JPH0259480A - Production of abrasive for jeans washing and washing method for jeans - Google Patents

Production of abrasive for jeans washing and washing method for jeans

Info

Publication number
JPH0259480A
JPH0259480A JP63209671A JP20967188A JPH0259480A JP H0259480 A JPH0259480 A JP H0259480A JP 63209671 A JP63209671 A JP 63209671A JP 20967188 A JP20967188 A JP 20967188A JP H0259480 A JPH0259480 A JP H0259480A
Authority
JP
Japan
Prior art keywords
jeans
parts
mixture
added
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63209671A
Other languages
Japanese (ja)
Other versions
JPH0518787B2 (en
Inventor
Tokuyoshi Fujishima
藤島 篤義
Masatomo Baba
馬場 正知
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KYUSHU HAITEKU KOGYO KK
Original Assignee
KYUSHU HAITEKU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KYUSHU HAITEKU KOGYO KK filed Critical KYUSHU HAITEKU KOGYO KK
Priority to JP63209671A priority Critical patent/JPH0259480A/en
Publication of JPH0259480A publication Critical patent/JPH0259480A/en
Publication of JPH0518787B2 publication Critical patent/JPH0518787B2/ja
Granted legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0093Treatments carried out during or after a regular application of treating materials, in order to get differentiated effects on the textile material
    • D06B11/0096Treatments carried out during or after a regular application of treating materials, in order to get differentiated effects on the textile material to get a faded look

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

PURPOSE:To obtain the title abrasive stone which is large in wear resistance and has a uniform structure by adding water to the kneaded material of silica sand and glass frit and mixing the mixture and furthermore adding carboxymethyl cellulose and sufficiently mixing this mixture, drying and calcining it. CONSTITUTION:After 5-30 pts.wt. glass frit is added to 100 pts.wt. silica sand and the mixture is kneaded, 15-40 pts.wt. water is added and mixed. Then 2-10 pts.wt. CMC is added to the mixture and after this mixture is mixed until toughness is sufficiently caused, it is pressurized and molded. This molded material is dried and thereafter calcined at 900-980 deg.C to obtain abrasive for jeans washing. Further as a washing method, both the above-mentioned porous abrasive and a bleaching agent aq. soln. are introduced into a freely rotatable tank and the porous abrasive is sufficiently impregnated with the bleaching agent aq. soln. Then the residual bleaching agent aq. soln. is discharged and thereafter an absorbent of the bleaching agent is distributed. Then the colored jeans are introduced into the tank and this tank is rotated on its axis and thereafter the jeans are taken out, washed with water and neutralized.

Description

【発明の詳細な説明】 (産業上の利用分野〉 本発明は深色に染色されたジーンズの脱色方法に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for decolorizing jeans dyed in a deep color.

〈従来の技術〉 例えばインジゴでブルーに染められたジーンズをはじめ
グリーンやレッド等信の色に染められた布地で作られた
服あるいは袋物を全体的又は部分的に脱色する事が近年
なされている。そしてこの様な方法で用いられている研
摩石は、従来天然の軽石であり、脱色剤を含浸した天然
の軽石を、ジーンズと共にあるタンク内で混練する事で
脱色している。また一部の方法だが、プラスチック製の
研摩石も使われている様である。
<Prior art> For example, in recent years, it has been possible to completely or partially bleach clothes or bags made from fabrics dyed in indigo colors, such as jeans dyed blue, green, or red. . The polishing stone used in this method is conventionally a natural pumice stone, and the color is removed by kneading the natural pumice impregnated with a bleaching agent in a tank that is included with the jeans. In some cases, plastic abrasive stones are also used.

