JPH02145694A - Dispersant for aqueous solid lubricant - Google Patents
Dispersant for aqueous solid lubricantInfo
- Publication number
- JPH02145694A JPH02145694A JP29894388A JP29894388A JPH02145694A JP H02145694 A JPH02145694 A JP H02145694A JP 29894388 A JP29894388 A JP 29894388A JP 29894388 A JP29894388 A JP 29894388A JP H02145694 A JPH02145694 A JP H02145694A
- Authority
- JP
- Japan
- Prior art keywords
- dispersant
- lubricant
- solid lubricant
- water
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 25
- 239000000314 lubricant Substances 0.000 title claims description 37
- 239000007787 solid Substances 0.000 title claims description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 18
- 229920000570 polyether Polymers 0.000 claims abstract description 18
- 229920000768 polyamine Polymers 0.000 claims abstract description 13
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 description 16
- 230000001050 lubricating effect Effects 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- -1 etc. Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229920002873 Polyethylenimine Polymers 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001281 polyalkylene Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000011163 secondary particle Substances 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000003827 glycol group Chemical group 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 241000588986 Alcaligenes Species 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000010727 cylinder oil Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 229910052981 lead sulfide Inorganic materials 0.000 description 1
- 229940056932 lead sulfide Drugs 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Abstract
Description
本発明は、新規な固体潤滑剤用分散剤に関するものであ
る。さらに詳しくは分散性が良好で高温安定性に優れた
水系の固体ｎ？ｒ）剤用分散剤に関するものである。The present invention relates to a novel dispersant for solid lubricants. More specifically, it is a water-based solid n? with good dispersibility and excellent high temperature stability. r) It relates to a dispersant for agents.
金属、ガラス、プラスチック、セラミックス等の機械加
工や、塑性加工たとえば圧延、引抜、切削、研削、鍛造
、ダイカスト加工などの時に潤滑剤や離型剤が使用され
、これらは、鉱油１合成油、動植物油などのいわゆる潤
滑油に、各種の固体または液体の添加剤を配合して潤滑
油に極圧性や耐ｙＩ擦性を４１ ｔｊ−する努力がなさ
れている。
従来、極圧性や耐ｆｆＪａ性を向上させるために固体潤
滑剤として、黒鉛やフッ化炭素、フッ素樹脂パウダーを
添加するのが有用であることが知られており、固体潤滑
剤を水に分散した水系の潤滑剤や１ｌｌｆｆｉ剤が開発
されている。固体潤滑用分散剤としては１例えば特開昭
５８−１３６９６号公報に黒鉛の分散にメチルセルロー
ス、カルボキシメチルセルロースを分散剤とし、増粘剤
（ポリエチレンオキサイド、ポリビニルアルコール）、
結合剤（Ｆｅ２０ａ、ＭｇＯ１Ａ ｌ ２０３等）、接
近剤（酢酩、ギ酸）を用いた方法、特開昭５６−６２５
３７、特開昭５７−４８３３６．４．シ開閉５７−５６
０３４、特開昭５９−１９５３０号公報に微粉末の水系
分散安定剤としてポリエーテルボリオール及びその誘導
体を用いる例が開示されている。Lubricants and mold release agents are used during machining of metals, glass, plastics, ceramics, etc., and plastic processing such as rolling, drawing, cutting, grinding, forging, and die casting. Efforts have been made to add various solid or liquid additives to so-called lubricating oils, such as oil, to improve the extreme pressure properties and abrasion resistance of the lubricating oil. Conventionally, it has been known that it is useful to add graphite, fluorocarbon, or fluororesin powder as a solid lubricant to improve extreme pressure properties and ffJa resistance. Water-based lubricants and lllffi agents have been developed. Dispersants for solid lubricants include 1. For example, JP-A-58-13696 discloses that methylcellulose or carboxymethylcellulose is used as a dispersant for dispersing graphite, thickeners (polyethylene oxide, polyvinyl alcohol),
Method using binders (Fe20a, MgO1A l 203, etc.) and access agents (vinegar, formic acid), JP-A-56-625
37, JP-A-57-48336.4. Opening/closing 57-56
No. 034 and JP-A-59-19530 disclose an example of using polyether polyol and its derivatives as a fine powder aqueous dispersion stabilizer.
