JPH03231821A - Manufacture of molded product with pattern and transfer foil - Google Patents
Manufacture of molded product with pattern and transfer foilInfo
- Publication number
- JPH03231821A JPH03231821A JP2736390A JP2736390A JPH03231821A JP H03231821 A JPH03231821 A JP H03231821A JP 2736390 A JP2736390 A JP 2736390A JP 2736390 A JP2736390 A JP 2736390A JP H03231821 A JPH03231821 A JP H03231821A
- Authority
- JP
- Japan
- Prior art keywords
- transfer foil
- resin
- cavity
- molded product
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011888 foil Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 239000002966 varnish Substances 0.000 claims abstract description 19
- 239000004033 plastic Substances 0.000 claims abstract description 13
- 229920003023 plastic Polymers 0.000 claims abstract description 13
- -1 polypropylene Polymers 0.000 claims abstract description 8
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 4
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 4
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 4
- 229920001721 polyimide Polymers 0.000 claims abstract description 4
- 239000009719 polyimide resin Substances 0.000 claims abstract description 4
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 229930182556 Polyacetal Natural products 0.000 claims description 6
- 229920006324 polyoxymethylene Polymers 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000298 Cellophane Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 210000004905 finger nail Anatomy 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14827—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using a transfer foil detachable from the insert
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
- B29C2037/0042—In-mould coating, e.g. by introducing the coating material into the mould after forming the article the coating being applied in solid sheet form, e.g. as meltable sheet
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は耐摩耗性、耐薬品性、機械的強度の優れた絵付
き成形品の製造方法に間するもので、自動車用部品、電
気製品、日用品、玩具部品等の製に通したものである。[Detailed Description of the Invention] <Industrial Field of Application> The present invention relates to a method for manufacturing painted molded products with excellent wear resistance, chemical resistance, and mechanical strength. , used in the manufacture of daily necessities, toy parts, etc.
〈従来の技術〉
従来、この種の成形品を製造する場合、スチレン系、オ
レフィン系のプラスチックを用いて成形品を製造すると
同時に転写紙の絵柄を成形品表面に転写する技術は特開
昭５６−２１４８号、特開昭５７−６１５４１号等に示
されるように既に広く知られており、日用品、玩具等の
製造に使われている。<Prior art> Conventionally, when manufacturing this type of molded product, the technology of manufacturing the molded product using styrene-based or olefin-based plastics and at the same time transferring the design of transfer paper onto the surface of the molded product was developed in Japanese Patent Application Laid-Open No. 1983-1995. It is already widely known as shown in Japanese Patent Laid-Open No. 57-61541 and No. 2148, and is used in the production of daily necessities, toys, etc.
〈発明が解決しようとする課題〉
しかし、上記従来の絵付き成形品の製造においてはスチ
レン系、オレフィン系プラスチック（例エバ、ＡＢＳ樹
脂、ポリスチレン、ポリプロピレン、ポリエチレン）が
使われているため、機械的強度、電気的性質、耐クリー
プ性、耐疲労性等の長期物性、耐摩耗性、耐薬品性等の
面で日用品等に使う場合は充分であっても、より苛酷な
条件で使う成形品やより優れた物性を要求される成形品
の場合はスチレン系やオレフィン系のプラスチックでは
要求品質が得られないという問題がある。<Problems to be Solved by the Invention> However, since styrene-based and olefin-based plastics (e.g. EVA, ABS resin, polystyrene, polypropylene, polyethylene) are used in the production of the above-mentioned conventional painted molded products, mechanical Although long-term physical properties such as strength, electrical properties, creep resistance, fatigue resistance, wear resistance, and chemical resistance are sufficient for use in daily necessities, molded products or products used under more severe conditions may be sufficient. In the case of molded products that require superior physical properties, there is a problem in that styrene-based or olefin-based plastics cannot provide the required quality.
そこで、近年はエンジニアリングプラスチックと称され
る上記したような物性面で優れたプラスチックが（吏わ
れるようになってきている。Therefore, in recent years, plastics that have excellent physical properties such as those described above, which are called engineering plastics, have been gaining popularity.
