JPH03237140A - Vinyl chloride based foaming resin composition - Google Patents
Vinyl chloride based foaming resin compositionInfo
- Publication number
- JPH03237140A JPH03237140A JP3350090A JP3350090A JPH03237140A JP H03237140 A JPH03237140 A JP H03237140A JP 3350090 A JP3350090 A JP 3350090A JP 3350090 A JP3350090 A JP 3350090A JP H03237140 A JPH03237140 A JP H03237140A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- zinc
- weight
- pts
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000011342 resin composition Substances 0.000 title claims description 9
- 238000005187 foaming Methods 0.000 title abstract description 10
- -1 zinc modified hydrotalcite Chemical class 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 8
- 239000004088 foaming agent Substances 0.000 claims abstract description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 5
- 150000001342 alkaline earth metals Chemical group 0.000 claims abstract description 5
- 239000011256 inorganic filler Substances 0.000 claims abstract description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 14
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 10
- 239000004408 titanium dioxide Substances 0.000 abstract description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 7
- 239000011701 zinc Substances 0.000 abstract description 7
- 229910052725 zinc Inorganic materials 0.000 abstract description 7
- 239000003381 stabilizer Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 description 17
- 239000004014 plasticizer Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000945 filler Substances 0.000 description 9
- 239000006260 foam Substances 0.000 description 9
- 210000000497 foam cell Anatomy 0.000 description 9
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Chemical class 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 4
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 4
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 description 3
- 229960001545 hydrotalcite Drugs 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 2
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 2
- RIZUCYSQUWMQLX-UHFFFAOYSA-N 2,3-dimethylbenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C RIZUCYSQUWMQLX-UHFFFAOYSA-N 0.000 description 2
- RRKBRXPIJHVKIC-UHFFFAOYSA-N 2-(2-ethylhexyl)phenol Chemical compound CCCCC(CC)CC1=CC=CC=C1O RRKBRXPIJHVKIC-UHFFFAOYSA-N 0.000 description 2
- QJQIVZBVEBCTKR-UHFFFAOYSA-N 2-(3-methylbutyl)phenol Chemical compound CC(C)CCC1=CC=CC=C1O QJQIVZBVEBCTKR-UHFFFAOYSA-N 0.000 description 2
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 2
- FDIPWBUDOCPIMH-UHFFFAOYSA-N 2-decylphenol Chemical compound CCCCCCCCCCC1=CC=CC=C1O FDIPWBUDOCPIMH-UHFFFAOYSA-N 0.000 description 2
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 2
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- LVAGMBHLXLZJKZ-UHFFFAOYSA-N 2-o-decyl 1-o-octyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC LVAGMBHLXLZJKZ-UHFFFAOYSA-N 0.000 description 2
- WCRKLZYTQVZTMM-UHFFFAOYSA-N 2-octadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC=CC=C1O WCRKLZYTQVZTMM-UHFFFAOYSA-N 0.000 description 2
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 2
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 2
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 2
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000005643 Pelargonic acid Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000008043 acidic salts Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
- 235000019399 azodicarbonamide Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 229940005605 valeric acid Drugs 0.000 description 2
- 150000003739 xylenols Chemical class 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
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- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 229940043825 zinc carbonate Drugs 0.000 description 1
- 229960001939 zinc chloride Drugs 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229960001296 zinc oxide Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、充填剤配合塩化ビニル系発泡性樹脂組成物に
関し、詳しくは、塩化ビニル系樹脂に充填剤、亜鉛化合
物、亜鉛変性ハイドロタルサイト系化合物及び熱分解型
有機発泡剤を配合してなる、作業性及び加工性が良好で
あり、均一な発泡セルを有し、しかもプレートアウト性
の改良された、充填剤配合塩化ビニル系発泡性樹脂組成
物に関する。Detailed Description of the Invention [Industrial Application Field] The present invention relates to a filler-containing vinyl chloride foamable resin composition. A filler-containing vinyl chloride foaming product that is made by blending a polyamide-based compound and a pyrolyzable organic foaming agent, has good workability and processability, has uniform foam cells, and has improved plate-out properties. The present invention relates to a resin composition.
〔従来の技術及び発明が解決しようとする課題〕塩化ヒ
ビニル系樹脂、比較的安価であり、良好な物理的、化学
的性質を有しているため、発泡成型品としてレザー、壁
紙、クツション材などの家具製品、自動車用品等に適用
するには好適な材料である。[Prior art and problems to be solved by the invention] Hivinyl chloride resin is relatively inexpensive and has good physical and chemical properties, so it can be used as foam molded products such as leather, wallpaper, cushion materials, etc. This material is suitable for use in furniture products, automobile supplies, etc.
かかる発泡成型品は、一般に塩化ビニル樹脂に発泡剤、
安定剤等を加えてブレンドし、カレンダ、押出し、射出
成形法などにより成型するか、又はペーストレジンに発
泡剤、安定剤等を加えてブレンドし、紙や布などにコー
ティングした後、熱を加えてゲル化し成型することによ
って製造される。また、このような発泡成型品において
、特に、白色度を要求される場合あるいは不透明化しよ
うとする場合には、二酸化チタンあるいは炭酸カルシウ
ム等の充填剤が配合されることが多い。Such foam molded products generally contain a foaming agent and a vinyl chloride resin.
Stabilizers, etc. are added and blended and molded using calendering, extrusion, injection molding, etc., or foaming agents, stabilizers, etc. are added to paste resin and blended, coated on paper or cloth, and then heated. It is manufactured by gelling and molding. In addition, in such foam molded products, fillers such as titanium dioxide or calcium carbonate are often added, especially when whiteness is required or when opacity is desired.
しかしながら、塩化ビニル系樹脂に多量の充填剤を配合
して発泡成型品を製造する場合、高粘度となり作業性が
著しく低下するばかりでなく、発泡セル荒れが生しると
ともにプレートアウトが大きくなる等の欠点を生しるた
め、これらの欠点を解消することが強く望まれていた。However, when manufacturing foam molded products by blending a large amount of filler with vinyl chloride resin, the viscosity becomes high and workability is significantly reduced, and the foam cells become rough and plate-out increases. Therefore, it has been strongly desired to eliminate these drawbacks.
例えば、粘度を低下させるために可塑剤を多量に添加す
る方法が提案されているが、発泡セル荒れやプレートア
ウト性は改良することはできず、実用上は不満足なもの
であった。アクリル系樹脂やメタクリル系樹脂等のセル
調整剤を添加する方法も提案されているが、この方法で
は比較的均一な発泡セルが得られるものの、充填剤を多
量に配合した場合は効果が小さく、粘度を低下させる効
果及びプレートアウトを防止する効果は有していない。For example, a method has been proposed in which a large amount of plasticizer is added to reduce the viscosity, but this method cannot improve the roughness of the foam cells or the plate-out property, and is unsatisfactory in practice. A method of adding a cell conditioner such as acrylic resin or methacrylic resin has also been proposed, but although this method produces relatively uniform foamed cells, the effect is small if a large amount of filler is blended. It does not have the effect of reducing viscosity or preventing plate-out.
また、多量の可塑剤及びセル調整剤を併用する方法でも
その効果は小さく、特にプレートアウトを防止すること
ができなかった。Further, a method in which a large amount of plasticizer and cell conditioner are used in combination has a small effect, and in particular, plate-out cannot be prevented.
