JPH02126265A - Pressure fixable capsule toner - Google Patents
Pressure fixable capsule tonerInfo
- Publication number
- JPH02126265A JPH02126265A JP63279471A JP27947188A JPH02126265A JP H02126265 A JPH02126265 A JP H02126265A JP 63279471 A JP63279471 A JP 63279471A JP 27947188 A JP27947188 A JP 27947188A JP H02126265 A JPH02126265 A JP H02126265A
- Authority
- JP
- Japan
- Prior art keywords
- core material
- silicone oil
- fine particles
- toner
- capsule toner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002775 capsule Substances 0.000 title claims description 31
- 239000011162 core material Substances 0.000 claims abstract description 42
- 229920002545 silicone oil Polymers 0.000 claims abstract description 39
- 239000010419 fine particle Substances 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 26
- 239000000049 pigment Substances 0.000 abstract description 12
- 239000006185 dispersion Substances 0.000 abstract description 7
- 239000003086 colorant Substances 0.000 abstract description 5
- 239000006247 magnetic powder Substances 0.000 abstract description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 19
- 229920005989 resin Polymers 0.000 description 18
- 239000011347 resin Substances 0.000 description 18
- -1 and Tsugaru Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 8
- 239000011257 shell material Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000007779 soft material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 230000005291 magnetic effect Effects 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- RVNAQNUKCZKJCP-UHFFFAOYSA-N 2,3-dihydroxypropyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(O)CO RVNAQNUKCZKJCP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 229920001890 Novodur Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920003146 methacrylic ester copolymer Polymers 0.000 description 1
- RVWOWEQKPMPWMQ-UHFFFAOYSA-N methyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OC RVWOWEQKPMPWMQ-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920005670 poly(ethylene-vinyl chloride) Polymers 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/0935—Encapsulated toner particles specified by the core material
- G03G9/09357—Macromolecular compounds
- G03G9/09371—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、電子写真法或いは、静電印刷法などに於いて
、電気的潜像を現像するのに用いられるトナーに関し、
特に圧力定着に適したカプセルトナーに関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a toner used for developing an electrical latent image in electrophotography, electrostatic printing, etc.
In particular, it relates to a capsule toner suitable for pressure fixing.
［従来の技術］
従来、電子写真法としては米国特許第２，２９７゜６３
１号明細書、特公昭４２−２３９１０号公報（米国特許
第３．８８６．３８３号明細書）及び特公昭４３−２４
７４８号公報（米国特許第４．゛０７１，３８１号明細
書）等に記載されている如く、多数の方法が知られてい
るが、一般には光導電性物質を利用し、種々の手段によ
り、感光体上に電気的潜像を形成し１次いで該潜像をト
ナーを用いて現像し、必要に応じて紙などの被転写材に
トナー画像を転写した後、定着して、複写物を得る工程
が取られる。[Prior Art] Conventionally, as an electrophotographic method, U.S. Patent No. 2,297゜63
Specification No. 1, Japanese Patent Publication No. 42-23910 (U.S. Patent No. 3.886.383), and Japanese Patent Publication No. 43-24
A number of methods are known, such as those described in U.S. Pat. An electrical latent image is formed on a photoreceptor, and then the latent image is developed using toner, and if necessary, the toner image is transferred to a transfer material such as paper, and then fixed to obtain a copy. The process is taken.
トナー画像を定着するためには、一般に、赤外線ヒータ
ーあるいは熱ローラーなどにより加熱溶融して支持体に
融着固化させる加熱定着方式が採用されているが、火災
の危険防止、消費電力の節減等の理由から、加熱が不要
であるか、あるいは本質的に軽減した、剛体ローラーに
よる加圧定着方式へと変りつつある。特に、この加圧定
着方式は、複写シートの焼は焦げの危険がないこと、複
写機の電源を入れれば待時間なしで複写が行なえること
、高速定着が可能なこと、定着装置が簡単なことなど利
点が多い。To fix a toner image, a heat fixing method is generally used in which the toner image is heated and melted using an infrared heater or a heated roller, and then fused and solidified to the support. For this reason, there is a shift toward pressure fixing methods using rigid rollers, which eliminate or essentially reduce the need for heating. In particular, this pressure fixing method has the following advantages: there is no risk of burning copy sheets, copying can be done without waiting time when the copier is turned on, high-speed fixing is possible, and the fixing device is simple. There are many advantages such as.
特に、この様な加圧定着用イ３なトリー一においては、
構成樹脂が加圧定着に適した特性を有している必要があ
り、この目的にあった樹脂の開発が積極的に行なわれて
いる。しかしながら、加圧定着性が優れ、加圧ローラー
へのオフセット現象を起さず、繰り返し使用に対しても
現像性能、定着性能が安定しており、キャリア、金属ス
リ・−ブ、感光体表面への癒着を起さず、保存中に凝集
、ケ・−キ化しない保存安定性の良好な実用的な圧力定
着トナーは得られていない。特に、」フセット現象は、
加圧口・−ラーに付着したトナーが転写紙を汚染する点
で、大きな問題である。In particular, in such a pressure fixing tree,
The constituent resins must have properties suitable for pressure fixing, and resins suitable for this purpose are being actively developed. However, it has excellent pressure fixing properties, does not cause any offset phenomenon to the pressure roller, and has stable developing and fixing performance even after repeated use. No practical pressure fixing toner has been obtained which has good storage stability and does not cause adhesion or agglomeration or caking during storage. In particular, the "fusset phenomenon"
This is a major problem in that the toner adhering to the pressurizing port contaminates the transfer paper.
