JPH0155919B2 - - Google Patents
Info
- Publication number
- JPH0155919B2 JPH0155919B2 JP2057282A JP2057282A JPH0155919B2 JP H0155919 B2 JPH0155919 B2 JP H0155919B2 JP 2057282 A JP2057282 A JP 2057282A JP 2057282 A JP2057282 A JP 2057282A JP H0155919 B2 JPH0155919 B2 JP H0155919B2
- Authority
- JP
- Japan
- Prior art keywords
- slag
- continuous casting
- electric furnace
- steel
- quenched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002893 slag Substances 0.000 claims description 41
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- 238000009749 continuous casting Methods 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 5
- 229910052602 gypsum Inorganic materials 0.000 claims description 4
- 239000010440 gypsum Substances 0.000 claims description 4
- 239000010802 sludge Substances 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 description 10
- 238000001816 cooling Methods 0.000 description 4
- 238000010410 dusting Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
Landscapes
- Furnace Details (AREA)
- Treatment Of Sludge (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Description
本発明は冷却の過程で崩壊し、取扱い難い高塩
基度製鋼スラグの有効利用方法に関するものであ
る。製鋼スラグとしては各種のものがあるが、本
願発明ではこれらの中、高塩基度の普通鋼の還元
期スラグ、特殊鋼の電気炉スラグ及び連続鋳造ス
ラグを対象とする。ここで普通鋼の還元期スラグ
とは、普通鋼を電気炉精練で造る場合の還元精練
工程で排出されるスラグのことである。
現在この3種類のスラグは、ノロ鍋に受け約8
〜12時間冷却後排出されているが、約150〜200℃
になるとダステイングを起こして崩壊飛散する為
作業環境は悪く、又飛散防止の為に散水後埋立廃
棄されているのが現状である。
本発明は上述の欠点を解消し、有効に利用する
方法に係り、その要旨は普通鋼の還元期スラグ、
特殊鋼の電気炉スラグ又は連続鋳造後に発生する
連続鋳造スラグを空気急冷しβ−2CaO・SiO2主
体物となした後、石膏を添加して粉砕しヘドロ固
化材や土質改良材として利用する方法である。
以下本願発明方法の作用効果を確認するために
行なつた実験及びその結果を示す。
実験に用いた試料の化学分析値、性状を第1表
に示す。
下記第1表中、還元期スラグとは普通鋼の還元
期スラグを、CCスラグとは連続鋳造スラグを、
電気炉スラグとは特殊鋼の電気炉スラグを、又酸
化期スラグとは普通鋼の酸化期スラグをそれぞれ
示す(以下同じ)。第1表中で還元期スラグ、CC
スラグ及び電気炉スラグの主含有鉱物はγ−
2CaO・SiO2以外はX線回折の結果バツクグラン
ド内に入る位の少量しかなかつた為に省略してい
る。
次に各スラグの可溶成分の分析値を第2表に示
す。
The present invention relates to a method for effectively utilizing high basicity steelmaking slag, which disintegrates during the cooling process and is difficult to handle. There are various types of steelmaking slag, and among these, the present invention targets reduction stage slag of ordinary steel with high basicity, electric furnace slag of special steel, and continuous casting slag. Here, the reduction stage slag of ordinary steel refers to slag discharged during the reduction scouring process when ordinary steel is produced by electric furnace smelting. Currently, these three types of slag are placed in a slag pot for about 80 minutes.
It is discharged after cooling for ~12 hours, approximately 150~200℃
When this happens, the work environment is bad because it causes dusting and disintegrates, and the current situation is that it is disposed of in a landfill after being sprinkled with water to prevent it from scattering. The present invention solves the above-mentioned drawbacks and relates to a method for effectively utilizing the slag in the reduction period of ordinary steel.
