JPH0241156A - Tape fastener base material - Google Patents

Tape fastener base material

Info

Publication number
JPH0241156A
JPH0241156A JP63191425A JP19142588A JPH0241156A JP H0241156 A JPH0241156 A JP H0241156A JP 63191425 A JP63191425 A JP 63191425A JP 19142588 A JP19142588 A JP 19142588A JP H0241156 A JPH0241156 A JP H0241156A
Authority
JP
Japan
Prior art keywords
core
nonwoven fabric
polyolefin
component
sheath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63191425A
Other languages
Japanese (ja)
Inventor
Tadashi Saeki
佐伯 忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unitika Ltd
Original Assignee
Unitika Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unitika Ltd filed Critical Unitika Ltd
Priority to JP63191425A priority Critical patent/JPH0241156A/en
Publication of JPH0241156A publication Critical patent/JPH0241156A/en
Pending legal-status Critical Current

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  • Absorbent Articles And Supports Therefor (AREA)
  • Adhesive Tapes (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE:To provide a tape fastener base material reduced in a lowering of tearing strength and generating no delamination by using a long fiber nonwoven fabric composed of a core-sheath type composite fiber wherein polyester is core a component and polyolefin is a sheath component. CONSTITUTION:When a long fiber nonwoven fabric composed of a core-sheath type composite fiber wherein polyester whose main repeating unit is composed of ethylene terephthalate is a core component and polyolefin is a sheath component is subjected to calendar processing at temp. equal to or less than the m.p. of polyolefin, the polyolefin component flows to fill the fiber gaps constituting the nonwoven fabric. Herein, since the polyolefin resin is not perfectly melting and the flexibility of the fabric remains, a lowering of tearing strength is reduced. Further, since the nonwoven fabric is composed of the core-sheath type composite fiber and the difference between the melting points of the polymers constituting the core and sheath component is large, the pressed part at the time of hot press bonding by a hot emboss roll is not made plastic perfectly and a temp. condition capable of bonding fibers can be properly selected. Therefore, the interlayer delamination of the nonwoven fabric can be prevented.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、使い捨ておむつ用テープファスナー基材に関
するものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a tape fastener base material for disposable diapers.

(従来の技術) 従来、使い捨ておむつには、おむつを固定するためにテ
ープファスナーが用いられている。
(Prior Art) Conventionally, tape fasteners have been used in disposable diapers to secure the diaper.

このテープファスナー基材としては、ポリエステル、ナ
イロン等の長繊維不織布の両面にポリエチレンフィルム
あるいは紙をラミネート加工した後2片面に粘着剤、他
面に離型材を塗布したものが用いられていた。
The tape fastener base material used was a long fiber nonwoven fabric such as polyester or nylon, laminated with polyethylene film or paper on both sides, and then coated with an adhesive on one side and a release agent on the other side.

(発明が解決しようとする課題) しかしながら、上記テープファスナーの場合、眉間剥離
が問題となり、使い捨ておむつの製造時又は着用時に2
層に剥離するものである。これら層間剥離を解消するた
め、ポリエチレンフィルムをラミネート加工にて不織布
内部迄フィルムを浸透させることが行われている。とこ
ろが、不織布内部迄フィルムを浸透させると、引裂強力
が低下し着用時にテープファスナーが切断する問題を有
していた。
(Problems to be Solved by the Invention) However, in the case of the above-mentioned tape fastener, peeling between the eyebrows becomes a problem.
It peels off into layers. In order to eliminate these delaminations, polyethylene film is laminated to allow the film to penetrate into the inside of the nonwoven fabric. However, when the film penetrates into the inside of the nonwoven fabric, there is a problem in that the tear strength decreases and the tape fastener breaks when worn.

(課題を解決するための手段) 本発明者らは、引裂強力の低下が少なく、かつ層間剥離
のないテープファスナー基材を提供するために鋭意研究
を行った結果、本発明に到達したものである。
(Means for Solving the Problems) The present inventors have arrived at the present invention as a result of intensive research to provide a tape fastener base material with less reduction in tear strength and without delamination. be.