このような圧力定着用トナーに要求される各種特性を、
トナー粒子の複層化により満足させるべく、硬質樹脂の
殻を設けたカプセル型のトナーも種々提案されている。We have developed various characteristics required for pressure fixing toners.
Various capsule-type toners provided with a hard resin shell have been proposed in order to satisfy the requirements by multi-layering toner particles.
このような提案には、例えば、特公昭５４−８１０４号
（米国特許部３，７８８，９９４号明細書）などに見ら
れる様な軟質物質を芯とするカプセルトナー、あるいは
また、軟質樹脂溶液芯カプセルトナーがあるが、オフセ
ット現象等の未解決の問題が多く、実用化されるに至っ
ていない。Such proposals include, for example, capsule toners having a soft material core as seen in Japanese Patent Publication No. 54-8104 (U.S. Pat. No. 3,788,994), or soft resin solution cores. Although there are capsule toners, there are many unresolved problems such as the offset phenomenon, and they have not been put into practical use.
このように、芯物質として軟質物質、あるいは液状物質
を用いた場合には、加圧ローラーによる殻材破壊で生じ
るオフセット現象は避けがたいものである。As described above, when a soft material or a liquid material is used as the core material, the offset phenomenon caused by the destruction of the shell material by the pressure roller is unavoidable.
一方、特にカプセルトナーにおいては、芯物質中に着色
材、磁性体等の微粒子を均一に分散させることがむずか
しいと考えられている。カプセルトナーに用いる芯物質
には、前記したように軟質物質、あるいは液状物質が用
いられるが、これらの物質中に微粒子を分散させようと
する場合、通常の樹１指と比較して微粒子にかかる分散
力が小さく、均一に分散することがむずかしい。特に、
微粒子が強固な２次凝集を起こしている場合は均一分散
は不可能に近い。On the other hand, especially in capsule toners, it is considered difficult to uniformly disperse fine particles of coloring material, magnetic material, etc. in the core material. As mentioned above, a soft material or a liquid material is used as the core material used in capsule toners, but when trying to disperse fine particles in these materials, the amount of material applied to the fine particles is higher than that of a single finger of normal wood. The dispersion force is small and it is difficult to disperse uniformly. especially,
If fine particles are strongly secondary agglomerated, uniform dispersion is almost impossible.
もし、このような不均一に微粒子が分散し７ている芯物
質を用いてカプセルトナーを製造すれば、トナー粒子各
々に大きな着色微粒子の含有量の差が生じ、その結果、
コピー画像にシミのような濃淡ムラをつくる原因となり
、トナーとしての使用は実際上不可能となる。If a capsule toner is manufactured using a core material in which fine particles are dispersed non-uniformly7, there will be a large difference in the content of colored fine particles in each toner particle, and as a result,
This causes uneven shading like spots on the copied image, making it practically impossible to use it as a toner.
これまで芯物質中にシ１）コーンオイルを含有させ離型
性を向−トさせることは、特開昭５５−１４２３６号公
報に開示されているが、シリコーンオイルを用いて微粒
子分散性とオフセット性の両方を同時に満足させる試み
は行なわれていない。Until now, it has been disclosed in JP-A-55-14236 that 1) corn oil is included in the core material to improve mold releasability. No attempt has been made to satisfy both sexes at the same time.
［発明が解決しようとする課題］
本発明の目的は、上述の如き欠点を補った圧力定着性カ
プセルトナーを提供することにある。[Problems to be Solved by the Invention] An object of the present invention is to provide a pressure-fixable capsule toner that overcomes the above-mentioned drawbacks.
即ち、本発明の目的は、芯物質中にシリコーンオイル処
理した微粒子を含有させることにより、加圧ローラーに
対するカプセルトナーの離型性を向上させ定着工程にお
いてトナーの加圧ローラーへの付着（オフセット）を防
ＩＦすることにある。That is, an object of the present invention is to improve the releasability of the capsule toner from the pressure roller by incorporating fine particles treated with silicone oil into the core material, thereby preventing the toner from adhering to the pressure roller (offset) in the fixing process. The purpose is to prevent IF.
また、本発明の目的は、微粒子をシリコーンオイル処理
することで微粒子の芯物質中への分散を良好にし、シミ
状の濃淡ムラのないコピー画像を提供することにある。Another object of the present invention is to improve the dispersion of the fine particles into the core material by treating the fine particles with silicone oil, thereby providing a copy image free from stain-like unevenness in density.