このため、安定剤の処方を変えることでこれらの課題を
解決しようとする試みもなされており、例えば、特開昭
６０−１９７７４４号公報にはハイドロタルサイト類を
添加することが提案されているが、ハイドロタルサイト
類を添加した場合には発泡セルの状態はある程度改良さ
れるものの、発泡初期の発泡倍率（立ち上がり）及び白
色度は未だ不充分であり、また、プレートアウト性の改
良も不満足なものであったため、さらに改良することが
要望されていた。Therefore, attempts have been made to solve these problems by changing the formulation of the stabilizer; for example, Japanese Patent Application Laid-open No. 197744/1983 proposes adding hydrotalcites. However, when hydrotalcites are added, although the condition of the foamed cells is improved to some extent, the expansion ratio (rise) and whiteness at the initial stage of foaming are still insufficient, and the improvement in plate-out properties is also unsatisfactory. As such, there was a demand for further improvements.
従って、本発明の目的は、作業性及び加工性が良好てあ
り、均一な発泡セルを有し、しかもプレートアウト性が
改良された、充填剤の配合された塩化ビニル系発泡性樹
脂組成物を提供することにある。Therefore, an object of the present invention is to provide a vinyl chloride foamable resin composition containing a filler, which has good workability and processability, has uniform foam cells, and has improved plate-out properties. It is about providing.
尚、特開昭６１−１７４２７０号公報には、亜鉛変性ハ
イドロタルサイト系化合物をハロゲン含有樹脂の着色抑
制剤として用いることが提案されているが、本発明の目
的である、充填剤を配合した発泡性樹脂組成物の問題点
をどのように解決するかについては全く示唆されていな
い。Incidentally, JP-A-61-174270 proposes the use of a zinc-modified hydrotalcite-based compound as a coloring inhibitor for a halogen-containing resin. There is no suggestion whatsoever as to how to solve the problems with foamable resin compositions.
本発明者等は、上記目的を達成すべく、鋭意検討を重ね
た結果、ハイドロタルサイト類のアルカリ土類金属成分
の一部を亜鉛で置き換えた、亜鉛変性ハイドロタルサイ
ト系化合物を亜鉛化合物と併用した場合には、充填剤を
配合した場合においても作業性及び加工性が良好であり
、均一な発泡セルを有し、しかもプレートアウト性が改
良されることを知見した。In order to achieve the above object, the present inventors have made extensive studies and have developed a zinc-modified hydrotalcite compound in which a part of the alkaline earth metal component of hydrotalcites is replaced with zinc. It has been found that when used in combination, even when a filler is added, workability and processability are good, uniform foam cells are formed, and plate-out properties are improved.
本発明は、上記知見に基づきなされたもので、塩化ビニ
ル系樹脂１００重量部に、（ａ）無機充填剤１０〜２５
０重量部、０）亜鉛化合物０．０１〜５重量部、（Ｃ）
次の一般式で表される亜鉛変性ハイドロタルサイト系化
合物０．０１〜５重量部及び（ｄ）熱分解型有機発泡剤
０． １〜１０重量部を配合してなる、塩化ビニル系発
泡性樹脂組成物を提供するものである。The present invention was made based on the above findings, and consists of adding (a) 10 to 25 parts by weight of an inorganic filler to 100 parts by weight of a vinyl chloride resin;
0 parts by weight, 0) 0.01 to 5 parts by weight of zinc compound, (C)
0.01 to 5 parts by weight of a zinc-modified hydrotalcite compound represented by the following general formula and (d) 0.01 to 5 parts by weight of a pyrolyzable organic blowing agent. The object of the present invention is to provide a vinyl chloride-based foamable resin composition containing 1 to 10 parts by weight.
Ｍ ｙＩ−Ｚｎ１、０＜ｙ２・ＡＩ、（ＯＨ） ｚ−（
ＣＯ３） Ｘ／Ｚ−ＩＲ）＋２０（式中、Ｍはアルカリ
土類金属を示し、ｘ、ｙ、、及びｙ２は各々下記式で表
される条件を満足する数を示し、ｍはＯまたは任意の正
数を示す。M yI-Zn1, 0<y2・AI, (OH) z-(
CO3) indicates a positive number.
０＜ｘ ≦ ０． ５ 、 ｙＩ ＋ １、０＜
ｙ２＝ Ｉ Ｘ 、 ！／Ｉ ≧ｙ２
−２０．３≦ｙ１〈１、Ｏ＜１、０＜ｙ２＜０．５）以
下、本発明の充填剤配合塩化ビニル系発泡性樹脂組成物
について詳述する。0<x≦0. 5, yI + 1, 0<
y2=IX,! /I ≧y2
-20.3≦y1<1, O<1, 0<y2<0.5) The filler-containing vinyl chloride foamable resin composition of the present invention will be described in detail below.
本発明において使用される塩化ビニル系樹脂としては、
塩化ビニル単独重合体、塩化ビニル−酢酸ビニル共重合
体、塩化ビニル−エチレン共重合体、塩化ビニル−エチ
レン−酢酸ビニル共重合体などの塩化ビニル系共重合体
；エチレン−酢酸ビニル共重合体又はエチレン−プロピ
レン系共重合体などに塩化ビニルをグラフト重合させた
塩化ビニル系グラフト共重合体などが挙げられ、その平
均重合度（ＪＩＳ Ｋ−６７２１）が６００〜１８０
０の範囲のものが好ましい。The vinyl chloride resin used in the present invention includes:
Vinyl chloride copolymers such as vinyl chloride homopolymer, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-ethylene-vinyl acetate copolymer; ethylene-vinyl acetate copolymer or Examples include vinyl chloride-based graft copolymers in which vinyl chloride is graft-polymerized to ethylene-propylene-based copolymers, etc., and the average degree of polymerization (JIS K-6721) is 600 to 180.
A value in the range of 0 is preferred.
本発明で用いられる無機充填剤としては、二酸化チタン
、炭酸カルシウム、硫酸カルシウム、亜硫酸カルシウム
、水酸化カルシウム、炭酸マグネシウム、硫酸バリウム
、水酸化アルミニウム、りルク、アスヘスト、カオリン
、クレー及びシリカ等があげられ、特に、二酸化チタン
及び炭酸カルシウムを用いた場合に本発明の効果が著し
い。Examples of the inorganic fillers used in the present invention include titanium dioxide, calcium carbonate, calcium sulfate, calcium sulfite, calcium hydroxide, magnesium carbonate, barium sulfate, aluminum hydroxide, liluc, ashest, kaolin, clay, and silica. In particular, the effects of the present invention are remarkable when titanium dioxide and calcium carbonate are used.
これらの無機充填剤の配合量は、樹脂１００重量部に対
して、１０〜２５０重量部、好ましくは２０〜２００重
量部である。The blending amount of these inorganic fillers is 10 to 250 parts by weight, preferably 20 to 200 parts by weight, based on 100 parts by weight of the resin.
本発明で用いられる亜鉛化合物としては、亜鉛の有機酸
塩及び無機亜鉛化合物が包含される。The zinc compound used in the present invention includes organic acid salts of zinc and inorganic zinc compounds.
