JPH0193347A - Vibration-attenuating composite metallic sheet - Google Patents
Vibration-attenuating composite metallic sheetInfo
- Publication number
- JPH0193347A JPH0193347A JP4442487A JP4442487A JPH0193347A JP H0193347 A JPH0193347 A JP H0193347A JP 4442487 A JP4442487 A JP 4442487A JP 4442487 A JP4442487 A JP 4442487A JP H0193347 A JPH0193347 A JP H0193347A
- Authority
- JP
- Japan
- Prior art keywords
- vibration
- butene
- propene
- ethene
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 27
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920001897 terpolymer Polymers 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 40
- 238000013016 damping Methods 0.000 claims description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000000748 compression moulding Methods 0.000 abstract description 2
- 150000002978 peroxides Chemical class 0.000 abstract description 2
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 239000002952 polymeric resin Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 239000003190 viscoelastic substance Substances 0.000 description 2
- 230000002747 voluntary effect Effects 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WEHZNZTWKUYVIY-UHFFFAOYSA-N 3-oxabicyclo[3.2.2]nona-1(7),5,8-triene-2,4-dione Chemical compound O=C1OC(=O)C2=CC=C1C=C2 WEHZNZTWKUYVIY-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- -1 etc. Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical compound C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 229940006076 viscoelastic substance Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Vibration Prevention Devices (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、２枚の金属板の間にフィルム状、あるいはシ
ート状の高い軟化点をもつ、著しく非品性のブテン−１
／プロペン／エテンーターボリマー樹脂を介在させてな
る振動減衰性複合金属板に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention is directed to the production of butene-1, which has a high softening point in the form of a film or sheet, between two metal plates.
The present invention relates to a vibration-damping composite metal plate having a propene/ethene polymer resin interposed therebetween.
（従来の技＊）
近年、住宅、自動車等の騒音規制強化に伴い、その対策
としているいろな方法が検討されているが、主として音
源、もしくはこれら音源の振動により発音する部品に割
振材を使用する傾向が高まっており、これまで種々の振
動減衰性複合金属板が提案されている。(Conventional technique*) In recent years, with the tightening of noise regulations for houses, automobiles, etc., various methods are being considered as countermeasures, but the main method is to use damping materials for sound sources or parts that produce sound due to the vibrations of these sound sources. There is a growing tendency to do this, and various vibration-damping composite metal plates have been proposed so far.
例えば特公昭３９−１２４５１にはビニルアセテートと
マレイン酸ジエステル、ビニルクロライドとエチルへキ
シルアクリレート等の共重合体を中間層とした振動減衰
金属板が開示されているが、これは粘弾性を有する樹脂
を利用して振動エネルギーを熱エネルギーとして吸収さ
せるという公知の事実を利用したものである。この粘弾
性を有する樹脂は、温度の変化に伴いその粘弾性が敏感
に変化することが予想される。For example, Japanese Patent Publication No. 39-12451 discloses a vibration-damping metal plate with an intermediate layer made of a copolymer of vinyl acetate and maleic diester, vinyl chloride and ethylhexyl acrylate, etc., but this is made of a viscoelastic resin. This method takes advantage of the well-known fact that vibrational energy is absorbed as thermal energy. It is expected that the viscoelasticity of this viscoelastic resin changes sensitively with changes in temperature.
また一般に、振動吸収性能は損失係数なる物理量で表現
可能であり、その値が０．０５以上であれば振動吸収材
としての効果があると言われている。In general, vibration absorbing performance can be expressed by a physical quantity called a loss coefficient, and it is said that if the value is 0.05 or more, it is effective as a vibration absorbing material.
このような材料としては、ゴム系、共重合樹脂系、アス
ファルト系などの粘弾性物質が有効と考えられる。しか
し、これらは振動減衰能は十分であっても、金属板との
密着性が悪かったり、２枚の金属板の間にはさみこむた
めの加工性が悪かったりして、現在に至るまで完全に満
足すべき材料は見当たらない。Viscoelastic substances such as rubber, copolymer resin, and asphalt are considered effective as such materials. However, even though these have sufficient vibration damping ability, they have poor adhesion to the metal plate and poor workability for sandwiching them between two metal plates, so to date they have not been completely satisfactory. No material found.
そこで本発明者は、上記粘弾性物質の諸欠点を改良すべ
く鋭意検討した結果、本発明に到達した。Therefore, the inventor of the present invention has conducted extensive studies to improve the various drawbacks of the viscoelastic materials described above, and as a result, has arrived at the present invention.