更に本発明の他の目的は、長期にわたりＭ続伸用した際
も初期の特性を維持し、トナー凝集や帯電特性の変化の
ないカプセルトナーを提供することにある。Still another object of the present invention is to provide a capsule toner that maintains its initial properties even when used continuously over a long period of time, and does not cause toner aggregation or change in charging properties.
［課題を解決するための手段及び作用］本発明のカプセ
ルトナーは、上述の目的達成のために開発されたもので
あり、圧力定着性成分を含有する芯物質と、該芯物質の
少なくとも一部を覆う外殻とから構成されるカプセルト
ナーに於いて、該芯物質中に、シリコーンオイルであら
かじめ処理され、かつ体積平均粒径１．０〜０．０１ｇ
＋ｍの範囲にある微粒子を含有することを特徴とするも
のである。[Means and effects for solving the problems] The capsule toner of the present invention was developed to achieve the above-mentioned object, and includes a core material containing a pressure fixing component and at least a portion of the core material. In a capsule toner consisting of an outer shell that covers the core material, the core material is pre-treated with silicone oil and has a volume average particle size of 1.0 to 0.01 g.
It is characterized by containing fine particles in the range of +m.
本発明者の検討によれば、カプセルトナーを構成する芯
物質中にシリコーンオイルであらかじめ処理した微粒子
を分散させることにより、トナーのオフセット性能を著
しく向上させ、さらに顔料等の微粒子が均一分散するこ
とで、特定のトナー粒子に顔料等が偏在しないことを知
見した。According to studies by the present inventors, by dispersing fine particles pre-treated with silicone oil in the core material constituting the capsule toner, the offset performance of the toner can be significantly improved, and fine particles such as pigments can be evenly dispersed. It was discovered that pigments and the like are not unevenly distributed in specific toner particles.
本発明のカプセルトナーにおいて、このような作用を発
揮する理由は必ずしも明確ではないが以下のように推定
される。The reason why the capsule toner of the present invention exhibits such an effect is not necessarily clear, but it is presumed as follows.
すなわち、微粒子をシリコーンオイル処理し、芯物質中
に含有させる場合には、直接シリコーンオイルを芯物質
中に添加する方法と比較１，５て、シリコーンオイルが
芯物質中に均一に分散される。That is, when fine particles are treated with silicone oil and incorporated into the core material, the silicone oil is more uniformly dispersed in the core material, compared to a method in which silicone oil is directly added to the core material1,5.
すなわち、微粒子をシリコーンオイル処理することで、
微粒子表面にシリコーンオイルの膜を形成し、微粒子の
凝集を防ぎ、加えて、シリコーンオイルを吸着した微粒
子を芯物質中に均一に分散させることが可能になる。そ
のため、微粒子及びその表面に吸着したシリコーンオイ
ルの分散が芯物質中で均一に行なわれ、オフセット性ｆ
Ｅが向上し、さらに、濃度ムラのない均一な画像が得ら
れるものと考えられる。In other words, by treating fine particles with silicone oil,
A film of silicone oil is formed on the surface of the fine particles to prevent agglomeration of the fine particles, and in addition, it becomes possible to uniformly disperse the fine particles adsorbed with silicone oil in the core material. Therefore, the fine particles and the silicone oil adsorbed on their surfaces are uniformly dispersed in the core material, and the offset property f
It is considered that E is improved and a uniform image without density unevenness can be obtained.
未発１！１１のカプセルトナーにおいては、芯物質中に
含まれる体積平均粒径１．０〜ｏ、ｏｉｇ謬、より好ま
しくは体積平均粒径０．５〜０．０５弘腸の粒度範囲に
ある微粒子を、シリコーンオイルで処理することが特徴
である。芯物質中に′含まれる微粒子の体積平均粒径が
１．（Ｉｇ、＋ｉより大きい場合には、体積平均粒径１
０．０μｍ程度のトナーに対しては微粒子の粒径が大き
く、芯物質中′にシリコーンオイルが十分均一に分散す
ることができない。また、芯物質中に含まれる微粒子の
体積平均粒径が０．０１μ腫より小さい場合には、シリ
コーンオイルで処理する段階で微粒子の凝集が十分はぐ
れず、カプセルトナー化）、。In the capsule toner of Unreleased 1!11, the volume average particle size contained in the core substance is in the particle size range of 1.0 to 0,000 g, more preferably the volume average particle size is 0.5 to 0.05 h. It is characterized by treating certain fine particles with silicone oil. The volume average particle size of the fine particles contained in the core material is 1. (If larger than Ig, +i, volume average particle size 1
For a toner of about 0.0 μm, the particle size of the fine particles is large, and the silicone oil cannot be sufficiently uniformly dispersed in the core material. In addition, if the volume average particle size of the fine particles contained in the core material is smaller than 0.01 μm, the fine particles are not sufficiently aggregated during the treatment with silicone oil and are turned into capsule toner).