A method in which electric furnace slag of special steel or continuous casting slag generated after continuous casting is quenched in air to form β-2CaO/SiO 2 as the main substance, and then gypsum is added and crushed to be used as a sludge solidification material or soil improvement material. It is. Experiments conducted to confirm the effects of the method of the present invention and their results will be shown below. Table 1 shows the chemical analysis values and properties of the samples used in the experiment. In Table 1 below, reduction stage slag refers to reduction stage slag of ordinary steel, CC slag refers to continuous casting slag,
Electric furnace slag refers to electric furnace slag of special steel, and oxidation stage slag refers to oxidation stage slag of ordinary steel (the same applies hereinafter). In Table 1, reduction stage slag, CC
The main mineral content of slag and electric furnace slag is γ-
Other than 2CaO・SiO 2 , the amount was omitted because the amount was so small that it fell within the background as a result of X-ray diffraction. Next, Table 2 shows the analytical values of the soluble components of each slag.
【表】
〓
〓*2 冷却の過程でダステイングを起して崩壊した
ので100%とした。
[Table] 〓
*2 It was set as 100% because it collapsed due to dusting during the cooling process.
【表】
第1表に示す還元期スラグ、CCスラグ、電気
炉スラグを電融マグネシアルツボに入れて再溶解
し、底に穴を開けたルツボから溶融スラグを流出
させ、エアーを強く吹付け鉄製容器に急冷された
球状あるいは楕円状急冷物を集めた。
この急冷されたスラグは、主含有鉱物はβ−
2CaO・SiO2であり、オートクレーブ処理
(ASTM)した場合の崩壊率は約1〜2%であつ
た。
この急冷スラグに二水石膏を4〜7重量%配合
してボールミルにてブレーン値約2000〜2500cm2/
gに粉砕し試料とした(以後普通鋼の還元期スラ
グ等の急冷粉砕物と記す)。又比較の為に市販の
普通ポルトランドセメント、高炉水滓粉砕物
(44μm以下、ブレーン値3100cm2/g)、転炉スラ
グ尾鉱(0.5mm以下で44μm以下約72%)、石灰
(試薬一級の生石灰)を用い水分50%のヘドロに
第3表に示す割合で配合し、撹拌機で混合し、ビ
ニール袋に入れて固化状態を調べた結果第3表に
示す如くであつた。第3表中配合割合は乾量での
重量%を示し、◎は手で押した場合に非常に硬い
ことを、〇は同硬いことを、△はやや硬いこと
を、×は固化していないことをそれぞれ示す。
又水分28%の関東ローム層土に、上述したのと
同じ様に普通鋼の還元期スラグ等の急冷粉砕物等
を添加し、モルタル練り鉢で混合し、土質試験モ
ールドにランマーで三層に分けて詰め(JIS法)、
10日間湿空養生(20℃、60%)後、圧縮強さを調
べた結果を第4表に示す。[Table] The reducing stage slag, CC slag, and electric furnace slag shown in Table 1 are put into an electro-fused magnesia crucible and remelted, the molten slag flows out from the crucible with a hole in the bottom, and is strongly blown with air. The quenched spherical or elliptical objects were collected in a container. The main mineral content of this rapidly cooled slag is β-
2CaO.SiO 2 , and the disintegration rate when autoclaved (ASTM) was approximately 1 to 2%. This rapidly cooled slag is mixed with 4 to 7% by weight of gypsum dihydrate and milled in a ball mill to obtain a Blaine value of approximately 2000 to 2500 cm 2 /
(hereinafter referred to as quenched pulverized product such as reduction period slag of ordinary steel). For comparison, commercially available ordinary Portland cement, ground blast furnace water slag (44 μm or less, Blaine value 3100 cm 2 /g), converter slag tailings (approximately 72% of 0.5 mm or less and 44 μm or less), lime (reagent grade 1) Quicklime) was added to sludge with a moisture content of 50% in the proportions shown in Table 3, mixed with a stirrer, placed in a plastic bag, and the solidification state was examined. The results were as shown in Table 3. The compounding ratio in Table 3 indicates the dry weight%, where ◎ means that it is very hard when pressed by hand, 〇 means that it is the same hardness, △ means that it is slightly hard, and × means that it is not solidified. Each shows that. In addition, quenched crushed slag of common steel was added to the Kanto loam layered soil with a moisture content of 28% in the same manner as described above, mixed in a mortar bowl, and then placed in a soil test mold in three layers with a rammer. Separate and pack (JIS method),
Table 4 shows the results of examining the compressive strength after 10 days of humid air curing (20°C, 60%).