しかしながら、このような従来の固体潤滑剤用分散剤に
あっては、分散剤単独では分散安定性が充分でなく固体
が分散するため、実用上潤滑性能を発揮せず、さらに長
期間保存するとハードな沈降層を形成するため、潤滑液
として全く満足されるものでなかった。したがって、こ
れら固体潤滑剤の分散安定性に優れた分散剤が要求され
ている０本発明者らは上記問題を解決するべく固体潤滑
剤の水中における分散安定性について鋭意研寒を行なっ
た結果、従来の分散剤では成し得なかった極めて長期安
定性に優れ、とりわけ５０〜９０℃といった高温下にお
いても安定性に優れた分散剤を見い出し１本発明を完成
するに至った。However, such conventional dispersants for solid lubricants do not have sufficient dispersion stability when used alone and solids are dispersed, so they do not exhibit practical lubricating performance, and furthermore, they become hard when stored for a long period of time. Because it forms a sedimentary layer, it is not completely satisfactory as a lubricant. Therefore, a dispersant with excellent dispersion stability for these solid lubricants is required. In order to solve the above problem, the present inventors conducted intensive research on the dispersion stability of solid lubricants in water. The present invention was completed by discovering a dispersant that has extremely excellent long-term stability, which could not be achieved with conventional dispersants, and that has particularly excellent stability even at high temperatures of 50 to 90°C.
【課題を解決するための手段】
この発明は、このような従来の課題に着目してなされた
ものである。すなわち窒素原子３〜２００個を有するポ
リアミン化合物にアルキレンオキサイドを付加して得ら
れる、分子１１０００〜１００万のポリエーテル化合物
とラムザンガムを必須成分として含有することを特徴と
する水系固体潤滑剤用分散剤である。
（手段を構成する要件）
本発明に使用するポリエーテルの出発物質であるポリア
ミン化合物は分子内に窒素原子数３〜２００個有するポ
リエチレンイミン、ポリエチレンイミン誘導体、ポリア
ルキレンポリアミン又はポリアルキレンポリアミン誘導
体が挙げられる。ポリエチレンイミン誘導体及びポリア
ルキレンポリアミン誘導体とはポリエチレンイミン及び
ポリアルキレンポリアミンから誘導されるすべての化合
物を含むもので、たとえば、アルコール類、ポリオール
類、フェノール類、アミン類、ポリアミン類、千オール
類、カルボン酸類、ポリカルボン酸類などの活性水素を
１個以上有する化合物を開始剤としたエチレンイミンの
付加重合体や、ポリエチレンイミン及びポリアルキレン
ポリアミンの活性水素に対して反応性を有するアルデヒ
ド類、ケトン類、アルキルハライド類、アクリルアミド
等の活性二重結合を有する化合物類、インシアネート類
、チオシアネート類、エポキシ化合物、エピハロヒドリ
ン類、カルボン酸類１ｍ無水物、シアナライド類、グア
ニジン類、尿素類などとの反応生成物が挙げられる。ま
た、ポリアルキレンポリアミンとはジエチレントリアミ
ン、トリエチレンテトラミン、テトラエチレンペンタミ
ン、ペンタエチレンへキサミン、ジプロピレントリアミ
ン、テトラエチレンペンタミン、又はポリエチレンポリ
アミンの製造工程において得られる蒸留残存物等が挙げ
られる。これらの出発物質は１種又は２種以上を使用す
ることができ、通常の方法によりアルキレンオキサイド
を付加反応することにより容易に製造することができる
。すなわち、出発物質のポリアミン化合物をアルカリ触
奴下で１ｏｏ−ｔａｏ℃、１〜１０気圧でアルキレンオ
キサイドを付加反応することにより目的物が得られる。
アルキレンオキサイドにはエチレンオキサイドが存在す
ることが好ましく、他に０〜４０重量％ノ範囲でプロピ
レンオキサイド、ブチレンオキサイドのＩＭＬ又は２種
を付加しても良いが、このエチレンオキサイド以外のア
ルキレンオキサイドは付加した全アルキレンオキサイド
の５０重量％以上含有すると凝集作用が強く働く為１分
散安定性が損なわれ好ましくない、エチレンオキサイド
の付加モル数はポリアミン化合物の活性水素１個当り、
２〜１５０モルが好ましい、また、アルキレンオキサイ
ドは、ブロック付加、ランダムイ・ｊ加、いずれの方法
でも良好であるが、エチレンオキサイドを末端にブロッ
ク付加したものがより好ましい、ポリエーテルの平均分
子量は１０００〜１００万、より好ましくは５０００〜
８０万である。平均分子量が１０００未満であると、分
散性が損なわれる。
さらに、前記ポリエーテル化合物の末端本ｍ基の一部又
は全部をエステル化したポリエーテル誘導体も有効であ
る。この場合のポリエーテル誘導体であるエステル化物
はアジピン酸、フタール酸、マレイン酸、コハク酸など
のジカルボン酸あるいはこれらの酸無水物やポリカルボ
ン酸との反応物であり、また、硫酸、モノクロルスルホ
ン酸、無水硫酸、無水リン酸等を使用して通常公知の方
