JPH0244348B2 - Bosuisoseibutsu*sonoseizohohooyobishujunohyomennobosuihogonishosuruhoho - Google Patents
Bosuisoseibutsu*sonoseizohohooyobishujunohyomennobosuihogonishosuruhohoInfo
- Publication number
- JPH0244348B2 JPH0244348B2 JP7631183A JP7631183A JPH0244348B2 JP H0244348 B2 JPH0244348 B2 JP H0244348B2 JP 7631183 A JP7631183 A JP 7631183A JP 7631183 A JP7631183 A JP 7631183A JP H0244348 B2 JPH0244348 B2 JP H0244348B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- alkyl
- composition
- copolymer
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 63
- 229920001577 copolymer Polymers 0.000 claims description 25
- 238000004078 waterproofing Methods 0.000 claims description 24
- 239000006185 dispersion Substances 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 239000004480 active ingredient Substances 0.000 claims description 12
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 11
- 230000009477 glass transition Effects 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000002917 insecticide Substances 0.000 claims description 10
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 9
- 239000000417 fungicide Substances 0.000 claims description 9
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 claims description 6
- 229960002809 lindane Drugs 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 230000000855 fungicidal effect Effects 0.000 claims description 5
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- RULKYXXCCZZKDZ-UHFFFAOYSA-N 2,3,4,5-tetrachlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C(Cl)=C1Cl RULKYXXCCZZKDZ-UHFFFAOYSA-N 0.000 claims description 3
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 claims description 3
- 229960000490 permethrin Drugs 0.000 claims description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 3
- IOUNQDKNJZEDEP-UHFFFAOYSA-N phosalone Chemical compound C1=C(Cl)C=C2OC(=O)N(CSP(=S)(OCC)OCC)C2=C1 IOUNQDKNJZEDEP-UHFFFAOYSA-N 0.000 claims description 3
- -1 alkyl methacrylate Chemical compound 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000002023 wood Substances 0.000 description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
- 238000000034 method Methods 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 9
- 238000005470 impregnation Methods 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 239000000284 extract Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000012632 extractable Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- IAKOZHOLGAGEJT-UHFFFAOYSA-N 1,1,1-trichloro-2,2-bis(p-methoxyphenyl)-Ethane Chemical compound C1=CC(OC)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(OC)C=C1 IAKOZHOLGAGEJT-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 2
- YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
- 229920000800 acrylic rubber Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000012738 dissolution medium Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 229940051250 hexylene glycol Drugs 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 125000004436 sodium atom Chemical group 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- UENOKZPGSFMVAY-UHFFFAOYSA-N 1-(2,2-dichloroethenyl)-2,3-dimethylcyclopropane Chemical compound CC1C(C1C=C(Cl)Cl)C UENOKZPGSFMVAY-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- VEQMUQZKBLIXLT-UHFFFAOYSA-N 2,3-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1C(C)C1C(O)=O VEQMUQZKBLIXLT-UHFFFAOYSA-N 0.000 description 1
- LCVQGUBLIVKPAI-UHFFFAOYSA-N 2-(2-phenoxypropoxy)propan-1-ol Chemical compound OCC(C)OCC(C)OC1=CC=CC=C1 LCVQGUBLIVKPAI-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- RHLVCLIPMVJYKS-UHFFFAOYSA-N 3-octanone Chemical compound CCCCCC(=O)CC RHLVCLIPMVJYKS-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241001600093 Coniophora Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241001492489 Postia placenta Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052774 Proactinium Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- CRPUJAZIXJMDBK-UHFFFAOYSA-N Toxaphene Natural products C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 1
- 241000222355 Trametes versicolor Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- AFVLVVWMAFSXCK-VMPITWQZSA-N alpha-cyano-4-hydroxycinnamic acid Chemical group OC(=O)C(\C#N)=C\C1=CC=C(O)C=C1 AFVLVVWMAFSXCK-VMPITWQZSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- PLOYJEGLPVCRAJ-UHFFFAOYSA-N buta-1,3-diene;prop-2-enoic acid;styrene Chemical compound C=CC=C.OC(=O)C=C.C=CC1=CC=CC=C1 PLOYJEGLPVCRAJ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- IYCOKCJDXXJIIM-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CCCCOC(=O)C=C IYCOKCJDXXJIIM-UHFFFAOYSA-N 0.000 description 1
- TUZBYYLVVXPEMA-UHFFFAOYSA-N butyl prop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C=C TUZBYYLVVXPEMA-UHFFFAOYSA-N 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 1
- RRUSYLYDWCIAGO-UHFFFAOYSA-N ethyl prop-2-enoate;styrene Chemical compound CCOC(=O)C=C.C=CC1=CC=CC=C1 RRUSYLYDWCIAGO-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 125000005625 siliconate group Chemical group 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- OEJNXTAZZBRGDN-UHFFFAOYSA-N toxaphene Chemical compound ClC1C(Cl)C2(Cl)C(CCl)(CCl)C(=C)C1(Cl)C2(Cl)Cl OEJNXTAZZBRGDN-UHFFFAOYSA-N 0.000 description 1
- DFNPRTKVCGZMMC-UHFFFAOYSA-M tributyl(fluoro)stannane Chemical compound CCCC[Sn](F)(CCCC)CCCC DFNPRTKVCGZMMC-UHFFFAOYSA-M 0.000 description 1
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 description 1
- PWBHRVGYSMBMIO-UHFFFAOYSA-M tributylstannanylium;acetate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(C)=O PWBHRVGYSMBMIO-UHFFFAOYSA-M 0.000 description 1
- JUEAPPHORMOWPK-UHFFFAOYSA-M tributylstannyl benzoate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)C1=CC=CC=C1 JUEAPPHORMOWPK-UHFFFAOYSA-M 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
- C04B41/4927—Alkali metal or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one SiâO bond
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Structural Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Roof Covering Using Slabs Or Stiff Sheets (AREA)
- Paints Or Removers (AREA)
Description
æ¬çºæã¯å»ºç©ã®å€è£
ãçŠãæšçã®ãããªçš®ã
ã®
è¡šé¢ã®é²æ°Žã»ä¿è·çšçµæç©ããããã®è£œé æ¹æ³ã
ãã³ããããè¡šé¢åŠçã«äœ¿çšããæ¹æ³ã«é¢ããã ***ç¹èš±åºé¡ïŒOLSïŒç¬¬2355813å·ã«ããèæ°Ž
æ§ã®æ¹è¯ãããå å€è£ çšã®çè²è¢«èŠã補é ããã
ãã®ãã€ã³ããŒãšããŠãã¢ã¯ãªã«é žããã«ãã¢ã¯
ãªã«é žãšãã«ãããã¯ã¢ã¯ãªã«é žã¡ãã«ã®åç¬é
åäœãããã¯ã¢ã¯ãªã«é žããã³ïŒãŸãã¯ã¡ã¿ã¯ãª
ã«é žãŸãã¯ãããã®ãšã¹ãã«ãããŒã¹ãšããå ±é
åäœãå«ãæ°Žæ§åæ£æ¶²ã§ãã€ãŠãåæ£æ¶²ã®ééåœ
ãïŒãïŒééïŒ ã®æ°Žçžã·ãªã³ãŒã³ããšãã«ãŸãžãŠ
ã ã»ã¡ãã«ã·ãªã³ããŒããå«æããåæ£æ¶²ã¯å ¬ç¥
ã§ããã ãŸããç±³åœç¹èš±ç¬¬4012355å·ã«ãããã¹ãã¬ã³
âãã¿ãžãšã³âã¢ã¯ãªã«é žãŸãã¯ã¢ã¯ãªã«é žãšã¹
ãã«ã®äžå å ±éåäœãããªãªã¬ãã€ã³ãé ¢é žãã
ã«å ±éåäœãã¢ã¯ãªã«é žãŸãã¯ã¡ã¿ã¯ãªã«é žã¢ã«
ãã«éåäœçã®ãããªè圢ææ§éåäœã®æ°Žæ§åæ£
液ãšãã·ãªã³ãŒã³ã®æ°Žæº¶æ¶²ãŸãã¯çåæ°ŽçŽ æº¶æ¶²ã
ãšãã«ã·ãªã³ããŒã氎溶液ãšãè圢ææ§éåäœïŒ
ã·ãªã³ãŒã³ã®ééæ¯ã12ïŒïŒãšïŒïŒïŒã®éã«ãªã
ããã«å«æããçµæç©ã§åŠçããããšã«ãã埮现
ã«åå²ããææã®è¡šé¢ã®è èãé²æ¢ããããšã¯å ¬
ç¥ã§ããã ãšãã«èå³æ·±ãã®ã¯ã氎硬æ§ãã€ã³ããŒãããŒ
ã¹ãšãã建ç©ã®å€è£ ãçŠçã®ãããªè¡šé¢ã®åŠçã«
䜿çšãããåæããªããŒãããŒã¹ãšããçµæç©ã¯
é²æ°Žæ§ã®ä»ã«ä»¥äžã®æ§è³ªã瀺ãããšã§ããã è圢ææ§è¯ãã 玫å€ç·ã«å¯Ÿããå®å®æ§ãè¯ãã ã¢ã«ã«ãªæ§åªäœäžã§å®å®æ§ãè¯ããããªã
ã¡ãã¢ã«ã«ãªæ§ããšãã«PH10ãè¶ ããåªäœäžã§ã
ãã€ããã鹞åãããªãã äŸãã°ãšãã¬ã³æ§ã¢ãã«ã«ãã³é žãŸãã¯ãžã«ã«
ãã³é žããå°ãããã«ã«ããã·éšåãå«ãããªã
ãŒã¯ã¢ã«ã«ãªæ§åªäœäžã§ã®å®å®æ§ãæªãã®ã§é€å€
ãããããšã確ãããããŠããã æ¬çºæè ãã¯ãã¢ã«ã«ãªåŽPHã«å®å®ãªæ°Žæ§åªäœ
ã«å ãŸããåæ£æ¶²ã®åœ¢ã®ã¹ãã¬ã³âã¢ã¯ãªã«é žã¢
ã«ãã«åå ±éåäœã以äžã«è¿°ã¹ãæ§è³ªãæããåŸ
æ¥æè¡ã®ã¢ã¯ãªã«é žã¢ã«ãã«å ±éåäœãããŒã¹ãš
ããçµæç©ã«ååšããéãããå®è³ªçã«å€ãé²æ°Ž
å€ãšçµã¿åãããããšãã§ããããšãèŠåºããã æ¬çºæè ãã¯ã貯èµå®å®æ§ã®ããçµæç©ãèŠåº
ããããã®çµæç©ã¯ã以äžã®æ§è³ªããã€ã åŸæ¥æ³ïŒããŒã«ããšã¢ã¬ã³çïŒã«ãã氎硬æ§
ãã€ã³ããŒãããŒã¹ãšãã建ç©å€è£ ã«çµæç©ã容
æã«é©çšã§ãããã®çµæç©ã¯ä¹Ÿç¥ãããšã¢ã¯ãªã«
æš¹èã®æ¥çæ§ã»çŽ«å€ç·å®å®æ§ãšã·ãªã³ãŒã³æš¹èã®
è¡šé¢æ§è³ªãšã䜵æãã建ç©å€è£ ã®é²æ°Žæ§ãæ¹åã
åŸãèã圢æããã åæ§ã«ãæšæã®è¡šé¢ããã³å éšã®é²æ°ŽãšåŠç
ãå¯èœã«ããã æ¬çºæã®ç®çã§ããçµæç©ã¯ã¢ã¯ãªã«é žã¢ã«ã
ã«å ±éåäœã®æ°Žæ§åæ£æ¶²ãšã¢ã«ã«ãªã¢ã«ãã«ã·ãª
ã³ããŒããšãå«æããŠããããã®çµæç©ã®ç¹åŸŽã¯
以äžã®éãã§ããã æ°Žæ§åæ£æ¶²ã¯å¡©åºæ§PHã«å®å®ãªæ°Žæ§åªäœã«å
ãŸããåæ£æ¶²ã®åœ¢ã®ã¢ã¯ãªã«é žã¢ã«ãã«ãšè³éŠæ
ããã«åéäœã®è圢ææ§å ±éåäœããæãã該è³
éŠæããã«åéäœã¯ãã®å¯Ÿå¿ããåç¬éåäœãã¬
ã©ã¹è»¢ç§»ç¹70ã170âã瀺ããããªåéäœã§ããã ã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã®ååšéã¯ä¹Ÿ
ç¥å ±éåäœ100ïœåœãã¢ã«ãã«ã·ãªã³ããŒã0.05
ã0.17ã¢ã«ã§ãããããã«ããã¢ã«ãã«çžåœãã
å®äœã¯æ¬¡ã®åºã§ããã è³éŠæããã«åéäœã®äŸãšããŠã¯ã¹ãã¬ã³ãšã¡
ãã«ã¹ãã¬ã³ãæããããã 䜿çšã§ããã¢ã¯ãªã«é žã¢ã«ãã«ã¯å¯Ÿå¿ããåç¬
éåäœã®ã¬ã©ã¹è»¢ç§»ç¹ãïŒ10âãâ60âã瀺ãå
éäœã§ããã ã¢ã¯ãªã«é žã¢ã«ãã«ãšããŠã¯ã¢ã«ãã«åºã®ççŽ
æ°ãïŒãïŒã奜ãŸããã¯ïŒãïŒã®ãã®ãæããã
ãã 䜿çšããè³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«
ãã«ã®éã¯ããããããåŸãããå ±éåäœã®ã¬ã©
ã¹è»¢ç§»ç¹ãâïŒâãïŒ25âãšãªãããã«éžã°ã
ãã åéäœã®äœ¿çšéã¯ã³ã¢ãããŒã®æ§è³ªãšææã®å ±
éåäœã®ã¬ã©ã¹è»¢ç§»ç¹ã«ãã€ãŠæ±ºãŸãããããã®
éã¯äŸãã°Bull.An Phys.Soc.ïŒïŒïŒ123ïŒ1956ïŒ
ã«èšèŒã®FOXã®åŒã«ãã容æã«æ±ºå®ãããã ããªãã¡ãã¹ãã¬ã³âã¢ã¯ãªã«é žãšãã«å ±éå
äœã¯ãã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãšãã«ã®æ¯ã26ïŒ74
ã45ïŒ55ã®ãšãã¬ã©ã¹è»¢ç§»ç¹ãïŒâã20âã§ã
ãããŸãã¹ãã¬ã³âã¢ã¯ãªã«é žãããã«å ±éåäœ
ã¯ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãããã«ã®æ¯ã36ïŒ64ã
52ïŒ48ã®ãšãã¬ã©ã¹è»¢ç§»ç¹ãïŒâã20âã§ããã
ããªã¹ãã¬ã³ã¯ã¬ã©ã¹è»¢ç§»ç¹ãïŒ100âã§ããã
ããªé ¢é žãšãã«ãšããªã¢ã¯ãªã«é žãããã«ã®ã¬ã©
ã¹è»¢ç§»ç¹ã¯ãããããâ24âãšâ37âã§ããã 瀺ãããã¬ã©ã¹è»¢ç§»ç¹ã®å€ã¯äŸãã°A.
