JPH03244335A - Rodent-proofing sheet - Google Patents
Rodent-proofing sheetInfo
- Publication number
- JPH03244335A JPH03244335A JP4222390A JP4222390A JPH03244335A JP H03244335 A JPH03244335 A JP H03244335A JP 4222390 A JP4222390 A JP 4222390A JP 4222390 A JP4222390 A JP 4222390A JP H03244335 A JPH03244335 A JP H03244335A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- rodent
- proofing
- terpenoid
- polybutylene terephthalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 24
- 150000003505 terpenes Chemical class 0.000 claims abstract description 22
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims description 13
- 229920005989 resin Polymers 0.000 abstract description 12
- 239000011347 resin Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 10
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 abstract description 8
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 abstract description 7
- 229940116411 terpineol Drugs 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 abstract description 6
- 229940087305 limonene Drugs 0.000 abstract description 2
- 235000001510 limonene Nutrition 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 230000000391 smoking effect Effects 0.000 abstract description 2
- 230000001846 repelling effect Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 description 15
- 230000002940 repellent Effects 0.000 description 15
- 241000283984 Rodentia Species 0.000 description 13
- 238000000465 moulding Methods 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 239000003094 microcapsule Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- YPHMISFOHDHNIV-FSZOTQKASA-N cycloheximide Chemical compound C1[C@@H](C)C[C@H](C)C(=O)[C@@H]1[C@H](O)CC1CC(=O)NC(=O)C1 YPHMISFOHDHNIV-FSZOTQKASA-N 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 241000700159 Rattus Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920011453 Hytrel® 4056 Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- GQVMHMFBVWSSPF-SOYUKNQTSA-N (4E,6E)-2,6-dimethylocta-2,4,6-triene Chemical compound C\C=C(/C)\C=C\C=C(C)C GQVMHMFBVWSSPF-SOYUKNQTSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 1
- ROKSAUSPJGWCSM-UHFFFAOYSA-N 2-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol Chemical compound C1C2C(C)(C)C1CC=C2CCO ROKSAUSPJGWCSM-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- 229940011037 anethole Drugs 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052916 barium silicate Inorganic materials 0.000 description 1
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- GQVMHMFBVWSSPF-UHFFFAOYSA-N cis-alloocimene Natural products CC=C(C)C=CC=C(C)C GQVMHMFBVWSSPF-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 150000002773 monoterpene derivatives Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229930006978 terpinene Natural products 0.000 description 1
- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、防鼠シートの改良に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to improvements in rat-proof sheets.
（従来の技術）
倉庫や市場、商店などにおける各種製品や食料品の保護
シートとしては、シート下の製品や食料品が判別できる
程度の透明性と、柔軟性、そして火災発生時には難燃性
の高いことが要求され、従来このような保護シートは軟
質ポリ塩化ビニル（ＰＶＣ）で成型されてきた。しかし
ながら、ＰＶＣシートは難燃性は充分である反面、燃焼
時に有害なハロゲンガスを発生するという欠点があつた
。(Conventional technology) Protective sheets for various products and food products in warehouses, markets, shops, etc. are transparent enough to allow the products and food products under the sheet to be identified, flexible, and flame-retardant in the event of a fire. Conventionally, such protective sheets have been molded from soft polyvinyl chloride (PVC). However, while PVC sheets have sufficient flame retardancy, they have the disadvantage of generating harmful halogen gas when burned.
また、このような保護シートは鼠による食害がしばしば
起こり、この対策として従来より公知の防鼠剤、例えば
シクロヘキシミドを練り込んでシート成型することが行
われているが、充分な防鼠効果を得るため多量のシクロ
へキシミドを添加するとシートの透明性が非常に悪くな
ってしまうという問題が生じている。In addition, such protective sheets often suffer from feeding damage by rats, and as a countermeasure to this problem, conventionally known rodent repellents, such as cycloheximide, have been kneaded into the sheet and molded into the sheet. Therefore, when a large amount of cycloheximide is added, a problem arises in that the transparency of the sheet becomes extremely poor.
