JPH03197596A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH03197596A JPH03197596A JP33622389A JP33622389A JPH03197596A JP H03197596 A JPH03197596 A JP H03197596A JP 33622389 A JP33622389 A JP 33622389A JP 33622389 A JP33622389 A JP 33622389A JP H03197596 A JPH03197596 A JP H03197596A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- formula
- silicone
- pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000003599 detergent Substances 0.000 title abstract 4
- 238000004140 cleaning Methods 0.000 claims abstract description 24
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000003021 water soluble solvent Substances 0.000 claims abstract description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 6
- 239000003352 sequestering agent Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 230000021148 sequestering of metal ion Effects 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 abstract description 23
- 230000000694 effects Effects 0.000 abstract description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 abstract description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract description 3
- 150000005215 alkyl ethers Chemical class 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000002280 amphoteric surfactant Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は、ポリプロピレン、ホーロー、ステンレス、Ｆ
ＲＰ等の材質からなる浴槽、湯桶、腰掛け、すのこ等（
以下、浴室用具という。）に付着している尚垢汚れ等を
除去する洗浄力に優れ、かつ材質の表面を保護し、艶を
与える効果を有する洗浄剤組成物に関する。[Detailed description of the invention] [Industrial field of application] The present invention is applicable to polypropylene, enamel, stainless steel, F
Bathtubs, tubs, seats, drainboards, etc. made of materials such as RP (
Hereinafter, they are referred to as bathroom utensils. This invention relates to a cleaning composition that has excellent detergency for removing scale and stains adhering to surfaces (1), and has the effect of protecting the surface of materials and giving gloss.
［従来の技術および課題］
浴室用具に付着している湯垢汚れは、−膜内には脂肪酸
金属塩（主としてカルシウム塩）、遊離脂肪酸、グリセ
リド、泥等の混合したものから成り立っている。[Prior Art and Problems] The scale stains on bathroom utensils consist of a mixture of fatty acid metal salts (mainly calcium salts), free fatty acids, glycerides, mud, etc. in the film.
従来、浴室用具に用いる洗浄剤としては、有機酸等の酸
物質、界面活性剤および水溶性溶剤等を配合した酸性の
洗浄剤や、有機アミン、界面活性剤および水溶性溶剤等
を配合したアルカリ性の洗浄剤が知られている。Conventionally, cleaning agents used for bathroom utensils include acidic cleaning agents containing organic acids and other acid substances, surfactants, and water-soluble solvents, and alkaline cleaning agents containing organic amines, surfactants, and water-soluble solvents, etc. cleaning agents are known.
しかし、これらの洗浄剤については、洗浄効果は認めら
れるが、長期間にわたって使用されたポリプロピレン、
ホーロー、ステンレス、ＦＲＰ等の材質からなる浴室用
具の材質の劣化を防止する効果は認められず、また洗浄
剤によっては材質を劣化させる問題があった。However, although these cleaning agents have a cleaning effect, polypropylene that has been used for a long time,
No effect on preventing deterioration of bathroom utensils made of materials such as enamel, stainless steel, and FRP has been found, and some cleaning agents have the problem of degrading the materials.
［課題を解決するための手段］
本発明者らは、上記の課題を解決すべく鋭意検討を重ね
た結果、洗浄剤組成物にシリコンを配合すること、より
好ましくは、以下の構造を有するシリコンを配合するこ
とにより、」−記の課題を解決できることを見いだし本
発明を完成するに至った。[Means for Solving the Problems] As a result of intensive studies to solve the above problems, the present inventors have found that silicone is blended into a cleaning composition, and more preferably silicone having the following structure is used. It was discovered that the problems mentioned in "-" can be solved by blending the above, and the present invention was completed.
すなわち本発明は、
（１）シリコンを配合することを特徴とする洗浄剤組成
物。That is, the present invention provides: (1) A cleaning composition characterized in that it contains silicone.