（問題点を解決するための手段）
即ち本発明は、ブテン−１１プロペン／エテンーターポ
リマー碍脂を中間層として２枚の金属板の間に接着して
なることを特徴とする振動減衰性複合金属板に関する。(Means for Solving the Problems) That is, the present invention provides a vibration-damping composite metal comprising a butene-11 propene/ethene terpolymer resin bonded between two metal plates as an intermediate layer. Regarding the board.
本発明で使用されるブテン−１１プロペンｌエテンータ
ーボリマー樹脂は、高い軟化点をもつ、著しく非品性の
ブテン−１／プロペンｌエテンーターポリマー樹脂であ
って、ブテン−１、プロペン、エテノの３種類のモノマ
ーを、通常の低圧法ポリオレフィン重合で直接共重合す
ることにより得られ、ＤＩＮ５２０１０による軟化温度
が５００Ｃ〜２０００Ｃ１好ましくは７５０Ｃ〜１８０
０Ｃの範囲にあることが必要である。The butene-11 propene l-ethene terpolymer resin used in the present invention is a highly inferior butene-1/propene l-ethene terpolymer resin with a high softening point, comprising butene-1, propene, It is obtained by direct copolymerization of three types of etheno monomers by ordinary low-pressure polyolefin polymerization, and has a softening temperature of 500C to 2000C1 according to DIN 52010, preferably 750C to 180C.
It is necessary that the temperature be within the range of 0C.
本発明の振動減衰性複合金属板の中間層であるブテン−
１７プロペンｌエテンーターボリマー樹脂には、軟化温
度、成形性等を改良するために、必要に応じて可塑剤、
無機充填材などを配合することができる。また、重合体
樹脂材料に添加する一般的添加剤である安定剤、帯電防
止剤等は、本発明の場合も従来材料と同様に適宜添加す
ることができる。Butene, which is the intermediate layer of the vibration-damping composite metal plate of the present invention.
In order to improve the softening temperature, moldability, etc. of the 17 propene l ethene turbo polymer resin, a plasticizer,
Inorganic fillers and the like can be added. Further, stabilizers, antistatic agents, etc., which are general additives added to polymer resin materials, can be appropriately added in the case of the present invention as well as in conventional materials.
さらに、本発明で使用されるブテン−１／プロペンｌエ
テンーターポリマー樹脂は、必要に応じて酸または酸無
水物を、あるいはこれらと過酸化物とを添加して変性す
ることにより、金属板との密着性を更に改良することが
できる。酸または酸無水物としては、飽和または不胞和
のモノカルボン酸、ジカルボン酸、トリカルボン酸およ
び多カルボン酸またはそれらの酸無水物が適当であり、
例えばプロピオン酸、ピバリン酸、カプリン酸、ラウリ
ン酸、フマル酸、オレイン酸、アクリル酸、メタクリル
酸、マレイン酸、イソフタル酸、テレフタル酸、トリメ
リット酸、ピロメリット酸、マレイン酸無水物、テレフ
タル酸無水物、トリメリット酸無水物などが挙げられる
。また、リンゴ酸、クエン酸など、オキシカルボン酸お
よびそれらの酸無水物も使用することができる
本発明のブテン−１１プロペンｌエテンーターボリマー
樹脂は、従来公知のＴ−グイフィルム製造装置、または
インフレーションフィルム製造装置を用いてフィルムや
シートに成形した後、２枚の金属板にはさみ加熱圧着し
て接着される。その際のフィルムやシートは、１０１１
ｍ〜１ｍｍ、特に２０〜１５０μｍの厚さのものが好ま
しい。Furthermore, the butene-1/propene-1 ethene terpolymer resin used in the present invention can be modified by adding an acid or an acid anhydride, or a peroxide together with the metal sheet, as necessary. It is possible to further improve the adhesion with. Suitable acids or acid anhydrides include saturated or unsaturated monocarboxylic acids, dicarboxylic acids, tricarboxylic acids, and polycarboxylic acids, or acid anhydrides thereof;
For example, propionic acid, pivalic acid, capric acid, lauric acid, fumaric acid, oleic acid, acrylic acid, methacrylic acid, maleic acid, isophthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, maleic anhydride, terephthalic anhydride. and trimellitic anhydride. In addition, oxycarboxylic acids and their acid anhydrides such as malic acid and citric acid can also be used. After being formed into a film or sheet using a blown film manufacturing device, it is sandwiched between two metal plates and bonded by heat and pressure. The film or sheet used in this case is 1011
Thicknesses of m to 1 mm, especially 20 to 150 μm are preferred.