法でポリエーテルをエステル化した硫酸エステル化物、
リン酸エステル化物が挙げられる。このエステル化物は
、水酸化ナトリウム、水酸化カリウム、水酸化カルシウ
ム、水酸化アンモン等の木酢化物又はアルカノールアミ
ン、ポリエチレンポリアミン、アルキルアミン等のアミ
ン類との中和物であってもよい。
さらに本発明に使用するラムザンガムは分子内に下記（
１）式にて示す骨格を連続して６個以上有し、かつそれ
らの内、主鎖にグルコース２個、グルクロン酸１個、ラ
ムノース１個と、側鎖にグルコース２個を構成単位とす
る分子撮１万〜６００万の化合物である。ラムザンガム
は、生産菌である微生物Ａｌｃａｌｉｇｅｎｅｓ Ａ
ＴＣＣ３１９６１によるグルコースの醗酵により容易に
製造することができる。
（Ｍ”はすトリウド
本発明の水系の固体ｄマ１滑剤用分散剤は前記のポリエ
ーテル化合物を分散液全体に対して０．０１〜５．０重
量％、好ましくは０．１〜２．０重量％の割合で使用す
る．また前記のラムザンガムを分散液全体に対して０．
０１〜１．０重量％好ましくは０．０５〜０．５重量％
の割合で使用する．ポリエーテル化合物とラムザンガム
の使用量は，これより少ないと効果が小さく、また、多
すぎても効果の改善が顕著でなく経済的に不利である．
本発明の水系の固体１１滑剤用分散剤は無機及び有機の
いずれの微粉末のｎ１滑剤に対しても有効であり，とく
に限定しないが例えば、無機微粉末の潤滑剤としては、
フッ化炭素，フッ化アルミニウム、フン化カルシウム、
天然黒鉛，カーボンブラック、モリブデンジチオカーバ
メイト、モリブデンジチオフォ．スフエート等の有機モ
リブデン。
Ｉ 化ケイ素、窒化ポロン、二硫化モリブデン、焼結セ
ラミックス、酸化鉛、酸化アルミ、酸化ボロン等の金属
酸化物、及び硫化鉛、二硫化モリブデン、フッ化カルシ
ウム等の固体潤滑剤に酸化ボロンをコーティングしたも
のが挙げられる．また有Ｊａ微粉末の潤滑剤としては、
ポリテトラフロロエチレン等のフッ素樹脂パウダー、メ
ラミンイソシアヌレート、樹脂パウダー等が挙げられる
。
これら本発明の分散剤はいずれの粒子径の固体潤滑剤に
対しても効果を示すが、通常１００ミクロン以下であり
、平均粒子径０．１〜５０ミクロンのもので、なるべく
粒径分布の均一なものが好ましい。
また、上記固体の潤滑剤を添加する分散媒である水は、
凍結防止、及びｆＩｌＩ！？性能の向上のために、水溶
性無機塩，尿素、メタノール、エタノール、ブチルセロ
ソルブ及びエチレングリコール、プロピレングリコール
、ソルビトール、グリセリン、ホリエチレングリコール
、ポリエチレン−ポリプロピレングリコール等の１種ま
たは２種以上を水に対し２０重量％以下混合溶解して使
用することもできる．さらに、必要に応じて他の界面活
性剤を含有させても差し支えない。
潤滑液組成物の固体潤滑剤の濃度は分散系が生成される
いずれの濃度でもよいが通常１重量％〜４０瓜量％がほ
とんどであり、ｌｆｆｉｆｆｉ％より少ない場合は満足
し得る潤滑性能が得られず，逆に４０重量％より多い場
合は経済上好ましくない。
また、潤滑液組成物の製造方法としては、例えば、本発
明の分散剤を溶解した潤滑液に所定量の固体潤滑剤を添
加し，ついで固体潤滑剤の二次粒子を崩すことができる
程度のせん断力をもった分散機，具体的には３本ロール
、コロイドミル、ホモジナイザー、ボールミルニーグー
、ラインミキサーなどにより、充分攪拌混合する．添加
するポリエーテル化合物とラムザンガムは、前記分散機
で二次粒子を粉砕する工程の前、あるいは後に加えるが
、一般には工程前に添加する方が分散が良好となり、二
次粒子の粉砕が？まるので好ましい、さらに本発明の微
粉末の水系分散液には防腐剤（有機アミン系、有機ｒｉ
黄系、有機ハロゲン系、安、Ｕ香酩エステル系）、消泡
剤（シリコン系、ポリグリコール系）又は水溶性防錆剤
等を併用することができる。[Means for Solving the Problems] The present invention has been made by paying attention to such conventional problems. That is, a dispersant for an aqueous solid lubricant characterized by containing as essential components a polyether compound with a molecular size of 11,000 to 1,000,000, obtained by adding an alkylene oxide to a polyamine compound having 3 to 200 nitrogen atoms, and Ramsan gum. It is. (Requirements constituting the means) The polyamine compound which is the starting material of the polyether used in the present invention includes polyethyleneimine, polyethyleneimine derivative, polyalkylene polyamine, or polyalkylene polyamine derivative having 3 to 200 nitrogen atoms in the molecule. It will be done. Polyethyleneimine derivatives and polyalkylenepolyamine derivatives include all compounds derived from polyethyleneimine and polyalkylenepolyamine, such as alcohols, polyols, phenols, amines, polyamines, 1,000-ols, carvone, etc. Addition