〈発明が解決しようとする課題〉 上記した従来からの方法の中で、天然の軽石を用いる方
法は、研摩石の摩減量が大で、多量のスラッジが発生し
、その排出処理が煩雑であると共に、該スラッジがズボ
ンのポケット等へ入り込みこれを取出すのも煩雑であり
、かつ又当然に摩滅骨は補給しなければならない。又天
然の軽石である為に、品質のバラツキが大で、脱色時の
コントロールが難しく毎回その時の軽石の特性を考慮し
て条件を変える必要がある。例えば、湿度が高いと脱色
剤の吸収が悪いばかりでなく、軽石内部に水分を保存す
るので、希望濃度の脱色剤を保持せしめる事が出来ない
等である。なお軽石内部の保有水分を乾燥除去するのは
非常に手間と時間を要するのである。
<Problems to be solved by the invention> Among the conventional methods described above, the method using natural pumice has a large amount of abrasion of the polishing stone, generates a large amount of sludge, and its discharge treatment is complicated. At the same time, the sludge gets into the pockets of pants, etc., and it is troublesome to take it out, and of course, the worn bones must be replenished. Also, since it is a natural pumice stone, its quality varies widely, and it is difficult to control when decolorizing it, so it is necessary to change the conditions each time taking into account the characteristics of the pumice stone at that time. For example, if the humidity is high, not only will the absorption of the bleaching agent be poor, but also moisture will be stored inside the pumice stone, making it impossible to maintain the desired concentration of the bleaching agent. It is noted that drying and removing the moisture retained inside pumice requires a great deal of effort and time.

また一部で実施されているプラスチック製研磨石を用い
る方法は、気孔が不均一で脱色剤の吸着保有能力が低い
ので脱色の仕上がりがよくない。
In addition, the method of using plastic polishing stones, which is practiced in some places, has uneven pores and has a low ability to adsorb and hold decolorants, resulting in poor decolorization results.

本発明では前記した如き従来法の欠点を解消し、耐摩耗
性が大で、均一構造を持つ研摩石の製法及びそれを用い
たウォッシュ方法を提供することを目的とするものであ
る。
The object of the present invention is to eliminate the drawbacks of the conventional methods as described above, and to provide a method for producing an abrasive stone with high wear resistance and a uniform structure, and a washing method using the same.

く課題を解決する為の手段〉 上記本発明の目的は、次の手段を採用する事により達成
出来る。即ち研摩石の製造方法として瓜珪砂100重量
部に対し、ガラスフリット5〜30重量部添加した混合
物を混練し、次いで水15〜40重量部を添加混合し、
更にカルボキシメチルセルロース2〜10重量部を添加
し十分に粘りが生起するまで混合し、該混合物を加圧成
型し、次いで乾燥の後焼成するの方法であり、又ウォッ
シュ方法としては、自転自在に配設されたタンクに、珪
砂を主成分としそれにガラスフリットを加えた混合物を
焼成して得た多孔質研磨石と、漂白剤水溶液とを入れ、
漂白剤水溶液を多孔質研磨石に十分含浸せしめた後、残
部の漂白剤水溶液を排出し、漂白剤吸収剤を散布し、次
いで染色されたジーンズをタンク内へ入れ、タンクを自
転させ、その後ジーンズを取出し水洗及び中和処理を行
う方法である。
Means for Solving the Problems> The above object of the present invention can be achieved by adopting the following means. That is, as a method for producing abrasive stones, a mixture of 5 to 30 parts by weight of glass frit added to 100 parts by weight of silica sand is kneaded, and then 15 to 40 parts by weight of water is added and mixed.
Furthermore, 2 to 10 parts by weight of carboxymethyl cellulose is added and mixed until it becomes sufficiently sticky, and the mixture is pressure-molded, then dried and fired. A porous abrasive stone obtained by firing a mixture containing silica sand as a main component and glass frit added thereto, and an aqueous bleach solution are placed in the tank provided.
After fully impregnating the porous abrasive stone with the bleach aqueous solution, the remaining bleach aqueous solution is drained, and the bleach absorbent is sprayed.Then, the dyed jeans are placed in the tank, the tank is rotated, and then the jeans are removed. In this method, the sample is taken out, washed with water, and neutralized.

、ここで珪砂100重量部に対し、ガラスフリットを5
〜30重量部添加する理由は、それが5重量部未満であ
れば焼成時に非常に高温にしなければ焼成出来ず、一方
30重量部を越えると気孔率が低下し目的とする多孔質
体が得られないからである。
Here, 5 parts of glass frit is added to 100 parts by weight of silica sand.
The reason for adding ~30 parts by weight is that if it is less than 5 parts by weight, it will not be possible to fire unless it is fired at a very high temperature, whereas if it exceeds 30 parts by weight, the porosity will decrease and the desired porous body will not be obtained. This is because it cannot be done.

