JPH02503A - Functional polymer sheet - Google Patents
Functional polymer sheetInfo
- Publication number
- JPH02503A JPH02503A JP63086197A JP8619788A JPH02503A JP H02503 A JPH02503 A JP H02503A JP 63086197 A JP63086197 A JP 63086197A JP 8619788 A JP8619788 A JP 8619788A JP H02503 A JPH02503 A JP H02503A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- substance
- functional
- polymer sheet
- functional powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001002 functional polymer Polymers 0.000 title claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 74
- 239000000126 substance Substances 0.000 claims abstract description 52
- 229920000642 polymer Polymers 0.000 claims abstract description 38
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims abstract description 17
- MBDHJOBKSBYBJB-UHFFFAOYSA-N oxygen(2-) platinum(2+) titanium(4+) Chemical compound [O-2].[Ti+4].[Pt+2].[O-2].[O-2] MBDHJOBKSBYBJB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 abstract description 10
- 230000003197 catalytic effect Effects 0.000 abstract description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 31
- 239000004810 polytetrafluoroethylene Substances 0.000 description 31
- 239000006185 dispersion Substances 0.000 description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000004544 sputter deposition Methods 0.000 description 7
- 238000004381 surface treatment Methods 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 239000011164 primary particle Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910010253 TiO7 Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000000861 blow drying Methods 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Abstract
Description
【発明の詳細な説明】
（ａ）産業上の利用分野
本発明は機能性高分子シートに関し、特に、所要ｙ′）
機能を著しく高めた機能性高分子シートに関士るもので
ある。Detailed Description of the Invention (a) Industrial Application Field The present invention relates to a functional polymer sheet, particularly the required y')
We are involved in functional polymer sheets with significantly enhanced functionality.
（Ｉｌ）従来の技術
１能性高分子シートとは、導電性、光導電性、触゛循性
、吸着性、殺菌性等の種々の物理的８！能、或−Ｉ）は
化学的機能を有する高分子シートであって、通常、高分
子シートに、これらの内の少な（とも一つの機能を有す
る粉末物質を担持させた溝道を有している。(Il) Conventional technology A monofunctional polymer sheet has various physical properties such as conductivity, photoconductivity, catalytic property, adsorption property, and sterilization property. (I) is a polymer sheet having a chemical function, and usually has a groove in which the polymer sheet carries a powder substance having one or more of these functions. There is.
一般に、機能性高分子シートにおいて、機能性を発揮さ
せるためには、上記のような機能性を有する粉末物質が
シート表面に露出していることが必要である。また、高
価な粉末物質を最大限に有効に作用させるためにも、機
能性を高める上ではかかる粉末物質がシート内部に存在
しることなく、表面に可能な限り全面に固定配列してい
ることが望まれる。Generally, in order for a functional polymer sheet to exhibit functionality, it is necessary that a powder substance having the above-mentioned functionality be exposed on the surface of the sheet. In addition, in order to make the most effective use of expensive powder substances, it is important that such powder substances do not exist inside the sheet and are fixedly arranged on the entire surface of the sheet as much as possible to improve functionality. is desired.
ところで、高分子シートに機能性粉末物質を担持させる
方法としては、以下のものが提案されている。即ち、■
高分子材料と（蔑能性粉末物質とを混合した後ロール成
形、押出成形等によってシート化する方法、０表面に解
放される連続気泡を有する多孔質高分子シートを用意し
、このシートの連続気泡に機能性粉末物質を充填する方
法、或いは、■機能性粉末物質を含まない高分子シート
、布、或いは紙の表面には血性粉末物質を接着剤等のバ
イングーを用いて固定させた機能性高分子シートが提案
されている。By the way, the following methods have been proposed for supporting a functional powder substance on a polymer sheet. That is, ■
A porous polymer sheet having open cells released on the surface is prepared, and a porous polymer sheet having open cells released on the surface is prepared, and the sheet is made into a continuous A method of filling air bubbles with a functional powder substance, or a method of fixing a blood powder substance on the surface of a polymer sheet, cloth, or paper that does not contain a functional powder substance using a binder such as an adhesive. Polymer sheets have been proposed.
（ｃ）発明がＩＩイ決しようとする同居、αしかしなが
ら、上記■のらのは、高分子材料と（機能性粉末物質が
均一に混合された後シート化されたり、又、上記■のも
のは連＆２気泡内に（機能性粉末物質が詰め込まれるた
め、このいずれらシート表面のみに機能性粉末物質を多
量に担持、存在させることが困難である。(c) Coexistence with which the invention is intended to be determined.α However, the above item (■) may be formed into a sheet after the polymeric material and (functional powder substance) are uniformly mixed, or the above item ((iii)) Since the functional powder material is packed into continuous and two-cell cells, it is difficult to support and make a large amount of the functional powder material exist only on the sheet surface.
ところで、機能性粉末物質がシート内部に存在すること
で特に不利な問題は、尤感応型機能性粉末物費、例えば
、尤反応触媒機能性粉末物質において、尤がシート内部
まで透過しないことから、そのは能、例えば、＠媒体用
が発現しないために怪清的な相欠が火さくなるのである
。By the way, a particularly disadvantageous problem with the presence of a functional powder material inside the sheet is that, in the case of a functional powder material of a potential-sensitive type, for example, a functional powder material of a functional reaction catalyst, the material does not permeate into the interior of the sheet. In the case of Noh, for example, because @medium use is not expressed, the mystery-like conflict becomes more intense.
また、上記■においては、研磨シートに代表される？品
がある。In addition, in the above item (■), what is represented by the abrasive sheet? There is a goods.
このシートの表面は多量に粉末が露出しているものの、
製造方法で研磨材粉末と接着剤との混合系で高分子シー
トに塗布していることから、接着剤で機能性粉末物質が
覆われているので、その機能の失格した部分が所々に出
ている。Although a large amount of powder is exposed on the surface of this sheet,
Because the manufacturing method involves coating the polymer sheet with a mixture of abrasive powder and adhesive, the functional powder material is covered with adhesive, so parts that are no longer functional may appear here and there. There is.
更に、上記■のらのではシート表面に機能性粉末物質を
多量に存在させることが困難になり、このため、機能性
粉末物質の機能性が高分子材料により妨げられることに
なる。従って、機能性粉末物質の機能性を充分に発現さ
せるにはシート表面に機能性粉末物質を高密度に露出さ
せる必要があり、このために、多量の機能性粉末物質を
混合する必要があるが、これでは、シートの強度を者し
く低下させると共にこれでも機能性粉末物質の露出は少
なく、充分な（茂能を発現しないという問題がある。Furthermore, in the case of the above-mentioned RANO, it is difficult to allow a large amount of the functional powder substance to exist on the sheet surface, and as a result, the functionality of the functional powder substance is hindered by the polymeric material. Therefore, in order to fully express the functionality of the functional powder material, it is necessary to expose the functional powder material at a high density on the sheet surface, and for this purpose, it is necessary to mix a large amount of the functional powder material. However, this poses a problem in that the strength of the sheet is significantly reduced, and even with this, the functional powder material is only exposed to a small extent and sufficient performance is not achieved.
