JPH0140335B2 - - Google Patents

Info

Publication number: JPH0140335B2
Authority: JP; Japan
Prior art keywords: carbon atoms; dye; silver; sharpening; composition
Prior art date: 1978-11-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP54502010A

Other languages

English (en)

Japanese (ja)

Other versions

JPS55501111A (no

Inventor

Baanaado Aran Rii

Ronarudo Uiriamu Baarozu

Jatsuku Ii Riisu

Haabei Ei Buraun

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

3M Co

Original Assignee

Minnesota Mining and Manufacturing Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-11-29

Filing date

1979-11-29

Publication date

1989-08-28

1978-11-29 Priority claimed from US05/964,480 external-priority patent/US4260676A/en

1978-11-29 Priority claimed from US05/964,479 external-priority patent/US4197131A/en

1979-11-29 Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co

1980-12-11 Publication of JPS55501111A publication Critical patent/JPS55501111A/ja

1989-08-28 Publication of JPH0140335B2 publication Critical patent/JPH0140335B2/ja

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 description 81
239000000975 dye Substances 0.000 description 66
125000004432 carbon atom Chemical group C* 0.000 description 47
229910052709 silver Inorganic materials 0.000 description 38
239000004332 silver Substances 0.000 description 38
150000001875 compounds Chemical class 0.000 description 32
125000000217 alkyl group Chemical group 0.000 description 31
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 28
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 22
229910052739 hydrogen Inorganic materials 0.000 description 22
239000001257 hydrogen Substances 0.000 description 22
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
-1 silver halide Chemical class 0.000 description 20
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 17
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 15
125000003545 alkoxy group Chemical group 0.000 description 13
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 13
125000001424 substituent group Chemical group 0.000 description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
125000004435 hydrogen atom Chemical group [H]* 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 11
150000002431 hydrogen Chemical class 0.000 description 10
229940100890 silver compound Drugs 0.000 description 10
150000003379 silver compounds Chemical class 0.000 description 10
239000003638 chemical reducing agent Substances 0.000 description 9
238000000034 method Methods 0.000 description 8
125000005843 halogen group Chemical group 0.000 description 7
QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 6
125000003342 alkenyl group Chemical group 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
125000000896 monocarboxylic acid group Chemical group 0.000 description 6
239000002904 solvent Substances 0.000 description 6
238000004458 analytical method Methods 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
238000011161 development Methods 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
239000000463 material Substances 0.000 description 5
238000002844 melting Methods 0.000 description 5
230000008018 melting Effects 0.000 description 5
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
229910052717 sulfur Inorganic materials 0.000 description 5
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
239000013078 crystal Substances 0.000 description 4
229910052736 halogen Inorganic materials 0.000 description 4
150000002367 halogens Chemical class 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000000047 product Substances 0.000 description 4
238000010992 reflux Methods 0.000 description 4
239000000523 sample Substances 0.000 description 4
AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 4
239000007787 solid Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000003710 aryl alkyl group Chemical group 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
FTKASJMIPSSXBP-UHFFFAOYSA-N ethyl 2-nitroacetate Chemical compound CCOC(=O)C[N+]([O-])=O FTKASJMIPSSXBP-UHFFFAOYSA-N 0.000 description 3
239000011872 intimate mixture Substances 0.000 description 3
DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 3
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
150000007524 organic acids Chemical class 0.000 description 3
125000005010 perfluoroalkyl group Chemical group 0.000 description 3
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000003756 stirring Methods 0.000 description 3
238000012360 testing method Methods 0.000 description 3
PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
238000000862 absorption spectrum Methods 0.000 description 2
238000007792 addition Methods 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000012043 crude product Substances 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
125000000623 heterocyclic group Chemical group 0.000 description 2
