JPH02120358A - Thermoplastic polyurethane resin composition - Google Patents
Thermoplastic polyurethane resin compositionInfo
- Publication number
- JPH02120358A JPH02120358A JP63273151A JP27315188A JPH02120358A JP H02120358 A JPH02120358 A JP H02120358A JP 63273151 A JP63273151 A JP 63273151A JP 27315188 A JP27315188 A JP 27315188A JP H02120358 A JPH02120358 A JP H02120358A
- Authority
- JP
- Japan
- Prior art keywords
- polyurethane resin
- thermoplastic polyurethane
- resin composition
- composition according
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims abstract description 26
- 239000011342 resin composition Substances 0.000 title claims description 18
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 16
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract 2
- 229920001577 copolymer Polymers 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 210000001124 body fluid Anatomy 0.000 claims description 3
- 239000010839 body fluid Substances 0.000 claims description 3
- 230000000704 physical effect Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 14
- 239000004593 Epoxy Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 description 19
- 239000002253 acid Substances 0.000 description 9
- 229920005749 polyurethane resin Polymers 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000005056 polyisocyanate Substances 0.000 description 8
- 229920001228 polyisocyanate Polymers 0.000 description 8
- 150000005846 sugar alcohols Polymers 0.000 description 8
- 229920005906 polyester polyol Polymers 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- -1 hydroxyl compound Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 239000011976 maleic acid Substances 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NEKBPETURGFTNC-UHFFFAOYSA-N 3-[(2,3-diisocyanato-6-methylphenyl)-phenylmethyl]-1,2-diisocyanato-4-methylbenzene Chemical compound CC1=CC=C(N=C=O)C(N=C=O)=C1C(C=1C(=C(N=C=O)C=CC=1C)N=C=O)C1=CC=CC=C1 NEKBPETURGFTNC-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- YHTLGFCVBKENTE-UHFFFAOYSA-N 4-methyloxan-2-one Chemical compound CC1CCOC(=O)C1 YHTLGFCVBKENTE-UHFFFAOYSA-N 0.000 description 1
- 241001323275 Andex Species 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical group CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- GMBHLHMRHUMBHU-UHFFFAOYSA-N butan-2-one;hydrochloride Chemical compound Cl.CCC(C)=O GMBHLHMRHUMBHU-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical group C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 210000004013 groin Anatomy 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 150000003440 styrenes Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、熱可塑性ポリウレタン樹脂組成物、特にフィ
ルム、シートとして用いた時のしなやかさといった感触
に優れたエラスチックフィルム用組成物に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a thermoplastic polyurethane resin composition, particularly a composition for elastic films that has excellent feel such as flexibility when used as a film or sheet. .
（従来の技術及びその問題点）
従来の紙おむつ等の体液処理用品用エラスチックフィル
ムは、素材としてＳＢＲ（スチレンーブタジエン系ラバ
ー）単独樹脂、ＳＢＲ／熱可塑性ポリウレタン樹脂ブレ
ンド系樹脂、または熱可塑性ポリウレタン単独樹脂に酸
アマイド系滑剤等を添加し粘着防止を施すことなどが行
われているが、しなやかさがなく（低モジュラスが高い
）、伸びも少なく、幼児用紙おむつに使用する際、肌を
強くしめつけられると共に大人用、幼児用としてフィル
ムブレード又はフィルムの構成を変更する等の工夫によ
って使用しているのが現状で、今だ充分満足できるエラ
スチックフィルムが得られていない。(Prior art and its problems) Conventional elastic films for body fluid treatment products such as disposable diapers are made of SBR (styrene-butadiene rubber) alone, SBR/thermoplastic polyurethane resin blend, or thermoplastic polyurethane alone. Although acid amide lubricants are added to the resin to prevent adhesion, it is not flexible (high low modulus) and has little elongation, so when used in infant disposable diapers, it does not tightly tighten the skin. Currently, elastic films are used for adults and children by changing the structure of the film blade or film, and a fully satisfactory elastic film has not yet been obtained.
（問題を解決するための手段）
本発明者らは上記の如き欠点のない熱可塑性Ｉリウレタ
ン樹脂組成物のエラスチックフィルムをｔｒ＋るべく鋭
意研究した結果、熱可塑性ポリウレタン樹脂に、カルブ
キシル基および／又はエポキシ基賞性オレフィン共重合
体を配合して成る組成物が相溶性に優れ、ポリウレタン
樹脂の優れた特性を失なうことなく、しなやかさが付与
され、成形時又は、フィルム巻き取り時の粘着性もなく
、実用性の極めて高い組成物を見い出し、本発明を完成
するに至った。(Means for Solving the Problem) As a result of intensive research by the present inventors in order to develop an elastic film made of a thermoplastic I-urethane resin composition free from the above-mentioned drawbacks, we found that the thermoplastic polyurethane resin has a carboxylic group and/or A composition containing an epoxy-based olefin copolymer has excellent compatibility, provides flexibility without losing the excellent properties of polyurethane resin, and has excellent adhesion during molding or film winding. The present inventors have discovered a composition that is both free and highly practical, and have completed the present invention.