すなわち1本発明は、主たる繰返し単位がエチレンテレ
フタレート単位からなるポリエステルを芯成分とし,ポ
リオレフインを鞘成分とする芯鞘型複合繊維からなるポ
リオレフィン系不織布であって、該不織布をカレンダー
加工機にてポリオレフィンの融点以下の温度で熱圧着せ
しめてなるテープファスナー基材を要旨とするものであ
る。
Specifically, the present invention provides a polyolefin-based nonwoven fabric made of a core-sheath composite fiber having a core component of polyester whose main repeating unit is an ethylene terephthalate unit and a sheath component of polyolefin. The gist of the invention is a tape fastener base material that is bonded under heat and pressure at a temperature below the melting point of the material.

芯鞘型複合繊維の芯成分を構成するポリエステルは、主
たる繰返し単位がエチレンテレフタレートもしくは、エ
チレンテレフタレートを主体とする共重合ポリエステル
である。共重合成分としては、従来公知の酸成分及びグ
リコール成分が使用でき、酸成分としてイソフタル酸、
アジピン酸等がグリコール成分としては、プロピレング
リコールジエチレングリコール等が使用される。
The polyester constituting the core component of the core-sheath type composite fiber is a copolyester whose main repeating unit is ethylene terephthalate or ethylene terephthalate as a main component. As the copolymerization component, conventionally known acid components and glycol components can be used, and the acid components include isophthalic acid,
Propylene glycol diethylene glycol and the like are used as the glycol component such as adipic acid.

一方、鞘成分を構成するポリオレフィンとしては、直鎖
状低密度ポリエチレン、高密度ポリエチレン、中密度ポ
リエチレン、低密度ポリエチレン、ポリプロピレン、エ
チレン−酢酸ビニル共重合体等が挙げられる。
On the other hand, examples of the polyolefin constituting the sheath component include linear low-density polyethylene, high-density polyethylene, medium-density polyethylene, low-density polyethylene, polypropylene, ethylene-vinyl acetate copolymer, and the like.

次に、芯鞘成分の割合については、ポリマー重量比が1
:0.1〜5であることが好ましい。上記ポリマー重量
比が1:5を超えるとカレンダー加工時に流動するポリ
マー量が多過ぎるため不織布の引裂強力の低下が大きい
。一方、上記重量比がに0.1未満の場合、不織布構成
繊維が殆んどポリエステル繊維から構成されるため、引
裂強力の低下が少ないものの、不織布を構成する繊維空
間に充填される樹脂量が少ないので、不織布の眉間剥離
を生じる。
Next, regarding the ratio of core-sheath components, the polymer weight ratio is 1.
: It is preferable that it is 0.1-5. If the polymer weight ratio exceeds 1:5, the amount of polymer that flows during calendering is too large, resulting in a significant decrease in the tear strength of the nonwoven fabric. On the other hand, when the above weight ratio is less than 0.1, the fibers constituting the nonwoven fabric are mostly composed of polyester fibers, so although there is little decrease in tear strength, the amount of resin filled into the fiber spaces constituting the nonwoven fabric is small. Since the amount is too small, peeling of the nonwoven fabric occurs between the eyebrows.

したがって、1:0.1〜5の範囲内に芯鞘比(ポリマ
ー重量比)があるのが望ましい。
Therefore, it is desirable that the core/sheath ratio (polymer weight ratio) be within the range of 1:0.1 to 5.

次に、上記ポリオレフィン系長繊維不織布は、スパンボ
ンド方式にて効率よく、長繊維不織布を得ることが可能
である。すなわち、従来公知の芯鞘型複合紡糸口金を有
する溶融紡糸装置を用い、連続フィラメントをエア・サ
ッカーにより延伸した後1捕集面上にて直接不織布を得
る方法で、その後。
Next, the polyolefin long fiber nonwoven fabric can be efficiently obtained by a spunbond method. That is, using a conventionally known melt spinning apparatus having a core-sheath type composite spinneret, a continuous filament is drawn by an air sucker and then a nonwoven fabric is obtained directly on one collection surface.