しかし、エンジニアリングプラスチック、例えば、ポリ
アセタール樹脂で成形した成形品の表面は他の樹脂との
接着性が悪く、アフター転写適性が良くない、すなわち
、−度、インジェクション成形されたポリアセタール樹
脂表面に転写箔を用いて絵柄を形成しても、セロハンテ
ープ密着は充分ではあるが、爪で表面を引っかくと絵柄
を形成しているインキが簡単に剥がれてしまうという問
題がある。However, the surface of molded products made of engineering plastics, such as polyacetal resin, has poor adhesion with other resins and is not suitable for after-transfer. Even if cellophane tape is used to form a pattern, the adhesion is sufficient, but there is a problem in that the ink forming the pattern easily peels off when the surface is scratched with a fingernail.
〈課題を解決するための手段〉
そこで、本発明はポリアセタール樹脂が成形され、表面
の接着性が低下する前（樹脂が流動性を維持し、結晶化
する前）に、転写箔に設けた接着ニス層を介して成形と
同時に絵付けを行うことを目的として考えられたもので
あり、一対の金型間に転写箔を供給した後、前記一対の
金型を型締めしてキャビティを形成し、このキャビティ
内に溶融プラスチックを供給して前記キャビティ内で成
形品を形成するとともに、この成形品に前記転写箔の転
写層を転写する絵付き成形品の製造方法において、前記
プラスチックはポリアセタール樹脂、ポリアミド樹脂、
ポリイミド樹脂、ポリシーボネート樹脂のうちの一種で
あり、前記転写箔は成形品との接着面にアクリル変性し
た塩素化ポリプロピレン樹脂を設けたことを特徴とする
絵付き成形品の製造方法及び一対の金型間に転写箔を供
給した後、前記一対の金型を型締めしてキャビティを形
成し、このキャビティ内に溶融プラスチックを供給して
前記キャビティ内で成形品を成形するとともに、この成
形品に前記転写箔の転写層を転写する絵付き成形品の製
造に用いる転写箔であって、基材フィルム、剥離ニス層
、絵柄層、接着ニス層を含み、前記接着ニス層がアクリ
ル変性した塩素化ポリプロピレン樹脂を主成分とするこ
とを特徴とする転写箔である。<Means for Solving the Problems> Therefore, the present invention provides adhesives provided on the transfer foil before the polyacetal resin is molded and the surface adhesiveness decreases (before the resin maintains fluidity and crystallizes). It was designed to perform painting simultaneously with molding through a varnish layer, and after supplying transfer foil between a pair of molds, the pair of molds are clamped to form a cavity. , a method for manufacturing a molded article with a picture, in which a molten plastic is supplied into the cavity to form a molded article in the cavity, and a transfer layer of the transfer foil is transferred to the molded article, wherein the plastic is a polyacetal resin, polyamide resin,
A method for manufacturing a molded product with a pattern, characterized in that the transfer foil is a type of polyimide resin or polycarbonate resin, and an acrylic-modified chlorinated polypropylene resin is provided on the adhesive surface with the molded product, and a pair of gold After supplying transfer foil between the molds, the pair of molds are clamped to form a cavity, and molten plastic is supplied into the cavity to mold a molded product within the cavity. A transfer foil used for manufacturing a molded article with a pattern to which the transfer layer of the transfer foil is transferred, which includes a base film, a release varnish layer, a pattern layer, and an adhesive varnish layer, the adhesive varnish layer being an acrylic-modified chlorinated product. This is a transfer foil characterized by containing polypropylene resin as a main component.
く作用〉
本発明の以上の構成になっており、樹脂が溶融状態にお
いて、転写箔が接着剤層を介して成形品の表面となる個
所に接触する。したがって、この後、キャビティ内への
樹脂の射出が完了して型開きをし、成形品を取出すと、
表面に完全に転写紙の絵柄が密着した成形品が得られる
。Effect> With the above structure of the present invention, when the resin is in a molten state, the transfer foil comes into contact with the surface of the molded product via the adhesive layer. Therefore, after this, when the injection of resin into the cavity is completed and the mold is opened and the molded product is taken out,
A molded product with the pattern of the transfer paper completely adhered to the surface can be obtained.
