具5の層厚さ
と同程度、即ち、0.05〜0.5mm、とりわけ0.07〜
0.2mmとするが好適である。一方、下釉層の厚さ
は上釉層よりも厚く、0.2〜1.5mm程度とすのが好
ましい。 本発明の方法によりタイルの装飾を行うには、
まず、第1図aの如く、タイル素地1に常法に従
つて下釉及び上釉を施す。そして、1000〜1200℃
で本焼きする。 次いで第1図bの如く、上釉層3の表面に転写
紙4を載せ、転写紙絵具5を転写した後、1050〜
1150℃の温度で0.5〜2時間焼付ける。焼成は、
約300〜400℃で約2〜6時間、次いで約2〜6時
間で約700〜900℃に昇温し、焼付けるのが一般的
であるが、これらに限定されるものではない。 焼成により、転写紙絵具はタイル表面に焼付け
られる(第1図cの5a)。この際、上釉の溶融
粘性が高いことから上釉と転写紙絵具の反応性は
低いが、上釉層3が薄いため、転写紙絵具は上釉
層3を貫通し、下釉と接触して反応することとな
る。しかして、下釉は溶融粘性が低く反応性が高
いため、転写紙絵具と下釉との反応は急速に進行
し、凹部6を形成する。 なお、上釉の反応性が低いことから、転写紙絵
具が上釉層3に拡散して模様の輪郭がぼけること
はなく、しかも下釉の反応性が高いことから、凹
部6が迅速に形成され、鋭角的で輪郭の明瞭なく
つきりとした凹部6が形成される。 このような本発明のタイルの装飾方法において
は、上釉、下釉、転写紙絵具の溶融粘性、層厚さ
を適宜変更することにより、多種多様な深さない
し形状の凹部を形成することが可能である。 例えば、上釉の溶融粘性をより高く、下釉の溶
融粘性をより低しすると共に上釉層の厚さを薄く
することにより、凹部は極めてくつくりした鋭角
的な輪郭のものとすることができる。逆に、上釉
の溶融粘性を下げ、下釉の溶融粘性を上げて、上
釉層の厚さを若干厚くすることにより、凹部の輪
郭はなだらかなものとなる。 [作用] 一般に溶融粘性の高い釉あるいは絵具は、熔融
温度が高く、反応性は低いものとなる。 本発明の如く、上釉の溶融粘性A、転写紙絵具
の溶融粘性B及び下釉の溶融粘性Cの間に A>B>C なる関係が成立するようにすることにより、各々
の反応性は 上釉<転写紙<下釉 となる。 このため、上釉層に転写紙絵具が焼付けられた
場合、上釉と転写紙絵具との反応性は低いもの
の、上釉層が薄いため、転写紙絵具は上釉層を貫
通し、下釉と接触して反応することとなる。しか
して、下釉は反応性が高いため、転写紙絵具と下
釉との反応は急速に進行し、凹部を形成する。こ
の際、上釉の反応性が低いことから、転写紙絵具
が上釉層に拡散して模様の輪郭がぼけることはな
く、しかも下釉の反応性が高いことから、凹部が
迅速に形成され、鋭角的でくつきりとした凹部が
得られる。 [実施例] 以下実施例について説明する。 実施例 1 (適当する数値等をご記入下さい。) 第1図a〜cに示す本発明方法によりタイルの
装飾を行つた。 上釉、下釉、転写紙絵具の組成、熔融温度及び
層厚は第1表に示す通りである。 転写紙としてはイングレーズ転写紙を用い、こ
れを製品釉面上に載せ1100℃で時間焼付けた。 その結果、転写紙絵具の転写印刷と同時に模様
部分及びその輪郭部分に、深さ約0.25mmのくつき
りとした鋭角的な凹部が形成され、深みのある極
めて装飾性の高いタイルが得られた。
[Industrial Field of Application] The present invention relates to a tile decoration method, and more particularly to a tile decoration method that includes a step of transferring paint to the glazed surface of the tile using a transfer paper. [Prior Art] Ceramic tiles are mainly divided into exterior, interior and floor tiles, and among these, interior tiles in particular are mostly glazed tiles with a glaze applied to the surface. Appearance has become an important item in evaluating the performance of tiles. Therefore, in order to further enhance the decorativeness of tiles, design tiles with decorative features such as printed patterns on the glazed surface are becoming widely used. A conventional method for applying patterns to the surface of glazed tiles is to use transfer paper. In this method, as shown in FIGS. 2a to 2c, a sheet of Inglace transfer paper is placed on the glaze layer 12 of the tile base 11.
However, in this case, a part of the paint 14 on the transfer paper 13 is transferred to the glaze layer 1 by baking.
It reacts with the glaze No. 2, penetrates into the glaze layer 12, and the surface of the glaze layer 12 becomes flat. This also applies to tiles in which a two-layer glaze is provided on the tile base 11. That is, the third
As shown in Figures a to c, the tile base 11 has a lower glaze (engobed) layer 12a and an upper glaze (transparent glaze) layer 12b.
is provided, when the inglaze transfer paper 13 is placed on the upper glaze layer 12b and baked, a part of the paint 14 on the transfer paper 13 reacts with the glaze of the upper glaze layer 12b, and the upper glaze layer 12b Penetrates into the upper glaze layer 12b
The surface of is a flat surface. [Problems to be Solved by the Invention] In the transfer surface obtained by such a conventional method, the transferred paint penetrates into the glaze, and the glazed surface becomes a flat surface.
Therefore, the transferred pattern becomes a mere flat pattern, which lacks a sense of depth and tends to lack interest such as depth. The reason why the transfer paper paint is flush with the glazed surface is that the glaze in the glaze layer has higher melt viscosity and lower reactivity than the transfer paper paint. That is, even though the glaze may react with the transfer paper paint and penetrate into the glazed layer, it does not react to the extent that the transfer paper paint sinks deeper than the glazed surface. Even when a two-layer glaze as shown in Figure 3 a to c is provided, the lower glaze (engove) layer is generally a thin layer with high