LambertïŒãããªããŒ10ã319ïŒ1969ïŒãã«èšèŒã®
ãå·®åèµ°æ»ç±éæ³ãã«ãã枬å®ããããã®ã§ããã è³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«ãã«ã®å ±
éåäœã®æ°Žæ§åæ£æ¶²ã¯ã¢ã«ã«ãªåŽPHã«å®å®ãªåªäœ
ã§å ãŸãããããã®ã¢ãããŒãæ°Žæ§ä¹³æ¿æ¶²äžã§é
åããããšã«ããåŸãããã äžèšéååªäœã¯äžèšã¢ãããŒã®ä»ã«æ°Žçžãšã¢ã«
ã«ãªæ§åªäœäžã§å®å®ãªãã®ããéžã°ããçš®ã ã®åŸ
æ¥å ¬ç¥ã®ãšãã«ãžãšã³éåæ·»å å€ïŒè§Šåªãä¹³æ¿å€
çïŒ è§Šåªã®äŸãšããŠã¯ãã¯ã¡ã³ããžã€ãœãããã«ã
ã³ãŒã³ããã©ã¡ã³ã¿ã³çã®ããããã«ãªãã·ãã®
ãããªææ©ããããã«ãªãã·ãé¡ããããªãŠã ã
ã«ãªãŠã ãŸãã¯ã¢ã³ã¢ããŠã®éç¡«é žå¡©ã®ãããªé
ç¡«é žå¡©é¡ãæããããã ä¹³æ¿å€ã®äŸãšããŠã¯ãèèªé žå¡©ãã¢ã«ãã«ã¹ã«
ããšãŒããã¢ã«ãã«ã¹ã«ãããŒããã¢ãªãŒã«ã¹ã«
ããšãŒããã¢ãªãŒã«ã¹ã«ãããŒããã¢ã«ãã«ã¢ãª
ãŒã«ã¹ã«ããšãŒããã¢ã«ãã«ã¢ãªãŒã«ã¹ã«ãããŒ
ããã¹ã«ãã¹ã¯ã·ããŒããã¢ã«ãã«ãã¹ããšãŒã
ã®ã¢ã«ã«ãªéå±å¡©çã®ãããªé°ã€ãªã³ç³»ä¹³æ¿å€ã
ããªãšããã·èèªæã¢ã«ã³ãŒã«ãããªãšããã·ã¢
ã«ãã«ããšããŒã«ãããªãšããã·èèªé žçã®ãã
ãªéã€ãªã³ç³»ä¹³æ¿å€ãæããããã è³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«ãã«ã®å ±
éåäœã®æ°Žæ§åæ£æ¶²ã¯20ã60ééïŒ ã奜ãŸããã¯
40ã55ééïŒ ã®ç²åŸã0.05ã0.5ÎŒïœã®ä¹Ÿç¥ææå
ãå«æããŠããŠãããã äžèšåæ£æ¶²ã¯åŠçãã¹ãè¡šé¢ã®æ§è³ªã«åŸã€ãŠåž
éããŠãããã æ¬çºæã®é²æ°Žçµæç©ã«äœ¿çšã§ãããã¢ã«ã«ãªã¢
ã«ãã«ã·ãªã³ããŒãã¯C1âC3ã¢ã«ãã«åºãæã
ããã®ã§ããã ãã®ã¢ã«ãã«ã·ãªã³ããŒãã®å¥œé©ãªäœ¿çšéã¯å ±
éåäœ100ïœåœã0.065ã0.1ã¢ã«ã§ããã 奜é©ãªã¢ã«ãã«ã·ãªã³ããŒãã¯ä»¥äžã®ãã®ã§ã
ãã 也ç¥å ±éåäœ100éééšåœã也ç¥ã¡ãã«ã·ãª
ã³ããŒã4.8ã16.3éééšã奜ãŸããã¯6.4ã9.8é
ééšã®å²åã®ãœãžãŠã ã¡ãã«ã·ãªã³ããŒãã 也ç¥å ±éåäœ100éééšåœã也ç¥ã¡ãã«ã·ãª
ã³ããŒã5.6ã19éééšã奜ãŸããã¯7.44ã11.4é
ééšã®å²åã®ããã¿ã³ãŠã ã¡ãã«ã·ãªã³ããŒãã æ¬çºæã®é²æ°Žçµæç©ã¯åæ§ã«è²çŽ ãæ©æ¢°çæ¹æ
ã«åŒç¶ããŠæ°æ³¡ã圢æãããããšãããã®ãé²æ¢
ããããã®æ¶æ³¡å€ïŒãžã¡ãã«ããªã·ãããµã³åïŒã
ããã³ããšãã«ãè³éŠæããã«åéäœãšã¢ã¯ãªã«
é žã¢ã«ãã«ã®å ±éåäœã®è圢æã®æäœæž©åºŠãå¿ èŠ
ã«å¿ãäœäžãããããã®é鹞åæ§æ¥çå€ãäŸãã°
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«ããšãã¬ã³ã°
ãªã³ãŒã«ããšãã«ãšãŒãã«ããããã¬ã³ã°ãªã³ãŒ
ã«ããšãã«ãšãŒãã«ããžãããã¬ã³ã°ãªã³ãŒã«ã
ãšãã«ãšãŒãã«ãŸãã¯è³éŠæååç©ã®å«éã®å°ãª
ãããã¯ã€ãã»ã¹ããªãããå補åã®ãããªçš®ã
ã®æ·»å ç©ãå«æããŠããŠãããããããã®æ¥çå€
ã®äœ¿çšéã¯è©²å ±éåäœåæ£æ¶²100éééšåœãïŒã
ïŒéééšçšåºŠã§ããã äžè¿°ã®ããã«ãæ¬çºæã®é²æ°Žå€çµæç©ã¯æšæã®
é²æ°Žã«ããé©åããŠããã ãæšæãã«ã¯ãããªå±ãèæ¿ãã¯ãåããæ¿ã
ç³ä»èæ¿æ§é äœããã¢ã€ããŒããŒããããŒãã¯ã«
ããŒããã»ã«ããŒã¹æ§ææãããŒã¹ãšããçš®ã ã®
è€å補åã®ãããªæšè³ªè£œåã®ç·äœãããã ç¹ã«å¥œé©ãªé©çšäŸãšããŠã¯ãæ¬çºæã®é²æ°Žçµæ
ç©ã¯çµæç©ã®å šééã®ïŒééïŒ è¿ã®æ®ºã«ãå€ãã
ã³ïŒãŸãã¯æ®ºè«å€åã®æšæã®ä¿è·å€ãããã«å«æ
ããŠããŠãããã 殺ã«ãå€ã¯ãã®ãé¡ãã«ãé¡ããã³è æèã®æ»
æã«å¯ŸåŠããããã«æšæãåŠçããã®ã«æ £çšãã
ãŠãããã®ããéžã°ããã殺è«å€ã®äŸãšããŠã¯ã
ããšããŒã«ã®ããã²ã³èªå°äœãäŸãã°ããã©ã¯ã
ãããšããŒã«ããã³ãã³ã¿ã¯ããããšããŒã«ãé
å±å¡©ãšãã«é ããã³ã¬ã³ãã³ãã«ããã¯ãã ãäº
éã®å¡©ãäŸãã°ããã¿ã³é žããªã¯ã¿ã³é žããã³ã
ããã³é žã®ãããªã«ã«ãã³é žã®èªå°äœãäŸãã°ã
ã¹ããªããã«é«é žåç©ãããªããã«é«ããåç©ã
ããªããã«é«ãªã³é žå¡©ãããªããã«é«å®æ¯éŠé žå¡©
ãŸãã¯ããªããã«é«é ¢é žå¡©ã®ãããªææ©é«é¯äœã
ã¡ãã¬ã³ãã¹ããªã·ã¢ããŒããã¡ã«ã«ãããã³ãŸ
ãã¢ãŸãŒã«ããžã¯ããã«ã¢ããïŒïŒ®âãžã¯ããã
ã«ãªãã¡ãã«ããªâNâ²ïŒNâ²âãžã¡ãã«ââã
ãšãã«ã¹ã«ãã¢ããïŒãæããããã ãããã¯åŠççšçµæç©ã®ééã®ïŒééïŒ ãŸã§å
åšããŠããŠãããããã®éã¯ãã¡ãã䜿çšãã殺
ã«ãå€ã®æŽ»æ§ã«ãã€ãŠæ±ºãŸãã 殺è«å€ã¯æè«ã«ããæšæé£å®³ãé²æ¢ããããã«
æšæãåŠçããã®ã«æ £çšããããã®ããéžã°ã
ããäŸãã°DDTïŒãžã¯ãããžããšãã«ããªã¯ãã
ãšã¿ã³ïŒãã¡ããã·ã¯ãã«ïŒãžã¡ããã·ãžããšã
ã«ããªã¯ãããšã¿ã³ããªã³ãã³ïŒãããµã¯ããã·
ã¯ããããµã³ã®ç°æ§äœïŒãã¯ãã«ãã³ïŒãªã¯ã¿ã¯
ãããããµãããã¡ã¿ãã€ã³ãã³ïŒãã¢ã«ããªã³
ïŒãšã³ããããµã¯ãããããµããããžã¡ã¿ããã
ã¿ãªã³ããããµããšã³ã®ãããªææ©ããã²ã³åå
ç©é¡ãäŸãã°ãžãšããªã³ïŒïŒ¯ïŒïŒ¯ïŒOâ²ïŒOâ²âã
ãã©ãšãã«ïŒ³ïŒSâ²âã¡ãã¬ã³ãžããªãã¹ããšãŒ
ãïŒããã©ããªã³ïŒïŒ¯ïŒïŒ¯âãžãšãã«ãã©ããã
ããšãã«ããªãã¹ããšãŒãïŒãããµãã³ïŒïŒ¯ïŒïŒ¯
âãžãšãã«ãžããªãã¹ããªã«ã¡ãã«âïŒã¯ããâ
ïŒãã³ãŸããµãŸãã³ïŒã®ãããªææ©ãªã³ååç©
é¡ãäŸãã°ã»ãã³ïŒããããã«ïŒ®âã¡ãã«ã«ãŒã
ã¡ãŒãïŒãã«ã«ããã©ã³ïŒãžã¡ãã«ãžããããã³
ãŸãã©ã㫠âã¡ãã«ã«ãŒãã¡ãŒãïŒã®ãããª
ã«ãŒãã¡ãŒããäŸãã°ãã«ã¡ã¹ãªã³ïŒÎ±âã·ã¢ã
ããšããã·ãã³ãžã« ãžããã¢ããã« ãžã¡ã
ã«ã·ã¯ããããã³ ã«ãŒããã·ã¬ãŒãïŒããã«ã¡
ã¹ãªã³ïŒããšããã·ãã³ãžã« ã·ã¹âãã©ã³ã¹
ãžã¡ãã« ãžã¯ããããã« ã·ã¯ããããã³ ã«
ãŒããã·ãŒããããšã³ãã¬ã¬ãŒãïŒÎ±âã·ã¢ã
ããšããã·ãã³ãžã« ã¯ããããšãã« ã¡ãã«ã
ãã«ããã¬ãŒãïŒã®ãããªåæãã¬ã¹ãªãã€ãé¡
ãæããããã ãããã¯åŠççšçµæç©ã®ééã®ïŒééïŒ ãŸã§å
åšããŠããŠãããããã®éã¯ãã¡ã¡ãã䜿çšãã
殺è«å€ã®æŽ»æ§ã«ãã€ãŠæ±ºãŸãã ç¹ã«éèŠãªæå¹æåã¯æ¬¡ã®çµã¿åããïŒæå¹æ
å100éééšåœãïŒããæãã ããã©ã¯ããããšããŒã«ããã³ïŒãŸãã¯ãã³
ã¿ã¯ããããšããŒã«ããã³ïŒãŸãã¯ææ©é«é¯äœã«
å Žåã«ãã€ãŠãžã¯ãããã«ã¢ãããæ··åãããã®
ããæã殺ã«ãå€70ã98éééš ãªã³ãã³ãã
ã³ïŒãŸãã¯ããµãã³ããã³ïŒãŸãã¯ã»ãã³ãã
ã³ïŒãŸãã¯ãã«ã¡ã¹ãªã³ããã³ïŒãŸãã¯ããšã³ã
ã¬ã¬ãŒãããæã殺è«å€30ãïŒéééšã æ¬çºæã®å Žåã«ãã€ãŠæ®ºã«ãå€ããã³ïŒãŸãã¯
殺è«å€ãæ·»å ããé²æ°Žçµæç©ã®ä¹Ÿç¥ææåå«æé
ã¯é²æ°Žãã¹ãè¡šé¢ã®æ§è³ªã«ããïŒã50ééïŒ ã奜
ãŸããã¯ïŒã25ïŒ ã§ããã æ¬çºæã¯ãŸãäžèšé²æ°Žçµæç©ã®è£œé æ³ãæäŸã
ãã ãã®æ¹æ³ã¯äžèšæ¯çã«åŸããçš®ã ã®æ§ææåã
ãã³å Žåã«ãã€ãŠçš®ã ã®è£ å ¥ç©ããã³æ·»å å€ãæ··
åããããšããæãã ã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã¯å¥œãŸããã¯ä¹Ÿ
ç¥ææåã50ééïŒ ãŸã§å«æãåŸã氎溶液ã®åœ¢ã§
å°å ¥ãããã å Žåã«ãã€ãŠäœ¿çšããã殺ã«ãå€ãšæ®ºè«å€ã¯å ±
éåäœãšã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã®æ°Žæ§å
æ£æ¶²ã«ããæ§æãããæ°Žæ§åªäœã«å ãŸããã圢
ã§ããããã液ç¶ã®å Žåã¯ãã®ãŸãŸããããã¯å¥œ
ãŸããã¯ææ©æº¶åªãŸãã¯å³æ©æº¶åªæ··åç©ã«æº¶è§£ã
ãŠå°å ¥ãããã 䜿çšãåŸã溶åªã®ãã¡ãäŸãã°ã¯ãããã³ãŒ
ã³ããžã¯ãããã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãŸã
ã¯100âã300âã®éã®èžçç»åã§ããç¯æ²¹ã®ãã
ãªç³æ²¹ã®èžçã«ããçŽæ¥åŸãããè³éŠæçåæ°ŽçŽ
æ··åç©ã®ãããªæ¶²ç¶è³éŠæçåæ°ŽçŽ é¡ãäŸãã°ã·
