JPH0314614B2 - - Google Patents
Info
- Publication number
- JPH0314614B2 JPH0314614B2 JP55149345A JP14934580A JPH0314614B2 JP H0314614 B2 JPH0314614 B2 JP H0314614B2 JP 55149345 A JP55149345 A JP 55149345A JP 14934580 A JP14934580 A JP 14934580A JP H0314614 B2 JPH0314614 B2 JP H0314614B2
- Authority
- JP
- Japan
- Prior art keywords
- coating layer
- resin
- photocurable coating
- weight
- room temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011247 coating layer Substances 0.000 claims description 46
- 229920003023 plastic Polymers 0.000 claims description 18
- 239000004033 plastic Substances 0.000 claims description 18
- 239000011521 glass Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 230000001678 irradiating effect Effects 0.000 claims description 3
- 229920005989 resin Polymers 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- 239000000463 material Substances 0.000 description 10
- 239000000113 methacrylic resin Substances 0.000 description 9
- 239000003504 photosensitizing agent Substances 0.000 description 9
- -1 polyethylene terephthalate Polymers 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000000016 photochemical curing Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 125000003396 thiol group Chemical group [H]S* 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 150000007517 lewis acids Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000004431 polycarbonate resin Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 2
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 239000012954 diazonium Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- GRDGBWVSVMLKBV-UHFFFAOYSA-N (2-amino-5-nitrophenyl)-(2-chlorophenyl)methanone Chemical compound NC1=CC=C([N+]([O-])=O)C=C1C(=O)C1=CC=CC=C1Cl GRDGBWVSVMLKBV-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- YNSNJGRCQCDRDM-UHFFFAOYSA-N 1-chlorothioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl YNSNJGRCQCDRDM-UHFFFAOYSA-N 0.000 description 1
- HEJLFBLJYFSKCE-UHFFFAOYSA-N 2',3'-Dihydroxyacetophenone Chemical compound CC(=O)C1=CC=CC(O)=C1O HEJLFBLJYFSKCE-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 208000003028 Stuttering Diseases 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- KVXNKFYSHAUJIA-UHFFFAOYSA-N acetic acid;ethoxyethane Chemical compound CC(O)=O.CCOCC KVXNKFYSHAUJIA-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Manufacturing Optical Record Carriers (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
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ã¯ã®è£œé æ³ã«é¢ãããDETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a reproduction disk for information recording, in which recorded information is read out by reflection of a laser beam.
ã¬ãŒã¶ãŒå
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å ±ãèª
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ãããŠããã The method of scanning a laser beam over a disk and reading recorded information based on the presence or absence of minute pits can significantly increase the recording density, and also makes it easy to manufacture a large number of duplicate plates from a single stamper. Because it can be used for many different purposes, it is expected to be used for things such as image and sound reproduction.
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ç±å¯å¡æ§æš¹èãçšã150â以äžã®é«æž©ã§å°åºæå
ããã¬ã¹æåã«ãã€ãŠç±å¯å¡æ§æš¹èã«ã¹ã¿ã³ããŒ
ã®ãããã転åããããšãåŸæ¥ããè©Šã¿ãããŠã
ããããããèšé²ã«çšãããããããã¯ãéåžžé·
ãåã³åŸã2Ό以äžã§æ·±ãã¯0.5Ό以äžåŸ®çŽ°ãªãã®ã§
ããçºã«ã粟床ã®ãããããã®åçãå°é£ã§ã
ããçç£å·¥çšã§ã®äžè¯çãé«ããšããæ¬ ç¹ãã
ãã The duplicate disk used in this recording/reproduction method is made of thermoplastic resin such as methacrylic resin or vinyl chloride resin, and the pits of the stamper are transferred to the thermoplastic resin by injection molding or press molding at a high temperature of 150°C or higher. This has been attempted in the past. However, the pits used for recording are usually microscopic, with a length and diameter of less than 2ÎŒ and a depth of less than 0.5ÎŒ, making it difficult to reproduce pits with high precision and resulting in a high defect rate in the production process. It has the disadvantage of being expensive.
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æ Œå¥ã®é«æž©åŠçãçšããããŠçç£æ§ãè¯å¥œã§ãã€
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ãšãç®çãšããã The present invention overcomes the drawbacks of the conventional manufacturing method for information recording duplicating disks, and makes it possible to achieve good productivity and save energy in the manufacturing process without using special high-temperature treatment as described above. The purpose of the present invention is to provide a method for manufacturing a new information recording reproduction disk.
