JPH02299530A - Reel composition for fishing - Google Patents
Reel composition for fishingInfo
- Publication number
- JPH02299530A JPH02299530A JP1118559A JP11855989A JPH02299530A JP H02299530 A JPH02299530 A JP H02299530A JP 1118559 A JP1118559 A JP 1118559A JP 11855989 A JP11855989 A JP 11855989A JP H02299530 A JPH02299530 A JP H02299530A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- fishing reel
- vccf
- fiber
- fishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000002134 carbon nanofiber Substances 0.000 claims description 6
- 239000011342 resin composition Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 abstract description 23
- 239000011347 resin Substances 0.000 abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- 239000004917 carbon fiber Substances 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 6
- 229920005992 thermoplastic resin Polymers 0.000 abstract description 5
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 5
- 239000012808 vapor phase Substances 0.000 abstract description 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 229930195733 hydrocarbon Natural products 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 2
- 238000001947 vapour-phase growth Methods 0.000 abstract 1
- 230000000007 visual effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 7
- 229920006122 polyamide resin Polymers 0.000 description 7
- 239000003575 carbonaceous material Substances 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920006215 polyvinyl ketone Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000007666 vacuum forming Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920006065 Leona® Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、魚釣用リール組成物に関する。[Detailed description of the invention] (Industrial application field) FIELD OF THE INVENTION The present invention relates to fishing reel compositions.
（従来の技術）
従来、魚釣用リール組成物は、アルミニウムダイキャス
ト製品が一般的であった。しかし、最近は、軽量化の市
場要求に伴い、樹脂組成物成形品が急速に普及し、魚釣
用リールの大半が樹脂組成物で置換えられてきている。(Prior Art) Conventionally, fishing reel compositions have generally been aluminum die-cast products. However, in recent years, with the market demand for weight reduction, resin composition molded products have rapidly become popular, and most fishing reels have been replaced with resin compositions.
然し、かかる樹脂組成物は、アルミニウムダイキャスト
製品に比べて軽量である反面、色、光沢、艶等に見劣り
すると共に、表面硬度が低いため外表面に傷が付き易く
、耐候性が低いため、変色、劣化して、強度が弱くなっ
たり、その上外観の高級イメージにも欠けていた。そこ
で質感及び装飾的な外観の向上と樹脂材料の保護のため
、メタリック塗装を行ったり、樹脂に、アルミニラｌ、
粉、ニッケル粉、銅粉、マグネシウム粉等を分散させた
メタリック惑のある魚釣用リール構成部材も出回ってい
る。However, although such resin compositions are lighter than aluminum die-cast products, they are inferior in color, luster, luster, etc., and their outer surfaces are easily scratched due to their low surface hardness, and their weather resistance is low. They were discolored and deteriorated, becoming weaker and lacking in a high-class appearance. Therefore, in order to improve the texture and decorative appearance and protect the resin material, we applied metallic coating and added aluminum to the resin.
There are also fishing reel components on the market that have a metallic appearance, in which powder, nickel powder, copper powder, magnesium powder, etc. are dispersed.
しかし、リールの用途、環境及び成形条件、品質、要求
その他色々の条件変化に伴い樹脂のみでは強度が目標に
達せず、補強材として、例えばガラス繊維、炭素繊維を
入れたり、また耐候性向上のため、光安定剤、熱安定剤
などの添加剤を入れた魚釣用リール構成部材も出回って
いる。However, due to changes in the reel's use, environment, molding conditions, quality, demands, and other conditions, the strength cannot be achieved with resin alone, so reinforcing materials such as glass fiber and carbon fiber are added, and improvements in weather resistance are required. Therefore, fishing reel components containing additives such as light stabilizers and heat stabilizers are also on the market.