238000003384 imaging method Methods 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
FBSFWRHWHYMIOG-UHFFFAOYSA-N methyl 3,4,5-trihydroxybenzoate Chemical compound COC(=O)C1=CC(O)=C(O)C(O)=C1 FBSFWRHWHYMIOG-UHFFFAOYSA-N 0.000 description 2
LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
238000012545 processing Methods 0.000 description 2
CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
229940081974 saccharin Drugs 0.000 description 2
235000019204 saccharin Nutrition 0.000 description 2
239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
LOTKRQAVGJMPNV-UHFFFAOYSA-N 1-fluoro-2,4-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(F)C([N+]([O-])=O)=C1 LOTKRQAVGJMPNV-UHFFFAOYSA-N 0.000 description 1
VKKFKIAFZAKWCX-UHFFFAOYSA-N 1-methyl-4-(nitromethylidene)quinoline Chemical compound C1=CC=C2N(C)C=CC(=C[N+]([O-])=O)C2=C1 VKKFKIAFZAKWCX-UHFFFAOYSA-N 0.000 description 1
PXNJGLAVKOXITN-UHFFFAOYSA-N 2-(4-nitrophenyl)acetonitrile Chemical compound [O-][N+](=O)C1=CC=C(CC#N)C=C1 PXNJGLAVKOXITN-UHFFFAOYSA-N 0.000 description 1
BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
MAWCOLFDMMNMNV-UHFFFAOYSA-N 4-(2,4-dinitrophenyl)-1-methyl-2-(nitromethylidene)-3,4-dihydroquinoline Chemical compound [N+](=O)([O-])C1=C(C=CC(=C1)[N+](=O)[O-])C1CC(N(C2=CC=CC=C12)C)=C[N+](=O)[O-] MAWCOLFDMMNMNV-UHFFFAOYSA-N 0.000 description 1
ZSUDUDXOEGHEJR-UHFFFAOYSA-N 4-methylnaphthalen-1-ol Chemical compound C1=CC=C2C(C)=CC=C(O)C2=C1 ZSUDUDXOEGHEJR-UHFFFAOYSA-N 0.000 description 1
ZVEWFTICTSQBDM-UHFFFAOYSA-N 4-methylphenol Chemical compound [CH2]C1=CC=C(O)C=C1 ZVEWFTICTSQBDM-UHFFFAOYSA-N 0.000 description 1
QQKKFVXSQXUHPI-NBVRZTHBSA-N Acidissiminol epoxide Chemical compound O1C(C)(C)C1CC(O)C(/C)=C/COC(C=C1)=CC=C1CCNC(=O)C1=CC=CC=C1 QQKKFVXSQXUHPI-NBVRZTHBSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
229920008347 Cellulose acetate propionate Polymers 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
206010034972 Photosensitivity reaction Diseases 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
FCHAMFUEENBIDH-UHFFFAOYSA-N Severin Natural products CC1CCC2C(C)C3CCC4(O)C(CC5C4CC(O)C6CC(CCC56C)OC(=O)C)C3CN2C1 FCHAMFUEENBIDH-UHFFFAOYSA-N 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
230000002238 attenuated effect Effects 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
229920002301 cellulose acetate Polymers 0.000 description 1
HKQOBOMRSSHSTC-UHFFFAOYSA-N cellulose acetate Chemical compound OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(O)C(O)C1O.CC(=O)OCC1OC(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(COC(C)=O)O1.CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 HKQOBOMRSSHSTC-UHFFFAOYSA-N 0.000 description 1
229920006217 cellulose acetate butyrate Polymers 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000013068 control sample Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
FJGRBSMBMCJJOM-UHFFFAOYSA-N ethyl 6-(3-ethyl-1,3-benzothiazol-2-ylidene)-2-nitrohexa-2,4-dienoate Chemical compound C1=CC=C2N(CC)C(=CC=CC=C(C(=O)OCC)[N+]([O-])=O)SC2=C1 FJGRBSMBMCJJOM-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
229940071870 hydroiodic acid Drugs 0.000 description 1
JJIKCECWEYPAGR-UHFFFAOYSA-N icosanoic acid;silver Chemical compound [Ag].CCCCCCCCCCCCCCCCCCCC(O)=O JJIKCECWEYPAGR-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
239000003550 marker Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
NGYIMTKLQULBOO-UHFFFAOYSA-L mercury dibromide Chemical compound Br[Hg]Br NGYIMTKLQULBOO-UHFFFAOYSA-L 0.000 description 1
IBKQQKPQRYUGBJ-UHFFFAOYSA-N methyl gallate Natural products CC(=O)C1=CC(O)=C(O)C(O)=C1 IBKQQKPQRYUGBJ-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
VLZLOWPYUQHHCG-UHFFFAOYSA-N nitromethylbenzene Chemical compound [O-][N+](=O)CC1=CC=CC=C1 VLZLOWPYUQHHCG-UHFFFAOYSA-N 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000033116 oxidation-reduction process Effects 0.000 description 1
FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
IWDCLRJOBJJRNH-UHFFFAOYSA-N para-hydroxytoluene Natural products CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
230000036211 photosensitivity Effects 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
229960004889 salicylic acid Drugs 0.000 description 1
230000001235 sensitizing effect Effects 0.000 description 1
150000003378 silver Chemical class 0.000 description 1
OIZSSBDNMBMYFL-UHFFFAOYSA-M silver;decanoate Chemical compound [Ag+].CCCCCCCCCC([O-])=O OIZSSBDNMBMYFL-UHFFFAOYSA-M 0.000 description 1
MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 1
LTYHQUJGIQUHMS-UHFFFAOYSA-M silver;hexadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCC([O-])=O LTYHQUJGIQUHMS-UHFFFAOYSA-M 0.000 description 1
ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000010345 tape casting Methods 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49836—Additives
- G03C1/49845—Active additives, e.g. toners, stabilisers, sensitisers
- G03C1/49854—Dyes or precursors of dyes

