JPH01287265A - Carbonaceous composite material - Google Patents
Carbonaceous composite materialInfo
- Publication number
- JPH01287265A JPH01287265A JP11363388A JP11363388A JPH01287265A JP H01287265 A JPH01287265 A JP H01287265A JP 11363388 A JP11363388 A JP 11363388A JP 11363388 A JP11363388 A JP 11363388A JP H01287265 A JPH01287265 A JP H01287265A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- substrate
- skeletal structure
- noble metal
- vitreous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 8
- 229910021397 glassy carbon Inorganic materials 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000010409 thin film Substances 0.000 claims abstract description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 5
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 3
- 229910052737 gold Inorganic materials 0.000 claims abstract 2
- 229910052763 palladium Inorganic materials 0.000 claims abstract 2
- 230000005484 gravity Effects 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011347 resin Substances 0.000 abstract description 6
- 229920005989 resin Polymers 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 4
- 239000012298 atmosphere Substances 0.000 abstract description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 238000004544 sputter deposition Methods 0.000 abstract description 2
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 2
- 239000011496 polyurethane foam Substances 0.000 abstract 2
- 239000003575 carbonaceous material Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 238000010304 firing Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- -1 alcohol compound Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
Landscapes
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】 Ｌ組Ｌ列札脂飢１ この発明はノコ−ボン質複合月ｙ４に関する。[Detailed description of the invention] L group L row bill fat starvation 1 This invention relates to the nocobonic composite moon y4.
従来の技術
三次元骨格構造を有する金属多孔体の触媒は従来公知で
ある。たとえば、発泡ウレタンフオームの表面にＮｉ等
の電気メツキを施し＝ １ −
たあど、ウレタンフオームを焼去ざせることにより連通
孔を有する発泡金属にして触媒を構成している。BACKGROUND OF THE INVENTION Porous metal catalysts having a three-dimensional skeleton structure are known in the art. For example, the surface of a foamed urethane foam is electroplated with Ni or the like, and then the urethane foam is burned off to form a foamed metal having communicating holes to form a catalyst.
一明が解′（シようとＬ乞ｌ」劇
従来の発泡金属においては、三次元骨格の断面がウレタ
ンフオームの焼去後に空洞とＩノで残存づる。In conventional metal foam, the cross section of the three-dimensional skeleton remains in the form of cavities and holes after the urethane foam is burned out.
発泡金属のみで成りたっているため、骨格構造の強度が
小ざくなる欠点があった。Since it was made only of foamed metal, it had the disadvantage that the strength of the skeletal structure was reduced.
発明の目的
そこで、この発明（Ｊ、従来の三次元骨格の金属多孔体
に比較し−（強度を向上さぜるこどのてきるカーボン′
ｆＩ複合材利、例えば触媒等に用いる複合１ｔ３ Ｊ”
ｌを提供することを目的としている。Purpose of the Invention Therefore, the present invention (J) is based on carbon'
fI composite materials, such as composite 1t3J used for catalysts, etc.
The aim is to provide l.
几Ｊし生方」Ｌ
前ｊホの１的を達成づるために、この発明は請求項１に
記載したカーボン質複合月利を要一 ２ 一
旨としている。In order to achieve the first objective of the above, the present invention focuses on the carbonaceous composite monthly interest rate set forth in claim 1.
ロ −「を ′するための二゛
所定の条件をみたずガラス状ノＪ−ボンににつで三次元
骨格構造の基材を構成し、その基材の表面に薄膜状にＰ
ｔ 、 Ｐｄ 、△１」またはＡ（＋の貴金属を被覆し
た。In order to achieve this, a base material with a three-dimensional skeleton structure is constructed of glass-like J-bonds, and a thin film of P is applied to the surface of the base material, without meeting certain conditions.
t, Pd, △1'' or A(+ noble metal was coated.
１１丸」
基材がガラス状カーボンよりなり高強度を有するため、
複合１の強度を大ぎくできる。11 Maru” Because the base material is made of glassy carbon and has high strength,
The strength of Composite 1 can be greatly increased.
また、貴金属の薄膜の厚みを小さくしても、強度上の問
題が生じない。Further, even if the thickness of the noble metal thin film is made small, no strength problems arise.
尖皿に
三次元骨格構造のポーラスな軟質のポリニスデル系ウレ
タンフオームに樹脂（たとえばフルフリルアルコール重
合物）を付着さぜる。A resin (for example, furfuryl alcohol polymer) is attached to a porous soft polynisder urethane foam with a three-dimensional skeleton structure on a pointed plate.
たどえば、ウレタンフオームにフリフリルアルコール手
合物を含浸させる操作において、目詰まりがなく、かつ
均一に脱液が行えるＪニうに遠心脱液装置を用いて含浸
するのが好ましい。For example, in the operation of impregnating the urethane foam with the frifuryl alcohol compound, it is preferable to impregnate the urethane foam using a centrifugal dewatering device that does not cause clogging and can uniformly remove the fluid.
