JPH0210270B2 - - Google Patents
Info
- Publication number
- JPH0210270B2 JPH0210270B2 JP5105882A JP5105882A JPH0210270B2 JP H0210270 B2 JPH0210270 B2 JP H0210270B2 JP 5105882 A JP5105882 A JP 5105882A JP 5105882 A JP5105882 A JP 5105882A JP H0210270 B2 JPH0210270 B2 JP H0210270B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- polyester
- carbon atoms
- alkyl group
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 16
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 description 13
- 239000004744 fabric Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 230000037303 wrinkles Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- -1 maleic acid (3.8) Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 208000012886 Vertigo Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、ポリエステル又はポリアミド繊維構
造体の耐久性帯電防止能、吸湿性並びに吸水性を
付与する方法に関するものである。
ポリエステル又はポリアミド繊維共通の欠点と
して、帯電しやすいこと、吸湿性及び吸水性が小
さいことが知られている。
従来、ポリエステル、ポリアミド繊維の後加工
による帯電防止、吸水加工法としては、いわゆる
帯電防止剤や吸湿剤を仕上加工段階において繊維
表面に付着処理させる方法が主に採られてきた
が、耐久性に乏しく２〜３回の洗濯によつて未加
工布と同じ程度まで低下してしまうという、欠点
を有していた。
最近、これら繊維に対して、耐久性帯電防止、
吸湿性を付与する目的で、紡糸段階での改質がな
されるようになつてきたが製糸性低下、糸特性低
下等の欠点があり、まだ完全なものにはいたつて
いないのが現状である。また、これら繊維に各種
の親水性モノマーを施与し、重合固着せしめるい
わゆるグラフト重合にて帯電防止、吸水性等の性
質を改質する方法も知られている。
しかし、これらに使用するモノマー類によつて
は、帯電防止、吸水性の性能、風合の変化、対皺
性低下、着色、染色性低下、並びに堅牢度低下等
が、顕著に表面化してくる場合がある。
本発明は、これらの問題点を解決すべく、改質
剤の単位となるモノマーの分子構造とこれらモノ
マーの組合せ、並びに熱処理方式と、帯電防止
性、吸水性の耐久性、風合、耐皺に、並びに堅牢
度等の低下との関連性について、広範囲に系統的
に研究した結果到達したものである。
すなわち、本発明はポリエステル又はポリアミ
ド繊維構造体に一般式(1)
（但し、Ｘは−Ｏ−、−NH−、−CH2−、−SO2
−、
The present invention relates to a method for imparting durable antistatic properties, hygroscopic properties, and water absorbing properties to polyester or polyamide fiber structures. It is known that common disadvantages of polyester or polyamide fibers include that they are easily charged, and that they have low hygroscopicity and water absorption. Conventionally, the main method of post-processing polyester and polyamide fibers to prevent static electricity and to absorb water has been to attach so-called antistatic agents or moisture absorbers to the fiber surface during the finishing process, but this method has not improved durability. It had the disadvantage that it deteriorated to the same level as untreated cloth after 2 to 3 washes. Recently, these fibers have been developed with durable antistatic,