（発明が解決しようとする課Ｍ）
以上の点に鑑みて、本発明は保護シートとして充分な難
燃性と非発煙性を有し、かつ透明性を良好に保ちながら
防鼠効果を大幅に向上させた防鼠シートを提供すること
を目的とする。(Problem M to be solved by the invention) In view of the above points, the present invention has sufficient flame retardancy and non-smoking properties as a protective sheet, and has a significant rat-proofing effect while maintaining good transparency. The purpose of the present invention is to provide an improved rat-proof sheet.
（課題を解決するための手段〉
本発明は即ち、少なくとも片側表面にテルペノイドモノ
マーおよび／またはその低重合体を含有することを特徴
とするポリブチレンテレフタレートを主成分とする防鼠
シートに関する。(Means for Solving the Problems) The present invention relates to a rodent-proofing sheet mainly composed of polybutylene terephthalate, which contains a terpenoid monomer and/or a low polymer thereof on at least one surface thereof.
本発明の防鼠シートは、防鼠剤としてテルペノイドモノ
マーおよび／またはその低重合体を使用して、これをポ
リブチレンテレフタレートを主成分とする樹脂に均一に
練り込みシート状に成型するか、あるいはポリブチレン
テレフタレートを主成分とするシートの表面に、前記防
鼠剤を含有するもう一枚のシートをラミネートさせるが
、または前記防鼠剤を含有する塗料をシート表面に塗布
するなどの方法により製造することができる。The rodent-proofing sheet of the present invention can be produced by using a terpenoid monomer and/or its low polymer as a rodent-proofing agent and uniformly kneading it into a resin whose main component is polybutylene terephthalate and forming it into a sheet. Manufactured by laminating another sheet containing the rodent repellent on the surface of a sheet containing polybutylene terephthalate as a main component, or by applying a paint containing the rodent repellent to the surface of the sheet. can do.
本発明においてシートを形成する樹脂は、透明性と難燃
性を兼ね備えたポリブチレンテレフタレートを使用し、
適宜これに他の熱可塑性樹脂や添加剤を樹脂分の５０重
量％以下の割合で添加することができる。ポリブチレン
テレフタレートとしては例えば大日本インキ株式会社製
の商品名プラナツクＢＴ−１５００等がある。また、添
加できる他の樹脂としては、ポリエステル系エラストマ
ー（具体的には東し・デュポン株式会社製 商品名ハイ
トレル４０５６）や、ポリウレタンエラストマー、ポリ
アミドエラストマー等が、シートの柔軟性を高める点か
ら特に好ましい。またこれらの熱可塑性樹脂や添加剤を
樹脂分の５０重量％を越えて配合するとシートの難燃性
が低下するので好ましくない。In the present invention, the resin forming the sheet is polybutylene terephthalate, which has both transparency and flame retardancy.
Other thermoplastic resins and additives may be added to this as appropriate in a proportion of 50% by weight or less based on the resin content. Examples of polybutylene terephthalate include Planac BT-1500, a trade name manufactured by Dainippon Ink Co., Ltd. In addition, as other resins that can be added, polyester elastomers (specifically, Hytrel 4056 manufactured by Toshi DuPont Co., Ltd.), polyurethane elastomers, polyamide elastomers, etc. are particularly preferred from the standpoint of increasing the flexibility of the sheet. . Furthermore, if these thermoplastic resins or additives are blended in an amount exceeding 50% by weight of the resin content, the flame retardance of the sheet will decrease, which is not preferable.
本発明においては防鼠剤としてテルペノイドモノマーお
よび／′ｉたはその低重合体を使用する。In the present invention, a terpenoid monomer and /'i or a low polymer thereof are used as a rodent repellent.
ここで、低重合体とはテルペノイド化合物以外のものと
の共重合体も含む。テルペノイドモノマーとは、植物の
水蒸気蒸留によって得られる植物精油または樹脂ゴム質
に含まれる一群の化合物であり、その本質はインプレン
２個またはそれ以上を含むもので炭素数１０個（Ｃ５Ｘ
２）のモノテルペノイド、炭素数１５個（Ｃｓ ｘ３）
のセスキテルペノイド、炭素数２０個（Ｃ５Ｘ４）のジ
テルペノイド、炭素数３０個（Ｃ，ｘ６）のトリテルペ
ノイドはいずれも使用可能である。これらのテルペノイ
ドモノマーは植物の芳香、精油成分であり、自然サイク
ルにまったく影響を与えない物質であり、従って人畜無
害である。Here, the term "low polymer" includes copolymers with substances other than terpenoid compounds. Terpenoid monomers are a group of compounds contained in plant essential oils or resin gums obtained by steam distillation of plants, and their essence is those containing two or more imprenes and 10 carbon atoms (C5X
2) monoterpenoid, carbon number 15 (Cs x3)
Sesquiterpenoids having 20 carbon atoms (C5×4), and triterpenoids having 30 carbon atoms (C,×6) can all be used. These terpenoid monomers are aromatic and essential oil components of plants, and are substances that do not affect the natural cycle at all, and are therefore harmless to humans and animals.
