JPH0214060B2 - - Google Patents

Info

Publication number: JPH0214060B2
Authority: JP; Japan
Prior art keywords: metal base; base material; oxide layer; metal; chromium
Prior art date: 1986-10-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP24716186A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6399868A (ja

Inventor

Takayuki Shimamune

Masashi Hosonuma

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

De Nora Permelec Ltd

Original Assignee

Permelec Electrode Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-10-17

Filing date

1986-10-17

Publication date

1990-04-06

1986-10-17 Application filed by Permelec Electrode Ltd filed Critical Permelec Electrode Ltd

1986-10-17 Priority to JP61247161A priority Critical patent/JPS6399868A/ja

1987-10-15 Priority to CA000549336A priority patent/CA1269898A/en

1987-10-16 Priority to DE8787830365T priority patent/DE3776066D1/de

1987-10-16 Priority to EP87830365A priority patent/EP0264354B1/de

1987-10-19 Priority to US07/109,378 priority patent/US4818572A/en

1988-05-02 Publication of JPS6399868A publication Critical patent/JPS6399868A/ja

1990-04-06 Publication of JPH0214060B2 publication Critical patent/JPH0214060B2/ja

Status Granted legal-status Critical Current

Links

229910052751 metal Inorganic materials 0.000 claims description 85
239000002184 metal Substances 0.000 claims description 85
239000000463 material Substances 0.000 claims description 84
239000010410 layer Substances 0.000 claims description 63
-1 calcium phosphate compound Chemical class 0.000 claims description 31
239000001506 calcium phosphate Substances 0.000 claims description 28
229910000389 calcium phosphate Inorganic materials 0.000 claims description 27
235000011010 calcium phosphates Nutrition 0.000 claims description 26
239000011247 coating layer Substances 0.000 claims description 24
239000010936 titanium Substances 0.000 claims description 24
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 23
229910052719 titanium Inorganic materials 0.000 claims description 23
238000010438 heat treatment Methods 0.000 claims description 15
238000000034 method Methods 0.000 claims description 15
239000010935 stainless steel Substances 0.000 claims description 14
229910001220 stainless steel Inorganic materials 0.000 claims description 14
239000003792 electrolyte Substances 0.000 claims description 13
239000008151 electrolyte solution Substances 0.000 claims description 13
239000002131 composite material Substances 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 9
229910001069 Ti alloy Inorganic materials 0.000 claims description 7
239000007864 aqueous solution Substances 0.000 claims description 7
230000003647 oxidation Effects 0.000 claims description 6
238000007254 oxidation reaction Methods 0.000 claims description 6
239000000243 solution Substances 0.000 claims description 6
229910000531 Co alloy Inorganic materials 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
AXTNPHLCOKUMDY-UHFFFAOYSA-N chromium cobalt Chemical compound [Co][Cr][Co] AXTNPHLCOKUMDY-UHFFFAOYSA-N 0.000 claims description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 3
229910052804 chromium Inorganic materials 0.000 claims 3
239000011651 chromium Substances 0.000 claims 3
229910017052 cobalt Inorganic materials 0.000 claims 3
229910001430 chromium ion Inorganic materials 0.000 claims 1
229910001429 cobalt ion Inorganic materials 0.000 claims 1
230000007935 neutral effect Effects 0.000 claims 1
229960001714 calcium phosphate Drugs 0.000 description 24
210000000988 bone and bone Anatomy 0.000 description 21
229910052588 hydroxylapatite Inorganic materials 0.000 description 17
XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 17
239000011248 coating agent Substances 0.000 description 13
238000000576 coating method Methods 0.000 description 13
239000000758 substrate Substances 0.000 description 13
239000007943 implant Substances 0.000 description 11
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
238000005868 electrolysis reaction Methods 0.000 description 8
229910045601 alloy Inorganic materials 0.000 description 7
239000000956 alloy Substances 0.000 description 7
230000007797 corrosion Effects 0.000 description 7
238000005260 corrosion Methods 0.000 description 7
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
239000000919 ceramic Substances 0.000 description 5
230000005611 electricity Effects 0.000 description 5
238000001727 in vivo Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
229910017604 nitric acid Inorganic materials 0.000 description 5