（２）下記式Ｉ
■
（（式Ｉ中、Ｒ，、Ｒ２、Ｒ３およびＲ４は、それぞれ
下記式■を示し、ＸおよびＹは、０〜２０００である。(2) The following formula I ((In formula I, R,, R2, R3 and R4 each represent the following formula (2), and X and Y are 0 to 2000.
）
（Ｃ１ｈ）□−（ＯＣ２Ｈ４）ＩＩ（ＯＣ３Ｈ３）１Ｒ
Ｈ一
（式■中、］、ｍおよびｎは１≧０、ｍ≧Ｏｎ≧０であ
り、Ｒ゛は、同じまたは異なってアルキル基またはフェ
ニル基を表す。））で表されるシリコンを０．０５〜２
０重量部配合す配合とを特徴とする洗浄剤組成物。) (C1h)□-(OC2H4)II(OC3H3)1R
H1 (in the formula ■, ], m and n are 1≧0, m≧On≧0, R゛ is the same or different and represents an alkyl group or a phenyl group)) is 0. .05~2
A cleaning composition characterized in that the composition contains 0 parts by weight.
（３）界面活性剤０．１〜３０重量部、水溶性溶剤０．
５〜２０重量部、金属イオン封鎖剤０．１〜１０重量部
および下記式Ｉ
（（式Ｉ中、ＲＩＩ Ｒ２，Ｒ３およびＲ４は、それぞ
れ下記式■を示し、ＸおよびＹは、Ｏ〜２０００である
。）
（ＣＲ２）「（ＯＣ２）１４）−（ＯＣｑＨｅ）■
ＲＨ（式■中、］、ｍおよびｎは１≧０、ｍ≧Ｏｎ≧０
であり、Ｒ′は、同じまたは異なってアルキル基または
フェニル基を表す。））で表されるシリコンを００５〜
２０重量部配合す配合とを特徴とする洗浄剤組成物。(3) 0.1 to 30 parts by weight of surfactant, 0.0 parts by weight of water-soluble solvent.
5 to 20 parts by weight, 0.1 to 10 parts by weight of a sequestering agent and the following formula I ((In formula I, RII R2, R3 and R4 each represent the following formula ) (CR2) "(OC2)14)-(OCqHe)■
RH (in the formula ■, ], m and n are 1≧0, m≧On≧0
and R's are the same or different and represent an alkyl group or a phenyl group. )) silicon represented by 005~
20 parts by weight of a cleaning composition.
以下、本発明の洗浄剤組成物について詳細に説明する。Hereinafter, the cleaning composition of the present invention will be explained in detail.
本発明の洗浄剤組成物は、シリコンを配合すること、好
ましくは、上述した構造を有するシリコンを配合するこ
とにより、浴室用具の材質の劣化を防止するという効果
が得られるのであるから、洗浄剤組成物として通常用い
られる成分であれば、いかなるものを用いても良い。The cleaning composition of the present invention has the effect of preventing deterioration of the materials of bathroom utensils by blending silicone, preferably silicone having the above-mentioned structure. Any component that is commonly used in compositions may be used.
通常用いられる洗浄剤組成物の成分の具体例としては、
ハイドロトロープ剤、殺菌剤、防腐剤、色素、香料、紫
外線吸収剤などが挙げられる。特に洗浄力と劣化防止効
果を期待する上で、界面活性剤、水溶性溶剤、金属イオ
ン封鎖剤を配合することがより好ましく、それらの種類
と配合量は、次のように添加するのが好ましい。Specific examples of components of commonly used cleaning compositions include:
Examples include hydrotropes, fungicides, preservatives, pigments, fragrances, and ultraviolet absorbers. In particular, it is preferable to incorporate surfactants, water-soluble solvents, and sequestering agents in order to achieve detergency and deterioration prevention effects, and it is preferable to add the following types and amounts of these: .