亜鉛の有機酸塩を構成する有機酸としては、例えば、酢
酸、プロピオン酸、酪酸、吉草酸、カプロン酸、エナン
ト酸、カプリル酸、２−エチルヘキシル酸、ペラルゴン
酸、カプリン酸、ネオデカン酸、ウンデカン酸、ラウリ
ン酸、トリデカン酸、ミリスチン酸、パルミチン酸、イ
ソステアリン酸、ステアリン酸、１２−ヒドロキシステ
アリン酸、ヘヘン酸、モンタン酸、アクリル酸、メタク
リル酸、オレイン酸、エライジン酸、リノール酸すルン
酸、チオグリコール酸、メルカプトプロピオン酸、オク
チルメルカプトプロピオン酸、安息香酸、モノクロル安
息香酸、Ｐ−第三ブチル安息香酸、トルイル酸、ジメチ
ル安息香酸、エチル安息香酸、サリチル酸、ｐ−第三オ
クチルサリチル酸などのカルボン酸及び例えば、フェノ
ール、クレゾール、キシレノール、エチルフェノール、
イソプロピルフェノール、ｎ−ブチルフェノール、第三
ブチルフェノール、イソアミルフェノール、イソオクチ
ルフェノール、２−エチルヘキシルフェノール、第三オ
クチルフェノール、ノニルフェノール、ジノニルフェノ
ール、混合モノ・ジノニルフェノール、デシルフェノー
ル、ドデシルフェノール、オクタデシルフェノール、シ
クロヘキシルフェノール、フェニルフェノール等のフェ
ノール類があげられ、これらは正塩、塩基性塩あるいは
酸性塩であってもよい。Examples of organic acids constituting the organic acid salt of zinc include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, 2-ethylhexylic acid, pelargonic acid, capric acid, neodecanoic acid, and undecanoic acid. , lauric acid, tridecanoic acid, myristic acid, palmitic acid, isostearic acid, stearic acid, 12-hydroxystearic acid, hehenic acid, montanic acid, acrylic acid, methacrylic acid, oleic acid, elaidic acid, linoleic acid, sulonic acid, thio Carboxylic acids such as glycolic acid, mercaptopropionic acid, octylmercaptopropionic acid, benzoic acid, monochlorobenzoic acid, p-tert-butylbenzoic acid, toluic acid, dimethylbenzoic acid, ethylbenzoic acid, salicylic acid, p-tert-octylsalicylic acid and, for example, phenol, cresol, xylenol, ethylphenol,
Isopropylphenol, n-butylphenol, tertiary-butylphenol, isoamylphenol, isooctylphenol, 2-ethylhexylphenol, tertiary-octylphenol, nonylphenol, dinonylphenol, mixed mono-dinonylphenol, decylphenol, dodecylphenol, octadecylphenol, cyclohexylphenol, phenyl Examples include phenols such as phenol, and these may be in the form of normal salts, basic salts, or acidic salts.
また、無機亜鉛化合物としては、酸化亜鉛、水酸化亜鉛
、塩化亜鉛、炭酸亜鉛、硫酸亜鉛等があげられる。Further, examples of inorganic zinc compounds include zinc oxide, zinc hydroxide, zinc chloride, zinc carbonate, zinc sulfate, and the like.
これらの亜鉛化合物の添加量は、樹脂１００重量部に対
して、０．０１〜５重量部、好ましくは０．１〜３重量
部である。The amount of these zinc compounds added is 0.01 to 5 parts by weight, preferably 0.1 to 3 parts by weight, based on 100 parts by weight of the resin.
本発明で用いられる前記−数式で表される亜鉛変性ハイ
ドロタルサイト系化合物において、Ｍで表されるアルカ
リ土類金属としては、マグネシウム、カルシウム、バリ
ウム及びストロンチウムがあげられ、特に、Ｍがマグネ
シウムであるものが好ましい。また、Ｍとして上記アル
カリ土類金属の二種以上を用いてもよい。In the zinc-modified hydrotalcite compound represented by the above formula used in the present invention, examples of the alkaline earth metal represented by M include magnesium, calcium, barium, and strontium, and in particular, when M is magnesium, Something is preferable. Furthermore, as M, two or more of the above alkaline earth metals may be used.
また、前記−数式における、Ｘ、Ｖ＋及びｙ２は亜鉛変
性ハイドロタルサイト系化合物における各金属成分の比
率を表し、本発明の目的を奏するためには各金属成分の
比率が前記の範囲内にあることが必要であるが、好まし
くは、Ｘが０． ２≦Ｘ≦０．４の範囲にあり、ｙｌ及
びｙ２が各々０．３５≦ｙ、≦０．７５．０．０５≦ｙ
２≦０．４の範囲から選ばれる。また、ｍは結合する結
晶水の量を表し０または任意の正数を示すが、一般には
２以下であることが好ましい。Furthermore, in the formula -, X, V+, and y2 represent the ratio of each metal component in the zinc-modified hydrotalcite compound, and in order to achieve the purpose of the present invention, the ratio of each metal component must be within the above range. However, preferably, X is 0. 2≦X≦0.4, yl and y2 are each 0.35≦y, ≦0.75.0.05≦y
Selected from the range of 2≦0.4. Further, m represents the amount of crystal water to be bound and is 0 or any positive number, but is generally preferably 2 or less.
更に、本発明で用いられる亜鉛変性ハイドロタルサイト
系化合物は、その平均粒子径が１０μ以下であり、その
ＢＥＴ比表面積が約３０ｒｒｆ／ｇ以下であることが好
ましい。また、本発明で用いられる亜鉛変性ハイドロタ
ルサイト系化合物は、樹脂との相溶性、分散性等を改良
するために、高級脂肪酸、界面活性剤、シラン系または
チタネート系カップリング剤等で表面処理されていても
よい。Further, the zinc-modified hydrotalcite compound used in the present invention preferably has an average particle diameter of 10 μm or less and a BET specific surface area of about 30 rrf/g or less. In addition, the zinc-modified hydrotalcite compound used in the present invention is surface-treated with higher fatty acids, surfactants, silane-based or titanate-based coupling agents, etc. in order to improve compatibility with resins, dispersibility, etc. may have been done.
本発明で用いられる亜鉛変性ハイドロタルサイト系化合
物は、公知の化合物であり、例えば、特公昭４６−２２
８０号公報、特公昭４７−３２１９８号公報、特公昭５
０−３００３９公報、特公昭４Ｂ−２９４７７号公報及
び特公昭５１−２９１２９号公報等に記載された公知の
製法に準じて容易に製造することが可能であり、また、
市販品（例えば、アルカマイチー４：協和化学工業）を
用いることもできる。The zinc-modified hydrotalcite compound used in the present invention is a known compound, for example, Japanese Patent Publication No. 46-22
Publication No. 80, Special Publication No. 47-32198, Special Publication No. 5
It can be easily produced according to the known manufacturing method described in Japanese Patent Publication No. 0-30039, Japanese Patent Publication No. 4B-29477, Japanese Patent Publication No. 51-29129, etc., and
Commercially available products (for example, Alkamaichi 4: Kyowa Kagaku Kogyo) can also be used.
本発明で用いられる亜鉛変性ハイドロタルサイト系化合
物の具体例としては、次に示すような化合物があげられ
る。Specific examples of the zinc-modified hydrotalcite compounds used in the present invention include the following compounds.
Ｍｇｏ、 ３１’ｚｎＯ，３−ＡＩｏ、 ３ｚ−（０）
１） ｚ−（ＣＯ３） ｏ、 ＋ ６・０．２Ｈ２ＯＭ
ｇｏ、 ４Ｓ”ｚｎＯ，２３，ＡＩｏ、 ：＋ｚ、（Ｏ
Ｈ）ｚ・（ＣＯｉ）ｏ、 ＋ｂＭｇｏ、 ４ｓ４ｎｏ、
＋５４１ｏ、 ｚｓ・（ＯＲ） ｚ・（Ｃ（ｈ） １
１．１？Ｍｇｏ、 ４．Ｚｎｏ、 ｚ・Ａｌｏ、 ３ｚ
・（Ｏｆ（） ｚ・（ＣＯ３） ｏ。Mgo, 31'znO,3-AIo, 3z-(0)
1) z-(CO3) o, + 6・0.2H2OM
go, 4S”znO,23,AIo, :+z,(O
H)z・(COi)o, +bMgo, 4s4no,
+541o, zs・(OR) z・(C(h) 1
1.1? Mgo, 4. Zno, z・Alo, 3z
・(Of() z・(CO3) o.