しかし乍ら、高級イメージ感を出すためメタリック塗装
を施したリール構成部材では、次の如き問題点があった
。成形後、表面研磨−脱脂一塗装−乾燥という多くの工
程を必要とし乾燥工程で高温処理するため、変形歪みが
発生し、寸法精度が悪く、高精度維持が難しい。又成形
後に塗装するため、塗膜の密着不良、硬度不良が発生し
易く、複雑な形状の場合は均一に塗装することが困難で
、塗装不良が発生し易く、かつ、色ムラが多い、このよ
うに工程数が多くなり製品コストがアップする。However, the reel components that are coated with metallic paint to give a high-class image have the following problems. After molding, many steps are required, including surface polishing, degreasing, painting, and drying, and the drying process involves high-temperature treatment, which causes deformation and distortion, poor dimensional accuracy, and makes it difficult to maintain high accuracy. In addition, since the coating is applied after molding, poor adhesion and hardness of the coating film are likely to occur, and in the case of complex shapes, it is difficult to coat uniformly, resulting in coating defects and color unevenness. As the number of steps increases, the product cost increases.
又、樹脂に金属粉（アルミニウム、ニッケル、銅、マグ
ネシウム）を添加したメタリック感のあるリール用構成
部材にあっては、金属粉による、亀裂、破損によりリー
ル本来の機械的強度の低下をきたし、そこで、またその
強度保持のためガラス繊維、炭素繊維を多量に使用しな
ければならなくなる。In addition, in the case of reel components with a metallic appearance that are made by adding metal powder (aluminum, nickel, copper, magnesium) to the resin, the mechanical strength of the reel may decrease due to cracks and breakage caused by the metal powder. Therefore, in order to maintain the strength, large amounts of glass fiber and carbon fiber must be used.
このように、樹脂に置換えたことにより軽量化されたも
のの、金属粉やガラス繊維、炭素繊維の併用で、重量増
となるばかりでなく工程も多くコスト面でも問題があっ
た。In this way, although the weight was reduced by replacing it with resin, the combined use of metal powder, glass fiber, and carbon fiber not only increased the weight but also caused problems in terms of cost due to the large number of steps.
（発明が解決しようとする課題）
本発明の目的は、きれいな外観を有し、触感も優れ、ま
た、寸法安定法、耐光性、及び耐久性に優れた魚釣用リ
ール構成部材を提供することにある。(Problems to be Solved by the Invention) An object of the present invention is to provide a fishing reel component that has a beautiful appearance, an excellent feel, and is excellent in dimensional stability, light resistance, and durability. It is in.
（課題を解決するための手段）
本発明者は、新しい炭素材料として、気相成長法炭素繊
維（以下、ＶＣＣＦと略称する）の特異な形態と化学的
、熱的安定性、耐光性に注目し各種の実用性試験を行っ
ていたところ、木ｖ ｃ ｃ Ｆの形状や凝集状態、他
の物質への分散状態に優れ、また、寸法安定性、耐候性
も向上し、劣化したり、変色することもなく、長期間強
度を保持する、リール用構成部材であることを見出し、
本発明に到達した。(Means for Solving the Problem) The present inventor has focused on the unique morphology, chemical and thermal stability, and light resistance of vapor grown carbon fiber (hereinafter abbreviated as VCCF) as a new carbon material. When conducting various practicality tests, it was found that the wood VCCF has excellent shape, agglomeration state, and dispersion state in other substances, and also has improved dimensional stability and weather resistance, and does not deteriorate or discolor. We discovered that it is a component for reels that maintains its strength for a long time without causing any damage.
We have arrived at the present invention.
即ち、本発明は、繊維径が０．０１〜５μｍのＶＣＣＦ
を５〜５０重量％含有する樹脂組成物で構成されている
ことを特徴とする、魚釣用リール組成物、である。That is, the present invention provides VCCF with a fiber diameter of 0.01 to 5 μm.
A fishing reel composition characterized in that it is composed of a resin composition containing 5 to 50% by weight of.
本発明で得られた魚釣用リール構成部材のＶＧＣＦの特
徴は黒色で、メタリック感のない高級イメージ感を有す
るものである。The VGCF of the fishing reel component obtained by the present invention is characterized by its black color and a high-class image without metallic appearance.