界面活性剤は、湯垢汚れへの湿潤および乳化分散作用の
あるものが用いられ、アニオン性、カヂオン性、ノニオ
ン性、両性の各種界面活性剤のいずれも使用できる。そ
の例を挙げると次の通りであり、これらは単独で、また
は２種以上組み合わせて用いることができる。The surfactant used is one that has wetting and emulsifying and dispersing effects on scale stains, and any of various anionic, cationic, nonionic, and amphoteric surfactants can be used. Examples are as follows, and these can be used alone or in combination of two or more.
（１）アニオン界面活性剤
（３）スルホネート系
・直鎖または分岐アルキル（０８〜、２）ベンゼンスル
ホン酸塩、
・長鎖アルキル（ＣＯ〜７．）スルホン酸塩等（ｂ）サ
ルフェート系
・長鎖モノアルギル（Ｃａｌ〜２２）硫酸エステル塩、
・ポリオキシエチレン（１〜６モル）長鎖アルキル（Ｃ
，−２２）エーテル硫酸エステル塩、・ポリオキンエチ
レン（１〜６モル）アルキル（ＣＳ−７２）フェニルエ
ーテル硫酸エステル塩等
（Ｃ）ホスフェート系
・長鎖モノアルキル、ジアルキルまたはセスキアルキル
（Ｃ８〜、２）リン酸塩、・ポリオキンエチレン（１〜
６モル）モノアルキル、ジアルキルまたはセスキアルキ
ル（ＣＳ−２２）リン酸塩等
（ｄ）カルボキンレート系
・炭素数６〜２４の飽和および／または炭素数６〜２４
不飽和脂肪酸塩等
上記各アニオン界面活性剤の対イオンは、アルカリ金属
イオン、アルカリ土類イオン、アルカノールアミンイオ
ン、アンモニウムイオン等である。(1) Anionic surfactant (3) Sulfonate type, straight chain or branched alkyl (08-, 2) benzene sulfonate, long chain alkyl (CO~7.) sulfonate, etc. (b) Sulfate type, long Chain monoargyl (Cal~22) sulfate ester salt, polyoxyethylene (1~6 mol) long chain alkyl (C
, -22) Ether sulfate ester salts, polyoxene ethylene (1 to 6 mol) alkyl (CS-72) phenyl ether sulfate ester salts, etc. (C) Phosphate type long chain monoalkyl, dialkyl or sesquialkyl (C8 ~, 2) Phosphate, polyoxene ethylene (1~
6 mol) Monoalkyl, dialkyl or sesquialkyl (CS-22) phosphate, etc. (d) Carboxylate type, saturated with 6 to 24 carbon atoms and/or 6 to 24 carbon atoms
Counter ions for each of the above anionic surfactants such as unsaturated fatty acid salts include alkali metal ions, alkaline earth ions, alkanolamine ions, ammonium ions, and the like.
（２）カチオン界面活性剤
・アルキルトリメチルアンモニウムクロリド、
・ジアルキルジメチルアンモニウムクロリド、
・アルキルベンジルアンモニウムクロリド等
（３）ノニオン界面活性剤
・ポリオキノエチレン（１〜２０モル）長鎖アルキル（
Ｃｅ−２ｔ）エーテル、
・ポリオキシエチレン（１〜２０モル）アルキル（Ｃ，
〜２．）フェニルエーテル、・ポリオキシエヂレンポリ
オキシプロピレンブロツクボリマー等
（４）両性界面活性剤
・アミノ酸型両性界面活性剤、
・アルキルスルホベタイン、アルキル酢酸ベタインなど
のベタイン型両性界面活性剤、
・イミダシリン型両性界面活性剤等
以上の界面活性剤は、０．１〜３０重量部、好ましくは
、１〜１５重量部の範囲で本発明の洗浄剤組成物中に配
合される。配合量が０．１重量部未満では、界面活性剤
の洗浄効果が十分発揮できない。一方、３０重量部をこ
えて配合しても、洗浄効果の格別な向上は認められない
うえ、シリコンの効果を阻害して好ましくない。(2) Cationic surfactants: alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, alkylbenzylammonium chloride, etc. (3) Nonionic surfactants: polyoquinoethylene (1 to 20 mol), long-chain alkyl (
Ce-2t) ether, polyoxyethylene (1 to 20 mol) alkyl (C,
~2. ) Phenyl ether, polyoxyethylene polyoxypropylene block polymer, etc. (4) Ampholytic surfactants/Amino acid type amphoteric surfactants, Betaine type amphoteric surfactants such as alkyl sulfobetaines and alkyl acetate betaines, ・Imidacillin The surfactant such as an amphoteric surfactant is blended into the cleaning composition of the present invention in an amount of 0.1 to 30 parts by weight, preferably 1 to 15 parts by weight. If the blending amount is less than 0.1 part by weight, the cleaning effect of the surfactant cannot be sufficiently exhibited. On the other hand, even if the amount exceeds 30 parts by weight, no particular improvement in the cleaning effect is observed, and the effect of silicone is inhibited, which is not preferable.