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

JP54502010A 1978-11-29 1979-11-29 Expired JPH0140335B2 (no)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US05/964,480 US4260676A (en)	1978-11-29	1978-11-29	Photothermographic emulsions containing thermolabile acutance dyes
US05/964,479 US4197131A (en)	1978-11-29	1978-11-29	Dry silver photo-sensitive compositions
GB7846459		1978-11-29

Publications (2)

Publication Number	Publication Date
JPS55501111A JPS55501111A (no)	1980-12-11
JPH0140335B2 true JPH0140335B2 (no)	1989-08-28

Family

ID=27260633

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP54502010A Expired JPH0140335B2 (no)	1978-11-29	1979-11-29

Country Status (5)

Country	Link
EP (1)	EP0012020B1 (no)
JP (1)	JPH0140335B2 (no)
DE (1)	DE2953375C2 (no)
GB (1)	GB2058116B (no)
WO (1)	WO1980001213A1 (no)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR965555A (no) *		1950-09-15
US2411507A (en) *	1943-12-20	1946-11-26	Ilford Ltd	Photographic material
GB849741A (en) *	1956-05-15	1960-09-28	Ilford Ltd	Improvements in or relating to hemicyanine dyestuffs
USRE29168E (en) *	1968-10-09	1977-04-05	Eastman Kodak Company	Photographic elements with light absorbing layers
DE2065606B2 (de) *	1970-09-09	1976-06-16		Azolindolin-farbstoffe, deren herstellung und verwendung zum faerben von organischen fasermaterialien
DE2211959A1 (de) *	1972-03-11	1973-09-20	Bayer Ag	Indolinfarbstoffe
US3988156A (en) *	1974-02-19	1976-10-26	Eastman Kodak Company	Photographic supports and elements utilizing photobleachable o-nitroarylidene dyes
US4028113A (en) *	1974-02-19	1977-06-07	Eastman Kodak Company	Photographic supports and elements utilizing photobleachable O-nitroarylidene dyes
US3984248A (en) *	1974-02-19	1976-10-05	Eastman Kodak Company	Photographic polymeric film supports containing photobleachable o-nitroarylidene dyes
US4033948A (en) *	1976-05-17	1977-07-05	Minnesota Mining And Manufacturing Company	Acutance agents for use in thermally-developable photosensitive compositions
JPS53133033A (en) *	1977-04-25	1978-11-20	Fuji Photo Film Co Ltd	Silver halide photographic material