ã¯ããããµããŒã«ã®ãããªã¢ãã¢ã«ã³ãŒã«é¡ãäŸ
ãã°ãšãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒ
ã«ãããã·ã¬ã³ã°ãªã³ãŒã«ããžã°ã©ã€ã ãããã
ã·ãšã¿ããŒã«ã®ãããªã°ãªã³ãŒã«é¡ãããªãªãŒã«
é¡ãŸãã¯ãããã®ã¢ã«ã«ããŒã«ãšã®ãšãŒãã«é¡ã
äŸãã°ãšãã«ã¢ãã«ã±ãã³ããžã€ãœããã«ã±ãã³
ã®ãããªèèªæã±ãã³é¡ãäŸãã°ãã¿ã«é žããã«
ãŸãã¯ãã¿ã«é žããã«ããããã¯ã³ãã¯é žãã¢ãž
ãã³é žãã·ãŠãŠé žãŸãã¯ããã³é žã®ãžã¡ãã«ãšã¹
ãã«ãŸãã¯ãžãšãã«ãšã¹ãã«ã®ãããªãšã¹ãã«
é¡ãäŸãã°ãžã¡ãã«ãã«ã ã¢ãããŸãã¯ãžã¡ãã«
ã¢ã»ã¿ããã®ãããªã¢ããé¡ãæããããããã
ãã¯åäžã®æº¶åªãšããŠããããã¯äºçš®é¡ä»¥äžã®æº¶
åªã®æ··åç©ãšããŠã䜿çšã§ããã æ°Žæ§åæ£æ¶²ãšã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã
ãæãæ°Žæ§åªäœã«å ãŸããæå¹æåã®ãšãã«éèŠ
ãªäœ¿çšæ³ã¯æ°Žã«ä¹³æ¿ãåŸãäžèšçµæã®æ¿çž®æ¶²ãä»
ããŠè©²æå¹æåãå°å ¥ããããšããæãã æå¹æåã¯æ®ºã«ãå€ããã³ïŒãŸãã¯æ®ºè«å€ã
ãæãã 液ç¶æº¶è§£åªäœã¯æå¹æåã«å¯Ÿããå°ãªããšã
äžçš®ã®ææ©æº¶åªãé°ã€ãªã³ç³»çé¢æŽ»æ§å€ããã³å Ž
åã«ãã€ãŠå°ãªããšãäžçš®ã®æ²¹ããã³ïŒãŸãã¯å°
ãªããšãäžçš®ã®åºçå€ããæãã ç¹ã«å¥œé©ãªæ¿çž®æ¶²ã¯ä»åœç¹èš±åºé¡å ¬é第
2498419å·ã«èšèŒãããŠãããã®ã§ãããããã¯
æ¿çž®æ¶²100éééšåœãäžèšã®ãã®ãå«æããã æå¹æå15ã40éééš æå¹æåã®æº¶åª30ã75éééš æ²¹ããã³ïŒãŸãã¯åºçå€ïŒã20éééš é°ã€ãªã³ç³»çé¢æŽ»æ§å€ïŒã25éééšã äžèšæ¿çž®æ¶²ã®çµæã«å«ãŸããçé¢æŽ»æ§å€ã¯äžèš
ã®ãã®ããéžã°ããã ïœ åŒïŒïŒã®ç¡«é žãšã¹ã㫠âïŒOCH2CH2ïŒoâOSO3M ïŒïŒ åŒäžãã¯é£œåãããã¯äžé£œåã®ïŒåãŸãã¯
ïŒå以äžã®ãããååãå«ãããšã®ããèèªæ
ïŒçŽéãŸãã¯åæïŒãèç°æãŸãã¯è³éŠæç±æ¥ã®
åºã瀺ããïœã¯çé¢æŽ»æ§å€ã®HLBã®å€ã10ã
16ã«çžåœãããããªå€ã«åºå®ãããæ°å€ã瀺
ããïŒã¯çé¢æŽ»æ§å€ãä¹³æ¿ãã¹ãæ¿çž®æ¶²ãšæ°Žãš
ã«æº¶è§£ããããã«éžã°ããç¡æ©ãŸãã¯ææ©æ®åº
ã瀺ãã ïœ åŒïŒïŒã®ææ©ãªã³ãšã¹ãã« ïŒåŒäžãããã³ïœã¯åŒïŒïŒãšåãæå³ãæ
ã€ãR1ã¯M1ãŸãã¯ïŒ²âïŒOCH2CH2ïŒoâã瀺
ããR1ãšïŒ²âïŒOCH2CH2ïŒoâãšåäžã§ãç°ãª
ã€ãŠããŠããããM1ã¯æ°ŽçŽ ååãŸãã¯åŒïŒïŒ
ã®ïŒãšåãæå³ã瀺ããäºã€ã®M1ïŒR1ïŒM1ã®
ãšãïŒã¯åäžã§ãç°ãªã€ãŠããŠããããïŒ HLBïŒèŠªæ°Žæ§éšïŒèŠªæ²¹æ§éšãã©ã³ã¹ïŒã¯ä¹³æ¿å€
ã®åéã§åšç¥ã®å€§ããã§ããã詳现ã«ã¯ãKIRK
âOTHMER Encyclopedia of chemical
Technology第ïŒç第ïŒå·»ç¬¬910é â第915é
ïŒ1979幎ïŒåç §ã 奜ãŸããã¯äžèšååç©ã¯åŒïŒïŒããã³ïŒïŒ
ã«ãããŠããïŒåãŸãã¯ïŒå以äžã®ççŽ æ°ïŒã
ïŒã®ã¢ã«ã³ãã·åºãŸãã¯ããšãã«åºã§çœ®æãããŠ
ããããšã®ããççŽ æ°ïŒã20ã®çŽéãŸãã¯åæç¶
ã¢ã«ãã«åºãã¢ã«ãã«åºã®å®çŸ©ãäžèšã®éãã§ã
ãã¢ã«ãã«ã«ã«ããã«åºãäžèšã¢ã«ãã«åºã«å¯Ÿã
ãŠç€ºãããããã«çœ®æãããŠããããšã®ããççŽ
æ°ïŒãïŒã®ã·ã¯ãã¢ã«ãã«åºããããã¯ã¢ã«ãã«
éšåãçŽéãŸãã¯åæç¶ã§ççŽ æ°ïŒã20ã§ããã¢
ã«ãã«ããšãã«åºã瀺ããïŒïŒåŒïŒïŒãã¢ã³ã¢
ããŠã åºãŸãã¯ã¢ã«ã«ãªéå±ååã瀺ããM1ã
æ°ŽçŽ ååãã¢ã³ã¢ããŠã åºãŸãã¯ã¢ã«ã«ãªéå±å
åã瀺ããã®ããéžã°ããã äžèšã¢ã³ã¢ããŠã åºã«ã¯åŒïŒ®ïŒR2R3R4R5ïŒïŒåŒ
äžãR2ïŒR3ïŒR4ããã³R5ããåäžãŸãã¯çžç°ãª
ã€ãŠãæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ããããã·ã¢
ã«ãã«åºã瀺ããïŒåã®ã¢ã«ãã«åºãäžç·ã«é žçŽ
ååãå«ãããšã®ããäºäŸ¡ã®åºã圢æããŠãã
ããïŒã®ååç©ãå«ãŸãããã¢ã³ã¢ããŠã åºã®å š
ççŽ æ°ã¯ïŒä»¥äžã§ããã äžèšå¥œé©ãªä¹³æ¿å€ã«ãããŠãåŒïŒïŒããã³
ïŒïŒã«ãããŠããççŽ æ°ïŒã20ã®çŽéã¢ã«ã
ã«åºããŸãã¯ã¢ã«ãã«éšåãççŽ æ°ïŒã20ã®çŽé
ã¢ã«ãã«ã§ããã¢ã«ãã«ã«ã«ããã«åºã瀺ããïŒ
ïŒåŒïŒïŒïŒãã¢ã³ã¢ããŠã åºãŸãã¯ãããªãŠã å
åã瀺ããM1ïŒåŒïŒïŒïŒãæ°ŽçŽ ååãã¢ã³ã¢ã
ãŠã åºãŸãã¯ãããªãŠã ååã瀺ãçé¢æŽ»æ§å€ã
ãšãã«å¥œé©ã§ããã 以äžã®ååç©ãäŸç€ºãããã ïœ ç¡«é žå¡© ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OSO3NH4 ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OSO3Na ã» CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒoâ
OSO3NH4 ã» CH3âïŒCH2ïŒ12âCOâïŒOCH2CH2ïŒoâ
OSO3NH4 äžåŒäžãïœã¯ïŒã10ã§ããã ïœ ãªã³é žå¡© ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OPO3ïŒM1ïŒ2 ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
ã2PO2M1 ã» CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒoâ
OPO3ïŒM1ïŒ2 ã» ãCH3âïŒCH2ïŒ11âCH2âïŒOCH2ïŒoâã
2PO2M1 äžåŒäžãïœã¯ïŒã10ã§ãããçš®ã M1ã¯ãåäž
ãŸãã¯çžç°ãªã€ãŠãïŒNH4ïŒNH2ïŒC2H4OHïŒïŒ
NHïŒC2H4OHïŒ3ãŸãã¯Naã瀺ãã æå¹æåã®æº¶åªãšããŠã¯åèšæº¶åªã䜿çšã§ã
ãã 溶解åªäœã補é ããã®ã«äœ¿çšãåŸãæ²¹ãããšã
ã«ãäŸãã°äºéº»ä»æ²¹ã倧è±æ²¹ãæŸæ ¹æ²¹ãã¿ããŒ
æ²¹ããã¬ãããŒã«é¡æ··åç©ã®ãããªæ€ç©æ§æ²¹é¡ã
äŸãã°ç¯æ²¹ãšãã©ãã€ã³ãšã®éã®ç³æ²¹ã®èžçç»å
ã§ãããã·ã³æ²¹ã®ãããªé±æ²¹é¡ãæããããã æšæã«åŠçå€ãåºçãããã®ã«é©ããæ¥çå€ã®
äŸãšããŠã¯ãã¢ããã³ãã«ã«ããã·ã¡ãã«ã»ã«ã
ãŒã¹ãã³ãããªããŠã èãŸãã¯ã³ãããªããŠã è
ãšã¹ãã«ãã¢ã©ãã¢ãŽã ãããªããã«ã¢ã«ã³ãŒ
ã«ãããã³é žãã°ãªã»ããã¿ã«é žæš¹èãã€ã³ãã³
ã«å¯ãç³æ²¹ç»åã®ã¯ã©ããã³ã°ã«ãã圢æããã
èèªæããã³ïŒãŸãã¯è³éŠæäžé£œåçåæ°ŽçŽ ã®äœ
ååééåäœããæãçåæ°ŽçŽ ã®äžèšæš¹èãæã
ãããã æ¬çºæã¯ããŸããäžèšçµæç©ã氎硬æ§ãã€ã³ã
補ã®å»ºç©å€è£ ãçŠãæšæçã®åã®çš®ã ã®è¡šé¢ã«å¯Ÿ
ããŠé²æ°ŽåŠçã«äœ¿çšããæ¹æ³ãæäŸããã 建ç©å€è£ ãšçŠã®åŠçã¯äžèšçµæç©ããã®ãŸãŸã
ããã¯æ°Žã§åžéããåŸãå¡è£ ããŒã«ãŸãã¯ãšã¢ã¬
ã³ã䜿çšããŠåŽé§ããããšã«ãããšãã«ç°¡åã«å®
æœã§ããã è¯å¥œãªé²æ°Žã»ä¿è·ãåŸãããã«äžèšè¡šé¢ã«çµæ
ç©ãå¡åžããéã¯äžè¬ã«20ã80ïœïŒm2çšåºŠã§ã
ããåŠçãããæ¯æäœã¯éåžžã«æ¥éã«é©çšåŸïŒæ
éçšåºŠã§é²æ°Žæ§ãç²åŸããã å Žåã«ãã€ãŠæ®ºã«ãå€ããã³ïŒãŸãã¯æ®ºè«å€æ
å¹æåãå«æããé²æ°Žæ§çµæç©ãæšæã«é©çšãã
æ¹æ³ã¯æšæããã®èªå°ç©ã®åŠçã«äœ¿çšãããæ £çš
ã®æ¹æ³ãäŸãã°æµžæŒ¬ããã±å¡ããç空äžããã³ïŒ
ãŸãã¯å å§äžãªãŒãã¯ã¬ãŒãå ã§ã®å«æµžæ³ãªã©ã
䜿çšã§ãããç¹ã«å¥œé©ãªæ¹æ³ã¯äºéç空æ³ãšãã
ããæ¹æ³ã§ããã æšæãåŠçããéã®äžèšçµæç©ã®äœ¿çšéã¯ã©ã
ãªå«æµžæ³ãéžã¶ãã«ãã€ãŠæ±ºãŸãã ããªãã¡ãå«æµžã浞挬ã«ãã€ãŠå®æœãããå Žå
ã¯ãåŠçè¡šé¢m2åœãã®å šçµæç©ïœæ°ã§è¡šãããã
çµæç©äœ¿çšéã¯50ã300ïœïŒm2çšåºŠã§ãããçµæ
ç©ãè¡šé¢ã«ãã±å¡ãããå Žåã¯20ã80ïœïŒm2çšåºŠ
ã®çµæç©ã®éã§ååã§ãããå«æµžãäºéç空äžãª
ãŒãã¯ã¬ãŒãå ã§å®æœãããå Žåã¯ãïŒã40KgïŒ
m2çšåºŠã®çµæç©ã®éã奜é©ã§ããã 以äžã«å®æœäŸãåç §ããŠæ¬çºæãããã«è©³çŽ°ã«
説æããããæ¬çºæã¯ãããã®å®æœäŸã«éå®ãã
ãªãã å®æœäŸ ïŒãïŒ é²æ°Žçµæç©ã®èª¿è£œ 以äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ã®ééæ¯ïŒçŽ