水溶性溶剤としては、下記式■で表されるものが用いら
れる。As the water-soluble solvent, one represented by the following formula (2) is used.
Ｔ 、０− （Ｓ ｌ）ｍ−（Ｓ ２）ｎ−Ｔ ２■
［弐■中、Ｔ、、Ｔ２は、同じまたは異なって炭素数１
〜６の直鎖または分岐アルキル基を示し、ＳｌおよびＳ
、は、同じまたは異なってエチレンオキツドまたはプロ
ピレンオキシド示す。なお、エチレンオキツドとプロピ
レンオキシドの付加順序および形式は問わない。ｍ 、
ｎは、末端基Ｔ、の種類によって異なり、ｍ＝０〜４
、ｎ ＝ ０〜４である。T , 0- (S 1)m-(S 2)n-T 2■ [2■ Middle, T,, T2 are the same or different and have 1 carbon number
~6 linear or branched alkyl groups, Sl and S
, are the same or different and represent ethylene oxide or propylene oxide. Note that the addition order and form of ethylene oxide and propylene oxide do not matter. m,
n varies depending on the type of terminal group T, and m=0 to 4
, n = 0-4.
水溶性溶剤の具体例を挙げると次の通りである。Specific examples of water-soluble solvents are as follows.
・エチレングリコールモノエチルエーテル、・エチレン
グリコールモノブチルエーテル、・エチレングリコール
モノヘキシルエーテル、・ジエチレングリコールモノエ
チルエーテル、・ジエチレングリコールモノブチルエー
テル、・エチレングリコールジメチルエーテル、・ジエ
チレングリコールツメチルエーテル、・ジエチレングリ
コールメチルブチルエーテル、・ジエチレングリコール
ジエチルエーテル、・プロピレングリコールモノブチル
エーテル、・ンプロピレングリコールモノブチルエーテ
ル、・プロピレングリコールモノプロビルエーテル、・
ジプロピレングリコールモノプロピルエーテル、
・トリプロピレングリコールモノブチルエーテル、
・ジプロピレングリコールモノエチルエーテル等。・Ethylene glycol monoethyl ether, ・ethylene glycol monobutyl ether, ・ethylene glycol monohexyl ether, ・diethylene glycol monoethyl ether, ・diethylene glycol monobutyl ether, ・ethylene glycol dimethyl ether, ・diethylene glycol methyl ether, ・diethylene glycol methyl butyl ether, ・diethylene glycol diethyl ether ,・Propylene glycol monobutyl ether,・Propylene glycol monobutyl ether,・Propylene glycol monopropyl ether,・
Dipropylene glycol monopropyl ether, tripropylene glycol monobutyl ether, dipropylene glycol monoethyl ether, etc.