本発明方法の範囲内であれば、900〜980°C位の
温度で十分に焼成可能であり、又耐摩耗性も十分で気孔
率は大体20〜50%の範囲にありウォッシュ用研磨石
として十分にその機能を発揮する。カルボキシメチルセ
ルロースは、混合粉末を住の状態で所望の形状に保つ為
の物で、それが2重量部未満ではその効果がなく、逆に
10重量部を越える程多量に入れても効果は殆ど変わら
ない上、逆に焼成体内に残留し焼成体の耐摩耗性を低下
せしめる、あるいは変質の要因となる等の問題があるの
で10重量部を限度とする。焼成前の生の成型体は、成
型時のパリを生じている事が多いので、ミキサーでこの
パリを除去する様にする。
Within the range of the method of the present invention, it can be fired at a temperature of about 900 to 980°C, has sufficient wear resistance, and has a porosity of approximately 20 to 50%, so it can be used as a polishing stone for washing. fully demonstrate its function. Carboxymethyl cellulose is a substance that keeps the mixed powder in the desired shape when it is in use.If it is less than 2 parts by weight, it has no effect, and even if it is added in a large amount exceeding 10 parts by weight, the effect will hardly change. In addition, there is a problem that it remains in the fired body and reduces the wear resistance of the fired body or becomes a cause of deterioration, so the limit is set at 10 parts by weight. Since the raw molded body before firing often has burr during molding, this burr is removed using a mixer.

次にジーンズウォッシュ方法につき詳述する。Next, the jeans washing method will be explained in detail.

前記した珪砂を主成分とする本発明方法による多孔質研
磨石は、それを用いて所謂ストーンウォッシュ法と称さ
れるこの研摩石のみをジーンズに接触させて脱色する方
法に用いられる事は勿論であるが、それ以上にこの研摩
石が多孔質であるという事を最大限に活かす事が出来る
のは、所謂ケミカルウォッシュ法である。本発明のジー
ンズウォッシュもこのケミカルウォッシュ法の一種であ
ヮて、漂白剤としては例えば次亜塩素ソ・−ダを用い、
研摩石表面の濡れを取り脱色作用を均一にする漂白剤吸
収剤を併用する。漂白剤の濃度や漂白剤吸収剤の使用量
は、対象とするジーンズの色や染色度合、更にはどの程
度にまで脱色するかにより決まる。脱色後は中和処理を
行う。
It goes without saying that the porous abrasive stone produced by the method of the present invention, which has silica sand as its main component, can be used in the so-called stone wash method, which is a method of decolorizing jeans by bringing only the abrasive stone into contact with the jeans. However, the so-called chemical wash method allows you to take full advantage of the porous nature of this abrasive stone. The jeans wash of the present invention is also a type of chemical wash method, in which hypochlorite soda, for example, is used as the bleaching agent.
A bleach absorber is also used to remove wetness from the surface of the polishing stone and make the decoloring effect uniform. The concentration of bleach and the amount of bleach absorbent used are determined by the color and degree of dyeing of the jeans, as well as the degree of bleaching. After decolorization, neutralization treatment is performed.

〈作用〉 本発明のジーンズウォッシュ方法においては、まず研摩
石の気孔内へ漂白剤水溶液を含浸させ、その後に研摩石
の表面に漂白剤吸収剤を散布し、この様な状態下でジー
ンズをタンク内へ入れ、攪拌するので研摩石の気孔内へ
含浸した漂白剤水溶液は、徐々に表面へ出てき、ジーン
ズを効果的に脱色する。
<Function> In the jeans washing method of the present invention, first, the pores of the polishing stone are impregnated with an aqueous bleach solution, then a bleach absorbent is sprinkled on the surface of the polishing stone, and the jeans are placed in a tank under these conditions. Since the abrasive stone is poured into the abrasive stone and stirred, the aqueous bleach solution impregnated into the pores of the abrasive stone gradually comes out to the surface, effectively decolorizing the jeans.

〈実施例〉 以下本発明をその実施例を示し乍ら詳述する。<Example> Hereinafter, the present invention will be described in detail while showing examples thereof.

支胤■ユ この実施例1は、まずSi0分が95%以上の珪砂10
0重量部に対し、ガラスフリットを15重量部配合し、
これをミキサーへ入れて十分に混練した。
In this Example 1, first, silica sand 10 with a Si0 content of 95% or more was used.
0 parts by weight, 15 parts by weight of glass frit is blended,
This was put into a mixer and thoroughly kneaded.

