JPH03269905A - Lamp reflector - Google Patents
Lamp reflectorInfo
- Publication number
- JPH03269905A JPH03269905A JP2068933A JP6893390A JPH03269905A JP H03269905 A JPH03269905 A JP H03269905A JP 2068933 A JP2068933 A JP 2068933A JP 6893390 A JP6893390 A JP 6893390A JP H03269905 A JPH03269905 A JP H03269905A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- lamp reflector
- inorganic
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 19
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 15
- 239000004593 Epoxy Substances 0.000 claims abstract description 12
- 239000011342 resin composition Substances 0.000 claims abstract description 11
- 239000011256 inorganic filler Substances 0.000 claims abstract description 10
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 10
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 4
- 238000001746 injection moulding Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 abstract description 8
- 239000011159 matrix material Substances 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000001771 impaired effect Effects 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- -1 sericite Chemical compound 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 239000013585 weight reducing agent Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- BQQUFAMSJAKLNB-UHFFFAOYSA-N dicyclopentadiene diepoxide Chemical compound C12C(C3OC33)CC3C2CC2C1O2 BQQUFAMSJAKLNB-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000011549 displacement method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Non-Portable Lighting Devices Or Systems Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は熱可塑性樹脂組成物を基体とする自動車専用ラ
ンプリフレクタ−に関するものであり、さらに詳しくは
、特定のポリフェニレンスルフィド樹脂組成物を射出成
形することにより得られる成形体を基体とする耐熱性、
耐久性、生産性に優れ、また金属化処理のなされた反射
面における金属塗膜の密着性が良好で、かつ軽量のラン
プリフレクタ−に関するものである。Detailed Description of the Invention <Industrial Application Field> The present invention relates to a lamp reflector for automobiles which is based on a thermoplastic resin composition. The heat resistance of the molded body obtained by
The present invention relates to a lightweight lamp reflector that has excellent durability and productivity, has good adhesion of a metal coating film on a metallized reflective surface, and is lightweight.
〈従来の技術〉
近年の自動車工業分野における金属部品のグラスチック
化は一段とその速度を増しており、しかも代替すべきプ
ラスチック材料に対する要求も単なる軽量化やデザイン
の自由度増加にとどまらず、部品の複合化による部品点
数の削減によってもたらされるトータル生産コストの抑
制、プラスチック部品自体の生産性向上へと高度化して
いる。その中でも自動車用ランプリフレクタ−は比較的
大型の部品であることから、軽量化や生産性向上による
低コスト化が強く求められる部品である。<Conventional technology> In recent years, the use of plastic parts for metal parts in the automobile industry has been rapidly increasing, and the demand for alternative plastic materials is not limited to simple weight reduction and increased freedom of design, but also demands for parts. Plastic parts are becoming more sophisticated, reducing total production costs by reducing the number of parts through compositing, and improving the productivity of the plastic parts themselves. Among these, automotive lamp reflectors are relatively large parts, and therefore there is a strong demand for lower costs by reducing weight and improving productivity.
そして、従来ラングリフレクタ−のプラスチック化は主
としてフェノール樹脂や不飽和ポリエステル樹脂などの
熱硬化性樹脂をベースとするコンパウンドによってなさ
れた。Conventionally, lang reflectors have been made of plastic using compounds based mainly on thermosetting resins such as phenolic resins and unsaturated polyester resins.
〈発明が解決しようとする課題〉
しかしながら、熱硬化性樹脂からなるランプリフレクタ
−は、軽量化、材料コストの低減という目的は一応達成
することができるものの、成形サイクルが長い、金型汚
れが多発しクリーニングが頻繁に必要となる、あるいは
成形品にパリが発生しやすいためこれを除去する工程が
必要になるなど生産性の点では多くの問題があり、これ
らの改良が望まれていた。<Problems to be Solved by the Invention> However, although lamp reflectors made of thermosetting resin can achieve the goals of reducing weight and material costs, they have long molding cycles and frequent mold stains. There are many problems in terms of productivity, such as the frequent need for cleaning, and the need for a process to remove debris as molded products tend to generate debris, and improvements to these problems have been desired.