水溶性溶剤は、本発明の洗浄剤組成物中に０．５〜２０
重量部、好ましくは１〜１０重量部配合配合る。この配
合量が０．５重量部未満では、湯垢汚れを除去する効果
が得られず、一方、２０重量部を越えて配合すると、溶
剤臭を放つため製品として問題がある。The water-soluble solvent may be present in the cleaning composition of the present invention at a concentration of 0.5 to 20%.
It is blended in an amount of 1 to 10 parts by weight, preferably 1 to 10 parts by weight. If the amount is less than 0.5 parts by weight, the effect of removing scale stains will not be obtained, while if it is more than 20 parts by weight, a solvent odor will be emitted, causing problems as a product.
金属イオン封鎖剤は、特に限定されるものではなく、通
常、洗浄剤等に使用されているものでよい。例えば、ク
エン酸およびその塩、エチレンジアミンテトラ酢酸およ
びその塩、有機酸およびその塩、アミノカルボン酸およ
びその塩等が好適である。The metal ion sequestering agent is not particularly limited, and may be one commonly used in cleaning agents and the like. For example, citric acid and its salts, ethylenediaminetetraacetic acid and its salts, organic acids and its salts, aminocarboxylic acids and its salts, etc. are suitable.
金属イオン封鎖剤は、組成物中に０．１−１０重量部、
好ましくは１〜５重量部配配合れる。この配合量が０．
１重量部未満では洗浄力が不十分であり、１０重量部を
越えて配合しても本発明の効果に著しい向上は認められ
ない。The sequestering agent is present in the composition in an amount of 0.1-10 parts by weight,
Preferably, the amount is 1 to 5 parts by weight. This blending amount is 0.
If the amount is less than 1 part by weight, the detergency will be insufficient, and if it is added in excess of 10 parts by weight, no significant improvement in the effect of the present invention will be observed.
シリコンとしては、下記式Ｉ
（（式Ｉ中、Ｒ＋、 Ｒ２，Ｒ３およびＲ４は、それぞ
れ下記式■を示し、ＸおよびＹは、０〜２０００である
。）
（ＣＩ２）−（ＯＣ２Ｈ４）、（ＯＣ３Ｈｅ）１Ｒ■（
式■中、ｌ、ｍおよびｎはｌ≧０、ｍ≧０゜ｎ≧０であ
り、Ｒｏは、同じまたは異なってアルキル基またはフェ
ニル基を表す。））で表される物質を単独、あるいは２
種以上で用いる。As silicon, the following formula I ((In formula I, R+, R2, R3 and R4 each represent the following formula (■), and X and Y are 0 to 2000.) (CI2)-(OC2H4), ( OC3He)1R■(
In the formula (1), l, m and n are l≧0, m≧0°n≧0, and Ro, which are the same or different, represent an alkyl group or a phenyl group. )) alone or in combination
Used for more than one species.
シリコンの種類としては、オイルタイプ、エマルジョン
タイプ、シリコン界面活性剤のいずれでもよい。具体例
としては、
・メチルポリシロキサン、
・メヂルフェニルボリシロギサン、
・ジメチルシロキサン・メチル（ポリオキシエチレン）
シロキサン共重合体、
・ジメチルシロキサン・メチル（ポリオキンエチレン・
ポリオキシプロピレン）シロキサン共重合体、・メチル
ポリシロキサンエマルジョン等である。The type of silicone may be any of oil type, emulsion type, and silicone surfactant. Specific examples include: ・Methylpolysiloxane, ・Medylphenylborisirogysan, ・Methyl dimethylsiloxane (polyoxyethylene)
Siloxane copolymer, ・Dimethylsiloxane・Methyl (polyoxane ethylene・
Polyoxypropylene) siloxane copolymers, methylpolysiloxane emulsions, etc.