本発明で使用される金属板としては、鉄、ニッケル、チ
タン、アルミニウム、マグネシウム、銅、亜鉛、錫など
の金属板や、前記金属板を主体とする各種の合金板、例
えばステンレススチール板などが挙げられる。これらの
金属板の厚さは、得られる振動減衰性複合金属板の曲げ
やしぼりなどの二次加工ができる範囲内であれば、特に
限定はされないが、−船釣には０．０１〜５ｍｍの厚さ
であればよい。これらの金属板は市販されているが、そ
れらには一般に油脂が付着しているので、脱脂したもの
を用いるのが好ましく、その脱脂方法としては従来公知
のどのような方法でもよい。The metal plates used in the present invention include metal plates made of iron, nickel, titanium, aluminum, magnesium, copper, zinc, tin, etc., and various alloy plates based on the above-mentioned metal plates, such as stainless steel plates. Can be mentioned. The thickness of these metal plates is not particularly limited as long as the obtained vibration-damping composite metal plate can be subjected to secondary processing such as bending and squeezing, but - 0.01 to 5 mm for boat fishing. It is sufficient that the thickness is . These metal plates are commercially available, but since they generally have oils and fats attached to them, it is preferable to use ones that have been degreased, and any conventionally known method may be used for the degreasing.
本発明における振動減衰性複合金属板の製造方法として
は、同種または異種の金属板の間にブテン−１／プロペ
ンｌエテンーターポリマー樹脂のフィルムあるいはシー
トを介在させ、これを圧縮成形機やロールを用いて加熱
圧縮するものが好ましい。The method for manufacturing the vibration-damping composite metal plate in the present invention involves interposing a film or sheet of butene-1/propene-1 ethene terpolymer resin between metal plates of the same or different types, and using a compression molding machine or a roll. It is preferable that the material be heated and compressed.
そめ際、金属板、ブテン−１１プロペンｌエテンーター
ポリマー樹脂とも次の二次加工に便利な適当な大きさ、
形に９７断してから接着する方法、図１に示す連続的製
造方法など種々の方法を採用することができる。なお、
図１の連続的製造方法で製造する際は、金属板を図２に
示すような工程であらかじめ脱脂しておくと、良好な接
着性かえられなお好ましい。At the end, the metal plate, butene-11propene l-ethene terpolymer resin, and the appropriate size convenient for the next secondary processing,
Various methods can be employed, such as a method in which the material is cut into 97 shapes and then bonded, and a continuous manufacturing method shown in FIG. 1. In addition,
When manufacturing by the continuous manufacturing method shown in FIG. 1, it is preferable to degrease the metal plate in advance in a step as shown in FIG. 2, since good adhesion can be obtained.
なお、本発明の実施態様としてブテン−１１プロペンｌ
エテンーターポリマー樹脂を中間層として、２枚以上の
複数枚の金属板の間に接着してなる多層構造の軽量複合
金属板もふくまれることはいうまでもない。In addition, as an embodiment of the present invention, butene-11propene l
Needless to say, the invention also includes a lightweight composite metal plate having a multilayer structure in which two or more metal plates are bonded together using an ethene terpolymer resin as an intermediate layer.
（発明の効果）
本発明によって提供される振動減衰性複合金属板は、良
好な振動減衰性を示すだけでなく、中間層のブテン−１
１プロペンｌエテンーターボリマー樹脂はフィルム化あ
るいはシート化が容易なため、複合化加工が非常に簡単
になり、しかも良好な密着性を示すものである。(Effects of the Invention) The vibration-damping composite metal plate provided by the present invention not only exhibits good vibration-damping properties, but also has butene-1 in the intermediate layer.
Since the 1-propene-1-ethene ether polymer resin can be easily formed into a film or sheet, composite processing is very simple, and moreover, it exhibits good adhesion.
（実施例） 本発明の詳細な説明するため、以下に実施例を示す。(Example) Examples are shown below to explain the present invention in detail.
実施例１〜５
２枚の金属板として、１．Ｏｘ１５０ｘ３００ｍｍの一
般冷延鋼板を用い、ブテン−１／プロペン／工テンータ
ーボリマー間脂は表１に示すものを用いた。Examples 1 to 5 As two metal plates, 1. A general cold-rolled steel plate with a size of 150 mm x 300 mm was used, and the butene-1/propene/temper polymer interstitial oil shown in Table 1 was used.