本発明において、ＶＣＣＦとは、炭化水素などの炭素源
を、触媒の存在下に加熱して気相成長させて作られる繊
維状の炭素質の物質、これを粉砕したり切断したりした
種々の形態の炭素質物質、あるいは、これらを加熱処理
した炭素質物質であり、本発明のＶＣＣＦは、電子顕微
鏡で観察すると、芯の部分と、これらを取巻く、−見し
て、年輪状の炭素層からなる特異な形状の繊維及びこれ
が粉砕、破砕、切断などの加工を受けたものである。In the present invention, VCCF is a fibrous carbonaceous material produced by heating a carbon source such as a hydrocarbon in the presence of a catalyst and growing it in a vapor phase, and various types of VCCF obtained by crushing or cutting this material. The VCCF of the present invention is a carbonaceous material in the form of a carbonaceous material or a carbonaceous material obtained by heat treatment of these materials, and when observed with an electron microscope, the VCCF of the present invention shows a core portion and a carbon layer surrounding them that looks like a tree ring. It is a uniquely shaped fiber consisting of fibers that has undergone processing such as crushing, crushing, and cutting.
本発明において、ＶＣＣＦは、直径が０．０１〜５μｍ
、好ましくは０．０１〜２μｍ、更に好ましくは０．０
１〜１μｍ、最も好ましくは０．０１〜０．５μｍであ
り、繊維の長さは特に制限はない。一般には５０００μ
ｍ以下であるが、更に短くても良く、１０００μｍや１
００μｍ、あるいは３．０μｍでも良く、又、これを更
に短く破砕や切断あるいは粉砕した繊維状物、あるいは
、粒状や不定形状の物も使用できる。In the present invention, the VCCF has a diameter of 0.01 to 5 μm.
, preferably 0.01 to 2 μm, more preferably 0.0
The fiber length is 1 to 1 μm, most preferably 0.01 to 0.5 μm, and there is no particular restriction on the length of the fiber. Generally 5000μ
m or less, but may be even shorter, such as 1000 μm or 1
The diameter may be 00 μm or 3.0 μm, and fibrous materials obtained by crushing, cutting, or pulverizing these into shorter lengths, or granular or irregularly shaped materials may also be used.
本発明のＶＣＣＦは、炭素の純度が高く、一般に９７．
５％以上、特に９８％以上、最も好ましくは９８．５％
以上である。The VCCF of the present invention has a high carbon purity, generally 97.
5% or more, especially 98% or more, most preferably 98.5%
That's all.
また、本発明において、ＶＣ，ＣＦは、易黒鉛化性の炭
素質物が好ましく、更に、その中でもＸ線解析による構
造解析において、その格子定数Ｃ８の７．１０〜６．８
８の範囲のものが特に好ましく、最も好ましくは７．０
６〜６．８９の範囲のものである。Further, in the present invention, VC and CF are preferably graphitizable carbonaceous materials, and among these, in the structural analysis by X-ray analysis, the lattice constant C8 is 7.10 to 6.8.
Particularly preferred are those in the range of 8, most preferably 7.0.
It is in the range of 6 to 6.89.
本発明において、樹脂とは熱可塑性樹脂および／または
熱硬化性樹脂を意味し、成形加工性、量産性から、熱可
塑性樹脂が好ましい。熱可塑性樹脂とは、常温では可塑
性を示さないが、適当な温度に加熱することにより可塑
性があられれる樹脂であり、例えばポリエチレン、ポリ
プロピレン、ポリスチレン、ポリーＰ−キシレン、ポリ
酢酸ビニル、ポリアクリレート、ポリメタクリレート、
ポリ塩化ビニル、ポリ塩化ビニリデン、フッ素含有プラ
スチック、ポリアクリロニトリル、ポリビニルエーテル
、ポリビニルケトン、ポリエーテル、ポリカーボネート
、熱可塑性ポリエステル、液晶ポリエステル、ポリビニ
ルケトン、ポリフェニレンサルファイド、ポリアミド、
ジエン系プラスチック、ポリウレタン系プラスチック等
があげられ好ましくは、ポリアミド、ポリカーボネート
類で特に好ましくはポリアミドである。In the present invention, resin means a thermoplastic resin and/or a thermosetting resin, and thermoplastic resins are preferred from the viewpoint of moldability and mass productivity. Thermoplastic resins are resins that do not exhibit plasticity at room temperature, but can be made plastic by heating to an appropriate temperature, such as polyethylene, polypropylene, polystyrene, poly-P-xylene, polyvinyl acetate, polyacrylate, and polyvinyl acetate. methacrylate,
Polyvinyl chloride, polyvinylidene chloride, fluorine-containing plastics, polyacrylonitrile, polyvinyl ether, polyvinyl ketone, polyether, polycarbonate, thermoplastic polyester, liquid crystal polyester, polyvinyl ketone, polyphenylene sulfide, polyamide,
Diene plastics, polyurethane plastics, etc. are preferred, and polyamides and polycarbonates are particularly preferred, with polyamide being particularly preferred.