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æ³ã§ããã That is, the present invention forms a photocurable coating layer having a viscosity of 2000 poise or more at room temperature and plasticity at room temperature or 100°C or less on a plastic or glass plate, and forms the photocurable coating layer with fine irregularities. Pressure molded by overlapping the engraved stamper,
This is a method for manufacturing a reproduction disk for information recording, characterized in that the coating layer is cured by irradiating ultraviolet rays from the surface of a plastic or glass plate, and then the stamper is removed from the mold.
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It is an ultraviolet transmitting layer during the photocuring reaction of the photocurable coating layer, and also serves as a support for the recording uneven pattern formed by the photocurable coating layer.
It becomes a transparent layer for laser light during recording and reproduction. Therefore, it is preferable to use a plastic material or glass that has good light transmittance and does not cause deformation such as warping or twisting, and plastic plates are usually made of methacrylic resin, vinyl chloride resin, polystyrene resin, acrylonitrile, styrene, etc. Vinyl polymers or copolymer resins such as polymer resins, polycarbonate resins, polyethylene terephthalate resins,
Polybutylene terephthalate resin etc. are used,
In particular, methacrylic resin having good light transmittance is preferred.
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ããã¬ããªã«ãåºæ¥ãããã The above plastic plates are usually manufactured by injection molding, extrusion molding, press molding or casting.
It is used by molding into a smooth plate with a thickness of 0.5 to 3 mm. The photocurable coating layer having plasticity of the present invention has a viscosity of 2000 poise or more at room temperature and a viscosity of 100 poise or more at room temperature.
It is a material that has plasticity at a temperature of 0.degree. That is, the above-mentioned photocurable coating layer is superimposed on a stamper with fine pits, and then heated at room temperature or
When pressed at a temperature below 100â and a pressure of usually 5 to 100 kg/ cm2 , the photocurable coating layer is easily embedded in the recesses of the stamper, and then the curing reaction progresses when UV rays are irradiated through the plastic or glass plate. When it hardens and loses its plasticity at room temperature and is removed from the stamper, a replica with the original pattern reversed is created.
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ïŒã20ÎŒçšåºŠã奜ãŸããã When producing a duplicate disk by the method of the present invention, a large number of disks are usually duplicated with one stamper, but from the viewpoint of the productivity of the duplicate disk and the life of the stamper, the photocurable coating layer is not used in the present invention. is not formed on a stamper, but on a plastic or glass plate. The method for forming the photocurable coating layer is to apply the material forming the photocurable coating layer onto a plastic or glass plate, and usually the material forming the photocurable coating layer is coated with an organic solvent. Alternatively, it can be formed by diluting it with water to a viscosity that is easy to apply, and then evaporating and removing the organic solvent or water in a dryer. Alternatively, a film for a photocurable coating layer may be formed as described above on a separate support such as release paper, and the film may be laminated onto the above plastic or glass plate to form a photocurable coating layer. . The thickness of the photocurable coating layer should be 2ÎŒ or more, but
The thickness is preferably about 5 to 20Ό.
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åãæããååç©ã The material forming the photocurable coating layer of the present invention has a viscosity of 2000 poise or more at room temperature and
Essentially any material can be used as long as it has plasticity at temperatures below 100°C, is photocured by irradiation with ultraviolet rays, and transmits light after photocuring.In general, resin components and photocurable materials can be used. It consists of a photosensitive resin-forming component and a photosensitizer. Examples of the above resin components include acrylic resin, polyester resin, epoxy resin, polyurethane resin, polyamide resin, vinyl chloride resin, polyvinyl petral resin, cellulose derivative resin, etc., and these resin components have photocurability. It doesn't matter if you have it or not. In order for these resin components to participate in the photocuring reaction and be incorporated into a crosslinked structure, (1) introducing an ethylenically unsaturated double bond into the terminal or side chain of the resin;
A method of crosslinking by a radical polymerization reaction using free radicals generated by a photosensitizer, (2) introducing an alkaline double bond into the end or side chain of the resin,
A method of promoting addition reaction with thiol groups and crosslinking by co-existing a photosensitizer and a thiol-containing compound, (3)
Introducing a thiol group to the terminal or side chain of the resin,
A method in which a resin-forming component having an allylic double bond and a photosensitizer coexist to cause additional crosslinking during ultraviolet irradiation; (4) an epoxy group is introduced into the terminal or side chain of the resin, and Therefore, there is a method in which epoxy groups are cationically ring-opened and crosslinked using a sensitizer that liberates a Lewis acid.