また、上記■のものでは、連続気泡に多量の粉末物質を
充填して機能性の高いものを得ることが可能であるが、
機能性粉末物質と母材である高分子材料との固定性が悪
く、このため、シートの取り扱い中や切断、加工中等に
８！能性粉末物質が少しでも脱落すると充填された該粉
末物質の相互間で弛みが起こり、この結果、粉末物質の
脱落が急激に増大するなどの問題がある。従って、機能
的振動等の動作を伴う動的な用途には不向きであり、そ
のような動作を伴わないを的な用途に利用範囲が限定さ
れるという難点がある。In addition, in the case of the above item (■), it is possible to fill the open cells with a large amount of powder substance to obtain a highly functional product.
The fixation between the functional powder substance and the polymeric material that is the base material is poor, and for this reason, during handling, cutting, processing, etc. of the sheet, 8! If even a small amount of the functional powder material falls off, the packed powder materials become loose with each other, and as a result, there is a problem that the amount of powder material falling off increases rapidly. Therefore, it is unsuitable for dynamic applications that involve movements such as functional vibrations, and has the disadvantage that its range of use is limited to general applications that do not involve such movements.
本発明は、上記のπ債を考慮しでなされたちのであって
、（機能性粉末物質の諸機能が充分に発揮でき、しかも
、汎用性に富むは能性高分子シートを提供することを目
的とするものである。The present invention was made in consideration of the above-mentioned π bond, and aims to provide a functional polymer sheet that can fully exhibit the various functions of a functional powder material and is highly versatile. That is.
（、Ｊ）問題、αを解決するための手段本発明者らは、
上記間運点を解決すべく鋭意、検５Ｉを重＃また結果、
機能性粉末物質の粒子（１次粒子、或いは、１次粒子に
近い２次粒子）を高分子シートの表面にのみ配列、固定
させると当該機能性粉末物質の機能が充分に発現するこ
とを見い出し、本発明を完成するに至ったものである。(, J) Means for solving the problem, α.
In order to solve the above-mentioned problems, we carried out the test 5I with great effort and the results,
It has been discovered that when particles of a functional powder material (primary particles or secondary particles close to primary particles) are arranged and fixed only on the surface of a polymer sheet, the functions of the functional powder material are fully expressed. , which led to the completion of the present invention.
即ち、本願第１請求項の機能性高分子シートは、高分子
シート内部には機能性粉末物質が全く存在′することな
く、予め成形されたシート表面に機能性粉末物質を配列
、固定させたことを特徴とするしのである。That is, the functional polymer sheet of the first claim of the present application has functional powder substances arranged and fixed on the surface of a pre-formed sheet, without any functional powder substances being present inside the polymer sheet. Shino is characterized by this.
本発明に用いられる高分子シートとしては、特に限定さ
れるものではないが、予め成形されたフィルム、或いは
シート状体であり、具体的には、ポリエステル、ポリイ
ミド、エポキシ８４脂、ポリテトラフルオロエチレン（
以下、ＰＴＦＥという）等の７７素系高分子材料、ポリ
アミドイミド、ポリ塩化ビニル、ポリエチレン、ポリス
チレン、アクリル樹脂等を使用することができる。The polymer sheet used in the present invention is not particularly limited, but may be a pre-formed film or sheet, and specifically, polyester, polyimide, epoxy 84 resin, polytetrafluoroethylene, etc. (
77-element polymer materials such as PTFE (hereinafter referred to as PTFE), polyamideimide, polyvinyl chloride, polyethylene, polystyrene, acrylic resin, etc. can be used.
この場合、後述する機能性粉末物質とは関係なく、シー
ト自体の強度、或いは、耐候性等の特性を持たせるため
に、〃う又ｆａ碓、或いは、炭素粉末等を混入させた高
分子シートであっても使用することができる。In this case, regardless of the functional powder substance described below, the polymer sheet is mixed with ``Umata Fa Usui'' or carbon powder, etc., in order to give the sheet itself characteristics such as strength or weather resistance. It can be used even if
また、本発明に用いられる（茂能性粉末ｖｌＪ′ｒ１と
しては、高分子シートに相溶しない物質、或いは、高分
子シートと反応しない物質であって導電性、光導７ｒｉ
性、触媒性、ｒｙｉ着性、殺菌性等のうち一つまたは、
二つ以上の機能を有するらのであり、無機物質、或いは
、有機物Ｔ！１等、特に、制限されるものではない。ま
た、このような８！能を有する粉末物質を２種以上併用
することも可能である。In addition, the high-performance powder vlJ'r1 used in the present invention is a substance that is incompatible with the polymer sheet or a substance that does not react with the polymer sheet and has conductivity and light conductivity.
one or more of the following:
It is an inorganic substance or an organic substance that has two or more functions. 1st class, but is not particularly limited. Also, 8 like this! It is also possible to use two or more kinds of powder substances having the above-mentioned properties in combination.
例えば、導電性を有する粉末物質に炭素粉末、酸化亜鉛
粉末、酸化チタンルチル型粉末、酸化錫等であり、光導
電性に硫化カドミウム、酸化亜鉛等であり、触媒性に酸
化チタン、ｍ、等であり、吸着性にゼオライト、活性炭
等であり、殺菌性では、ヨードホルム等が挙げられる。For example, conductive powder substances include carbon powder, zinc oxide powder, titanium oxide rutile type powder, tin oxide, etc., photoconductivity includes cadmium sulfide, zinc oxide, etc., and catalytic properties include titanium oxide, m, etc. For adsorption properties, examples include zeolite and activated carbon, and for bactericidal properties, examples include iodoform.
そして、本発明の特徴は、機能性粉末物質を高分子シー
トの表面に配列、固定するようにさせた点にある。A feature of the present invention is that the functional powder material is arranged and fixed on the surface of the polymer sheet.
このように、高分子シート表面に機能性粉末物質を配列
固定させるには、次のような手段を講じればよいのであ
る。In this way, the following measures can be taken to arrange and fix the functional powder substances on the surface of the polymer sheet.
即ち、高分子シートは予め作成したシートであってもよ
く、河ら特殊なものを用いる必要はないのである。That is, the polymer sheet may be a sheet prepared in advance, and there is no need to use a special one.