上記のシリコンは、組成物中に０．０５〜２０重量部、
好ましくは０．５〜１０重量部配合配合る。この配合量
が０．０５重量部未満では、ポリプロピレン、ホーロー
、ステンレス、ＦＲＰ等の材質からなる浴室用具の表面
保護と艶を与える効果が不十分であり、２０重量部を越
えて配合しても本発明の効果に著しい向上が認められな
い。The above silicone is contained in the composition in an amount of 0.05 to 20 parts by weight,
Preferably, it is blended in an amount of 0.5 to 10 parts by weight. If the amount is less than 0.05 parts by weight, the effect of protecting and glossing the surface of bathroom utensils made of materials such as polypropylene, enamel, stainless steel, FRP, etc. will be insufficient, and even if it is more than 20 parts by weight, No significant improvement was observed in the effects of the present invention.
次に、本発明の洗浄剤組成物の製剤の実施例を挙げて、
本発明をさらに詳細に説明するが、本発明はこれにより
何ら制限されるものではない。Next, examples of formulations of the cleaning composition of the present invention will be given,
The present invention will be explained in more detail, but the present invention is not limited thereto.
なお実施例、比較例中の■〜＠は以下の如くである。Note that ■ to @ in Examples and Comparative Examples are as follows.
■ポリオキシエチレン（ｎ・１０）アルキル（ＣＩ２）
エーテル
■ＣＩ２アルキルベンゼンスルホン酸ナトリウム■ミラ
ノールＯ８（ミラノール社製両性界面活性剤）
■エヂレングリコールモノブチルエーテル■クエン酸
■エチレンジアミン四酢酸二ナトリウム■メヂルボリン
ロキサン（１００ｃｓ）■ジメチルシロキサン・メチル
（ポリオキシエチレン）ソロキサン共重合体
■ＢＹ２２’−００’７（）−レ・シリコーン社製シリ
コーンエマルジョン）
［相］ケーソンＣＧ（ローム・アンド・ハース社製殺菌
剤）
■エタノール
＠水
実施例１
実施例３
５重量部
６重量部
１重量部
３重量部
２重量部
２重量部
１０重量部
３重量部
１０重量部
０．０５重量部
実施例２
７重量部
８重量部
１重量部
５重量部
０．５重量部
０．０５重量部
７８．４５重量部
１００重量部
実施例４
０５重量部
１重量部
０．５重量部
０２重量部
０．５重量部
０．５重量部
５重量部
９１．８重量部
１００重量部
５
６
次に、実施例で得た本発明の洗浄剤組成物の効果につい
て、実験例を挙げて説明するが、実験に先たち比較のた
め、次に示す洗浄剤組成物を調整した。■Polyoxyethylene (n・10) alkyl (CI2)
Ether ■Sodium CI2 alkylbenzene sulfonate ■Milanol O8 (ampholytic surfactant manufactured by Milanol) ■Ethylene glycol monobutyl ether ■Citric acid ■Disodium ethylenediaminetetraacetate ■Medylborinoxane (100cs) ■Dimethylsiloxane methyl (polymer) (oxyethylene)soloxane copolymer ■BY22'-00'7 ()-Silicone emulsion manufactured by Le Silicone) [Phase] Caisson CG (bactericide manufactured by Rohm and Haas) ■Ethanol @ water Example 1 Example 3 5 parts by weight 6 parts by weight 1 part by weight 3 parts by weight 2 parts by weight 2 parts by weight 10 parts by weight 3 parts by weight 10 parts by weight 0.05 parts by weight Example 2 7 parts by weight 8 parts by weight 1 part by weight 5 parts by weight 0. 5 parts by weight 0.05 parts by weight 78.45 parts by weight 100 parts by weight Example 4 05 parts by weight 1 part by weight 0.5 parts by weight 02 parts by weight 0.5 parts by weight 0.5 parts by weight 5 parts by weight 91.8 parts by weight parts 100 parts by weight 5 6 Next, the effects of the cleaning compositions of the present invention obtained in the examples will be explained using experimental examples. It was adjusted.