た場合、微粒子の偏在が見られ、画像濃度ムラの原因と
なる。また、同時にシリコーンオイルの分散不良から、
オフセット性能も不十分となる。In this case, uneven distribution of fine particles is observed, which causes unevenness in image density. At the same time, due to poor dispersion of silicone oil,
Offset performance also becomes insufficient.
本発明のカプセルトナーの芯物質中に含有する微粒子ｌ
よ、シリコーンオイルであらかじめ処理されて使用され
る。このようなシリコーンオイルの例を以下に示す。Fine particles contained in the core material of the capsule toner of the present invention
Yes, it is pre-treated with silicone oil before use. Examples of such silicone oils are shown below.
ジメチルシリコーンオイル、メチルフェニルシリコーン
オイル、に代表される一連のシリコーンオイル。また、
アミ！変性シリコーンオイル、α−メチルスチレン変性
シリコーンオイル、アルキル変性シリコーンオイル、ア
ルコール変性シリコーンオイル、ポリエーテル変性シリ
コーンオイル、等の変性シリコーンオイルが挙げられる
。A series of silicone oils represented by dimethyl silicone oil and methylphenyl silicone oil. Also,
Ami! Modified silicone oils include modified silicone oil, α-methylstyrene-modified silicone oil, alkyl-modified silicone oil, alcohol-modified silicone oil, polyether-modified silicone oil, and the like.
本発明に使用される微粒子の具体的製造方法としては、
例えば、微粒子に適当なせん断力（場合によっては熱と
併用）を与え微粒子の凝集物をほぐしながらシリコーン
オイルを徐々に加えて行く方法が考えられる。A specific method for producing the fine particles used in the present invention is as follows:
For example, a method can be considered in which silicone oil is gradually added while applying an appropriate shearing force (combined with heat in some cases) to the fine particles to loosen aggregates of the fine particles.
このように処理された微粒子中のシリコーンオイル含有
量は、微粒子に対して、３０〜１．０重量部、より好ま
しくは２５〜２．０重量部が良い。The silicone oil content in the fine particles treated in this way is preferably 30 to 1.0 parts by weight, more preferably 25 to 2.0 parts by weight, based on the fine particles.
本発明に用いる微粒子とは、例えば、着色剤、磁性粉、
笠を示す。The fine particles used in the present invention include, for example, colorants, magnetic powders,
Showing a hat.
このような着色剤としては、従来公知の顔料、例えばア
ントラキノン系、キナクリドン系、フタロシアニン系、
ペリレン系、ペリノン系、アゾ系等の各種有機顔料及び
酸化チタン、酸化鉄、黄鉛、群青、紺Ｎ等の各種無機顔
料あるいは、各種金属酸化物や金属塩化物又はこれらの
混合物、金属錯体などの金属化合物等が使用できる。Such colorants include conventionally known pigments such as anthraquinone, quinacridone, phthalocyanine,
Various organic pigments such as perylene-based, perinone-based, and azo-based pigments; various inorganic pigments such as titanium oxide, iron oxide, yellow lead, ultramarine, and navy blue; various metal oxides and metal chlorides; mixtures thereof; metal complexes, etc. metal compounds etc. can be used.
これらのｎ色剤は、前記方法によってシリコーンオイル
であらかじめ処理されて使用され、一般に２成分現像剤
用のカプセルトナーを得るために用いられ、芯材バイン
ダー１００重φ部に対し０．５〜１５東量部の割合で加
えることが好ましい。These n coloring agents are used after being pretreated with silicone oil by the method described above, and are generally used to obtain capsule toners for two-component developers. It is preferable to add it in a proportion of 100%.
また、磁性粉としては、磁場の中にとかれて磁化される
物質が用いられ、鉄、コバルト、−−ツヶルなどの強磁
性金属の粉末、もしく Ｊｄマグネタイト、ヘマタイト
、フェティトなどの合金や化合物がある。この磁性粉を
着色剤と兼用させてもよい。In addition, as the magnetic powder, substances that are magnetized when dissolved in a magnetic field are used, such as powders of ferromagnetic metals such as iron, cobalt, and Tsugaru, or alloys and compounds such as Jd magnetite, hematite, and fetite. There is. This magnetic powder may also be used as a coloring agent.
これらの磁性粉は、前記方法によ−〕てシリコーンオイ
ルであらかじめ処理されて使用され、一般にｌ成分磁性
トナーとして用いられ、芯物質中の全ての樹脂１００重
量部に対して５０〜９０重量部の範囲が良い。These magnetic powders are used after being pretreated with silicone oil by the above-mentioned method, and are generally used as component 1 magnetic toners, in an amount of 50 to 90 parts by weight based on 100 parts by weight of the total resin in the core material. Good range.