【表】【table】
【表】
* 普通鋼の還元期スラグ等のダステイング物
[Table] * Dusting materials such as slag during the reduction stage of ordinary steel
【表】【table】
【表】
以上述べて来た様に本願発明方法によれば、溶
融状態から空気急冷される事により、鉱物組成が
β−2CaO・SiO2で崩壊性が無く、かつ水硬性を
有する急冷スラグとなり、これに石膏を添加した
ものはセメントや高炉水滓粉末を用いた場合と同
様に、ヘドロや火山灰土等を固化させる事が出
来、しかも少量の添加で圧縮強さの大なる安定土
質が得られるという効果がある。
更に本願発明方法では溶融スラグの急冷時に、
顕熱を熱風等として回収し有効利用する事も出来
る。[Table] As described above, according to the method of the present invention, by air quenching from a molten state, quenched slag with a mineral composition of β-2CaO・SiO 2 , non-collapsible, and hydraulic property is formed. Adding gypsum to this can solidify sludge, volcanic ash, etc. in the same way as cement or blast furnace water slag powder, and even with a small amount of addition, stable soil with high compressive strength can be obtained. It has the effect of being Furthermore, in the method of the present invention, when rapidly cooling the molten slag,
Sensible heat can also be recovered and used effectively as hot air, etc.
Claims (1)
グ又は連続鋳造後に発生する連続鋳造スラグを空
気急冷しβ−2CaO・SiO2主体物となした後、石
膏を添加して粉砕しヘドロ固化材や土質改良材と
して利用する方法。1 Reduction stage slag of ordinary steel, electric furnace slag of special steel, or continuous casting slag generated after continuous casting is quenched in air to form β-2CaO/SiO 2 main components, and then gypsum is added and crushed to form a sludge solidification material. and how to use it as a soil improvement material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2057282A JPS58137498A (en) | 1982-02-10 | 1982-02-10 | Utilization of high-basicity steel slag |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2057282A JPS58137498A (en) | 1982-02-10 | 1982-02-10 | Utilization of high-basicity steel slag |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS58137498A JPS58137498A (en) | 1983-08-15 |
JPH0155919B2 true JPH0155919B2 (en) | 1989-11-28 |
Family
ID=12030904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2057282A Granted JPS58137498A (en) | 1982-02-10 | 1982-02-10 | Utilization of high-basicity steel slag |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58137498A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008022827A (en) * | 2006-07-25 | 2008-02-07 | Sangyo Shinko Kk | Planting base material and method for growing plant |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61497A (en) * | 1984-04-28 | 1986-01-06 | Nippon Jiryoku Senko Kk | Utilization of high basicity steel making slug |
JPS6121794A (en) * | 1984-07-10 | 1986-01-30 | Nippon Jiryoku Senko Kk | Utilization of steel making slag |
JPS6121793A (en) * | 1984-07-10 | 1986-01-30 | Nippon Jiryoku Senko Kk | Utilization of steel making slag |
JP2805065B2 (en) * | 1988-07-13 | 1998-09-30 | 株式会社星野産商 | Slag wool production method |
DE10023074C1 (en) * | 2000-05-05 | 2001-11-15 | Mannesmann Ag | Process for the production of granules from converter slag |
JP3839331B2 (en) * | 2002-02-25 | 2006-11-01 | 日本磁力選鉱株式会社 | Steelmaking slag treatment method |
KR101234787B1 (en) * | 2010-11-10 | 2013-02-20 | 주식회사 에코마이스터 | Ultra-fast hard hydraulic binder using reduced slag powder and its manufacturing method |
CN105300795B (en) * | 2014-06-18 | 2018-02-02 | 上海宝冶钢渣综合开发实业有限公司 | A kind of detection method of slag product stability |
-
1982
- 1982-02-10 JP JP2057282A patent/JPS58137498A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008022827A (en) * | 2006-07-25 | 2008-02-07 | Sangyo Shinko Kk | Planting base material and method for growing plant |
Also Published As
Publication number | Publication date |
---|---|
JPS58137498A (en) | 1983-08-15 |
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