Ｍｇｏ、 Ｓ’Ｚｎｏ、 Ｉ ｔ・Ａｌｏ、 ３３ ・
（ＯＨ） ｚ 。（ＣＯ３） ｏ、 ＋ ｂｓ・０．４
５Ｈ２ＯＭｇｏ、 ｓ・Ｚｎｏ、 ＋５４１ｏ、 ：＋
ｚ・（ＯＨ）ｚ、（ｃｏ：＋）ｏ、 ＋ｂＭｇｏ、 、
’Ｚｎｏ、 ｚ・Ａｌｏ、 ３・（ＯＨ） ｚ・（ＣＯ
３） ｏ。Mgo, S'Zno, It・Alo, 33・
(OH)z. (CO3) o, + bs・0.4
5H2OMgo, s・Zno, +541o, :+
z・(OH)z, (co:+)o, +bMgo, ,
'Zno, z・Alo, 3・(OH) z・(CO
3) o.
Ｍｇｏ、 ｓ ’ｚｎＯ，ｚ、Ａ Ｉｏ、 ：＋ ・（
ＯＨ） ｚ、（Ｃ（ｈ） ｏ、 ＋ 、・０．５２Ｈ２
ＯＭｇｏ、 Ｓ’Ｚｎｏ、 ｚ、・Ａｌｏ、 ｚｓｉＯ
Ｈ）ｚ・（ＣＯｘ）ｏ、 ＋ｚｓＭｇｏ、 ｓ＋４ｎｏ
、 １４１ｏ、 ：＋ｚ・（ＯＨ）２．（ＣＯ：＋）ｏ
。Mgo, s'znO,z, A Io, :+ ・(
OH) z, (C(h) o, +, ・0.52H2
OMgo, S'Zno, z,・Alo, zsiO
H)z・(COx)o, +zsMgo, s+4no
, 141o, :+z・(OH)2. (CO:+)o
.
Ｍｇｏ、 ５ｚ４ｎｏ、 ＋ ｉ、４１ｏ、 ３ｚ・（
ＯＨ） ｚ・（ＣＯ：＋） ｏ、 １６・０．５Ｈ２Ｏ
Ｍｇｏ、 ５．’Ｚｎｏ、 ＋５４１ｏ、 ｚ・（ＯＨ
） ｚ・（Ｃ（ｈ） ｏ。Mgo, 5z4no, +i, 41o, 3z・(
OH) z・(CO:+) o, 16・0.5H2O
Mgo, 5. 'Zno, +541o, z・(OH
) z・(C(h) o.
Ｍｇｏ、 ｂ４ｎｏ、 ＋ ４・Ａｌｏ、 ｚｂ、（Ｏ
Ｈ） ｚ、（ＣＯ３） ｏ、 ＋ ｘＭｇｏ６４ｎｏ、
＋、Ａ１ｏ、 ｚａ・（０）１）ｚｉｃｏ：＋）ｏ、
＋ｚＭｇｏ、 ｈ・Ｚｎｏ、 ｚ４１ｏ、 ｚ・（Ｏ
Ｈ） ｚ・（Ｃｏｔ） ｏ。Mgo, b4no, + 4・Alo, zb, (O
H) z, (CO3) o, + xMgo64no,
+, A1o, za・(0)1)zico:+)o,
+zMgo, h・Zno, z41o, z・(O
H) z・(Cot) o.
Ｍｇｏ、 ４’Ｃａｏ、 ＋４ｎｏ、 ＋、Ａ１ｏ、
ｉｚ、（ＯＨ）ｚｉｃｏ：＋）ｏ、 ＋ｂＭｇｏ、 ：
＋・Ｃａａ、 ｚ４ｎｏ、 ｚ・Ａｌｏ、 ３・（ＯＨ
） ｚ・（ＣＯ３） Ｏ，Ｉｓこれらの亜鉛変性ハイド
ロタルサイト系化合物の添加量は、樹脂１００重量部に
対して、０．０１〜５重量部、好ましくは００１〜３重
量部である。Mgo, 4'Cao, +4no, +, A1o,
iz, (OH)zico:+)o, +bMgo, :
+・Caa, z4no, z・Alo, 3・(OH
) z.(CO3) O, Is The amount of these zinc-modified hydrotalcite compounds added is 0.01 to 5 parts by weight, preferably 0.01 to 3 parts by weight, based on 100 parts by weight of the resin.
さらに、本発明で使用される熱分解型有機発泡剤として
は、例えばＮ、Ｎ’ −ジニトロペンタメチレンテトラ
ミン、アゾジカルボンアミド、ｐＰ′−ビス（ヘンゼン
スルホニルヒドラジト）エーテル、ｐ−トルエンスルホ
ニルヒドラジド等があげられる。Further, examples of the thermally decomposable organic blowing agent used in the present invention include N,N'-dinitropentamethylenetetramine, azodicarbonamide, pP'-bis(henzensulfonylhydrazito)ether, p-toluenesulfonylhydrazide. etc. can be mentioned.
これらの発泡剤の中で、アゾジカルボンアミド（ＡＤＣ
Ａ）を用いた発泡体は耐熱性及び耐光性に優れ、また、
ｐ、ｐ’−ビス（ヘンゼンスルホニルヒドラジド）エー
テル（ＯＢＳＨ）は、製品の白色性及び色目の安定性に
優れ、また比較的発泡温度が低い利点を有しているが、
従来、これらの発泡剤を用いた場合には耐熱性が劣る欠
点があった。しかし、本発明の組成物は、前述のように
作業性及び加工性が良好であり、均一な発泡セルを有し
、しかもプレートアウト性が改良されるばかりでなく、
加工時の耐熱性（経時着色）を改善する効果が著しく大
きいので、特にこれらの発泡剤を用いた場合に適してい
る。Among these blowing agents, azodicarbonamide (ADC
The foam using A) has excellent heat resistance and light resistance, and
p,p'-bis(hensensulfonyl hydrazide) ether (OBSH) has excellent product whiteness and color stability, and has the advantage of a relatively low foaming temperature.
Conventionally, when these blowing agents were used, they had the disadvantage of poor heat resistance. However, as mentioned above, the composition of the present invention not only has good workability and processability, has uniform foam cells, and has improved plate-out properties;
Since the effect of improving heat resistance during processing (coloration over time) is extremely large, it is particularly suitable when these foaming agents are used.
本発明の組成物は、通常可塑剤が配合された軟質成型品
として用いられる場合が多く、かかる可塑剤としては、
塩化ビニル系樹脂に用いられる通常の可塑剤ならば特に
制限されるものではない。The composition of the present invention is often used as a soft molded product containing a plasticizer, and the plasticizer includes:
There are no particular restrictions on the plasticizer as long as it is a common plasticizer used for vinyl chloride resins.
例えば、フタル酸ジ−ｎ−ブチル、フタル酸ジ−ｎ−オ
クチル、フタル酸ジ〜２−エチルヘキシル、フタル酸ジ
イソオクチル、フタル酸オクチルデシル、フタル酸ジイ
ソデシル、フタル酸ジＣ１〜。For example, di-n-butyl phthalate, di-n-octyl phthalate, di~2-ethylhexyl phthalate, diisooctyl phthalate, octyldecyl phthalate, diisodecyl phthalate, diC1~ phthalate.