melt viscosity, and the upper glaze (transparent glaze) layer has a slightly lower melt viscosity. , is a thick layer. Therefore, even if transfer paper paint is transferred onto the upper glaze layer, the melt viscosity of the glaze in the upper glaze layer is still higher than the melt viscosity of the transfer paper paint, and the transfer paper paint may sink deeper than the surface of the lower glaze layer. There isn't. On the other hand, if the reactivity of the transfer paper paint is increased, the glazed surface may sink due to the reaction with the transfer paper paint, but if the reactivity of the transfer paper paint is increased, the transfer paper paint will react with the glaze of the glazed layer. It reacts and diffuses widely into the glazed layer. As a result, the outline of the design transferred to the glazed surface becomes blurred, making it impossible to obtain a beautiful decorative surface. The product value of tiles will be significantly reduced. In this way, there are limits to increasing the reactivity of transfer paper paints. [Means for Solving the Problems] The present invention provides a method for decorating tiles by transferring and baking transfer paper paint onto the glazed surface of a glazed tile, in which the glazed layer is divided into a lower glaze layer and an upper glazed layer. The top glaze, transfer paper paint, and bottom glaze are made into a two-layer glaze, and the relationship A>B>C is established between the melt viscosity A of the top glaze, the melt viscosity B of the transfer paper paint, and the melt viscosity C of the bottom glaze. It is used. The present invention will be explained in detail below with reference to the drawings. FIGS. 1a to 1c are cross-sectional views illustrating the tile decoration method of the present invention. In the method of the present invention, a lower glaze layer 2 such as an engraving and an upper glaze layer 3 such as a transparent glaze are formed on a tile base 1, and the paint 5 of the transfer paper 4 is transferred and baked thereon. At this time, the relationship A>B>C is established between the melt viscosity A of the upper glaze, the melt viscosity B of the transfer paper paint, and the melt viscosity C of the lower glaze. Specifically, each melting temperature is as follows: Top glaze: 1000~
1250℃, transfer paper paint: 1000-1200℃, lower glaze: 980
It is preferable to use glazes and paints that are formulated to have a temperature in the range of ~1180°C. Transfer paper paints are usually made by blending a pigment such as a metal compound with a flux, but it is possible to adjust the melt viscosity of the transfer paper paint by making various changes to the formulation of this flux. can. Preferred combinations of top glaze, transfer paper paint, and bottom glaze are as follows. Combination example 1 (Please enter composition examples, etc.) Top glaze composition: K 2 O−CaO−Al 2 O 3 −B 2 O 3 −SiO 2 Melting temperature: 1100℃ Transfer paper paint composition: K 2 O−CaO −Al 2 O 3 −B 2 O 3 −SiO 2 Melting temperature: 1080℃ Lower glaze composition: (K, Na) 2 OZnO−CaO−Li 2 O−Al 2 O 3
2 O 3 −SiO 2 Melting temperature: 1020℃ Combination example 2 Top glaze Composition: K 2 O−CaO−Al 2 O 3 −SiO 2 −ZnO Melting temperature: 1150℃ Transfer paper paint Composition: K 2 O−CaO− Al 2 O 3 −SiO 2 −ZnO−B 2 O 3 Melting temperature: 1100℃ Lower glaze composition: K 2 O−CaO−Al 2 O 3 −SiO 2 −ZnO−Li 2 O Melting temperature 1050℃ The combination examples are merely examples, and the present invention is not limited thereto. Further, in the present invention, the thickness of the upper glaze layer 3 needs to be thin, and is generally the same as the layer thickness of the transfer paper paint 5, that is, 0.05 to 0.5 mm, particularly 0.07 to 0.5 mm.
A suitable value is 0.2 mm. On the other hand, the thickness of the lower glaze layer is thicker than the upper glaze layer, and is preferably about 0.2 to 1.5 mm. To decorate tiles according to the method of the invention,