Modifications have been made at the spinning stage to impart hygroscopicity, but there are drawbacks such as reduced spinnability and reduced yarn properties, and the current situation is that it has not yet been perfected. be. Also known is a method of modifying properties such as antistatic properties and water absorbency by applying various hydrophilic monomers to these fibers and polymerizing and fixing them, so-called graft polymerization. However, depending on the monomers used in these products, problems such as antistatic performance, water absorption performance, changes in texture, decrease in wrinkle resistance, coloration, decrease in dyeability, and decrease in fastness become apparent. There are cases. In order to solve these problems, the present invention aims to improve the molecular structure of the monomer that is the unit of the modifier, the combination of these monomers, the heat treatment method, the antistatic property, the durability of water absorption, the texture, and the wrinkle resistance. This was reached as a result of extensive and systematic research into the relationship between this and a decrease in fastness, etc. That is, the present invention provides a polyester or polyamide fiber structure having the general formula (1). (However, X is -O-, -NH-, -CH 2 -, -SO 2
-,
【式】び【Formula】bi
【式】から選ばれた基、 ＹはA group selected from [formula], Y is
【式】
ｍ、ｎは０〜30の整数、ｍ＞ｎ、ｍ＋ｎ＝５〜
30、
Ｚは水素又は炭素数１〜２のアルキル基を示
す）、
及び
一般式(2)
（但し、Ｒは[Formula] m and n are integers from 0 to 30, m>n, m+n=5 to
30, Z represents hydrogen or an alkyl group having 1 to 2 carbon atoms), and General formula (2) (However, R is
【式】【formula】
【式】又は[Formula] or
【式】
ｍ、ｎは０〜10の整数、ｍ＋ｎ＜10、
R1は水素又は炭素数１〜２のアルキル基、
R2はH+、Na+、K+、NH4 +、
R3〜R6は水素又は炭素数１〜２のアルキル基、
R7は水酸基を示す）
で表わされるビニルモノマーを含有する処理液あ
るいはこれにさらに化合物(3)として無機性と有機
性の比の値が、0.55〜4.0の一官能性ビニルモノ
マー又は多官能性ビニルモノマーを少なくとも一
種加えた処理液を施与し、次いで熱処理すること
を特徴とするポリエステル又はポリアミド繊維構
造体に耐久性帯電防止能、吸湿及び吸水性を付与
するための改質処理方法である。
本発明によると、ポリエステル又はポリアミド
繊維構造体の耐皺、各種堅牢度等に悪影響を与え
ることなく、耐久性のある帯電防止性、吸湿、吸
水性を容易かつ経済的に付与することが可能とな
る。
本発明において使用されるモノマーについて
は、一般式(1)、一般式(2)で示しているが、各々の
代表例をあげるとすれば化合物(1)群として
化合物(2)群として
等があげられる。
本発明にて所望により使用する一官能性ビニル
モノマーとは、モノマー中に１個のビニル基を有
するものであり、多官能性ビニルモノマーとは、
モノマー中に２個以上のビニル基を有するもので
ある。
無機性と有機性の比とは、藤田（化学の領域、
11、719、1957）によつて提唱された有機概念に
基づくものであり、これによればその数値が零よ
り大きくなるにつれて無機性が強く、すなわち親
水性になることを示し、逆に零に近ずくにつれて
有機性が強く、すなわち親油性になることを示す
概念である。
化合物(3)群としては、加工本来の目的すなわち
吸水、吸湿性を付与するためには、有機性のある
範囲より大きいものは親水性とは全く逆の性質と
なるため、使用をさけなければならないが、これ
に属する代表例と、無機性と有機性の比の数値を
記せば、アクリル酸（2.53）、メタクリル酸
（1.90）等の不飽和酸類、２−ヒドロキシエチル
メタアクリレート（1.35）、グリシジルメタクリ
レート（0.59）、ポリエチレングリコールジメタ
アクリレート（ｎ＝１の場合、3.94 ｎ＝23の場
合0.94）等の不飽和酸エステル、マレイン酸
（3.8）、イタコン酸（3.0）等の不飽和酸無水物
類、Ｎ−メチロールアクリルアミド（3.8）、ジメ
チルアミノエチルメタアクリレート（0.83）、等
の不飽和アミン類、アクリルニトリル（0.9）、メ
タアクリルニトリル（0.72）等の不飽和ニトリル
類、等がある。