このような生産性の問題を解決するための方法としては
、射出成形可能な熱可塑樹脂の使用が考えられ、一部で
はナイロン樹脂やＰＢＴ、ＰＥＴなどのポリエステル樹
脂を用いた検討もなされているが、ランプリフレクタ−
は強い光源の近傍で用いられることから高い耐熱性が要
求され、しかも真空蒸着などの方法で表面を金属化され
た際、平滑な金属表面を与えるための高度な表面平滑性
や金属塗膜との良好な密着性、温度、湿度などの異なる
環境下でも焦点に″ブレ″を生じさせないための高い寸
法安定性および高い機械強度などら同時に要求されるた
めまだこれらの諸要求を全て満足できる熱可塑性樹脂材
料は見出されていない。さらに最近の軽量化要求の高度
化にともなって熱硬化樹脂系コンパウンド品よりもさら
に低比重化の要求も出ているのである。One possible way to solve these productivity problems is to use thermoplastic resins that can be injection molded, and some are also considering using polyester resins such as nylon resin, PBT, and PET. But the lamp reflector
Since it is used near a strong light source, it requires high heat resistance, and when the surface is metallized by methods such as vacuum evaporation, it has a high level of surface smoothness and a metal coating to give a smooth metal surface. At the same time, good adhesion is required, as well as high dimensional stability to prevent the focus from blurring even under different environments such as temperature and humidity, and high mechanical strength. No plastic resin material has been found. Furthermore, as the recent demands for weight reduction have become more sophisticated, there is also a demand for lower specific gravity than thermosetting resin compound products.
そこで本発明者らは上記の耐熱性、表面平滑性、金属塗
膜との密着性、寸法安定性および強度などの諸要求特性
を満足し、かつ軽量で生産性の高い熱可塑性樹脂製ラン
プリフレクタ−を得ることを課題として鋭意検討した結
果、ポリフェニレンスルフィド樹脂（以下ＰＰ５ｔ！Ｉ
Ｊ脂と略す）をマトリクス樹脂として選択し、さらに１
！！機充填材と特定の無機質中空状充填材および分子内
に少なくとも２個のエポキシ基を有する多官能エポキシ
化合物を特定の割合で組合せて得られる樹脂組成物を射
出成形することにより、従来の問題点を一挙に解決でき
、上記要求特性を全て満足するランプリフレクタ−が得
られることを見出し本発明に到達した。Therefore, the present inventors developed a lamp reflector made of thermoplastic resin that satisfies the required characteristics such as heat resistance, surface smoothness, adhesion to metal coatings, dimensional stability, and strength, and is lightweight and highly productive. - As a result of intensive study on the issue of obtaining polyphenylene sulfide resin (hereinafter referred to as PP5t!I
J resin) was selected as the matrix resin, and 1
! ! Conventional problems can be solved by injection molding a resin composition obtained by combining a mechanical filler, a specific inorganic hollow filler, and a polyfunctional epoxy compound having at least two epoxy groups in the molecule in a specific ratio. The inventors have discovered that the problems can be solved all at once, and that a lamp reflector can be obtained that satisfies all of the above-mentioned required characteristics, and has thus arrived at the present invention.
〈課題を解決するための手段〉
すなわち本発明は、ポリフェニレンスルフィド樹脂３０
〜７０重量％、繊維状または非繊維状の無機質充填材２
５〜６０重量％および無機質中空充填材５〜３０重量％
からなる樹脂組成物１００重量部に対し、分子内に少な
くとも２個のエポキシ基を有する分子量２，０００以下
の多官能エポキシ化合物０．１〜１０！量部を添加して
なるポリフェニレンスルフィド樹脂組成物を溶融射出成
形することにより得られる成形体を基体とするランプリ
フレクタ−を提供するものである。<Means for solving the problem> That is, the present invention provides polyphenylene sulfide resin 30
~70% by weight, fibrous or non-fibrous inorganic filler 2
5-60% by weight and 5-30% by weight of inorganic hollow filler
0.1 to 10 parts by weight of a polyfunctional epoxy compound having a molecular weight of 2,000 or less and having at least two epoxy groups in the molecule, per 100 parts by weight of the resin composition. The object of the present invention is to provide a lamp reflector having a molded body obtained by melt injection molding a polyphenylene sulfide resin composition containing a certain amount of the present invention.
