JPH02299528A - Construction material for fishing reel - Google Patents
Construction material for fishing reelInfo
- Publication number
- JPH02299528A JPH02299528A JP1118552A JP11855289A JPH02299528A JP H02299528 A JPH02299528 A JP H02299528A JP 1118552 A JP1118552 A JP 1118552A JP 11855289 A JP11855289 A JP 11855289A JP H02299528 A JPH02299528 A JP H02299528A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- fishing reel
- vgcf
- carbon fiber
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004035 construction material Substances 0.000 title abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 23
- 239000000470 constituent Substances 0.000 claims description 15
- 239000002134 carbon nanofiber Substances 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 abstract description 25
- 239000011347 resin Substances 0.000 abstract description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 6
- 239000004917 carbon fiber Substances 0.000 abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 5
- 229920005992 thermoplastic resin Polymers 0.000 abstract description 4
- 239000012808 vapor phase Substances 0.000 abstract description 3
- 239000011357 graphitized carbon fiber Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003365 glass fiber Substances 0.000 description 5
- 229920006122 polyamide resin Polymers 0.000 description 5
- -1 that is Substances 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000007666 vacuum forming Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 101100326920 Caenorhabditis elegans ctl-1 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920006065 Leona® Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、魚釣用リール構成素材に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to fishing reel constituent materials.
（従来の技術）
従来、魚釣用リール構成素材は、アルミニウムダイキャ
スト製品が一般的であった。しかし、最近は、軽量化の
市場要求に応じ、樹脂組成物成形−品が急速に普及し、
魚釣用リールの大半が樹脂組成物で置換えられてきてい
る。(Prior Art) Conventionally, fishing reel constituent materials have generally been aluminum die-cast products. However, in recent years, resin composition molded products have rapidly become popular in response to market demands for weight reduction.
Most fishing reels have been replaced with resin compositions.
然し、かかる樹脂組成物は、アルミニウムダイキャスト
製品に比べて軽量である反面、色、光沢、艶等に見劣り
すると共に、表面硬度が低いため、外表面に傷が付き易
い上に、耐候性が悪く、変色、劣化して、強度が弱くな
ったり、その上、外観の高級イメージにも欠けていた。However, although such resin compositions are lighter than aluminum die-cast products, they are inferior in color, luster, luster, etc., and their surface hardness is low, so the outer surface is easily scratched and their weather resistance is poor. It was bad, discolored, deteriorated, and weakened, and what's more, it lacked a high-class appearance.
そこで、質感及び装飾的な外観の向上と樹脂材料の保護
のため、メタリック塗装を行ったり、樹脂に、アルミニ
ウム粉、ニッケル粉、銅粉、マグネシウム粉等を分散さ
せたメタリック感のある魚釣用リール構成素材も出回っ
ている。Therefore, in order to improve the texture and decorative appearance and protect the resin material, we applied metallic coating or used resin with aluminum powder, nickel powder, copper powder, magnesium powder, etc. dispersed in it. Reel construction materials are also available.
しかし、リールの用途、環境及び成形条件、品質、要求
その他色々の条件変化に伴い樹脂のみでは強度が目標に
達せず、補強材として、例えばガラス繊維、炭素繊維を
入れたり、また耐候性向上のため、光安定剤、熱安定剤
などの添加剤を入れた魚釣用リール構成素材も出回って
いる。However, due to changes in the reel's use, environment, molding conditions, quality, demands, and other conditions, the strength cannot be achieved with resin alone, so reinforcing materials such as glass fiber and carbon fiber are added, and improvements in weather resistance are required. Therefore, fishing reel construction materials containing additives such as light stabilizers and heat stabilizers are also on the market.
しかし乍ら、高級イメージを出すためメタリック塗装を
施したリール構成素材では、次の如き問題点があった。However, the reel construction material, which is coated with metallic paint to give it a high-class image, has the following problems.
