JPH03273069A - Screen printing paste - Google Patents

Screen printing paste

Info

Publication number
JPH03273069A
JPH03273069A JP2073006A JP7300690A JPH03273069A JP H03273069 A JPH03273069 A JP H03273069A JP 2073006 A JP2073006 A JP 2073006A JP 7300690 A JP7300690 A JP 7300690A JP H03273069 A JPH03273069 A JP H03273069A
Authority
JP
Japan
Prior art keywords
paste
screen printing
printing paste
acid
solid content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2073006A
Other languages
Japanese (ja)
Inventor
Chiharu Hayashi
千春 林
Kazuyuki Okano
和之 岡野
Tatsuo Ogawa
立夫 小川
Yasuto Isozaki
康人 礒崎
Hiroshi Hasegawa
洋 長谷川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2073006A priority Critical patent/JPH03273069A/en
Publication of JPH03273069A publication Critical patent/JPH03273069A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the title paste which gives a smooth dried film with homogeneous composition by incorporating a specified solid material into a paste. CONSTITUTION:A paste containing a solid material which, when heated, will disappear to form a homogeneous composition (e.g. a mixture of ruthenium 2-ethylhexanoate and a salt of abietic acid with NH3).

Description

【発明の詳細な説明】 産業上の利用分野 本発明はスクリーン印刷用ペーストに関するものである
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a screen printing paste.

従来の技術 ロジンに代表されるテルペノイドに属するカルボン酸や
そのエステル類、もしくはその組成物との混合物はワニ
スの形で塗料として使われている。また上記ワニスをビ
ヒクルとして含有した印刷用ペーストは印刷性の良さや
、顔料、溶剤との相溶性の良さなどから、抵抗体形成用
ペーストや各種印刷用ペーストとして工業的に広く利用
されている。
BACKGROUND OF THE INVENTION Carboxylic acids belonging to terpenoids, typified by rosin, their esters, or mixtures thereof with compositions are used as paints in the form of varnishes. Furthermore, printing pastes containing the above-mentioned varnish as a vehicle are widely used industrially as resistor forming pastes and various printing pastes because of their good printability and good compatibility with pigments and solvents.

発明が解決しようとする課題 上記テルペノイドのカルボン酸やそのエステル類、もし
くはその組成物を用いたスクリーン印刷ペーストは、ス
クリーン印刷時にペーストがスクリーン版のメツシュを
通過する際に生じる泡が原因となってムラのない、平滑
な印刷膜面を得ることが非常に困難であるという課題が
あった。
Problems to be Solved by the Invention Screen printing pastes using the above-mentioned terpenoid carboxylic acids, esters thereof, or compositions thereof have a problem that bubbles are generated when the paste passes through the mesh of the screen plate during screen printing. There has been a problem in that it is very difficult to obtain an even and smooth printed film surface.

本発明は以上のような従来の欠点を除去するもので平滑
でかつ均一な組成膜面の得られるスクリーン印刷ペース
トを提供しようとするものである。
The present invention is intended to eliminate the above-mentioned conventional drawbacks and to provide a screen printing paste that provides a smooth and uniform film surface.

課題を解決するための手段 上記課題を解決するために本発明のスクリーン印刷ペー
ストは、加熱によって消失する固形分をスクリーン印刷
用ペーストの主要成分として構成するものである。
Means for Solving the Problems In order to solve the above-mentioned problems, the screen printing paste of the present invention has a solid content that disappears upon heating as a main component of the screen printing paste.

作用 上記構成とすることにより、ペースト中に粉末として存
在する固形物は自身によってペーストの表面張力を下げ
、泡液を破壊し、印刷時のメツシュ通過によっても泡が
発生することなくペーストを被印刷物上に移されるよう
になる。さらに、この固形物は加熱によって消失し、か
つ均一な組成の乾11Mを与える。したがって、本発明
のスクリーン印刷用ペーストを使用することにより非常
に平滑でムラのない乾燥膜が得られることになる。
Effect: By having the above structure, the solid matter present in the form of powder in the paste lowers the surface tension of the paste by itself, destroys the bubble liquid, and allows the paste to be printed without generating bubbles even when it passes through the mesh during printing. It will be moved upwards. Furthermore, this solid substance disappears upon heating and gives a dry 11M of uniform composition. Therefore, by using the screen printing paste of the present invention, a very smooth and even dried film can be obtained.

実施例 以下、本発明の実施例について説明する。Example Examples of the present invention will be described below.

(実施例1) 第1表に示した組成物とアンモニアとを1:1のモル比
で反応した生成物を100g調製し、これらに2−エチ
ルへキサン酸ルテニウムを10g添加し、溶剤としてテ
ルピネオールを30g加えて混練し、スクリーン印刷ペ
ーストを製造した。
(Example 1) 100 g of a product obtained by reacting the composition shown in Table 1 with ammonia at a molar ratio of 1:1 was prepared, 10 g of ruthenium 2-ethylhexanoate was added thereto, and terpineol was used as a solvent. 30g was added and kneaded to produce a screen printing paste.