本発明で使用するｐｐｓ＠脂とは、構造式モル％以上、
より好ましくは９０モル％以上を含む重合体であり、上
記繰返し単位が７０モル％未満では耐熱性が損われるた
め好ましくない。The pps@fat used in the present invention has a structural formula of mol% or more,
More preferably, it is a polymer containing 90 mol% or more, and if the content of the repeating unit is less than 70 mol%, heat resistance will be impaired, which is not preferable.
ＰＰ５１１１脂は一般に、特公昭４５−３３６８号公報
で代表される製造法により得られる比較的分子量の小さ
い重合体と、特公昭５２−１２２４０号公報で代表され
る製造法により得られる本質的に線状で比較的高分子量
の重合体などがあり、前記特公昭４５−３３６８号公報
記載の方法で得られた重合体・においては、重合後酸素
雰囲気下において加熱することにより、あるいは過酸化
物などの架橋剤を添加して加熱することにより高重合度
化して用いることも可能である。本発明においてはいか
なる方法により得られたＰＰＳ樹脂を用いることも可能
であるが、線状で比較的高分子量の重合体がより好まし
く使用される。PP5111 resin is generally a polymer with relatively low molecular weight obtained by the production method typified by Japanese Patent Publication No. 45-3368, and an essentially linear polymer obtained by the production method typified by Japanese Patent Publication No. 52-12240. In the case of the polymer obtained by the method described in the above-mentioned Japanese Patent Publication No. 45-3368, it is possible to obtain the polymer by heating in an oxygen atmosphere after polymerization, or by heating it in an oxygen atmosphere after polymerization, or by adding a peroxide or the like. It is also possible to increase the degree of polymerization by adding a crosslinking agent and heating. In the present invention, it is possible to use PPS resin obtained by any method, but a linear polymer having a relatively high molecular weight is more preferably used.
また、ＰＰＳ樹脂はその繰返し単位の３０モル％未満を
下記のＳ造式を有する繰返し単位などで構成することが
可能である。Furthermore, less than 30 mol% of the repeating units in the PPS resin can be composed of repeating units having the following S formula.
本発明で使用されるｐｐｓ＠脂は上記重合工程を経て生
成した後、酸処理、熱水処理または有機溶媒による洗浄
など従来公知の後処理を施されたものであってもよい。The pps@fat used in the present invention may be produced through the above polymerization step and then subjected to conventionally known post-treatments such as acid treatment, hot water treatment, or washing with an organic solvent.
またその重合度については特に制限なく、通常３００℃
、すり速度２００秒−１の条件下における溶融粘度が１
００〜１００，００ボイズのものを任意に用いることが
できる。The degree of polymerization is not particularly limited, and is usually 300°C.
, the melt viscosity under the condition of a sliding speed of 200 seconds-1 is 1
00 to 100,00 voids can be arbitrarily used.
本発明で使用される繊維状無機質充填材の具体例として
はカラス繊維、炭素繊維、アルミナ繊維、炭化ケイ素繊
維、アスベスト繊維、チタン酸カリウムウィスカーなど
を挙げることかでき、また非繊維状の無機質充填材の具
体例としてはワラステナイト、シリカ、セリサイト、カ
オリン、マイカ、クレー、ベントナイト、アスベスト、
タルク、アルミナシリゲートなどの珪酸塩、アルミナ、
塩化珪素、酸化マグネシウム、酸化ジルコニウム、酸化
チタンなどの金属酸化物、炭酸カルシウム、炭酸マグネ
シウム、ドロマイトなどの炭酸塩、硫酸カルシウム、Ｆ
ｉＢバリウムなどのｔＥ酸塩、ガラス・ビーズ、窒化ホ
ウ素および炭化珪素などを挙げることができる。Specific examples of the fibrous inorganic fillers used in the present invention include glass fibers, carbon fibers, alumina fibers, silicon carbide fibers, asbestos fibers, potassium titanate whiskers, and non-fibrous inorganic fillers. Specific examples of materials include wollastenite, silica, sericite, kaolin, mica, clay, bentonite, asbestos,
Silicates such as talc, alumina silicate, alumina,
Metal oxides such as silicon chloride, magnesium oxide, zirconium oxide, and titanium oxide, carbonates such as calcium carbonate, magnesium carbonate, and dolomite, calcium sulfate, F
Mention may be made of tE salts such as iB barium, glass beads, boron nitride and silicon carbide.