238000007750 plasma spraying Methods 0.000 description 5
238000007751 thermal spraying Methods 0.000 description 5
229910000684 Cobalt-chrome Inorganic materials 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
WAIPAZQMEIHHTJ-UHFFFAOYSA-N [Cr].[Co] Chemical compound [Cr].[Co] WAIPAZQMEIHHTJ-UHFFFAOYSA-N 0.000 description 4
229910052786 argon Inorganic materials 0.000 description 4
239000010952 cobalt-chrome Substances 0.000 description 4
229910044991 metal oxide Inorganic materials 0.000 description 4
150000004706 metal oxides Chemical class 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
239000002245 particle Substances 0.000 description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
238000002441 X-ray diffraction Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
239000007789 gas Substances 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
238000005507 spraying Methods 0.000 description 3
238000005979 thermal decomposition reaction Methods 0.000 description 3
238000005406 washing Methods 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
229910052586 apatite Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000000470 constituent Substances 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000000921 elemental analysis Methods 0.000 description 2
238000010828 elution Methods 0.000 description 2
238000005530 etching Methods 0.000 description 2
238000010304 firing Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 2
229910000027 potassium carbonate Inorganic materials 0.000 description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
229940078499 tricalcium phosphate Drugs 0.000 description 2
235000019731 tricalcium phosphate Nutrition 0.000 description 2
229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
206010067482 No adverse event Diseases 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000005422 blasting Methods 0.000 description 1
238000001354 calcination Methods 0.000 description 1
YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
229940062672 calcium dihydrogen phosphate Drugs 0.000 description 1
FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
235000011132 calcium sulphate Nutrition 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000788 chromium alloy Substances 0.000 description 1
GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
229940044175 cobalt sulfate Drugs 0.000 description 1
229910000361 cobalt sulfate Inorganic materials 0.000 description 1
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007850 degeneration Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
235000019700 dicalcium phosphate Nutrition 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000010335 hydrothermal treatment Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000002513 implantation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
235000019691 monocalcium phosphate Nutrition 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000002161 passivation Methods 0.000 description 1
238000000053 physical method Methods 0.000 description 1
238000005554 pickling Methods 0.000 description 1
UUWCBFKLGFQDME-UHFFFAOYSA-N platinum titanium Chemical compound [Ti].[Pt] UUWCBFKLGFQDME-UHFFFAOYSA-N 0.000 description 1
230000010287 polarization Effects 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
238000004544 sputter deposition Methods 0.000 description 1
238000013020 steam cleaning Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000003115 supporting electrolyte Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
210000001519 tissue Anatomy 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000004506 ultrasonic cleaning Methods 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
229910000859 α-Fe Inorganic materials 0.000 description 1

Landscapes

Materials For Medical Uses (AREA)
Dental Prosthetics (AREA)

JP61247161A 1986-10-17 1986-10-17 リン酸カルシウム化合物被覆複合材の製造方法 Granted JPS6399868A (ja)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
JP61247161A JPS6399868A (ja)	1986-10-17	1986-10-17	リン酸カルシウム化合物被覆複合材の製造方法
CA000549336A CA1269898A (en)	1986-10-17	1987-10-15	Process for production of calcium phosphate compound- coated composite material
DE8787830365T DE3776066D1 (de)	1986-10-17	1987-10-16	Verfahren zur herstellung eines verbundwerkstoffes, beschichtet mit einer kalziumphosphatverbindung.
EP87830365A EP0264354B1 (de)	1986-10-17	1987-10-16	Verfahren zur Herstellung eines Verbundwerkstoffes, beschichtet mit einer Kalziumphosphatverbindung
US07/109,378 US4818572A (en)	1986-10-17	1987-10-19	Process for production of calcium phosphate compound-coated composite material