そのあと、１５０’Ｃで樹脂を乾燥硬化させる。しかる
後、非酸化性雰囲気（たとえば窒素雰囲気）において９
５０℃で焼成覆る。この焼成によりウレタンフオームは
炭化し、樹脂はガラス状カーボンとなり、骨格中に連通
孔を右するガラス状カーボン三次元骨格構造基材を形成
づる。Thereafter, the resin is dried and cured at 150'C. Thereafter, in a non-oxidizing atmosphere (e.g. nitrogen atmosphere) 9
Cover and bake at 50°C. By this firing, the urethane foam is carbonized, the resin becomes glassy carbon, and a three-dimensional glassy carbon skeleton structure base material having communicating holes in the skeleton is formed.
なお、前述の含浸→硬化→焼成の工程を複数回くり返し
たり、焼成後に純化のために塩素ガスと接触させながら
約２３００ ’Ｃで加熱してもにい。In addition, the above-mentioned impregnation → hardening → firing process may be repeated several times, or after firing, the material may be heated at about 2300'C while being brought into contact with chlorine gas for purification.
ガラス状カーボンの結晶子の大ぎさ１ａ（Ｘ）が３００
人よりも大きいと、結晶子が大ぎずぎるため、強度の低
下がみられる。また、ブタノール浸漬法の比重が１．７
０ｑ／ＣＣよりも大ぎいど、製造が極めて困難となる。The crystallite size 1a (X) of glassy carbon is 300
If it is larger than a human, the crystallites will be too large, resulting in a decrease in strength. In addition, the specific gravity of the butanol immersion method is 1.7.
If it is larger than 0q/CC, manufacturing becomes extremely difficult.
前述のようにして作られた三次元骨格構造のガラス状カ
ーボン基材の表面にスパッタリング法ににすＰｔ 、Ｐ
ｄ 、ＡＵまたはＡｇの薄膜を形成１ノ、各骨格の表面
を被覆する。、薄膜の厚みは２０μｎ１未満であると二
次元骨格構造の強度が十分でなく、２ｍｍを越えると三
次元骨格構造の空隙が少なくなるので、２０μｍ〜２ｍ
ｍが好ましい。スパッタリング法以外の方法（たとえば
、プラズマ法、電解メツキ法、非電解メツキ法、ＣＶＤ
法等）によって薄膜を形成してもＪ：い。Pt and P were sputtered onto the surface of the glassy carbon substrate with the three-dimensional skeleton structure prepared as described above.
d. Form a thin film of AU or Ag to coat the surface of each skeleton. If the thickness of the thin film is less than 20 μm, the strength of the two-dimensional skeleton structure will not be sufficient, and if it exceeds 2 mm, the voids in the three-dimensional skeleton structure will decrease.
m is preferred. Methods other than sputtering (for example, plasma method, electrolytic plating method, non-electrolytic plating method, CVD method)
J: It is not possible to form a thin film by a method such as a method.
Claims (1)
ノール浸漬法の比重が１．７０ｇ／ｃｃ以下であるガラ
ス状カーボンからなるカーボン三次元骨格構造基材の表
面にＰｔ、Ｐｄ、ＡｕまたはＡｇの貴金属の薄膜を被覆
したことを特徴とするカーボン質複合材料。1. Pt, Pd, Au on the surface of a three-dimensional carbon skeleton structure base material made of glassy carbon whose crystallite size La (Å) is 300 Å or less and the specific gravity by butanol immersion method is 1.70 g/cc or less Or, a carbonaceous composite material characterized by being coated with a thin film of a noble metal such as Ag.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11363388A JPH01287265A (en) | 1988-05-12 | 1988-05-12 | Carbonaceous composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11363388A JPH01287265A (en) | 1988-05-12 | 1988-05-12 | Carbonaceous composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01287265A true JPH01287265A (en) | 1989-11-17 |
Family
ID=14617181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11363388A Pending JPH01287265A (en) | 1988-05-12 | 1988-05-12 | Carbonaceous composite material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01287265A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003516508A (en) * | 1999-12-07 | 2003-05-13 | エスケイエフ エンジニアリング アンド リサーチ センター ビーブイ | Drum brakes and electric actuators therefor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5161404A (en) * | 1974-11-27 | 1976-05-28 | Ulvac Corp | Kinzokuzairyoto tansosenitokaranaru fukugozairyono seizoho |
| JPS5579871A (en) * | 1978-12-06 | 1980-06-16 | Sumitomo Electric Ind Ltd | Metal covering method for non-conductive substance |
-
1988
- 1988-05-12 JP JP11363388A patent/JPH01287265A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5161404A (en) * | 1974-11-27 | 1976-05-28 | Ulvac Corp | Kinzokuzairyoto tansosenitokaranaru fukugozairyono seizoho |
| JPS5579871A (en) * | 1978-12-06 | 1980-06-16 | Sumitomo Electric Ind Ltd | Metal covering method for non-conductive substance |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003516508A (en) * | 1999-12-07 | 2003-05-13 | エスケイエフ エンジニアリング アンド リサーチ センター ビーブイ | Drum brakes and electric actuators therefor |
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