これら無機質充填材のうちから強度、寸法安定性、表面
平滑性などの要求に適合したものを単独あるいは２種以
上の混合物の形で任意に選択することが可能であるが好
ましく用いられるものとしてはワラステナイト、炭酸カ
ルシウムおよびチタン酸カリウムウィスカーなど強度と
寸法安定性を同時に付与できる充填材が挙げられる。こ
れら充填材は必要に応じてシラン系あるいはチタネート
系、アルミネート系、などのカップリング剤で予備処理
して使用することができる。これら無機質充填材の配合
量は２５〜６０重量％、好ましくは３０〜５５重量％の
範囲である。配合量が２５重量％に満だないと最終製品
の強度が不足するため好ましくなく、一方６０重量％を
越えると表面平滑性、流動性などが損われるので好まし
くない。Among these inorganic fillers, it is possible to arbitrarily select one that meets the requirements for strength, dimensional stability, surface smoothness, etc., either alone or in the form of a mixture of two or more, but the ones that are preferably used are: Fillers that can provide strength and dimensional stability at the same time include wollastenite, calcium carbonate, and potassium titanate whiskers. These fillers can be used after being pretreated with a silane-based, titanate-based, or aluminate-based coupling agent, if necessary. The blending amount of these inorganic fillers is in the range of 25 to 60% by weight, preferably 30 to 55% by weight. If the amount is less than 25% by weight, the strength of the final product will be insufficient, which is undesirable, while if it exceeds 60% by weight, surface smoothness, fluidity, etc. will be impaired, which is not preferred.
本発明で用いられるもう１つの配合成分である無機質中
空状充填材の代表例としてはガラスバルーン、シラスバ
ルーン、アルミナシリゲートバルーンおよびシリカバル
ーンなどを挙げることができる。これら中空状充填材に
は各々その比重の異なるいくつかの種類が存在するが本
発明においては最終製品の強度、比重、寸法安定性など
の要求に合せて適宜選択することができ、また前記無機
充填材と同様、必要に応じてカップリング剤で予備処理
して使用することもできる。中でもガラスバルーンは破
裂強度が高く、また平滑な表面を付与することができる
ため好適に用いられる。これら無機質中空状充填材の配
合量はＰＰＳ＠脂に対し、５〜３０重量％の範囲内であ
り、さらに好ましくは７〜２０重量％である。配合量が
５重量％に満たないと軽量化効果が不十分であり好まし
くなく、一方３０重量％を越えると機ｍ強度の損失が著
しくなるため好ましくない。Representative examples of the inorganic hollow filler, which is another compounding component used in the present invention, include glass balloons, glass balloons, alumina silicate balloons, and silica balloons. There are several types of hollow fillers with different specific gravity, but in the present invention, they can be appropriately selected according to the requirements of the final product, such as strength, specific gravity, and dimensional stability. Like the filler, it can be used after being pretreated with a coupling agent if necessary. Among them, glass balloons are preferably used because they have high bursting strength and can provide a smooth surface. The blending amount of these inorganic hollow fillers is within the range of 5 to 30% by weight, more preferably 7 to 20% by weight, based on PPS@fat. If the amount is less than 5% by weight, the weight reduction effect will be insufficient, which is undesirable, while if it exceeds 30% by weight, the loss of mechanical strength will become significant, which is not preferable.
本発明で使用される多官能エポキシ化合物はＰＰ５ＶＩ
Ｊ脂と金属塗膜との密着性の向上のために必要であり、
このような効果を有する多官能エポキシ化合物の具体例
としてはビスフェノールＡ、ビスフェノールＳ、ハイド
ロキノン、レゾルシノール、１，３．５−トリヒドロキ
シベンゼンなどの多官能フェノール系化合物のグリシジ
ルエーテル類、エチレングリコール、ブタンジオール、
ネオペンチルグリコール、グリセリン、ペンタエリスリ
トールなどの脂肪族多価アルコールのグリシジルエーテ
ル類、フタル酸、テトラヒドロフタル酸、ヘキサヒドロ
フタル酸、アジピン酸などの多官能カルボン酸のグリシ
ジルエステル類、グリシジルエポキシ樹脂およびエポキ
シ変性シリコーン化合物、ビニルシクロヘキセンジオキ
シド、ジシクロペンタジェンジオキシドなどを挙げるこ
とができる。The polyfunctional epoxy compound used in the present invention is PP5VI
Necessary for improving the adhesion between J-type fat and metal coating,
Specific examples of polyfunctional epoxy compounds having such effects include glycidyl ethers of polyfunctional phenolic compounds such as bisphenol A, bisphenol S, hydroquinone, resorcinol, and 1,3.5-trihydroxybenzene, ethylene glycol, and butane. diol,
Glycidyl ethers of aliphatic polyhydric alcohols such as neopentyl glycol, glycerin, and pentaerythritol; glycidyl esters of polyfunctional carboxylic acids such as phthalic acid, tetrahydrophthalic acid, hexahydrophthalic acid, and adipic acid; glycidyl epoxy resins and epoxy Examples include modified silicone compounds, vinylcyclohexene dioxide, dicyclopentadiene dioxide, and the like.