比較例１ ■ ２重量部 ■ ６重量部 ■ ０．５重量部 ＠ｌ ０１０５重量部 比較例２ １０重量部 ２重量部 ５重量部 ８３重量部 比較例３ ■ ２０重量部 上記の洗浄剤組成物を以下の方法に従って評価した。Comparative example 1 ■ 2 parts by weight ■ 6 parts by weight ■ 0.5 parts by weight @l 0105 parts by weight Comparative example 2 10 parts by weight 2 parts by weight 5 parts by weight 83 parts by weight Comparative example 3 ■ 20 parts by weight The above cleaning composition was evaluated according to the following method.
（評価法）
湯垢汚れが付着したポリプロピレン製の湯桶に、実施例
および比較例で得た本発明の洗浄剤組成物をかけ、桶表
面を約５００ｇ重の加重でウレタン製のスポンジにて１
０回往復して擦り、汚れの除去状態および表面の艶、感
触を判定した。(Evaluation method) The cleaning composition of the present invention obtained in the Examples and Comparative Examples was poured onto a polypropylene bath with scale stains, and the surface of the bath was rubbed with a urethane sponge under a weight of about 500 g.
The surface was rubbed back and forth 0 times, and the state of dirt removal and the gloss and feel of the surface were evaluated.
１００重量部
以上の実験から本発明の洗浄剤組成物は、ポリプロピレ
ン、ポーロー、ステンレス、ＦＲＰ等の材質からなる浴
室用具に付着した湯垢汚れに対し、優れた洗浄力を発揮
すると同時に、浴室用具の表面の保護と艶出しを行うこ
とが出来るという、従来の洗浄剤にはなかった効果がも
たらされる。Experiments using 100 parts by weight or more have shown that the cleaning composition of the present invention exhibits excellent cleaning power for cleaning scale stains on bathroom utensils made of materials such as polypropylene, porous, stainless steel, and FRP, and at the same time shows that It has the ability to protect and polish surfaces, an effect not found in conventional cleaning agents.
９9
Claims (3)
物。(1) A cleaning composition characterized by containing silicone.
、それぞれ下記式IIを示し、ＸおよびＹは、０〜２００
０である。） ▲数式、化学式、表等があります▼ （式II中、ｌ、ｍおよびｎはｌ≧０、ｍ≧０、ｎ≧０で
あり、Ｒ′は、同じまたは異なってアルキル基またはフ
ェニル基を表す。）｝で表されるシリコンを０．０５〜
２０重量部配合することを特徴とする洗浄剤組成物。(2) Formula I below ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ {(In formula I, R_1, R_2, R_3 and R_4 each represent the following formula II, and
It is 0. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In formula II, l, m and n are l≧0, m≧0, n≧0, and R' is the same or different and represents an alkyl group or a phenyl group. 0.05~
A cleaning composition characterized by containing 20 parts by weight.
５〜２０重量部、金属イオン封鎖剤０．１〜１０重量部
および下記式 I ▲数式、化学式、表等があります▼ ｛（式 I 中、Ｒ＿１、Ｒ＿２、Ｒ＿３およびＲ＿４は
、それぞれ下記式IIを示し、ＸおよびＹは、０〜２００
０である。） −（ＣＨ＿２）＿ｎ−（ＯＣ＿２Ｈ＿４）＿ｍ−（ＯＣ
＿３Ｈ＿５）＿１−Ｒ′II （式II中、ｌ、ｍおよびｎはｌ≧０、ｍ≧０、ｎ≧０で
あり、Ｒ′は、同じまたは異なってアルキル基またはフ
ェニル基を表す。）｝で表されるシリコンを０．０５〜
２０重量部配合することを特徴とする洗浄剤組成物。(3) 0.1 to 30 parts by weight of surfactant, 0.0 parts by weight of water-soluble solvent.