50ïŒ50 㻠也ç¥æœåºåå«æéïŒ çŽ50ïŒ ã» ä¹³æ¿å€ïŒ ã¢ã«ãã«ã¹ã«ãã³é žãããªãŠã ã
ãã³ã¢ã«ãã«ããšããŒã«ãªãã·ãšãã¬ã³ 㻠觊åªïŒ éç¡«é žã¢ã³ã¢ããŠã ã» ç²åŸïŒ 0.05ã0.40ÎŒïœ ã» è圢æ§æäœæž©åºŠïŒ 16â ã» ç²åºŠïŒ 50mïŒPaïŒïŒ³ïŒãã«ãã¯ãã€ãŒã«ã
ç²åºŠèšã䜿çšã20âã«ãããŠ50tïŒåã§æž¬å®ïŒ
ãæããã¹ãã¬ã³âã¢ã¯ãªã«é žããã«å ±éåäœ
ã®æ°Žæ§åæ£æ¶²100éééšãšãè¡šã«ç€ºãéééš
æ°ã®ä»¥äžã®æ§è³ªïŒ 㻠也ç¥æœåºåïŒ çŽ47ïŒ ã» å¯åºŠïŒ20âïŒïŒ 1.34 ã» ã¢ã«ã«ãªæ»Žå®éïŒ 18ïŒ ïŒK2OïŒ ãæããããã¿ã·ãŠã ã»ã¡ãã«ã·ãªã³ããŒãã®æ°Ž
溶液ãšãæ··åããã ãã®ããã«ããŠåŸãããæ··åç©ã®ç²åºŠã¯è¡šã«
瀺ãïŒãã«ãã¯ãã€ãŒã«ãç²åºŠèšã䜿çšããŠ20â
ã«ãããŠ50tïŒåã§æž¬å®ïŒã 貯èµå®å®æ§ åšå²æž©åºŠã§ïŒå¹Žé貯èµããåŸãäžèšã®ããã«ã
ãŠåŸãããçµæç©ã®ç²åºŠã®å¢å ã¯èªããããªãã
ã¢ã«ã«ãªæ§åªäœäžã®å®å®æ§ å®æœäŸïŒã«åŸã調補ãããçµæç©ãïŒã«é40â
ã«ä¿ã€ãã 以äžã®ããšã確èªãããã ç²åºŠã®å¢å ã¯ãªãã 鹞åãããã¢ã¯ãªã«é žããã«ã®éã¯ãã¢ã¯ãª
ã«é žããã«ã®ééã«å¯ŸããééïŒ ã§è¡šãããšã
0.1ïŒ æªæºïŒæž¬å®ã¯éé¢ãã¿ããŒã«éã«ãããïŒã§
ããã èã®é²æ°Žæ§ ãã®æ§è³ªã¯è©Šéšãµã³ãã«ïŒã¬ã©ã¹ïŒã®è¡šé¢çœ®ã
ãã氎滎ã®æ¥è§Šè§ÎžããJ.BIKERMANïŒ
âPhysical Surfacesâã第251é ã¢ã«ãããã¯ãã¬
ã¹ç€ŸããŠãŒãšãŒã¯ïŒ1970幎ïŒã«èšèŒã®æ¹æ³ã«åŸã€
ãŠåºŠïŒãïŒã§æž¬å®ããããšã«ãã€ãŠæ±ºå®ãããã ãã®æž¬å®çµæã¯è¡šã«ç€ºãã å®æœäŸ ïŒ ã¹ãã¬ã³âã¢ã¯ãªã«é žããã«å ±éåäœã®æ°Žæ§å
æ£æ¶²ã®ä»£ããã«ä»¥äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãšãã«ã®ééæ¯ïŒ41ïŒ
59 㻠也ç¥æœåºåïŒ çŽ50ïŒ ã» è圢ææäœæž©åºŠïŒ çŽ16â ãæããã¹ãã¬ã³âã¢ã¯ãªã«é žãšãã«ã䜿çšãã
以å€ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©ã調補ããã ãã®çµæç©ã®æ§è³ªã¯è¡šã«ç€ºãã å®æœäŸ ïŒâ11ïŒæ¯èŒäŸïŒ 以äžã®çµæã®çµæç©ã調補ããã ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ïŒã¢ã¯ãªã«é žã®
ééæ¯ãçŽ47ïŒ49ïŒïŒã也ç¥æœåºåçŽ50ïŒ ããã³
è圢ææäœæž©åºŠçŽ16âã®ã¹ãã¬ã³âã¢ã¯ãªã«é žã
ãã«âã¢ã¯ãªã«é žäžå å ±éåäœã®æ°Žæ§åæ£æ¶²100
éééšãããã³ è¡šã«ç€ºãéééšã®å®æœäŸïŒãïŒã«èšèŒã®ã
ãã¿ã·ãŠã ã»ã¡ãã«ã·ãªã³ããŒãã®æ°Žæº¶æ¶²ã ãã®çµæç©ã®æ§è³ªã¯è¡šã«ç€ºãããã®ãããªçµ
æç©ã¯ç²åºŠã倧ãéãããã䜿çšãé£ããé©çšç
究ã«ã䜿çšããããšããã§ããªãããšã確ããã
ããã
è¡šé¢ã®é²æ°Žã»ä¿è·çšçµæç©ããããã®è£œé æ¹æ³ã
ãã³ããããè¡šé¢åŠçã«äœ¿çšããæ¹æ³ã«é¢ããã ***ç¹èš±åºé¡ïŒOLSïŒç¬¬2355813å·ã«ããèæ°Ž
æ§ã®æ¹è¯ãããå å€è£ çšã®çè²è¢«èŠã補é ããã
ãã®ãã€ã³ããŒãšããŠãã¢ã¯ãªã«é žããã«ãã¢ã¯
ãªã«é žãšãã«ãããã¯ã¢ã¯ãªã«é žã¡ãã«ã®åç¬é
åäœãããã¯ã¢ã¯ãªã«é žããã³ïŒãŸãã¯ã¡ã¿ã¯ãª
ã«é žãŸãã¯ãããã®ãšã¹ãã«ãããŒã¹ãšããå ±é
åäœãå«ãæ°Žæ§åæ£æ¶²ã§ãã€ãŠãåæ£æ¶²ã®ééåœ
ãïŒãïŒééïŒ ã®æ°Žçžã·ãªã³ãŒã³ããšãã«ãŸãžãŠ
ã ã»ã¡ãã«ã·ãªã³ããŒããå«æããåæ£æ¶²ã¯å ¬ç¥
ã§ããã ãŸããç±³åœç¹èš±ç¬¬4012355å·ã«ãããã¹ãã¬ã³
âãã¿ãžãšã³âã¢ã¯ãªã«é žãŸãã¯ã¢ã¯ãªã«é žãšã¹
ãã«ã®äžå å ±éåäœãããªãªã¬ãã€ã³ãé ¢é žãã
ã«å ±éåäœãã¢ã¯ãªã«é žãŸãã¯ã¡ã¿ã¯ãªã«é žã¢ã«
ãã«éåäœçã®ãããªè圢ææ§éåäœã®æ°Žæ§åæ£
液ãšãã·ãªã³ãŒã³ã®æ°Žæº¶æ¶²ãŸãã¯çåæ°ŽçŽ æº¶æ¶²ã
ãšãã«ã·ãªã³ããŒã氎溶液ãšãè圢ææ§éåäœïŒ
ã·ãªã³ãŒã³ã®ééæ¯ã12ïŒïŒãšïŒïŒïŒã®éã«ãªã
ããã«å«æããçµæç©ã§åŠçããããšã«ãã埮现
ã«åå²ããææã®è¡šé¢ã®è èãé²æ¢ããããšã¯å ¬
ç¥ã§ããã ãšãã«èå³æ·±ãã®ã¯ã氎硬æ§ãã€ã³ããŒãããŒ
ã¹ãšãã建ç©ã®å€è£ ãçŠçã®ãããªè¡šé¢ã®åŠçã«
䜿çšãããåæããªããŒãããŒã¹ãšããçµæç©ã¯
é²æ°Žæ§ã®ä»ã«ä»¥äžã®æ§è³ªã瀺ãããšã§ããã è圢ææ§è¯ãã 玫å€ç·ã«å¯Ÿããå®å®æ§ãè¯ãã ã¢ã«ã«ãªæ§åªäœäžã§å®å®æ§ãè¯ããããªã
ã¡ãã¢ã«ã«ãªæ§ããšãã«PH10ãè¶ ããåªäœäžã§ã
ãã€ããã鹞åãããªãã äŸãã°ãšãã¬ã³æ§ã¢ãã«ã«ãã³é žãŸãã¯ãžã«ã«
ãã³é žããå°ãããã«ã«ããã·éšåãå«ãããªã
ãŒã¯ã¢ã«ã«ãªæ§åªäœäžã§ã®å®å®æ§ãæªãã®ã§é€å€
ãããããšã確ãããããŠããã æ¬çºæè ãã¯ãã¢ã«ã«ãªåŽPHã«å®å®ãªæ°Žæ§åªäœ
ã«å ãŸããåæ£æ¶²ã®åœ¢ã®ã¹ãã¬ã³âã¢ã¯ãªã«é žã¢
ã«ãã«åå ±éåäœã以äžã«è¿°ã¹ãæ§è³ªãæããåŸ
æ¥æè¡ã®ã¢ã¯ãªã«é žã¢ã«ãã«å ±éåäœãããŒã¹ãš
ããçµæç©ã«ååšããéãããå®è³ªçã«å€ãé²æ°Ž
å€ãšçµã¿åãããããšãã§ããããšãèŠåºããã æ¬çºæè ãã¯ã貯èµå®å®æ§ã®ããçµæç©ãèŠåº
ããããã®çµæç©ã¯ã以äžã®æ§è³ªããã€ã åŸæ¥æ³ïŒããŒã«ããšã¢ã¬ã³çïŒã«ãã氎硬æ§
ãã€ã³ããŒãããŒã¹ãšãã建ç©å€è£ ã«çµæç©ã容
æã«é©çšã§ãããã®çµæç©ã¯ä¹Ÿç¥ãããšã¢ã¯ãªã«
æš¹èã®æ¥çæ§ã»çŽ«å€ç·å®å®æ§ãšã·ãªã³ãŒã³æš¹èã®
è¡šé¢æ§è³ªãšã䜵æãã建ç©å€è£ ã®é²æ°Žæ§ãæ¹åã
åŸãèã圢æããã åæ§ã«ãæšæã®è¡šé¢ããã³å éšã®é²æ°ŽãšåŠç
ãå¯èœã«ããã æ¬çºæã®ç®çã§ããçµæç©ã¯ã¢ã¯ãªã«é žã¢ã«ã
ã«å ±éåäœã®æ°Žæ§åæ£æ¶²ãšã¢ã«ã«ãªã¢ã«ãã«ã·ãª
ã³ããŒããšãå«æããŠããããã®çµæç©ã®ç¹åŸŽã¯
以äžã®éãã§ããã æ°Žæ§åæ£æ¶²ã¯å¡©åºæ§PHã«å®å®ãªæ°Žæ§åªäœã«å
ãŸããåæ£æ¶²ã®åœ¢ã®ã¢ã¯ãªã«é žã¢ã«ãã«ãšè³éŠæ
ããã«åéäœã®è圢ææ§å ±éåäœããæãã該è³
éŠæããã«åéäœã¯ãã®å¯Ÿå¿ããåç¬éåäœãã¬
ã©ã¹è»¢ç§»ç¹70ã170âã瀺ããããªåéäœã§ããã ã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã®ååšéã¯ä¹Ÿ
ç¥å ±éåäœ100ïœåœãã¢ã«ãã«ã·ãªã³ããŒã0.05
ã0.17ã¢ã«ã§ãããããã«ããã¢ã«ãã«çžåœãã
å®äœã¯æ¬¡ã®åºã§ããã è³éŠæããã«åéäœã®äŸãšããŠã¯ã¹ãã¬ã³ãšã¡
ãã«ã¹ãã¬ã³ãæããããã 䜿çšã§ããã¢ã¯ãªã«é žã¢ã«ãã«ã¯å¯Ÿå¿ããåç¬
éåäœã®ã¬ã©ã¹è»¢ç§»ç¹ãïŒ10âãâ60âã瀺ãå
éäœã§ããã ã¢ã¯ãªã«é žã¢ã«ãã«ãšããŠã¯ã¢ã«ãã«åºã®ççŽ
æ°ãïŒãïŒã奜ãŸããã¯ïŒãïŒã®ãã®ãæããã
ãã 䜿çšããè³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«
ãã«ã®éã¯ããããããåŸãããå ±éåäœã®ã¬ã©
ã¹è»¢ç§»ç¹ãâïŒâãïŒ25âãšãªãããã«éžã°ã
ãã åéäœã®äœ¿çšéã¯ã³ã¢ãããŒã®æ§è³ªãšææã®å ±
éåäœã®ã¬ã©ã¹è»¢ç§»ç¹ã«ãã€ãŠæ±ºãŸãããããã®
éã¯äŸãã°Bull.An Phys.Soc.ïŒïŒïŒ123ïŒ1956ïŒ
ã«èšèŒã®FOXã®åŒã«ãã容æã«æ±ºå®ãããã ããªãã¡ãã¹ãã¬ã³âã¢ã¯ãªã«é žãšãã«å ±éå
äœã¯ãã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãšãã«ã®æ¯ã26ïŒ74
ã45ïŒ55ã®ãšãã¬ã©ã¹è»¢ç§»ç¹ãïŒâã20âã§ã
ãããŸãã¹ãã¬ã³âã¢ã¯ãªã«é žãããã«å ±éåäœ
ã¯ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãããã«ã®æ¯ã36ïŒ64ã
52ïŒ48ã®ãšãã¬ã©ã¹è»¢ç§»ç¹ãïŒâã20âã§ããã
ããªã¹ãã¬ã³ã¯ã¬ã©ã¹è»¢ç§»ç¹ãïŒ100âã§ããã
ããªé ¢é žãšãã«ãšããªã¢ã¯ãªã«é žãããã«ã®ã¬ã©
ã¹è»¢ç§»ç¹ã¯ãããããâ24âãšâ37âã§ããã 瀺ãããã¬ã©ã¹è»¢ç§»ç¹ã®å€ã¯äŸãã°A.