本発明のカプセルトナーの芯物質は、基本的には、圧力
定着性成分としての樹脂中に、上述の微粒子を分散させ
て微粒化してなる。芯物質を構成する樹脂としては、好
ましい定着性を示す軟質固体状物質は、すべて利用でき
る。このような物質としては、ワー、クス類（密ろう、
カルナウバろう、パラフィンワックス、マイクロクリス
タリンワックスなど）、高級脂肪酸（ステアリン酸、バ
ルミチン酸、ラウリン酸など）、高級脂肪酸金属塩（ス
テアリン酸アルミニウム、ステアリン酸鉛、ステアリン
酸バリウム、ステアリン酸マグネシウム、ステアリン酸
亜鉛、パルミチン酸亜鉛など）、高級脂肪酸誘導体（メ
チルヒドロキシステアレート、グリセロールモノヒドロ
キシステアレートなど）、ポリオレフィン（低分子量ポ
リエチレン、低分子量ポリプロピレン、酸化ポリエチレ
ン、ポリイソブチレン、ポリ４弗化エチレンなど）及び
これらのアミノ基含有モノマーとの化学反応物、オレフ
ィン共重合体（エチレン−アクリル酸共重合体、エチレ
ン−アクリル酸エステル共重合体、エチレン−メタクリ
ル酸共重合体、エチレン−メタクリル酸エステル共重合
体、エチレン−塩化ビニル共重合体、エチレン−酢酸ビ
ニル共重合体、アイオノマー樹脂など）、スチレン系樹
脂（低分子量ポリスチレン、スチレン−ブタジェン共重
合体（七ツマー重量比５〜３０：９５〜７０）、スチレ
ン−アクリル系化合物共重合体など）、エポキシ樹脂、
ポリ−エステル樹脂（酸価１０以下）、ゴム類（インブ
チレンゴム、ニトリルゴム、Ｉ化ゴムなど）、ポリビニ
ルピロリドン、ポリアミド、クマロン−インデン樹脂、
メチルビニルエーテル−無水マレイン酸共重合体、マレ
イン酸変性フェノール樹脂、フェノール変性テルペン樹
脂、シリコン樹脂などがあり、これらの中から単独又は
組合せて用いることができる。The core material of the capsule toner of the present invention is basically formed by dispersing the above-mentioned fine particles in a resin as a pressure fixing component. As the resin constituting the core material, any soft solid material exhibiting favorable fixing properties can be used. Such substances include wax, beeswax,
carnauba wax, paraffin wax, microcrystalline wax, etc.), higher fatty acids (stearic acid, valmitic acid, lauric acid, etc.), higher fatty acid metal salts (aluminum stearate, lead stearate, barium stearate, magnesium stearate, zinc stearate) , zinc palmitate, etc.), higher fatty acid derivatives (methyl hydroxystearate, glycerol monohydroxystearate, etc.), polyolefins (low molecular weight polyethylene, low molecular weight polypropylene, polyethylene oxide, polyisobutylene, polytetrafluoroethylene, etc.) and these Chemical reaction products with amino group-containing monomers, olefin copolymers (ethylene-acrylic acid copolymers, ethylene-acrylic ester copolymers, ethylene-methacrylic acid copolymers, ethylene-methacrylic ester copolymers, ethylene - vinyl chloride copolymer, ethylene-vinyl acetate copolymer, ionomer resin, etc.), styrenic resin (low molecular weight polystyrene, styrene-butadiene copolymer (hetamine weight ratio 5-30:95-70), styrene- acrylic compound copolymers, etc.), epoxy resins,
Polyester resin (acid value 10 or less), rubbers (inbutylene rubber, nitrile rubber, I rubber, etc.), polyvinylpyrrolidone, polyamide, coumaron-indene resin,
Examples include methyl vinyl ether-maleic anhydride copolymer, maleic acid-modified phenol resin, phenol-modified terpene resin, and silicone resin, and these can be used alone or in combination.
本発明のカプセルトナーの芯材は、上記成分を、例えば
溶融混練し、スプレードライヤー等にて造粒し、更に必
要に応じて分級することにより１体積平均粒径が５〜２
０終の微粒子として３Ｉ製される。The core material of the capsule toner of the present invention can be obtained by melt-kneading the above-mentioned components, granulating them using a spray dryer, etc., and further classifying them if necessary, so that the average particle size per volume is 5 to 2.
3I is produced as fine particles with zero end.