すなわち、本発明は、熱可塑性ポリウレタン樹脂■、変
性ポリオレフィン樹脂（ｎ）とからなる熱可塑性ポリウ
レタン樹脂組成物、及びこの熱可塑性ポリウレタン樹脂
組成物を用いたことを特徴とするエラスチックフィルム
もしくはシートを提供するものである。That is, the present invention provides a thermoplastic polyurethane resin composition comprising a thermoplastic polyurethane resin (1) and a modified polyolefin resin (n), and an elastic film or sheet characterized by using this thermoplastic polyurethane resin composition. It is something to do.
（構 成）
本発明で使用する熱可塑性ポリウレタン樹脂は、好まし
くは、２５℃で硬度（ＪＩＳ ）が８０〜１００、特に
好ましくは８５〜９５０、抗張力が好ましくは２００
ｋｇ／ａｎ２以上、特に好ましくは３００〜５００ ｋ
ｇ７’ｍ２．破断伸度が好ましくは３００％以上、特に
好ましくは４００チ以上の物性を有するものであり、ポ
リヒドロキシル化合物（？リオール成分）と、ｌβリイ
ソシアネート化合物（イソシアネート成分）とを反応し
てなるポリウレタン樹脂が好ましく使用出来る。(Structure) The thermoplastic polyurethane resin used in the present invention preferably has a hardness (JIS) of 80 to 100 at 25°C, particularly preferably 85 to 950, and preferably a tensile strength of 200.
kg/an2 or more, particularly preferably 300 to 500 k
g7'm2. A polyurethane resin having physical properties such that the elongation at break is preferably 300% or more, particularly preferably 400% or more, and is obtained by reacting a polyhydroxyl compound (?liol component) and an lβ-liisocyanate compound (isocyanate component). can be preferably used.
、１？ ＩＪヒドロキシル化合物としては、例えば一般
のウレタン化合物の製造に用いられる種々のポリエステ
ルポリオール及び／又はポリエーテルポリオールが挙げ
られる。, 1? Examples of the IJ hydroxyl compound include various polyester polyols and/or polyether polyols used in the production of general urethane compounds.
ここで言うポリエステルポリオールとは、多価アルコー
ルと多塩晶性カルがン酸の縮合物、ヒドロキシカルボン
酸と多価アルコールの縮合物などが挙げられ、これらに
使用される多価アルコールとしては例えばエチレングリ
コール、プロピレングリコール、ブタン・ジオール、ジ
エチレングリコール、グリセリン、ヘキサントリオール
、トリメチロールプロノクンなどが挙げられ、多塩基性
カルボン酸としては例えばアジピン酸、ゲルタール酸。The polyester polyols mentioned here include condensates of polyhydric alcohols and polyhydric crystalline carboxylic acids, condensates of hydroxycarboxylic acids and polyhydric alcohols, etc. The polyhydric alcohols used in these include, for example. Examples of the polybasic carboxylic acids include ethylene glycol, propylene glycol, butane diol, diethylene glycol, glycerin, hexanetriol, and trimethylolpronocone, and examples of polybasic carboxylic acids include adipic acid and geltaric acid.
アゼライン酸、フマール酸、マレイン酸、フタール酸、
テレフタール酸、ダイマー酸、ピロメリット酸などが挙
げられる。又、ヒドロキシカルボン酸と多価アルコール
の縮合物としてはヒマシ油、ヒマシ油トエチレングリコ
ール、フロピレンクリコールなどの反応生成物も有用で
ある。更にポリエステルポリオールとしては、ε−カプ
ロラクトン等のラクトン順を開環重合して得られるラク
トン系ポリエステルポリオール類も用いる本が出来る。azelaic acid, fumaric acid, maleic acid, phthalic acid,
Examples include terephthalic acid, dimer acid, and pyromellitic acid. Also useful as condensates of hydroxycarboxylic acids and polyhydric alcohols are reaction products such as castor oil, castor oil, ethylene glycol, and phlopylene glycol. Furthermore, as polyester polyols, lactone-based polyester polyols obtained by ring-opening polymerization of lactones such as ε-caprolactone can also be used.
このラクトン系ポリエステルポリオール類としては、先
に述べた多価アルコール類にと一カプロラクトン、δ−
バレロラクトン、β−メチル−δ−バレロラクトン等の
一種又は二種以上を付加重合させたものがいずれも使用
出来る。These lactone-based polyester polyols include the polyhydric alcohols mentioned above, monocaprolactone, δ-
Any addition polymerization of one or more types of valerolactone, β-methyl-δ-valerolactone, etc. can be used.