5 to 20 parts by weight, 0.1 to 10 parts by weight of metal ion sequestering agent, and the following formula I ▲ Numerical formulas, chemical formulas, tables, etc. , X and Y are 0 to 200
It is 0. ) −(CH_2)_n-(OC_2H_4)_m-(OC
_3H_5)_1-R'II (In formula II, l, m and n are l≧0, m≧0, n≧0, and R's are the same or different and represent an alkyl group or a phenyl group.)} Silicon expressed as 0.05~
A cleaning composition characterized by containing 20 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1336223A JP2797571B2 (en) | 1989-12-27 | 1989-12-27 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1336223A JP2797571B2 (en) | 1989-12-27 | 1989-12-27 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03197596A true JPH03197596A (en) | 1991-08-28 |
| JP2797571B2 JP2797571B2 (en) | 1998-09-17 |
Family
ID=18296909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1336223A Expired - Fee Related JP2797571B2 (en) | 1989-12-27 | 1989-12-27 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2797571B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05311196A (en) * | 1992-05-14 | 1993-11-22 | T Paul Kk | Sterilizing detergent |
| JPH07109486A (en) * | 1993-10-15 | 1995-04-25 | Lion Corp | Washing of clothes |
| WO1996000274A1 (en) * | 1994-06-24 | 1996-01-04 | Unilever Plc | Glass and ceramic cleaning compositions |
| JPH08325559A (en) * | 1995-06-01 | 1996-12-10 | Yokohama Yushi Kogyo Kk | Polishing treatment auxiliary composition and elimination of stain using the same |
| JP2001011492A (en) * | 1999-06-30 | 2001-01-16 | Lion Corp | Liquid detergent composition |
| WO2006018917A1 (en) * | 2004-08-20 | 2006-02-23 | Kobayashi Pharmaceutical Co., Ltd. | Antifouling agent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5183608A (en) * | 1975-01-21 | 1976-07-22 | Uemura Kogyo Kk | Yokusosenjoyono soseibutsu |
| JPS587496A (en) * | 1981-06-30 | 1983-01-17 | エス・シ−・ジヨンソン・アンド・サン・インコ−ポレ−テツド | Cleaner polishing agent for fiber glass and ceramic surface |
| JPS58206694A (en) * | 1982-05-28 | 1983-12-01 | ダスキンフランチヤイズ株式会社 | Bath boiler detergent composition |
-
1989
- 1989-12-27 JP JP1336223A patent/JP2797571B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5183608A (en) * | 1975-01-21 | 1976-07-22 | Uemura Kogyo Kk | Yokusosenjoyono soseibutsu |
| JPS587496A (en) * | 1981-06-30 | 1983-01-17 | エス・シ−・ジヨンソン・アンド・サン・インコ−ポレ−テツド | Cleaner polishing agent for fiber glass and ceramic surface |
| JPS58206694A (en) * | 1982-05-28 | 1983-12-01 | ダスキンフランチヤイズ株式会社 | Bath boiler detergent composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05311196A (en) * | 1992-05-14 | 1993-11-22 | T Paul Kk | Sterilizing detergent |
| JPH07109486A (en) * | 1993-10-15 | 1995-04-25 | Lion Corp | Washing of clothes |
| WO1996000274A1 (en) * | 1994-06-24 | 1996-01-04 | Unilever Plc | Glass and ceramic cleaning compositions |
| JPH08325559A (en) * | 1995-06-01 | 1996-12-10 | Yokohama Yushi Kogyo Kk | Polishing treatment auxiliary composition and elimination of stain using the same |
| JP2001011492A (en) * | 1999-06-30 | 2001-01-16 | Lion Corp | Liquid detergent composition |
| WO2006018917A1 (en) * | 2004-08-20 | 2006-02-23 | Kobayashi Pharmaceutical Co., Ltd. | Antifouling agent composition |
| JP2006057027A (en) * | 2004-08-20 | 2006-03-02 | Kobayashi Pharmaceut Co Ltd | Stainproofing agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2797571B2 (en) | 1998-09-17 |
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