これら多官能エポキシ化合物の添加量はＰＰＳ樹脂と上
記充填材とからなる組成物１００重量部に対して０．１
〜１０を置部であり、好ましくは０．２〜７重量部であ
る。添加量が０．１重量部に満たないと金属塗膜との密
着性改良効果が損われ、また逆に添加量が１０重量部を
越えると樹脂組成物の増粘が起こり、成形性が低下する
ため好ましくない。The amount of these polyfunctional epoxy compounds added is 0.1 parts by weight per 100 parts by weight of the composition consisting of PPS resin and the above filler.
-10 parts by weight, preferably 0.2-7 parts by weight. If the amount added is less than 0.1 parts by weight, the effect of improving adhesion to the metal coating will be impaired, and if the amount added exceeds 10 parts by weight, the resin composition will thicken and the moldability will decrease. It is not desirable because
本発明におけるＰＰＳ樹脂組成物の調製方法は特に制限
がなく、ＰＰＳ樹脂、繊維状または非繊維状無機質充填
材、無機質中空状充填材および多官能エポキシ化合物を
リボンブレンダーヘンシエルミキサー、■ブレンダーな
どを用いてトライブレンドした後、バンバリーミキサ−
ミキシングロール、単軸または２軸の押出機、ニーダ−
などを用いて溶融混練する方法などを挙げることができ
る。中でも単軸または２軸の押出機を用いて溶融混練す
る方法が簡便かつ効率的であることから好ましい。The method for preparing the PPS resin composition in the present invention is not particularly limited. After tri-blending using Banbury mixer
Mixing rolls, single or twin screw extruders, kneaders
Examples include a method of melting and kneading using, for example. Among these, a method of melt-kneading using a single-screw or twin-screw extruder is preferred because it is simple and efficient.
また本発明で用いるＰＰＳ樹脂組成物には、本発明の効
果を損わない範囲で、酸化防止剤、熱安定剤、滑剤、結
晶核剤、紫外線防止剤、着色剤、難燃剤などの通常の添
加剤および少蓋の多種ポリマを添加することができ、さ
らに、ＰＰＳ樹脂の架橋度を制御する目的で、通常の過
酸化剤および特開昭５９−１３１６５０号公報に記載さ
れているチオホスフィン酸金属塩などの架橋促進剤また
は特開昭５８−２０４０４５号公報、特開昭５８−２０
４０４６号公報などに記載されているジアルキル錫ジカ
ルボキシレート、アミノトリアゾールなどの架橋防止剤
を配合することも可能である。In addition, the PPS resin composition used in the present invention may contain conventional additives such as antioxidants, heat stabilizers, lubricants, crystal nucleating agents, ultraviolet inhibitors, colorants, and flame retardants to the extent that the effects of the present invention are not impaired. Additives and a small amount of various polymers can be added, and for the purpose of controlling the degree of crosslinking of the PPS resin, ordinary peroxidants and thiophosphinic acid described in JP-A-59-131650 can be added. Crosslinking accelerators such as metal salts or JP-A-58-204045, JP-A-58-20
It is also possible to incorporate crosslinking inhibitors such as dialkyltin dicarboxylate and aminotriazole described in Japanese Patent No. 4046 and the like.
このようにして得られたＰＰＳ樹脂組成物を十分な容量
および型締力を有する射出成形機を用いて通常シリンダ
ー温度２８０〜３５０℃、金型温度５０〜１６０℃の条
件で射出成形し、得られた成形体の表面に真空蒸着など
の方法を用いてアルミニウム、亜鉛などの金属コーティ
ングを施すことにより本発明のランプリフレクタ−が形
成される。The PPS resin composition thus obtained is injection molded using an injection molding machine with sufficient capacity and mold clamping force under the usual conditions of a cylinder temperature of 280 to 350°C and a mold temperature of 50 to 160°C. The lamp reflector of the present invention is formed by coating the surface of the molded body with a metal such as aluminum or zinc using a method such as vacuum deposition.
この際、金属膜と成形体表面の間の密着性能をさらに向
上させる目的でコーティングの前に予め成形体表面を公
知のアクリル系、シリコーン系、ウレタン系などのプラ
イマーで処理することが可能である０通常ランプリフレ
クターが点灯時には２００（’Ｃ）前後の高温にさらさ
れるので、プライマーとしては例えばシリコーン系など
の耐熱性の高いプライマーを選択することがさらに好ま
しい。At this time, in order to further improve the adhesion performance between the metal film and the surface of the molded object, it is possible to treat the surface of the molded object with a known primer such as acrylic, silicone, or urethane-based primer before coating. Since the lamp reflector is normally exposed to high temperatures of around 200 ('C) when lit, it is more preferable to select a primer with high heat resistance, such as a silicone-based primer.
本発明のランプリフレクタ−は射出成形により生産され
るため生産性が高く、また強度、表面平滑性、寸法安定
性、耐熱性に優れ、しかも金属塗膜との密着性が良好で
、かつ軽量であるという優れた特徴を有するものである
。The lamp reflector of the present invention is produced by injection molding, so it has high productivity, and also has excellent strength, surface smoothness, dimensional stability, and heat resistance, as well as good adhesion to metal coatings, and is lightweight. It has the excellent characteristics of:
〈実施例〉
以下に実施例を挙げて本発明をさ−らに詳しく説明する
。なお、実施例および比較例に記された特性は次の方法
で測定した。<Examples> The present invention will be described in more detail with reference to Examples below. Note that the characteristics described in Examples and Comparative Examples were measured by the following method.
（１）成形品の比重 ： 水中置換法
（２）引張強度： ＡＳＴＭ Ｄ６３８（３）曲げ強
度：
１４）衝撃強度：
（５）表面平滑性 ：
（６）
金属塗膜の密着性能
ＡＳＴＭ Ｄ７９０
ＡＳＴＭ Ｄ２５６
射出成形で得た成形基
体表面にブライマー処
理後、真空蒸着法でア
ルミニウムを蒸着せし
め、その鏡面に蛍光灯
を反射させ、その反射
像のゆがみの有無を目
視判定した。(1) Specific gravity of molded product: Underwater displacement method (2) Tensile strength: ASTM D638 (3) Bending strength: 14) Impact strength: (5) Surface smoothness: (6) Adhesion performance of metal coating ASTM D790 ASTM D256 After the surface of the molded substrate obtained by injection molding was subjected to a brimer treatment, aluminum was deposited by vacuum evaporation, a fluorescent lamp was reflected on the mirror surface, and the presence or absence of distortion in the reflected image was visually determined.
二 上記のようにし て得られた金属化され た成形体表面にカミソ リで５Ｂ間隔で格子状 に切込みを入れ、マス 目が１００個できるよ うにする０次に表面に セロテープを貼った後、 一気に剥す操作を行っ た。上記操作の後に或 形体表面に残った金属 塗膜のマス目の数を集 形して密着性能を比較 する。2. Do as above. metallized Camiso on the surface of the molded product. grid pattern with 5B spacing Make a cut in the square and I can have 100 eyes to the surface After applying sellotape, Perform the peeling operation all at once. Ta. After the above operation Metal remaining on the surface of the feature Collect the number of squares in the paint film. Compare adhesion performance do.
参考例（ＰＰＳ樹脂の重合）
オートクレーブに硫化ナトリウム３．２６ｋｇ（２５モ
ル、結晶水４０％を含む）、水酸化ナトリウム４ｇ、酢
酸ナトリウム三水和物１．３６＆Ｉｇ ＜約１０モル）
およびＮ−メチル−２−ピロリドン（以下ＮＭＰと称す
） ７．９ ｋｇを仕込み、撹拌しながら徐々に２０５
℃まで昇温し、水１゜３６ｋＩｒを含む留出水約１．５
１を除去した。残留混合物に１．４−ジクロルベンゼン
３．７５ｍ（２５，５モル）およびＮＭＰ２ｋｇを加え
、２６５℃で４時間加熱した０反応生成物を７０℃の温
水で５回洗浄し、８０℃で２４時間減圧乾燥して、溶融
粘度的１，５００ボイズ（３００℃、剪断速度２００秒
″１）の粉末状ＰＰＳ樹脂約２鯖を得た。Reference example (Polymerization of PPS resin) In an autoclave, 3.26 kg of sodium sulfide (25 mol, containing 40% water of crystallization), 4 g of sodium hydroxide, 1.36 & Ig of sodium acetate trihydrate <about 10 mol)
and 7.9 kg of N-methyl-2-pyrrolidone (hereinafter referred to as NMP), and gradually added 205 kg while stirring.
The temperature is raised to ℃ and distilled water containing 1°36 kIr of water is about 1.5
1 was removed. 3.75 m (25.5 mol) of 1,4-dichlorobenzene and 2 kg of NMP were added to the residual mixture and heated at 265°C for 4 hours. The reaction product was washed 5 times with hot water at 70°C and heated at 80°C for 24 hours. After drying under reduced pressure for an hour, a powdered PPS resin having a melt viscosity of 1,500 voids (300° C., shear rate 200 seconds) was obtained.
同様の操作を繰返し、以下に記載の実施例に供した。The same operation was repeated and used in the examples described below.
実施例１
参考例に記載のＰＰ５１！ｌ脂５０１Ｅ量％、炭酸カル
シウム４０重量％およびガラスバルーン（スリーエム■
社製″グラスバブルズ５ＳＸ）１０重量％からなる混合
物１００重量部およびエポキシ変性シリコーン化合物、
トート・シリコーン■製ＢＹ１６−８５５１重量部から
なる混合物をＶブレンダーを用いて均一ブレンドした後
、４５ｗφ、Ｌ／Ｄ ＝ ３０の単軸押出機のホッパー
に供給し、シリンダー温度３２０℃、８０ｒｐｍの条件
で溶融混線を行い、吐出ガツトを冷却後ペレタイザーで
ベレット化した。Example 1 PP51 described in Reference Example! L fat 501E amount%, calcium carbonate 40% by weight and glass balloon (3M ■
100 parts by weight of a mixture consisting of 10% by weight of "Glass Bubbles 5SX" manufactured by Co., Ltd. and an epoxy-modified silicone compound,
A mixture consisting of 1 part by weight of BY16-855 manufactured by Torto Silicone ■ was homogeneously blended using a V-blender, and then supplied to the hopper of a 45 wφ, L/D = 30 single screw extruder, under conditions of a cylinder temperature of 320°C and 80 rpm. After melting and mixing, the discharge gut was cooled and pelletized using a pelletizer.
このペレットを１４０℃で５時間熱風乾燥した後、シリ
ンダー温度３２０℃、金型温度１３０℃での射出成形に
供し、特性評価用試験片および乗用車ヘッドライト用ラ
ンプリフレクタ−基体成形品を得た。ランプリフレクタ
−基体成形品については、市販のシリコーン系耐熱プラ
イマーで前処理をした後、さらに真空蒸着法によりアル
ミニウム蒸着を行い、その表面平滑性および密着性を評
価した。結果は第１表に示したとおりであり、ここで得
られたＰＰＳｆＭ脂組Ｔｔｉ、物は低比重でかつ良好な
機械的物性を有していた。また、これをベースに調整さ
れたランプリフレクタ−は良好な表面平滑性と密着性を
有する極めて実用価値の高いものであることが判明した
。The pellets were dried with hot air at 140°C for 5 hours and then subjected to injection molding at a cylinder temperature of 320°C and a mold temperature of 130°C to obtain test pieces for characteristic evaluation and lamp reflector base molded articles for passenger car headlights. The lamp reflector base molded product was pretreated with a commercially available silicone heat-resistant primer, and then aluminum was deposited using a vacuum deposition method, and its surface smoothness and adhesion were evaluated. The results are shown in Table 1, and the PPSfM resin assembly Tti obtained here had a low specific gravity and good mechanical properties. Further, it has been found that a lamp reflector prepared based on this has excellent surface smoothness and adhesion and is of extremely high practical value.