成形後、表面研磨−脱脂−塗装−乾燥という多くの工程
を必要とし乾燥工程で高温処理するため、変形歪みが発
生し、寸法精度が悪く、高精度維持が難しい。又、成形
後に塗装するため、塗膜の密着不良、硬度不良が発生し
易く、複雑な形状の場合は均一に塗装することが困難で
、塗装不良が発生し易く、かっ、色ムラが多い。このよ
うに工程数が多くなり製品コストがアップする。After molding, many steps are required: surface polishing, degreasing, painting, and drying, and the drying process involves high temperature treatment, which causes deformation and distortion, poor dimensional accuracy, and difficulty in maintaining high accuracy. In addition, since the coating is applied after molding, poor adhesion and hardness of the coating film are likely to occur, and in the case of complex shapes, it is difficult to coat uniformly, and coating defects are likely to occur, causing a lot of scratches and uneven coloring. In this way, the number of steps increases and the product cost increases.
又、樹脂に金属粉（アルミニウム、ニッケル、銅、マグ
ネシウム）を添加したメタリック感のあるリール用構成
素材にあっては、金属粉による、亀裂、破損によりリー
ル本来の機械的強度の低下をきたし、そこで、また強度
保持のためガラス繊維、炭素繊維を多量に使用しなけれ
ばならなくなる。このように、樹脂に置換えられたこと
より軽量化されたものの、金属粉やガラス繊維、炭素繊
維の併用で、重量増となるばかりでなく工程も多くコス
ト面でも問題があった。In addition, in the case of reel constituent materials with a metallic feel that are made by adding metal powder (aluminum, nickel, copper, magnesium) to resin, the original mechanical strength of the reel may decrease due to cracks and breakage due to the metal powder. Therefore, large amounts of glass fiber and carbon fiber must be used to maintain strength. Although the weight was reduced by replacing the resin with resin, the combined use of metal powder, glass fiber, and carbon fiber not only increased the weight but also caused problems in terms of cost due to the large number of steps.
（発明が解決しようとする課題）
本発明の目的は、きれいな外観を有し、触感にも優れ、
また、寸法安定性、耐光性、耐久性に優れた魚釣用リー
ル構成素材を提供することにある。(Problems to be Solved by the Invention) An object of the present invention is to have a beautiful appearance, excellent tactile sensation,
Another object of the present invention is to provide a fishing reel constituent material that has excellent dimensional stability, light resistance, and durability.
（課題を解決するための手段）
本発明は、新しい炭素材料として、気相成長法炭素繊維
の黒鉛化物（以下、ＶＧＣＦ−Ｇと略称する）の特異な
形態と化学的、熱的安定性、耐光性に注目し、各種の実
用性試験を行っていたところ、木ＶＧＣＦ−Ｇの形状や
凝集状態、他の物質への分散状態に優れ、また寸法安定
性、耐候性が良く、劣化したり、変色することなく、長
期間強度を保持することのできるリール用構成素材であ
ることを見出し、本発明に到達した。(Means for Solving the Problems) The present invention provides, as a new carbon material, a graphitized product of vapor grown carbon fiber (hereinafter abbreviated as VGCF-G), which has a unique morphology, chemical and thermal stability, When we conducted various practical tests focusing on light resistance, we found that wood VGCF-G has excellent shape, agglomeration state, and dispersion state in other substances, and also has good dimensional stability and weather resistance, and does not deteriorate. They discovered that this is a constituent material for a reel that can maintain its strength for a long period of time without discoloring, and have arrived at the present invention.
即ち、本発明は、繊維径が０．０１〜５μｍのｖｃｃｐ
−Ｇを５〜５０重量％含有する樹脂組成物で構成されて
いることを特徴とする魚釣用リール構成素材である。That is, the present invention provides vccp with a fiber diameter of 0.01 to 5 μm.
This is a fishing reel constituent material characterized by being composed of a resin composition containing 5 to 50% by weight of -G.