polymers of ethyleneimine using a compound having one or more active hydrogens such as acids and polycarboxylic acids as an initiator, aldehydes and ketones that are reactive with the active hydrogens of polyethyleneimine and polyalkylene polyamines, Reaction products with compounds having active double bonds such as alkyl halides and acrylamide, incyanates, thiocyanates, epoxy compounds, epihalohydrins, carboxylic acids, 1m anhydrides, cyanalides, guanidines, ureas, etc. Can be mentioned. Examples of the polyalkylene polyamine include diethylene triamine, triethylene tetramine, tetraethylene pentamine, pentaethylene hexamine, dipropylene triamine, tetraethylene pentamine, and distillation residues obtained in the process of producing polyethylene polyamine. These starting materials can be used alone or in combination of two or more, and can be easily produced by addition reaction with alkylene oxide by a conventional method. That is, the desired product is obtained by addition-reacting a polyamine compound as a starting material with an alkylene oxide under an alkaline atmosphere at 10° C. and 1 to 10 atm. It is preferable that ethylene oxide exists in the alkylene oxide, and IML or two of propylene oxide and butylene oxide may be added in a range of 0 to 40% by weight, but alkylene oxides other than this ethylene oxide may be added. If the content exceeds 50% by weight of the total alkylene oxide, the agglomeration effect will be strong and the dispersion stability will be impaired, which is undesirable.The number of moles of ethylene oxide added per active hydrogen of the polyamine compound is
The average molecular weight of the polyether is preferably 2 to 150 moles.Alkylene oxide can be used by block addition, random addition, or any other method, but it is more preferable to add block addition to the terminals of ethylene oxide.The average molecular weight of the polyether is 1,000 to 1,000,000, more preferably 5,000 to 1,000,000
It is 800,000. If the average molecular weight is less than 1000, dispersibility will be impaired. Furthermore, polyether derivatives obtained by esterifying a part or all of the terminal m group of the polyether compound are also effective. In this case, the esterified polyether derivatives are dicarboxylic acids such as adipic acid, phthalic acid, maleic acid, and succinic acid, or their reaction products with acid anhydrides and polycarboxylic acids, and also sulfuric acid, monochlorosulfonic acid, etc. , sulfuric acid esterified product obtained by esterifying polyether by a commonly known method using sulfuric anhydride, phosphoric anhydride, etc.