本発明による加工処理は、上記モノマーを含む
水溶液又は、水乳化液をポリエステル又はポリア
ミド繊維構造体に施与し、熱処理することによつ
て行われる。
施与手段としては、浸漬法、パツテング法、ス
プレー法等公知の方法を用いる。
熱処理としては、浸漬加熱法、常圧〜高圧加熱
法、高周波加熱法、紫外線光加熱法、乾燥加熱法
等、又はその組合せ法を繊維構造体の違いに応じ
て用いるが、熱処理の効率を高めるために、触媒
を必要に応じて使用することができる。触媒とし
ては有機又は無機の過酸化物類、過硫酸塩類等が
ある。
また、熱処理に必要な温度と時間は、通常30℃
〜200℃の範囲で0.5分〜60分であるが、好ましく
は50℃〜180℃の範囲で１分〜20分である。
モノマー濃度は、水溶液又は水乳化液で５ｇ／
〜200ｇ／の範囲で用いられるが、耐久性帯
電防止、吸水、吸湿性を顕著に出すには、これら
重合物の繊維構造物上の固着、附着量が0.5〜15
重量パーセントの範囲であつて、最も好ましくは
2.0〜8.0重量パーセントの範囲である。一般式(1)
と(2)で示したモノマーの使用量比は特に制限され
ないが、通常化合物(1)を幾分多く用いることが好
ましく、両者の重量比で表わして化合物(1)：(2)の
モノマー比が50〜80：50〜20程度が好ましい。化
合物(3)も上記に準ずる量関係で好ましく用いられ
る。ポリエステル又はポリアミド繊維構造体とは
ポリエチレンテレフタレート、ナイロン６、ナイ
ロン66等の繊維を少なくとも必須構成繊維として
含むものをいい、編物、織物、不織布等いづれの
形態のものでもよい。
以下に実施例をあげ、本発明を更に詳しく説明
する。
尚、実施例に示した耐久性、摩擦帯電圧、半減
期、吸水性、吸湿性、耐皺性、それぞれ次の測定
法にて測定した。
耐久性：合成洗剤「ザブ」１ｇ／を含んだ40℃
の湯（浴比１：50）で家庭用洗濯機を用い、10
分間洗濯を行い５分間すすぎを行う。これを洗
濯１回とし、30回迄行う。
摩擦帯電圧：20℃、50％RHの雰囲気において、
京大化研式ロータリースタチツクテスター（興
亜商会製）を用い、綿金巾３号を摩擦布として
測定する。
半減期：20℃、50％RHの雰囲気下において、オ
ネストメーター（穴戸商会製）を用いて測定す
る。
吸水性：20℃、65％RHの雰囲気下において、水
平に張つた試料に、５cm上のビユーレツト先端
から一滴の水を落下せしめ、水滴が拡がり消滅
するまでの時間を測定する。
吸湿性：絶乾布を、20℃、65％RHの雰囲気下に
４時間放置、その雰囲気下で重量測定し、その
重量増分を重量パーセントとして算出する。
耐皺性：20℃、65％RHの雰囲気下で、モンサン
ト法にて測定する。
実施例 １
ポリエステル繊維からなる60番手スパン織物の
染色品を、下記組成のパツド液に浸漬し、マング
ルにてピツクアツプ60％に均一に絞つた。[Formula] m and n are integers from 0 to 10, m+n<10, R 1 is hydrogen or an alkyl group having 1 to 2 carbon atoms, R 2 is H + , Na + , K + , NH 4 + , R 3 ~ (R 6 is hydrogen or an alkyl group having 1 to 2 carbon atoms, and R 7 is a hydroxyl group. , a treatment solution containing at least one monofunctional vinyl monomer or polyfunctional vinyl monomer of 0.55 to 4.0 is applied to the polyester or polyamide fiber structure, which is then heat-treated to provide durable antistatic ability and moisture absorption. and a modification treatment method for imparting water absorbency. According to the present invention, it is possible to easily and economically impart durable antistatic properties, moisture absorption, and water absorption properties to polyester or polyamide fiber structures without adversely affecting wrinkle resistance, various fastness properties, etc. Become. The monomers used in the present invention are shown in general formula (1) and general formula (2), but representative examples of each are given as compound (1) group. As compound (2) group etc. can be mentioned. The monofunctional vinyl monomer optionally used in the present invention is one that has one vinyl group in the monomer, and the polyfunctional vinyl monomer is one that has one vinyl group in the monomer.