熱エンボスロールにて熱圧接を行い、シート化するもの
である。
Heat pressure welding is performed using a hot embossing roll to form a sheet.

次いで、上記ポリオレフィン系不織布の鞘成分を構成す
−るポリオレフィンの融点以下の温度にてカレンダー加
工を行い、鞘成分のポリオレフィンを軟化流動させるこ
とで、不織布を構成する繊維空間にポリオレフィン樹脂
を充填させ、低通気度の不織布を得る。
Next, calendering is performed at a temperature below the melting point of the polyolefin constituting the sheath component of the polyolefin nonwoven fabric to soften and fluidize the polyolefin constituting the sheath component, thereby filling the fiber spaces constituting the nonwoven fabric with polyolefin resin. , obtain a nonwoven fabric with low air permeability.

カレンダー加工温度をポリオレフィンの融点以上の温度
で行うと、溶融したポリオレフィン樹脂がカレンダーロ
ール表面に付着し、安定した不織布シートを得ることが
困難である。また,ポリオレフイン樹脂の融点以上で加
圧すると、ポリマーの流動性が良好であるため、あらゆ
る部分の繊維空間にポリオレフィン樹脂が充填され、ペ
ーパーライクになり、引裂強力の低い不織布シートしか
得られない。特に1本発明では、カレンダー加工温度を
ポリオレフィンの融点より10〜30℃低い温度で行う
のが好ましい。
If the calendering temperature is higher than the melting point of the polyolefin, the molten polyolefin resin will adhere to the surface of the calender roll, making it difficult to obtain a stable nonwoven fabric sheet. Furthermore, when pressure is applied above the melting point of the polyolefin resin, since the polymer has good fluidity, the polyolefin resin fills the fiber spaces in all parts, making it paper-like and producing only a nonwoven sheet with low tear strength. Particularly in the present invention, the calendering temperature is preferably 10 to 30°C lower than the melting point of the polyolefin.

本発明の使い捨ておむつ用テープファスナー基材は、従
来のポリエステル又は、ナイロン長繊維不織布からなる
テープファスナー基材と異なり1次に示す長所を有する
ものである。すなわち、従来のテープファスナー基材の
場合、その片面に粘着剤を、もう一方の面に離型剤を付
与するに対し、これら薬剤が他の面に浸透しないように
両面にポリエチレン等のフィルムがラミネートされてい
る。
The tape fastener base material for disposable diapers of the present invention has the following advantages, unlike conventional tape fastener base materials made of polyester or nylon long fiber nonwoven fabric. In other words, in the case of conventional tape fastener base materials, an adhesive is applied to one side and a release agent is applied to the other side, but a film such as polyethylene is placed on both sides to prevent these agents from penetrating the other side. It is laminated.

ところが9本発明の場合、カレンダー加工により8不織
布を構成する繊維空間に鞘成分を構成するポリオレフィ
ン樹脂が充填され9通気度がコントロールされており、
上記薬剤の塗布による裏面への浸透をな(することがで
きる。これを達成するため1通気度試験法JIS L−
1096B法にて2秒/100mj!以上の通気度を有
しているものが好ましい。
However, in the case of the present invention, the polyolefin resin constituting the sheath component is filled into the fiber spaces constituting the nonwoven fabric by calendering, and the air permeability is controlled.
It is possible to penetrate the back surface by coating the above chemicals.In order to achieve this, 1 air permeability test method JIS L-
2 seconds/100mj using 1096B method! It is preferable that the material has an air permeability higher than that.

なお、従来のテープファスナー基材の場合、不織布にポ
リエチレンフィルムをラミネートした後。
In addition, in the case of conventional tape fastener base material, after laminating a polyethylene film to a nonwoven fabric.

さらに粘着剤の基布への接着性を向上させるため紙をラ
ミネートすることも行われている。本発明についてもこ
の紙のラミネート加工を行うことも可能である。
Furthermore, in order to improve the adhesion of the adhesive to the base fabric, paper is sometimes laminated. In the present invention, it is also possible to perform lamination processing of this paper.