In this case, the above photocurable resin forming components may or may not be used together. However, from the viewpoint of moldability, it is desirable that the photocurable resin component described above has a softening point of 100° C. or less, preferably room temperature or below, and a viscosity at room temperature of 2000 poise or more.
When the resin components are composed of only those without photocurability, it is essential to use the photocurable resin forming components in combination. The above-mentioned photocurable resin-forming component is a low molecular weight substance that usually has a molecular weight of 1000 or less and can cause the photocurable coating layer to lose its plasticity through a photocuring reaction, such as (i) a radical polymerizable component; A compound having an ethylenic double bond and having a boiling point of 200°C or more as a monomer or a compound having two or more ethylenic double bonds in one molecule.
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ããå€äŸ¡ã¢ãªã«ååç©ã(iii) A polyvalent allylic compound having two or more allylic double bonds in one molecule.
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ã§ããããšã奜ãŸããã Normally, the above-mentioned photocurable resin forming components are not suitable when used alone in the method of the present invention because they have low viscosity and high stickiness, making them difficult to handle and causing a large amount of protrusion during pressure molding. It is preferable to use the mixture together with the viscosity of 2000 poise or more at least at room temperature.
As the photosensitizer used in combination with the above resin component and photocurable resin forming component, known photosensitizers that are activated by ultraviolet rays can be used, and they can be roughly divided into (a) Photosensitizer that generates radicals
(b) There are photosensitizers that generate Lewis acids when irradiated with ultraviolet rays. Examples of sensitizers belonging to (a) include benzophenones such as benzophenone and chlorobenzophenone, and anthraquinones such as ethyl anthraxinone. benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isobutyl ether, acetophenones such as diethoxyacetophenone, dihydroxyacetophenone, thioxanthone such as chlorothioxanthone, and benzyl ketals. Examples of sensitizers belonging to (b) include diazonium salts, sulfonium salts, and iodonium salts of Lewis acids such as boron fluoride ions and phosphorus fluoride ions. The proportion of the photosensitizer used is usually preferably 1 to 5% by weight based on the total amount of the resin component and resin forming component.
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ãã€ãããªãã Furthermore, as a component of the photocurable coating layer of the present invention, for example, silicon, which improves the releasability from the stamper,
Mold release aids such as wax, fatty acid metal salts, adhesion improving aids such as silane coupling agents, phosphate esters, titanium coupling agents, etc. that improve adhesion to plastic or glass plates, and photocuring reactions. For example, reaction accelerators such as tertiary amines, plasticizers, and auxiliary agents such as antioxidants may be added to the extent that they do not impede the achievement of the objects of the present invention.
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å·®ã0.05以äžã§ããããšãç¹ã«å¥œãŸããã After the photocurable coating layer used in the present invention, which is composed of the above-mentioned components, is cured by irradiation with ultraviolet rays or the like, when reproducing the recording by applying laser light from the plastic or glass surface, Since it is necessary to transmit light, when using multiple components, it is necessary to consider their mutual compatibility and use them in combination, and the refractive index of the photocurable coating layer is is preferably 1.4 to 1.6,
It is particularly preferred that the difference in refractive index with the plastic or glass plate used is 0.05 or less.
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以äžã®æ··åç©ãçšããã In the present invention, the organic solvent or water used to dilute the material forming the photocurable coating layer may be one that dissolves these materials well and is easily removed by evaporation after application. Typical examples include hydrocarbons such as toluene, xylene, solvent naphtha, hexane, pentane, and cyclohexane, esters such as ethyl acetate and butyl acetate, ethanol, isopropanol, Alcohols such as butanol, diacetone alcohol, cyclohexanol, ketones such as methyl ethyl ketone, methyl isobutyl ketone, isophorone, cyclohexanone, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, ethylene glycol monoethyl ether, acetate, etc. Examples include glycol ethers or esters thereof, organic solvents such as nitrogen-containing solvents such as dimethylformamide, N-methylpyrrolidone, and dimethylacetamide, and water, and one or a mixture of two or more of these may be used.