First, as shown in FIG. 1a, a lower glaze and an upper glaze are applied to a tile base 1 according to a conventional method. And 1000~1200℃
I'm going to bake the book. Next, as shown in FIG. 1b, a transfer paper 4 is placed on the surface of the upper glaze layer 3, and after transferring the transfer paper paint 5,
Bake at a temperature of 1150℃ for 0.5 to 2 hours. The firing is
It is common to bake at about 300 to 400°C for about 2 to 6 hours, then to about 700 to 900°C for about 2 to 6 hours, but the method is not limited thereto. By firing, the transfer paper paint is baked onto the tile surface (5a in Figure 1c). At this time, the reactivity between the top glaze and transfer paper paint is low due to the high melt viscosity of the top glaze, but since the top glaze layer 3 is thin, the transfer paper paint penetrates through the top glaze layer 3 and comes into contact with the bottom glaze. This will cause a reaction. Since the lower glaze has low melt viscosity and high reactivity, the reaction between the transfer paper paint and the lower glaze progresses rapidly, forming the recesses 6. Furthermore, since the reactivity of the upper glaze is low, the transfer paper paint will not diffuse into the upper glaze layer 3 and the outline of the pattern will become blurred, and since the reactivity of the lower glaze is high, the recesses 6 will be formed quickly. As a result, a sharp recess 6 with an acute angle and a clear outline is formed. In the tile decoration method of the present invention, recesses of various depths and shapes can be formed by appropriately changing the melt viscosity and layer thickness of the upper glaze, lower glaze, and transfer paper paint. It is possible. For example, by increasing the melt viscosity of the upper glaze and lowering the melt viscosity of the lower glaze, and by reducing the thickness of the upper glaze layer, the recess can be made to have an extremely sharp contour. can. Conversely, by lowering the melt viscosity of the upper glaze, increasing the melt viscosity of the lower glaze, and slightly increasing the thickness of the upper glaze layer, the contour of the recess becomes gentle. [Function] Generally, glazes or paints with high melt viscosity have a high melting temperature and low reactivity. As in the present invention, by establishing the relationship A>B>C between the melt viscosity A of the top glaze, the melt viscosity B of the transfer paper paint, and the melt viscosity C of the bottom glaze, the reactivity of each Top glaze < transfer paper < bottom glaze. For this reason, when transfer paper paint is baked onto the upper glaze layer, although the reactivity between the upper glaze and the transfer paper paint is low, because the upper glaze layer is thin, the transfer paper paint penetrates through the upper glaze layer and transfers to the lower glaze. It will react when it comes into contact with. Since the lower glaze is highly reactive, the reaction between the transfer paper paint and the lower glaze progresses rapidly, forming recesses. At this time, since the reactivity of the upper glaze is low, the transfer paper paint will not diffuse into the upper glaze layer and blur the outline of the pattern, and the reactivity of the lower glaze is high, so the recesses will be formed quickly. , a sharp and tight recess is obtained. [Example] Examples will be described below. Example 1 (Please enter appropriate values, etc.) Tiles were decorated by the method of the present invention shown in FIGS. 1a to 1c. The compositions, melting temperatures, and layer thicknesses of the top glaze, bottom glaze, and transfer paper paint are as shown in Table 1. Inglaze transfer paper was used as the transfer paper, and this was placed on the glazed surface of the product and baked at 1100°C for an hour. As a result, sharp, sharp recesses with a depth of approximately 0.25 mm were formed in the pattern and its outline at the same time as the transfer paper paint was transferred, resulting in a deep and highly decorative tile. .