(作 用) 本発明によれば、芯成分にポリエステル、鞘成分にポリ
オレフィンを用いた芯鞘型複合繊維からなる長繊維不織
布を鞘成分を構成するポリオレフインの融点以下の温度
でカレンダー加工することで層間剥離がなく、シかも引
裂強力の低下の少ないテープファスナー基材を得ること
ができる。
(Function) According to the present invention, by calendering a long-fiber nonwoven fabric made of a core-sheath composite fiber using polyester as a core component and polyolefin as a sheath component at a temperature below the melting point of the polyolefin that constitutes the sheath component. It is possible to obtain a tape fastener base material that is free from delamination and exhibits less deterioration in tear strength.

この理由について1本発明者らは9次のように推察して
いる。
The inventors of the present invention speculate as to the reason for this as follows.

鞘成分にポリオレフィンを用いた不織布をポリオレフィ
ンの融点以下の温度でカレンダー加工することで,ポリ
オレフイン成分が流動して不織布を構成する繊維間隙が
充填される。ところが1ポリオレフイン樹脂については
、完全に溶融していないため、その結合は弱いもので、
外力が付加されると、その結合が容易に解除されるもの
である。
By calendering a nonwoven fabric using polyolefin as a sheath component at a temperature below the melting point of the polyolefin, the polyolefin component flows and fills the gaps between the fibers that make up the nonwoven fabric. However, 1 polyolefin resin is not completely melted, so its bond is weak.
When an external force is applied, the connection is easily released.

このため1テープフアスナー基材の生地の融通性が残っ
ており、引裂強力の低下が少ないと考えられる。また1
層間剥離の少ない理由として1本発明の不織布が芯鞘型
複合繊維からなっており、芯成分と鞘成分を構成するポ
リマーの融点の差が大きいので、熱エンボスロールによ
る熱圧着め際、押圧部分を完全なプラスチック化させな
いで1 しかも繊維間接着できる温度条件を適切に選択
することが可能であるからである。
Therefore, the flexibility of the fabric of the one-tape fastener base material remains, and it is thought that there is little decrease in tear strength. Also 1
One of the reasons for the low delamination is that the nonwoven fabric of the present invention is made of core-sheath composite fibers, and there is a large difference in melting point between the polymers constituting the core component and the sheath component. This is because it is possible to appropriately select temperature conditions that allow fiber-to-fiber bonding without completely converting the material into plastic.

したがって、不織布として層間剥離が少なく、かつ、し
かも引裂強力の低下の少ない性能を得るには2本発明の
構成からなる芯鞘型複合繊維を使用することにより初め
て達成できるものである。
Therefore, performance as a nonwoven fabric with less delamination and less deterioration in tear strength can only be achieved by using a core-sheath composite fiber having the two structures of the present invention.

(実施例) 以下5本発明を実施例によって具体的に説明する。(Example) The present invention will be explained in detail below using five examples.

なお、実施例中で示した物性値の測定方法は2次の通り
である。
The physical property values shown in the examples were measured in the following manner.

(1)通気度 JIS L−1096B法に阜じて1通気度秒/100
mffを測定した。
(1) Air permeability 1 air permeability second/100 according to JIS L-1096B method
mff was measured.

(2)引裂強力 JIS L−1096D法に阜じて、引裂強力を測定し
た。
(2) Tear strength Tear strength was measured according to JIS L-1096D method.

(3)恭■離強力 離型加工及び粘着加工を施していない不織布をヨコ方向
に幅5 am X長さ20cm採取し、試料の端を手で
剥離してつかみ代を作り、引張速度100+u/分でT
剥離強力を測定した。
(3) Sample a nonwoven fabric that has not been subjected to strong release or adhesive processing in the horizontal direction with a width of 5 am x length of 20 cm, peel off the edge of the sample by hand to create a gripping area, and pull at a tensile speed of 100 + u/ T in minutes
Peel strength was measured.