熱硬化性樹脂とは、加熱することにより、架橋反応が進
み、三次元的な構造に変化し、熱可梨状態からついに不
溶、不融の状態に硬化する樹脂であり、例えば、フェノ
ール樹脂、フラン樹脂、キシレンホルムアルデヒド樹脂
、尿素樹脂、メラミン樹脂、アニリン樹脂、アルキド樹
脂、不飽和ポリエステル樹脂、エポキシ樹脂などがある
。A thermosetting resin is a resin that undergoes a crosslinking reaction when heated, changes to a three-dimensional structure, and finally hardens from a thermoplastic state to an insoluble and infusible state. For example, phenolic resin, Examples include furan resin, xylene formaldehyde resin, urea resin, melamine resin, aniline resin, alkyd resin, unsaturated polyester resin, and epoxy resin.
本発明の魚釣用リール構成部材はＶＧＣＦの組成割合が
５〜５０重量％、好ましくは１０〜４０重量％、特に好
ましくは５〜３５重量％である。In the fishing reel component of the present invention, the composition ratio of VGCF is 5 to 50% by weight, preferably 10 to 40% by weight, particularly preferably 5 to 35% by weight.
５重量％以下では強度が低く５０重量％以上では強度は
増加するが分散状態を良くするのに長時間要しコスト面
で不利であるし、樹脂溶融時の流動性が低下し、成形加
工性を損なう。If it is less than 5% by weight, the strength is low, and if it is more than 50% by weight, the strength increases, but it takes a long time to improve the dispersion state, which is disadvantageous in terms of cost, and the fluidity when melting the resin decreases, making it difficult to mold. damage.
本発明の魚釣用リール組成物は、結晶核剤、増粘剤、難
燃化剤、希釈剤、安定剤、酸化防止剤、滑剤、充填剤、
成形の際の金型からの離型性を良くするための添加剤等
、公知の種々の配合剤を含有していてもよい。The fishing reel composition of the present invention includes a crystal nucleating agent, a thickener, a flame retardant, a diluent, a stabilizer, an antioxidant, a lubricant, a filler,
It may contain various known compounding agents, such as additives for improving the releasability from the mold during molding.
本発明の魚釣用リール組成物を製造する場合、まづ、樹
脂と本ＶＣＣＦをブレンドして均一な分散を計る。ブレ
ンドの方法はトライブレンドしてもよく、また、湿式ブ
レンドでも、含浸ブレンドでもよく、特に限定されない
。When producing the fishing reel composition of the present invention, first, the resin and the present VCCF are blended to ensure uniform dispersion. The blending method may be tri-blending, wet blending, or impregnation blending, and is not particularly limited.
トライブレンドは、ヘンシェルミキサー等の撹拌機を用
い、撹拌時間及び回転数は樹脂粉末とＶＣＣＦが均一に
混合するように任意に設定される。Triblend uses a stirrer such as a Henschel mixer, and the stirring time and rotation speed are arbitrarily set so that the resin powder and VCCF are mixed uniformly.
この際、樹脂はｌ ｍｍ以下の粒径の粉末を使用するこ
とが有効である。また、湿式ブレンドは、まづ、撹拌可
能な容器中に、水、アルコール等の樹脂を溶解しない液
体を入れ、これにＶＣＣＦを投入して撹拌し、スラリー
状とする。次いでこのスラリーに所望の種類の樹脂粉末
を所定量投入し、さらに撹拌する。その後、このスラリ
ーを濾過して、乾燥する。さらに、含浸ブレンドは、予
め別々に溶媒に溶解した樹脂と、ＶＧＣＦとを混合、撹
拌した後、溶媒を除去乾燥する。熱可塑性樹脂の場合の
溶融混練は、バンバリーミキサ−、ニーダ−、ロールミ
ルおよびスクリュ一式押出機のごとき混練機を使用する
ことができる。このように、予めブレンドし得られた組
成物を溶融混練することによって均一に分散した魚釣用
リール組成物を得ることができる。At this time, it is effective to use resin powder with a particle size of 1 mm or less. In addition, in wet blending, first, a liquid that does not dissolve the resin, such as water or alcohol, is placed in a stirrable container, and VCCF is added thereto and stirred to form a slurry. Next, a predetermined amount of a desired type of resin powder is added to this slurry and further stirred. This slurry is then filtered and dried. Furthermore, the impregnated blend is prepared by mixing and stirring the resin and VGCF, which have been separately dissolved in a solvent in advance, and then removing the solvent and drying. For melt-kneading thermoplastic resins, a kneader such as a Banbury mixer, kneader, roll mill, or screw extruder can be used. As described above, by melt-kneading the pre-blended composition, a uniformly dispersed fishing reel composition can be obtained.