LambertïŒãããªããŒ10ã319ïŒ1969ïŒãã«èšèŒã®
ãå·®åèµ°æ»ç±éæ³ãã«ãã枬å®ããããã®ã§ããã è³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«ãã«ã®å ±
éåäœã®æ°Žæ§åæ£æ¶²ã¯ã¢ã«ã«ãªåŽPHã«å®å®ãªåªäœ
ã§å ãŸãããããã®ã¢ãããŒãæ°Žæ§ä¹³æ¿æ¶²äžã§é
åããããšã«ããåŸãããã äžèšéååªäœã¯äžèšã¢ãããŒã®ä»ã«æ°Žçžãšã¢ã«
ã«ãªæ§åªäœäžã§å®å®ãªãã®ããéžã°ããçš®ã ã®åŸ
æ¥å ¬ç¥ã®ãšãã«ãžãšã³éåæ·»å å€ïŒè§Šåªãä¹³æ¿å€
çïŒ è§Šåªã®äŸãšããŠã¯ãã¯ã¡ã³ããžã€ãœãããã«ã
ã³ãŒã³ããã©ã¡ã³ã¿ã³çã®ããããã«ãªãã·ãã®
ãããªææ©ããããã«ãªãã·ãé¡ããããªãŠã ã
ã«ãªãŠã ãŸãã¯ã¢ã³ã¢ããŠã®éç¡«é žå¡©ã®ãããªé
ç¡«é žå¡©é¡ãæããããã ä¹³æ¿å€ã®äŸãšããŠã¯ãèèªé žå¡©ãã¢ã«ãã«ã¹ã«
ããšãŒããã¢ã«ãã«ã¹ã«ãããŒããã¢ãªãŒã«ã¹ã«
ããšãŒããã¢ãªãŒã«ã¹ã«ãããŒããã¢ã«ãã«ã¢ãª
ãŒã«ã¹ã«ããšãŒããã¢ã«ãã«ã¢ãªãŒã«ã¹ã«ãããŒ
ããã¹ã«ãã¹ã¯ã·ããŒããã¢ã«ãã«ãã¹ããšãŒã
ã®ã¢ã«ã«ãªéå±å¡©çã®ãããªé°ã€ãªã³ç³»ä¹³æ¿å€ã
ããªãšããã·èèªæã¢ã«ã³ãŒã«ãããªãšããã·ã¢
ã«ãã«ããšããŒã«ãããªãšããã·èèªé žçã®ãã
ãªéã€ãªã³ç³»ä¹³æ¿å€ãæããããã è³éŠæããã«åéäœãšã¢ã¯ãªã«é žã¢ã«ãã«ã®å ±
éåäœã®æ°Žæ§åæ£æ¶²ã¯20ã60ééïŒ ã奜ãŸããã¯
40ã55ééïŒ ã®ç²åŸã0.05ã0.5ÎŒïœã®ä¹Ÿç¥ææå
ãå«æããŠããŠãããã äžèšåæ£æ¶²ã¯åŠçãã¹ãè¡šé¢ã®æ§è³ªã«åŸã€ãŠåž
éããŠãããã æ¬çºæã®é²æ°Žçµæç©ã«äœ¿çšã§ãããã¢ã«ã«ãªã¢
ã«ãã«ã·ãªã³ããŒãã¯C1âC3ã¢ã«ãã«åºãæã
ããã®ã§ããã ãã®ã¢ã«ãã«ã·ãªã³ããŒãã®å¥œé©ãªäœ¿çšéã¯å ±
éåäœ100ïœåœã0.065ã0.1ã¢ã«ã§ããã 奜é©ãªã¢ã«ãã«ã·ãªã³ããŒãã¯ä»¥äžã®ãã®ã§ã
ãã 也ç¥å ±éåäœ100éééšåœã也ç¥ã¡ãã«ã·ãª
ã³ããŒã4.8ã16.3éééšã奜ãŸããã¯6.4ã9.8é
ééšã®å²åã®ãœãžãŠã ã¡ãã«ã·ãªã³ããŒãã 也ç¥å ±éåäœ100éééšåœã也ç¥ã¡ãã«ã·ãª
ã³ããŒã5.6ã19éééšã奜ãŸããã¯7.44ã11.4é
ééšã®å²åã®ããã¿ã³ãŠã ã¡ãã«ã·ãªã³ããŒãã æ¬çºæã®é²æ°Žçµæç©ã¯åæ§ã«è²çŽ ãæ©æ¢°çæ¹æ
ã«åŒç¶ããŠæ°æ³¡ã圢æãããããšãããã®ãé²æ¢
ããããã®æ¶æ³¡å€ïŒãžã¡ãã«ããªã·ãããµã³åïŒã
ããã³ããšãã«ãè³éŠæããã«åéäœãšã¢ã¯ãªã«
é žã¢ã«ãã«ã®å ±éåäœã®è圢æã®æäœæž©åºŠãå¿ èŠ
ã«å¿ãäœäžãããããã®é鹞åæ§æ¥çå€ãäŸãã°
ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãšãŒãã«ããšãã¬ã³ã°
ãªã³ãŒã«ããšãã«ãšãŒãã«ããããã¬ã³ã°ãªã³ãŒ
ã«ããšãã«ãšãŒãã«ããžãããã¬ã³ã°ãªã³ãŒã«ã
ãšãã«ãšãŒãã«ãŸãã¯è³éŠæååç©ã®å«éã®å°ãª
ãããã¯ã€ãã»ã¹ããªãããå補åã®ãããªçš®ã
ã®æ·»å ç©ãå«æããŠããŠãããããããã®æ¥çå€
ã®äœ¿çšéã¯è©²å ±éåäœåæ£æ¶²100éééšåœãïŒã
ïŒéééšçšåºŠã§ããã äžè¿°ã®ããã«ãæ¬çºæã®é²æ°Žå€çµæç©ã¯æšæã®
é²æ°Žã«ããé©åããŠããã ãæšæãã«ã¯ãããªå±ãèæ¿ãã¯ãåããæ¿ã
ç³ä»èæ¿æ§é äœããã¢ã€ããŒããŒããããŒãã¯ã«
ããŒããã»ã«ããŒã¹æ§ææãããŒã¹ãšããçš®ã ã®
è€å補åã®ãããªæšè³ªè£œåã®ç·äœãããã ç¹ã«å¥œé©ãªé©çšäŸãšããŠã¯ãæ¬çºæã®é²æ°Žçµæ
ç©ã¯çµæç©ã®å šééã®ïŒééïŒ è¿ã®æ®ºã«ãå€ãã
ã³ïŒãŸãã¯æ®ºè«å€åã®æšæã®ä¿è·å€ãããã«å«æ
ããŠããŠãããã 殺ã«ãå€ã¯ãã®ãé¡ãã«ãé¡ããã³è æèã®æ»
æã«å¯ŸåŠããããã«æšæãåŠçããã®ã«æ £çšãã
ãŠãããã®ããéžã°ããã殺è«å€ã®äŸãšããŠã¯ã
ããšããŒã«ã®ããã²ã³èªå°äœãäŸãã°ããã©ã¯ã
ãããšããŒã«ããã³ãã³ã¿ã¯ããããšããŒã«ãé
å±å¡©ãšãã«é ããã³ã¬ã³ãã³ãã«ããã¯ãã ãäº
éã®å¡©ãäŸãã°ããã¿ã³é žããªã¯ã¿ã³é žããã³ã
ããã³é žã®ãããªã«ã«ãã³é žã®èªå°äœãäŸãã°ã
ã¹ããªããã«é«é žåç©ãããªããã«é«ããåç©ã
ããªããã«é«ãªã³é žå¡©ãããªããã«é«å®æ¯éŠé žå¡©
ãŸãã¯ããªããã«é«é ¢é žå¡©ã®ãããªææ©é«é¯äœã
ã¡ãã¬ã³ãã¹ããªã·ã¢ããŒããã¡ã«ã«ãããã³ãŸ
ãã¢ãŸãŒã«ããžã¯ããã«ã¢ããïŒïŒ®âãžã¯ããã
ã«ãªãã¡ãã«ããªâNâ²ïŒNâ²âãžã¡ãã«ââã
ãšãã«ã¹ã«ãã¢ããïŒãæããããã ãããã¯åŠççšçµæç©ã®ééã®ïŒééïŒ ãŸã§å
åšããŠããŠãããããã®éã¯ãã¡ãã䜿çšãã殺
ã«ãå€ã®æŽ»æ§ã«ãã€ãŠæ±ºãŸãã 殺è«å€ã¯æè«ã«ããæšæé£å®³ãé²æ¢ããããã«
æšæãåŠçããã®ã«æ £çšããããã®ããéžã°ã
ããäŸãã°DDTïŒãžã¯ãããžããšãã«ããªã¯ãã
ãšã¿ã³ïŒãã¡ããã·ã¯ãã«ïŒãžã¡ããã·ãžããšã
ã«ããªã¯ãããšã¿ã³ããªã³ãã³ïŒãããµã¯ããã·
ã¯ããããµã³ã®ç°æ§äœïŒãã¯ãã«ãã³ïŒãªã¯ã¿ã¯
ãããããµãããã¡ã¿ãã€ã³ãã³ïŒãã¢ã«ããªã³
ïŒãšã³ããããµã¯ãããããµããããžã¡ã¿ããã
ã¿ãªã³ããããµããšã³ã®ãããªææ©ããã²ã³åå
ç©é¡ãäŸãã°ãžãšããªã³ïŒïŒ¯ïŒïŒ¯ïŒOâ²ïŒOâ²âã
ãã©ãšãã«ïŒ³ïŒSâ²âã¡ãã¬ã³ãžããªãã¹ããšãŒ
ãïŒããã©ããªã³ïŒïŒ¯ïŒïŒ¯âãžãšãã«ãã©ããã
ããšãã«ããªãã¹ããšãŒãïŒãããµãã³ïŒïŒ¯ïŒïŒ¯
âãžãšãã«ãžããªãã¹ããªã«ã¡ãã«âïŒã¯ããâ
ïŒãã³ãŸããµãŸãã³ïŒã®ãããªææ©ãªã³ååç©
é¡ãäŸãã°ã»ãã³ïŒããããã«ïŒ®âã¡ãã«ã«ãŒã
ã¡ãŒãïŒãã«ã«ããã©ã³ïŒãžã¡ãã«ãžããããã³
ãŸãã©ã㫠âã¡ãã«ã«ãŒãã¡ãŒãïŒã®ãããª
ã«ãŒãã¡ãŒããäŸãã°ãã«ã¡ã¹ãªã³ïŒÎ±âã·ã¢ã
ããšããã·ãã³ãžã« ãžããã¢ããã« ãžã¡ã
ã«ã·ã¯ããããã³ ã«ãŒããã·ã¬ãŒãïŒããã«ã¡
ã¹ãªã³ïŒããšããã·ãã³ãžã« ã·ã¹âãã©ã³ã¹
ãžã¡ãã« ãžã¯ããããã« ã·ã¯ããããã³ ã«
ãŒããã·ãŒããããšã³ãã¬ã¬ãŒãïŒÎ±âã·ã¢ã
ããšããã·ãã³ãžã« ã¯ããããšãã« ã¡ãã«ã
ãã«ããã¬ãŒãïŒã®ãããªåæãã¬ã¹ãªãã€ãé¡
ãæããããã ãããã¯åŠççšçµæç©ã®ééã®ïŒééïŒ ãŸã§å
åšããŠããŠãããããã®éã¯ãã¡ã¡ãã䜿çšãã
殺è«å€ã®æŽ»æ§ã«ãã€ãŠæ±ºãŸãã ç¹ã«éèŠãªæå¹æåã¯æ¬¡ã®çµã¿åããïŒæå¹æ
å100éééšåœãïŒããæãã ããã©ã¯ããããšããŒã«ããã³ïŒãŸãã¯ãã³
ã¿ã¯ããããšããŒã«ããã³ïŒãŸãã¯ææ©é«é¯äœã«
å Žåã«ãã€ãŠãžã¯ãããã«ã¢ãããæ··åãããã®
ããæã殺ã«ãå€70ã98éééš ãªã³ãã³ãã
ã³ïŒãŸãã¯ããµãã³ããã³ïŒãŸãã¯ã»ãã³ãã
ã³ïŒãŸãã¯ãã«ã¡ã¹ãªã³ããã³ïŒãŸãã¯ããšã³ã
ã¬ã¬ãŒãããæã殺è«å€30ãïŒéééšã æ¬çºæã®å Žåã«ãã€ãŠæ®ºã«ãå€ããã³ïŒãŸãã¯
殺è«å€ãæ·»å ããé²æ°Žçµæç©ã®ä¹Ÿç¥ææåå«æé
ã¯é²æ°Žãã¹ãè¡šé¢ã®æ§è³ªã«ããïŒã50ééïŒ ã奜
ãŸããã¯ïŒã25ïŒ ã§ããã æ¬çºæã¯ãŸãäžèšé²æ°Žçµæç©ã®è£œé æ³ãæäŸã
ãã ãã®æ¹æ³ã¯äžèšæ¯çã«åŸããçš®ã ã®æ§ææåã
ãã³å Žåã«ãã€ãŠçš®ã ã®è£ å ¥ç©ããã³æ·»å å€ãæ··
åããããšããæãã ã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã¯å¥œãŸããã¯ä¹Ÿ
ç¥ææåã50ééïŒ ãŸã§å«æãåŸã氎溶液ã®åœ¢ã§
å°å ¥ãããã å Žåã«ãã€ãŠäœ¿çšããã殺ã«ãå€ãšæ®ºè«å€ã¯å ±
éåäœãšã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã®æ°Žæ§å
æ£æ¶²ã«ããæ§æãããæ°Žæ§åªäœã«å ãŸããã圢
ã§ããããã液ç¶ã®å Žåã¯ãã®ãŸãŸããããã¯å¥œ
ãŸããã¯ææ©æº¶åªãŸãã¯å³æ©æº¶åªæ··åç©ã«æº¶è§£ã
ãŠå°å ¥ãããã 䜿çšãåŸã溶åªã®ãã¡ãäŸãã°ã¯ãããã³ãŒ
ã³ããžã¯ãããã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãŸã
ã¯100âã300âã®éã®èžçç»åã§ããç¯æ²¹ã®ãã
ãªç³æ²¹ã®èžçã«ããçŽæ¥åŸãããè³éŠæçåæ°ŽçŽ
æ··åç©ã®ãããªæ¶²ç¶è³éŠæçåæ°ŽçŽ é¡ãäŸãã°ã·
ã¯ããããµããŒã«ã®ãããªã¢ãã¢ã«ã³ãŒã«é¡ãäŸ
ãã°ãšãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãããã¬ã³ã°ãªã³ãŒ
ã«ãããã·ã¬ã³ã°ãªã³ãŒã«ããžã°ã©ã€ã ãããã
ã·ãšã¿ããŒã«ã®ãããªã°ãªã³ãŒã«é¡ãããªãªãŒã«
é¡ãŸãã¯ãããã®ã¢ã«ã«ããŒã«ãšã®ãšãŒãã«é¡ã
äŸãã°ãšãã«ã¢ãã«ã±ãã³ããžã€ãœããã«ã±ãã³
ã®ãããªèèªæã±ãã³é¡ãäŸãã°ãã¿ã«é žããã«
ãŸãã¯ãã¿ã«é žããã«ããããã¯ã³ãã¯é žãã¢ãž
ãã³é žãã·ãŠãŠé žãŸãã¯ããã³é žã®ãžã¡ãã«ãšã¹
ãã«ãŸãã¯ãžãšãã«ãšã¹ãã«ã®ãããªãšã¹ãã«
é¡ãäŸãã°ãžã¡ãã«ãã«ã ã¢ãããŸãã¯ãžã¡ãã«
ã¢ã»ã¿ããã®ãããªã¢ããé¡ãæããããããã
ãã¯åäžã®æº¶åªãšããŠããããã¯äºçš®é¡ä»¥äžã®æº¶
åªã®æ··åç©ãšããŠã䜿çšã§ããã æ°Žæ§åæ£æ¶²ãšã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã
ãæãæ°Žæ§åªäœã«å ãŸããæå¹æåã®ãšãã«éèŠ
ãªäœ¿çšæ³ã¯æ°Žã«ä¹³æ¿ãåŸãäžèšçµæã®æ¿çž®æ¶²ãä»
ããŠè©²æå¹æåãå°å ¥ããããšããæãã æå¹æåã¯æ®ºã«ãå€ããã³ïŒãŸãã¯æ®ºè«å€ã
ãæãã 液ç¶æº¶è§£åªäœã¯æå¹æåã«å¯Ÿããå°ãªããšã
äžçš®ã®ææ©æº¶åªãé°ã€ãªã³ç³»çé¢æŽ»æ§å€ããã³å Ž
åã«ãã€ãŠå°ãªããšãäžçš®ã®æ²¹ããã³ïŒãŸãã¯å°
ãªããšãäžçš®ã®åºçå€ããæãã ç¹ã«å¥œé©ãªæ¿çž®æ¶²ã¯ä»åœç¹èš±åºé¡å ¬é第
2498419å·ã«èšèŒãããŠãããã®ã§ãããããã¯
æ¿çž®æ¶²100éééšåœãäžèšã®ãã®ãå«æããã æå¹æå15ã40éééš æå¹æåã®æº¶åª30ã75éééš æ²¹ããã³ïŒãŸãã¯åºçå€ïŒã20éééš é°ã€ãªã³ç³»çé¢æŽ»æ§å€ïŒã25éééšã äžèšæ¿çž®æ¶²ã®çµæã«å«ãŸããçé¢æŽ»æ§å€ã¯äžèš
ã®ãã®ããéžã°ããã ïœ åŒïŒïŒã®ç¡«é žãšã¹ã㫠âïŒOCH2CH2ïŒoâOSO3M ïŒïŒ åŒäžãã¯é£œåãããã¯äžé£œåã®ïŒåãŸãã¯