ポリエーテルポリオールとしては例えばエチレンオキサ
イド、プロピレンオキサイド、ブチレンオキサイド、テ
トラヒドロフランなどのアルキレンオキサイＰの一種も
しくは二種以上を、２個以上の活性水素を有する化合物
に付加重合せしめた生成物であり、通常のポリウレタン
樹脂の製造に用いられる公知のポリエーテルポリオール
がいずれも使用できる。この場合２個以上の活性水素を
有する化合物としては、例えば先にのべた多価アルコー
ル、多塩基性カルボン酸の他、エチレンシアミン、ヘキ
サメチレンジアミンなどのアミン頌、エタノールアミン
、フロパノールアミンなどのアルカノールアミン類、レ
ゾルシン、ビスフェノールの如き多価フェノール類、ヒ
マシ油などが挙げられる。Polyether polyols are products obtained by addition-polymerizing one or more alkylene oxides P such as ethylene oxide, propylene oxide, butylene oxide, and tetrahydrofuran to a compound having two or more active hydrogens, and are usually Any of the known polyether polyols used in the production of polyurethane resins can be used. In this case, examples of compounds having two or more active hydrogens include, in addition to the polyhydric alcohols and polybasic carboxylic acids mentioned above, amines such as ethylenecyamine and hexamethylene diamine, ethanolamine, and furopanolamine. Examples include alkanolamines such as resorcinol, polyhydric phenols such as bisphenol, and castor oil.
ポリヒドロキシル化合物は、ポリエステルポリオール及
びポリエーテルポリオールの一種もしくは二種以上を用
い、更にこれらに先に述べた多価アルコールの如き低分
子！ポリヒドロキシ化合物を鎖伸長剤として併用して屯
良い。The polyhydroxyl compound uses one or more of polyester polyols and polyether polyols, and further contains low molecules such as the polyhydric alcohols mentioned above! A polyhydroxy compound may also be used as a chain extender.
ポリイソシアネート化合物とは、分子中にインシアネー
ト基を２個以上有する化合物であり、通常のポリウレタ
ン樹脂４脂の製造に用いられる種々のものが使用でき、
例えばトリレンジイソシアネート、ジフェニルメタンジ
イソシアネート、ジアニジンノイソシアネート、ナフタ
レンジイソ７アネート、トリフェニルメタントリイソシ
アネート、ビス（ジイソシアナトトリル）フェニルメタ
ン、ポリメチレンポリフェニルポリイソシアネートなど
の芳香族系ポリイソシアネート化合物、脂肪族系又は脂
環族系のポリイソシアネート化合物としては、インホロ
ンジイソシアネート、ジシクロヘキシルメタンジイソシ
アネート（水素添加ジフェニルメタ７ジインシアネート
）、ヘキサメチレンジイソシアネート、キシリレンジイ
ソシアネート、水素伶加トリレンジイソシアネート、イ
ソプロピリデンビス（シクロヘキシルイソシアネート）
等である。A polyisocyanate compound is a compound having two or more incyanate groups in the molecule, and various compounds used in the production of ordinary polyurethane resins can be used.
For example, aromatic polyisocyanate compounds such as tolylene diisocyanate, diphenylmethane diisocyanate, dianidine noisocyanate, naphthalene diiso7anate, triphenylmethane triisocyanate, bis(diisocyanatotolyl)phenylmethane, polymethylene polyphenyl polyisocyanate, and fatty acids. Examples of group-based or alicyclic-based polyisocyanate compounds include inphorone diisocyanate, dicyclohexylmethane diisocyanate (hydrogenated diphenylmethane-7 diincyanate), hexamethylene diisocyanate, xylylene diisocyanate, hydrogenated tolylene diisocyanate, isopropylidene bis( cyclohexyl isocyanate)
etc.
本発明に用いられるポリイソシアネート化合物は、２種
以上のポリイソシアネート化合物を併用してもよく、特
に脂肪族系又は脂環族系ポリイソシアネート化合物に芳
香族系ポリイソシアネート化合物を併用してもよい。The polyisocyanate compound used in the present invention may be a combination of two or more types of polyisocyanate compounds, and particularly an aromatic polyisocyanate compound may be used in combination with an aliphatic or alicyclic polyisocyanate compound.
ポリウレタン樹脂のポリオール成分としては、イソシア
ネート基含有ウレタンブレポリマーの製造に用いられる
前記のポリヒドロキシル化合物が全て使用出来る。即ち
、前記のポリエステルポリオール及びポリエーテルポリ
オールの−１もしくは二種以上を用いる事が出来る。又
、前記の多価アルコールの如き低分子量ポリヒドロキシ
化合物をポリオール成分として併用する事も出来る。As the polyol component of the polyurethane resin, all of the above-mentioned polyhydroxyl compounds used in the production of isocyanate group-containing urethane polymers can be used. That is, one or more of the above polyester polyols and polyether polyols can be used. Furthermore, a low molecular weight polyhydroxy compound such as the above-mentioned polyhydric alcohol can also be used in combination as a polyol component.