この溶融混練では、一旦ペレット状物にし、成形に供す
るのが一般的である。このようにして得られた組成物は
射出成形法により所望の大きさの脚、ギヤー収納部のカ
バ一部、スプールの取付は部、また押出成形法、カレン
ダー成形法などにより、シート状またはフィルム状の中
間製品に成形され、これを真空成形法などによって魚釣
用リール構成部剤として製造される。In this melt-kneading process, it is common to once form pellets and then use them for molding. The composition thus obtained can be molded into desired size legs, a part of the cover for the gear storage part, and a part to which the spool is attached by injection molding, and can be molded into a sheet or film by extrusion molding, calendar molding, etc. This intermediate product is then manufactured as a component of a fishing reel using a vacuum forming method or the like.
一方、熱硬化性樹脂を用いる場合は、ブレンドして得ら
れる組成物（ＶＣ，ＣＦ士熟熱硬化性樹脂を、圧縮成形
、真空成形などの方法によって所望の大きさを有する魚
釣用リール構成部材として製造される。On the other hand, when using a thermosetting resin, a composition obtained by blending (VC, CF) thermosetting resin is formed into a fishing reel having a desired size by compression molding, vacuum forming, etc. Manufactured as a component.
このようにして製造された魚釣用リール構成部材は黒色
の高級イメージの部材となる。また、■ＧＣＦは針状で
繊維径が０．０１〜５μｍと微小のため、ＰＡＮ−ＣＦ
やガラス繊維等の樹脂複合材の如く表面に突出して表面
粗度が荒くなり、手ざわり、汚れ等に悪影響を与えるこ
ともなくイメージとして高級感がある。又、成形後の熱
処理の必要もないので、寸法安定性、耐光性、耐久性に
も優れた魚釣用リール構成部材である。The fishing reel component manufactured in this manner is black and has a high-class image. In addition, ■GCF is needle-like and has a microscopic fiber diameter of 0.01 to 5 μm, so PAN-CF
It protrudes from the surface and has a rough surface like resin composite materials such as glass fiber and glass fiber, and it has a high-quality image without affecting the texture or dirt. Further, since there is no need for heat treatment after molding, the fishing reel component has excellent dimensional stability, light resistance, and durability.
（実施例）
以下実施例および比較例によって本発明をさらに詳しく
説明する。(Examples) The present invention will be explained in more detail below using Examples and Comparative Examples.
尚、実施例および比較例における各特性値は、下記の方
法又はＪＩＳ基準に従って測定した。In addition, each characteristic value in Examples and Comparative Examples was measured according to the following method or JIS standard.
引張り強度 、 ＪＩＳ Ｋ−６８１０曲げ強度 、
ＪＩＳ Ｋ−６８１０
曲げ弾性率 ； ＪＩＳ Ｋ−６８１０耐光性；ＪＩＳ
Ｋ−７１０２（装置−ＦＶ型照躬法−Ｂ−１法 ４８
時間照射）
表面粗度 ；表面性測定−万能表面形状測定器（ＳＥ−
３Ａ）
摩擦特性 ；■摩耗量；スラスト摩擦摩耗試験で動摩擦
係数を測定、相
手材料としては５４５Ｃ銅を用い、
全て無潤滑状態で、摩耗速度
６０ｃｍ／ｓｅｃ、面圧１．５ｋｇ１０ｆｆで連続運転
し、摩擦距離１０１ａｎに
達した時の摩擦係数を求め、
単位距離あたりの摩耗量を求
めた。Tensile strength, JIS K-6810 bending strength,
JIS K-6810 Flexural modulus; JIS K-6810 Light resistance; JIS
K-7102 (Apparatus - FV type verification method - B-1 method 48
Time irradiation) Surface roughness; Surface quality measurement - Universal surface profile measuring instrument (SE-
3A) Friction characteristics; ■Amount of wear; Dynamic friction coefficient was measured by thrust friction and wear test. 545C copper was used as the mating material, and all were operated continuously without lubrication at a wear rate of 60 cm/sec and a surface pressure of 1.5 kg/10 ff. The friction coefficient when the friction distance reached 101an was determined, and the amount of wear per unit distance was determined.