混合アルキル、フタル酸ブチルベンジル、イソフタル酸
ジー２−エチルへキシル等のフタル酸系可塑剤、アジピ
ン酸ジー２−エチルヘキシル、アジピン酸ジイソデシル
、アゼライン酸ジー２−エチルヘキシル、セバシン酸ジ
プチル、セパシン酸ジ２−エチルヘキシル等の脂肪酸エ
ステル系可塑剤、リン酸トリブチル、リン酸トリー２−
エチルへキシル、リン酸トリクレジル、リン酸トリキシ
リル等のリン酸エステル系可塑剤、塩素化パラフィン、
塩素化脂肪酸エステル等の塩素系可塑剤、エポキシ系可
塑剤、ポリエステル系可塑剤等があげられ、これらの一
種又は二種以上を混合して使用することができる。Mixed alkyl, phthalic acid plasticizers such as butylbenzyl phthalate, di-2-ethylhexyl isophthalate, di-2-ethylhexyl adipate, diisodecyl adipate, di-2-ethylhexyl azelaate, diptyl sebacate, di-2-sepacate -Fatty acid ester plasticizers such as ethylhexyl, tributyl phosphate, triphosphate 2-
Phosphate ester plasticizers such as ethylhexyl, tricresyl phosphate, tricylyl phosphate, chlorinated paraffin,
Examples include chlorine plasticizers such as chlorinated fatty acid esters, epoxy plasticizers, polyester plasticizers, etc., and these can be used alone or in combination of two or more.
これらの可塑剤の添加量は、樹脂１００重量部に対して
２０−１５０重量部、特に３０〜１００重量部とするの
が好ましい。The amount of these plasticizers added is preferably 20 to 150 parts by weight, particularly 30 to 100 parts by weight, per 100 parts by weight of the resin.
また、本発明の組成物に対して、Ｉｏ族またはＩｌａ族
金属の有機酸塩（通常の金属石ケン類等）の併用が行わ
れてもよいことは勿論である。この場合の金属成分の例
としてはＬｔ＋ Ｎａ、 Ｋ１Ｍｇ＋ ＣａＢａ、 Ｓ
ｒ等があげられ、有機酸残基としては 次のカルボン酸
及びフェノールの残基があげられる。Furthermore, it goes without saying that organic acid salts of group Io or group Ila metals (common metal soaps, etc.) may be used in combination with the composition of the present invention. Examples of metal components in this case are Lt+ Na, K1Mg+ CaBa, S
Examples of organic acid residues include the following carboxylic acid and phenol residues.
カルボン酸の例としては、酢酸、プロピオン酸、酪酸、
吉草酸、カプロン酸、エナント酸、カプリル酸、ネオ酸
、２−エチルヘキシル酸、ペラルゴン酸、カプリン酸、
ウンデカン酸、ラウリン酸、トリデカン酸、ミリスチン
酸、パルミチン酸、イソステアリン酸、ステアリン酸、
１２−ヒドロキシステアリン酸、ベヘン酸、モンタン酸
、安息香酸、モノクロル安息香酸、ｐ−第三ブチル安息
香酸、ジメチルヒドロキシ安息香酸、３，５−第三ブチ
ル−４−ヒドロキシ安息香酸、トルイル酸、ジメチル安
息香酸、エチル安息香酸、クミン酸、ｎ−プロピル安息
香酸、アミノ安息香酸、Ｎ、 Ｎ−ジメチル安息香酸、
アセトキシ安息香酸、サリチル酸、Ｐ−第三オクチルサ
リチル酸、オレイン酸、エライジン酸、リノール酸、リ
ルン酸、チオグリコール酸、メルカプトプロピオン酸、
オクチルメルカプトプロピオン酸なとのｍ個カルボン酸
、シュウ酸、マロン酸、コハク酸、グルタル酸、アジピ
ン酸、ピメリン酸、スヘリン酸、アゼライン酸、セハチ
ン酸、フタル酸、イソフタル酸、テレフタル酸、オキシ
フタル酸、クロルフタル酸、アミノフタル酸、マレイン
酸、フマール酸、シトラゴン酸、メタコン酸、イタコン
酸、アコニツト酸、チオジプロピオン酸等の二価カルボ
ン酸のモノエステル又はモノアマイド化合物、ヘミメリ
ント酸、トリメリット酸、メロファン酸、ピロメリット
酸、メリント酸等の三価又は四価カルボン酸のジ又はト
リエステル化合物があげられる。Examples of carboxylic acids include acetic acid, propionic acid, butyric acid,
Valeric acid, caproic acid, enanthic acid, caprylic acid, neoacid, 2-ethylhexylic acid, pelargonic acid, capric acid,
undecanoic acid, lauric acid, tridecanoic acid, myristic acid, palmitic acid, isostearic acid, stearic acid,
12-hydroxystearic acid, behenic acid, montanic acid, benzoic acid, monochlorobenzoic acid, p-tert-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-tert-butyl-4-hydroxybenzoic acid, toluic acid, dimethyl Benzoic acid, ethylbenzoic acid, cumic acid, n-propylbenzoic acid, aminobenzoic acid, N, N-dimethylbenzoic acid,
Acetoxybenzoic acid, salicylic acid, P-tertiary octylsalicylic acid, oleic acid, elaidic acid, linoleic acid, linoleic acid, thioglycolic acid, mercaptopropionic acid,
Octylmercaptopropionic acid and other m-carboxylic acids, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, schelic acid, azelaic acid, cehatic acid, phthalic acid, isophthalic acid, terephthalic acid, oxyphthalic acid , monoesters or monoamide compounds of dicarboxylic acids such as chlorophthalic acid, aminophthalic acid, maleic acid, fumaric acid, citragonic acid, methaconic acid, itaconic acid, aconitic acid, thiodipropionic acid, hemimellinate acid, trimellitic acid, merophane Examples thereof include di- or triester compounds of trivalent or tetravalent carboxylic acids such as pyromellitic acid and mellitic acid.
またフェノール類としては、例えば第三ブチルフェノー
ル、ノニルフェノール、ジノニルフェノ−／Ｌ／、ン昆
合モノ・ジノニルフェノールキシルフェノール、フェニ
ルフェノール、オクチルフェノール、フェノール、クレ
ゾール、キシレノール、ｎ−ブチルフェノール、イソア
ミルフェノール、エチルフェノール、イソプロピルフェ
ノール、イソオクチルフェノール、２−エチルヘキシル
フェノール、第三ノニルフェノール、デシルフェノール
、第三オクチルフェノール、イソヘキシルフェノール、
オクタデシルフェノール、ジイソブチルフェノール、メ
チルプロピルフェノール、シア砧ルフェノール、メチル
イソヘキシルフェノール、メチル第三オクチルフェノー
ル等があげられる。Examples of phenols include tert-butylphenol, nonylphenol, dinonylphenol/L/, mono-dinonylphenol, phenylphenol, octylphenol, phenol, cresol, xylenol, n-butylphenol, isoamylphenol, ethylphenol, Isopropylphenol, isooctylphenol, 2-ethylhexylphenol, tertiary nonylphenol, decylphenol, tertiary octylphenol, isohexylphenol,
Examples include octadecylphenol, diisobutylphenol, methylpropylphenol, siakinitolphenol, methylisohexylphenol, and methyltertiary-octylphenol.
また、これらの金属有機酸塩は、正塩、酸性塩あるいは
塩基性塩のいずれでもよく、さらには、いわゆる過塩基
性塩であってもよい。Further, these metal organic acid salts may be normal salts, acidic salts or basic salts, and may also be so-called overbased salts.
これらの金属有機酸塩の添加量は、樹脂１００重量部に
対して、０．０１〜１０重量部、特に０、１〜５重量部
とするのが好ましい。The amount of these metal organic acid salts added is preferably 0.01 to 10 parts by weight, particularly 0.1 to 5 parts by weight, based on 100 parts by weight of the resin.
本発明の組成物に、さらに有機ホスファイト化合物及び
／またはエポキシ化合物を併用することによりその熱安
定性を更に改善することができる。By further using an organic phosphite compound and/or an epoxy compound in the composition of the present invention, its thermal stability can be further improved.
