JPS6298B2 - - Google Patents
Info
- Publication number
- JPS6298B2 JPS6298B2 JP8326979A JP8326979A JPS6298B2 JP S6298 B2 JPS6298 B2 JP S6298B2 JP 8326979 A JP8326979 A JP 8326979A JP 8326979 A JP8326979 A JP 8326979A JP S6298 B2 JPS6298 B2 JP S6298B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- frit
- firing
- heat
- pigments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000010304 firing Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- 239000001023 inorganic pigment Substances 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 239000010410 layer Substances 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000010422 painting Methods 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 6
- 239000005357 flat glass Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- -1 B 2 O 3 Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Description
【発明の詳細な説明】
本発明は耐熱性基材表面の絵付能の改良方法に
関するものである。更に詳しくは、耐熱性基材表
面加工に用いるフリツト成分を改良することによ
つて、基材表面が無機顔料のみでなく有機顔料に
よつても、容易に絵付することができるようにし
て、従来不良であつた耐熱性基材表面の絵付能を
改良することを目的とするものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for improving the painting ability of a heat-resistant substrate surface. More specifically, by improving the frit component used in the surface treatment of heat-resistant substrates, the surface of the substrate can be easily decorated with not only inorganic pigments but also organic pigments, making it possible to easily decorate the surface of the substrate with not only inorganic pigments but also organic pigments. The purpose is to improve the painting ability of the surface of a heat-resistant base material, which has been poor.
従来、例えばガラス、ホーロー、タイル等の耐
熱性基材表面に絵付しようとする場合は、無機顔
料を用いて図柄を形成し、その上にPbO，K2O，
Na2O，CaO，Al2O3，B2O3，SiO2，MgO，ZnO
等を成分とするフリツトを塗布し焼成するか、又
は無機顔料と前記フリツトとの混合物を塗布し焼
成する方法がとられていた。しかしこれらの方法
によつて形成された基材表面は機械的強度には優
れているものの、フリツト中の無機顔料を固定化
するためにフリツトを完全に溶融状態にする必要
があつた。そのため、焼成後フリツトは不活性な
層になり、基材表面に絵付することはできなかつ
た。また通常450℃〜1000℃の焼成温度を必要と
し、そのため図柄が変退色するおそれがあつた。
よつて焼成温度で変退色しない無機顔料を選択使
用しなければならず、その結果、使用可能な着色
材の色相、彩度、明度が限定されることになり、
陶磁器、ホーロー等の絵付に関してデザイナーの
要求に十分答えることができなかつた。 Conventionally, when painting the surface of a heat-resistant substrate such as glass, enamel, or tile, a pattern is formed using an inorganic pigment, and then PbO, K 2 O,
Na 2 O, CaO, Al 2 O 3 , B 2 O 3 , SiO 2 , MgO, ZnO
A method has been used in which a frit containing such as the above-mentioned frit is coated and fired, or a mixture of an inorganic pigment and the frit is coated and fired. However, although the substrate surface formed by these methods has excellent mechanical strength, it is necessary to completely melt the frit in order to fix the inorganic pigment in the frit. Therefore, after firing, the frit becomes an inactive layer and cannot be painted on the surface of the base material. Furthermore, firing temperatures of 450°C to 1000°C are usually required, which may cause the design to discolor and fade.
Therefore, it is necessary to select and use inorganic pigments that do not discolor or fade at firing temperatures, and as a result, the hue, saturation, and brightness of usable colorants are limited.
It was not possible to fully meet the demands of designers regarding the painting of ceramics, enamel, etc.
本発明者はこのような従来法の欠点に鑑み種々
考察した結果、焼成によつても溶融状態にならな
いフリツトを使用すれば前記欠点を解決しうると
の点に着目し、フリツトについて研究を進めたと
ころ焼成によつて染顔料の吸着性を呈するアルミ
ナゾル又はシリカゾルを用いれば、良好な結果が
得られるとの結論に達し、本発明を完成するに至
つたものである。 As a result of various considerations in view of the shortcomings of the conventional method, the inventors of the present invention focused on the point that the above-mentioned shortcomings could be solved by using a frit that does not become molten even when fired, and proceeded with research on frits. The inventors came to the conclusion that good results could be obtained by using alumina sol or silica sol, which exhibits the ability to adsorb dyes and pigments upon firing, leading to the completion of the present invention.