上記のようにして得られた芯物質粒子を殻材樹脂により
被覆する。殻材樹脂としては、公知の樹脂が使用可能で
あり、例えば、次の様なモノマー類から成る樹脂がある
。スチレン、Ｐ−クロルスチレン、Ｐ−ジメチルアミノ
−スチレンなどのスチレン及びその置換体；アクリル酸
メチル、アクリル酸エチル、アクリル酸ブチル、メタク
リル酸メチル、メタクリル酸エチル、メタクリル酸ブチ
ル、メタクリル酸Ｎ、Ｎ−ジメチルアミノエチルエステ
ルなどのアクリル酸あるいはメタクリル酸のエステル；
無水マレイン酸あるいは無水マレイン酸のハーフエステ
ル、ハーフアミドあるいはジエステルイミド、ビニルピ
リジン、トビニルイミダゾールなどの含窒素ビニル；ビ
ニルポルマール、ビニルブチラールなどのビニルアセタ
ール；塩化ビニル、アクリロニトリル、酢酸ビニルなど
のビニルモノマー：塩、化ビニリデン、フッ化ビニリデ
ンなどのビニリデンモノマー：エチレン、プロピレンな
どのオレフィンモノマーである。また、ポリエステル、
ポリカーボネート、ポリスルホネート、ポリアミド、ポ
リウレタン、ポリウレア、エポキシ樹脂、ロジン、変成
ロジン、テルペン樹脂、フェノール樹脂、脂肪族又は脂
環族炭化水素樹脂、芳香族系石油樹脂、メラミン樹脂、
ポリフェニレンオキサイドのようなポリエーテル樹脂あ
るいはチオエーテル樹脂、などの単独重合体、あるいは
共重合体、もしくは混合物が使用できる。The core material particles obtained as described above are coated with a shell material resin. As the shell material resin, known resins can be used, such as resins made of the following monomers. Styrene and its substituted products such as styrene, P-chlorostyrene, and P-dimethylamino-styrene; methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, N, N methacrylate - esters of acrylic or methacrylic acid, such as dimethylaminoethyl ester;
Nitrogen-containing vinyls such as maleic anhydride or half esters, half amides or diesterimides of maleic anhydride, vinylpyridine and tovinylimidazole; Vinyl acetals such as vinyl polymer and vinyl butyral; Vinyls such as vinyl chloride, acrylonitrile and vinyl acetate. Monomer: Vinylidene salt, vinylidene chloride, vinylidene fluoride, etc. Monomer: Olefin monomer such as ethylene, propylene, etc. Also, polyester,
Polycarbonate, polysulfonate, polyamide, polyurethane, polyurea, epoxy resin, rosin, modified rosin, terpene resin, phenolic resin, aliphatic or alicyclic hydrocarbon resin, aromatic petroleum resin, melamine resin,
Homopolymers, copolymers, or mixtures of polyether resins such as polyphenylene oxide or thioether resins can be used.
これら重合体を外殻とするカプセルトナーを得るには、
種々の公知のカプセル化技術を利用することができる０
例えば、スプレードライ法、液中乾燥法、相分離法など
が好適に使用できるほか、１ｎ−ｓｉｔｕ重合法、米国
特許第３，３３８，９９１号明細書、同第３．３２８．
８４８号明細書、同第３．５０２．５８２号明細書に記
載されている方法なども使用できる。To obtain a capsule toner having an outer shell made of these polymers,
Various known encapsulation techniques can be utilized.
For example, spray drying method, submerged drying method, phase separation method, etc. can be suitably used, as well as 1n-situ polymerization method, US Pat. No. 3,338,991, US Pat. No. 3,328.
The methods described in Japanese Patent No. 848 and Japanese Patent No. 3.502.582 can also be used.
かくして得られる本発明のカプセルトナーは、一般に、
０．０５〜０．５にの厚さの外殻を有し、体積平均粒径
が６〜２２．のマイクロカプセルとなる。The capsule toner of the present invention thus obtained generally has the following characteristics:
It has an outer shell thickness of 0.05 to 0.5 mm and a volume average particle size of 6 to 22 mm. become microcapsules.
本発明のカプセルトナーには、先にも述べたように、更
に荷電制御、流動性付与、着色等の目的でカーボンブラ
ック、各種染顔料、疎水性コロイド状シリカ等を外添混
合することができ、それらの添加効果を安定的に発揮せ
しめることができる。これら外添成分はカプセルトナ−
１ｏｏ部に対１、て０．μｍ〜５？Ｂ程度が適当である
。As mentioned above, carbon black, various dyes and pigments, hydrophobic colloidal silica, etc. can be externally added to the capsule toner of the present invention for the purpose of charge control, fluidity imparting, coloring, etc. , it is possible to stably exhibit the effects of their addition. These external additive ingredients are used in capsule toner.
1 to 10 parts, 0. μm~5? A grade of B is appropriate.
［実施例］ 以下、部は重量部を意味する。[Example] Hereinafter, parts mean parts by weight.
製造例１
攪拌機、温度計、滴下ロートを備えたフラスコを、ホッ
トプレート上にセットし、体積平均粒径０．１μｍのア
ゾ系顔料１００部をフラスコ内に入れ強攪拌先行なった
。さらに、強攪拌を行ないつつホットプレートを６０℃
に加熱し、６０℃に保ったジメチルシリコーンオイル１
０部を滴下ロートにより滴ドした。滴下終了後５分間攪
拌を続は室温まで冷却し、処理品Ａを得た。Production Example 1 A flask equipped with a stirrer, a thermometer, and a dropping funnel was set on a hot plate, and 100 parts of an azo pigment having a volume average particle diameter of 0.1 μm was placed in the flask and vigorously stirred. Furthermore, while stirring strongly, heat the hot plate to 60°C.
Dimethyl silicone oil heated to 60℃ and kept at 60℃
0 part was added dropwise through a dropping funnel. After the dropwise addition was completed, the mixture was stirred for 5 minutes and then cooled to room temperature to obtain treated product A.
覧五１ス
体ｖｔモ均粒径０．ＩＩＬｍのアゾ系顔料１００部のか
わりに１体積モ均粒径０．０５μ層のフタロシアニン系
顔料１００部を用いた以外は、製造例１と同様の方法で
処理品Ｂを得た。Table 1. Average particle size of the 1st mass body: 0. A treated product B was obtained in the same manner as in Production Example 1, except that 100 parts of a phthalocyanine pigment having an average particle diameter of 0.05 μm layer per volume was used instead of 100 parts of the azo pigment of IILm.
正直ＡＡ
体積平均粒径０＝μ厘のアゾ系顔料１００部のがわりに
、体積平均粒径０．２）Ｌｍの磁性体を１００部、ジメ
チルシリコーンオイル１０部のかわりにアミノ変性シリ
コーンオイル５部を用いた以外は、製造例１と同様の方
法で゛処理品Ｃを得た。Honest AA Instead of 100 parts of azo pigment with a volume average particle size of 0 = μ, 100 parts of a magnetic material with a volume average particle size of 0.2) Lm, and 5 parts of amino-modified silicone oil instead of 10 parts of dimethyl silicone oil. A treated product C was obtained in the same manner as in Production Example 1 except that .
実施例１
芯材料としてパラフィンワックス８０部、ポリエチレン
ワックス２０部、及び処理品Ａ１．０部を溶融混合しス
プレードライヤーで造粒を行ない、さらに分級すること
により、体積平均粒径が１２、θμ層の球状芯物質を得
た。この芯物質金、有機相からの相分離方法によりスチ
レン−ジメチルアミ２ノエチルメタクリレート（モル比
８５／１５）共重合体で０．３０μ諺の膜厚で被覆しカ
プセル粒子を得た。Example 1 80 parts of paraffin wax, 20 parts of polyethylene wax, and 1.0 part of treated product A were melt-mixed as core materials, granulated with a spray dryer, and further classified to form a core material with a volume average particle diameter of 12 and a θμ layer. A spherical core material was obtained. This core material gold was coated with a styrene-dimethylamino 2-noethyl methacrylate (molar ratio 85/15) copolymer to a film thickness of 0.30 .mu.m by a phase separation method from the organic phase to obtain capsule particles.
次に、このカプセル化粒子１００ｇに疎水性シリカ１．
ｆ） ｌ：を外添混合し、カプセルトナーを得た。Next, 1.0 g of hydrophobic silica was added to 100 g of the encapsulated particles.
f) l: was externally added and mixed to obtain a capsule toner.
このカプセルトナー！Ｏｇに鉄粉キャリア９０ｇを混合
し、現像剤とした後、上質紙上に転写した。４１）られ
た転写紙を２本の加圧ローラーからなる圧力定着機を通
したところ、１０ｋｇ／Ｃｍの線圧力でほぼ完全な定着
性を示し、画像濃度は高く、シミ等の濃淡ムラのない鮮
明な画像が形成された。同時に定着ローラー上のオフセ
ットを観察したところ、オフセ−／ トは全く見られず
、定着画像上にもオフセー、１・に起因する汚れは全く
見られなかった。さらにＡ４サイズの原稿を２０００枚
耐久試験を行なったところ、定着ローラーへのオフセッ
トは見られず、得られた画像はシミ等の濃淡ムラのない
鮮明なものであった。This capsule toner! After mixing Og with 90 g of iron powder carrier to prepare a developer, the developer was transferred onto high-quality paper. 41) When the transferred transfer paper was passed through a pressure fixing machine consisting of two pressure rollers, it showed almost perfect fixing performance with a linear pressure of 10 kg/cm, and the image density was high and there was no unevenness in density such as stains. A clear image was formed. At the same time, when the offset on the fixing roller was observed, no offset was observed, and no stains due to offset or 1. were observed on the fixed image. Furthermore, when a durability test was performed on 2,000 sheets of A4 size originals, no offset to the fixing roller was observed, and the images obtained were clear and free from unevenness in density such as stains.
実施例２
処理品Ｂを用いる以外は、実施例１と同様の方法をくり
返した。Example 2 The same method as Example 1 was repeated except that treated product B was used.
結果は、初期、耐久時ともに″オフセットは見られず、
実施例１と同等にシミ等のｅ淡ムラのない！′Ｆ明な画
像が得られた。As a result, no offset was observed both at the initial stage and during durability.
Same as Example 1, no unevenness such as stains! 'F A clear image was obtained.
実施例３
処理品Ｃを６０部用いる以外は、実施例１と同様の方法
でカプセルトナーを得た。このカプセルトチ−をそのま
ま現像剤として用い、実施例１と同様の方法で画出し試
験を行なった。Example 3 A capsule toner was obtained in the same manner as in Example 1, except that 60 parts of treated product C was used. An image formation test was carried out in the same manner as in Example 1 using this capsule torch as it was as a developer.
結果は、初期、耐久時ともにオフセットは見られず、実
施例１と同等に鮮明な画像が得られた。As a result, no offset was observed both at the initial stage and during durability, and a clear image equivalent to that of Example 1 was obtained.