このスクリーン印刷ペーストを乳剤厚み15μm。This screen printing paste was made into an emulsion with a thickness of 15 μm.

250メツシユのステンレス製スクリーン版を用いてグ
レーズドアルミナ基板上に1−×1−の正方形状パター
ンに印刷を行った。この被印刷物を150℃で10分間
加熱し、評価を行った。評価は印刷膜中の固形分の有無
と印刷時の泡立ちの有無、および乾燥膜面の均一性、平
滑性について行った。
A 1-×1-square pattern was printed on a glazed alumina substrate using a 250-mesh stainless steel screen plate. This printing material was heated at 150° C. for 10 minutes and evaluated. Evaluations were made regarding the presence or absence of solid content in the printed film, the presence or absence of foaming during printing, and the uniformity and smoothness of the dried film surface.

(以 下 余 白) これら評価結果も、第1表中に示した。これから解るよ
うに、固形分を含有したペーストは印刷時の泡立ちもな
く、均一な乾燥膜面を得ることができた。
(See margin below) These evaluation results are also shown in Table 1. As can be seen from this, the paste containing solid content did not generate bubbles during printing, and a uniform dried film surface could be obtained.

実施例において加熱条件は150℃、10分間であるが
第2表に示した固形物の消失と加熱条件の関係より、固
形分消失の範囲内であれば目的に応じて加熱条件を適宜
選択することができる。
In the examples, the heating conditions are 150° C. for 10 minutes, but based on the relationship between the disappearance of solids and heating conditions shown in Table 2, the heating conditions can be selected as appropriate depending on the purpose as long as it is within the range of solids disappearance. be able to.

但し表中の○は固形分が消失した条件、×は固形分が消
失していない条件を表わす。
However, in the table, ○ represents a condition in which the solid content disappeared, and × represents a condition in which the solid content did not disappear.

本発明で使用することのできるテルペノイドのカルボン
酸は天然樹脂に含有される例えばアビエチン酸とその誘
導体であるピマル酸、ネオアビエチン酸、レボピマル酸
、またグアヤコン酸とその誘導体グアヤク酸ルベニン酸
などである。さらにはダンマルゴムに含有されるダンマ
ロール酸とその誘導体、ウルソル酸、オレアノール酸、
ベツリン酸なども用いることができる。モノテルペノイ
ドのカルボン酸は常温で液体のものが多いためジテルベ
ノイドやトリテルペノイドのカルボン酸と混合すれば使
用可能である。これらは、精製分離されたものが一般に
は入手し難く高価でもあるので、それらを含む天然樹脂
であるロジンやグアヤク脂、カナダバルサム、ダンマル
、ニーパルなどを利用することができる。このような天
然樹脂は産地やメーカーによって成分が大幅に興なり、
カルボン酸以外の成分も含まれていることがあるが、本
発明の目的には一向に差し支えな(使用できる。ただし
、粘度、印刷適正等の良好なペーストを得るためにはジ
テルペン・イドのカルボン酸を用いることが最良である
Terpenoid carboxylic acids that can be used in the present invention include those contained in natural resins, such as abietic acid and its derivatives pimaric acid, neoabietic acid, and levopimaric acid, as well as guaiaconic acid and its derivatives guaiac acid and rubenic acid. . Furthermore, dammarolic acid and its derivatives, ursolic acid, oleanolic acid, which are contained in dammar rubber,
Betulinic acid and the like can also be used. Since many monoterpenoid carboxylic acids are liquid at room temperature, they can be used if mixed with diterpenoid or triterpenoid carboxylic acids. Since refined and separated products of these are generally difficult to obtain and are expensive, natural resins containing them such as rosin, guaiac, Canada balsam, dammar, and neepal can be used. The ingredients of such natural resins vary greatly depending on the production area and manufacturer.
Components other than carboxylic acids may also be included, but they do not pose any problem for the purpose of the present invention (they can be used. However, in order to obtain a paste with good viscosity and printability, diterpene ide carboxylic acids It is best to use

テルペノイドのカルボン酸のアミンとの塩はこれらの酸
とアミン類との中和反応によって合成されたものが使用
でき、上記のような効果が現れるアミンの種類と組成に
ついては、第1級、第2級、第3級の全てアルキルアミ
ンについて反応量を問わず使えるが、良好なスクリーン
印刷ペーストを得るために必要なこれらアミン類の添加
すべき最小量はアンモニア、第1級アミン、第2級アミ
ン、第3級アミンの順に増加していき、アミンの炭素数
増加と共に増加する傾向にある。
Salts of terpenoid carboxylic acids with amines can be synthesized by neutralizing these acids with amines. Regarding the type and composition of amines that exhibit the above effects, primary, primary, etc. All secondary and tertiary alkylamines can be used regardless of the reaction amount, but the minimum amount of these amines necessary to obtain a good screen printing paste is ammonia, primary amines, secondary amines. It increases in the order of amine and tertiary amine, and tends to increase as the number of carbon atoms in the amine increases.