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP61247161A JPS6399868A (ja)	1986-10-17	1986-10-17	リン酸カルシウム化合物被覆複合材の製造方法

Publications (2)

Publication Number	Publication Date
JPS6399868A JPS6399868A (ja)	1988-05-02
JPH0214060B2 true JPH0214060B2 (de)	1990-04-06

Family

ID=17159343

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP61247161A Granted JPS6399868A (ja)	1986-10-17	1986-10-17	リン酸カルシウム化合物被覆複合材の製造方法

Country Status (1)

Country	Link
JP (1)	JPS6399868A (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH06128793A (ja) *	1992-10-15	1994-05-10	Natl Inst For Res In Inorg Mater	アパタイト皮膜形成用電解液
US20080183278A1 (en) *	2007-01-26	2008-07-31	Boston Scientific Scimed, Inc.	Implantable medical endoprostheses
EP2772313A4 (de)	2007-03-09	2014-09-03	Kao Corp	Mit einer pumpe ausgestatteter behälter und doppelentsorgungsbehälter

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6234566A (ja) *	1985-08-08	1987-02-14	住友化学工業株式会社	骨内インプラントの製造法

1986
- 1986-10-17 JP JP61247161A patent/JPS6399868A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6234566A (ja) *	1985-08-08	1987-02-14	住友化学工業株式会社	骨内インプラントの製造法

Also Published As

Publication number	Publication date
JPS6399868A (ja)	1988-05-02

Publication	Publication Date	Title
EP0264354B1 (de)	1992-01-15	Verfahren zur Herstellung eines Verbundwerkstoffes, beschichtet mit einer Kalziumphosphatverbindung
US4965088A (en)	1990-10-23	Calcium phosphate-coated composite material and process for production thereof
JP5135439B2 (ja)	2013-02-06	生物活性コーティングを形成する方法
US5478237A (en)	1995-12-26	Implant and method of making the same
US5413693A (en)	1995-05-09	Electrocrystallization of strongly adherent brushite coatings on prosthetic alloys
CN1974876B (zh)	2010-07-07	钛金属表面生物活性膜层及其喷砂-微弧氧化复合工艺
US4794023A (en)	1988-12-27	Process for producing a calcium phosphate compound coated composite material
EP1364079B1 (de)	2005-01-12	Verfahren zur elektrochemischen abscheidung von tantal
KR100985005B1 (ko)	2010-10-04	금속 임플란트
JP4457230B2 (ja)	2010-04-28	医用インプラント材の表面処理方法
KR20030031664A (ko)	2003-04-23	티타늄 금속 또는 티타늄 합금으로 구성된 임플란트의전기화학적 기능성 표면처리방법
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JPH0731627A (ja)	1995-02-03	インプラントとその製造方法
JPH0214060B2 (de)	1990-04-06
JPH08173523A (ja)	1996-07-09	骨内インプラント及びその製造方法
CA2073781A1 (en)	1994-01-14	Process for forming bioactive composite coatings on implantable devices
JP3654204B2 (ja)	2005-06-02	酸素発生用陽極
JPH0214061B2 (de)	1990-04-06
JP3129041B2 (ja)	2001-01-29	インプラント及びその製造方法
JPH0747116A (ja)	1995-02-21	インプラントの製造方法
JPH0747115A (ja)	1995-02-21	インプラント及びその製造方法
KR20100122783A (ko)	2010-11-23	치과용 임플란트의 표면개질 후 생체활성화를 위한 하이드록시아파타이트 코팅법
JPS62221359A (ja)	1987-09-29	リン酸カルシウム化合物被覆チタン複合材とその製造方法
JPH0420988B2 (de)	1992-04-07
Ozyilmaz et al.	2016	ÇağlaSürmelioğlu.(2016)