本発明で得られた魚釣用リール構成素材のＶＧＣＦ−Ｇ
の特徴は黒色でメタリック感のない、高級イメージ感を
有するものである。VGCF-G of fishing reel constituent material obtained by the present invention
It is characterized by its black color and no metallic feel, giving it a high-class image.
本発明において、ＶＧＣＦ−Ｇとは、炭化水素などの炭
素源を触媒存在下に加熱し気相成長させて作られる繊維
状の炭素質物質すなわち気相成長法炭素繊維に、黒鉛化
熱処理を行って得られる繊維状およびこれを粉砕したり
切断したりした種々の形態の黒鉛質物質であり、その繊
維を電子顕微鏡で観察すると、芯の部分と、これを取巻
く、−見して、年輪状の炭素層からなる特異な形状を有
しておるものである。In the present invention, VGCF-G is a fibrous carbonaceous material made by heating a carbon source such as a hydrocarbon in the presence of a catalyst and growing it in a vapor phase, that is, vapor-grown carbon fiber, which is subjected to graphitization heat treatment. It is a graphite material in the form of fibers obtained by pulverizing or cutting the fibers, and when the fibers are observed with an electron microscope, the core and the surrounding parts - looking like tree rings - can be seen. It has a unique shape consisting of carbon layers.
本発明で用いられるＶＧＣＦ−Ｇは、直径が０．０１〜
５μｍ、好ましくは０．０１〜２μｍ、更に好ましくは
０．０１〜１μｍ１最も好ましくは０．０１〜０．５μ
ｍであり、繊維の長さは特に制限はない。一般には、５
０００μｍ以下であるが、更に短くても良く、１０００
μｍや１００μｍ、あるいは１．０μｍでも良く、又、
これを更に短く破砕や切断あるいは粉砕した繊維状物、
あるいは、粒状や不定形状の物も使用できる。The VGCF-G used in the present invention has a diameter of 0.01 to
5 μm, preferably 0.01-2 μm, more preferably 0.01-1 μm, most preferably 0.01-0.5 μm
m, and the length of the fiber is not particularly limited. In general, 5
000 μm or less, but may be even shorter, 1000 μm or less
It may be μm, 100 μm, or 1.0 μm, or
Fibrous materials that are further crushed, cut, or crushed into shorter lengths,
Alternatively, granular or irregularly shaped materials can also be used.
本発明で用いられるＶＧＣＦ−Ｇは、炭素の純度が高く
、一般に９８゜５％以上、特に９９％以上、最も好まし
くは９９．５％以上である。The VGCF-G used in the present invention has a high carbon purity, generally 98.5% or more, particularly 99% or more, and most preferably 99.5% or more.
また、本発明で用いられるＶＧＣＦ−Ｇは黒鉛性の高い
物質であり、更に、その中でもＸ線解析による構造解析
において、その黒鉛の結晶構造においての格子定数Ｃｏ
が６．８８以下の範囲のものであり、好ましくは、６．
８６以下、特に好ましくは６．８０〜６．７０の範囲、
最も好ましくは６．７８〜６．７２の範囲のものである
。In addition, VGCF-G used in the present invention is a highly graphitic substance, and furthermore, in the structural analysis by X-ray analysis, the lattice constant Co in the graphite crystal structure is
is in the range of 6.88 or less, preferably 6.
86 or less, particularly preferably in the range of 6.80 to 6.70,
The most preferred range is 6.78 to 6.72.
本発明で用いられるＶＧＣＩ？−Ｇは気相成長法炭素繊
維を高温度において熱処理する事により得られるが、熱
処理温度としては１５００°Ｃ以上、好ましくは１７０
０°Ｃ以上、特に２０００°Ｃ以上であり、最も好まし
い範囲は２１００〜３０００°Ｃの範囲である。VGCI used in the present invention? -G can be obtained by heat-treating vapor grown carbon fiber at high temperature, and the heat treatment temperature is 1500°C or higher, preferably 170°C or higher.