次いで水を上記珪砂に対し20重量部の割合で加え混合
し、更にカルボキシメチルセルロースを上記珪砂に対し
5重量部加え、十分な粘りが生じるまで混練した。この
混練物を長径が5cm、短径が3amのだ円球状に加圧
成型し、乾燥の後にミキサーで成型時のパリを除去し、
再度乾燥の後焼成した。
Next, 20 parts by weight of water was added to the silica sand and mixed, and 5 parts by weight of carboxymethyl cellulose was added to the silica sand and kneaded until sufficient viscosity was obtained. This kneaded material was pressure-molded into an ellipsoidal shape with a major axis of 5 cm and a minor axis of 3 am, and after drying, the paris from the molding was removed using a mixer.
After drying again, it was fired.

焼成パターンは、徐々に温度を上げ、15時間かけて9
80’Cまで上げ、980℃で3時間保持後、炉冷する
方法によった。
The firing pattern is to gradually increase the temperature and bake 9 times over 15 hours.
The temperature was raised to 80'C, held at 980C for 3 hours, and then cooled in a furnace.

得られた焼成体は、その気孔率が約30%の多孔質体で
あった。
The obtained fired body was a porous body with a porosity of about 30%.

支1貝ユ この実施例2は、1400mmφX1300mm幅の横
置状円筒タンク内に、上記実施例1で得た研摩石を40
廟投入し、10分間から回しを行い、その後次亜塩素酸
ソーダ原液をlO!と水1002を入れ、2分間放置し
、タンク下部の排出孔を開き、次亜塩素酸ソーダ水溶液
を排出した。次いで硫酸ナトリウム粉末を研摩石の表面
に均等に散布し、インジゴでブルーに染色したジーンズ
製ズボンを10本人れ、タンクを20〜25rpmにて
約20分間回転させた。次いでジーンズ製ズボンをタン
クから取出し、上記脱色用タンクと略同形、同大の自転
自在な横置状水洗タンクで水洗の後炭酸ナトリウムに過
酸化水素を付加した中和剤で中和し、更に水洗し、脱水
、乾燥させた。得られたズボンは、効果的にムラなく白
っぽく脱色されていた。なお上記脱色用タンク内にはや
はり研摩石の摩砕物が多少あり、残った研摩石の重量を
調べた結果1回の操作で約1重量%が摩砕している事が
判った。
In this Example 2, 40 abrasive stones obtained in Example 1 above were placed in a horizontal cylindrical tank measuring 1400 mmφ x 1300 mm wide.
Pour in the mausoleum, swirl for 10 minutes, then add 100 ml of sodium hypochlorite solution! and water 1002, left for 2 minutes, opened the drain hole at the bottom of the tank, and drained the sodium hypochlorite aqueous solution. Next, sodium sulfate powder was evenly spread over the surface of the abrasive stone, 10 jeans pants dyed blue with indigo were placed, and the tank was rotated at 20-25 rpm for about 20 minutes. Next, the jeans pants were taken out of the tank, washed in a horizontal washing tank of approximately the same shape and size as the decolorizing tank, which can rotate freely, and then neutralized with a neutralizing agent made by adding hydrogen peroxide to sodium carbonate. Washed with water, dehydrated, and dried. The resulting pants were effectively and evenly bleached to a whitish color. It should be noted that there was still some ground material of the abrasive stones in the decolorizing tank, and as a result of examining the weight of the remaining abrasive stones, it was found that about 1% by weight was ground in one operation.

従って、上記操作を10回繰返す(但し最初のから回し
は2回目以降は不要)毎に、約4 kg位の研摩石を補
充すればよい事となる。
Therefore, it is sufficient to replenish approximately 4 kg of abrasive stones every time the above operation is repeated 10 times (however, the first rounding is unnecessary from the second time onwards).

〈発明の効果〉 以上述べて来た如く、本発明の研摩石の製造方法は、面
潔であり、しかも耐摩耗性に富み多孔質の研摩石が高い
再現性の下に得られ、この様な研摩石を用いたジーンズ
ウォッシュ方法は、研摩石が均一な連通孔を有する三次
元セラミックス構造体であり、吸液性が大であるので脱
色剤の保持能力が大で、しかも耐摩耗性に優れているの
で耐久性に富むと共に、摩砕物が少量しか生起しないの
で後処理が容易であるという効果を奏する。更に、同一
条件下のケミカルウォッシュにおいて脱色効果の再現性
がよく、条件を変えることにより、仕上がりも任意に選
択できる。
<Effects of the Invention> As described above, the method for producing an abrasive stone of the present invention is clean, wear-resistant, and porous abrasive stone can be obtained with high reproducibility. The method of washing jeans using abrasive stones is that the abrasive stones have a three-dimensional ceramic structure with uniform communication holes, have high liquid absorption properties, have a large capacity to retain decolorants, and are also highly abrasion resistant. Because of its excellent properties, it is highly durable, and since only a small amount of ground material is generated, post-processing is easy. Furthermore, the reproducibility of the decolorizing effect is good in chemical washes under the same conditions, and the finish can be arbitrarily selected by changing the conditions.