本発明に使用可能なテルペノイドモノマーの具体例とし
ては、β−ミルセン（ＣＩＯＨＩ６＞ 、アロオシメン
（ｃ ｒ。ＨＩ６＞、シトラール（Ｃ＋。ＨＩ６０）、
リナロール（ＣＩＯＨ１６０） 、リモネン（ＣｔｏＨ
３６）、ジペンテン（ＣＩＯＨ１６） 、テルピネン（
Ｃ８゜ＨＩ３）、テルピネオール（ＣＳ。ＨｔｓＯ）、
アネトール（ＣＩｏＨ＋２０ ） 、ピネン（Ｃ１０Ｈ
１６） 、ノポール（Ｃ１０８１９０）、カンフエン（
ＣＩＯＨＩ６）、ノビルアセテート（Ｃｓ、Ｈ２ｒ○２
）、インボルニルアセテート（Ｃ１ｘＨ２ｏ０２）等が
ある。Specific examples of terpenoid monomers that can be used in the present invention include β-myrcene (CIOHI6>, alloocimene (cr.HI6>), citral (C+.HI60),
Linalool (CIOH160), limonene (CtoH)
36), dipentene (CIOH16), terpinene (
C8°HI3), terpineol (CS.HtsO),
Anethole (CIoH+20), Pinene (C10H
16), Nopol (C108190), Can Huen (
CIOHI6), nobyl acetate (Cs, H2r○2
), inbornyl acetate (C1xH2o02), etc.
また、本発明においてはこれらのテルペノイドモノマー
の重量平均分子量１０００以下、重合度２〜７１体程度
の低重合体または低共重合体も使用できる。これらの低
重合体または低共重合体はモノマーに比べて防鼠効果が
より長期にわたって持続する。Further, in the present invention, low polymers or low copolymers of these terpenoid monomers having a weight average molecular weight of 1000 or less and a degree of polymerization of about 2 to 71 molecules can also be used. These low polymers or low copolymers maintain their rat-proofing effect for a longer period of time than monomers.
また、本発明においてはこれらのテルペノイドモノマー
および／またはその低重合体の他に、忌避効果の持続性
をさらに高める目的で保留剤を併用することかできる。Further, in the present invention, in addition to these terpenoid monomers and/or their low polymers, a retention agent may be used in combination for the purpose of further increasing the sustainability of the repellent effect.
保留剤としては、多価アルコール（グリセリン、プロピ
レンアルコール、ソルビトール、ポリエチレングリコー
ルなど〉、糖類−（ショ糖、乳糖、ブトｒ′７糖など）
、フタル酸ジエチル、安息香酸ベンジルなどがある。As retention agents, polyhydric alcohols (glycerin, propylene alcohol, sorbitol, polyethylene glycol, etc.), sugars (sucrose, lactose, butr'7 sugar, etc.)
, diethyl phthalate, and benzyl benzoate.
本発明においては上述のテルペノイドモノマーおよび／
またはその低重合体（または必要に応じて上記保留剤を
混合したもの）をそのまま添加することもできるが、そ
の効果をより長期にわたって持続させるために、シリカ
粉、炭酸カルシウム、ゼオライト等の無機多孔質粉体に
封入して粒径０゜１〜５００μｍ程度のマイクロカプセ
ルとして添加することもできる。In the present invention, the above-mentioned terpenoid monomer and/or
Alternatively, a low polymer thereof (or a mixture with the above-mentioned retention agent if necessary) can be added as is, but in order to maintain the effect for a longer period of time, inorganic porous materials such as silica powder, calcium carbonate, and zeolite may be added. It can also be added in the form of microcapsules with a particle size of about 0.1 to 500 μm by encapsulating it in a solid powder.