The temperature is 0°C or higher, particularly 2000°C or higher, and the most preferred range is 2100 to 3000°C.
本発明において、樹脂とは熱可塑性樹脂および／または
熱硬化性樹脂を意味し、成形加工性、量産性から、熱可
塑性樹脂が好ましい。熱可塑性樹脂とは、常温では可塑
性を示さないが、適当な温度に加熱することにより可塑
性があられれる樹脂であり、例えばポリエチレン、ポリ
プロピレン、ポリスチレン、ポリ−ｐ−キシレン、ポリ
酢酸ビニル、ポリアクリレート、ポリメタクリレ−１・
、ポリ塩化ビニール、ポリ塩化ビニリデン、フッ素含有
プラスチック、ポリアクリロニトリル、ポリビニルエー
テル、ポリビニルケトン、ポリエーテル、ポリカーポー
ト、熱可塑性ポリエステル、液晶ポリエステル、ポリエ
ーテルケトン、ポリフェニレンサルファイド、ポリアミ
ド、ジエン系プラスチック、ポリウレタン系プラスチッ
ク等があげられ好ましくは、ポリアミド、ポリカーボネ
ート類で特に好ましくはポリアミドである。In the present invention, resin means a thermoplastic resin and/or a thermosetting resin, and thermoplastic resins are preferred from the viewpoint of moldability and mass productivity. Thermoplastic resins are resins that do not exhibit plasticity at room temperature, but can be made plastic by heating to an appropriate temperature, such as polyethylene, polypropylene, polystyrene, poly-p-xylene, polyvinyl acetate, polyacrylate, Polymethacrylate-1・
, polyvinyl chloride, polyvinylidene chloride, fluorine-containing plastics, polyacrylonitrile, polyvinyl ether, polyvinyl ketone, polyether, polycarport, thermoplastic polyester, liquid crystal polyester, polyether ketone, polyphenylene sulfide, polyamide, diene plastic, polyurethane Examples include plastics, and preferred are polyamides and polycarbonates, with polyamide being particularly preferred.
熱硬化性樹脂とは、加熱することにより、架橋反応が進
み、三次元的な構造に変化し、熱可塑状態からついに不
溶、不融の状態に硬化する樹脂であり、例えば、フェノ
ール樹脂、フラン樹脂、キシレンホルムアルデヒド樹脂
、尿素樹脂、メラミン樹脂、アニリン樹脂、アルキド樹
脂、不飽和ポリエステル樹脂、エポキシ樹脂などがある
。A thermosetting resin is a resin that undergoes a crosslinking reaction when heated, changes to a three-dimensional structure, and finally hardens from a thermoplastic state to an insoluble or infusible state.For example, phenolic resin, furan resin, etc. resins, xylene formaldehyde resins, urea resins, melamine resins, aniline resins, alkyd resins, unsaturated polyester resins, epoxy resins, etc.
本発明の魚釣用リール構成素材はＶＧＣＦ−Ｇの組成割
合が５〜５０重量％、好ましくは、１０〜４０重量％、
特に好ましくは１５〜３５重量％である。The fishing reel constituent material of the present invention has a composition ratio of VGCF-G of 5 to 50% by weight, preferably 10 to 40% by weight,
Particularly preferably 15 to 35% by weight.
５重量％以下では強度が低く、５０重量％以上では強度
は増加するが分散状態を良くするのに長時間要しコスト
面で不利であるし、樹脂溶融時の流動性が低下し、成形
加工性を損なう。If it is less than 5% by weight, the strength will be low, and if it is more than 50% by weight, the strength will increase, but it will take a long time to improve the dispersion state, which is disadvantageous in terms of cost, and the fluidity when melting the resin will decrease, making it difficult to mold. detract from sexuality.