本発明の変性ポリオレフィン樹脂（Ｂ）とは、酸もしく
はニブキシ化合物で変性したポリオレフィン樹脂であり
、好ましくはカルボキシル基含有オレフィン共重合体及
び／又はエポキシ基含有オレフィン共重合体である。こ
の（Ｂ）成分は、好ましくは■成分９９〜５０に対し、
１〜５０（重量比）で用いられ、特に（Ａ） ： （Ｂ
）＝ ９８〜６０：２〜４０である。The modified polyolefin resin (B) of the present invention is a polyolefin resin modified with an acid or a niboxy compound, preferably a carboxyl group-containing olefin copolymer and/or an epoxy group-containing olefin copolymer. This component (B) is preferably for component (1) 99 to 50,
It is used in a ratio of 1 to 50 (weight ratio), especially (A) : (B
)=98-60:2-40.
カルボキシル基含有オレフィン共重合体は、少なくとも
５０モルチ、好適には７０モルチの１−オレフィン、例
えばエチレン、プロピレン、ブテン−１、イソブチン、
ペンテン−１、ヘキセン−１、デセン−１，４−メチル
ブテン−１，４−メチルインテン−１，４，４−ジメチ
ルペンテン−１、ビニルシクロヘキサン、スチレン、α
−メチルスチレン、（２）級アルキル置換分で置換され
たスチレン又はその類似化合物を含有すべきであシ、ま
た上記オレフィンの混合物を使用することもできる。The carboxyl group-containing olefin copolymer contains at least 50 molti, preferably 70 molti of 1-olefins, such as ethylene, propylene, butene-1, isobutyne,
Pentene-1, hexene-1, decene-1,4-methylbutene-1,4-methylinten-1,4,4-dimethylpentene-1, vinylcyclohexane, styrene, α
- methylstyrene, styrene substituted with (2) class alkyl substituents or similar compounds thereof; it is also possible to use mixtures of the above-mentioned olefins.
好適にはエチレンとブテン−１、又はプロピレンから得
られる共重合体が好ましく、市販されている製品として
、例えばタフマーＡ４０８５、タフマーＡ４０９０、タ
フマーＡ ２００９０等のタフマーＡシリーズ〔エチレ
ン−ブテン−］共重合体、三井石油化学工業（株）製品
〕及びタフマーＰＯ２８０、タフマーＰＯ４８０、タフ
マーＰＯ６８０、タフマーｐｏｓｓｏ等のタフマーＰシ
リーズ〔エチレン−プロ♂レン共重合体、三井石油化学
工業（株）製品〕が挙げられる。Copolymers obtained from ethylene and butene-1 or propylene are preferred, and commercially available products include Tafmer A series [ethylene-butene-] copolymers such as Tafmer A4085, Tafmer A4090, and Tafmer A 20090. Tafmer P series [ethylene-pro♂lene copolymer, manufactured by Mitsui Petrochemical Industries, Ltd.] such as Tafmer PO280, Tafmer PO480, Tafmer PO680, and Tafmer posso]. .
上記カルボキシル基含有オレフィン共重合体は、α、β
−不飽和カルデン酸コモノマート上記オレフィンとの直
接の共重合やポリオレフィン及びポリオレフィン共重合
体へグラフト共重合する等の方法によって製造される。The above carboxyl group-containing olefin copolymer has α, β
-Unsaturated caldicic acid comonomer It is produced by direct copolymerization with the above-mentioned olefins or graft copolymerization with polyolefins and polyolefin copolymers.
ここで用いる酸成分としては１例えばアクリル酸、メタ
アクリル酸、メタクリル酸、イタコン酸、（無水）マレ
イン酸、フマル酸及び上記カルゲン酸のモノエステル等
ヲ例示でき、好適にはアクリル酸、メタクリル酸及び（
無水）マレイン酸を挙げることができる。なかでも（無
水）マレイン酸が他の酸に比べて少畦の添加で十分な酸
変性効果が得られるので特に好ましい。好適なカルボキ
シル基含有オレフィン共重合体としてはエチレン−ブテ
ン−１−（無水）マレイン酸共重合体、エチレン−プロ
ピレン−（無水）マレイン酸共重合体等を挙げることが
出来る°。Examples of the acid component used here include acrylic acid, methacrylic acid, methacrylic acid, itaconic acid, (anhydrous) maleic acid, fumaric acid, and monoesters of the above-mentioned calgenic acids. Preferably, acrylic acid, methacrylic acid, etc. as well as(
anhydrous) maleic acid. Among these, maleic acid (anhydride) is particularly preferred since it can provide a sufficient acid modification effect even with the addition of fewer ridges than other acids. Suitable carboxyl group-containing olefin copolymers include ethylene-butene-1-(anhydrous) maleic acid copolymer, ethylene-propylene-(anhydrous) maleic acid copolymer, and the like.
エポキシ基含有オレフィン共重合体は、ニブキシ化合物
としてα、β−不飽和カル？ン酸のグリシジルエステル
と前記オレフィンとの直接の共重合やポリオレフィン及
びポリオンフィン共重合体へグラフト共重合する等の方
法によって製造される。Epoxy group-containing olefin copolymers are α,β-unsaturated cal? It is produced by a method such as direct copolymerization of glycidyl ester of phosphoric acid and the above-mentioned olefin, or graft copolymerization with a polyolefin and polyonefin copolymer.
