JPH03266681A - Thermal transfer ribbon and decoration of character pattern formed by use of same - Google Patents
Thermal transfer ribbon and decoration of character pattern formed by use of sameInfo
- Publication number
- JPH03266681A JPH03266681A JP2065918A JP6591890A JPH03266681A JP H03266681 A JPH03266681 A JP H03266681A JP 2065918 A JP2065918 A JP 2065918A JP 6591890 A JP6591890 A JP 6591890A JP H03266681 A JPH03266681 A JP H03266681A
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- character pattern
- ink layer
- transfer ribbon
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005034 decoration Methods 0.000 title 1
- 239000011888 foil Substances 0.000 claims abstract description 37
- 239000000049 pigment Substances 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 229920005989 resin Polymers 0.000 abstract description 23
- 239000011347 resin Substances 0.000 abstract description 23
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000012188 paraffin wax Substances 0.000 abstract description 3
- 229920002050 silicone resin Polymers 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract 4
- 239000000314 lubricant Substances 0.000 abstract 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 20
- -1 polypropylene Polymers 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000001993 wax Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229920006243 acrylic copolymer Polymers 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001289 polyvinyl ether Polymers 0.000 description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は熱転写リボンおよびそれを用いて形成した文字
模様を金属転写箔または顔料転写箔を用いて加飾する方
法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a thermal transfer ribbon and a method for decorating a character pattern formed using the same using a metal transfer foil or a pigment transfer foil.
［従来の技術］
従来より、文字模様など所望のデザインをトナー使用タ
イプの複写機でコピーをし、そのトナー上に金属転写箔
または顔料転写箔を重ね加熱下に加圧してトナー印字通
りの文字模様など所望のデザインを金属調または顔料色
に加飾することが知られている。[Prior Art] Conventionally, a desired design such as a character pattern is copied using a toner-based copying machine, and a metal transfer foil or a pigment transfer foil is layered on top of the toner and pressurized under heat to produce the letters exactly as printed on the toner. It is known to decorate desired designs such as patterns with metallic or pigment colors.
一方、ワードプロセッサー コンピューターなどにおけ
る熱転写プリンターに用いられている従来の熱転写リボ
ンで印字された文字模様は、従来の金属転写箔または顔
料転写箔を用いて加飾することができなかった。On the other hand, character patterns printed with conventional thermal transfer ribbons used in thermal transfer printers such as word processors and computers cannot be decorated using conventional metal transfer foils or pigment transfer foils.
したがって、従来の熱転写リボンで印字された文字模様
は一見トナー使用タイプの複写機でコピーをし、そのト
ナー上に金属転写箔または顔料転写箔を重ね加熱下に加
圧してトナー印字通りの文字模様など所望のデザインを
金属調または顔料色に加飾する必要があるという欠点が
ある。Therefore, character patterns printed with conventional thermal transfer ribbons are copied using a toner type copying machine, and a metal transfer foil or pigment transfer foil is layered on top of the toner and pressed under heat to make the character pattern exactly as printed on the toner. There is a disadvantage that it is necessary to decorate the desired design with a metallic tone or pigment color.
［発明が解決しようとする課題〕
本発明は前記従来技術の欠点に鑑み、熱転写リボンを用
いて所望の文字模様などのデザインを熱転写プリンター
で印字し、ついで金属転写箔または顔料転写箔を重ね加
熱下または非加熱下に加圧して印字通りの文字模様など
所望のデザインを金属調または顔料色に加飾することを
可能ならしめることをｎ的とする。[Problems to be Solved by the Invention] In view of the drawbacks of the prior art, the present invention prints a desired character pattern or other design using a thermal transfer ribbon using a thermal transfer printer, and then overlays a metal transfer foil or a pigment transfer foil and heats it. The objective is to make it possible to decorate a desired design, such as a letter pattern as printed, in a metallic or pigment color by applying pressure under or without heating.
［課題を解決するための手段］
すなわち本発明は、ベースフィルムの上に離型剤層およ
び感熱感圧接石性インキ層を形成したことを特徴とする
熱転写リボンを提供する。[Means for Solving the Problems] That is, the present invention provides a thermal transfer ribbon characterized in that a release agent layer and a heat-sensitive pressure-sensitive ink layer are formed on a base film.