It has two or more vinyl groups in the monomer. Fujita (chemistry field,
11, 719, 1957), and according to this, as the value becomes larger than zero, it becomes more inorganic, that is, more hydrophilic; This is a concept that indicates that the closer you get to it, the more organic it becomes, that is, the more lipophilic it becomes. As for the compound (3) group, for the original purpose of processing, that is, to impart water absorption and hygroscopicity, it is necessary to avoid using compounds larger than a certain range of organicity, as they have properties completely opposite to hydrophilicity. However, typical examples belonging to this category and the ratio of inorganic to organic are unsaturated acids such as acrylic acid (2.53) and methacrylic acid (1.90), 2-hydroxyethyl methacrylate (1.35), Unsaturated acid esters such as glycidyl methacrylate (0.59), polyethylene glycol dimethacrylate (3.94 when n = 1, 0.94 when n = 23), unsaturated acid anhydrides such as maleic acid (3.8), itaconic acid (3.0), etc. unsaturated amines such as N-methylolacrylamide (3.8) and dimethylaminoethyl methacrylate (0.83); unsaturated nitrites such as acrylonitrile (0.9) and methacrylonitrile (0.72); The processing according to the present invention is carried out by applying an aqueous solution or water emulsion containing the above monomer to a polyester or polyamide fiber structure and heat-treating the structure. As the application method, known methods such as dipping, pattening, and spraying are used. For heat treatment, immersion heating method, normal pressure to high pressure heating method, high frequency heating method, ultraviolet light heating method, dry heating method, etc., or a combination thereof is used depending on the fiber structure, but the efficiency of heat treatment is improved. For this reason, a catalyst can be used if necessary. Examples of catalysts include organic or inorganic peroxides and persulfates. In addition, the temperature and time required for heat treatment are usually 30℃.
The heating time is 0.5 minutes to 60 minutes at a temperature of ~200°C, preferably 1 minute to 20 minutes at a temperature of 50°C to 180°C. Monomer concentration is 5g/in aqueous solution or water emulsion.
It is used in the range of ~200g/, but in order to achieve remarkable durability, antistatic properties, water absorption, and hygroscopicity, the amount of adhesion and adhesion of these polymers on the fiber structure must be 0.5 to 15%.
weight percent range, most preferably
It ranges from 2.0 to 8.0 weight percent. General formula (1)
Although the usage ratio of the monomers shown in is preferably about 50-80: 50-20. Compound (3) is also preferably used in the same amount relationship as above. The polyester or polyamide fiber structure refers to one containing fibers such as polyethylene terephthalate, nylon 6, and nylon 66 as at least essential constituent fibers, and may be in any form such as knitted fabric, woven fabric, or nonwoven fabric. The present invention will be explained in more detail with reference to Examples below. The durability, frictional charging voltage, half-life, water absorption, moisture absorption, and wrinkle resistance shown in Examples were each measured using the following measuring methods. Durability: 40℃ containing 1g of synthetic detergent "Zabu"
Using a household washing machine with hot water (bath ratio 1:50),
Wash for 5 minutes and rinse for 5 minutes. This is considered to be one wash, and it can be repeated up to 30 times. Frictional charging voltage: In an atmosphere of 20℃ and 50%RH,
Using a Kyoto University Kaken type rotary static tester (manufactured by Koa Shokai), the measurement was performed using a cotton gold cloth No. 3 as the friction cloth. Half-life: Measured using an honest meter (manufactured by Anato Shokai) in an atmosphere of 20°C and 50% RH. Water absorption: In an atmosphere of 20°C and 65% RH, a drop of water is dropped from the tip of the burette 5 cm above a horizontal sample, and the time taken for the water drop to spread and disappear is measured. Hygroscopicity: Leave the absolutely dry cloth in an atmosphere of 20°C and 65% RH for 4 hours, measure the weight in that atmosphere, and calculate the weight increase as a weight percentage. Wrinkle resistance: Measured using the Monsanto method in an atmosphere of 20°C and 65% RH. Example 1 A dyed 60 count spun fabric made of polyester fibers was immersed in a pad solution having the composition shown below and uniformly squeezed with a mangle to a pick-up of 60%.
【表】
そして、100℃の常圧飽和蒸気中で20分熱処理
を行い、耐久性テスト（洗濯30回）を実施した。
実施例 ２
実施例１に示した同じ染色品を、実施例１で用
いたパツド液に浸漬し、実施例１と同条件で絞つ
た布を巻取り、出力7KWの高周波発生器に入れ、
回転させながら10分加熱処理を行い、実施例１と
同条件で耐久性テストを実施した。
実施例 ３
実施例１に示した同じ染色品を、下記組成のパ
ツド液に浸漬し、実施例１と同条件で絞つた。[Table] Then, heat treatment was performed for 20 minutes in normal pressure saturated steam at 100°C, and a durability test (washing 30 times) was conducted. Example 2 The same dyed product shown in Example 1 was immersed in the padding solution used in Example 1, the cloth was wrung out under the same conditions as Example 1, wound up, and placed in a high frequency generator with an output of 7KW.
A durability test was conducted under the same conditions as in Example 1 by heating for 10 minutes while rotating. Example 3 The same dyed product shown in Example 1 was immersed in a pad solution having the following composition and squeezed under the same conditions as Example 1.
【表】
そして、110℃の飽和蒸気中で５分熱処理を行
い、実施例１と同条件で耐久性テストを実施し
た。
比較例 １
本発明の効果を比較するため、実施例１に示し
た同じ染色品を処理することなく、実施例１と同
じ条件で耐久性テストを実施した。
以上の処理を施与して得られた織物の性能を測
定し、表１の結果を得た。[Table] Then, heat treatment was performed for 5 minutes in saturated steam at 110°C, and a durability test was conducted under the same conditions as in Example 1. Comparative Example 1 In order to compare the effects of the present invention, a durability test was conducted on the same dyed product shown in Example 1 under the same conditions as Example 1 without being treated. The performance of the fabric obtained by applying the above treatment was measured, and the results shown in Table 1 were obtained.
【表】
実施例 ４
ポリアミド繊維からなる30dトリコツト編物を
通常の方法にて、精練し、下記組成液をつくり浴
比１：42にて密閉式染色用器を用い、50℃より１
℃／分で100℃まで昇温し、100℃にて30分処理し
たのち廃液、水洗を行つた。[Table] Example 4 A 30D tricot knitted fabric made of polyamide fibers was scoured in the usual manner to prepare the following composition solution, and dyed at 50°C using a closed dyeing vessel at a bath ratio of 1:42.
The temperature was raised to 100°C at a rate of 100°C/min, and the solution was treated at 100°C for 30 minutes, followed by waste liquid and washing with water.
【表】
そして、次に硫酸水素ナトリウム1.00ｇ／、
過硫酸アンモニウム10％o.w.f.の溶液を浴比１：
42にて注入し、50℃より１℃／分で100℃ま昇温
し、100℃にて30分処理し脱液水洗後、実施例１
と同条件で耐久性テストを実施した。
比較例 ２
本発明の効果を比較するため、実施例４に示し
た同じ編物を、実施例４と同条件にて精練し、処
理することなく実施例１と同条件で耐久性テスト
を実施した。
以上の処理を施与して得られた編物の性能を測
定し、表２の結果を得た。[Table] Then, sodium hydrogen sulfate 1.00g/,
A solution of ammonium persulfate 10% owf in a bath ratio of 1:
Example 1
A durability test was conducted under the same conditions. Comparative Example 2 In order to compare the effects of the present invention, the same knitted fabric shown in Example 4 was refined under the same conditions as Example 4, and a durability test was conducted under the same conditions as Example 1 without treatment. . The performance of the knitted fabric obtained by applying the above treatment was measured, and the results shown in Table 2 were obtained.