実施例２〜５
無機質充填材、無機質中空充填材および多官能エポキシ
化合物の配合量を第１表に示したように変えて実施例１
と同様の手順で溶融混練、射出成形を行った場合の評価
結果を第１表に示す、その結果、実施例１と同じく極め
て実用価値の高いランプリフレクタ−が得られることが
判明した。Examples 2 to 5 Example 1 was prepared by changing the blending amounts of the inorganic filler, inorganic hollow filler, and polyfunctional epoxy compound as shown in Table 1.
Table 1 shows the evaluation results when melt-kneading and injection molding were carried out in the same manner as in Example 1. As a result, it was found that a lamp reflector with extremely high practical value could be obtained as in Example 1.
比較例１
多官能エポキシ化合物を加えない以外は実施例１と同様
の手順で溶融混練、射出成形を行った場合の評価結果を
第１表に示す、その結果、得られたランプリフレクタ−
は金属膜との密着性が不十分であった。Comparative Example 1 Table 1 shows the evaluation results when melt-kneading and injection molding were performed in the same manner as in Example 1 except that the polyfunctional epoxy compound was not added.
had insufficient adhesion to the metal film.
〈発明の効果〉
以上説明したように、本発明によれば、ＰＰＳ樹脂をマ
トリクス樹脂として使用し、特定の無機質充填材、無機
質中空充填材および多官能エポキシ化合物を混合して得
られるＰＰＳ樹脂樹脂樹脂組金物形成形ことにより軽量
、耐熟性、強度、寸法安定性、表面平滑性、金属膜との
密着性能などの諸要求を満足するランプリフレクタ−を
生産性よく製造することが可能である。<Effects of the Invention> As explained above, according to the present invention, a PPS resin is obtained by using a PPS resin as a matrix resin and mixing a specific inorganic filler, an inorganic hollow filler, and a polyfunctional epoxy compound. By forming resin composite metal parts, it is possible to manufacture lamp reflectors with high productivity that satisfy various requirements such as light weight, aging resistance, strength, dimensional stability, surface smoothness, and adhesion performance with metal films. .
Claims (1)
維状または非繊維状の無機質充填材２５〜６０重量％お
よび無機質中空状充填材５〜３０重量％からなる樹脂組
成物１００重量部に対して、分子内に少なくとも２個の
エポキシ基を有する分子量２，０００以下の多官能エポ
キシ化合物０．１〜１０重量部を添加してなる樹脂組成
物を溶融射出成形することにより得られる成形体を基体
とするランプリフレクター。For 100 parts by weight of a resin composition consisting of 30 to 70% by weight of polyphenylene sulfide resin, 25 to 60% by weight of fibrous or non-fibrous inorganic filler, and 5 to 30% by weight of inorganic hollow filler, A lamp reflector based on a molded product obtained by melt injection molding a resin composition containing 0.1 to 10 parts by weight of a polyfunctional epoxy compound having a molecular weight of 2,000 or less and having at least two epoxy groups. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2068933A JPH03269905A (en) | 1990-03-19 | 1990-03-19 | Lamp reflector |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2068933A JPH03269905A (en) | 1990-03-19 | 1990-03-19 | Lamp reflector |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03269905A true JPH03269905A (en) | 1991-12-02 |
Family
ID=13387962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2068933A Pending JPH03269905A (en) | 1990-03-19 | 1990-03-19 | Lamp reflector |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03269905A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006002105A (en) * | 2004-06-21 | 2006-01-05 | Tosoh Corp | Polyarylene sulfide composition and case containing it |
| JP2006045293A (en) * | 2004-08-02 | 2006-02-16 | Tosoh Corp | Polyarylene sulfide composition |
-
1990
- 1990-03-19 JP JP2068933A patent/JPH03269905A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006002105A (en) * | 2004-06-21 | 2006-01-05 | Tosoh Corp | Polyarylene sulfide composition and case containing it |
| JP2006045293A (en) * | 2004-08-02 | 2006-02-16 | Tosoh Corp | Polyarylene sulfide composition |
| JP4725050B2 (en) * | 2004-08-02 | 2011-07-13 | 東ソー株式会社 | Polyarylene sulfide composition |
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