即ち、耐熱性が必要であればポリイミドシート、また、
耐薬品性であればＰＴＦＥシート等のように、所望によ
り、選定すればよい。このようなシートの表面処理を行
い、シート表面に疎水性、或いは、親水性の特性を持た
せる。That is, if heat resistance is required, polyimide sheets,
As long as it is chemical resistant, it may be selected as desired, such as a PTFE sheet. Such a surface treatment of the sheet is performed to impart hydrophobic or hydrophilic properties to the surface of the sheet.
上記表面処理の方法としては、スパッタ、フロナ放電、
或いは、化学的な酸化等の各種表面処理などの手段が挙
げられる。The above surface treatment methods include sputtering, fluora discharge,
Alternatively, various surface treatments such as chemical oxidation may be used.
上記のスパッタ処理を施す方法としては、例えば、特公
昭５３−３１８２７号公報に記載されているように既に
知られており、耐圧容器内で；威圧雰囲気下に陰・陽電
極間に高周波電圧を印加し、放電域のイオンエネルギー
の大きい陰極暗部にｔ；いて、放電によって生じたＩ’
２イオンを加速して陰極上の成形物表面に衝突させて処
理するのである。The method of performing the above sputtering treatment is already known, for example, as described in Japanese Patent Publication No. 53-31827. t; is in the dark part of the cathode where the ion energy is large in the discharge region, and the I' generated by the discharge is
The treatment is carried out by accelerating two ions and causing them to collide with the surface of the molded article on the cathode.
このための装置は耐圧容器内に陰極と陽極が対向して配
設され、陰極はインビーグンス整合器を介して高周波電
源に接続され、陽極は高周波電源のアース部に接続され
て構成されている。The device for this purpose has a cathode and an anode placed facing each other in a pressure-resistant container, the cathode being connected to a high-frequency power source via an InBegins matching device, and the anode being connected to the grounding part of the high-frequency power source.
Ｉ１３極の外側にはシールド電極が配設され、アース電
位に保たれる。A shield electrode is provided on the outside of the I13 pole and is kept at ground potential.
上記シート母体（高分子材料）の表面処理は、装置によ
り、バッチ式、連続式のいずれも可能である。The surface treatment of the sheet matrix (polymer material) can be performed either batchwise or continuously, depending on the equipment.
スパッタ処理は、通常、常温で行なわれる。Sputtering treatment is usually performed at room temperature.
用いられる高周波電力の周波数は、数百Ｋ ＨＺ〜数十
Ｍ Ｉ−（ｚにわたって使用可能であるが、実用上は工
業割り当て周波数である１３．５（ｉＭＨｚを用いるの
が高都合である。The frequency of the high-frequency power used can range from several hundred KHz to several tens of MHz, but in practice it is convenient to use the industrially allocated frequency of 13.5 (iMHz).
電極間距離はスパッタ処理雰囲気下の平方根の逆数に比
例して定められ、例えば、雰囲気圧が０゜００５ Ｔｏ
ｒｒのとき、３０＋ａｍ以上とされる。The distance between the electrodes is determined in proportion to the reciprocal of the square root of the sputtering atmosphere. For example, when the atmospheric pressure is 0°005 To
When rr, it is assumed to be 30+am or more.
雰囲気としては、通常、空気や水蒸気を用いるが、この
池にも窒素、アルゴン、ヘリウム等の不活性ガスや炭酸
〃ス等も用いることができる。Air or water vapor is usually used as the atmosphere, but inert gases such as nitrogen, argon, helium, carbon dioxide, etc. can also be used in this pond.
そして、上記シート母材（高分子材料）の表面をスパッ
タエツチング処理するには、具体的に、０゜０００５〜
ＩＴｏｒｒの雰囲気圧下で処理電極密度と処理時間との
積で定義される放電処理量が０゜１−２００ｗａｔｔ・
秒／ｃ１１２、好ましくは１〜１８０ ｔｕａｔＬ・秒
／ｃａ＋”の範囲内で行なわれる。Specifically, in order to sputter-etch the surface of the sheet base material (polymer material),
The discharge processing amount defined as the product of the processing electrode density and processing time under an atmospheric pressure of ITorr is 0°1-200 watts.
sec/c112, preferably within the range of 1 to 180 tuatL·sec/ca+''.
このような表面処理において、場合によって、両面に機
能性を持たす必要があるときには両面を処理することら
可能である。In such surface treatment, if it is necessary to provide functionality to both sides, it is possible to treat both sides.
次に、そのシートの処Ｆ！！表面に、機能性粉末物質を
溶媒に分散した分散液を塗布し、この分散液の溶媒を乾
燥、除去させる。Next, the seat F! ! A dispersion of a functional powder substance dispersed in a solvent is applied to the surface, and the solvent of this dispersion is dried and removed.
この分散液において、機能性粉末物質或いは、溶媒は高
分子に対して親和性のあるものを適当に選別して使用で
きるのである。In this dispersion, functional powder substances or solvents that have affinity for polymers can be appropriately selected and used.
但し、この分散液は、不揮発性の液体、或いは、機能性
粉末物質の機能を阻害するような接着側を含めたｆｊＳ
３物質は添加せず、単に、８！能性粉末物質と揮発性溶
媒（分散剤）との分散体である。However, this dispersion liquid is a non-volatile liquid or fjS containing adhesive side that may inhibit the function of the functional powder substance.
3 substances are not added, just 8! It is a dispersion of a functional powder substance and a volatile solvent (dispersant).
また、分散液の塗布、乾燥方法はごく一般のデツピング
法、バーコード法など種々の塗工方法が採Ｊ′Ｈされる
のであり、又、乾燥方法も分散剤が除去できれば装置の
限定はないのである。In addition, the dispersion can be applied and dried using a variety of coating methods, such as the very common dipping method and barcode method, and the drying method is not limited by equipment as long as the dispersant can be removed. It is.
この塗布、乾燥させたシートは高分子シートの表面に機
能性粉末物質が仮固定されている状態である。The coated and dried sheet is in a state in which the functional powder substance is temporarily fixed on the surface of the polymer sheet.
このため、完全にシート表面に機能性粉末物質を配列、
固定させるためロールによる圧着を行う。For this reason, functional powder substances are completely arranged on the sheet surface,
Crimp with a roll to fix it.
この際、ロール温度は高分子シートのプラス転移点（以
下、Ｔｇという）以上が望ましいが、機能性粉末物質の
特性によっては７ｇ以下、或いは、室温でのロール圧着
による機能性粉末物質の配列、固定が可能であり、また
、塗布、乾燥だけで高分子シートにおける機能性粉末物
質の担持性が良好であればロール圧着しない場合も可能
である。At this time, the roll temperature is preferably higher than the positive transition point (hereinafter referred to as Tg) of the polymer sheet, but depending on the characteristics of the functional powder material, it may be 7 g or less, or the functional powder material may be arranged by roll compression at room temperature. Fixation is possible, and if the functional powder substance is well supported by the polymer sheet simply by coating and drying, it is also possible to use it without roll pressure bonding.