ここで用いるα、β−不飽和カルがン酸のグリシ（式中
、Ｒは水素原子または低級アルキル基である。ン
で示される１種又はそれ以上の混合物であり、例えばア
クリル酸グリシジル、メタクリル酸グリシジル、エタク
リル酸グリシジル等が挙げられ、なかでもメタクリル酸
グリシジルが好ましく使用される。One or more mixtures of α,β-unsaturated carboxyl acids (wherein R is a hydrogen atom or a lower alkyl group), such as glycidyl acrylate, methacrylate, Examples include glycidyl acid and glycidyl ethacrylate, among which glycidyl methacrylate is preferably used.
このようなカルホキフル基及び／又はエポキシ基変性ポ
リオレフィン樹脂は、これら官能基を有するモノマーを
構成成分として好ましくは０．０１〜２０ｉ量係、特に
０．０５〜５重量％の範囲で含有する。Such a carphokyfur group- and/or epoxy group-modified polyolefin resin preferably contains monomers having these functional groups in an amount of 0.01 to 20% by weight, particularly 0.05 to 5% by weight.
本発明のポリウレタン樹脂組成物には、少量の離型剤、
カップリング剤、着色剤、滑剤、耐候性安定剤、発泡剤
、防錆剤、乳白剤、防ばい剤、充てん剤等の添加剤を添
加しても良い。本発明では、ことに充てん剤を添加する
ことは、その粘着性防止の点からも重要である。充てん
剤としては、例えば炭酸カルシウム、クレー アルミナ
粉、砕石粉、タルク、硫酸バリウム、シリカッやウダー
マイカ、がラスツクウダー等の粉体が挙げられ、特に
炭酸カルシウムが好ましい。The polyurethane resin composition of the present invention contains a small amount of a mold release agent,
Additives such as a coupling agent, a coloring agent, a lubricant, a weathering stabilizer, a foaming agent, a rust preventive agent, an opacifying agent, a fungicide, and a filler may be added. In the present invention, the addition of a filler is particularly important from the viewpoint of preventing stickiness. Examples of the filler include powders such as calcium carbonate, clay alumina powder, crushed stone powder, talc, barium sulfate, silica, powder mica, and rust powder, with calcium carbonate being particularly preferred.
本発明の樹脂組成物は、その柔軟性、触感に優れること
から、フィルム、シート、成形物の形で人の肌と接触す
る物に用いられるが、好ましくはフィルム、シートの形
状で用いられる。特に人と接触することの多い製品の伸
縮フィルムとして有用で、例えば紙おむつ等の体液処理
用品のウェスト部、足つけ根部に用いられる。フィルム
の厚みは、好ましくは１０〜２００ミクロンであυ、シ
ートの厚みは、２００ミクロンより厚いものである。こ
れらのフィルム、シートは、通常の押出し、Ｔダイ、イ
ン７レーシ薔ン等の方法で製造される。Since the resin composition of the present invention has excellent flexibility and tactile feel, it is used in the form of films, sheets, and molded articles that come into contact with human skin, and is preferably used in the form of films and sheets. It is particularly useful as a stretch film for products that often come into contact with people, and is used, for example, in the waist and groin areas of body fluid treatment products such as disposable diapers. The thickness of the film is preferably between 10 and 200 microns, and the thickness of the sheet is greater than 200 microns. These films and sheets are manufactured by conventional methods such as extrusion, T-die, and in-striping.
また、本発明の実施に際しては１本発明の目的を逸脱し
ない範囲で他の熱可塑性樹脂又はエラストマー、例えば
ポリ塩化ビニル、エチレン−ｆｆ［ビニル共重合体、ポ
リエステル共重合体、スチレン系エラストマー ポリブ
タジェン、塩ビ系エラストマー アクリル系ポリマー
２リアミド、ポリイミド°、ポリアミドイミ ド、ポリ
フェニレンサルファイド等を併用すること本可能である
。In carrying out the present invention, other thermoplastic resins or elastomers, such as polyvinyl chloride, ethylene-ff [vinyl copolymer, polyester copolymer, styrene elastomer, polybutadiene, PVC elastomer Acrylic polymer
It is also possible to use diamide, polyimide, polyamideimide, polyphenylene sulfide, etc. in combination.
本発明の熱可塑性樹脂組成物の調製は種々の公知の方法
で可能である。例えば、原料を予めタンブラ−又はヘン
シェルミキサーのような混合後で均一に混合した後、−
軸又は二軸の押出機等に供給して溶融混練した後、はレ
ットとして調製する方法がある。The thermoplastic resin composition of the present invention can be prepared by various known methods. For example, after the raw materials have been mixed uniformly using a tumbler or Henschel mixer, -
There is a method in which the mixture is fed into a screw or twin screw extruder, melted and kneaded, and then prepared as pellets.