即ち本発明は、耐熱性基材に、焼成により染顔
料の吸着性を呈するアルミナゾル又はシリカゾル
の、少くとも一種を主成分とするフリツトに無機
顔料を混合したものを塗布し、焼成することを特
徴とする耐熱性基材表面の絵付能の改良方法であ
る。 That is, the present invention is characterized by coating a heat-resistant base material with a mixture of an inorganic pigment and a frit containing at least one type of alumina sol or silica sol, which exhibits adsorption properties for dyes and pigments when fired, and then firing. This is a method for improving the painting ability of the surface of a heat-resistant substrate.
次に本発明について更に詳しく説明する。 Next, the present invention will be explained in more detail.
本発明において対象とする耐熱性基材とはガラ
ス、ホーロー、タイル、陶磁器、ステンレス、鍛
銅等である。 The heat-resistant base materials targeted in the present invention include glass, enamel, tiles, ceramics, stainless steel, and wrought copper.
本発明において基材に塗布するフリツトとして
は、焼成により染顔料の吸着性を呈するアルミナ
ゾル又はシリカゾルの少くとも一種以上を主成分
とするものを使用する。ここで主成分とは少くと
も30％以上の組成であることを意味する。これ以
下の組成のときは絵付時の染顔料の吸着能が劣る
からである。また前記アルミナゾル又はシリカゾ
ルは従来用いられているフリツト成分に混合して
用いてもよい。さらにフリツトには顔料を混合す
る。顔料は焼成温度で変退色しない無機顔料を選
ばなければならない。顔料を混合したフリツトを
塗布、焼成すると、有彩色又は無彩色の隠蔽性の
強い層が形成され、該層に図柄を形成した際に、
着色インキの発色が非常によくなるという特徴が
ある。 In the present invention, the frit applied to the substrate is one whose main component is at least one type of alumina sol or silica sol, which exhibits dye and pigment adsorption properties upon firing. Here, the term "main component" means a composition of at least 30% or more. This is because if the composition is less than this, the ability to adsorb dyes and pigments during painting will be poor. Further, the alumina sol or silica sol may be mixed with a conventionally used frit component. Furthermore, a pigment is mixed into the frit. The pigment must be an inorganic pigment that does not discolor or fade at the firing temperature. When frit mixed with pigment is applied and fired, a chromatic or achromatic layer with strong hiding properties is formed, and when a pattern is formed on this layer,
It has the characteristic that the color development of colored ink is very good.
フリツトの塗布層を厚くしようとする場合はフ
リツトにバインダーを混合するのが好ましい。バ
インダーとしては焼成温度以下で燃焼揮散する、
例えばポリビニルアルコール、ヒドロキシプロピ
ルセルロース等の結合剤を用いる。 When it is desired to thicken the coating layer of the frit, it is preferable to mix a binder with the frit. As a binder, it burns and volatilizes below the firing temperature.
For example, a binder such as polyvinyl alcohol or hydroxypropylcellulose is used.
フリツトの塗布はスプレー方式、フローコート
方法、浸漬方法等による。塗布後表面平滑性を保
持するために、フリツト中の水分を乾燥により蒸
発させるのが望ましい。 The frit is applied by a spray method, a flow coating method, a dipping method, etc. In order to maintain surface smoothness after coating, it is desirable to evaporate water in the frit by drying.