1979
- 1979-11-29 JP JP54502010A patent/JPH0140335B2/ja not_active Expired
- 1979-11-29 EP EP79302730A patent/EP0012020B1/en not_active Expired
- 1979-11-29 DE DE2953375T patent/DE2953375C2/de not_active Expired - Fee Related
- 1979-11-29 WO PCT/GB1979/000203 patent/WO1980001213A1/en unknown
- 1979-11-29 GB GB8022130A patent/GB2058116B/en not_active Expired

Also Published As

Publication number	Publication date
GB2058116A (en)	1981-04-08
DE2953375T1 (de)	1980-12-04
EP0012020A1 (en)	1980-06-11
GB2058116B (en)	1983-05-18
EP0012020B1 (en)	1983-01-26
JPS55501111A (no)	1980-12-11
WO1980001213A1 (en)	1980-06-12
DE2953375C2 (de)	1996-09-05

Publication	Publication Date	Title
US4123274A (en)	1978-10-31	Heat developable imaging materials and process
US4088497A (en)	1978-05-09	Acutance agents for use in thermally-developable photosensitive compositions
US4271263A (en)	1981-06-02	Thermally developable photosensitive compositions containing acutance agents
US4524128A (en)	1985-06-18	Spectrally sensitized silver halide photothermographic material
JPH09509503A (ja)	1997-09-22	写真および光熱写真物品用ハレーション防止およびアキュタンス（ａｃｕｔａｎｃｅ）物質としてのジヒドロペリミジンスクエア酸錯体染料
JP2648774B2 (ja)	1997-09-03	ポジ型光熱写真材料
JP2912535B2 (ja)	1999-06-28	熱漂白性染料組成物
JPH07119953B2 (ja)	1995-12-20	フオトサ−モグラフイツク材料
EP0107093B1 (en)	1989-03-08	Photothermographic recording material comprising a substituted triazine stabilizer precursor compound
EP0119831B1 (en)	1988-01-07	Heat bleachable dye systems
US4283487A (en)	1981-08-11	Thermolabile acutance dyes for dry silver
EP0350202A2 (en)	1990-01-10	Photothermographic elements
US6040130A (en)	2000-03-21	Photothermographic and thermographic films containing low levels of unsaturated fatty acid to prevent fog
US4197131A (en)	1980-04-08	Dry silver photo-sensitive compositions
JP2986667B2 (ja)	1999-12-06	第４アンモニウムフェニルスルホニルアセテート熱染料漂白剤
JP2004163932A (ja)	2004-06-10	熱現像性組成物、フォトサーモグラフィ材料および画像形成方法
JPS63187233A (ja)	1988-08-02	安定な発色現像剤を含有するフオトサーモグラフイー乳剤
JPH0140335B2 (no)	1989-08-28
US5260180A (en)	1993-11-09	Photothermographic imaging media employing silver salts of tetrahydrocarbyl borate anions
US4308379A (en)	1981-12-29	Acutance agents for use in thermally developable photosensitive compositions
JP2785129B2 (ja)	1998-08-13	非感光性熱現像型乾式銀塩材料
US4316984A (en)	1982-02-23	Thermolabile acutance dyes
JPH0652387B2 (ja)	1994-07-06	熱現像性感光材料
JPS63172264A (ja)	1988-07-15	フオトサーモグラフイー乳剤
US4260676A (en)	1981-04-07	Photothermographic emulsions containing thermolabile acutance dyes