（効 果）
本発明の構成する必須成分は、ポリウレタン樹脂および
変性オレフィン樹脂であり、該オレフィン共重合体の添
加量が多くなる程柔軟性、風合、しなやかさは向上する
が、耐熱性や永久歪が低下する傾向を示すので目的に応
じて添加量を適宜決定することが有用である。また添加
量が１重量部よυ少ない場合には本発明の効果が少なく
不発明を達成することが難しい。(Effect) The essential components constituting the present invention are a polyurethane resin and a modified olefin resin, and as the amount of the olefin copolymer added increases, flexibility, texture, and suppleness improve, but heat resistance and Since permanent deformation tends to decrease, it is useful to appropriately determine the amount added depending on the purpose. Further, if the amount added is less than 1 part by weight, the effect of the present invention is small and it is difficult to achieve non-invention.
このようにして得られる本発明のポリウレタン樹脂組成
物はポリウレタン樹脂との相溶性に優れる変性ｒ ＩＪ
オレフィン樹脂が混合されているため引張強度、伸度、
耐寒性、ｌ１ｌＩｔ、１！耗性等に優れる・というぼり
ウレタン樹脂の特性を失うことなく、しなやかさ、柔軟
性、風合が付与され、成形時又はフィルム巻き取り時の
粘着性もない組成物であり、本発明のポリウレタン樹脂
組成物を成形して得られるフィルムは、紙おむつのウエ
ストギャザーレグヤヤザー用エラスチックフィルムとし
て実用性が極めて高いものである。The polyurethane resin composition of the present invention obtained in this way has modified r IJ which has excellent compatibility with polyurethane resin.
Because olefin resin is mixed, tensile strength, elongation,
Cold resistance, l1lIt, 1! The polyurethane of the present invention is a composition that has flexibility, softness, and texture without losing the characteristics of urethane resins, such as excellent wear resistance, and has no stickiness during molding or film winding. The film obtained by molding the resin composition has extremely high practicality as an elastic film for waist gather legs and diapers of disposable diapers.
（実施例）
以下に、本発明を実施例により具体的に説明するが、本
発明はこれらの実施例のみに限定されるものではない。(Examples) The present invention will be specifically explained below with reference to Examples, but the present invention is not limited only to these Examples.
尚、例中の部は重量部を意味する。In addition, parts in the examples mean parts by weight.
参考例１（カルボキシル基含有オレフィン共重合体の製
造）
エチレン−ブテン−１共重合体（タフマーＡ４０９０
） １００部、１．３−ビス（ｔａｒｔ−プチルノ臂−
オキシプロピル）ベンゼン０．５ 部及び無水マレイン
酸１部を均一に混合した。次いでシリンダー温度２２０
℃に設定した押出機で混練し、ベレット化を行ない、カ
ルボキシル基含有オレフィン共重合体を得た。赤外スイ
クトルにて無水マレイン酸ノグラフト量を測定した所、
このオレフィン共重合体はエチレン−ブテン−１共重合
体１００部に対して０．７５部の無水マレイン酸がグラ
フトしていることが確認された。これを共重合体（Ｉ）
と称す。Reference Example 1 (Production of carboxyl group-containing olefin copolymer) Ethylene-butene-1 copolymer (Tafmer A4090
) 100 parts, 1,3-bis(tart-
0.5 parts of (oxypropyl)benzene and 1 part of maleic anhydride were mixed uniformly. Then cylinder temperature 220
The mixture was kneaded in an extruder set at ℃ and pelletized to obtain a carboxyl group-containing olefin copolymer. When the amount of maleic anhydride nograft was measured using an infrared suction unit,
It was confirmed that this olefin copolymer had 0.75 parts of maleic anhydride grafted to 100 parts of the ethylene-butene-1 copolymer. This is copolymer (I)
It is called.
参考例２（エポキシ基含有オレフィン共重合体の製造）
エチレン−ブテン−１共重合体（タフマーＡ４０９０）
１００部、ジクミルノや−オキサイド０．５部及びメタ
クリル酸グリシジルエーテル２部を均一に混合した。次
いでシリンダー温度２００℃に設定した２軸押量機で混
練し、ベレット化を行ない、エポキシ基含有オレフィン
共重合体を得た。Reference Example 2 (Production of epoxy group-containing olefin copolymer) Ethylene-butene-1 copolymer (Tafmer A4090)
100 parts of dicumyl oxide, 0.5 part of dicumyl oxide, and 2 parts of methacrylic acid glycidyl ether were uniformly mixed. Next, the mixture was kneaded using a twin-screw extruder set at a cylinder temperature of 200° C., and pelletized to obtain an epoxy group-containing olefin copolymer.
塩酸−メチルエチルケトン溶液によりメタクリル酸グリ
シジルエーテルのグラフト量を測定した所。The amount of grafted glycidyl ether of methacrylate was measured using a hydrochloric acid-methyl ethyl ketone solution.
このオレフィン共重合体はエチレン−ブテン−１共重合
体１００部に対して１．２５重量部のメタクリル酸グリ
シジルエーテルがグラフトしていることが判明した。こ
れを共重合体（ｎ）と称す。It was found that this olefin copolymer had 1.25 parts by weight of methacrylic acid glycidyl ether grafted to 100 parts of the ethylene-butene-1 copolymer. This is called copolymer (n).