このように構成することにより、シートの表面にのみ機
能性粉末物質が配列、固定される。With this configuration, the functional powder substance is arranged and fixed only on the surface of the sheet.
こめようにして形成された機能性高分子シートを使用す
るに当ｒこって、機能性粉末物質がシート表面に配列し
、固定されているその上にも、更に当該粉末物質が付着
して過剰となり、このため用途」−問題がある場合には
、水中超音波中に、そのシートを浸漬し過剰な機能性粉
末物質を除去することもＩｉＴ能である。また、逆に、
より以上に粉末がシートより脱落が悪念される場合には
ロール圧符を弥り返す１：とも可能である６
また、本発明の構成において、表面摩擦の起こる所で若
千問題となる場合には、樹脂等によるオーバーフートも
可能であるが、この場合、機能性粉末物質の諸機能が失
われないように高分子シート入面に（茂能性粉末物質が
配列、固定されていることが重要である。When using the functional polymer sheet formed in this way, the functional powder substance is arranged and fixed on the sheet surface, and the powder substance also adheres to the sheet surface, causing excess Therefore, if there is a problem with the application, it is also possible to immerse the sheet in underwater ultrasound to remove excess functional powder material. Also, conversely,
If the powder is more likely to fall off the sheet, it is possible to turn back the roll pressure. In addition, in the structure of the present invention, if there is a problem where surface friction occurs, It is also possible to overfoot with resin, etc., but in this case, the functional powder material must be arranged and fixed on the surface of the polymer sheet so that the various functions of the functional powder material are not lost. is important.
本発明の８！１能性高分子シートは、８！能性粉末物質
そのものが発現する機能特性に基づく用途に用いられで
もよく、或いは、その機能の特性を変性させた用途、例
えば、医療関係等の薬剤徐放用シート、或いは、バイオ
関係の酵素固定用シートとしても使用できる。The 8!1 functional polymer sheet of the present invention has 8! It may be used for applications based on the functional properties expressed by the functional powder substance itself, or applications with modified functional properties, such as sheets for sustained release of drugs in medical applications, or enzyme immobilization in bio-related applications. It can also be used as a sheet.
又、本願第２請求項のは血性高分子シートにおいて、機
能性粉末物質が触媒である二酸化マンガン或いは酸化チ
タン−白金系触媒を用いたしのは、二酸化マンガンの持
つ触媒（蔑能と経済性との観点より、産業上の瓜途が広
く有益であり、或いは酸化チタン−白金系触媒は触媒能
が康めて高く、又、この＠媒は染粒子であることより本
来その取扱いが極めて困難であるが、このように構成す
ることにより、その取扱い性が極めて高くなってその用
途が著しく拡大ｒるのである。In addition, in the blood-based polymer sheet of the second claim of the present application, the functional powder substance used as a catalyst is manganese dioxide or a titanium oxide-platinum catalyst. From the viewpoint of this, titanium oxide-platinum catalysts have a wide range of industrial applications and are useful, and titanium oxide-platinum catalysts have a stable and high catalytic ability, and since this @ medium is dye particles, it is originally extremely difficult to handle. However, by configuring it in this way, it becomes extremely easy to handle and its uses are greatly expanded.
（ｅ）作用
」二連のように本発明に係る機能性高分子シートでは、
シート入面における機能性を有する粉末物０を配列、固
定しているので、高い機能性を定押−ｒる二とができる
。In the functional polymer sheet according to the present invention, as shown in the double series of "(e) action",
Since the functional powder material 0 is arranged and fixed on the sheet entrance surface, high functionality can be maintained at a constant pressure.
しかも、シート表面部に機能性粉末物質を固着している
から、可撓性、柔軟性、強度等の（茂械的特性を確保し
て、機械的振動等を伴う動的な箇所にも使用できる汎用
性に富んだものが得られる作用を有する。In addition, since the functional powder material is fixed to the surface of the sheet, it ensures mechanical properties such as flexibility, pliability, and strength, and can be used even in dynamic areas with mechanical vibrations. It has the effect of providing highly versatile products.
（ｆ）実施例
以下、本発明を実施例に基づき、詳細に説明するが、本
発明はこれに限定されるしのではない６実施例１
高分子シートとしてポリテトラフルオロエチレン（厚み
１００μｌの切削ＰＴＦＥシート）を用い、まず、この
シートの表面にスパッタ親木処理を行った。(f) Examples Hereinafter, the present invention will be explained in detail based on Examples, but the present invention is not limited thereto. 6 Example 1 Polytetrafluoroethylene as a polymer sheet (100 μl thick cut PTFE sheet), and the surface of this sheet was first subjected to sputtering parent wood treatment.
スパッタ処理条件は８替・砂／Ｃ輸２である。The sputtering conditions were 8-change, sand/C-export 2.
又、機能性粉末物質として酸化チタン（ＴｉＯｚ・ルチ
ル型）を用い、これを水で９重量！６濃度になるように
調整した。In addition, titanium oxide (TiOz, rutile type) is used as a functional powder substance, and it is mixed with water to make 9 parts by weight! The concentration was adjusted to 6.
この調製液は全１をＳＯ，にして、足音製分散器（シャ
ープＤＴ ５２）に３０分間かけて均一な分散液とし
た。This prepared liquid was made into a homogeneous dispersion liquid by changing the total amount of 1 to SO, and applying it to a disperser made by Ashinee (Sharp DT 52) for 30 minutes.
この分散液を、上記高分子シートのスパッタ処理面（面
積３０＋ａｍＸ ５０ａ＋ｍ）に滴下した。This dispersion liquid was dropped onto the sputter-treated surface (area: 30+am x 50a+m) of the polymer sheet.
この際、高分子シートの変形を防ぐために当該シートの
両端をクリップで固定してから行った。At this time, both ends of the polymer sheet were fixed with clips to prevent deformation of the polymer sheet.
この滴下した分散液をガラス棒で全面に濡れるよう・に
広げ、次いで、このシートをクリップを付けたまま温度
１９０’Ｃに加熱した８坂にのせ、分散液の水を蒸発さ
せ、完全（ｉ２．燥させた。The dropped dispersion was spread over the entire surface with a glass rod, and then the sheet, with the clip attached, was placed on an 8-slope heated to 190'C to evaporate the water in the dispersion and completely (i2 ．Dried.
かくして得られたシートはＰＴＦＥシート表面にＴ ｉ
Ｏ！が仮付着しているだけであるが、これを固定する
ためにこのシートを、等速圧延ロールの温度２１０〜２
２０℃に調節して、ロールによる通過加圧を竹った。The thus obtained sheet has Ti on the surface of the PTFE sheet.
O! However, in order to fix this, the sheet was heated at a constant speed rolling roll at a temperature of 210 to 2.
The temperature was adjusted to 20° C., and passing pressure was applied using rolls.
この場合、この加圧はＰＴＦＥシートが変形しない程度
に調整することにした。これによって、ＰＴＦＥンート
の片面にＴ ｒ ０２が固定、配列される。しかしなが
ら、このシートにおけるＴｉＯ２はＰＴＦＥシートに配
列、固定されているが、その表面に過剰に存在している
ため、これを除去するため、当該シートを超音波分散器
（シャープ製ＤＴ−５２）で水中発振を３０分間かけた
。In this case, the pressure was adjusted to such an extent that the PTFE sheet would not be deformed. As a result, T r 02 is fixed and arranged on one side of the PTFE net. However, although the TiO2 in this sheet is arranged and fixed on the PTFE sheet, it exists in excess on the surface of the PTFE sheet, so in order to remove this, the sheet is treated with an ultrasonic disperser (DT-52 manufactured by Sharp). Underwater oscillation was applied for 30 minutes.
かくして、余分なＴ ｉ ０２を除去した。In this way, excess T i 02 was removed.
この結果を説明すると、第１図は走査型電子顕微ｌ（Ｓ
ＥＭ）による２０００倍の表面写真であり、ｆ５２図は
透過型電子顕微鏡（ＴＥＭ）による１０゜０００倍の断
面写真である。To explain this result, Fig. 1 shows a scanning electron microscope l (S
This is a surface photograph taken at a magnification of 2,000 times using an EM), and the f52 diagram is a cross-sectional photograph taken at a magnification of 10°,000 times using a transmission electron microscope (TEM).
この第１図とｆｊＳｚ図は本発明の機能性高分子シート
の構造をより明確にするために採用したものである。This FIG. 1 and the fjSz diagram were adopted in order to clarify the structure of the functional polymer sheet of the present invention.
第１図により、機能性高分子シート表面のＴｉＯ７がは
１ｒ全而に配列、固定していることが認めらｈ ７＋。From FIG. 1, it is confirmed that TiO7 on the surface of the functional polymer sheet is arranged and fixed throughout 1rh7+.
又、第２図において、その右側はＰＴＦＥの断面、左側
はエポキシ包埋Ｕ（脂である。その境におけるＰＴＦＥ
面にＴｉＯ□が配列、固定していることが認められる。In addition, in Figure 2, the right side is a cross section of PTFE, and the left side is an epoxy-embedded U (oil).
It is observed that TiO□ is arranged and fixed on the surface.
実施例２
高分子シートとしては実施例１と同様のものを用い、実
施例１と同様の表面処理を行った。Example 2 The same polymer sheet as in Example 1 was used, and the same surface treatment as in Example 1 was performed.
又、機能性粉末物質として酸化錫（３１１０２）（三菱
金属！Ｔ−１）を用いた。Furthermore, tin oxide (31102) (Mitsubishi Metals! T-1) was used as a functional powder material.
分散には、実施例１と同様の手法で４重量％の）二度の
分散液を作成した。さらに、塗布も同じ手法にした。た
だ、この作成ではロールによる加圧は行わなかった。For dispersion, two 4% by weight dispersions were prepared in the same manner as in Example 1. Furthermore, the same method was used for application. However, in this preparation, no pressure was applied using rolls.
この結果を第３図に示す。The results are shown in FIG.
第３図に示すＳＥＭ２０００倍の表面写真よりシート表
面全体に略均−にＳ ｎ Ｏ２が配列していることが判
る。From the 2000x SEM surface photograph shown in FIG. 3, it can be seen that SnO2 is arranged approximately evenly over the entire sheet surface.
次に、第４図に示すＴＥＭＩｏ、０００倍の断面写真よ
り、この右側はＰＴＦＥの断面、左側はエポキシ包埋樹
脂で、Ｓｌ＋０２は１次粒子が約０゜０２μｌであり分
散液の水が除去されると凝集する。そのため、この状態
で固定、配列しているので面方向にテスターによる導電
性が測定できる。Next, from the cross-sectional photograph of TEMIo shown in Figure 4 at 000x, the right side is the cross section of PTFE, the left side is the epoxy embedding resin, and the primary particles of Sl+02 are approximately 0°02 μl, and the water in the dispersion has been removed. When exposed, it aggregates. Therefore, since they are fixed and arranged in this state, the conductivity can be measured using a tester in the plane direction.
この測定は試料幅１８ｍｍであって電極間１０ＩＩ＋ｏ
とし、金メツキクリップで挟みアナログテスターにより
測定した結果、２メグオームであった。In this measurement, the sample width was 18 mm, and the electrode distance was 10 II + o.
The result was 2 megohms as a result of measurement using an analog tester held between gold-plated clips.
実施例３
高分子シートとしてポリテトラフルオロエチレン（Ｊ！
７み１００μ曽の切削ＰＴＦＥシート）を用い、まず、
このシートの表面にスパッタ親木処理を行った。Example 3 Polytetrafluoroethylene (J!
First, using a cut PTFE sheet with a diameter of 7 mm and 100 μm,
Sputter parent wood treatment was performed on the surface of this sheet.
スパッタ処理条件は８ｗ・秒／ｃｍ”である。The sputtering conditions were 8 W·sec/cm''.
又、機能性粉末物質として、触媒である二酸化マンガン
（Ｍｎ０２、化学用）を用い、これを水で１０重量％濃
度になるように調整した。In addition, manganese dioxide (Mn02, chemical grade), which is a catalyst, was used as a functional powder material, and the concentration was adjusted to 10% by weight with water.
この調整液は全量を５０ｇにして、超音波発振器（シャ
ープＤＴ−５２）に３０分間かけて均一な分散液とした
。The total amount of this adjustment liquid was 50 g, and a uniform dispersion was obtained by applying an ultrasonic oscillator (Sharp DT-52) for 30 minutes.
この分散液を、上記高分子シートのスパッタ処理面にバ
ーフート法により連続的に塗布を行い、それを温度１０
０°Ｃ前後の送風乾燥炉に通すことにより、分散液の水
を蒸発させ、完全乾燥させた。This dispersion liquid was continuously applied to the sputter-treated surface of the polymer sheet using the Barhoot method, and the dispersion was applied at a temperature of 10°C.
The water in the dispersion was evaporated and completely dried by passing it through a blow drying oven at around 0°C.
かくして得られたシートはＰＴＦＥシート表面にＭｎＯ
２が仮付着しているだけであるが、これを固定するため
にこのシートを、等速圧延ロールの温度２１０〜２２０
°Ｃに調節して、ロールによる通過加圧を行った。The sheet thus obtained has MnO on the surface of the PTFE sheet.
2 is only temporarily attached, but in order to fix this, the sheet was heated at a constant speed rolling roll at a temperature of 210 to 220.
The temperature was adjusted to .degree. C., and passing pressure was applied using rolls.
この場合、この加圧はＰＴＦＥシートが変形しない程度
に調整することにした。これによって、ＰＴＦＥシート
の片面にＭ ｎ Ｏ２が固定、配列される。しかしなが
ら、このシートにおけるＭ ｎ Ｏ２はＰＴＦＥシート
に配列、固定されているが、その表面に過剰に存在して
いるため、これを除去するため、当該シートを超音波発
振器（シャープ製ＤＴ−５２）で水中発振を３０分間か
けた。In this case, the pressure was adjusted to such an extent that the PTFE sheet would not be deformed. As a result, MnO2 is fixed and arranged on one side of the PTFE sheet. However, although the MnO2 in this sheet is arranged and fixed on the PTFE sheet, it exists in excess on the surface of the PTFE sheet, so in order to remove this, the sheet is subjected to an ultrasonic oscillator (DT-52 manufactured by Sharp). Underwater oscillation was applied for 30 minutes.
かくして、余分なＭｎＯ□を除去した。In this way, excess MnO□ was removed.
この結果を説明すると、第５図は走査型電子顕微鏡（Ｓ
ＥＭ）による２０００倍の表面写真であり、第６図は透
過型電子顕微鏡（ＴＥＭ）による１０゜０００倍の表面
部分の断面写真である。To explain this result, Fig. 5 shows a scanning electron microscope (S
6 is a cross-sectional photograph of the surface portion taken at a magnification of 10°000 by a transmission electron microscope (TEM).
この第５図と第６図は本発明の機能性高分子シート、こ
の場合、触媒担持シートの信遺をより明確にするために
採用したものである。FIGS. 5 and 6 were adopted in order to clarify the characteristics of the functional polymer sheet of the present invention, in this case, the catalyst-supporting sheet.
第５図により、触媒高分子シー）３面のＭｎＯ２がほぼ
全面に配列、固定していることが認められる。From FIG. 5, it can be seen that MnO2 on three surfaces of the catalytic polymer sheet is arranged and fixed on almost the entire surface.
又、第６図において、その下側はＰＴＦＥの断面、上側
はエポキシ包埋樹脂である。その境におけるｒ’ＴＦＥ
面にＭ ｎ Ｏ２が配列、固定していることが恐められ
る。Further, in FIG. 6, the lower side is a cross section of PTFE, and the upper side is an epoxy embedding resin. r'TFE at the boundary
It is feared that M n O2 is arranged and fixed on the surface.
このＭ ｎ Ｏ２シートの実証実験の一例を示す。An example of a demonstration experiment using this MnO2 sheet is shown below.
このＭｎ０ｚは従来から、例えば過酸化水素（Ｈ２Ｏ２
）と反応させ酸素〃ス（０２）を発生させる触媒として
代表的なものである。この反応は、Ｈ２Ｏ２水；３液に
ＭｎＯ２粉末を直接作用させることから、−度反応を行
うと、反応を途中で停止させることは非常：こ困難であ
る。ところが、このＭｎ０２−ＰＴＦＥシートを用いれ
ば、Ｈ２Ｏ２水溶液に入れた時だけ反応が起こり、取り
出せば反応が停止するので非常に有利である。Conventionally, this Mn0z has been produced using, for example, hydrogen peroxide (H2O2
) to generate oxygen (02). In this reaction, since MnO2 powder is directly applied to H2O2 water, it is extremely difficult to stop the reaction midway through the reaction. However, if this Mn02-PTFE sheet is used, the reaction occurs only when it is placed in the H2O2 aqueous solution, and the reaction stops when it is taken out, which is very advantageous.
実験として、このＭｎ０２ＰＴＦＥシートを３０鴫ｎＸ
５０ ｏｈｍに切断し、別にＨ２Ｏ，水溶液（三菱瓦
斯化学（抹）製）を水で希釈して、０．２容量％、１．
０容１％、５ 、 Ｑ 容ｆｉ％、１０．０容１％の
１１度に各々調製した液を各々４００ｍ０広口瓶に入れ
、この中に切断したシートを低濃度から順次に入れ替え
て液中捕集により０２の発生量を測定した。この場合、
測定温度は２２℃とした。As an experiment, this Mn02PTFE sheet was
50 ohm, and separately diluted a H2O aqueous solution (manufactured by Mitsubishi Gas Chemical Co., Ltd.) with water to give 0.2% by volume, 1.
0 volume 1%, 5 volume, Q volume fi%, 10.0 volume 1%, each prepared at 11 degrees, were placed in a 400m0 wide-mouthed bottle, and the cut sheets were sequentially placed in the bottles, starting from the lowest concentration, and placed in the liquid. The amount of 02 generated was measured by collection. in this case,
The measurement temperature was 22°C.
この結果を第１表に示す。The results are shown in Table 1.
第１３（ＭｎＯ２担持ＰＴＦＥシートのＨ，０２０分解
）実施例４
高分子シートとして、実施例１と同様のものを用い、実
施例１と同様の表面処理を行った。Thirteenth (H,020 decomposition of MnO2-supported PTFE sheet) Example 4 The same polymer sheet as in Example 1 was used, and the same surface treatment as in Example 1 was performed.
また、触媒粉末物質として酸化チタン・白金（ＴｉＯよ
・アナターゼ型・Ｐｔ２％）の光触媒を用いた。In addition, a photocatalyst of titanium oxide/platinum (TiO, anatase type, 2% Pt) was used as a catalyst powder material.
この作成方法は実施例１とまったく同様の手法である。This production method is exactly the same as that of the first embodiment.
この結果の構造写真を第７図に上記第５図と、又第８図
に第６図に相当する写真を挙げた。A structural photograph of this result is shown in FIG. 7, and a photograph corresponding to FIG. 6 is shown in FIG. 8.
第８図において、右側にＰＴＦＥシートの表面部分を、
左側にエポキシ包ＩＩ樹脂、その境にＴｉＯ２・ｐｔが
配列していることが認められる。この結果、実施例３と
同様に高分子シートのＰＴＦＥ面にＴｉＯ，−Ｐｔが配
列、固定していることが確認される。In Figure 8, the surface part of the PTFE sheet is on the right side,
It can be seen that the epoxy envelope II resin is on the left, and TiO2.pt is arranged on the border thereof. As a result, as in Example 3, it was confirmed that TiO and -Pt were arranged and fixed on the PTFE surface of the polymer sheet.
この先触Ｗ Ｔ ｉ Ｏ２−Ｐ Ｌはその物質のほとん
どの物が酸化・還元反応を起こし分解することがよく知
られでいる。しかしながら、この触媒は微粒子であるこ
とがら取扱いが困難で、−度触媒として使用すれば回収
困難で特殊なフィルターによる回収しかできなかった。It is well known that most of the substances in this precursor W T i O2-P L undergo oxidation and reduction reactions and decompose. However, since this catalyst is in the form of fine particles, it is difficult to handle, and if used as a catalyst, it is difficult to recover and could only be recovered using a special filter.
これをこのように構成することにより解決した触媒担持
高分子シートであることが認められる。このＴｉ０２−
ｐ（担持ＰＴＦＥシートにつき簡単な光反応実験結果を
第２表に示す。It is recognized that this is a catalyst-supported polymer sheet that solves the problem by configuring it in this way. This Ti02-
Table 2 shows the results of simple photoreaction experiments for p(supported PTFE sheets).
この第２表はＴｉＯ□−ｐｔ担持ＰＴＦＥシートの存在
下での紫外線によるトリクレンの分解試験である。Table 2 is a test for decomposition of trichlene by ultraviolet light in the presence of a TiO□-pt-supported PTFE sheet.
（以下余白）
第２表（ＴｉＯｚ Ｐｔ担持ＰＴＦＥシートの存在下
での紫外線によるトリクレンの分解試験）Ｔｉ０２−Ｐ
ｔ担持ＰＴＦＥシートの大きさ５０ＩＩＩＩＩ×５０１
１ＩＩ！１トリクレンｇｌｏｏｍＮをシャーレに入れて
石英ガラス蓋をする。この中に上記Ｔｉｅ、−Ｐｉ担持
ＰＴＦＥシートを浸漬し、望外線ランプ（東芝製０４０
０Ｐ）４００Ｗを用い、照射距離５００＋ａｍで紫外線
を照射した。(Left below) Table 2 (Decomposition test of trichlene by ultraviolet rays in the presence of TiOz Pt-supported PTFE sheet) Ti02-P
Size of t-supported PTFE sheet: 50III×501
1II! Place 1 trichloride GroomN in a Petri dish and cover with a quartz glass lid. The above Tie, -Pi-supported PTFE sheet was immersed in this, and the extra-television lamp (Toshiba 040
0P) Using 400W, ultraviolet rays were irradiated at an irradiation distance of 500+am.
注）トリクレン中の酸の量は紫外線照射後Ｔ ｉ Ｏ２
−Ｐｔ担持シートを取り出し、瓶に入れ２００ｍ１の水
を投入し、攪拌した後、その水の中和滴定により側定し
た。Note) The amount of acid in trichlene is T i O2 after UV irradiation.
- The Pt-supporting sheet was taken out, placed in a bottle, and 200 ml of water was added thereto, stirred, and then determined by neutralization titration of the water.
この実験の結果、トリクレンは紫外線により分解は起き
るもののＴ ｉｏ ２− Ｐ を担持ＰＴＦＥシートに
より分解がより促進していることが１′ｑる３このシー
トは１枚のシートを繰り返し７！、験に使用した結果で
あり、紫外線の照射時間とトリクレンの分解量比例して
いることから再現性のあるデーグーの取れる取り扱い容
易な触媒担持高分子シートであることが認められる。As a result of this experiment, it was found that although trichlene decomposes when exposed to ultraviolet light, the decomposition is further accelerated by the PTFE sheet carrying T io 2-P. This is the result of using it in an experiment, and the amount of decomposition of trichlene is proportional to the irradiation time of ultraviolet rays, so it is recognized that the catalyst-supported polymer sheet is easy to handle and can produce reproducible degreasing.
（ｇ）発明の効果
上記のように本発明に係る機能性高分子シートでは、高
分子シートの表面に接着剤等のパイングーを使用せず、
機能性粉末物質のみをシート表面に配列、固定されてな
り、当該シート表面の機能性粉末物質の密度が高くなり
、従来にない、まったく新しい構成で高い機能性を定押
することができる。(g) Effect of the invention As mentioned above, the functional polymer sheet according to the present invention does not use adhesive such as adhesive on the surface of the polymer sheet.
Only functional powder substances are arranged and fixed on the sheet surface, and the density of the functional powder substances on the sheet surface is increased, making it possible to maintain high functionality with a completely new structure that has never existed before.
しかも、シート表面に粉体が固定した構成になっている
ので水中超音波でも粉体が脱落しないで可視性、柔軟性
、強度などのＰｙｉ械的時的特性保して、成械的振動を
伴う動的な箇所にも使用できる汎用性に富んだしのが得
られる効果を有するのである。Moreover, since the powder is fixed on the sheet surface, the powder will not fall off even under underwater ultrasound, maintaining mechanical and temporal properties such as visibility, flexibility, and strength, and preventing mechanical vibration. This has the effect of providing a highly versatile shield that can be used in dynamic locations.
又、本発明の（凌能性高号子シートにおいて、機能性粉
末物質が触媒である二酸化マンガン或いは酸化チタン−
白金系触媒を用いｒこらのは、二酸化マンガンの持つ触
媒（茂能と経済性との観点より、産業上の用途が広く有
益であり、或いは酸化チタン−白金系触媒は触媒能が極
めて高く、又、この触媒は微粒子であることより本来そ
の取扱いが極めて困難であるが、このように構成−ｒる
ことにより、その取扱い性が極めて高くなってその用途
が著しく拡大するなどの効果を有するのである。In addition, in the high performance high grade sheet of the present invention, the functional powder material is manganese dioxide or titanium oxide as a catalyst.
Using a platinum-based catalyst, the catalyst of manganese dioxide (which has a wide range of industrial uses and is useful from the viewpoint of efficiency and economy), or the titanium oxide-platinum-based catalyst has extremely high catalytic ability, In addition, since this catalyst is made of fine particles, it is originally extremely difficult to handle, but by structuring it in this way, it has the effect of becoming extremely easy to handle and significantly expanding its uses. be.
第１図はｒ’ＴＦＥシート表面にルチル型Ｔｉｅ。
を配列、固定せしめたシート表面の粒子構造を示す図面
に代わる拡大写真であり、Ｐｒ５２図はその内部の粒子
−措遣を示す図面に代わる拡大写真であり、第３図はＰ
ＴＦＥシート表面に５１１０２を配列、固定せしめたシ
ー）１面の粒子構造を示す図面に代わる拡大写真であり
、第４図はその内部の粒子構造を示す図面に代わる拡大
写真、第５図はＰＴＦＥシート表面にＭｎＯ２を配列、
固定せしめたシート表面の粒子構造を示す図面に代わる
拡大写真であり、第６図はその内部の粒子構造を示す図
面に代わる拡大写真であり、第７図はＰＴＦＥシート表
面にＴ ｉｏ ２− Ｐ Ｌを配列、固定せしめたシー
ト表面の粒子構造を示す図面に代わる拡大写真であり、
第８図はその内部の粒子構造を示す図面に代わる拡大写
真である。
Ｍｌ
図
第３
図
図面の浄書
第２
図
：ツー１ｍ
図面のイ争書
第４
図
２左ｍ
第５
図
第７図
図面の浄書
第６
図
図面の浄書
図
２ノ−ｍ
２ルｍFigure 1 shows a rutile type tie on the surface of an r'TFE sheet. This is an enlarged photograph in place of a drawing showing the particle structure on the surface of the sheet in which particles are arranged and fixed, Pr52 is an enlarged photograph in place of a drawing showing the arrangement of internal particles, and Fig. 3 is a
51102 is arranged and fixed on the surface of the TFE sheet). Figure 4 is an enlarged photograph in place of a drawing showing the grain structure on one side of the sheet. Figure 4 is an enlarged photograph in place of a diagram showing the internal grain structure. Figure 5 is an enlarged photograph in place of a diagram showing the grain structure inside the sheet. Arranging MnO2 on the sheet surface,
FIG. 6 is an enlarged photograph in place of a drawing showing the particle structure on the surface of a fixed sheet, FIG. 6 is an enlarged photograph in place of a drawing showing the internal particle structure, and FIG. It is an enlarged photograph in place of a drawing showing the particle structure of the sheet surface in which L is arranged and fixed,
FIG. 8 is an enlarged photograph in place of a drawing showing the internal particle structure. Ml Figure 3 Engraving of the drawings 2 Figure: 1 m Dispute of the drawings 4 Figure 2 left m Figure 7 Engraving of the drawings 6 Engraving of the drawings 2 m 2 m
Claims (2)
定したことを特徴とする機能性高分子シート。(1) A functional polymer sheet characterized in that functional powder substances are arranged and fixed on the surface of the polymer sheet.
は酸化チタン−白金系触媒である請求項１記載の機能性
高分子シート。(2) The functional polymer sheet according to claim 1, wherein the functional powder material is a catalyst of manganese dioxide or titanium oxide-platinum catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63086197A JP2565371B2 (en) | 1987-09-30 | 1988-04-06 | Functional polymer sheet |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24849187 | 1987-09-30 | ||
| JP62-248491 | 1987-09-30 | ||
| JP63086197A JP2565371B2 (en) | 1987-09-30 | 1988-04-06 | Functional polymer sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02503A true JPH02503A (en) | 1990-01-05 |
| JP2565371B2 JP2565371B2 (en) | 1996-12-18 |
Family
ID=26427358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63086197A Expired - Lifetime JP2565371B2 (en) | 1987-09-30 | 1988-04-06 | Functional polymer sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2565371B2 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0866635A (en) * | 1993-12-14 | 1996-03-12 | Toto Ltd | Photocatalytic thin film and its formation |
| JPH08208414A (en) * | 1994-11-01 | 1996-08-13 | Toray Ind Inc | Resin composition and antimicrobial and antifungal methods |
| JPH09249871A (en) * | 1996-03-14 | 1997-09-22 | Toli Corp Ltd | Stainproofing and deodorizing structure and interior material utilizing the same structure |
| JPH10217383A (en) * | 1996-12-03 | 1998-08-18 | Achilles Corp | Decorative sheet and production thereof |
| JPH11166082A (en) * | 1997-12-04 | 1999-06-22 | Nitto Denko Corp | Molding of ultra-high molecular-weight polyethylene and its production |
| JP2001328195A (en) * | 2000-05-19 | 2001-11-27 | Tdk Corp | Functional film |
| JP2002036411A (en) * | 1999-12-28 | 2002-02-05 | Tdk Corp | Functional coating film and manufacturing method therefor |
| JP2003015286A (en) * | 2001-06-28 | 2003-01-15 | Tdk Corp | Substrate where functional layer pattern is formed and method for forming functional layer pattern |
| KR100704986B1 (en) * | 2006-04-27 | 2007-04-09 | 한국생명공학연구원 | Establishment of functional microbial community being capable of degrading diesel oil and the preservation method |
| KR100806208B1 (en) * | 2006-08-04 | 2008-02-22 | (주)지노첵 | A Polynucleotide probe and chip kit for skate and ray species discrimination based on the single nucleotide polymorphisms in the mitochondrial COI gene |
| KR100832570B1 (en) * | 2006-12-11 | 2008-05-28 | 대한민국 | PCR primer set for sex determination in pig horse deer and cattle And Method for Sex determination in Pig horse deer and cattle using these Primers |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52142961U (en) * | 1976-04-22 | 1977-10-29 | ||
| JPS5767667A (en) * | 1980-10-13 | 1982-04-24 | Matsushita Electric Ind Co Ltd | Coated surface for self-cleaning |
-
1988
- 1988-04-06 JP JP63086197A patent/JP2565371B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52142961U (en) * | 1976-04-22 | 1977-10-29 | ||
| JPS5767667A (en) * | 1980-10-13 | 1982-04-24 | Matsushita Electric Ind Co Ltd | Coated surface for self-cleaning |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0866635A (en) * | 1993-12-14 | 1996-03-12 | Toto Ltd | Photocatalytic thin film and its formation |
| JPH08208414A (en) * | 1994-11-01 | 1996-08-13 | Toray Ind Inc | Resin composition and antimicrobial and antifungal methods |
| JPH09249871A (en) * | 1996-03-14 | 1997-09-22 | Toli Corp Ltd | Stainproofing and deodorizing structure and interior material utilizing the same structure |
| JPH10217383A (en) * | 1996-12-03 | 1998-08-18 | Achilles Corp | Decorative sheet and production thereof |
| JPH11166082A (en) * | 1997-12-04 | 1999-06-22 | Nitto Denko Corp | Molding of ultra-high molecular-weight polyethylene and its production |
| JP2002036411A (en) * | 1999-12-28 | 2002-02-05 | Tdk Corp | Functional coating film and manufacturing method therefor |
| JP2001328195A (en) * | 2000-05-19 | 2001-11-27 | Tdk Corp | Functional film |
| JP4534305B2 (en) * | 2000-05-19 | 2010-09-01 | Ｔｄｋ株式会社 | Method for producing conductive film |
| JP2003015286A (en) * | 2001-06-28 | 2003-01-15 | Tdk Corp | Substrate where functional layer pattern is formed and method for forming functional layer pattern |
| KR100704986B1 (en) * | 2006-04-27 | 2007-04-09 | 한국생명공학연구원 | Establishment of functional microbial community being capable of degrading diesel oil and the preservation method |
| KR100806208B1 (en) * | 2006-08-04 | 2008-02-22 | (주)지노첵 | A Polynucleotide probe and chip kit for skate and ray species discrimination based on the single nucleotide polymorphisms in the mitochondrial COI gene |
| KR100832570B1 (en) * | 2006-12-11 | 2008-05-28 | 대한민국 | PCR primer set for sex determination in pig horse deer and cattle And Method for Sex determination in Pig horse deer and cattle using these Primers |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2565371B2 (en) | 1996-12-18 |
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