〈実施例〉 以下、図面に基いて本発明の詳細な説明する。<Example> Hereinafter, the present invention will be explained in detail based on the drawings.
第１図は本実施例における絵付き成形品の製造方法を示
す説明図であり、（Ａ）は溶融プラスチックを供給して
成形品を射出成形する金型であり、可動型（１）と固定
型（２）とから成り、可動型（１）には皿状の成形品を
得るためのキャビティを形成する凹部（３）が設けられ
、固定型（２）には前記凹部（３）と対応してコア（４
）が設けられ、溶融樹脂の射出用のゲート（５）が設け
られている。FIG. 1 is an explanatory diagram showing the method for manufacturing a molded product with a picture in this example, and (A) is a mold for injection molding a molded product by supplying molten plastic, with a movable mold (1) and a fixed mold. The movable mold (1) is provided with a recess (3) that forms a cavity for obtaining a dish-shaped molded product, and the fixed mold (2) is provided with a recess (3) that corresponds to the recess (3). and core (4
) and a gate (5) for injection of molten resin.
（Ｂ）は本実施例に用いられる転写箔であり、ポリエス
テルフィルムから成る基材（６）に該基材（６）に対し
て耐熱性を付与するための離型ニス（例えばエポキシ−
メラミン系、アミノ−アルキッド系）層を設け、剥離ニ
ス（８）を介して、アクリル変性した塩素化ポリプロピ
レン樹脂から成る接着ニス層（９）を設けた構造になっ
ている。(B) is a transfer foil used in this example, and is a mold release varnish (for example, epoxy) used to impart heat resistance to the base material (6) made of a polyester film.
It has a structure in which a melamine-based, amino-alkyd-based) layer is provided, and an adhesive varnish layer (9) made of an acrylic-modified chlorinated polypropylene resin is provided via a release varnish (8).
なお、図中（１０）は剥離ニスＮ（８）上に設けられた
絵柄層である。Note that (10) in the figure is a pattern layer provided on the release varnish N (8).
上記巻取状の転写箔（Ｂ）を用いて、射出成形を行う場
合、第１図に示すように基材（６）をキャビティ（３）
側に向けて可動型（１）と固定型（２）の間にセットし
、可動型（１）をスライドさせて閉じてキャビティを形
成する。When injection molding is performed using the above-mentioned rolled transfer foil (B), the base material (6) is placed in the cavity (3) as shown in Figure 1.
It is set between the movable mold (1) and the fixed mold (2) facing toward the side, and the movable mold (1) is slid and closed to form a cavity.
次いで金型温度３５°Ｃ〜４５°Ｃにおいて成形射出温
度２００’Ｃ〜２２０’Ｃでポリアセタール樹脂をゲー
ト（５）からキャビティ内に射出した後、金型を開いて
脱型し、転写紙（Ｂ）の基材（６）、離型ニス（７）の
部分を剥離ニスＮ（８）から剥がして絵付き成形品が得
られる。Next, polyacetal resin is injected into the cavity from the gate (5) at a mold temperature of 35°C to 45°C and a molding injection temperature of 200'C to 220'C, the mold is opened and removed, and a transfer paper ( The base material (6) and the release varnish (7) in B) are peeled off from the release varnish N (8) to obtain a molded product with a pattern.
このようにして得られた絵付き成形品は絵柄と成形品と
の一体感が優れ、セロハンテープ密着性が強いのはもち
ろんのこと、爪で表面を引っかいても絵柄が剥がれるこ
とがなかった。The patterned molded product thus obtained had an excellent sense of unity between the pattern and the molded product, and not only had strong cellophane tape adhesion, but the pattern did not peel off even when the surface was scratched with a fingernail.