表１に示す高い軟化点をもつ、著しく非品性のブテン−
１／プロペンｌエテンーターポリマー樹脂（Ｈｆｉｌｓ
社製ＶＥＳＴＯＰＬＡＳＴ）を用いて、通常のＴ−ダイ
押出機で厚さ８０１１ｍのフィルムを製造し、上記２枚
の鋼板の間にはさんで、２０００Ｃ１５ｋｇ／ａｍ２．
５分の条件で熱接着し、複合金属板を作成した。これら
複合金属板を用い、接着強度としてＴ−剥離試験を、加
工適性としてエリクセン試験をおこなった。結果を表１
に示す。A significantly inferior butene with a high softening point as shown in Table 1.
1/Propene l-ethene terpolymer resin (Hfils)
A film with a thickness of 8,011 m was produced using a regular T-die extruder using a VESTOPLAST (manufactured by Kogyo Corporation), and was sandwiched between the two steel plates mentioned above to produce a film of 2,000C15 kg/am2.
They were thermally bonded for 5 minutes to create a composite metal plate. Using these composite metal plates, a T-peel test was conducted to determine adhesive strength, and an Erichsen test was conducted to determine processing suitability. Table 1 shows the results.
Shown below.
また、上記複合鋼板の振動減衰性能を調べるため、機械
インピーダンス法により損失係数を測定した。結果を図
３に示す。In addition, in order to examine the vibration damping performance of the composite steel plate, the loss coefficient was measured using the mechanical impedance method. The results are shown in Figure 3.
比較例１
市販振動減衰性複合金属板、即ち厚さが１００１１ｍで
ある酢酸ビニル系尉脂で接着した複合金属板を用い、実
施例１〜５と全く同様にして接着強度、加工適性、振動
減衰性能を測定した。結果を表１、図３に示すが、実施
例１〜５に比較して全ての点で劣っていることがわかる
。Comparative Example 1 Using a commercially available vibration-damping composite metal plate, that is, a composite metal plate with a thickness of 10,011 m bonded with vinyl acetate adhesive, adhesive strength, workability, and vibration damping were evaluated in exactly the same manner as in Examples 1 to 5. Performance was measured. The results are shown in Table 1 and FIG. 3, and it can be seen that they are inferior in all respects compared to Examples 1 to 5.
比較例２
一般冷延鋼板を用い、振動減衰性能を測定した結果を表
１に示す。実施例１〜５で作成した複合金属板に比較し
、減衰性能が明らかに劣っていることがわかる。Comparative Example 2 Table 1 shows the results of measuring vibration damping performance using a general cold rolled steel plate. It can be seen that the damping performance is clearly inferior to the composite metal plates prepared in Examples 1 to 5.
図１は、振動減衰性複合金属板の連続的製造方法を、図
２は金属板の連続的脱脂工程を、図３は実施例１〜５、
比較例１．２で使用した材料の損失係数の温度依存性を
示す結果である。
なお図１において、１，１′は金属板、２．２’、３．
３’はロール、４，４’、８はレベラー、５，５′は余
熱工程、６，６゛はロール、９は再加熱工程、１０は第
一冷却工程、工１は第二冷却工程、１２．１３はスリッ
ター、７は高い軟化点をもつ、著しく非品性のブテン−
１１プロペンｌエテンーターポリマー樹脂フイルム、１
４は製品である振動減衰性複合金属板である。また図２
において、１５はロール、１６，１８は電解液槽、１７
は陽電極板、１９は陰電極板、２０は電源、２１は水洗
工程、２２は乾燥工程、２３は脱脂前の金属板、２４は
脱脂後の金属板を示す。
特許出願人ダイセルセユルス株式会社
手 続 補 正 書 （自発）１．事件の表示
昭和６２年特許願第４４４２４号
２、発明の名称
振動減衰性複合金属板
３、補正をする者
４、補正の対象
５、補正の内容
が用いられる。」
（２）明細書第８頁第８行と９行の間に次の文を加入す
る。
示す、損失係数（極大値）は０．１であった。
（３）明細書第９頁の表１を次のように訂正する。
（４）図面の図３を別紙の通り訂正する。
昭和６３年９月３日
特許庁庁官 吉田文毅 殿 １諾１、
事件の表示
昭和６２年特許願第４４４２４号
２、発明の名称
振動減衰性複合金属板
３、補正をする者
事件との関係 特許出願人
郵便番号 １００
住 所 東京都千代田区霞が関三丁目８番１号氏
名 ダイセル・ヒュルス株式会社昭和６３年９月６
日
５、補正の対象
昭和６３年５月２４日付提出の手続補正書の発明の名称
の欄手 続 補 正 書 （自発）昭和６３年
５月２４日Figure 1 shows a continuous manufacturing method for a vibration-damping composite metal plate, Figure 2 shows a continuous degreasing process for a metal plate, and Figure 3 shows Examples 1 to 5.