無機多孔質基体として使用できる無機材料を例示すると
、アルカリ土類金属炭酸塩（炭酸カルシウム、炭酸バリ
ウム、炭酸マグネシウムなど）、アルカリ土類金属珪酸
塩（珪酸カルシウム、珪酸バリウム、珪酸マグネシウム
など）、金属酸化物（シリカ、酸化コバルト、酸化ニッ
ケル）、金属炭酸塩（炭酸コバルト、炭酸ニッケル、塩
基性炭酸銅など〉、金属（コバルト、ニッケル、銅など
）などがあげられる。Examples of inorganic materials that can be used as the inorganic porous substrate include alkaline earth metal carbonates (calcium carbonate, barium carbonate, magnesium carbonate, etc.), alkaline earth metal silicates (calcium silicate, barium silicate, magnesium silicate, etc.), and metals. Examples include oxides (silica, cobalt oxide, nickel oxide), metal carbonates (cobalt carbonate, nickel carbonate, basic copper carbonate, etc.), and metals (cobalt, nickel, copper, etc.).
マイクロカプセルは、例えば界面反応法により形成され
た中空球状で２０〜１０００オンダストロームの微細孔
を有する無機多孔質壁材と、テルペノイドモノマーおよ
び／またはその低重合体とを混合した後に減圧し、ある
いは減圧しながら混合し、その後常圧に戻す方法で製造
することができる。また、多孔質化された中実球状の無
機多孔質基体に、上記テルペノイドを封入することによ
り製造することもできる。あるいはこれらの無機多孔質
基体とテルペノイド成分とを混合放置して、成分を基体
に含浸させることによっても製造できる。なお、テルペ
ノイド成分は酢酸エチルやアセトンなどの低沸点溶剤で
希釈して使用しても良い。Microcapsules are produced by, for example, mixing a hollow spherical inorganic porous wall material having micropores of 20 to 1000 Å formed by an interfacial reaction method with a terpenoid monomer and/or a low polymer thereof, and then reducing the pressure, or It can be produced by mixing under reduced pressure and then returning to normal pressure. It can also be produced by encapsulating the above-mentioned terpenoid in a porous solid spherical inorganic porous substrate. Alternatively, it can also be produced by mixing these inorganic porous substrates and terpenoid components and leaving them to stand, so that the substrate is impregnated with the components. Note that the terpenoid component may be used after being diluted with a low boiling point solvent such as ethyl acetate or acetone.
この場合は、テルペノイド成分を封入後に温度をかけて
溶剤を除去するようにする。In this case, the solvent is removed by applying heat after encapsulating the terpenoid component.
このようにしてマイクロカプセル化を行えば、テルペノ
イド成分の防鼠効果は、さらに長期に亘って持続される
。また、上記テルペノイド成分のうち七ツマ−のみを使
用する場合には、マイクロカプセル化によってその効果
の持続は大幅に改善される。If microencapsulation is performed in this manner, the rodent repellent effect of the terpenoid component will be maintained for a longer period of time. Furthermore, when only the terpenoid component is used, the duration of its effect is greatly improved by microencapsulation.
本発明においては上述のテルペノイドモノマーおよび／
またはその低重合体、あるいはこれらのマイクロカプセ
ルを、ポリブチレンテレフタレートを主成分とする樹脂
に均一に練り込みシート状に成型するか、あるいはポリ
ブチレンテレフタレートを主成分とするシートの表面に
、前記防鼠剤を含有するもう一枚のシートをラミネート
させるか、またはこれらの防鼠剤を含有する塗料をポリ
ブチレンテレフタレートを主成分とするシートの表面に
塗布するなどの方法により、得られるシートの少なくと
も片側表面にこれらの防鼠剤が含有されるようにする。In the present invention, the above-mentioned terpenoid monomer and/or
or a low polymer thereof, or these microcapsules are uniformly kneaded into a resin whose main component is polybutylene terephthalate and formed into a sheet, or the above-mentioned barrier is applied to the surface of a sheet whose main component is polybutylene terephthalate. At least one of the resulting sheets is laminated with another sheet containing a rodent repellent, or a paint containing these rodent repellents is applied to the surface of a sheet whose main component is polybutylene terephthalate. These rodent repellents should be contained on one side of the surface.