なお、本実施例においては成形樹脂はポリアセタール樹
脂を用いたが、その他、所謂、アフター転写には向かな
い樹脂であれば、これに限定されるものではなく、ポリ
アミド樹脂、ポリイミド樹脂、ポリカーボネート樹脂等
にも適用できるものである。In this example, polyacetal resin was used as the molding resin, but the resin is not limited to this as long as it is not suitable for so-called after-transfer, such as polyamide resin, polyimide resin, polycarbonate resin, etc. It can also be applied to
〈発明の効果〉
本発明は以上の構成になっているので、成形樹脂と転写
箔の絵柄との接着性が優れており、成形品と絵柄との一
体感の優れた成形品が得られる。<Effects of the Invention> Since the present invention has the above-described configuration, a molded product with excellent adhesion between the molding resin and the pattern of the transfer foil and an excellent sense of unity between the molded product and the pattern can be obtained.
第１図は本発明の一実施例を示す説明図である。
１ ・・・可動型 ２）・・・固定型３ ・・・
凹部 ４）・・・コア５ ・・・ゲート
６）・・・基材７ ・・・離型ニス ８）・・・
剥離ニス９ ・・・接着ニス １０）・・・絵柄層
時 許 出 願 人
凸版印刷株式会社
代表者 鈴木和夫FIG. 1 is an explanatory diagram showing one embodiment of the present invention. 1...Movable type 2)...Fixed type 3...
Recess 4) Core 5 Gate
6)... Base material 7... Release varnish 8)...
Release varnish 9...Adhesive varnish 10)...Picture layer Applicant: Toppan Printing Co., Ltd. Representative Kazuo Suzuki
Claims (2)
金型を型締めしてキャビティを形成し、このキャビティ
内に溶融プラスチックを供給して前記キャビティ内で成
形品を形成するとともに、この成形品に前記転写箔の転
写層を転写する絵付き成形品の製造方法において、前記
プラスチックはポリアセタール樹脂、ポリアミド樹脂、
ポリイミド樹脂、ポリカーボネート樹脂のうちの一種で
あり、前記転写箔は成形品との接着面にアクリル変性し
た塩素化ポリプロピリン樹脂を設けたことを特徴とする
絵付き成形品の製造方法。(1) After supplying a transfer foil between a pair of molds, the pair of molds are clamped to form a cavity, and molten plastic is supplied into this cavity to form a molded product within the cavity. In addition, in the method for producing a molded article with a picture, in which the transfer layer of the transfer foil is transferred to the molded article, the plastic is polyacetal resin, polyamide resin,
1. A method for manufacturing a molded article with a picture, which is a type of polyimide resin or polycarbonate resin, and the transfer foil has an acrylic-modified chlorinated polypropyline resin provided on the adhesive surface with the molded article.
金型を型締めしてキャビティを形成し、このキャビティ
内に溶融プラスチックを供給して前記キャビティ内で成
形品を形成するとともに、この成形品に前記転写箔の転
写層を転写する絵付き成形品の製造に用いる転写箔であ
って、基材フィルム、剥離ニス層、絵柄層、接着ニス層
を含み、前記接着ニス層がアクリル変性した塩素化ポリ
プロピレン樹脂を主成分とすることを特徴とする転写箔
。(2) After supplying a transfer foil between a pair of molds, the pair of molds are clamped to form a cavity, and molten plastic is supplied into this cavity to form a molded product within the cavity. In addition, a transfer foil used for manufacturing a molded article with a pattern to which a transfer layer of the transfer foil is transferred to the molded article, which includes a base film, a release varnish layer, a pattern layer, and an adhesive varnish layer, and the adhesive varnish layer A transfer foil characterized in that the main component is acrylic-modified chlorinated polypropylene resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2736390A JPH03231821A (en) | 1990-02-07 | 1990-02-07 | Manufacture of molded product with pattern and transfer foil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2736390A JPH03231821A (en) | 1990-02-07 | 1990-02-07 | Manufacture of molded product with pattern and transfer foil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03231821A true JPH03231821A (en) | 1991-10-15 |
Family
ID=12218968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2736390A Pending JPH03231821A (en) | 1990-02-07 | 1990-02-07 | Manufacture of molded product with pattern and transfer foil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03231821A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0549326U (en) * | 1991-12-03 | 1993-06-29 | 大日本印刷株式会社 | Plastic model kit |