比較例１
処理品Ａを用いるかわりに、アゾ系顔料をそのまま用い
、実施例′１と同様の方法をくり返した。Comparative Example 1 Instead of using treated product A, the azo pigment was used as it was, and the same method as in Example '1 was repeated.
その結果、定着ローラーに画像を１枚通したところ、定
着ローラーににオフセットによる汚れが発生した。さら
に、画像を１００枚通紙したところ、定着ローラー上の
オフセー７トはさらにひどくなり、定着画像上にも定着
ローラー上の汚れが現れた。さらに画像上には、初期か
ら１００枚を通じて顔料の分散不良が原因と思われるシ
ミ状の濃淡ムラが発生した。As a result, when one image was passed through the fixing roller, stains due to offset occurred on the fixing roller. Furthermore, when 100 images were passed through the paper, the offset on the fixing roller became even worse, and stains on the fixing roller also appeared on the fixed images. Furthermore, stain-like unevenness in density appeared on the images from the initial stage through the 100th printing, which was thought to be caused by poor dispersion of the pigment.
［発明の効果］
本発明によれば、シリコーンオイル処理された特定粒径
の微粒子を芯物質中に含有させるため、オフセットがな
く、画像濃度ムラのない良好な画像を与える。更に、コ
ピー又はプリントアウトを続けた場合でも、初期画像と
同様な高画質を保持するものである。[Effects of the Invention] According to the present invention, fine particles of a specific particle size treated with silicone oil are contained in the core material, so that a good image without offset and without uneven image density is provided. Furthermore, even if copying or printing is continued, the same high image quality as the initial image is maintained.
Claims (1)
少なくとも一部を覆う外殻とから構成されるカプセルト
ナーに於いて、該芯物質中に、シリコーンオイルであら
かじめ処理され、かつ体積平均粒径１．０μｍ〜０．０
１μｍの範囲にある微粒子を含有することを特徴とする
圧力定着性カプセルトナー。(1) In a capsule toner composed of a core material containing a pressure fixing component and an outer shell covering at least a portion of the core material, the core material is pretreated with silicone oil, and Volume average particle diameter 1.0 μm ~ 0.0
A pressure fixable capsule toner characterized by containing fine particles in the range of 1 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63279471A JPH02126265A (en) | 1988-11-07 | 1988-11-07 | Pressure fixable capsule toner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63279471A JPH02126265A (en) | 1988-11-07 | 1988-11-07 | Pressure fixable capsule toner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02126265A true JPH02126265A (en) | 1990-05-15 |
Family
ID=17611522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63279471A Pending JPH02126265A (en) | 1988-11-07 | 1988-11-07 | Pressure fixable capsule toner |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02126265A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0658819A2 (en) | 1993-11-30 | 1995-06-21 | Canon Kabushiki Kaisha | Toner and developer for developing electrostatic image, process for production thereof and image forming method |
| KR100708993B1 (en) * | 2005-06-07 | 2007-04-18 | 주식회사 엘지화학 | Polymeric lubricant having multi layer structure and manufacturing method thereof |
-
1988
- 1988-11-07 JP JP63279471A patent/JPH02126265A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0658819A2 (en) | 1993-11-30 | 1995-06-21 | Canon Kabushiki Kaisha | Toner and developer for developing electrostatic image, process for production thereof and image forming method |
| KR100708993B1 (en) * | 2005-06-07 | 2007-04-18 | 주식회사 엘지화학 | Polymeric lubricant having multi layer structure and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS60158460A (en) | Encapsulated toner | |
| JPH0431581B2 (en) | ||
| JPS5927900B2 (en) | Magnetic developer and its manufacturing method | |
| JPH026962A (en) | Metallic capsule toner and its production | |
| JPH0812451B2 (en) | Method for producing encapsulated toner composition | |
| JPH02126265A (en) | Pressure fixable capsule toner | |
| JPH01259369A (en) | Toner encapsulated in microcapsule | |
| JPS58211159A (en) | Magnetic toner | |
| JPH01100561A (en) | Pressure fixable capsule toner | |
| JPS59123847A (en) | Capsulated toner | |
| JP2568176B2 (en) | Capsule toner | |
| JPS6159351A (en) | Capsule toner | |
| JPS6183546A (en) | Color toner kit | |
| JPH026053B2 (en) | ||
| JPS6183549A (en) | Manufacture of capsule toner | |
| JP4261642B2 (en) | Magnetic toner for development and development method | |
| JPS6159363A (en) | Image forming method | |
| JPS6165260A (en) | Capsule toner | |
| JPS59170853A (en) | Toner for developing electrostatic charge image | |
| JPH02105162A (en) | Production of microcapsule toner | |
| JPS60107037A (en) | Encapsulated toner | |
| JPH0322980B2 (en) | ||
| EP0402882A2 (en) | Master batch for production of toners used in electrophotography | |
| JPS63128356A (en) | Insulating magnetic capsule toner | |
| JPH01224775A (en) | Production of encapsulated toner |