本発明はさらに、ベースフィルムの上に離型剤層および
感熱感圧接着性インキ層を形成した熱転写リボンを用い
て熱転写プリンターで所望の文字模様を印字した後、所
望の金属転写箔または顔料転写箔の転写層側を重ね合わ
せ加熱下または非加熱下に加圧して、前記プリンターで
印字した文字模様を所望の金属転写箔または顔料転写箔
で加飾した文字模様を作成する方法を提供する。The present invention further provides a method for printing a desired character pattern using a thermal transfer printer using a thermal transfer ribbon having a release agent layer and a heat-sensitive pressure-sensitive adhesive ink layer formed on a base film, and then printing a desired metal transfer foil or pigment transfer ribbon. To provide a method for creating a character pattern in which the character pattern printed by the printer is decorated with a desired metal transfer foil or pigment transfer foil by overlapping the transfer layer sides of the foils and applying pressure with or without heating.
［作用および実施例］
本発明の熱転写リボンは感熱感圧接着性インキ層をＨし
ているので、これを用いて印字された文字模様などは、
従来のトナー使用タイプの複写機でコピーをしたものと
同様にその印字上に金属転写箔または顔料転写箔を重ね
、加熱下または非加熱下に加圧して印字通りの文字模様
など所望のデザインを金属調または類１色に加飾するこ
とが可能となり、従来技術の欠点が解消されている。[Function and Examples] Since the thermal transfer ribbon of the present invention has a heat-sensitive pressure-sensitive adhesive ink layer, character patterns etc. printed using this are
Similar to copies made using conventional toner-based copying machines, a metal transfer foil or pigment transfer foil is layered over the print, and pressure is applied with or without heating to create the desired design, such as a character pattern exactly as printed. It is now possible to decorate in a metallic tone or in a single color, eliminating the drawbacks of the prior art.
本発明の熱転写リボンは、第１図に示されるごとく、ベ
ースフィルム（１）の上に離型剤層（２１および感熱感
圧接着性インキ層（３）を順次形成したものである。The thermal transfer ribbon of the present invention, as shown in FIG. 1, has a release agent layer (21) and a heat-sensitive pressure-sensitive adhesive ink layer (3) formed in this order on a base film (1).
かかる構成により、従来の技術ではワードプロセッサー
などで印字したものを一旦トナー使用タイプの複写機で
コピーをし、しかる後に金属転写箔または顔料転写箔を
重ね合わせ加熱下に加圧して加飾するしか方法がなかっ
たのを、ワードプロセッサーなどで印字したものに直接
金属転写箔または顔料転写箔を重ね合わせ加熱下または
非加熱下に加圧して加飾することが可能となった。Due to this configuration, the conventional technique is to first copy what is printed using a word processor or the like using a toner type copying machine, and then to decorate it by overlaying metal transfer foil or pigment transfer foil and applying pressure under heat. It is now possible to directly overlay metal transfer foil or pigment transfer foil onto printed materials using a word processor or the like, and then apply pressure with or without heating to decorate the printed material.
本発明の熱転写リボンにおけるベースフィルム（１）と
しては従来から熱転写リボンに用いられているものが使
用できるが、たとえばポリエステル樹脂、ポリアミド樹
脂、ポリアミドイミド樹脂、ポリエチレン樹脂、ポリプ
ロピレン樹脂、セルロースアセテート樹脂、ポリカーボ
ネート樹脂、ポリ塩化ビニル樹脂、フッ素樹脂などの樹
脂類、またはセロハン紙、グラシン紙などのフィルム状
物もしくはシート状物や、剥離紙または剥離フィルムな
どが適宜用いられる。ベースフィルム（１）としてとく
に前記樹脂類のフィルム状物で厚さが４〜７５ｊ！ｍ程
度のものを用いるのが、しわや亀裂などのない熱転写リ
ボンを連続的に大量生産できる点から好ましい。As the base film (1) in the thermal transfer ribbon of the present invention, those conventionally used for thermal transfer ribbons can be used, such as polyester resin, polyamide resin, polyamideimide resin, polyethylene resin, polypropylene resin, cellulose acetate resin, and polycarbonate. Resins such as resins, polyvinyl chloride resins, and fluororesins, film-like materials or sheet-like materials such as cellophane paper and glassine paper, and release paper or release films are used as appropriate. The base film (1) is preferably a film-like material made of the above-mentioned resins and has a thickness of 4 to 75J! It is preferable to use a ribbon having a diameter of about m from the viewpoint of continuous mass production of thermal transfer ribbons without wrinkles or cracks.
本発明の熱転写リボンにおける離型剤ｆｔ （２）とし
ては従来から熱転写リボンに用いられているものが使用
できるが、たとえばパラフィンワックス、シリコーン樹
脂、フッ素樹脂、界面活性剤などを厚さ０．５〜２）ｓ
程度に常法により塗布形成したものが用いられる。As the release agent ft (2) in the thermal transfer ribbon of the present invention, those conventionally used in thermal transfer ribbons can be used, such as paraffin wax, silicone resin, fluororesin, surfactant, etc. ~2)s
A material coated by a conventional method to a certain extent is used.
本発明の熱転与リボンにおける感熱感圧接着性インキ層
（３）は感熱転写性を有すると共に、加熱加圧下に接着
性を示すが、あるいは常温で加圧下に接君性を示すもの
である。かがるインキ層（３）に用いるインキ組成物と
しては、たとえば鯨ロウ、ミツロウ、ラノリン、カルナ
バワックス、キャンデリラワックス、モンタンワックス
などの天然ワックス、パラフィンワックス、マイクロク
リスタリンワックス、酸化ワックス、エステルワックス
、低分子ロポリエチレンヮノクス、ポリプロピレンワッ
クス、塩素化ポリエチレンワックス、塩素化ポリプロピ
レンワックスなどの合成ワックス、ラウリン酸、ミリス
チン酸、パルミチン酸、ステアリン酸、フロメン酸、ベ
ヘニン酸などの高級脂肪酸、ステアリルアルコール、ベ
ヘニルアルコールなどの高級アルコール、ショ糖の脂肪
酸エステル、ソルビタンの脂肪酸エステルなどのエステ
ル類、ステアリンアミド、オレインアミドなどのアミド
類、ポリアミド系樹脂、ポリエステル系樹脂、エポキシ
系樹脂、ポリウレタン系樹脂、アクリル系樹脂、塩化ビ
ニル系樹脂、セルロース系樹脂、ポリ酢酸ビニル系樹脂
、石油系樹脂、エチレン−酢酸ビニル共重合樹脂、エチ
レン−アクリル系共重合樹脂およびその塩素化物（たと
えばエチレン−エチルアクリレート共重合樹脂およびそ
の塩素化物、エチレン−アクリル酸共重合樹脂およびそ
の塩素化物など）、フェノール系樹脂、スチレン系樹脂
、スチレン−アクリル系共重合樹脂、ポリビニルエーテ
ル類（たとえばポリビニルメチルエーテル、ポリビニル
エチルエーテル、ポリビニルイソブチルエーテルなど）
、ポリブテン、ポリイソブチレン、天然ゴム、スチレン
−ブタジェンゴム、インブレンゴム、クロロブレンゴム
などの樹脂類ないしエラストマー類、ロジンおよびその
話導体、テルペン樹脂、水添石油樹脂などのタッキファ
イヤ−などの単独または混合物に、適宜顔料や染料など
の色材、さらに必要により充填剤、可塑剤、酸化防ｄ−
剤などが添加されたものが好ましく用いられる。The heat-sensitive and pressure-sensitive adhesive ink layer (3) in the heat transfer ribbon of the present invention has heat-sensitive transferability and exhibits adhesion under heat and pressure, or exhibits adhesion under pressure at room temperature. . Examples of the ink composition used for the darkening ink layer (3) include natural waxes such as spermaceti wax, beeswax, lanolin, carnauba wax, candelilla wax, and montan wax, paraffin wax, microcrystalline wax, oxidized wax, and ester wax. , low molecular weight polyethylene wax, polypropylene wax, chlorinated polyethylene wax, synthetic waxes such as chlorinated polypropylene wax, higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, fromene acid, behenic acid, stearyl alcohol, Higher alcohols such as behenyl alcohol, esters such as fatty acid esters of sucrose and fatty acid esters of sorbitan, amides such as stearinamide and oleinamide, polyamide resins, polyester resins, epoxy resins, polyurethane resins, acrylic resins , vinyl chloride resins, cellulose resins, polyvinyl acetate resins, petroleum resins, ethylene-vinyl acetate copolymer resins, ethylene-acrylic copolymer resins and their chlorinated products (e.g. ethylene-ethyl acrylate copolymer resins and their chlorinated products, ethylene-acrylic acid copolymer resins and their chlorinated products), phenolic resins, styrene resins, styrene-acrylic copolymer resins, polyvinyl ethers (e.g. polyvinyl methyl ether, polyvinylethyl ether, polyvinyl isobutyl ether, etc.) )
, resins or elastomers such as polybutene, polyisobutylene, natural rubber, styrene-butadiene rubber, inbrene rubber, chloroprene rubber, rosin and its conductors, terpene resins, tackifiers such as hydrogenated petroleum resins, etc. alone or in mixtures. , colorants such as pigments and dyes, and fillers, plasticizers, and antioxidants as necessary.
Preferably, those to which an agent or the like is added are used.
非加熱下で接着性を有するインキ紺成物の主剤としては
前記のポリビニルエーテル類、ポリブテン、ポリイソブ
チレンなどが好ましく用いられる。The above-mentioned polyvinyl ethers, polybutene, polyisobutylene, etc. are preferably used as the main ingredient of the ink composition which has adhesive properties without heating.
感熱感圧接着性インキ層（３）の形成は、前記感熱感圧
接釣性インキ組成物の有機溶剤溶液、水溶液などをロー
ルコーティング法、グラビアニーティング法、リバース
コーティング法、スプレーコーティング法、ホットメル
トコーティング法などの通常のコーティング法により塗
布し、乾燥することによって行われる。感熱感圧接着性
インキ層（３）の厚さはとくに制限はないが、通常は３
〜２０．程度の範囲、好ましくは５〜Ｉ５ＡＩｍ程度の
範囲である。The heat-sensitive pressure-sensitive adhesive ink layer (3) is formed by applying an organic solvent solution, aqueous solution, etc. of the heat-sensitive pressure-sensitive adhesive ink composition to a roll coating method, a gravure annealing method, a reverse coating method, a spray coating method, or a hot melt method. This is done by applying by a common coating method such as a coating method and drying. There is no particular limit to the thickness of the heat- and pressure-sensitive adhesive ink layer (3), but it is usually 3.
~20. It is preferably in the range of about 5 to I5AIm.
本発明に用いる金属転写箔または顔料転写箔としては従
来より使用されているものがとくに制限なく使用可能で
あるが、接着剤層（感圧接着剤層または感圧接着剤層）
を有するものが好ましい。As the metal transfer foil or pigment transfer foil used in the present invention, conventionally used ones can be used without particular restrictions, but adhesive layers (pressure-sensitive adhesive layers or pressure-sensitive adhesive layers)
It is preferable to have the following.
つぎに実施例をあげて本発明を説明する。Next, the present invention will be explained with reference to Examples.
実施例１
厚さ５０癖のポリエチレンテレフタレートフィルムの片
面に、シリコーン系樹脂１０部（重量部、以下同様）お
よびイソシアネ−１・系樹脂０．１部をトルエン−酢酸
ブチル−ｎ−へキサン（７：２：ｌ容量比）からなる混
合溶剤１５０部に溶解してするコーティング溶液を塗布
、乾燥して厚さ ０．５−のＭ型剤層を形成し、ついで
エチレン−アクリル系共重合樹脂（アクリル酸含ｍ：２
０重葺％、メルトインデックス： ５００ｇ／ １０分
（１９０℃）、ガラス転移点＝７０℃）の２０重量％ア
ンモニア性エマルジョン溶液１００部に青色染料０．１
部を加えたコーティング溶液を塗布、乾燥して厚さ１０
ρの感熱感圧接着性インキ層を形成して本発明の熱転写
リボンをえた。Example 1 On one side of a polyethylene terephthalate film with a thickness of 50 mm, 10 parts of a silicone resin (parts by weight, the same applies hereinafter) and 0.1 part of an isocyanate-1 resin were added to toluene-butyl acetate-n-hexane (7 parts by weight). A coating solution prepared by dissolving in 150 parts of a mixed solvent consisting of ethylene-acrylic copolymer resin (volume ratio: Acrylic acid content m: 2
0 ply %, melt index: 500g/10 minutes (190°C), glass transition point = 70°C), 100 parts of a 20% by weight ammonia emulsion solution with 0.1 part of blue dye
Apply a coating solution containing 100% of
A heat-sensitive pressure-sensitive adhesive ink layer of ρ was formed to obtain a thermal transfer ribbon of the present invention.
実施例２
実施例１において、感熱感圧接着性インキ層用のコーテ
ィング溶液として、スチレン−アクリル系共重合樹脂（
５０重口％トルエン溶液粘度：４６９ポアズ（２５°Ｃ
）、酸価： ０，８９＋ｇｇ ＫＯＩＩ／ｇ −ガラ
ス転移点１６５℃）２０部およびカーボンブラック２部
をトルエン １００部に溶解分散した溶液を用いたほか
は実施例１と同様にして熱転写リボンをえた。Example 2 In Example 1, a styrene-acrylic copolymer resin (
50% by weight toluene solution viscosity: 469 poise (25°C
), acid value: 0.89+gg KOII/g - glass transition point 165°C) A thermal transfer ribbon was obtained in the same manner as in Example 1, except that a solution in which 20 parts of carbon black and 2 parts of carbon black were dissolved and dispersed in 100 parts of toluene was used. .
実施例３
実施例１において、感熱感圧接着性インキ層用のコーテ
ィング溶液として、塩素化エチレン−アクリル系共重合
樹脂（実施例１で用いたエチレン−アクリル系共重合樹
脂を６０モル％塩素化したもの）１０部、エチレン−酢
酸ビニルノ（重合樹脂（酢酸ビニル含量；２部柑ｍ％）
５部およびカーボンラック１部をアセトン １００部に
溶解分散した溶液を用いたほかは実施例１と同様にして
熱転写リボンをえた。Example 3 In Example 1, a chlorinated ethylene-acrylic copolymer resin (60 mol% chlorinated ethylene-acrylic copolymer resin used in Example 1) was used as a coating solution for the heat-sensitive pressure-sensitive adhesive ink layer. 10 parts of ethylene-vinyl acetate (polymer resin (vinyl acetate content; 2 parts, 1%)
A thermal transfer ribbon was obtained in the same manner as in Example 1, except that a solution prepared by dissolving and dispersing 5 parts of carbon rack and 1 part of carbon rack in 100 parts of acetone was used.
実施例１〜３でえられた本発明の熱転写リボンを用いて
熱転写プリンターを備えたワードプロセッサーで文字模
様を印字し、この印字面」二に市販の黄金色の金属転写
箔（商品名：エコー尾池工業鈎製）を市ね合わせ熱プレ
スで加熱加圧してワードプロセッサーで印字した文字模
様」−に転写した。Using the thermal transfer ribbon of the present invention obtained in Examples 1 to 3, a character pattern was printed using a word processor equipped with a thermal transfer printer. (manufactured by Ike Kogyo Kagi) was heated and pressed using a heat press and transferred to a character pattern printed using a word processor.
転写箔の転写はワードプロセッサーで印字した文字模様
、ににのみ行なわれており、兄事に黄金色に加飾されて
いた。The transfer foil was only used to transfer the letter patterns printed using a word processor, and the letters were decorated in gold.
なお通當の熱転写リボンを用いてワードプロセッサーで
文字模様を印字したものを、−旦トナー使用タイプの複
写機でコピーをし、しかる後に金属転写箔を重ね合わせ
、加熱加圧してトナーの文字模様上に転写したものと比
較したが、全く損色はなかった。In addition, a character pattern is printed using a word processor using a regular thermal transfer ribbon, then it is copied using a toner type copying machine, and then a metal transfer foil is overlaid and heated and pressed to print on the toner character pattern. I compared it with the one transferred to , and there was no color loss at all.
実施例４
実施例１において、感熱感圧接着性インキ雇用のコーテ
ィング溶洗として、ポリビニルエチルエーテル２０部、
カルナバワックス２部およびカーボンブラック１部をイ
ソプロピルアルコール１００部に溶解分散した溶液を用
いたほかは実施例１と同様にして熱転写リボンをえた。Example 4 In Example 1, 20 parts of polyvinylethyl ether,
A thermal transfer ribbon was obtained in the same manner as in Example 1, except that a solution in which 2 parts of carnauba wax and 1 part of carbon black were dissolved and dispersed in 100 parts of isopropyl alcohol was used.
実施例４でえられた本発明の熱転写リボンを用いて熱転
写プリンターを備えたワードプロセッサーで文字模様を
印字し、この印字面上に市販の黄金色の金属転写箔（商
品名：エコー、尾池工業■製）を重ね合わせプレスで室
温下加圧してワードプロセッサーで印字した文字模様」
−に転写した。Using the thermal transfer ribbon of the present invention obtained in Example 4, a character pattern was printed using a word processor equipped with a thermal transfer printer, and a commercially available golden metal transfer foil (product name: ECHO, Oike Kogyo) was printed on the printed surface. "The character pattern was printed using a word processor after pressing the sheets (manufactured by ■) at room temperature using a press."
-Transferred to.
転写箔の転写はワードプロセッサーで印字した文字模様
上にのみ行なオ）れており、見・１．ｌに黄金色に加飾
されていた。The transfer foil is only transferred onto the character pattern printed using a word processor. The l was decorated in gold.
［発明の効果］
本発明の熱転写リボンを用いて熱転写プリンターで形成
した文字模様を金属転写箔または顔料転写箔を用いて加
飾する方法によるときは、従来技術における熱転写プリ
ンターで形成した文字模様を一旦トナー使用タイプのｌ
Ｓｌ与機でコピーをし、しかる後に金属転写箔や顔料転
写箔を市ね合わせ加圧して文字模様上に転写し加飾しな
ければならないという欠点が解消され、トナー使用タイ
プの複写機を必要とせず、作業は工程数が少なく容易で
あるという効果が奏される。[Effects of the Invention] When using a method of decorating a character pattern formed by a thermal transfer printer using the thermal transfer ribbon of the present invention with a metal transfer foil or a pigment transfer foil, the character pattern formed by a thermal transfer printer in the prior art is Once the toner usage type l
This eliminates the drawback of having to make copies using a Sl copying machine and then press metal transfer foils or pigment transfer foils together and apply pressure to transfer and decorate character patterns, making it necessary to use a toner-based copying machine. The effect is that the number of steps is small and the work is easy.
才１ 図Sai 1 diagram
第１図は本発明の熱転写リボンの構成を示す概略断面図
である。
（図面のｎ号）
（１）二ベースフィルム
（２１： ｌｉ１型剤層
（３）：感熱感圧接６性インキ層
１ ：ベースフイルム
２：離型剤層
６：感熱感圧接着性インキ層FIG. 1 is a schematic cross-sectional view showing the structure of the thermal transfer ribbon of the present invention. (No. n in the drawing) (1) Two base films (21: li1 type agent layer (3): heat-sensitive pressure-sensitive adhesive ink layer 1: base film 2: release agent layer 6: heat-sensitive pressure-sensitive adhesive ink layer
Claims (1)
性インキ層を形成したことを特徴とする熱転写リボン。 ２ ベースフィルムの上に離型剤層および感熱感圧接着
性インキ層を形成した熱転写リボンを用いて熱転写プリ
ンターで所望の文字模様を印字した後、所望の金属転写
箔または顔料転写箔の転写層側を重ね合わせ加熱下また
は非加熱下に加圧して、前記プリンターで印字した文字
模様を所望の金属転写箔または顔料転写箔で加飾した文
字模様を成形する方法。[Scope of Claims] 1. A thermal transfer ribbon characterized in that a release agent layer and a heat-sensitive pressure-sensitive adhesive ink layer are formed on a base film. 2. After printing a desired character pattern with a thermal transfer printer using a thermal transfer ribbon with a release agent layer and a heat-sensitive pressure-sensitive adhesive ink layer formed on a base film, a desired transfer layer of metal transfer foil or pigment transfer foil is applied. A method of forming a character pattern in which the character pattern printed by the printer is decorated with a desired metal transfer foil or pigment transfer foil by overlapping the sides and applying pressure with or without heating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2065918A JP2585829B2 (en) | 1990-03-15 | 1990-03-15 | Thermal transfer ribbon and method for decorating character pattern formed using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2065918A JP2585829B2 (en) | 1990-03-15 | 1990-03-15 | Thermal transfer ribbon and method for decorating character pattern formed using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03266681A true JPH03266681A (en) | 1991-11-27 |
| JP2585829B2 JP2585829B2 (en) | 1997-02-26 |
Family
ID=13300834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2065918A Expired - Lifetime JP2585829B2 (en) | 1990-03-15 | 1990-03-15 | Thermal transfer ribbon and method for decorating character pattern formed using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2585829B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5707082A (en) * | 1995-07-18 | 1998-01-13 | Moore Business Forms Inc | Thermally imaged colored baggage tags |
| GB2328215A (en) * | 1997-08-16 | 1999-02-17 | Simon Ellis | A printing ink used in the process of foil stamping |
| CN103042845A (en) * | 2013-01-15 | 2013-04-17 | 杭州兴甬复合材料有限公司 | Thermal transfer ribbon |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS59171691A (en) * | 1983-03-18 | 1984-09-28 | Naigai Ink Seizo Kk | Pressure and heat-sensitive carbon copying paper |
| JPS61206693A (en) * | 1985-03-12 | 1986-09-12 | General Kk | Thermal transfer recording medium |
| JPS61244591A (en) * | 1985-04-24 | 1986-10-30 | Fuji Xerox Co Ltd | Thermal recording material |
| JPS61244592A (en) * | 1985-04-24 | 1986-10-30 | Fuji Xerox Co Ltd | Thermal recording material |
| JPS61273989A (en) * | 1985-05-30 | 1986-12-04 | Toppan Printing Co Ltd | Thermal transfer sheet |
| JPS62240583A (en) * | 1986-04-12 | 1987-10-21 | Kazuichi Sugiura | Transfer printing method |
| JPS62255184A (en) * | 1986-04-28 | 1987-11-06 | Nippon Seiki Co Ltd | Simple thermal transfer press |
| JPS63115781A (en) * | 1986-11-04 | 1988-05-20 | Oike Ind Co Ltd | Super-heat-resistant thermal transfer foil |
| JPH01141788A (en) * | 1987-11-28 | 1989-06-02 | Toppan Printing Co Ltd | Thermal transfer recording material |
-
1990
- 1990-03-15 JP JP2065918A patent/JP2585829B2/en not_active Expired - Lifetime
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS59171691A (en) * | 1983-03-18 | 1984-09-28 | Naigai Ink Seizo Kk | Pressure and heat-sensitive carbon copying paper |
| JPS61206693A (en) * | 1985-03-12 | 1986-09-12 | General Kk | Thermal transfer recording medium |
| JPS61244591A (en) * | 1985-04-24 | 1986-10-30 | Fuji Xerox Co Ltd | Thermal recording material |
| JPS61244592A (en) * | 1985-04-24 | 1986-10-30 | Fuji Xerox Co Ltd | Thermal recording material |
| JPS61273989A (en) * | 1985-05-30 | 1986-12-04 | Toppan Printing Co Ltd | Thermal transfer sheet |
| JPS62240583A (en) * | 1986-04-12 | 1987-10-21 | Kazuichi Sugiura | Transfer printing method |
| JPS62255184A (en) * | 1986-04-28 | 1987-11-06 | Nippon Seiki Co Ltd | Simple thermal transfer press |
| JPS63115781A (en) * | 1986-11-04 | 1988-05-20 | Oike Ind Co Ltd | Super-heat-resistant thermal transfer foil |
| JPH01141788A (en) * | 1987-11-28 | 1989-06-02 | Toppan Printing Co Ltd | Thermal transfer recording material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5707082A (en) * | 1995-07-18 | 1998-01-13 | Moore Business Forms Inc | Thermally imaged colored baggage tags |
| GB2328215A (en) * | 1997-08-16 | 1999-02-17 | Simon Ellis | A printing ink used in the process of foil stamping |
| CN103042845A (en) * | 2013-01-15 | 2013-04-17 | 杭州兴甬复合材料有限公司 | Thermal transfer ribbon |
| CN104057733A (en) * | 2014-06-28 | 2014-09-24 | 周永生 | Full-resin thermal transfer printing ribbon suitable for various print substrates |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2585829B2 (en) | 1997-02-26 |
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