シート成型は、Ｔダイ成型法、インフレーションフィル
ム成型法等の通常の成型方法で行うことができる。Sheet molding can be performed by a normal molding method such as a T-die molding method or a blown film molding method.
なお、ポリブチレンテレフタレートは加工時に比較的高
い温度での加熱が必要な樹脂であるので、防鼠剤に対す
る加熱をできるだけ少なくするには、エチレン−＃酸ビ
ニル共重合体（ＥＶＡ）やエチレン−アクリル酸エチル
共重合体（ＥＥＡ）等の融点の低い樹脂にこれを添加し
てシート化した後、ポリブチレンテレフタレートを主成
分とするシートにラミネートする方法が適する。この場
合、得られるシートの難燃性を低下させないために、Ｅ
ＶＡ等をベースとする防鼠剤添加シートは厚さ３０μｍ
以下が望ましい。また、防鼠剤含有塗料をシート表面に
塗布する場合には、ポリブチレンテレフタレートシート
の透明性を損なわないように、アクリル系などの透明な
塗料を使用することが望ましい。Note that polybutylene terephthalate is a resin that requires heating at relatively high temperatures during processing, so in order to minimize the heating required for the rodent repellent, ethylene-vinyl acid copolymer (EVA) or ethylene-acrylic acid copolymer A suitable method is to add this to a resin with a low melting point such as ethyl acid copolymer (EEA), form a sheet, and then laminate it onto a sheet containing polybutylene terephthalate as the main component. In this case, in order not to reduce the flame retardancy of the sheet obtained, E
The rodent repellent additive sheet based on VA etc. has a thickness of 30 μm.
The following are desirable. Furthermore, when applying a rodent repellent-containing paint to the surface of the sheet, it is desirable to use a transparent paint such as acrylic paint so as not to impair the transparency of the polybutylene terephthalate sheet.
（作用〉
本発明の防鼠シートは、ポリブチレンテレフタレートと
主成分としているので難燃性に優れており、また防鼠剤
としてテルペノイドモノマーおよび２．／またはその低
重合体を使用しているので鼠忌避効果か高く、しかもシ
ートの透明度を良好に維持している。(Function) The rodent repellent sheet of the present invention has excellent flame retardancy because it has polybutylene terephthalate as its main component, and also uses terpenoid monomer and/or its low polymer as a rodent repellent. It has a high rat repellent effect and maintains good transparency of the sheet.
（実施例） 本発明の実施例について説明する。(Example) Examples of the present invention will be described.
実方１！Ｍｌ
ポリブチレンテレフタレート５０重量部とハイトレル４
０５６を５０重量部とからなる樹脂混和物に、テルピネ
オールをシリカに封入したマイクロカプセル（粒径１μ
ｍ程度）１０重量部を添加混線し、Ｔダイ成型により厚
さ５０μｍの防鼠シートを製造した。Actor 1! Ml 50 parts by weight of polybutylene terephthalate and Hytrel 4
Microcapsules (particle size 1μ) are made by encapsulating terpineol in silica and a resin mixture consisting of 056 and 50 parts by weight.
10 parts by weight (approximately 1.5 m) was added and mixed, and a rat-proofing sheet with a thickness of 50 μm was produced by T-die molding.
実施例２
ＥＶＡ （ＶＡ含量２０％＞１００重量部にテルピネオ
ールの２〜３量体を１０重量部添加した組成物をインフ
レーションフィルム成型法により厚さ２０μｍのシート
に成型した。これを厚さ５０μｍのポリブチレンテレフ
タレートシートにラミネーションにより貼り合わせて防
鼠シートを製造した。Example 2 A composition containing EVA (VA content > 100 parts by weight and 10 parts by weight of dimers of terpineol added) was molded into a sheet with a thickness of 20 μm by a blown film molding method. A rat-proofing sheet was manufactured by laminating it onto a polybutylene terephthalate sheet.