焼成温度はフリツトの主成分により多少異なる
が、使用するアルミナゾル又はシリカゾルが焼成
によつて吸着性を呈する温度範囲で焼成しなけれ
ばならない。それはアルミナゾルが主成分である
場合は450℃〜1000℃の範囲、シリカゾルが主成
分である場合は250℃〜1000℃の範囲である。焼
成時間はフリツトの塗布量、基材の熱伝導率等に
より多少異なるが、10分間〜300分間の範囲で焼
成される。 Although the firing temperature varies somewhat depending on the main components of the frit, the firing must be carried out within a temperature range at which the alumina sol or silica sol used exhibits adsorption properties upon firing. It ranges from 450°C to 1000°C when alumina sol is the main component, and from 250°C to 1000°C when silica sol is the main component. The firing time varies depending on the amount of frit coated, the thermal conductivity of the base material, etc., but the firing time ranges from 10 minutes to 300 minutes.
以上のようにして処理されたフリツトは焼成中
溶融せずに、多孔質のアルミナ層、シリカ層また
はそれらの混合物層を形成する。これらの層は活
性であるから染顔料を吸着することができる。従
つて本発明の適用によつて表面処理した耐熱性基
材表面に通常の絵付方法、例えば直接印刷、転写
印刷方法等によつて図柄を形成し、加熱すれば図
柄中のインキは前記アルミナ層、シリカ層に吸着
され絵付を容易に行うことができる。故に本発明
では限定された無機顔料のみでなく、有機染顔料
を用いても絵付することができ、しかも隠蔽性の
強い、発色の優れた図柄を形成できるから、耐熱
性基材表面に多彩な模様を形成することができ
る。 The frit treated as described above does not melt during firing and forms a porous alumina layer, silica layer, or a porous layer of a mixture thereof. Since these layers are active, they can adsorb dyes and pigments. Therefore, by applying the present invention, a pattern is formed on the surface of a heat-resistant base material that has been surface-treated by a normal painting method, such as direct printing or transfer printing, and when heated, the ink in the pattern is transferred to the alumina layer. , it is adsorbed to the silica layer and can be easily painted. Therefore, in the present invention, not only limited inorganic pigments but also organic dyes and pigments can be used for decoration, and patterns with strong hiding properties and excellent color development can be formed, so a variety of colors can be applied to the surface of a heat-resistant base material. A pattern can be formed.
以下本発明の実施例を示す。 Examples of the present invention will be shown below.
実施例 １
下記配合の下塗剤をデツプコーテイングによつ
て、透明ガラス化粧ビンに塗布して120℃20分間
乾燥した後、該化粧ビンを500℃１時間焼成する
と白色の化粧ビンが得られた。Example 1 A base coat of the following composition was applied to a transparent glass cosmetic bottle by dip coating, dried at 120°C for 20 minutes, and then baked at 500°C for 1 hour to obtain a white cosmetic bottle. .
アルミナゾル固型分 80部
酸化チタン 13部
酸化錫 ７部
水 900部
計 1000部
次にポリエステル・ポリプロピレンラミネート
フイルムのポリプロピレン上に下記組成(イ)(ロ)(ハ)(
ニ)
のインキにて図柄層を形成し、その上に下記組成
(ホ)の接着剤により接着層を形成した転写材を用い
て、前記白色の化粧ビンにローラー転写機により
200℃，10cm／gsecの条件で加圧して転写した
後、化粧ビンをドライオーブン中で180℃，10分
間の乾燥処理した後、水洗すると美しい図柄を有
した化粧ビンが得られた。Alumina sol solid content 80 parts Titanium oxide 13 parts Tin oxide 7 parts Water 900 parts Total 1000 parts Next, the following composition (a) (b) (c) (
D)
A pattern layer is formed using ink, and the following composition is applied on top of it.
Using the transfer material with an adhesive layer formed with the adhesive in (e), transfer it to the white cosmetic bottle using a roller transfer machine.
After transferring under pressure at 200°C and 10cm/gsec, the cosmetic bottle was dried in a dry oven at 180°C for 10 minutes, and then washed with water to obtain a cosmetic bottle with a beautiful design.
インキ
(イ) ヒドロキシプロピルセルロース
（日本曹達） ８部
カヤセツトフラビンFG
（日本化薬） ８部
メチルエチルケトン 42部
エチルアルコール 42部
(ロ) ヒドロキシプロピルセルロース ８部
ミケトンポリエステルレツドFB
（三井東圧） 10部
メチルエチルケトン 41部
エチルアルコール 41部
(ハ) ヒドロキシプロピルセルロース ８部
カヤセツトブルーA2R（日本化薬） 10部
メチルエチルケトン 41部
エチルアルコール 41部
(ニ) ヒドロキシプロピルセルロース ７部
カヤセツトフラビンFG ３部
ミケトンポリエステルレツドFB ４部
カヤセツトブルーA2R ４部
メチルエチルケトン 41部
エチルアルコール 41部
接着剤
(ホ) ポリビニルピロリドン 20部
グリセリン 0.5部
水 2.5部
メタノール 77部
実施例 ２
下記配合の下塗剤をペイントシエーカーで１時
間練肉分散させた後、７cm×14cmの透明板ガラス
にスプレーコーテイングした。Ink (a) Hydroxypropyl cellulose (Nippon Soda) 8 parts Kayasetoflavin FG (Nippon Kayaku) 8 parts methyl ethyl ketone 42 parts Ethyl alcohol 42 parts (b) Hydroxypropyl cellulose 8 parts Miketone Polyester Red FB (Mitsui Toatsu) 10 parts methyl ethyl ketone 41 parts ethyl alcohol 41 parts (c) Hydroxypropyl cellulose 8 parts Kayaset Blue A2R (Nippon Kayaku) 10 parts methyl ethyl ketone 41 parts ethyl alcohol 41 parts (d) Hydroxypropyl cellulose 7 parts Kayaset Flavin FG 3 parts Mike Polyester Red FB 4 parts Kayaset Blue A2R 4 parts Methyl ethyl ketone 41 parts Ethyl alcohol 41 parts Adhesive (e) Polyvinylpyrrolidone 20 parts Glycerin 0.5 parts Water 2.5 parts Methanol 77 parts Example 2 Paint shader with the following combination of primer After dispersing the minced meat for 1 hour, it was spray coated onto a 7 cm x 14 cm transparent plate glass.
アルミナゾル（10％溶液）固型分 61.7部
シリカゾル （ 〃 ）固型分 10.9部
長石 7.3部
石灰石 5.4部
カオリン 6.4部
ドロマイト 3.3部
酸化コバルト 5.0部
水 900部
計 1000部
次に該板ガラスを550℃，30分間焼成するとブ
ルー色のスリガラス調の板ガラスが得られた。次
に実施例１で使用した(ロ)の赤インキで該板ガラス
を上から下にスプレーコーテイングしてボケ柄を
形成した後、該板ガラスをドライオープン中で
190℃10分間の乾熱処理し冷却後インキ膜層を水
洗剥膜すると、上から下に紫からブルーへと変化
してゆくボケ柄のスリガラス調の板ガラスが得ら
れた。Alumina sol (10% solution) solid content 61.7 parts Silica sol (〃) solid content 10.9 parts feldspar 7.3 parts limestone 5.4 parts Kaolin 6.4 parts Dolomite 3.3 parts Cobalt oxide 5.0 parts Water 900 parts Total 1000 parts Next, the plate glass was heated at 550°C. After firing for 30 minutes, a blue-colored frosted-glass plate glass was obtained. Next, the plate glass was spray-coated from top to bottom with the red ink (b) used in Example 1 to form a blurred pattern, and then the plate glass was placed in a dry open state.
After dry heat treatment at 190°C for 10 minutes and cooling, the ink film layer was removed by washing with water to obtain a ground glass-like plate glass with a blurred pattern that changes from purple to blue from top to bottom.
実施例 ３
下記配合の下塗剤をペイントシエーカーで１時
間練肉分散させた後、７cm×14cmのクロムメツキ
レスの金属板にスプレーコーテイングした。Example 3 A primer having the following composition was dispersed in a paint shaker for 1 hour and then spray coated on a 7 cm x 14 cm chromeless metal plate.
シリカゲル 70部
酸化錫 ５部
カオリン ５部
共立カドミイエローNo.118（共立化学）
５部
ポリビニルアルコール（日本合成） 15部
水 900部
計 1000部
次に該金属板を400℃１時間焼成すると黄色の
金属板が得られた。更に実施例１で使用した(ハ)の
青インキで以下実施例２のように処理すると、表
面に黄→緑→青にいたるボケ柄の金属板が得られ
た。Silica gel 70 parts Tin oxide 5 parts Kaolin 5 parts Kyoritsu Kadomi Yellow No.118 (Kyoritsu Chemical)
5 parts Polyvinyl alcohol (Nippon Gosei) 15 parts Water 900 parts Total 1000 parts Next, the metal plate was fired at 400°C for 1 hour to obtain a yellow metal plate. Further, when the metal plate was treated with the blue ink (c) used in Example 1 as in Example 2, a metal plate with a blurred pattern ranging from yellow to green to blue was obtained on the surface.
比較例
下記配合のガラス用フリツトに透明ガラス化粧
ビンをスプレーコーテイングし550℃40分間焼成
した。Comparative Example A glass frit having the following composition was spray coated with a transparent glass cosmetic bottle and baked at 550°C for 40 minutes.
GF−72（日本フエロー） 60部
酸化チタン 9.5部
CMC（京都合成） 0.5部
水 30部
以下実施例１と同様に処理したが、図柄を形成
することは全くできなかつた。GF-72 (Nippon Fellow) 60 parts Titanium oxide 9.5 parts CMC (Kyoto Seisen) 0.5 parts Water 30 parts The following treatment was carried out in the same manner as in Example 1, but no pattern could be formed.
実施例 ４
実施例１と同じ配合の下塗剤を15cm×15cmの素
焼タイルにスプレーコーテイングし、800℃15分
間焼成し、以下実施例１と同様に処理すると美し
い図柄を有する白色タイルが得られた。Example 4 A 15 cm x 15 cm unglazed tile was spray-coated with a primer having the same composition as in Example 1, baked at 800°C for 15 minutes, and then treated in the same manner as in Example 1 to obtain a white tile with a beautiful pattern. .
Claims (1)
呈するアルミナゾル又はシリカゾルの少くとも一
種を主成分とするフリツトに無機顔料を混合した
ものを塗布し、焼成することを特徴とする耐熱性
基材表面の絵付能の改良方法。1. A heat-resistant group characterized by coating a heat-resistant base material with a mixture of an inorganic pigment and a frit whose main component is at least one type of alumina sol or silica sol that exhibits adsorption properties for dyes and pigments upon firing, and firing the mixture. A method for improving the ability to paint on wood surfaces.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8326979A JPS569248A (en) | 1979-06-30 | 1979-06-30 | Improving method for suitability of heat resistant substrate surface to painting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8326979A JPS569248A (en) | 1979-06-30 | 1979-06-30 | Improving method for suitability of heat resistant substrate surface to painting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS569248A JPS569248A (en) | 1981-01-30 |
| JPS6298B2 true JPS6298B2 (en) | 1987-01-06 |
Family
ID=13797629
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8326979A Granted JPS569248A (en) | 1979-06-30 | 1979-06-30 | Improving method for suitability of heat resistant substrate surface to painting |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS569248A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5845137A (en) * | 1981-09-10 | 1983-03-16 | Okuno Seiyaku Kogyo Kk | Ceramic color composition |
| DE3224349A1 (en) * | 1982-06-30 | 1984-01-05 | Degussa Ag, 6000 Frankfurt | SCREEN PRINT OIL FOR THE PRODUCTION OF FINE COLOR GRIDS AND RELIEF PRINTS ON CERAMIC MATERIALS |
| ES2081736B1 (en) * | 1992-02-26 | 1996-10-01 | Solvi Soluciones Del Vidrio S | MIXED PROCEDURE FOR BOTTLE AND GLASS IN GENERAL. |
| DE102006043535B4 (en) * | 2006-09-12 | 2017-11-09 | Wendel Gmbh | Chemically resistant enamel |
-
1979
- 1979-06-30 JP JP8326979A patent/JPS569248A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS569248A (en) | 1981-01-30 |
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