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ãããŠèšé²ãåçãè¡ãå Žåã«ãæçšã§ããã Ultraviolet rays are usually irradiated using a lamp such as a high-pressure mercury lamp or metal halide lamp with a power output of 50 to 200 W/cm.
Photocuring can be completed by irradiation for a short time of less than 1 minute, and the molding of a replica disk for information recording is completed by removing the mold from the stamper.
Furthermore, a metal vapor-deposited reflective layer for laser light is usually formed on the photocurable coating layer by vacuum vapor deposition, stuttering, or ion plating of a metal such as aluminum, and a protective coating is applied to the metal vapor-deposited reflective layer. information by laminating the plastic or glass sides of this single-sided plate with adhesive to form a double-sided plate, or by gluing the vapor-deposited sides together with adhesive to form a double-sided plate. Recording reproduction discs are manufactured. That is, the method for manufacturing a reproduction disk for information recording of the present invention can be applied both when reproducing recorded information by applying a laser beam from the plastic or glass plate side, and when performing recording and reproducing by applying a laser beam from the metal vapor deposition layer side. Useful.
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é²ä¿ç®¡çšã«æ¥µããŠæçšã§ããã The thus produced duplicate disks are extremely useful for video, audio, and record keeping purposes for computers and the like.
以äžã«æ¬çºæã®ä»£è¡šçãªå®æœäŸã瀺ãã Representative examples of the present invention are shown below.
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70 parts by weight of the copolymer, 30 parts by weight of trimethylolpropane trimethacrylate, and 30 parts by weight of benzoin ethyl ether were dissolved in 100 parts by weight of ethylene glycol monoethyl ether as a solvent, and coated with a reverse roll coater at 80°C for 30 minutes. The solvent was evaporated off by drying for a few minutes to form a photocurable coating layer with a thickness of 10 Όm. This photocurable coating layer had a viscosity of 3000 poise at room temperature and exhibited some tackiness and plasticity at room temperature.
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ãªãã€ã¹ã¯ãšããŠè¯å¥œãªç»åãåŸãããã Next, the photocurable coating layer was pressed onto a nickel stamper with fine irregularities, a press pressure of 50 kg/cm 2 was applied for 30 seconds, and after the pressure was released, it was heated under a high-pressure mercury lamp with an output of 100 W/cm every minute. The photocurable coating layer was cured by irradiating ultraviolet rays from the surface of the methacrylic resin plate while passing through the plate at a speed of 1 m, and then removed from the mold. Next, a reflective layer was formed by vapor-depositing the photocurable coating layer using an aluminum vacuum vapor deposition apparatus, and an acrylic lacquer was applied to the aluminum-deposited surface and dried to produce a reproduction disc for information recording. The thus-manufactured duplicate disk had good transfer of the unevenness of the stamper, formed sharp pits, and produced a good image as a video disk.
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1 mol of phthalic anhydride and 4 mol of propylene glycol
Unsaturated polyester resin obtained by condensing moles
A methacrylic resin plate similar to that used in Example 1 was prepared by dissolving 80 parts by weight of diallylphthalate, 20 parts by weight of diallylphthalate, 2 parts by weight of benzophenone, and 0.5 parts by weight of dimethylbenzylamine as a photocuring reaction accelerator in 100 parts by weight of toluene. It was applied in the same manner and dried. This photocurable coating layer had a viscosity of 2200 poise at room temperature and exhibited some tackiness and plasticity at room temperature.
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ãããŠããã¹ãã€ãã®ããå¯å¡æ§ã瀺ããã The photocurable coating layer was formed using 1 mol of trimethylolpropane and 1 mol of polycaprolactone with a molecular weight of 1000.
Add 3 parts by weight of methylanthraxinone to 250 parts by weight of ethyl acetate solution and dissolve 40% by weight of a polyurethane resin having a double bond at the end obtained by polycondensing 4 mols of isophorone diisocyanate and 4 mols of hydroxyethyl acrylate. The coating was applied on the same methacrylic resin plate as used in Example 1 and dried. This photocurable coating layer had a viscosity of 2,500 poise at room temperature and exhibited slightly sticky plasticity at room temperature.