(4)粘着力 離型加工及び粘着加工を施した不織布をヨコ方向に幅5
 cm X長さ20cm採取し、粘着加工面にステンレ
ス板を貼りつけ、粘着面のT剥離強力を引張速度100
m1/分で測定した。
(4) Adhesive force A nonwoven fabric that has been subjected to mold release and adhesive processing has a width of 5 mm in the horizontal direction.
cm x length 20cm, stick a stainless steel plate on the adhesive surface, and measure the T-peel strength of the adhesive surface at a tensile speed of 100.
Measured in m1/min.

実施例1 芯成分がポリエチレンテレフタレート、鞘成分が直鎖状
低密度ポリエチレン(融点125°C)からなり、芯/
鞘型量比が1=1である芯鞘型複合繊維を芯鞘型複合紡
糸口金を有する溶融紡糸装置を用い、エア・サッカーに
て引き取り速度5 、000 m7分で吸引、延伸を行
った後、ネットコンベア上に芯鞘型複合繊維を堆積させ
てランダムウェブを形成した。
Example 1 The core component is polyethylene terephthalate, the sheath component is linear low-density polyethylene (melting point 125°C), and the core /
A core-sheath type composite fiber with a sheath type weight ratio of 1 = 1 was drawn using a melt spinning device having a core-sheath type composite spinneret at a take-up speed of 5,000 m7 minutes using an air sucker. A random web was formed by depositing core-sheath composite fibers on a net conveyor.

次いで、熱エンボスロールにて交絡するフィラメント間
を圧接面積率10%、エンボスロール表面温度110℃
にて熱圧接を行い、目付70 g / rn’のポリオ
レフィン系不織布を製造した。
Next, the intertwined filaments were pressed with a hot embossing roll at a contact area ratio of 10% and an embossing roll surface temperature of 110°C.
A polyolefin nonwoven fabric having a basis weight of 70 g/rn' was produced by heat-pressure welding.

このポリオレフィン系不織布を高圧カレンダーを用いて
カレンダーの表面温度105°C9線圧250kg/ 
cmの条件で処理し、 JIS Lユ1096  B法
にて通気度2.5秒/100mAのシートを得た。
This polyolefin nonwoven fabric was heated using a high-pressure calender at a calender surface temperature of 105°C and a linear pressure of 250 kg/
A sheet with an air permeability of 2.5 seconds/100 mA was obtained using the JIS L Yu 1096 B method.

次に1離型加工を下記処方1に示すシリコン樹脂を用い
1固型分にて0.5g/mをリバースコーターで塗布し
、100℃×3分間の条件で乾燥し、100℃×2分間
の条件で熱処理した。
Next, 1 mold release processing was performed using a silicone resin shown in the following formulation 1 at a rate of 0.5 g/m per solid layer using a reverse coater, dried at 100°C for 3 minutes, and dried at 100°C for 2 minutes. It was heat treated under the following conditions.

〔処方1〕 シリコン樹脂           10部(信越化学
工業−製品、製品名: 信越シリコンKS719.  固形分20%)硬化触媒
             0,4部(信越化学工業(
掬製品、製品名: 信越シリコンC−PS−3) 希釈剤              10部(トルエン
) 次いで、粘着加工は、粘着剤としてアクリル酸エステル
エマルジョン(大日本インキ化学工業G1製品、商品名
:ボンコ−) P S −307)を用い、固形分にて
30g/mをリバースロールコータ−にて塗布し110
0℃×2分間の条件にて乾燥した。
[Formulation 1] Silicone resin 10 parts (Shin-Etsu Chemical Co., Ltd. - product, product name: Shin-Etsu Silicon KS719. Solid content 20%) Curing catalyst 0.4 parts (Shin-Etsu Chemical Co., Ltd.
Scoop product, product name: Shin-Etsu Silicon C-PS-3) Diluent: 10 parts (toluene) Next, for adhesive processing, use an acrylic acid ester emulsion (Dainippon Ink and Chemicals G1 product, product name: Bonco) as the adhesive. S-307) was applied using a reverse roll coater at a solid content of 30 g/m.
It was dried at 0° C. for 2 minutes.