■ｐｖ値；摩擦速度３０ｃｍ／ｓｅｃを一定とし、荷重
を変化させて
２時間後、摩擦面を観察し測
定した。（尚、ここにいう
「限界ｐｖ値」とは、部材が一
定の荷重Ｐ （ｋｇ ／ Ｃ１１１）において、ある周
速度ｖ（ｃｎ＋／５ｅｃ）以上になった時、溶けたり、
焼付い
たりする負荷の限界ＰとＶとの
積を意味する。(2) pv value: The friction surface was observed and measured 2 hours after keeping the friction speed constant at 30 cm/sec and varying the load. (The "limit pv value" referred to here means that when a member reaches a certain peripheral speed v (cn+/5ec) or higher under a constant load P (kg/C111), it will melt,
It means the product of the load limit P and V that causes seizure.
外観・ ；北向きの窓際の自然光の中で、イメージ
肉眼により装飾的外観を４段階に判定した。Appearance: The decorative appearance was judged by the naked eye in natural light near a north-facing window.
実施例１
直径が０．０５〜０．１μｍのＶＣＣＦ （１−リスア
セチルアセトナト鉄とベンゼンを１４００°Ｃの加熱空
間に導入し浮遊状態で合成した、炭素含有９９％以上、
格子定数７．０２ ）を若干破砕し、分散操作がしやす
くした。又、繊維長は電子顕微鏡観察で、実質的に５μ
ｍ以上のＶＣＣＦを得た。Example 1 VCCF with a diameter of 0.05 to 0.1 μm (1-lithacetylacetonatoiron and benzene were introduced into a heating space at 1400°C and synthesized in a suspended state, containing 99% or more carbon,
The lattice constant (7.02) was slightly crushed to make dispersion easier. In addition, the fiber length was found to be approximately 5μ by electron microscopy observation.
A VCCF of m or more was obtained.
このＶＣＣＦを１５０ｇとポリアミド樹脂（レオナ、タ
イプ１３００Ｓ （旭化成工業■商晶名）を低温粉砕し
、平均粒径３０μｍに調整したちの８５０ｇとをヘンシ
ェルミキサーで、５分間混合し得られた組成物を池貝鉄
工■製のＭ２Ｏ型の二軸押出機でペレット化した。さら
にこのペレットを乾燥させた後、用ロ鉄工Ｑ＠製のＫＣ
−２０型の射出成形機で、射出温度２９０°Ｃ１金型温
度８５°Ｃで射出成形しテストピースを作成し各種物性
を測定した。その結果を表−１に示す。A composition obtained by mixing 150 g of this VCCF and 850 g of a polyamide resin (Leona, type 1300S (trade name: Asahi Kasei Industries), which was cold-pulverized and adjusted to an average particle size of 30 μm, in a Henschel mixer for 5 minutes. was pelletized using an M2O type twin-screw extruder manufactured by Ikegai Tekko ■.Furthermore, after drying the pellets, the KC manufactured by Yoro Tekko Q@
A test piece was prepared by injection molding using a -20 type injection molding machine at an injection temperature of 290° C. and a mold temperature of 85° C., and various physical properties were measured. The results are shown in Table-1.
実施例２
ＶＧＣＦを２５０ ｇ、ポリアミド樹脂７５０ｇと配合
量を変えた以外は実施例１と同様の方法でテストピース
を作成し物性評価し、その結果を表−１に示す。Example 2 A test piece was prepared in the same manner as in Example 1 except that the blended amounts were changed to 250 g of VGCF and 750 g of polyamide resin, and the physical properties were evaluated. The results are shown in Table 1.