実施例１〜６
熱可塑性ポリウレタン樹脂〔犬日本インキ化学社製、Ｐ
ＡＮＤＥＸ Ｔ−５１６７、及びＰＡＮＤＥＸ Ｔ−６
０９０、）、参考例１で得られた共重合体（Ｉ）、参考
例２で得られた共重合体（ｎ）および少量の充填剤とし
ての炭酸カルシウム、滑剤としての脂肪酸アマイドを第
１表に示した割合で配合したものを、５０ ｍ１ｍ押出
機を用いて１９０〜２００℃で混練し被レフト化した。Examples 1 to 6 Thermoplastic polyurethane resin [manufactured by Inu Nippon Ink Chemical Co., Ltd., P
ANDEX T-5167, and PANDEX T-6
Table 1 shows the copolymer (I) obtained in Reference Example 1, the copolymer (n) obtained in Reference Example 2, a small amount of calcium carbonate as a filler, and fatty acid amide as a lubricant. The mixture blended in the ratio shown in 1 was kneaded at 190 to 200°C using a 50 ml extruder to form a left.
その（レットをインフＶ−シ目ン押出機（６５ｉ）で厚
み３０〜４０μのフィルム成形しテストピースとした。The film was molded into a film with a thickness of 30 to 40 μm using an ink V-slit extruder (65i) to form a test piece.
試験結果を第１表に示した。The test results are shown in Table 1.
比較例１〜３
比較例として、熱可塑性ポリウレタン樹脂（大日本イン
キ化学社製ＰＡＮＤＥＸ Ｔ−５１６７）、ＳＢＲ樹脂
（日本合成コ０ム社製Ｔ−Ｒ２０００）を混合したもの
及び各々単独のものに関して実施例と同様の評価を行っ
た。その結果を第１表にまとめて示した。Comparative Examples 1 to 3 As comparative examples, a mixture of thermoplastic polyurethane resin (PANDEX T-5167 manufactured by Dainippon Ink Chemical Co., Ltd.) and an SBR resin (T-R2000 manufactured by Nippon Gosei Co., Ltd.) and a mixture of each of them individually Evaluations similar to those in Examples were performed. The results are summarized in Table 1.
ン
乙雨
※１ 評価基準：◎漬方、○良好、Δやや不良、Ｘ不良
※２ 〃 ：◎なし、○若干あり、Δややあり、Ｘ
著るしくあり
フィルムの柔軟性：フィルムを巻き物にした時の柔かさ
を検討した。*1 Evaluation criteria: ◎ Pickling method, ○ Good, Δ Slightly poor, X Poor *2 〃: ◎ None, ○ Slightly, Δ Slightly, X
Remarkable flexibility of film: We investigated the flexibility of film when rolled.
フィルムの風合：フィルムの肌触りを検討した。Film texture: The texture of the film was examined.
フィルムシワ発生：フィルムを握って元に戻した時のシ
ワの残り具合を触れて検討した。Occurrence of film wrinkles: The degree of wrinkles remaining when the film was grasped and returned to its original position was examined by touch.
代理人 弁理士 高 橋 勝 利Agent Patent Attorney Katsutoshi Takahashi
Claims (10)
リオレフィン樹脂とからなる熱可塑性ポリウレタン樹脂
組成物。(1) A thermoplastic polyurethane resin composition comprising (A) a thermoplastic polyurethane resin and (B) a modified polyolefin resin.
０〜１００、抗張力２００ｋｇ／ｃｍ２以上、破断伸度
３００％以上の物性のものでなる請求項１の熱可塑性ポ
リウレタン樹脂組成物。(2) The thermoplastic polyurethane resin has a hardness (JIS) of 8
2. The thermoplastic polyurethane resin composition according to claim 1, which has physical properties of 0 to 100%, tensile strength of 200 kg/cm2 or more, and elongation at break of 300% or more.
び／又はエポキシ基含有オレフィン共重合体からなる請
求項１の熱可塑性ポリウレタン樹脂組成物。(3) The thermoplastic polyurethane resin composition according to claim 1, wherein the modified polyolefin resin comprises an olefin copolymer containing a carboxyl group and/or an epoxy group.
９９〜５０部、変性ポリオレフィン樹脂（Ｂ）が１〜５
０部（重量比）である請求項１の熱可塑性ポリウレタン
樹脂組成物。(4) Blending ratio is thermoplastic polyurethane resin (A)
99 to 50 parts, modified polyolefin resin (B) 1 to 5 parts
The thermoplastic polyurethane resin composition according to claim 1, which contains 0 parts (weight ratio).
ピレン共重合体である請求項１の熱可塑性ポリウレタン
樹脂組成物。(5) The thermoplastic polyurethane resin composition according to claim 1, wherein the modified polyolefin resin is a modified ethylene/propylene copolymer.
タン樹脂組成物。(6) The thermoplastic polyurethane resin composition according to claim 1, comprising a filler.