Examples include phosphoric acid esters. This esterified product may be a plyacetate such as sodium hydroxide, potassium hydroxide, calcium hydroxide, ammonium hydroxide, or a neutralized product with amines such as alkanolamine, polyethylene polyamine, and alkylamine. Furthermore, Ramzan gum used in the present invention contains the following (
1) It has 6 or more consecutive skeletons represented by the formula, and among them, the main chain has 2 glucose, 1 glucuronic acid, and 1 rhamnose, and the side chain has 2 glucose as constituent units. It is a compound with a molecular weight of 10,000 to 6,000,000. Ramzan gum is produced by the microorganism Alcaligenes A.
It can be easily produced by fermentation of glucose using TCC31961. (M'') The aqueous solid dM lubricant dispersant of the present invention contains the above-mentioned polyether compound in an amount of 0.01 to 5.0% by weight, preferably 0.1 to 2.0% by weight, based on the entire dispersion. The Ramsan gum is used in a proportion of 0% by weight based on the entire dispersion.
01-1.0% by weight, preferably 0.05-0.5% by weight
Use at a ratio of If the amount of polyether compound and Ramzan gum used is less than this, the effect will be small, and if it is too large, the improvement in effect will not be significant and it will be economically disadvantageous.
The aqueous solid 11 lubricant dispersant of the present invention is effective for both inorganic and organic fine powder n1 lubricants. Although not particularly limited, for example, as an inorganic fine powder lubricant,
Carbon fluoride, aluminum fluoride, calcium fluoride,
Natural graphite, carbon black, molybdenum dithiocarbamate, molybdenum dithiophore. Organic molybdenum such as sulfate. I Coating silicon oxide, poron nitride, molybdenum disulfide, sintered ceramics, metal oxides such as lead oxide, aluminum oxide, boron oxide, etc., and solid lubricants such as lead sulfide, molybdenum disulfide, calcium fluoride, etc. with boron oxide. Here are some examples. In addition, as a lubricant containing Ja fine powder,
Examples include fluororesin powder such as polytetrafluoroethylene, melamine isocyanurate, and resin powder. Although these dispersants of the present invention are effective for solid lubricants of any particle size, they are usually 100 microns or less, with an average particle size of 0.1 to 50 microns, and preferably have a uniform particle size distribution. Preferably. In addition, water, which is a dispersion medium to which the solid lubricant is added, is
Freeze protection and fIlI! ? In order to improve performance, one or more of water-soluble inorganic salts, urea, methanol, ethanol, butyl cellosolve and ethylene glycol, propylene glycol, sorbitol, glycerin, polyethylene glycol, polyethylene-polypropylene glycol, etc., are added to water. It can also be used by mixing and dissolving up to 20% by weight. Furthermore, other surfactants may be included if necessary. The concentration of the solid lubricant in the lubricating liquid composition may be any concentration that produces a dispersion system, but it is usually 1% by weight to 40% by weight, and if it is less than lffiffi%, satisfactory lubricating performance is not obtained. On the contrary, if it exceeds 40% by weight, it is economically unfavorable. Further, as a method for producing a lubricating liquid composition, for example, a predetermined amount of solid lubricant is added to a lubricating liquid in which the dispersant of the present invention is dissolved, and then a sufficient amount of solid lubricant is added to the lubricating liquid in which the dispersant of the present invention is dissolved. Thoroughly stir and mix using a dispersing machine with shearing force, specifically a three-roll mill, colloid mill, homogenizer, ball mill, line mixer, etc. The polyether compound and Ramsan gum to be added are added before or after the process of pulverizing the secondary particles with the dispersion machine, but generally, adding them before the process improves the dispersion and improves the pulverization of the secondary particles. Furthermore, the aqueous dispersion of the fine powder of the present invention contains preservatives (organic amine type, organic RI).
Antifoaming agents (silicon-based, polyglycol-based), water-soluble rust preventives, etc. can be used in combination.
このようにして得られた水系の潤滑液組成物は、固体潤
滑剤の分散安定性にすぐれ、たとえば６ケ月以上といっ
た長期間にわたって放置しても、またたとえば５０〜９
０℃といった高温下においても安定性が優れる。
また本発明の分散剤を添加した固体潤滑剤含有の水系の
潤滑液組成物１蓬良好な極圧性と低いｙ！擦係数を有し
−・般機械への潤滑液として、たとえＩｆ 、マシン油
、タービン油、ギヤー油、シリンダー油等の代用や熱間
圧延用水系潤滑剤、鍛造用水系潤滑剤、ｍ管引抜用水系
潤滑剤、アルミダイキャスト用離望剤、ガラスモールド
用離型剤、及び外装用滑剤として、苛酷な条件下におい
ても焼付きを防止し、摺動面の摩耗量の減少に大きな効
果を発揮する。さらに、セラミック、プラスチック離型
加工液、繊維処理用の潤滑液などとしても有効である。
本発明の微粉末の水系分散安定化の方法が、今までに類
を見ない多種類の微粉末物質を広範囲のＣ度でハンドリ
ング性の良いスラリーと成し、長期間安定で分離しない
優れた分散性と安定性の効果が得られるのは、必須成分
のポリエーテル化合物が、高分子量でかざばりの大きい
特殊な分子構造と、親水性の強いポリエチレングリコー
ル鎖より構成し、一方のラムザンガムが、２個のグリコ
ール鎖を側鎖に有する特殊な分子構造で、′！Ｂ水性の
強い高分子量の糖類を構成しているため、微粉末粒子に
対し、水中で、前記二者の薬剤がバランス良く、効果的
に、強く吸着することと、微粉末粒子に対する保護コロ
イド作用が大きく、分散性の相乗効果が現・れ、−次粒
子への分散性と再凝集の防止する力（作用）がより強力
に働く為と名えられる。
以下 この発明の実施例を記載してより具体的に説明す
るが、本発明はこれらの実施例に限定されるものではな
い。The aqueous lubricant composition thus obtained has excellent dispersion stability of the solid lubricant, and even when left for a long period of time, for example, 6 months or more,
Excellent stability even at high temperatures such as 0°C. In addition, an aqueous lubricating liquid composition containing a solid lubricant containing the dispersant of the present invention has good extreme pressure properties and low y! As a lubricant for general machinery, it can be used as a substitute for machine oil, turbine oil, gear oil, cylinder oil, etc., water-based lubricant for hot rolling, water-based lubricant for forging, m-pipe drawing. As a water-based lubricant, a release agent for aluminum die casting, a mold release agent for glass molds, and a lubricant for exteriors, it prevents seizure even under harsh conditions and is highly effective in reducing the amount of wear on sliding surfaces. Demonstrate. Furthermore, it is effective as a mold release liquid for ceramics and plastics, a lubricating liquid for textile processing, etc. The method of aqueous dispersion stabilization of fine powder of the present invention makes it possible to form an unprecedented slurry of a wide variety of fine powder substances into a slurry with good handling properties over a wide range of C degrees, and is stable for a long period of time and does not separate. The dispersibility and stability effects can be obtained because the essential component polyether compound has a special molecular structure with high molecular weight and bulk, and a polyethylene glycol chain with strong hydrophilicity. Ramsan gum, on the other hand, It has a special molecular structure with two glycol chains in its side chains, '! B: Because it is composed of highly aqueous, high-molecular-weight saccharides, the two drugs mentioned above are well-balanced, effective, and strongly adsorbed to the fine powder particles in water, and the protective colloid has a protective colloid effect on the fine powder particles. This is said to be because the dispersibility is large, a synergistic effect of dispersibility appears, and the force (action) of dispersibility into secondary particles and prevention of reagglomeration works more strongly. Hereinafter, the present invention will be described in more detail by describing examples, but the present invention is not limited to these examples.
水系の潤滑液として水１３８．８ｇに分散剤のポリエー
テル化合ｆｌｙ １ 、０ ｇとラムザンガム０゜２ｇ
を溶解したのち固体用滑剤６０ 、Ｏｇを添加し、ボー
ルミルで充分混合して均一に分散する。
調製した潤滑液を１００ｍ文のメスシリンダーに移し密
栓する。６０℃の恒温槽中に１００日保存し、シリンダ
ー内の沈降層を観察分散安定性を判定した。結果を第１
表に示す０表中の記号は次のことを意味する。
０：沈降物が認められない。
Δ：沈降物がわずかに認められる。
×：沈降物が多量に認められる。
（以下余白）As a water-based lubricant, 138.8 g of water, polyether compound fly 1,0 g as a dispersant, and 0.2 g of Ramsan gum
After dissolving the solid lubricant, 60 g of solid lubricant was added and thoroughly mixed using a ball mill to uniformly disperse the mixture. Transfer the prepared lubricating liquid to a 100 m measuring cylinder and seal it tightly. The mixture was stored in a constant temperature bath at 60° C. for 100 days, and the dispersion stability was determined by observing the sedimented layer inside the cylinder. Results first
0 Symbols in the table mean the following. 0: No sediment observed. Δ: A slight amount of sediment is observed. ×: A large amount of sediment is observed. (Margin below)
本発明は種類の異なる固体潤滑剤を安定なスラリーとす
る為の分散剤であって、上記試験結果より、本発明の分
散剤を用いた場合、高温下において長期間安定な潤滑液
が得られた。
一方、比較例の分散剤を用いた場合、いずれも多量の沈
降層が認められた。この結果からも明らかなように、本
発明の分散剤を用いれば高温下において固体？１１滑剤
の長期安定性に優れた潤滑液が得られる事がわかる。
水系の潤滑液は不燃性で、毒性もなく、安全性の高い潤
滑液となるが、これに使用する分散安定剤を提供し得た
ことは、分散技術の進歩に対し広く寄与しうるちのであ
る。
特許出願人 第−工業製薬株式会社The present invention is a dispersant for making a stable slurry of different types of solid lubricants, and the above test results show that when the dispersant of the present invention is used, a lubricating liquid that is stable for a long period of time at high temperatures can be obtained. Ta. On the other hand, when the dispersants of Comparative Examples were used, a large amount of sedimentation layer was observed in all cases. As is clear from this result, if the dispersant of the present invention is used, it will become solid at high temperatures. It can be seen that a lubricating liquid with excellent long-term stability of lubricant No. 11 can be obtained. Water-based lubricating fluids are non-flammable, non-toxic, and highly safe lubricating fluids, and being able to provide a dispersion stabilizer for use in these fluids will greatly contribute to the advancement of dispersion technology. be. Patent applicant: Dai-Kogyo Seiyaku Co., Ltd.
Claims (1)
アルキレンオキサイドを付加して得られる分子量１００
０〜１００万のポリエーテル化合物とラムザンガムを必
須成分として含有することを特徴とする水系固体潤滑剤
用分散剤。 ２、ポリエーテル化合物がエチレンオキサイドを末端に
有する構造である特許請求の範囲第１項記載の水系固体
潤滑剤用分散剤。[Claims] 1. Molecular weight 100 obtained by adding alkylene oxide to a polyamine compound having 3 to 200 nitrogen atoms
A dispersant for a water-based solid lubricant characterized by containing 0 to 1 million polyether compounds and Ramsan gum as essential components. 2. The dispersant for a water-based solid lubricant according to claim 1, wherein the polyether compound has a structure having ethylene oxide at the end.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29894388A JPH02145694A (en) | 1988-11-25 | 1988-11-25 | Dispersant for aqueous solid lubricant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29894388A JPH02145694A (en) | 1988-11-25 | 1988-11-25 | Dispersant for aqueous solid lubricant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02145694A true JPH02145694A (en) | 1990-06-05 |
Family
ID=17866195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29894388A Pending JPH02145694A (en) | 1988-11-25 | 1988-11-25 | Dispersant for aqueous solid lubricant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02145694A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005523372A (en) * | 2002-04-16 | 2005-08-04 | エイドゲントシッシュ テクニーシェ ホッシュール チューリッヒ | Environmentally compatible additives for aqueous lubricants |
-
1988
- 1988-11-25 JP JP29894388A patent/JPH02145694A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005523372A (en) * | 2002-04-16 | 2005-08-04 | エイドゲントシッシュ テクニーシェ ホッシュール チューリッヒ | Environmentally compatible additives for aqueous lubricants |
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