従ってジーンズウォッシュ工場の安定した行程。Hence the stable process of the jeans wash factory.

品質管理が容易になり、また自動化操業にもつながる。This makes quality control easier and also leads to automated operations.

Claims (1)

【特許請求の範囲】 1、珪砂100重量部に対し、ガラスフリット5〜30
重量部添加した混合物を混練し、次いで水15〜40重
量部を添加混合し、更にカルボキシメチルセルロース2
〜10重量部を添加し十分に粘りが生起するまで混合し
、該混合物を加圧成型し、次いで乾燥の後焼成すること
を特徴とする気孔率20〜50%を有するジーンズウオ
ッシュ用多孔質研磨石の製造方法。 2、自転自在に配設されたタンクに、珪砂を主成分とし
それにガラスフリットを加えた混合物を焼成して得た多
孔質研磨石と、漂白剤水溶液とを入れ、漂白剤水溶液を
多孔質研磨石に十分含浸せしめた後、残部の漂白剤水溶
液を排出し、漂白剤吸収剤を散布し、次いで染色された
ジーンズをタンク内へ入れ、タンクを自転させ、その後
ジーンズを取出し水洗及び中和処理を行うことを特徴と
するジーンズウオッシュ方法。
[Claims] 1. 5 to 30 parts of glass frit per 100 parts by weight of silica sand
The mixture containing the added parts by weight is kneaded, then 15 to 40 parts by weight of water is added and mixed, and further 2 parts by weight of carboxymethyl cellulose are mixed.
Porous polishing for jeans wash having a porosity of 20 to 50%, characterized in that ~10 parts by weight is added and mixed until sufficient stickiness occurs, the mixture is pressure molded, and then dried and fired. Stone manufacturing method. 2. A porous polishing stone obtained by firing a mixture of silica sand as a main component and glass frit added thereto, and an aqueous bleach solution are placed in a rotatably arranged tank, and the aqueous bleach solution is used to polish porous polishers. After fully impregnating the stone, the remaining bleach aqueous solution is drained, a bleach absorbent is sprayed, the dyed jeans are placed in the tank, the tank is rotated, and then the jeans are taken out and washed and neutralized. A jeans washing method characterized by carrying out the following.
JP63209671A 1988-08-23 1988-08-23 Production of abrasive for jeans washing and washing method for jeans Granted JPH0259480A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63209671A JPH0259480A (en) 1988-08-23 1988-08-23 Production of abrasive for jeans washing and washing method for jeans

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63209671A JPH0259480A (en) 1988-08-23 1988-08-23 Production of abrasive for jeans washing and washing method for jeans

Publications (2)

Publication Number Publication Date
JPH0259480A true JPH0259480A (en) 1990-02-28
JPH0518787B2 JPH0518787B2 (en) 1993-03-12

Family

ID=16576678

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63209671A Granted JPH0259480A (en) 1988-08-23 1988-08-23 Production of abrasive for jeans washing and washing method for jeans

Country Status (1)

Country Link
JP (1) JPH0259480A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0642400A1 (en) * 1992-05-27 1995-03-15 OAT, Henry C. Synthetic abrasive stones and method for making same
CN110819003A (en) * 2019-11-13 2020-02-21 佛山市敬展纺织材料有限公司 Washing material replacing pumice and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0642400A1 (en) * 1992-05-27 1995-03-15 OAT, Henry C. Synthetic abrasive stones and method for making same
EP0642400A4 (en) * 1992-05-27 1995-03-22 Henry C Oat Synthetic abrasive stones and method for making same.
CN110819003A (en) * 2019-11-13 2020-02-21 佛山市敬展纺织材料有限公司 Washing material replacing pumice and preparation method thereof

Also Published As

Publication number Publication date
JPH0518787B2 (en) 1993-03-12

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