上記有機ホスファイト化合物としては、トリブチルホス
ファイト、トリ （２−エチルヘキシル）ホスファイト
、トリデシルホスファイト、トリラウリルホスファイト
、ジブチルアシドホスファイト、ジラウリルアシドホス
ファイト、２−エチルへキシルジフェニルホスファイト
、フエニルジイソデシルホスファイト、ジフェニルデシ
ルホスファイト、トリフェニルホスファイト、トリス（
ノニルフェニル）ホスファイト、トリス（モノ／ジ混合
ノニルフェニル）ホスファイト、ジフェニルアシドホス
ファイト、ジステアリルペンタエリスリトールジホスフ
ァイト、ジイソデシルペンタエリスリトールジホスファ
イト、フェニル−４．４′イソプロピリデンジフエノー
ル・ペンタエリスリトールジホスファイト、ヘキサ（ト
リデシル）１、１．３−トリス（２“−メチル−５′−
第三ブチル−４゛−ヒドロキシフェニル）ブタントリホ
スファイト、テトラ（Ｃ，２〜ＣＩＳ混合アルキル）−
４．４“−イソプロピリデンジフェニルジホスファイト
、テトラ（トリデシル）−４，４。The above organic phosphite compounds include tributyl phosphite, tri(2-ethylhexyl) phosphite, tridecyl phosphite, trilauryl phosphite, dibutyl acid phosphite, dilauryl acid phosphite, 2-ethylhexyl diphenyl phosphite. , phenyldiisodecyl phosphite, diphenyldecyl phosphite, triphenyl phosphite, tris(
nonylphenyl) phosphite, tris(mono/dimixed nonylphenyl) phosphite, diphenyl acid phosphite, distearyl pentaerythritol diphosphite, diisodecyl pentaerythritol diphosphite, phenyl-4.4' isopropylidene diphenol penta Erythritol diphosphite, hexa(tridecyl)1,1,3-tris(2"-methyl-5'-
Tert-butyl-4'-hydroxyphenyl)butane triphosphite, tetra(C,2-CIS mixed alkyl)-
4.4"-isopropylidene diphenyl diphosphite, tetra(tridecyl)-4,4.
ｎ−ブチリデンビス（２−第三ブチル−５−メチルフェ
ノール）ジホスファイト、水素化−４。n-Butylidenebis(2-tert-butyl-5-methylphenol) diphosphite, hydrogenated-4.
４゛ −イソプロピリデンジフェノールポリホスファイ
ト、ジフェニル・ビス〔４．４’ −ｎ−ブチリデンビ
ス（２−第三ブチル−５−メチルフェノール）］チオジ
ェタノールジホスファイト、ビス（オクチルフェニル）
・ビス（４、４’ −ｎ−ブチリデンビス（２−第三ブ
チル−５−メチルフェノール）＞１．６−ヘキサンジオ
ールジホスファイト、トリス（２，４−ジ−第三ブチル
フェニル）ホスファイト等があげられる。4′-isopropylidene diphenol polyphosphite, diphenyl bis[4.4′-n-butylidene bis(2-tert-butyl-5-methylphenol)]thioditanol diphosphite, bis(octylphenyl)
・Bis(4,4'-n-butylidenebis(2-tert-butyl-5-methylphenol)>1,6-hexanediol diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, etc. can be given.
これらの有機ホスファイト化合物の添加量は、樹脂１０
０重量部に対して、０，０１〜５重量部、特に０．１〜
３重量部とするのが好ましい。The amount of these organic phosphite compounds added is 10% of the resin.
0.01 to 5 parts by weight, especially 0.1 to 5 parts by weight relative to 0 parts by weight
The amount is preferably 3 parts by weight.
また、上記エポキシ化合物としては、エポキシ化大豆油
、エポキシ化アマニ油、エポキシ化牛脂油、エポキシ化
魚油、エポキシ化トール油脂肪酸エステル、エポキシ化
ヒマシ油、エポキシ化すフラワー油、エポキシ化ポリブ
タジェン、エポキシ化アマニ油脂肪酸ブチル、エポキシ
化ステアリン酸メチル、−フチル，ー２ーエチルヘキシ
ル。In addition, the above-mentioned epoxy compounds include epoxidized soybean oil, epoxidized linseed oil, epoxidized beef tallow oil, epoxidized fish oil, epoxidized tall oil fatty acid ester, epoxidized castor oil, epoxidized flower oil, epoxidized polybutadiene, and epoxidized Butyl linseed oil fatty acid, epoxidized methyl stearate, -phthyl, -2-ethylhexyl.
ステアリル、トリス（エポキシプロピル）イソシアヌレ
ート、３−（２−キセノキン）−１，２エポキシプロパ
ン、ビスフェノールＡジグリシジルエーテル、ビニルシ
クロヘキセンジエボキサイド、ジシクロペンタジエンジ
エボキサイド、３４−エポキシシクロへキンルー６−メ
チルエポキンシクロヘキサンカルポキシレート等があげ
られる。Stearyl, tris(epoxypropyl) isocyanurate, 3-(2-xenoquine)-1,2 epoxypropane, bisphenol A diglycidyl ether, vinylcyclohexene dieboxide, dicyclopentadiene dieboxide, 34-epoxycyclohexene Ru6 -Methylepokine cyclohexanecarpoxylate and the like.
上記のエポキシ化合物の添加量は、樹脂１００重量部に
対して、０．０１〜１０重量部、特に０．５〜５重量部
とするのが好ましい。The amount of the epoxy compound added is preferably 0.01 to 10 parts by weight, particularly 0.5 to 5 parts by weight, based on 100 parts by weight of the resin.
本発明のＵ酸物には、成形品の物理的特性を阻害しない
範囲で、着色剤、難燃剤、酸化防止剤、帯電防止剤、光
安定剤、防黴剤等を適宜添加しても良い。Coloring agents, flame retardants, antioxidants, antistatic agents, light stabilizers, antifungal agents, etc. may be added to the U acid product of the present invention, as long as they do not impede the physical properties of the molded product. .
（実施例〕
以下、実施例により本発明を説明するが、本発明はこれ
らの実施例に限定されるものではない。(Examples) The present invention will be explained below with reference to Examples, but the present invention is not limited to these Examples.
実施例１
次の配合物を播潰機を使用し２０分間屯合し、均一なペ
ーストゾルを作成した。このペーストゾルを難燃紙上に
０．１８ｎ＋ｍ厚になるように塗布し、１４０°Ｃのオ
ーブン中で１分間セミキュアーした後２２０°Ｃで３０
〜７０秒間加熱し、発泡体を作成した。得られた発泡体
の発泡倍率、６０秒加熱後の黄色度を測定し、発泡セル
の状態を観察した。Example 1 The following formulations were combined for 20 minutes using a crusher to create a uniform paste sol. This paste sol was applied on flame retardant paper to a thickness of 0.18n+m, semi-cured for 1 minute in an oven at 140°C, and then heated at 220°C for 30 minutes.
Heated for ~70 seconds to create a foam. The expansion ratio of the obtained foam and the degree of yellowness after heating for 60 seconds were measured, and the state of the foam cells was observed.
また、セミキュアーした試片の塗布面にクロムメンキし
た金属板を重ね、１５０″Ｃで５分間加熱後詰片を剥離
する操作を１０回繰り返し、金属板の曇り状態（コーテ
ィング時プレートアウト）を観察した。また、同様に２
２０“Ｃで２分間加熱発泡後試片を剥離する操作を５回
繰り返し、金属板の曇り状態（エンボス時プレートアウ
ト）を観察した。なお、発泡セルの状態及びプレードア
カド性はｌＯ段階で評価し、数字の少ない程良好である
ことを示す。また、発泡体の黄色度は、東京電色社製デ
ジタルカラーメーターで測定した。In addition, a chrome-plated metal plate was placed on the coated surface of the semi-cured test piece, and the operation of peeling off the filler plate after heating at 150''C for 5 minutes was repeated 10 times, and the cloudy state of the metal plate (plate out during coating) was observed. Also, similarly 2
After heating and foaming at 20"C for 2 minutes, the test piece was peeled off five times and the cloudy state of the metal plate (plate out during embossing) was observed.The state of the foamed cells and plaid academia were evaluated at the 1O stage. The lower the number, the better the results.The yellowness of the foam was measured using a digital color meter manufactured by Tokyo Denshoku Co., Ltd.