実施例３
ＶＣＣＦを３３０ｇと、ポリアミド樹脂６７０ｇと配合
量を変えた以外は実施例１と同様の方法でテストピース
を作成し物性を評価した。その結果を表−１に示す。Example 3 A test piece was prepared in the same manner as in Example 1, except that the blended amounts were changed to 330 g of VCCF and 670 g of polyamide resin, and the physical properties were evaluated. The results are shown in Table-1.
比較例１
ポリアミド樹脂（実施例１で使用したレオナタイプ１３
００Ｓ）のみを実施例１の方法でテストピースを作成し
評価した。その結果を表−１に示す。Comparative Example 1 Polyamide resin (Leonatype 13 used in Example 1)
A test piece was prepared and evaluated using the method of Example 1. The results are shown in Table-1.
比較例２
ガラスファイバー（繊維径９μｍ、繊維長３ｍｍ）を３
３０ｇ、ポリアミド樹脂を６７０ｇの配合量で実施例１
の方法でテストピースを作成し評価した。その結果を表
−１に示す。Comparative Example 2 Three glass fibers (fiber diameter 9 μm, fiber length 3 mm)
Example 1 with a blending amount of 30g and 670g of polyamide resin.
A test piece was created and evaluated using the following method. The results are shown in Table-1.
比較例３
アクリル繊維を焼成して得られたＰＡＮ−ＣＦ（旭化成
カーボンファイバー製）のチョプドストランド（３ｍｍ
ｃｕｔ）を３３０ｇ、ポリアミド樹脂を６７０ｇの配合
量で実施例１の方法でテストピースを作成し評価した。Comparative Example 3 Chopped strands (3 mm) of PAN-CF (manufactured by Asahi Kasei Carbon Fiber) obtained by firing acrylic fibers.
A test piece was prepared and evaluated using the method of Example 1 using 330 g of polyamide resin (cut) and 670 g of polyamide resin.
その結果を表−１に示す。The results are shown in Table-1.
以下 余白
（発明の効果）
本発明の魚釣用リール組成物は、合成樹脂との成形が容
易であり且つ軽量化ができ、補強効果も他の補強材を添
加することなく、ＶＣＣＦ単独で可能となり、耐光性、
耐熱性の向上のための表面メッキや、金属粉添加混合な
どの必要もなくコスト面でも有利であり、魚釣用リール
として最適の素材である。Below Margin (Effects of the Invention) The fishing reel composition of the present invention can be easily molded with synthetic resin and can be lightweight, and the reinforcing effect can be achieved by using VCCF alone without adding other reinforcing materials. Therefore, light resistance,
It is advantageous in terms of cost since there is no need for surface plating or mixing with metal powder to improve heat resistance, making it the ideal material for fishing reels.
尚、本発明の構成素材を用いて作られた魚釣用リールは
、外観がきれいで高級感を与え、触感もよく、また寸法
安定性、耐光性、及び耐久性（変色、強度等）にも優れ
たものである。Furthermore, fishing reels made using the constituent materials of the present invention have a beautiful appearance, give a sense of luxury, have a good feel, and have good dimensional stability, light resistance, and durability (discoloration, strength, etc.). is also excellent.
特許出願人 旭化成工業株式会社 代 理 人 弁理士 液通 −雄 ＝ １６−Patent applicant: Asahi Kasei Industries, Ltd. Representative Patent Attorney Yutsutsu = 16-
Claims (1)
５０重量％含有する樹脂組成物で構成されていることを
特徴とする魚釣用リール組成物。5 to 5 vapor grown carbon fibers with a fiber diameter of 0.01 to 5 μm
A fishing reel composition comprising a resin composition containing 50% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1118559A JPH02299530A (en) | 1989-05-15 | 1989-05-15 | Reel composition for fishing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1118559A JPH02299530A (en) | 1989-05-15 | 1989-05-15 | Reel composition for fishing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02299530A true JPH02299530A (en) | 1990-12-11 |
Family
ID=14739590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1118559A Pending JPH02299530A (en) | 1989-05-15 | 1989-05-15 | Reel composition for fishing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02299530A (en) |
-
1989
- 1989-05-15 JP JP1118559A patent/JPH02299530A/en active Pending
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