本発明の魚釣用リール構成素材は、結晶核剤、増粘剤、
難燃化剤、希釈剤、安定剤、酸化防止剤、滑剤、充填剤
、成形の際の金型からの離型性を良くするための添加剤
等、公知の種々の配合剤を含有していてもよい。The fishing reel constituent material of the present invention includes a crystal nucleating agent, a thickener,
Contains various known compounding agents such as flame retardants, diluents, stabilizers, antioxidants, lubricants, fillers, and additives to improve release from molds during molding. It's okay.
本発明の魚釣用リール構成素材を製造する場合、まず樹
脂と本ＶＧＣＦ−Ｇをブレンドして均一な分散を計る。When manufacturing the fishing reel constituent material of the present invention, first the resin and the present VGCF-G are blended to ensure uniform dispersion.
ブレンド方法はトライブレンドしてもよく、また湿式ブ
レンドでも、含浸ブレンドでもよい。トライブレンドは
ヘンシェルミキサー等の撹拌機を用い撹拌時間及び回転
数は樹脂粉末とＶＧＣＦ−Ｇが均一に混合するように任
意に設定される。この際、該樹脂の１ ｍｍ以下の粒径
を有する粉末を使用することが有効である。また、湿式
ブレンドは、まず、撹拌可能な容器中に、水、アルコー
ル等の樹脂を溶解しない液体を入れ、これにＶＧＣＦ−
Ｇを投入して撹拌し、スラリー状とする。次いでこのス
ラリーに所望の種類の樹脂粉末を所定量投入し、さらに
撹拌する。その後、このスラリーを濾過して、乾燥する
。さらに、含浸ブレンドは、予め別々に溶媒に溶解した
樹脂とＶＧＣＦ−Ｇとを混合、撹拌した後、溶媒を除去
、乾燥する。溶融混練はバンバリーミキサ−、ニーダ−
、ロールミルおよびスクリュ一式押出機のごとき混練機
を使用することができる。The blending method may be tri-blending, wet blending, or impregnation blending. For the triblend, a stirrer such as a Henschel mixer is used, and the stirring time and rotation speed are arbitrarily set so that the resin powder and VGCF-G are mixed uniformly. At this time, it is effective to use a powder of the resin having a particle size of 1 mm or less. In addition, in wet blending, first, a liquid that does not dissolve the resin, such as water or alcohol, is placed in a stirrable container, and then VGCF-
Add G and stir to form a slurry. Next, a predetermined amount of a desired type of resin powder is added to this slurry and further stirred. This slurry is then filtered and dried. Furthermore, the impregnated blend is prepared by mixing and stirring the resin and VGCF-G, which have been separately dissolved in a solvent in advance, and then removing the solvent and drying. Banbury mixer and kneader are used for melting and kneading.
Kneading machines such as , roll mills and single screw extruders can be used.
このように、予めブレンドし得られた組成物を溶融混練
することによって均一に分散した魚釣用リール構成素材
を得ることができる。By melt-kneading the pre-blended composition in this manner, a uniformly dispersed fishing reel constituent material can be obtained.
この溶融混練では、一旦、ペレット状物にし、成形に供
するのが一般的である。このようにして得られた組成物
は射出成形法により所望の大きさの脚、ギヤー収納部の
カバ一部、スプールの取付は部、また押出成形法、カレ
ンダー成形法などにより、シート状またはフィルム状の
中間製品に成形され、これを真空成形法などによって魚
釣用リール構成素材として製造される。In this melt-kneading process, it is common to once form pellets and then use them for molding. The composition thus obtained can be molded into desired size legs, a part of the cover for the gear storage part, and a part to which the spool is attached by injection molding, and can be molded into a sheet or film by extrusion molding, calendar molding, etc. This intermediate product is then manufactured as a fishing reel component using a vacuum forming method or the like.
一方、熱硬化性樹脂を用いる場合は、ブレンドして得ら
れる組成物（ＶＧＣＦ−Ｇ＋熱硬化性樹脂）を、圧縮成
形、真空成形などの方法によって所望の大きさの魚釣用
リール構成素材として製造される。On the other hand, when using a thermosetting resin, the composition obtained by blending (VGCF-G + thermosetting resin) is made into a fishing reel constituent material of the desired size by compression molding, vacuum forming, etc. Manufactured.