その結果を下記表−１に示す。The results are shown in Table 1 below.
（配合）
ｐ ｖ Ｃ（ＰＳＬ−２８０鐘淵化学製）ジオクチルフ
タレート
炭酸カルシウム（Ｈ）
二酸化チタン（Ｒ）
アヅジカーボンアミド
ミネラルスピリット
オクチル酸亜鉛
酢酸亜鉛
重量部
ＯＯ
０
００
５
１，５
０，５
＊ １ ： ＤＨＴ−４Ａ
協和化学工業■製合成ハイドロタルサイト＊２：亜鉛変
性ハイドロタルサイ）Ｉ
Ｍｇｏ、 ：＋＋＋４ｎｏ、 ｘＨ＾ｌｏ、 ：＋ｚ・
（ＯＨ） ｚ・（ＣＯ：ｌ） ｏ、 ＋ ６・０．５Ｈ
ｚ。(Composition) p v C (PSL-280 manufactured by Kanebuchi Chemical) Dioctyl phthalate Calcium carbonate (H) Titanium dioxide (R) Azudicarbonamide mineral spirit Zinc octylate Zinc acetate Weight parts OO 0 00 5 1,5 0,5 *1: DHT-4A Synthetic hydrotalcite manufactured by Kyowa Chemical Industry *2: Zinc-modified hydrotalcite) I Mgo, :+++4no, xH^lo, :+z・
(OH) z・(CO:l) o, + 6・0.5H
z.
＊３：亜鉛変性ハイドロタルサイト２
Ｍｇｏ、 ａｓ４ｎｏ、 ＋５４１ｏ、 ＋ｚ、（ＯＨ
）ｚ、（Ｃｏｘ）ｏ、 Ｉ７＊４：亜鉛変性ハイドロタ
ルサイト３
Ｍｇｏ、 ５４ｎｏ、 ＋ □４ｉｏ、 ｘｘ、（ＯＨ
） ｚ、（ＣＯ：ｌ） ｏｌｂｓ・０．４５Ｈ２Ｏ＊５
：亜鉛変性ハイドロタルサイト４
Ｍｇｏ、 Ｓ・Ｚｎｏ、 ｚｓ４１ｏ、 ｚｓｓ（ＯＨ
）ｚ・（Ｃｏ：＋）ｏ、 ＋ｚｓ＊６：亜鉛変性ハイド
ロタルサイト５
Ｍｇｏ、 ＳＳ’ｚｎＯ，Ｉ ｓ ・ＡＩｏ、 ３．（
ＯＨ） ｚ、（ＣＯ３） ｏ。*3: Zinc-modified hydrotalcite 2 Mgo, as4no, +541o, +z, (OH
)z, (Cox)o, I7*4: Zinc-modified hydrotalcite 3 Mgo, 54no, + □4io, xx, (OH
) z, (CO:l)olbs・0.45H2O*5
: Zinc modified hydrotalcite 4 Mgo, S・Zno, zs41o, zss(OH
)z・(Co:+)o, +zs*6: Zinc-modified hydrotalcite 5 Mgo, SS'znO, Is・AIo, 3. (
OH) z, (CO3) o.
＊７：亜鉛変性ハイドロタルサイト６
Ｍｇｏ、ａ ・Ｃａｏ、Ｉ−ｚｎＯ，ｌ 、ＡＩｏ、ｘ
ｚ・ （ＯＨ）ｚ、（ＣＯ：ｌ）ｏ、＋ ａ＊８：亜鉛
変性ハイドロタルサイト７
Ｍｇｏ、 １’ｃａＯ，ｚ’Ｚｎｏ、 ｚ４１ｏ、 ３
・（ＯＨ）ｚ・（ＣＯｚ）ｏ、 ＋ｓ実施例２
次の配合により実施例１と同様にして、ペーストゾル及
び試片を作威し、実施例１と同様の試験を行った。その
結果を下記表−２に示す。*7: Zinc-modified hydrotalcite 6 Mgo, a ・Cao, I-znO, l , AIo, x
z・(OH)z, (CO:l)o, + a*8: Zinc-modified hydrotalcite 7 Mgo, 1'caO, z'Zno, z41o, 3
・(OH)z・(COz)o, +s Example 2 A paste sol and a sample were prepared in the same manner as in Example 1 using the following formulations, and the same tests as in Example 1 were conducted. The results are shown in Table 2 below.
（配合） 重量部Ｐ Ｖ Ｃ
（ＰＳＬ−２８０鐘淵化学製）（ＯＯジオクチルフタレ
ート ６０炭酸カルシウム（Ｈ）
１００二酸化チタン（Ｒ）
１５アゾシカ−ボンアミド ３ミネラ
ルスピリツト ８塩化亜鉛
２実施例３
次の配合により実施例Ｉと同様にして、ペーストゾル及
び試片を作威し、実施例１と同様の試験を行った。その
結果を下記表−３に示す。(Composition) Part by weight P V C
(PSL-280 Kanebuchi Chemical) (OO dioctyl phthalate 60 calcium carbonate (H)
100 titanium dioxide (R)
15 Azocicabonamide 3 Mineral spirits 8 Zinc chloride
2 Example 3 Paste sol and specimens were prepared in the same manner as in Example I using the following formulations, and the same tests as in Example 1 were conducted. The results are shown in Table 3 below.
（配合） 重量部Ｐ Ｖ Ｃ
（ＰＸ−ＱＬＴ住友化学製） １００ジオクチ
ルフタレート ５５エポキシ化大豆油
５炭酸カルシウム（Ｈ）
６０二酸化チタン（Ｒ） １５
三酸化アンチモン ２ビス（ベンゼ
ンスルホニルヒドラ ３シト）エーテル
ミネラルスピリット １０亜鉛オクト
エート ２添加剤（表−３）
、０． ５実施例４
次の配合により実施例１と同様にして、ペーストゾル及
び試片を作威し、実施例１と同様にして加熱３０秒〜７
０秒間の発泡倍率及び加熱６０秒後の黄色度を測定した
。(Composition) Part by weight P V C
(PX-QLT manufactured by Sumitomo Chemical) 100 dioctyl phthalate 55 epoxidized soybean oil
5 Calcium carbonate (H)
60 Titanium dioxide (R) 15
Antimony trioxide 2 bis(benzenesulfonyl hydra 3 sites) ether mineral spirit 10 Zinc octoate 2 Additives (Table 3)
,0. 5 Example 4 A paste sol and a sample were prepared in the same manner as in Example 1 using the following formulations, and heated in the same manner as in Example 1 for 30 seconds to 7 seconds.
The foaming ratio for 0 seconds and the degree of yellowness after 60 seconds of heating were measured.
その結果を下記表−４に示す。The results are shown in Table 4 below.
（配合） 重量部Ｐ Ｖ Ｃ
（ＰＳＬ−２８０鐘淵化学製） １００ジオクチ
ルフタレート ６０炭酸カルシウム（
Ｈ） １００二酸化チタン（Ｒ）
１５アゾシカ−ボンアミド
３亜鉛化合物（表−４参照）
２市販亜鉛変性ハイドロタルサイト １（アルカ
マシザー４：協和化学工業製）また、比較のため、亜鉛
を含まない市販のハイドロタルサイト化合物（ＤＨＴ−
４Ａ：協和化学工業■製）を用いたものについても同様
の試験を行った。(Composition) Part by weight P V C
(PSL-280 manufactured by Kanebuchi Chemical) 100 dioctyl phthalate 60 calcium carbonate (
H) 100 titanium dioxide (R)
15 Azocica-bonamide
3 Zinc compounds (see Table-4)
2 Commercially available zinc-modified hydrotalcite 1 (Arkamascissor 4: Kyowa Chemical Industry Co., Ltd.) For comparison, a commercially available hydrotalcite compound containing no zinc (DHT-
4A: manufactured by Kyowa Kagaku Kogyo ■) was also subjected to a similar test.