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ç»åãäžãã The photocurable coating layer is made of 40 parts by weight of a copolymer resin of 80% by weight of vinyl chloride and 20% by weight of vinyl acetate, 30% by weight of methyl methacrylate, and 50% by weight of ethyl acrylate.
and 30 parts by weight of an epoxy group-containing acrylic resin obtained by copolymerizing 20% by weight of glycidyl methacrylate, 30 parts by weight of bisphenol A diglycidyl ether, 3 parts by weight of boron trifluoride/allyl diazonium, 75 parts by weight of methyl ethyl ketone, and ethylene glycol. It was dissolved in a mixed solvent containing 75 parts by weight of monoethyl ether acetate, coated on the above transparent plate in the same manner as in Example 1, and dried to obtain a photocurable coating layer with a thickness of 15 ÎŒm. This photocurable coating layer has a viscosity at room temperature of
It had a poise of 3500 poise and showed almost no tackiness at room temperature, but showed tackiness when heated to 60°C. This photocurable coating layer was pressed onto a nickel stamper, heated to 60°C, and a press pressure of 50 kg/cm 2 was applied for 30 seconds. Thereafter, the same procedure as in Example 1 was carried out to obtain a reproduction disc for information recording. Ta. The thus manufactured duplicate disk had good transfer of the irregularities of the master disk, formed sharp pits, and gave a good image as a video disk.
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ãããããªãã€ã¹ã¯ãšããŠè¯å¥œãªç»åãäžãããExample 5 Information was recorded in the same manner as in Example 1 using a 1.0 mm thick transparent polycarbonate resin plate instead of the transparent methacrylic resin plate used in Example 1 and using the photocurable coating layer shown below. A replica disk was manufactured. The photocurable coating layer is made of 70 parts by weight of a polyester resin having a thiol group and a softening point of 70°C obtained by an esterification reaction between a hydroxyl group-terminated polyester resin and thioglycolic acid, and 15 parts by weight of diarylidene pentaerythritol. , 15 parts by weight of triallyl isocyanurate and 2 parts by weight of diethoxyacetophenone were dissolved in 100 parts by weight of ethylene glycol monoethyl ether, and the solution was coated on the above polycarbonate resin plate in the same manner as in Example 1, and dried. This photocurable coating layer had a viscosity of 2300 poise at room temperature and exhibited some stickiness and plasticity at room temperature. Thereafter, a replica disk for information recording was manufactured in exactly the same manner as in Example 1. The information recording reproduction disc manufactured in this manner had good transfer of the unevenness of the master disc, formed sharp pits, and provided a good image as a video disc.
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芳å¯ãããªãã€ãã In addition, in the duplicate disks obtained in Examples 1 to 5, no protrusion of the material forming the photocurable coating layer was observed.
Claims (1)
ãç²åºŠã2000ãã€ãºä»¥äžã§äžã€åžžæž©åã¯100â以
äžã§å¯å¡æ§ãæããå 硬åæ§è¢«èŠå±€ã圢æããå
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æ å ±èšé²çšè€è£œãã€ã¹ã¯ã®è£œé æ³ã1. Form a photocurable coating layer on a plastic or glass plate with a viscosity of 2000 poise or more at room temperature and plasticity at room temperature or below 100°C, and apply the photocurable coating layer to a stamper with fine irregularities. 1. A method for manufacturing a reproduction disc for information recording, which comprises: superimposing the coating layer on the plastic or glass plate, curing the coating layer by irradiating ultraviolet rays from the surface of the plastic or glass plate, and then removing the stamper from the mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14934580A JPS5772823A (en) | 1980-10-27 | 1980-10-27 | Production of duplicate disk for information recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14934580A JPS5772823A (en) | 1980-10-27 | 1980-10-27 | Production of duplicate disk for information recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5772823A JPS5772823A (en) | 1982-05-07 |
| JPH0314614B2 true JPH0314614B2 (en) | 1991-02-27 |
Family
ID=15473081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14934580A Granted JPS5772823A (en) | 1980-10-27 | 1980-10-27 | Production of duplicate disk for information recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5772823A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101198903B (en) * | 2005-06-10 | 2011-09-07 | 奥èŽèŸŸå ç¹å ¬åž | Pattern replication with intermediate stamp |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5333244A (en) * | 1976-09-09 | 1978-03-29 | Kanegafuchi Chem Ind Co Ltd | Apparatuses for preparating coagulated latexes |
-
1980
- 1980-10-27 JP JP14934580A patent/JPS5772823A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5333244A (en) * | 1976-09-09 | 1978-03-29 | Kanegafuchi Chem Ind Co Ltd | Apparatuses for preparating coagulated latexes |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5772823A (en) | 1982-05-07 |
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