性ポリウレタン樹脂組成物。(7) The thermoplastic polyurethane resin composition according to claim 6, wherein the filler is calcium carbonate.
なるフィルムもしくはシート。(8) A film or sheet comprising the thermoplastic polyurethane resin composition according to claim 1.
体液処理用品。(9) A body fluid treatment article using the film or sheet according to claim 8.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63273151A JP2987835B2 (en) | 1988-10-31 | 1988-10-31 | Thermoplastic polyurethane resin composition |
| US07/429,431 US5274023A (en) | 1988-10-31 | 1989-10-31 | Thermoplastic polyurethane resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63273151A JP2987835B2 (en) | 1988-10-31 | 1988-10-31 | Thermoplastic polyurethane resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02120358A true JPH02120358A (en) | 1990-05-08 |
| JP2987835B2 JP2987835B2 (en) | 1999-12-06 |
Family
ID=17523823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63273151A Expired - Fee Related JP2987835B2 (en) | 1988-10-31 | 1988-10-31 | Thermoplastic polyurethane resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2987835B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0819570A (en) * | 1994-07-06 | 1996-01-23 | Kuraray Co Ltd | Leakage preventing sheet and sanitary material |
| JPH10193871A (en) * | 1997-01-10 | 1998-07-28 | Pilot Ink Co Ltd | Thermally discoloring laminated sheet and its manufacture |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5076165A (en) * | 1973-07-30 | 1975-06-21 | ||
| JPS5818256A (en) * | 1981-07-27 | 1983-02-02 | 株式会社クラレ | Water swelling composite body |
| JPS59120653A (en) * | 1982-12-27 | 1984-07-12 | Sumitomo Chem Co Ltd | Water-absorptive and water-retaining material |
| JPS6189254A (en) * | 1984-10-08 | 1986-05-07 | Sumitomo Chem Co Ltd | Water-absorbing material |
| JPS62236854A (en) * | 1986-04-09 | 1987-10-16 | Sumitomo Chem Co Ltd | Water-absorbing material |
-
1988
- 1988-10-31 JP JP63273151A patent/JP2987835B2/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5076165A (en) * | 1973-07-30 | 1975-06-21 | ||
| JPS5818256A (en) * | 1981-07-27 | 1983-02-02 | 株式会社クラレ | Water swelling composite body |
| JPS59120653A (en) * | 1982-12-27 | 1984-07-12 | Sumitomo Chem Co Ltd | Water-absorptive and water-retaining material |
| JPS6189254A (en) * | 1984-10-08 | 1986-05-07 | Sumitomo Chem Co Ltd | Water-absorbing material |
| JPS62236854A (en) * | 1986-04-09 | 1987-10-16 | Sumitomo Chem Co Ltd | Water-absorbing material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0819570A (en) * | 1994-07-06 | 1996-01-23 | Kuraray Co Ltd | Leakage preventing sheet and sanitary material |
| JPH10193871A (en) * | 1997-01-10 | 1998-07-28 | Pilot Ink Co Ltd | Thermally discoloring laminated sheet and its manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2987835B2 (en) | 1999-12-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0347794B1 (en) | Thermoplastic resinous composition | |
| JP4212643B2 (en) | Biodegradable polyester resin composition, and molded product, foam and molded container obtained therefrom | |
| JP3195334B2 (en) | Mechanically miscible polyurethane / polyolefin thermoplastic polymer blend | |
| US6001464A (en) | Water vapor permeable breathable films and their use | |
| JPH02160868A (en) | Polyurethane blend having improved | |
| US5274023A (en) | Thermoplastic polyurethane resin | |
| JPH02120358A (en) | Thermoplastic polyurethane resin composition | |
| JP2003119402A (en) | Thermoplastic resin composition | |
| JP2004182916A (en) | Moisture-permeating resin composition and moisture-permeating elastic film | |
| JPH079637A (en) | Resin composite using modified propylene polymer | |
| EP1832570B1 (en) | Novel Phase Change solvents | |
| JPH06184367A (en) | Polymer alloy | |
| JPH03234755A (en) | Thermoplastic elastomer composition excellent in adhesive power | |
| JP3214084B2 (en) | Thermoplastic polyurethane resin composition and article using the same | |
| JP2001106628A (en) | Substrate film for pasting and pasting material | |
| JP3449877B2 (en) | Thermoplastic polyurethane composition | |
| JPH02305855A (en) | Thermoplastic resin composition and its film or sheet | |
| JP2000034372A (en) | Thermoplastic elastomer composition | |
| JP3489949B2 (en) | Thermoplastic polyurethane composition | |
| JP4566444B2 (en) | Stretch film made of thermoplastic polyurethane resin composition and gather using the same | |
| JP3405792B2 (en) | Polymer composition | |
| JP3784516B2 (en) | Thermoplastic polymer composition | |
| JP3693486B2 (en) | Thermoplastic resin composition | |
| JPH11228809A (en) | Thermoplastic resin composition | |
| JP3863983B2 (en) | Thermoplastic resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |