JPH02300270A - Printing ink - Google Patents
Printing inkInfo
- Publication number
- JPH02300270A JPH02300270A JP1122176A JP12217689A JPH02300270A JP H02300270 A JPH02300270 A JP H02300270A JP 1122176 A JP1122176 A JP 1122176A JP 12217689 A JP12217689 A JP 12217689A JP H02300270 A JPH02300270 A JP H02300270A
- Authority
- JP
- Japan
- Prior art keywords
- compsn
- printing ink
- vehicle
- terpenoid
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 16
- -1 amine salt Chemical class 0.000 claims abstract description 11
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims abstract description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 12
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001412 amines Chemical class 0.000 abstract description 8
- 239000002904 solvent Substances 0.000 abstract description 6
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 abstract description 4
- 150000003505 terpenes Chemical class 0.000 abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 abstract description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 229940116411 terpineol Drugs 0.000 abstract description 2
- GTOFXGPXYNYBEC-UHFFFAOYSA-K 2-ethylhexanoate;ruthenium(3+) Chemical compound [Ru+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O GTOFXGPXYNYBEC-UHFFFAOYSA-K 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明はビヒクル組成物を含有してなる印刷インキに関
するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to printing inks containing vehicle compositions.
従来の技術
アビエチン酸はテルペノイドに属するカルボン酸で、植
物が産する天然樹脂の主要成分として知られている。こ
れは従来よりテルペノイドのカルボン酸やそのエステル
類、もしくはその組成物との混合物としてフェスの形で
塗料として使われたり、またビヒクルとして含有した印
刷インキ用としても印刷性の良さや、顔料、溶剤との相
溶性の良さなどから、工業的に広（利用されている。BACKGROUND OF THE INVENTION Abietic acid is a carboxylic acid belonging to terpenoids and is known as a major component of natural resins produced by plants. It has traditionally been used as a paint in the form of a face as a mixture with terpenoid carboxylic acids, their esters, or their compositions, and it has also been used as a printing ink containing it as a vehicle due to its good printability, pigments, and solvents. It is widely used industrially due to its good compatibility with
発明が解決しようとする課題
その中で商業的に流通し、利用できるテルペノイドのカ
ルボン酸やそのエステル類、もしくはその組成物は印刷
時にインキがスクリーン版のメツシュを通過する際に生
じる泡が原因となってムラのない、平滑な印刷膜面を得
ることが非常に困難であるという課題があった。Problems to be Solved by the Invention Among the commercially available terpenoid carboxylic acids, their esters, or their compositions, the problems arise due to bubbles generated when ink passes through the mesh of a screen plate during printing. Therefore, there was a problem in that it was very difficult to obtain an even and smooth printed film surface.
本発明は以上のような従来の大魚を除去するもので平滑
な印刷膜面の得られる印刷インキを提供しようとするも
のである。The present invention aims to provide a printing ink which eliminates the conventional large fish as described above and which provides a smooth printing film surface.
課題を解決するための手段
上記課題を解決するために本発明は、ビヒクルをアビエ
チン酸３５重量％以下としたテルペノイドのカルボン酸
の組成物のアンモニウム塩かアミンとの塩の主要成分と
して構成するものである。Means for Solving the Problems In order to solve the above-mentioned problems, the present invention comprises a composition of a terpenoid carboxylic acid in which the vehicle is 35% by weight or less of abietic acid as the main component of an ammonium salt or a salt with an amine. It is.
作用
テルペノイドのカルボン酸はアンモニウムとの塩もしく
はアミンとの塩に変性することによってカルボン酸特有
の性質である分子間水素結合を持たない物質になる。こ
れによってインキの粘着性が小さくなり、印刷時のメツ
シュ通過によっても泡が発生することな（被印刷物上に
移されるようになる。従って、非常に平滑でムラのない
印刷膜が得られるものである。When the carboxylic acid of the active terpenoid is modified into a salt with ammonium or a salt with an amine, it becomes a substance that does not have intermolecular hydrogen bonds, which is a characteristic characteristic of carboxylic acids. This reduces the tackiness of the ink and allows it to pass through the mesh during printing without forming bubbles (transferring onto the printing substrate. Therefore, a very smooth and even printing film can be obtained. be.
実施例 以下、本発明の実施例について説明する。Example Examples of the present invention will be described below.
第１表に示した組成物とアンモニアとを１＝１のモル比
で反応したものをビヒクルとして１００ｇ調製し、これ
らに２−エチルへキサン塩ルテニウムを１０ｇ添加し、
溶剤としてテルピネオールを３０ｇ加えて混練し、スク
リーン印刷インキを製造した。このスクリーン印刷イン
キを乳剤厚み１５μｍ、２５０メツシユのスクリーン版
を用いてグレーズドアルミナ基板上に１ｗｌｌ１１×１
＋ＩＩｌの正方形状パターンに印刷を行った。この被印
刷物を１５０℃で３０分間乾燥し、評価を行った。評価
はビヒクルの溶剤に対する溶解性と、印刷膜面のムラの
有無および印刷時の泡立ちの有無で行った。100 g of a vehicle was prepared by reacting the composition shown in Table 1 with ammonia at a molar ratio of 1=1, and 10 g of ruthenium 2-ethylhexane salt was added thereto.
30 g of terpineol was added as a solvent and kneaded to produce a screen printing ink. This screen printing ink was printed on a glazed alumina substrate using a screen plate with an emulsion thickness of 15 μm and a mesh size of 250.
+IIl square pattern was printed. This printed material was dried at 150° C. for 30 minutes and evaluated. The evaluation was based on the solubility of the vehicle in the solvent, the presence or absence of unevenness on the printed film surface, and the presence or absence of foaming during printing.