This is a result showing the temperature dependence of the loss coefficient of the material used in Comparative Example 1.2. In FIG. 1, 1, 1' are metal plates, 2.2', 3.
3' is a roll, 4, 4', 8 is a leveler, 5, 5' is a preheating process, 6, 6' is a roll, 9 is a reheating process, 10 is a first cooling process, Step 1 is a second cooling process, 12.13 is a slitter, 7 is a highly inferior butene with a high softening point.
11 Propene l ethene terpolymer resin film, 1
4 is a product, a vibration-damping composite metal plate. Also, Figure 2
, 15 is a roll, 16, 18 is an electrolyte tank, 17
19 is a positive electrode plate, 19 is a negative electrode plate, 20 is a power source, 21 is a washing process, 22 is a drying process, 23 is a metal plate before degreasing, and 24 is a metal plate after degreasing. Patent Applicant Daicel Seyurus Co., Ltd. Procedural Amendment (Voluntary) 1. Display of the case 1988 Patent Application No. 44424 2, Title of invention: Vibration damping composite metal plate 3, Person making the amendment 4, Subject of the amendment 5, Contents of the amendment are used. (2) Add the following sentence between lines 8 and 9 on page 8 of the specification. The loss coefficient (maximum value) shown was 0.1. (3) Table 1 on page 9 of the specification is corrected as follows. (4) Correct Figure 3 of the drawing as shown in the attached sheet. September 3, 1986 Patent Office Officer Fumiyoshi Yoshida 1.
Display of the case Patent Application No. 44424 of 1988 2, Name of the invention Vibration-damping composite metal plate 3, Person making the amendment Relationship to the case Patent applicant Postal code 100 Address 3-8-1 Kasumigaseki, Chiyoda-ku, Tokyo Mr. No.
Name: Daicel-Hüls Co., Ltd. September 6, 1986
Day 5, Subject of amendment Procedural amendment (voluntary) May 24, 1988
Claims (1)
間層として２枚の金属板の間に接着してなることを特徴
とする振動減衰性複合金属板。A vibration-damping composite metal plate comprising a butene-1/propene/ethene terpolymer resin bonded between two metal plates as an intermediate layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4442487A JPH0193347A (en) | 1987-02-27 | 1987-02-27 | Vibration-attenuating composite metallic sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4442487A JPH0193347A (en) | 1987-02-27 | 1987-02-27 | Vibration-attenuating composite metallic sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0193347A true JPH0193347A (en) | 1989-04-12 |
Family
ID=12691106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4442487A Pending JPH0193347A (en) | 1987-02-27 | 1987-02-27 | Vibration-attenuating composite metallic sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0193347A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5286576A (en) * | 1989-08-21 | 1994-02-15 | The B. F. Goodrich Company | Compression molded flame retardant and high impact strength ultra high molecular weight polyethylene composition |
| JP2008202782A (en) * | 2007-01-26 | 2008-09-04 | Jtekt Corp | Rolling bearing device |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57170946A (en) * | 1981-04-15 | 1982-10-21 | Mitsui Toatsu Chem Inc | Modified polypropylene composition |
-
1987
- 1987-02-27 JP JP4442487A patent/JPH0193347A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57170946A (en) * | 1981-04-15 | 1982-10-21 | Mitsui Toatsu Chem Inc | Modified polypropylene composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5286576A (en) * | 1989-08-21 | 1994-02-15 | The B. F. Goodrich Company | Compression molded flame retardant and high impact strength ultra high molecular weight polyethylene composition |
| JP2008202782A (en) * | 2007-01-26 | 2008-09-04 | Jtekt Corp | Rolling bearing device |
| EP1950433A3 (en) * | 2007-01-26 | 2013-05-01 | JTEKT Corporation | Rolling bearing device |
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