上記の各実施例から明らかなように、亜鉛で変性されて
いないハイドロタルサイト化合物を用いた場合には、発
泡セルの状態、プレートアウト性及び黄色度はある程度
改善されるものの未だ不充分であり、しかも、発泡初期
の発泡倍率は全く不充分であり実用上満足できるもので
はなかった。As is clear from the above examples, when a hydrotalcite compound that is not modified with zinc is used, the condition of the foamed cells, plate-out property, and yellowness are improved to some extent, but it is still insufficient. Moreover, the foaming ratio at the initial stage of foaming was completely insufficient and was not practically satisfactory.
これに対し、亜鉛変性ハイドロタルサイト化合物を用い
た本発明の組成物は、発泡セルの状態、プレートアウト
性及び黄色度を著しく改善しており、しかも、発泡の立
ち上がりが早く、短時間で所望の発泡倍率に到達できる
ので、生産性の向上に著しく寄与するばかりでなく、加
熱時間も短いので、樹脂の劣化に起因する着色を更に低
減することもできることが明らかである。On the other hand, the composition of the present invention using a zinc-modified hydrotalcite compound has significantly improved foam cell condition, plate-out property, and yellowness.Moreover, the foam rises quickly, and the desired result can be achieved in a short period of time. Since it is possible to reach a foaming ratio of , it not only significantly contributes to improving productivity, but also because the heating time is short, it is clear that it is also possible to further reduce discoloration caused by resin deterioration.
本発明の塩化ビニル系発泡性樹脂組成物は、作業性及び
加工性が良好であり、均一な発泡セルを有し、しかもプ
レートアウト性が改良されたものである。The vinyl chloride foamable resin composition of the present invention has good workability and processability, has uniform foam cells, and has improved plate-out properties.
Claims (1)
０〜２５０重量部、（ｂ）亜鉛化合物０．０１〜５重量
部、（ｃ）次の一般式で表される亜鉛変性ハイドロタル
サイト系化合物０．０１〜５重量部及び（ｄ）熱分解型
有機発泡剤０．１〜１０重量部を配合してなる、塩化ビ
ニル系発泡性樹脂組成物。 Ｍ＿ｙ＿１・Ｚｎ＿ｙ＿２・Ａｌ＿ｘ・（ＯＨ）＿２・
（ＣＯ＿３）＿ｘ＿／＿２・ｍＨ＿２Ｏ（式中、Ｍはア
ルカリ土類金属を示し、ｘ、ｙ＿１、及びｙ＿２は各々
下記式で表される条件を満足する数を示し、ｍは０また
は任意の正数を示す。 ０＜ｘ≦０．５、ｙ＿１＋ｙ＿２＝１−ｘ、ｙ＿１≧ｙ
＿２、０．３≦ｙ＿１＜１、０＜ｙ＿２＜０．５）[Scope of Claims] 100 parts by weight of vinyl chloride resin, (a) 1 inorganic filler
0 to 250 parts by weight, (b) 0.01 to 5 parts by weight of a zinc compound, (c) 0.01 to 5 parts by weight of a zinc-modified hydrotalcite compound represented by the following general formula, and (d) thermal decomposition. A vinyl chloride foamable resin composition containing 0.1 to 10 parts by weight of an organic foaming agent. M_y_1・Zn_y_2・Al_x・(OH)_2・
(CO_3)_x_/_2・mH_2O (In the formula, M represents an alkaline earth metal, x, y_1, and y_2 each represent a number that satisfies the conditions expressed by the following formula, and m is 0 or any positive value. Indicates the number. 0<x≦0.5, y_1+y_2=1-x, y_1≧y
_2, 0.3≦y_1<1, 0<y_2<0.5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3350090A JP2883145B2 (en) | 1990-02-14 | 1990-02-14 | Vinyl chloride foamable resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3350090A JP2883145B2 (en) | 1990-02-14 | 1990-02-14 | Vinyl chloride foamable resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03237140A true JPH03237140A (en) | 1991-10-23 |
| JP2883145B2 JP2883145B2 (en) | 1999-04-19 |
Family
ID=12388270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3350090A Expired - Fee Related JP2883145B2 (en) | 1990-02-14 | 1990-02-14 | Vinyl chloride foamable resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2883145B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007039644A (en) * | 2005-07-07 | 2007-02-15 | Jsp Corp | Method for producing inorganic material-based foamed article |
| JP2007204525A (en) * | 2006-01-31 | 2007-08-16 | Adeka Corp | Liquid stabilizer composition for vinyl chloride-based resin and plastisol composition containing the liquid stabilizer composition |
| WO2008061665A1 (en) * | 2006-11-21 | 2008-05-29 | Nabaltec Ag | Novel zinc-containing calcium-aluminium double salts |
| US7405359B2 (en) * | 1999-02-05 | 2008-07-29 | Toda Kogyo Corporation | Mg-Al-based hydrotalcite-type particles, chlorine-containing resin composition and process for producing the particles |
| WO2011024399A1 (en) | 2009-08-24 | 2011-03-03 | 株式会社Adeka | Vinyl chloride resin composition for transparent products |
| WO2011102115A1 (en) | 2010-02-22 | 2011-08-25 | 株式会社Adeka | Weather-resistant vinyl chloride resin composition |
| JP2013032427A (en) * | 2011-08-01 | 2013-02-14 | Eiwa Kasei Kogyo Kk | Gas generating agent for producing foam |
| WO2014141608A1 (en) | 2013-03-12 | 2014-09-18 | 株式会社Adeka | Vinyl chloride resin composition for transparent article |
-
1990
- 1990-02-14 JP JP3350090A patent/JP2883145B2/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7405359B2 (en) * | 1999-02-05 | 2008-07-29 | Toda Kogyo Corporation | Mg-Al-based hydrotalcite-type particles, chlorine-containing resin composition and process for producing the particles |
| JP2007039644A (en) * | 2005-07-07 | 2007-02-15 | Jsp Corp | Method for producing inorganic material-based foamed article |
| JP2007204525A (en) * | 2006-01-31 | 2007-08-16 | Adeka Corp | Liquid stabilizer composition for vinyl chloride-based resin and plastisol composition containing the liquid stabilizer composition |
| WO2008061665A1 (en) * | 2006-11-21 | 2008-05-29 | Nabaltec Ag | Novel zinc-containing calcium-aluminium double salts |
| US8168078B2 (en) | 2006-11-21 | 2012-05-01 | Nabaltec Ag | Zinc-containing calcium-aluminium double salts |
| WO2011024399A1 (en) | 2009-08-24 | 2011-03-03 | 株式会社Adeka | Vinyl chloride resin composition for transparent products |
| WO2011102115A1 (en) | 2010-02-22 | 2011-08-25 | 株式会社Adeka | Weather-resistant vinyl chloride resin composition |
| JP2011168744A (en) * | 2010-02-22 | 2011-09-01 | Adeka Corp | Weather-resistant vinyl chloride-based resin composition |
| JP2013032427A (en) * | 2011-08-01 | 2013-02-14 | Eiwa Kasei Kogyo Kk | Gas generating agent for producing foam |
| WO2014141608A1 (en) | 2013-03-12 | 2014-09-18 | 株式会社Adeka | Vinyl chloride resin composition for transparent article |
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|---|---|
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