【表】 [効果] 以上詳述した通り、本発明のタイルの装飾方法
によれば、転写紙の絵具部分に凹部を形成するこ
とができる。而して、形成される凹部は、鋭角的
でくつきりとしたものであり、しかも転写紙絵具
の溶融粘性及び上釉薬、下釉薬の溶融粘性又は、
上釉層、下釉層の厚さを適宜選択することによ
り、その陥没に程度を任意に変化させることが可
能である。 このため、本発明のタイルの装飾方法によれ
ば、従来にない凹凸模様を有する極めて装飾性の
高いデザインタイルを容易に得ることができる。
[Table] [Effects] As detailed above, according to the tile decoration method of the present invention, recesses can be formed in the paint portion of the transfer paper. Therefore, the recesses formed are sharp and solid, and the melt viscosity of the transfer paper paint and the melt viscosity of the top glaze and bottom glaze, or
By appropriately selecting the thicknesses of the upper glaze layer and the lower glaze layer, it is possible to arbitrarily change the degree of depression. Therefore, according to the tile decoration method of the present invention, it is possible to easily obtain highly decorative designed tiles having an unprecedented uneven pattern.

【図面の簡単な説明】[Brief explanation of drawings]

第1図a〜cは本発明のタイルの装飾方法を説
明する断面図、第2図a〜c及び第3図a〜c
は、各々、従来のタイルの装飾方法を説明する断
面図である。 1……タイル素地、2……下釉層、3……上釉
層、4……転写紙、5……転写紙絵具、6……凹
部。
Figures 1 a to c are sectional views explaining the tile decoration method of the present invention, Figures 2 a to c, and Figures 3 a to c.
1 and 2 are cross-sectional views illustrating a conventional tile decoration method. 1...Tile base, 2...Lower glaze layer, 3...Upper glaze layer, 4...Transfer paper, 5...Transfer paper paint, 6...Recessed portion.

Claims (1)

【特許請求の範囲】 1 施釉タイルの施釉面に転写紙絵具を転写して
焼付けることによりタイルの装飾を行う方法にお
いて、施釉層を下釉層と上釉層との二層釉とし、
かつ上釉の溶融粘性A、転写紙絵具の溶融粘性B
及び下釉の溶融粘性Cの間に A>B>C なる関係が成立する上釉、転写紙絵具及び下釉を
用いることを特徴とするタイルの装飾方法。 2 上釉の層厚が0.05〜0.5mmであり、下釉の層
厚が0.2〜1.5mmであることを特徴とする特許請求
の範囲第1項に記載のタイルの装飾方法。
[Claims] 1. A method for decorating tiles by transferring and baking transfer paper paint onto the glazed surface of a glazed tile, wherein the glazed layer is a two-layer glaze consisting of a lower glaze layer and an upper glaze layer,
And melt viscosity A of the top glaze, melt viscosity B of the transfer paper paint
A tile decoration method characterized by using an upper glaze, a transfer paper paint, and a lower glaze in which the relationship A>B>C holds between the melt viscosity C of the lower glaze and the melt viscosity C of the lower glaze. 2. The tile decoration method according to claim 1, wherein the layer thickness of the upper glaze is 0.05 to 0.5 mm, and the layer thickness of the lower glaze is 0.2 to 1.5 mm.
JP14184985A 1985-06-28 1985-06-28 Decoration of tile Granted JPS623043A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14184985A JPS623043A (en) 1985-06-28 1985-06-28 Decoration of tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14184985A JPS623043A (en) 1985-06-28 1985-06-28 Decoration of tile

Publications (2)

Publication Number Publication Date
JPS623043A JPS623043A (en) 1987-01-09
JPH03351B2 true JPH03351B2 (en) 1991-01-07

Family

ID=15301591

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14184985A Granted JPS623043A (en) 1985-06-28 1985-06-28 Decoration of tile

Country Status (1)

Country Link
JP (1) JPS623043A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0218100A (en) * 1988-07-07 1990-01-22 Inax Corp Surface additive decoration of sanitation toilet fixture
JPH0647512B2 (en) * 1990-04-10 1994-06-22 東陶機器株式会社 Method for forming surface pattern of ceramic products
SE536897C2 (en) * 2010-09-28 2014-10-21 Ifö Sanitär AB A method of glazing a ceramic body

Also Published As

Publication number Publication date
JPS623043A (en) 1987-01-09

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