(実施例2) 実施例1の第1表に示した組成物とアンモニアとを1=
10モル比で反応した生成物を第3表に示した組成物と
イソプロピルアミンとを1:2のモル比で反応したもの
に代えて実施例1と同様な方法によりスクリーン印刷ペ
ーストを作製し、評価を行った。評価は印刷膜中の固形
分の有無と印刷時の泡立ちの有無、および乾燥膜面の均
一性。
(Example 2) The composition shown in Table 1 of Example 1 and ammonia were mixed at 1=
A screen printing paste was prepared in the same manner as in Example 1 except that the product obtained by reacting the product in a molar ratio of 10 with the composition shown in Table 3 and isopropylamine in a molar ratio of 1:2 was used. We conducted an evaluation. Evaluations include the presence or absence of solid content in the printed film, the presence or absence of bubbles during printing, and the uniformity of the dry film surface.

平滑性について行った。I checked the smoothness.

(以  下  余  白) これら評価結果も、第3表中に示した。これからも解る
ように、固形分を含有したペースト中は印刷時の泡立ち
もなく、均一な乾燥膜面を得ることができた。
(Margin below) These evaluation results are also shown in Table 3. As can be seen, there was no bubbling during printing in the paste containing solid content, and a uniform dried film surface could be obtained.

なお、具体的な実施例において印刷ペーストはルテニウ
ム化合物含有ペーストについてのみ記載したが、溶剤に
溶解可能な物質であれば本発明の構成は適用することが
できる。
In the specific examples, only a paste containing a ruthenium compound was described as the printing paste, but the structure of the present invention can be applied to any substance that can be dissolved in a solvent.

発明の効果 以上のように本発明の加熱時に消失する固形物を含有す
るスクリーン印刷用ペーストは均一で、平滑な乾燥膜を
得ることができ、産業上の効果は多大なものである。
Effects of the Invention As described above, the screen printing paste of the present invention containing solid matter that disappears upon heating can provide a uniform and smooth dry film, and has great industrial effects.

Claims (2)

【特許請求の範囲】[Claims] (1)加熱によって消失し、均一組成物となる固形分を
ペースト中に含有することを特徴とするスクリーン印刷
用ペースト。
(1) A paste for screen printing, characterized in that the paste contains a solid content that disappears upon heating and becomes a uniform composition.
(2)テルペノイドのカルボン酸とアミンとの塩の粉末
および構造中にルテニウムを含む化合物を主な構成成分
として含有することを特徴とする請求項1記載のスクリ
ーン印刷用ペースト。
(2) The screen printing paste according to claim 1, which contains as main constituents a powder of a salt of a terpenoid carboxylic acid and an amine and a compound containing ruthenium in its structure.
JP2073006A 1990-03-22 1990-03-22 Screen printing paste Pending JPH03273069A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2073006A JPH03273069A (en) 1990-03-22 1990-03-22 Screen printing paste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2073006A JPH03273069A (en) 1990-03-22 1990-03-22 Screen printing paste

Publications (1)

Publication Number Publication Date
JPH03273069A true JPH03273069A (en) 1991-12-04

Family

ID=13505829

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2073006A Pending JPH03273069A (en) 1990-03-22 1990-03-22 Screen printing paste

Country Status (1)

Country Link
JP (1) JPH03273069A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0743284A1 (en) * 1995-05-15 1996-11-20 Matsushita Electric Industrial Co., Ltd Paste for manufacturing ferrite and ferrite
WO2008149748A1 (en) * 2007-05-30 2008-12-11 Hitachi Chemical Company, Ltd. Composition containing inorganic particle, method for formation of inorganic layer, and plasma display panel
WO2009028081A1 (en) * 2007-08-31 2009-03-05 Hitachi, Ltd. Method for manufacturing plasma display panel and dielectric paste for use in the method
WO2009081491A1 (en) * 2007-12-26 2009-07-02 Hitachi, Ltd. Plasma display panel, method of manufacturing plasma display panel, and paste for sealing

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0743284A1 (en) * 1995-05-15 1996-11-20 Matsushita Electric Industrial Co., Ltd Paste for manufacturing ferrite and ferrite
US5698131A (en) * 1995-05-15 1997-12-16 Matsushita Electric Industrial Co., Ltd. Paste for manufacturing ferrite and ferrite
WO2008149748A1 (en) * 2007-05-30 2008-12-11 Hitachi Chemical Company, Ltd. Composition containing inorganic particle, method for formation of inorganic layer, and plasma display panel
WO2009028081A1 (en) * 2007-08-31 2009-03-05 Hitachi, Ltd. Method for manufacturing plasma display panel and dielectric paste for use in the method
WO2009081491A1 (en) * 2007-12-26 2009-07-02 Hitachi, Ltd. Plasma display panel, method of manufacturing plasma display panel, and paste for sealing

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