実施例３
テルピネオールおよびその２〜３量体をシリカに封入し
たマイクロカプセル（粒径１μｍ程度）をアクリル系バ
インダーに対して３０重量％添加した塗料を、ポリブチ
レンチレフタレ−）８０重量部とハイトレル４０５６を
２０重量部とからなる樹脂シート（厚さ５０μｍ）の片
側表面に約７μｍ厚さに塗布した。Example 3 A paint in which 30% by weight of microcapsules (particle size of about 1 μm) containing terpineol and its dimers encapsulated in silica was added to an acrylic binder was mixed with 80 parts by weight of polybutylene terephthalate. Hytrel 4056 was applied to a thickness of approximately 7 μm on one surface of a resin sheet (50 μm thick) containing 20 parts by weight.
これらの実施例により得られたシートを用いて、難燃性
試験（ＪＩＳ Ａ １３２２ 建築用材料の難燃
性試験方法に準拠）、透明性試験（目視によりシート下
の文字を判読できるか否か）、燃焼時発煙性試験（ＮＢ
Ｓ式スモークチャンバーによる指数）、防鼠性試験（得
られたシートで一重に包んださつま揚げを、ドブネズミ
を入れたケージ内に置き一週間後の食害状況を観察〉を
行った。Using the sheets obtained in these examples, a flame retardancy test (based on JIS A 1322 Flame retardant test method for building materials) and a transparency test (whether the letters under the sheet can be visually read or not) were conducted. ), combustion smoke test (NB
An index using an S-type smoke chamber) and a rat-proofing test (the fish cakes wrapped in a single layer of the obtained sheet were placed in a cage containing brown rats and the status of feeding damage was observed one week later) were conducted.
結果を表に示す。The results are shown in the table.
比較例１
比較として、軟質ＰＶＣ１００重量部にテルピネオール
の２〜３Ｊ１体を１０重量部添加した組成物をＴダイ成
型により厚さ５０μｍのシートに製造した。Comparative Example 1 As a comparison, a composition in which 10 parts by weight of 2-3J of terpineol was added to 100 parts by weight of soft PVC was manufactured into a sheet having a thickness of 50 μm by T-die molding.
比較例２
ポリエチレン１００重量部にテルピネオールの２〜３量
体を１０重量部添加した組成物をＴダイ成型により厚さ
５０μｍのシートに製造した。Comparative Example 2 A composition obtained by adding 10 parts by weight of terpineol dimers to 100 parts by weight of polyethylene was manufactured into a sheet with a thickness of 50 μm by T-die molding.
比較例３
ポリエチレン１００重量部に、テルピネオールの２〜３
量体を１０重量部と難燃剤（デカブロモジフェニルエー
テル）１０重量部とを添加した組成物をＴダイ成型によ
り厚さ５０μｍのシートに製造した。Comparative Example 3 2 to 3 parts of terpineol to 100 parts by weight of polyethylene
A composition containing 10 parts by weight of a polymer and 10 parts by weight of a flame retardant (decabromodiphenyl ether) was produced into a sheet with a thickness of 50 μm by T-die molding.
これらの比較例についても実施例１と同様に試験した。These comparative examples were also tested in the same manner as in Example 1.
結果を表に示す。The results are shown in the table.
（以下余白）
（発明の効果〉
以上、本発明の防鼠シートは、難燃性、低発煙性に優れ
ており、かつ透明性を良好に保ちながら鼠忌避効果を大
幅に向上させることができる。(The following is a blank space) (Effects of the invention) As described above, the rat-proofing sheet of the present invention has excellent flame retardancy and low smoke emission, and can greatly improve the rat-repelling effect while maintaining good transparency. .
Claims (1)
び／またはその低重合体を含有することを特徴とするポ
リブチレンテレフタレートを主成分とする防鼠シート。(1) A rat-proofing sheet mainly composed of polybutylene terephthalate, which contains a terpenoid monomer and/or a low polymer thereof on at least one surface thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4222390A JPH03244335A (en) | 1990-02-22 | 1990-02-22 | Rodent-proofing sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4222390A JPH03244335A (en) | 1990-02-22 | 1990-02-22 | Rodent-proofing sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03244335A true JPH03244335A (en) | 1991-10-31 |
Family
ID=12630038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4222390A Pending JPH03244335A (en) | 1990-02-22 | 1990-02-22 | Rodent-proofing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03244335A (en) |
-
1990
- 1990-02-22 JP JP4222390A patent/JPH03244335A/en active Pending
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