このようにして製造された魚釣用リール構成素材は黒色
の高級イメージの部材となる。また、ＶＧＣＦ−Ｇは針
状で繊維径が０．０１〜５μｍと微小のため、ＰＡＮ−
ＣＰガラス繊維等の樹脂複合材の如く表面に突出して表
面粗度が荒くなり、手ざわり、汚れ等に悪影響を与える
ことがなくイメージとして高級感がある。又、成形後の
熱処理も必要ないので寸法安定性、耐光性、耐久性にも
優れた魚釣用リール構成素材である。The fishing reel constituent material manufactured in this manner becomes a member with a black color and a high-class image. In addition, since VGCF-G is needle-like and has a minute fiber diameter of 0.01 to 5 μm, PAN-G
Like resin composite materials such as CP glass fibers, it protrudes from the surface and has a rough surface, giving it a high-quality image without adversely affecting the texture or dirt. Furthermore, since no heat treatment is required after molding, the material is excellent in dimensional stability, light resistance, and durability.
（実施例）
以下、実施例および比較例によって本発明をさらに詳し
く説明する。(Examples) Hereinafter, the present invention will be explained in more detail with reference to Examples and Comparative Examples.
尚、実施例および比較例における各特性値は、下記の方
法又はＪＩＳ基準に従って測定した。In addition, each characteristic value in Examples and Comparative Examples was measured according to the following method or JIS standard.
引張り強度、 ＪＩＳ Ｋ−６８１０
曲げ強度 ； ＪＩＳ Ｋ−６８１０
曲げ弾性率、 ＪＩＳ Ｋ−６８１０
耐光性、 ＪＩＳ Ｋ−７１０２（装置−ＦＶ形、照射
法＝Ｂ−１法４８時間照射）
表面粗度；表面性測定−万能表面形状測定器（ＳＥ−３
Ａ）
摩擦特性；
■摩耗量；鈴本式摩耗試験で動摩擦係数を測定、相手材
料としては５４５Ｃ鋼を用い、全て無潤滑状態で、摩耗
速度３０■／ｓｅｃ、荷重１０ｋｇ ／ ｃＴｆｌで連
続運転し、摩擦距離１０ｋｍに達した時の摩擦係数を求
め、単位距離あたりの摩耗量を求めた。Tensile strength, JIS K-6810 Bending strength; JIS K-6810 Bending modulus, JIS K-6810 Light resistance, JIS K-7102 (Apparatus - FV type, irradiation method = B-1 method 48 hour irradiation) Surface roughness; Surface property measurement - Universal surface profile measuring instrument (SE-3
A) Friction characteristics; ■Amount of wear: The coefficient of dynamic friction was measured using the Suzumoto type wear test. 545C steel was used as the mating material, and all were operated continuously at a wear rate of 30 cm/sec and a load of 10 kg/cTfl without lubrication. The friction coefficient when the friction distance reached 10 km was determined, and the amount of wear per unit distance was determined.
■ｐｖ値；摩擦速度３０ｃｍ／ｓｅｃを一定とし、荷重
を変化させて２時間後、摩擦面を観察し測定した。（尚
、ここにいう「限界Ｐｖ値」とは、部材が一定の荷重Ｐ
（ｋｇ／ＣＴｌ１））において、ある周速度Ｖ（ｃｍ／
５ｅｃ）以上になった時、溶けたり、焼付いたりする負
荷の限界ＰとＶとの積を意味する。(2) pv value: The friction surface was observed and measured 2 hours after keeping the friction speed constant at 30 cm/sec and varying the load. (The "limit Pv value" referred to here means that the member is under a certain load P
(kg/CTl1)), at a certain circumferential speed V (cm/
5ec) or more, it means the product of the limit P and V of the load that melts or seizes.