Claims (1)
一般式(1) （但し、Ｘは−Ｏ−、−NH−、−CH2−、SO2−、 【式】及び【式】から選ばれた基、 Ｙは【式】ｍ、 ｎは０〜30の整数、ｍ＞ｎ、ｍ＋ｎ＝５〜30、 Ｚは水素又は炭素数１〜２のアルキル基を示
す）、及び一般式(2) （但し、Ｒは 【式】【式】又は 【式】 ｍ、ｎは０〜10の整数、ｍ＋ｎ＜10、R1は水
素又は炭素数１〜２のアルキル基、R2はH+、
Na+、K+又はNH4 +、R3〜R6は水素又は炭素数
１〜２のアルキル基、R7は水酸基を示す）で表
わされるビニルモノマーを含有する混合液を施与
し次いで熱処理することを特徴とするポリエステ
ル又はポリアミド繊維構造体に耐久性帯電防止
能、吸湿及び吸水性を付与する方法。[Claims] 1. A polyester or polyamide fiber structure,
General formula (1) (However, X is a group selected from -O-, -NH-, -CH 2 -, SO 2 -, [Formula] and [Formula], Y is [Formula] m, n is an integer from 0 to 30, m>n, m+n=5-30, Z represents hydrogen or an alkyl group having 1 to 2 carbon atoms), and general formula (2) (However, R is [Formula] [Formula] or [Formula] m, n are integers of 0 to 10, m + n < 10, R 1 is hydrogen or an alkyl group having 1 to 2 carbon atoms, R 2 is H + ,
A mixed solution containing a vinyl monomer represented by Na + , K + or NH 4 + , R 3 to R 6 are hydrogen or an alkyl group having 1 to 2 carbon atoms, and R 7 is a hydroxyl group) is applied and then heat treated. A method for imparting durable antistatic ability, moisture absorption and water absorption properties to a polyester or polyamide fiber structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5105882A JPS58169569A (en) | 1982-03-31 | 1982-03-31 | Modification of polyester and polyamide fiber structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5105882A JPS58169569A (en) | 1982-03-31 | 1982-03-31 | Modification of polyester and polyamide fiber structure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58169569A JPS58169569A (en) | 1983-10-06 |
| JPH0210270B2 true JPH0210270B2 (en) | 1990-03-07 |
Family
ID=12876201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5105882A Granted JPS58169569A (en) | 1982-03-31 | 1982-03-31 | Modification of polyester and polyamide fiber structure |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58169569A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6034673A (en) * | 1983-08-05 | 1985-02-22 | 東レ株式会社 | Treatment of fiber structure |
-
1982
- 1982-03-31 JP JP5105882A patent/JPS58169569A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58169569A (en) | 1983-10-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3645989A (en) | Fluorinated oil- and water-repellent and dry soil resistant polymers | |
| US4065598A (en) | Process for polymeric modification of a fiber | |
| US4135877A (en) | Process for improving antistatic and hygroscopic properties of fibers or fibrous structures made thereof | |
| US3676052A (en) | Polypropylene glycols and substituted polypropylene glycols are used in conjunction with crosslinking agents to produce durable press fabrics with improved soil release performance | |
| JPS5812389B2 (en) | Method for processing synthetic fibers or their fiber structures | |
| US3476581A (en) | Treatment of textiles with cross-linkable acrylic polymers and the resulting products | |
| JPS6410622B2 (en) | ||
| JPH0210270B2 (en) | ||
| JPS5818464B2 (en) | Modifier for fibers or fiber structures | |
| JPS597827B2 (en) | Hydrophilic treatment agent | |
| JPS5818481A (en) | Treatment of polyester fiber | |
| US2767107A (en) | Antistatic treatment of hydrophobic resin articles | |
| US3457213A (en) | Coapplication of softeners with an acid halide containing polymeric shrinkproofing agent to textile fibers | |
| JPS5818480A (en) | Treatment of polyester fiber | |
| JPH045789B2 (en) | ||
| JPS6197478A (en) | Treatment of fiber | |
| KR19980045571A (en) | Modification of polyester fabric by graft polymerization | |
| JPS6024225B2 (en) | Modified fiber structure | |
| JPS584871A (en) | Treatment of synthetic fiber | |
| JPS6040553B2 (en) | Modification treatment method for synthetic fiber materials | |
| JPS5818479A (en) | Treatment of polyester fiber | |
| KR830002222B1 (en) | Method for producing hydrophilic polyamide fiber | |
| JPH059548B2 (en) | ||
| JPS5846588B2 (en) | Modification treatment method for synthetic fiber materials | |
| JPS60104576A (en) | Processing treatment of synthetic fiber/cellulose fiber |