ïŒå以äžã®ãããååãå«ãããšã®ããèèªæ
ïŒçŽéãŸãã¯åæïŒãèç°æãŸãã¯è³éŠæç±æ¥ã®
åºã瀺ããïœã¯çé¢æŽ»æ§å€ã®HLBã®å€ã10ã
16ã«çžåœãããããªå€ã«åºå®ãããæ°å€ã瀺
ããïŒã¯çé¢æŽ»æ§å€ãä¹³æ¿ãã¹ãæ¿çž®æ¶²ãšæ°Žãš
ã«æº¶è§£ããããã«éžã°ããç¡æ©ãŸãã¯ææ©æ®åº
ã瀺ãã ïœ åŒïŒïŒã®ææ©ãªã³ãšã¹ãã« ïŒåŒäžãããã³ïœã¯åŒïŒïŒãšåãæå³ãæ
ã€ãR1ã¯M1ãŸãã¯ïŒ²âïŒOCH2CH2ïŒoâã瀺
ããR1ãšïŒ²âïŒOCH2CH2ïŒoâãšåäžã§ãç°ãª
ã€ãŠããŠããããM1ã¯æ°ŽçŽ ååãŸãã¯åŒïŒïŒ
ã®ïŒãšåãæå³ã瀺ããäºã€ã®M1ïŒR1ïŒM1ã®
ãšãïŒã¯åäžã§ãç°ãªã€ãŠããŠããããïŒ HLBïŒèŠªæ°Žæ§éšïŒèŠªæ²¹æ§éšãã©ã³ã¹ïŒã¯ä¹³æ¿å€
ã®åéã§åšç¥ã®å€§ããã§ããã詳现ã«ã¯ãKIRK
âOTHMER Encyclopedia of chemical
Technology第ïŒç第ïŒå·»ç¬¬910é â第915é
ïŒ1979幎ïŒåç §ã 奜ãŸããã¯äžèšååç©ã¯åŒïŒïŒããã³ïŒïŒ
ã«ãããŠããïŒåãŸãã¯ïŒå以äžã®ççŽ æ°ïŒã
ïŒã®ã¢ã«ã³ãã·åºãŸãã¯ããšãã«åºã§çœ®æãããŠ
ããããšã®ããççŽ æ°ïŒã20ã®çŽéãŸãã¯åæç¶
ã¢ã«ãã«åºãã¢ã«ãã«åºã®å®çŸ©ãäžèšã®éãã§ã
ãã¢ã«ãã«ã«ã«ããã«åºãäžèšã¢ã«ãã«åºã«å¯Ÿã
ãŠç€ºãããããã«çœ®æãããŠããããšã®ããççŽ
æ°ïŒãïŒã®ã·ã¯ãã¢ã«ãã«åºããããã¯ã¢ã«ãã«
éšåãçŽéãŸãã¯åæç¶ã§ççŽ æ°ïŒã20ã§ããã¢
ã«ãã«ããšãã«åºã瀺ããïŒïŒåŒïŒïŒãã¢ã³ã¢
ããŠã åºãŸãã¯ã¢ã«ã«ãªéå±ååã瀺ããM1ã
æ°ŽçŽ ååãã¢ã³ã¢ããŠã åºãŸãã¯ã¢ã«ã«ãªéå±å
åã瀺ããã®ããéžã°ããã äžèšã¢ã³ã¢ããŠã åºã«ã¯åŒïŒ®ïŒR2R3R4R5ïŒïŒåŒ
äžãR2ïŒR3ïŒR4ããã³R5ããåäžãŸãã¯çžç°ãª
ã€ãŠãæ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ããããã·ã¢
ã«ãã«åºã瀺ããïŒåã®ã¢ã«ãã«åºãäžç·ã«é žçŽ
ååãå«ãããšã®ããäºäŸ¡ã®åºã圢æããŠãã
ããïŒã®ååç©ãå«ãŸãããã¢ã³ã¢ããŠã åºã®å š
ççŽ æ°ã¯ïŒä»¥äžã§ããã äžèšå¥œé©ãªä¹³æ¿å€ã«ãããŠãåŒïŒïŒããã³
ïŒïŒã«ãããŠããççŽ æ°ïŒã20ã®çŽéã¢ã«ã
ã«åºããŸãã¯ã¢ã«ãã«éšåãççŽ æ°ïŒã20ã®çŽé
ã¢ã«ãã«ã§ããã¢ã«ãã«ã«ã«ããã«åºã瀺ããïŒ
ïŒåŒïŒïŒïŒãã¢ã³ã¢ããŠã åºãŸãã¯ãããªãŠã å
åã瀺ããM1ïŒåŒïŒïŒïŒãæ°ŽçŽ ååãã¢ã³ã¢ã
ãŠã åºãŸãã¯ãããªãŠã ååã瀺ãçé¢æŽ»æ§å€ã
ãšãã«å¥œé©ã§ããã 以äžã®ååç©ãäŸç€ºãããã ïœ ç¡«é žå¡© ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OSO3NH4 ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OSO3Na ã» CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒoâ
OSO3NH4 ã» CH3âïŒCH2ïŒ12âCOâïŒOCH2CH2ïŒoâ
OSO3NH4 äžåŒäžãïœã¯ïŒã10ã§ããã ïœ ãªã³é žå¡© ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
OPO3ïŒM1ïŒ2 ã» CH3âïŒCH2ïŒ10âCH2âïŒOCH2CH2ïŒoâ
ã2PO2M1 ã» CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒoâ
OPO3ïŒM1ïŒ2 ã» ãCH3âïŒCH2ïŒ11âCH2âïŒOCH2ïŒoâã
2PO2M1 äžåŒäžãïœã¯ïŒã10ã§ãããçš®ã M1ã¯ãåäž
ãŸãã¯çžç°ãªã€ãŠãïŒNH4ïŒNH2ïŒC2H4OHïŒïŒ
NHïŒC2H4OHïŒ3ãŸãã¯Naã瀺ãã æå¹æåã®æº¶åªãšããŠã¯åèšæº¶åªã䜿çšã§ã
ãã 溶解åªäœã補é ããã®ã«äœ¿çšãåŸãæ²¹ãããšã
ã«ãäŸãã°äºéº»ä»æ²¹ã倧è±æ²¹ãæŸæ ¹æ²¹ãã¿ããŒ
æ²¹ããã¬ãããŒã«é¡æ··åç©ã®ãããªæ€ç©æ§æ²¹é¡ã
äŸãã°ç¯æ²¹ãšãã©ãã€ã³ãšã®éã®ç³æ²¹ã®èžçç»å
ã§ãããã·ã³æ²¹ã®ãããªé±æ²¹é¡ãæããããã æšæã«åŠçå€ãåºçãããã®ã«é©ããæ¥çå€ã®
äŸãšããŠã¯ãã¢ããã³ãã«ã«ããã·ã¡ãã«ã»ã«ã
ãŒã¹ãã³ãããªããŠã èãŸãã¯ã³ãããªããŠã è
ãšã¹ãã«ãã¢ã©ãã¢ãŽã ãããªããã«ã¢ã«ã³ãŒ
ã«ãããã³é žãã°ãªã»ããã¿ã«é žæš¹èãã€ã³ãã³
ã«å¯ãç³æ²¹ç»åã®ã¯ã©ããã³ã°ã«ãã圢æããã
èèªæããã³ïŒãŸãã¯è³éŠæäžé£œåçåæ°ŽçŽ ã®äœ
ååééåäœããæãçåæ°ŽçŽ ã®äžèšæš¹èãæã
ãããã æ¬çºæã¯ããŸããäžèšçµæç©ã氎硬æ§ãã€ã³ã
補ã®å»ºç©å€è£ ãçŠãæšæçã®åã®çš®ã ã®è¡šé¢ã«å¯Ÿ
ããŠé²æ°ŽåŠçã«äœ¿çšããæ¹æ³ãæäŸããã 建ç©å€è£ ãšçŠã®åŠçã¯äžèšçµæç©ããã®ãŸãŸã
ããã¯æ°Žã§åžéããåŸãå¡è£ ããŒã«ãŸãã¯ãšã¢ã¬
ã³ã䜿çšããŠåŽé§ããããšã«ãããšãã«ç°¡åã«å®
æœã§ããã è¯å¥œãªé²æ°Žã»ä¿è·ãåŸãããã«äžèšè¡šé¢ã«çµæ
ç©ãå¡åžããéã¯äžè¬ã«20ã80ïœïŒm2çšåºŠã§ã
ããåŠçãããæ¯æäœã¯éåžžã«æ¥éã«é©çšåŸïŒæ
éçšåºŠã§é²æ°Žæ§ãç²åŸããã å Žåã«ãã€ãŠæ®ºã«ãå€ããã³ïŒãŸãã¯æ®ºè«å€æ
å¹æåãå«æããé²æ°Žæ§çµæç©ãæšæã«é©çšãã
æ¹æ³ã¯æšæããã®èªå°ç©ã®åŠçã«äœ¿çšãããæ £çš
ã®æ¹æ³ãäŸãã°æµžæŒ¬ããã±å¡ããç空äžããã³ïŒ
ãŸãã¯å å§äžãªãŒãã¯ã¬ãŒãå ã§ã®å«æµžæ³ãªã©ã
䜿çšã§ãããç¹ã«å¥œé©ãªæ¹æ³ã¯äºéç空æ³ãšãã
ããæ¹æ³ã§ããã æšæãåŠçããéã®äžèšçµæç©ã®äœ¿çšéã¯ã©ã
ãªå«æµžæ³ãéžã¶ãã«ãã€ãŠæ±ºãŸãã ããªãã¡ãå«æµžã浞挬ã«ãã€ãŠå®æœãããå Žå
ã¯ãåŠçè¡šé¢m2åœãã®å šçµæç©ïœæ°ã§è¡šãããã
çµæç©äœ¿çšéã¯50ã300ïœïŒm2çšåºŠã§ãããçµæ
ç©ãè¡šé¢ã«ãã±å¡ãããå Žåã¯20ã80ïœïŒm2çšåºŠ
ã®çµæç©ã®éã§ååã§ãããå«æµžãäºéç空äžãª
ãŒãã¯ã¬ãŒãå ã§å®æœãããå Žåã¯ãïŒã40KgïŒ
m2çšåºŠã®çµæç©ã®éã奜é©ã§ããã 以äžã«å®æœäŸãåç §ããŠæ¬çºæãããã«è©³çŽ°ã«
説æããããæ¬çºæã¯ãããã®å®æœäŸã«éå®ãã
ãªãã å®æœäŸ ïŒãïŒ é²æ°Žçµæç©ã®èª¿è£œ 以äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ã®ééæ¯ïŒçŽ
50ïŒ50 㻠也ç¥æœåºåå«æéïŒ çŽ50ïŒ ã» ä¹³æ¿å€ïŒ ã¢ã«ãã«ã¹ã«ãã³é žãããªãŠã ã
ãã³ã¢ã«ãã«ããšããŒã«ãªãã·ãšãã¬ã³ 㻠觊åªïŒ éç¡«é žã¢ã³ã¢ããŠã ã» ç²åŸïŒ 0.05ã0.40ÎŒïœ ã» è圢æ§æäœæž©åºŠïŒ 16â ã» ç²åºŠïŒ 50mïŒPaïŒïŒ³ïŒãã«ãã¯ãã€ãŒã«ã
ç²åºŠèšã䜿çšã20âã«ãããŠ50tïŒåã§æž¬å®ïŒ
ãæããã¹ãã¬ã³âã¢ã¯ãªã«é žããã«å ±éåäœ
ã®æ°Žæ§åæ£æ¶²100éééšãšãè¡šã«ç€ºãéééš
æ°ã®ä»¥äžã®æ§è³ªïŒ 㻠也ç¥æœåºåïŒ çŽ47ïŒ ã» å¯åºŠïŒ20âïŒïŒ 1.34 ã» ã¢ã«ã«ãªæ»Žå®éïŒ 18ïŒ ïŒK2OïŒ ãæããããã¿ã·ãŠã ã»ã¡ãã«ã·ãªã³ããŒãã®æ°Ž
溶液ãšãæ··åããã ãã®ããã«ããŠåŸãããæ··åç©ã®ç²åºŠã¯è¡šã«
瀺ãïŒãã«ãã¯ãã€ãŒã«ãç²åºŠèšã䜿çšããŠ20â
ã«ãããŠ50tïŒåã§æž¬å®ïŒã 貯èµå®å®æ§ åšå²æž©åºŠã§ïŒå¹Žé貯èµããåŸãäžèšã®ããã«ã
ãŠåŸãããçµæç©ã®ç²åºŠã®å¢å ã¯èªããããªãã
ã¢ã«ã«ãªæ§åªäœäžã®å®å®æ§ å®æœäŸïŒã«åŸã調補ãããçµæç©ãïŒã«é40â
ã«ä¿ã€ãã 以äžã®ããšã確èªãããã ç²åºŠã®å¢å ã¯ãªãã 鹞åãããã¢ã¯ãªã«é žããã«ã®éã¯ãã¢ã¯ãª
ã«é žããã«ã®ééã«å¯ŸããééïŒ ã§è¡šãããšã
0.1ïŒ æªæºïŒæž¬å®ã¯éé¢ãã¿ããŒã«éã«ãããïŒã§
ããã èã®é²æ°Žæ§ ãã®æ§è³ªã¯è©Šéšãµã³ãã«ïŒã¬ã©ã¹ïŒã®è¡šé¢çœ®ã
ãã氎滎ã®æ¥è§Šè§ÎžããJ.BIKERMANïŒ
âPhysical Surfacesâã第251é ã¢ã«ãããã¯ãã¬
ã¹ç€ŸããŠãŒãšãŒã¯ïŒ1970幎ïŒã«èšèŒã®æ¹æ³ã«åŸã€
ãŠåºŠïŒãïŒã§æž¬å®ããããšã«ãã€ãŠæ±ºå®ãããã ãã®æž¬å®çµæã¯è¡šã«ç€ºãã å®æœäŸ ïŒ ã¹ãã¬ã³âã¢ã¯ãªã«é žããã«å ±éåäœã®æ°Žæ§å
æ£æ¶²ã®ä»£ããã«ä»¥äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žãšãã«ã®ééæ¯ïŒ41ïŒ
59 㻠也ç¥æœåºåïŒ çŽ50ïŒ ã» è圢ææäœæž©åºŠïŒ çŽ16â ãæããã¹ãã¬ã³âã¢ã¯ãªã«é žãšãã«ã䜿çšãã
以å€ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©ã調補ããã ãã®çµæç©ã®æ§è³ªã¯è¡šã«ç€ºãã å®æœäŸ ïŒâ11ïŒæ¯èŒäŸïŒ 以äžã®çµæã®çµæç©ã調補ããã ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ïŒã¢ã¯ãªã«é žã®
ééæ¯ãçŽ47ïŒ49ïŒïŒã也ç¥æœåºåçŽ50ïŒ ããã³
è圢ææäœæž©åºŠçŽ16âã®ã¹ãã¬ã³âã¢ã¯ãªã«é žã
ãã«âã¢ã¯ãªã«é žäžå å ±éåäœã®æ°Žæ§åæ£æ¶²100
éééšãããã³ è¡šã«ç€ºãéééšã®å®æœäŸïŒãïŒã«èšèŒã®ã
ãã¿ã·ãŠã ã»ã¡ãã«ã·ãªã³ããŒãã®æ°Žæº¶æ¶²ã ãã®çµæç©ã®æ§è³ªã¯è¡šã«ç€ºãããã®ãããªçµ
æç©ã¯ç²åºŠã倧ãéãããã䜿çšãé£ããé©çšç
究ã«ã䜿çšããããšããã§ããªãããšã確ããã
ããã
ãè¡šã
ãè¡šã
ïŒïŒ è£
眮ã«ãã枬å®å¯èœãªç²åºŠãè¶
ãã
ãåŸæ¥æ³ã«ããå±éäžèœã®è£œåã
å®æœäŸ 12ããã³13 é²æ°Žçµæç©ã®èª¿è£œ 以äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ã®ééæ¯ïŒçŽ
50ïŒ50 㻠也ç¥æœåºåå«æéïŒ çŽ50ïŒ ã» ä¹³æ¿å€ïŒã¢ã«ãã«ã¹ã«ãã³é žãããªãŠã ãã
ã³ã¢ã«ãã«ããšããŒã«ãªãã·ãšãã¬ã³ 㻠觊åªïŒ éç¡«é žã¢ã³ã¢ããŠã ã» ç²åŸïŒ 0.05ã0.40ÎŒïœ ã» è圢ææäœæž©åºŠïŒ 16â ã» ç²åºŠïŒ 50m.Pa.SïŒãã«ãã¯ãã€ãŒã«ãç²åºŠ
èšã䜿çšããŠ20âã«ãããŠ50tïŒå枬å®ïŒãæ
ããã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«å ±éåäœã®æ°Ž
æ§åæ£æ¶²100éééš ä»¥äžã®æ§è³ªïŒ 㻠也ç¥æœåºåå«æéïŒ çŽ47ïŒ ã» å¯åºŠïŒ20âïŒïŒ 1.34 ã» ã¢ã«ã«ãªæ»Žå®éïŒ 18ïŒ ïŒK2OïŒ ãæããããã¿ã·ãŠã ïŒã¡ãã«ã·ãªã³ããŒãã®æ°Ž
溶液10éééšã ããã«ãžã°ãªã³ãŒã«3.5éééšã ããŒãã»ãã©ã³ã¯ç€Ÿã«ããåžè²©ãããŠãã
RHODOSIL416ãæ¶æ³¡å€ãšããŠ0.15éééšããã
ã³ å®æœäŸ12ã«ãããŠã¯20ïŒ ãå®æœäŸ13ã«ãããŠã¯
ïŒïŒ ã®ä¹Ÿç¥æœåºåã®éãåŸãã®ã«ååãªéã®æ°Žã
æ··åããã é²æ°Žæ§è©Šéš 40Ã15ÃïŒmmãªãã60Ã30ÃïŒmmã®å¯žæ³ã®æ æ
ãã©ãã¯ïŒåµ©å¯åºŠ0.15ã0.2ã®å¯ã§ãªããã®ïŒã
ãã«ã NFÃ40â500ïŒç¬¬26é ïŒïŒïŒïŒïŒæ®µïŒã«åŸ
ã€ãŠèŠå¶ãããåšèŸºå«æµžè©Šéšã«äŸããã 20容ãªãŒãã¯ã¬ãŒãããã©ãã¯1500ïœããã³
äžèšã«ãã調補ãããé²æ°Žçµæç©ã䜿çšããã ïœ å«æµžãµã€ã¯ã« å«æµžãµã€ã¯ã«ã¯ä»¥äžã®éãã§ããã ååçç©ºïŒ 650mbã§10åé å«æµžïŒ 10åé æçµçç©ºïŒ 650mbã§45åé æš100ïœã«åžåãããçµæç©ã®éã¯è¡šã«ç€ºãã ïœ æ°Žã®åå蟌ã¿ãµã€ã¯ã« ãã®ããã«åŠçãããã©ãã¯ãïŒæé颚也ãã
次ãã§ïŒæéæ°Žã«æµžæŒ¬ããã ãã©ãã¯ãæ°Žåãããééå€åã«ããæ°Žã®åå
ã蟌ã¿ã枬å®ãããåŸãããçµæã¯è¡šã«ç€ºãã ïœ æŽãèœãæå æ°Žã®ååã蟌ã¿ãµã€ã¯ã«åŸãã©ãã¯ãïŒé±é也
ç¥ãã次ãã§ïŒæéæ°Žã«æµžæŒ¬ããã ãã©ãã¯ã®æ°Žåããããæ°Žã®ååã蟌ã¿ã枬å®
ããã åŸãããçµæã¯è¡šã«ç€ºãã è¡šã«ã¯ããŸããæ¯èŒã®ããã«ç¡åŠçãã©ãã¯
ããã³ããŒãã»ãã©ã³ã¯ç€Ÿã«ããåžè²©ãããŠãã
ã·ãªã³ãŒã³æ²¹47V100ã®10ïŒ ãã¯ã€ãã¹ããªãã
溶液ã§åŠçãããã©ãã¯ã䜿çšããŠåŸãããçµæ
ããããã瀺ãã äžèšè©Šéšã®çµæã次ã®ããšã確ãããããã ã·ãªã³ãŒã³æ²¹ã§åŠçãããã©ãã¯ã¯ãµã€ã¯ã«ïœ
ã§æŽãèœããå°ãªãã æ¬çºæã®çµæç©ã§åŠçãããã©ãã¯ã¯ãµã€ã¯ã«
ïœã«ãããŠæŽãèœãããªãã€ãã ãã§ãªããé²æ°Ž
æ§ãããã«æ¹åãããã äžèšè©Šéšã®å¶éå ã§é²æ°Žçµæç©ã®ä¹Ÿç¥æœåºåã®
æ¿åºŠã®æ°Žã®ååã蟌ã¿ã«å¯Ÿãã圱é¿ã¯é¡èã§ã¯ãª
ãã å®æœäŸ 14 é²æ°Žçµæç©ã10éééšã®ä»£ããã«15éééšäœ¿çš
ããŠå®æœäŸ13ã«èšèŒã®é²æ°Žæ§è©Šéšãç¹°ãè¿ããã
ãã ãããã®é²æ°Žçµæç©ã¯ä¹Ÿç¥æœåºåå«éãïŒïŒ
ãšãªãããã«ååéã®æ°Žãå«æããŠããã é²æ°Žæ§è©Šéšã®çµæã¯è¡šã«ç€ºãã åŸãããé²æ°Žæ§ã¯å®æœäŸïŒã§åŸããããã®ãã
ãæ¹åãããŠããã å®æœäŸ 15 é²æ°Žçµæç©ã®èª¿è£œ ã» å®æœäŸ12ããã³13ã§äœ¿çšãããã¹ãã¬ã³âã¢
ã¯ãªã«é žããã«ã©ããã¯ã¹100éééš ã» å®æœäŸ12ããã³13ã§äœ¿çšãããã¡ãã«ã·ãªã³
ããŒã溶液10éééš ã» ããã«ãžã°ãªã³ãŒã«3.5éééšãããã³ ã» RHODOSIL 416 0.15éééš ãã調補ããã也ç¥æœåºåå«æé48.5ïŒ ã®é²æ°Žå€
åæ£æ¶²8.25ééïŒ ãšã ã» ãã³ã¿ã¯ããããšããŒã«27.3éééšã ã» ãªã³ãã³4.8éééš ã» ãªã«ããžã¯ãããã³ãŒã³22.7éééš ã» ããã·ã¬ã³ã°ãªã³ãŒã«25.8éééš ã» DERTOLINEPãšããå称ã§ããªãã»ã¬ãž
ããŒã¯ã»ãšã»ãã«ãããŒã¯ç€Ÿããåžè²©ãããŠã
ãã³ãããªããŠã èãšãã³ã¿ãšãªã¹ãªããŒã«ã®
ãšã¹ãã«8.1éééšãããã³ ã» æ¬¡åŒ CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒ3â
OSO3NH4 ã®ä¹³æ¿å€11.3éééš ãã調補ãããä¹³æ¿å¯èœæ¿çž®ç©ïŒééïŒ ãšã ã» é²æ°Žå€åæ£æ¶²ã®ä¹Ÿç¥æœåºåïŒïŒ ã» ãã³ã¿ã¯ããããšããŒã«ïŒïŒ ãããã³ ã» å šçµæç©100ïœåœããªã³ãã³0.4ïŒ ã«ã»ãŒçžåœããæ°Ž82.75ééïŒ ãšãæ··åããŠå šçµ
æç©100ïœãšããã ãã®ããã«ããŠèª¿è£œããé²æ°Žçµæç©ã¯éåžžã®äœ¿
çšæ¡ä»¶äžã§å®å®ã§ããã é²æ°Žæ§è©Šéš ã·ã«ãã¹ã¿ãŒãã€ã³ã®ãµã³ãã«ïŒæé¢ïŒÃïŒ
cmãé·ã30cmïŒãäžèšã®ããã«èª¿è£œãããçµæç©
ã«ïŒåé浞挬ããã å¹³ååžåéã¯çŽ30KgïŒcm3ã§ããã ã» æ°Žã®ååã蟌ã¿ãµã€ã¯ã« ãµã³ãã«ãïŒæé颚也ããïŒæéæ°Žã«æµžæŒ¬ãã
ã®ã¡æ°Žåãããã æ°Žã®ååã蟌ã¿éã¯12ïŒ ã§ãã€ãã ç¡åŠçãµã³ãã«ã«åæ§ã®è©Šéšãè¡ãªã€ãçµæã¯
20ïŒ ã§ãã€ãã ã» æŽãèœããµã€ã¯ã« ãµã³ãã«ãåŒãç¶ãïŒé±é颚也ããïŒæéæ°Žã«
浞挬ãã次ãã§æ°Žåãããã åŠçãµã³ãã«ã®æ°Žã®ååã蟌ã¿éã¯ïŒïŒ ã§ãã€
ãããç¡åŠçãµã³ãã«ã®å Žåã¯25ïŒ ã§ããã 殺ã«ãè©Šéš ã·ã«ãã¹ã¿ãŒãã€ã³æã®ãµã³ãã«ãšã¶ãªæã®ãµ
ã³ãã«ããã®ãã®ãã·ãžãªãã»ãŒãã¹ã»ãªã°ãã
ã¬ã¹ã«å¯Ÿããæšæã®ä¿å補åã®è©äŸ¡ã®åºæºãšãªã
欧å·ãã«ã 113ã«å¯Ÿå¿ããNFÃ41â552ã®è©Šéšã«
äŸããã ãã®çµæãäžèšçµæç©ã§åŠçãããµã³ãã«ã¯ã³
ããªããªã©ã»ããã¢ããã³ãªãªã«ã¹ã»ãã«ã·ã³ã
ã«ãããªã¢ã»ãã©ã»ã³ã¿ããã³ã°ã¬ãªãã€ã«ã ã»
ãã©ããŠã ã®æ»æã«ããããããšãã«ïŒïŒ æªæºã®
å¹³å質éæ倱ã瀺ããã
ãåŸæ¥æ³ã«ããå±éäžèœã®è£œåã
å®æœäŸ 12ããã³13 é²æ°Žçµæç©ã®èª¿è£œ 以äžã®æ§è³ªïŒ ã» ã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«ã®ééæ¯ïŒçŽ
50ïŒ50 㻠也ç¥æœåºåå«æéïŒ çŽ50ïŒ ã» ä¹³æ¿å€ïŒã¢ã«ãã«ã¹ã«ãã³é žãããªãŠã ãã
ã³ã¢ã«ãã«ããšããŒã«ãªãã·ãšãã¬ã³ 㻠觊åªïŒ éç¡«é žã¢ã³ã¢ããŠã ã» ç²åŸïŒ 0.05ã0.40ÎŒïœ ã» è圢ææäœæž©åºŠïŒ 16â ã» ç²åºŠïŒ 50m.Pa.SïŒãã«ãã¯ãã€ãŒã«ãç²åºŠ
èšã䜿çšããŠ20âã«ãããŠ50tïŒå枬å®ïŒãæ
ããã¹ãã¬ã³ïŒã¢ã¯ãªã«é žããã«å ±éåäœã®æ°Ž
æ§åæ£æ¶²100éééš ä»¥äžã®æ§è³ªïŒ 㻠也ç¥æœåºåå«æéïŒ çŽ47ïŒ ã» å¯åºŠïŒ20âïŒïŒ 1.34 ã» ã¢ã«ã«ãªæ»Žå®éïŒ 18ïŒ ïŒK2OïŒ ãæããããã¿ã·ãŠã ïŒã¡ãã«ã·ãªã³ããŒãã®æ°Ž
溶液10éééšã ããã«ãžã°ãªã³ãŒã«3.5éééšã ããŒãã»ãã©ã³ã¯ç€Ÿã«ããåžè²©ãããŠãã
RHODOSIL416ãæ¶æ³¡å€ãšããŠ0.15éééšããã
ã³ å®æœäŸ12ã«ãããŠã¯20ïŒ ãå®æœäŸ13ã«ãããŠã¯
ïŒïŒ ã®ä¹Ÿç¥æœåºåã®éãåŸãã®ã«ååãªéã®æ°Žã
æ··åããã é²æ°Žæ§è©Šéš 40Ã15ÃïŒmmãªãã60Ã30ÃïŒmmã®å¯žæ³ã®æ æ
ãã©ãã¯ïŒåµ©å¯åºŠ0.15ã0.2ã®å¯ã§ãªããã®ïŒã
ãã«ã NFÃ40â500ïŒç¬¬26é ïŒïŒïŒïŒïŒæ®µïŒã«åŸ
ã€ãŠèŠå¶ãããåšèŸºå«æµžè©Šéšã«äŸããã 20容ãªãŒãã¯ã¬ãŒãããã©ãã¯1500ïœããã³
äžèšã«ãã調補ãããé²æ°Žçµæç©ã䜿çšããã ïœ å«æµžãµã€ã¯ã« å«æµžãµã€ã¯ã«ã¯ä»¥äžã®éãã§ããã ååçç©ºïŒ 650mbã§10åé å«æµžïŒ 10åé æçµçç©ºïŒ 650mbã§45åé æš100ïœã«åžåãããçµæç©ã®éã¯è¡šã«ç€ºãã ïœ æ°Žã®åå蟌ã¿ãµã€ã¯ã« ãã®ããã«åŠçãããã©ãã¯ãïŒæé颚也ãã
次ãã§ïŒæéæ°Žã«æµžæŒ¬ããã ãã©ãã¯ãæ°Žåãããééå€åã«ããæ°Žã®åå
ã蟌ã¿ã枬å®ãããåŸãããçµæã¯è¡šã«ç€ºãã ïœ æŽãèœãæå æ°Žã®ååã蟌ã¿ãµã€ã¯ã«åŸãã©ãã¯ãïŒé±é也
ç¥ãã次ãã§ïŒæéæ°Žã«æµžæŒ¬ããã ãã©ãã¯ã®æ°Žåããããæ°Žã®ååã蟌ã¿ã枬å®
ããã åŸãããçµæã¯è¡šã«ç€ºãã è¡šã«ã¯ããŸããæ¯èŒã®ããã«ç¡åŠçãã©ãã¯
ããã³ããŒãã»ãã©ã³ã¯ç€Ÿã«ããåžè²©ãããŠãã
ã·ãªã³ãŒã³æ²¹47V100ã®10ïŒ ãã¯ã€ãã¹ããªãã
溶液ã§åŠçãããã©ãã¯ã䜿çšããŠåŸãããçµæ
ããããã瀺ãã äžèšè©Šéšã®çµæã次ã®ããšã確ãããããã ã·ãªã³ãŒã³æ²¹ã§åŠçãããã©ãã¯ã¯ãµã€ã¯ã«ïœ
ã§æŽãèœããå°ãªãã æ¬çºæã®çµæç©ã§åŠçãããã©ãã¯ã¯ãµã€ã¯ã«
ïœã«ãããŠæŽãèœãããªãã€ãã ãã§ãªããé²æ°Ž
æ§ãããã«æ¹åãããã äžèšè©Šéšã®å¶éå ã§é²æ°Žçµæç©ã®ä¹Ÿç¥æœåºåã®
æ¿åºŠã®æ°Žã®ååã蟌ã¿ã«å¯Ÿãã圱é¿ã¯é¡èã§ã¯ãª
ãã å®æœäŸ 14 é²æ°Žçµæç©ã10éééšã®ä»£ããã«15éééšäœ¿çš
ããŠå®æœäŸ13ã«èšèŒã®é²æ°Žæ§è©Šéšãç¹°ãè¿ããã
ãã ãããã®é²æ°Žçµæç©ã¯ä¹Ÿç¥æœåºåå«éãïŒïŒ
ãšãªãããã«ååéã®æ°Žãå«æããŠããã é²æ°Žæ§è©Šéšã®çµæã¯è¡šã«ç€ºãã åŸãããé²æ°Žæ§ã¯å®æœäŸïŒã§åŸããããã®ãã
ãæ¹åãããŠããã å®æœäŸ 15 é²æ°Žçµæç©ã®èª¿è£œ ã» å®æœäŸ12ããã³13ã§äœ¿çšãããã¹ãã¬ã³âã¢
ã¯ãªã«é žããã«ã©ããã¯ã¹100éééš ã» å®æœäŸ12ããã³13ã§äœ¿çšãããã¡ãã«ã·ãªã³
ããŒã溶液10éééš ã» ããã«ãžã°ãªã³ãŒã«3.5éééšãããã³ ã» RHODOSIL 416 0.15éééš ãã調補ããã也ç¥æœåºåå«æé48.5ïŒ ã®é²æ°Žå€
åæ£æ¶²8.25ééïŒ ãšã ã» ãã³ã¿ã¯ããããšããŒã«27.3éééšã ã» ãªã³ãã³4.8éééš ã» ãªã«ããžã¯ãããã³ãŒã³22.7éééš ã» ããã·ã¬ã³ã°ãªã³ãŒã«25.8éééš ã» DERTOLINEPãšããå称ã§ããªãã»ã¬ãž
ããŒã¯ã»ãšã»ãã«ãããŒã¯ç€Ÿããåžè²©ãããŠã
ãã³ãããªããŠã èãšãã³ã¿ãšãªã¹ãªããŒã«ã®
ãšã¹ãã«8.1éééšãããã³ ã» æ¬¡åŒ CH3âïŒCH2ïŒ11âCH2âïŒOCH2CH2ïŒ3â
OSO3NH4 ã®ä¹³æ¿å€11.3éééš ãã調補ãããä¹³æ¿å¯èœæ¿çž®ç©ïŒééïŒ ãšã ã» é²æ°Žå€åæ£æ¶²ã®ä¹Ÿç¥æœåºåïŒïŒ ã» ãã³ã¿ã¯ããããšããŒã«ïŒïŒ ãããã³ ã» å šçµæç©100ïœåœããªã³ãã³0.4ïŒ ã«ã»ãŒçžåœããæ°Ž82.75ééïŒ ãšãæ··åããŠå šçµ
æç©100ïœãšããã ãã®ããã«ããŠèª¿è£œããé²æ°Žçµæç©ã¯éåžžã®äœ¿
çšæ¡ä»¶äžã§å®å®ã§ããã é²æ°Žæ§è©Šéš ã·ã«ãã¹ã¿ãŒãã€ã³ã®ãµã³ãã«ïŒæé¢ïŒÃïŒ
cmãé·ã30cmïŒãäžèšã®ããã«èª¿è£œãããçµæç©
ã«ïŒåé浞挬ããã å¹³ååžåéã¯çŽ30KgïŒcm3ã§ããã ã» æ°Žã®ååã蟌ã¿ãµã€ã¯ã« ãµã³ãã«ãïŒæé颚也ããïŒæéæ°Žã«æµžæŒ¬ãã
ã®ã¡æ°Žåãããã æ°Žã®ååã蟌ã¿éã¯12ïŒ ã§ãã€ãã ç¡åŠçãµã³ãã«ã«åæ§ã®è©Šéšãè¡ãªã€ãçµæã¯
20ïŒ ã§ãã€ãã ã» æŽãèœããµã€ã¯ã« ãµã³ãã«ãåŒãç¶ãïŒé±é颚也ããïŒæéæ°Žã«
浞挬ãã次ãã§æ°Žåãããã åŠçãµã³ãã«ã®æ°Žã®ååã蟌ã¿éã¯ïŒïŒ ã§ãã€
ãããç¡åŠçãµã³ãã«ã®å Žåã¯25ïŒ ã§ããã 殺ã«ãè©Šéš ã·ã«ãã¹ã¿ãŒãã€ã³æã®ãµã³ãã«ãšã¶ãªæã®ãµ
ã³ãã«ããã®ãã®ãã·ãžãªãã»ãŒãã¹ã»ãªã°ãã
ã¬ã¹ã«å¯Ÿããæšæã®ä¿å補åã®è©äŸ¡ã®åºæºãšãªã
欧å·ãã«ã 113ã«å¯Ÿå¿ããNFÃ41â552ã®è©Šéšã«
äŸããã ãã®çµæãäžèšçµæç©ã§åŠçãããµã³ãã«ã¯ã³
ããªããªã©ã»ããã¢ããã³ãªãªã«ã¹ã»ãã«ã·ã³ã
ã«ãããªã¢ã»ãã©ã»ã³ã¿ããã³ã°ã¬ãªãã€ã«ã ã»
ãã©ããŠã ã®æ»æã«ããããããšãã«ïŒïŒ æªæºã®
å¹³å質éæ倱ã瀺ããã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ°Žæ§åæ£æ¶²ãå¡©åºæ§PHã«å®å®ãªæ°Žæ§åªäœã«å
ãŸããåæ£æ¶²ã®åœ¢ã®ãççŽ æ°ïŒãïŒã®ã¢ã«ãã«åº
ãæããã¢ã¯ãªã«é žã¢ã«ãã«ãšè³éŠæããã«åé
äœã®è圢ææ§å ±éåäœããæãã該è³éŠæããã«
åéäœã¯ãã®å¯Ÿå¿ããåç¬éåäœãã¬ã©ã¹è»¢ç§»ç¹
70ã170âã瀺ããããªãã€è©²ã¢ã¯ãªã«é žã¢ã«ã
ã«ãšã®å ±éåäœãã¬ã©ã¹è»¢ç§»ç¹âïŒâãïŒ25âã
瀺ããããªåéäœã§ããããã€ã¢ã«ã«ãªã¢ã«ãã«
ã·ãªã³ããŒãã®ååšéã也ç¥å ±éåäœ100ïœåœã
ã¢ã«ãã«ã·ãªã³ããŒã0.05ã0.17ã¢ã«ã§ããããš
ãç¹åŸŽãšãããã¢ã¯ãªã«é žã¢ã«ãã«å«æå ±éåäœ
ãšã¢ã«ã«ãªã¢ã«ãã«ã·ãªã³ããŒãã®æ°Žæ§åæ£æ¶²ã
ãæãé²æ°Žçµæç©ã ïŒ è©²ã¢ã¯ãªã«é žã¢ã«ãã«ãšè©²è³éŠæããã«åé
ã®å ±éåäœã®è©²æ°Žæ§åæ£æ¶²ãç²åŸ0.05ã0.5ÎŒïœã®
也ç¥ææå20ã60ééïŒ ãå«æãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ããã«æ®ºã«ãå€ããã³ïŒãŸãã¯æ®ºè«å€ããæ
ãæå¹æåãå šééã«å¯ŸããŠïŒééïŒ ãŸã§å«æã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé ã®ããã
ãäžã€ã«èšèŒã®çµæç©ã ïŒ è©²æå¹æåããããã©ã¯ããããšããŒã«ãã
ã³ïŒãŸãã¯ãã³ã¿ã¯ããããšããŒã«ããã³ïŒãŸã
ã¯ææ©é«é¯äœã«å Žåã«ãã€ãŠãžã¯ãããã«ã¢ãã
ãæ··åããŠæã殺ã«ãå€70ã98ééïŒ ãšããªã³ã
ã³ããã³ïŒãŸãã¯ããµãã³ããã³ïŒãŸãã¯ã»ãã³
ããã³ïŒãŸãã¯ãã«ã¡ã¹ãªã³ããã³ïŒãŸãã¯ããš
ã³ãã¬ã¬ãŒãããæã殺è«å€30ãïŒééïŒ ãšãçµ
ã¿åãããŠæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµ
æç©ã
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8207619A FR2526033A1 (fr) | 1982-05-03 | 1982-05-03 | Compositions hydrofugeantes, leur procede de preparation et leur mise en oeuvre pour l'hydrofugation et la protection de surfaces diverses |
FR8207619 | 1982-05-03 | ||
FR8304719 | 1983-03-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5925870A JPS5925870A (ja) | 1984-02-09 |
JPH0244348B2 true JPH0244348B2 (ja) | 1990-10-03 |
Family
ID=9273644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7631183A Expired - Lifetime JPH0244348B2 (ja) | 1982-05-03 | 1983-05-02 | Bosuisoseibutsu*sonoseizohohooyobishujunohyomennobosuihogonishosuruhoho |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPH0244348B2 (ja) |
BE (1) | BE896634A (ja) |
CA (1) | CA1199440A (ja) |
FR (1) | FR2526033A1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3685132D1 (de) * | 1985-02-08 | 1992-06-11 | Levasseur S A G | Beschichtung fuer baumaterialien und verfahren zur herstellung der bestandteile dieser beschichtung. |
JPH0569412A (ja) * | 1991-09-17 | 1993-03-23 | Nishi Nippon Riyokaku Tetsudo Kk | æšæåŠçå€åã³æšæåŠçæ¹æ³ |
FR2688917A1 (fr) * | 1992-03-20 | 1993-09-24 | Rhone Poulenc Chimie | Composition aqueuse hydrofugeante et son utilisation comme formulation pour revetement interieur ou exterieur de surfaces diverses. |
JP4771652B2 (ja) * | 2003-11-07 | 2011-09-14 | ãšã¹ã±ãŒåç æ ªåŒäŒç€Ÿ | æ°Žæ§å¡æçµæç© |
JP4771653B2 (ja) * | 2003-11-07 | 2011-09-14 | ãšã¹ã±ãŒåç æ ªåŒäŒç€Ÿ | æ°Žæ§å¡æçµæç© |
WO2006070183A1 (en) * | 2004-12-30 | 2006-07-06 | Syngenta Limited | Aqueous coating compositions |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2211944A5 (en) * | 1972-12-27 | 1974-07-19 | Sedip Inter | Styrene-butadiene-acrylate ester copolymer dispersion - in PVA-contg. compsn. for coating and moulding in educative toys |
US4012355A (en) * | 1973-12-26 | 1977-03-15 | The Dow Chemical Company | Composition useful in preventing environmental erosion containing film forming organic polymer and silicone |
FR2467232A1 (fr) * | 1979-10-11 | 1981-04-17 | Robert Dubois | Procede pour empecher la formation de verglas sur les routes et composition pour sa mise en oeuvre |
-
1982
- 1982-05-03 FR FR8207619A patent/FR2526033A1/fr active Granted
-
1983
- 1983-05-02 BE BE0/210676A patent/BE896634A/fr not_active IP Right Cessation
- 1983-05-02 JP JP7631183A patent/JPH0244348B2/ja not_active Expired - Lifetime
- 1983-05-02 CA CA000427212A patent/CA1199440A/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR2526033A1 (fr) | 1983-11-04 |
BE896634A (fr) | 1983-11-03 |
FR2526033B1 (ja) | 1985-05-03 |
JPS5925870A (ja) | 1984-02-09 |
CA1199440A (fr) | 1986-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6821631B2 (en) | Method and composition for treating substrates | |
DE3115601A1 (de) | "kunstharzemulsion und deren verwendung als klebstoff, papierbehandlungsmittel, anstrichmaterial, faser- und textilbehandlungsmittel und zementmodifizierungsmittel" | |
DE3147007C2 (de) | Selbstvernetzende wÀÃrige Kunststoff dispersion | |
DE2161645A1 (de) | Beschlagverhinderndes beschichtungsmittel | |
WO2003037532A1 (en) | Method and composition for treating wood | |
DE3302767A1 (de) | Grundierungsmittel und seine verwendung | |
EP0754737A2 (de) | Beschichtungsmassen auf Basis von in Wasser redispergierbaren, wasserlösliches Polymer und Organosiliciumverbindung enthaltenden Pulvern | |
US3509083A (en) | Protective repellent solution | |
US7709016B2 (en) | Insect proof boards | |
DE102008023389A1 (de) | Polyvinylesterdispersionen und deren Verwendung | |
DE60022456T2 (de) | Neue fluorhaltige Copolymerisate fÃŒr die Ãl- und wasserabweisende Behandlung von Substraten | |
DE69305554T2 (de) | Nichtentfernbare, fleckenbestÀndige Beschichtungen | |
JPH0244348B2 (ja) | Bosuisoseibutsu*sonoseizohohooyobishujunohyomennobosuihogonishosuruhoho | |
DE19545608A1 (de) | Dispersionspulver fÃŒr wasserfeste Klebstoffe | |
DE60119395T2 (de) | Fluorierte copolymere zur hydrophobierung und oleophobierung von baumaterialien | |
GB2121424A (en) | Waterproofing compositions, their preparation and their use | |
DE4313401C2 (de) | WÀÃrige Emulsion und leicht aufschlieÃbares, feuchtigkeitsbestÀndiges Papier | |
DE1669024B2 (de) | Ueberzugsmittel | |
DE1519201B2 (de) | Waessriges ueberzugsmittel | |
EP0036993A1 (de) | Verfahren zum Veredeln von Papier, Pappe und Karton | |
DE1519229A1 (de) | Veredelungsmittel und Verfahren zu seiner Herstellung | |
CN110511677A (zh) | äžç§ç¯ä¿èŽçŠ»åé¢æ¶ååå ¶å¶å€æ¹æ³ | |
DE2412066A1 (de) | Zur herstellung von harzueberzuegen mit hoher opazitaet geeignete latices | |
EP1475421A1 (de) | Universal-Grundierungsmittel | |
EP1006106B1 (de) | Benetzungsmittel, enthaltend sulfonierte DicarbonsÀureester |