外観・イメージ；北向き窓際の自然光の中で肉眼により
装飾的外観を４段階に判定した。Appearance/Image: The decorative appearance was judged on a four-level scale by the naked eye in natural light near a north-facing window.
実施例１
直径が０．０５〜０．１μｍの気相成長法炭素繊維（ト
リスアセチルアセトナト鉄とベンゼンを１４００°Ｃの
加熱空間に導入して浮遊状態で合成した）を２４００°
Ｃのアルゴン気流化で熱処理を行い炭素含有量９９％、
格子定数６．７４の黒鉛化物を得、これを若干破砕し、
分散操作がし易くした。又、繊維長は電子顕微鏡で観察
し、実質的に５．０μｍ以上のＶＧＣＦ−Ｇを得た。Example 1 Vapor-grown carbon fibers with a diameter of 0.05 to 0.1 μm (synthesized in a floating state by introducing trisacetylacetonate iron and benzene into a heating space at 1400°C) were grown at 2400°C.
Carbon content is 99% by heat treatment with argon gasification of C.
A graphitized material with a lattice constant of 6.74 was obtained, which was slightly crushed,
Made distributed operations easier. Further, the fiber length was observed using an electron microscope, and VGCF-G having a length of substantially 5.0 μm or more was obtained.
このＶＧＣＦ−Ｇを１５０ｇとポリアミド樹脂（レオナ
、タイプ１３００Ｓ （旭化成工業（Ｊ＠（商品名）
）を低温粉砕し、平均粒径３０μｍに調整したもの８５
０ｇとをヘンシェルミキサーで、５分間混合し得られた
組成物を池貝鉄工■製のＰＣＭ−３０型二軸押出機でペ
レット化した。さらにこのペレットを乾燥させた後、川
口鉄工（Ｉｌ製のＫＣ−２０型の射出成形機で、射出温
度２９０°Ｃ１金型温度８５°Ｃで射出成形しテストピ
ースを作成し各種物性を測定した。150g of this VGCF-G and polyamide resin (Leona, type 1300S (Asahi Kasei Corporation (J@ (product name))
) was cryogenically ground and adjusted to an average particle size of 30 μm85
0 g for 5 minutes using a Henschel mixer, and the resulting composition was pelletized using a PCM-30 type twin screw extruder manufactured by Ikegai Iron Works. After drying the pellets, the pellets were injection molded using a KC-20 injection molding machine manufactured by Kawaguchi Iron Works (Il) at an injection temperature of 290°C and a mold temperature of 85°C to create test pieces and measure various physical properties. .
その結果を表−１に示す。The results are shown in Table-1.
実施例２
ＶＧＣＦ−Ｇを２５０ｇ、ポリアミド射出７５０ｇと配
合量を変えた以外は実施例１と同様の方法でテストピー
スを作成し物性を評価した。その結果を表−１に示す。Example 2 A test piece was prepared in the same manner as in Example 1, except that the blending amounts were changed to 250 g of VGCF-G and 750 g of polyamide injection, and the physical properties were evaluated. The results are shown in Table-1.
実施例３
ＶＧＣＦ−Ｇを３３０ｇ、ポリアミド樹脂６７０ｇと配
合量を変えた以外は実施例１と同様の方法でテストピー
スを作成し物性を評価した。その結果を表−１に示す。Example 3 A test piece was prepared in the same manner as in Example 1, except that the blending amounts were changed to 330 g of VGCF-G and 670 g of polyamide resin, and the physical properties were evaluated. The results are shown in Table-1.
比較例１
ポリアミド樹脂（実施例１で使用したレオナタイプ１３
００Ｓ）のみを実施例１の方法でテストピースを作成し
評価した。その結果を表−１に示す。Comparative Example 1 Polyamide resin (Leonatype 13 used in Example 1)
A test piece was prepared and evaluated using the method of Example 1. The results are shown in Table-1.