次に、離型加工、粘着加工を行ったテープファスナー基
材の性能を評価した。結果を第1表に示す。
Next, the performance of the tape fastener base material subjected to mold release processing and adhesive processing was evaluated. The results are shown in Table 1.

第1表 性能を評価した。結果を第1表に示す。Table 1 Performance was evaluated. The results are shown in Table 1.

表から明らかなように比較例1の場合9層間剥離するも
のであり、比較例2の場合引裂強力が低(、いずれもテ
ープファスナー基材として問題があった。
As is clear from the table, in the case of Comparative Example 1, nine layers peeled, and in the case of Comparative Example 2, the tear strength was low (both had problems as tape fastener base materials).

(発明の効果) 本発明によれば、芯成分がポリエステル、鞘成分がポリ
オレフィンからなる芯鞘型複合繊維から構成されるポリ
オレフィン系長繊維不織布をカレンダー加工することに
より、引裂強力が高く、かつ層間剥離のしにくいテープ
ファスナーが得られる。
(Effects of the Invention) According to the present invention, by calendering a polyolefin long fiber nonwoven fabric composed of a core-sheath type composite fiber whose core component is polyester and whose sheath component is polyolefin, the tear strength is high and the interlayer A tape fastener that is difficult to peel off can be obtained.

比較例1〜2Comparative examples 1-2

Claims (1)

【特許請求の範囲】[Claims] (1) 主たる繰返し単位がエチレンテレフタレート単
位からなるポリエステルを芯成分とし,ポリオレフイン
を鞘成分とする芯鞘型複合繊維からなるポリオレフイン
系長繊維不織布であって,該不織布をカレンダー加工機
にてポリオレフインの融点以下の温度で熱圧着せしめて
なるテープフアスナー基材。
(1) A polyolefin-based long-fiber nonwoven fabric consisting of a core-sheath type composite fiber whose core component is polyester whose main repeating unit is an ethylene terephthalate unit and whose sheath component is polyolefin. A tape fastener base material made by thermocompression bonding at a temperature below the melting point.
JP63191425A 1988-07-29 1988-07-29 Tape fastener base material Pending JPH0241156A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63191425A JPH0241156A (en) 1988-07-29 1988-07-29 Tape fastener base material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63191425A JPH0241156A (en) 1988-07-29 1988-07-29 Tape fastener base material

Publications (1)

Publication Number Publication Date
JPH0241156A true JPH0241156A (en) 1990-02-09

Family

ID=16274401

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63191425A Pending JPH0241156A (en) 1988-07-29 1988-07-29 Tape fastener base material

Country Status (1)

Country Link
JP (1) JPH0241156A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09158025A (en) * 1995-12-04 1997-06-17 Unitika Ltd Nonwoven fabric for joining
JPH10121359A (en) * 1996-10-17 1998-05-12 Kao Corp Nonwoven fabric
US20180162107A1 (en) * 2016-12-12 2018-06-14 Hong Xu Composite articles including surface layers that provide enhanced formability

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09158025A (en) * 1995-12-04 1997-06-17 Unitika Ltd Nonwoven fabric for joining
JPH10121359A (en) * 1996-10-17 1998-05-12 Kao Corp Nonwoven fabric
US20180162107A1 (en) * 2016-12-12 2018-06-14 Hong Xu Composite articles including surface layers that provide enhanced formability
KR20190097126A (en) * 2016-12-12 2019-08-20 한화 아즈델 인코포레이티드 Composite articles comprising surface layers that provide improved formability
CN110573340A (en) * 2016-12-12 2019-12-13 汉华阿兹德尔股份有限公司 composite article including a surface layer providing enhanced formability
AU2017375758B2 (en) * 2016-12-12 2023-02-02 Hanwha Azdel, Inc. Composite articles including surface layers that provide enhanced formability
US11780215B2 (en) 2016-12-12 2023-10-10 Hanwha Azdel, Inc. Composite articles including surface layers that provide enhanced formability

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