| DE102004041833A1 (en) * | 2004-08-27 | 2006-03-02 | Leonhard Kurz Gmbh & Co. Kg | Decorated injection molded article, method of making a decorated injection molded article, and transfer sheet for use in such method |
| DE102004041867A1 (en) * | 2004-08-27 | 2006-03-16 | Leonhard Kurz Gmbh & Co. Kg | Decorated injection molded article, as well as transfer film and method for producing such |
| US7922952B2 (en) | 2007-10-04 | 2011-04-12 | Nissha Printing Co., Ltd. | Simultaneous injection-molding and decorating method |
-
1990
- 1990-02-07 JP JP2736390A patent/JPH03231821A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0549326U (en) * | 1991-12-03 | 1993-06-29 | 大日本印刷株式会社 | Plastic model kit |
| DE102004041833A1 (en) * | 2004-08-27 | 2006-03-02 | Leonhard Kurz Gmbh & Co. Kg | Decorated injection molded article, method of making a decorated injection molded article, and transfer sheet for use in such method |
| DE102004041867A1 (en) * | 2004-08-27 | 2006-03-16 | Leonhard Kurz Gmbh & Co. Kg | Decorated injection molded article, as well as transfer film and method for producing such |
| US7906054B2 (en) | 2004-08-27 | 2011-03-15 | Leonhard Kurz Stiftung & Co. Kg | Decorated injection-moulded article, method for producing one such article, and transfer film for using in one such method |
| US7922952B2 (en) | 2007-10-04 | 2011-04-12 | Nissha Printing Co., Ltd. | Simultaneous injection-molding and decorating method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU713604B2 (en) | Decoration foil for decoration of three-dimensional substrate surfaces | |
| JPS59202831A (en) | Manufacture of foil decorated molded product, its product and transfer foil | |
| US8241456B2 (en) | Method for producing electric-wave-transmissible transferring member | |
| KR100361134B1 (en) | Heat-transfer paper for label made of thermosetting material and method of making the same | |
| CN108621484B (en) | Silica gel object with three-dimensional colorful pattern surface layer and manufacturing method thereof | |
| JPH0415457Y2 (en) | ||
| JPH03231821A (en) | Manufacture of molded product with pattern and transfer foil | |
| KR870005805A (en) | Synthetic resin molded article coated with synthetic leather and manufacturing method thereof | |
| JP2954651B2 (en) | Injection molding method | |
| JPH01108799A (en) | Thermoplastic resin molding and manufacture thereof | |
| JPS6280045A (en) | Molded shape with hologram and manufacture thereof | |
| JPH0911275A (en) | Manufacture of molding having pattern | |
| JP2652119B2 (en) | Molding simultaneous molding die and method of manufacturing molding simultaneous painting | |
| JP2840751B2 (en) | Thermal transfer foil | |
| JPH077242A (en) | Smooth board and manufacture thereof | |
| JPH0584769A (en) | Production of injection molded product | |
| KR970033707A (en) | Bonding disks and manufacturing apparatus thereof and manufacturing method thereof | |
| JP2837175B2 (en) | Manufacturing method of synthetic resin injection molded products | |
| JPH0659670B2 (en) | Manufacturing method for embossed products | |
| JPS62251199A (en) | Manufacture of thermoplastic polyurethane elastomer molded from having picture and transfer sheet used for said manufacture | |
| JPH06355B2 (en) | Method for manufacturing molded article having hologram | |
| CN214727102U (en) | Decorative diaphragm for embedding injection molding in mold | |
| JPH05145265A (en) | Manufacture of electromagnetic wave shielding molded item | |
| JPS5658824A (en) | Insertion of decorative member | |
| JPH03207620A (en) | Decorative injection molded body |