比較例２
ガラスファイバー（繊維径９μｍ、繊維長３論）を３３
０ｇ、ポリアミド樹脂を６７０ｇの配合量で実施例１の
方法でテストピースを作成し評価した。その結果を表−
１に示す。Comparative Example 2 Glass fiber (fiber diameter 9 μm, fiber length 3)
A test piece was prepared and evaluated using the method of Example 1 with a blending amount of 0g and 670g of polyamide resin. Table the results.
Shown in 1.
比較例３
アクリル繊維を焼成して得られたＰＡＮ−ＣＦ （旭化
成カーボンファイバー■製）のチョツプドストランド（
３ｍｍｃｕｔ）を３３０ｇ、ポリアミド樹脂を６７０ｇ
の配合量で実施例１の方法でテストピースを作成し評価
した。その結果を表−１に示す。Comparative Example 3 Chopped strands of PAN-CF (manufactured by Asahi Kasei Carbon Fiber ■) obtained by firing acrylic fibers (
330g of 3mm cut), 670g of polyamide resin
A test piece was prepared and evaluated using the method of Example 1 with the amount of the following. The results are shown in Table-1.
以下余白
（発明の効果）
本発明のリール構成素材は、合成樹脂との成形が容易で
あり、且つ、軽量化ができ、補強効果も他の補強材を添
加することなく、 ＶＧＣＦ−Ｇ単独で可能となり、耐
光性、耐熱性向上のための表面メッキや金属粉添加混合
などの必要もなく、コスト・面でも有利であり、魚釣用
リールとして最適の素材である。Blank space below (effects of the invention) The reel component material of the present invention is easy to mold with synthetic resin, can be lightweight, and has a reinforcing effect that can be achieved by using VGCF-G alone without adding other reinforcing materials. There is no need for surface plating or addition of metal powder to improve light resistance and heat resistance, and it is advantageous in terms of cost and production, making it the ideal material for fishing reels.
尚、本発明の構成素材を用いて作られた魚釣用リールは
、外観がきれいで高級感を与え、触感もよく、また寸法
安定性、耐光性、及び耐久性（変色、強度等）にも優れ
たたものである。Furthermore, fishing reels made using the constituent materials of the present invention have a beautiful appearance, give a sense of luxury, have a good feel, and have good dimensional stability, light resistance, and durability (discoloration, strength, etc.). is also excellent.
特許出願人 旭化成工業株式会社 代理人 弁理士 渡 辺 −雄 ＝１６一Patent applicant: Asahi Kasei Industries, Ltd. Agent: Patent Attorney Watanabe - Yu =16 one
Claims (1)
化物を５〜５０重量％含有する樹脂組成物で構成されて
いることを特徴とする魚釣用リール構成素材A fishing reel constituent material comprising a resin composition containing 5 to 50% by weight of graphitized vapor grown carbon fibers having a fiber diameter of 0.01 to 5 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1118552A JPH02299528A (en) | 1989-05-15 | 1989-05-15 | Construction material for fishing reel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1118552A JPH02299528A (en) | 1989-05-15 | 1989-05-15 | Construction material for fishing reel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02299528A true JPH02299528A (en) | 1990-12-11 |
Family
ID=14739410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1118552A Pending JPH02299528A (en) | 1989-05-15 | 1989-05-15 | Construction material for fishing reel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02299528A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1108356A1 (en) * | 1999-12-03 | 2001-06-20 | Shimano Inc. | Spinning reel spool |
-
1989
- 1989-05-15 JP JP1118552A patent/JPH02299528A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1108356A1 (en) * | 1999-12-03 | 2001-06-20 | Shimano Inc. | Spinning reel spool |
| SG93912A1 (en) * | 1999-12-03 | 2003-01-21 | Shimano Kk | Spinning reel spool |
| US6572044B2 (en) | 1999-12-03 | 2003-06-03 | Shimano Inc. | Spinning reel spool |
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