（以 下 余 白 ）
これら評価結果も、第１表中に示した。これから分かる
ように、アビエチン酸とアンモニウム塩およびアミンと
の塩は結晶化しやすく、アビエチン酸が３５重量％以上
含有した組成物の塩は溶剤に不溶である。よってテルペ
ノイドのカルボン酸の組成物中のアビエチン酸の量が３
５重量％以下に限定される。(See margin below) These evaluation results are also shown in Table 1. As can be seen, salts of abietic acid with ammonium salts and amines are easily crystallized, and salts of compositions containing 35% by weight or more of abietic acid are insoluble in solvents. Therefore, the amount of abietic acid in the terpenoid carboxylic acid composition is 3
It is limited to 5% by weight or less.
しかしながら、スクリーン印刷インキとしての特性を最
大に満足するためにはアビエチン酸の含有量は５重量％
から２５重量％までの範囲内が最適である。However, in order to maximize the properties as a screen printing ink, the content of abietic acid must be 5% by weight.
The optimum range is from 25% by weight to 25% by weight.
テルペノイドのカルボン酸のアンモニウム塩かアミンと
の塩はこれらの酸とアンモニアやアミン類との中和反応
によって合成されたものが使用でき、上記のような効果
が現れるアミン塩の種類と組成につい・では、第１級、
第２級、第３級の全ての種類および脂肪族、芳香族の種
類１反応量を問わず使えるが、良好なインキを得るため
に必要なこれらアミン類の添加すべき最小量はアンモニ
ア、第１級アミン、第２級アミン、第３級アミンの順に
増加していき、アミンの炭素数増加と共に増加する傾向
にある。Ammonium salts of terpenoid carboxylic acids or salts with amines can be synthesized by neutralizing these acids with ammonia or amines, and the types and composition of amine salts that exhibit the above effects are as follows. So, first grade,
All types of secondary and tertiary amines and aliphatic and aromatic types can be used regardless of the reaction amount, but the minimum amount of these amines necessary to obtain a good ink is ammonia, The number increases in the order of primary amine, secondary amine, and tertiary amine, and tends to increase as the number of carbon atoms in the amine increases.
なお、具体的な実施例において印刷インキは塩化ルテニ
ウム系抵抗体形成用インキについてのみ記載したが、溶
剤に溶解可能な物質であれば本発明の構成は適用するこ
とができる。In the specific examples, only the ruthenium chloride resistor forming ink was described as the printing ink, but the structure of the present invention can be applied to any substance that can be dissolved in a solvent.
発明の効果
以上のように本発明のビヒクル組成物を含有する印刷イ
ンキは、ムラのない平滑な印刷膜を得ることができ、産
業上の効果は多大なものである。Effects of the Invention As described above, the printing ink containing the vehicle composition of the present invention can provide an even and smooth printed film, and has great industrial effects.
Claims (2)
ドのカルボン酸の組成物のアンモニウム塩かアミンとの
塩を主な構成成分とするビヒクル組成物を含有してなる
印刷インキ。(1) A printing ink comprising a vehicle composition whose main constituent is an ammonium salt or an amine salt of a terpenoid carboxylic acid composition containing 35% by weight or less of abietic acid.
請求項１記載の抵抗体形成用印刷インキ。(2) The printing ink for forming a resistor according to claim 1, which contains a compound containing ruthenium in its structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1122176A JPH02300270A (en) | 1989-05-16 | 1989-05-16 | Printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1122176A JPH02300270A (en) | 1989-05-16 | 1989-05-16 | Printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02300270A true JPH02300270A (en) | 1990-12-12 |
Family
ID=14829456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1122176A Pending JPH02300270A (en) | 1989-05-16 | 1989-05-16 | Printing ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02300270A (en) |
-
1989
- 1989-05-16 JP JP1122176A patent/JPH02300270A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0307933B1 (en) | Ink compositions for ink jet printing | |
| EP0294044B1 (en) | Method of printing on plastic substrate using a water-based ink | |
| EP0497782A4 (en) | Stable, fluid, aqueous pigment dispersions. | |
| JPS6144893A (en) | Organic titanate containing reactants of titanium ortho ester and alkyl phosphate | |
| JPH01249781A (en) | Zirconium (iv) chelate compound and solution thereof, production thereof and printing ink containing said compound | |
| JPH02300270A (en) | Printing ink | |
| JPH02503092A (en) | Water-dispersible polyamide formulation | |
| US3361582A (en) | Base vehicles for water-content printing ink, and water color printing ink made therewith | |
| DE2635226C2 (en) | Printing processes and suitable melt printing inks | |
| US3028349A (en) | High gloss printing inks | |
| DE3002922C2 (en) | ||
| DE3213032C2 (en) | ||
| JPH03273069A (en) | Screen printing paste | |
| EP0596685A2 (en) | Printing ink composition | |
| JPH02302476A (en) | Printing ink | |
| JP2650351B2 (en) | Screen printing ink | |
| JPH02274776A (en) | Ink for screen printing | |
| US3880785A (en) | Stencil-print colour | |
| JPH0552339B2 (en) | ||
| CN104194476A (en) | Assistant for water-based ink | |
| DE2812054A1 (en) | ALCOHOLIC PAINT | |
| JP3102155B2 (en) | Manufacturing method of printing ink for oral products | |
| JP3443957B2 (en) | Resin composition for printing ink and printing ink | |
| DE2526592A1 (en) | PROCEDURE FOR DESENSITIZING PRESSURE SENSITIVE REGISTRY PADS | |
| JPS6043314B2 (en) | Pressure-sensitive typo correction material |