JPH01275138A - Decoration sheet - Google Patents
Decoration sheetInfo
- Publication number
- JPH01275138A JPH01275138A JP10615388A JP10615388A JPH01275138A JP H01275138 A JPH01275138 A JP H01275138A JP 10615388 A JP10615388 A JP 10615388A JP 10615388 A JP10615388 A JP 10615388A JP H01275138 A JPH01275138 A JP H01275138A
- Authority
- JP
- Japan
- Prior art keywords
- pattern
- recesses
- curable resin
- unevenness
- thermoplastic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005034 decoration Methods 0.000 title 1
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 15
- 239000002932 luster Substances 0.000 claims description 15
- 230000000007 visual effect Effects 0.000 abstract description 11
- 238000004049 embossing Methods 0.000 abstract description 4
- 238000013461 design Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- -1 etc. Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は床材、壁装材、弱電機器のキャビネット、家電
機器の表面化粧シートに用いられる化粧シートに関する
。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a decorative sheet used for flooring materials, wall covering materials, cabinets of light electrical appliances, and surface decorative sheets for home appliances.
更に詳しくは、本発明は、金属光沢面に深さＯ１１〜２
０μの極めて浅い凹凸を形成することにより、その反射
光によって光沢又は明暗の相異を生じさせて興趣ある視
覚的な模様を形成した化粧シートに関する。More specifically, the present invention provides a metallic luster surface with a depth of O11-2.
The present invention relates to a decorative sheet in which an interesting visual pattern is formed by creating gloss or differences in brightness and darkness by the reflected light by forming extremely shallow irregularities of 0 μm.
〈従来技術〉
金属光沢面に極めて浅い凹凸を設けることにより上述の
ような模様が得られることは良く知られている。<Prior Art> It is well known that the above-mentioned pattern can be obtained by providing extremely shallow irregularities on a metallic shiny surface.
このような浅い凹凸を形成する方法としては、三つの方
法がある。■は微細なエンボス形状を有する印刷版に金
属光沢を有するインキを用いて微細な盛り上げ印刷を行
なう方法であり、■の方法は微細なエンボス版を用いて
シート表面にエンボス加工する方法であり、■の方法は
レーザーを利用してシート表面にエンボス加工する方法
である。There are three methods for forming such shallow irregularities. Method (2) is a method in which fine raised printing is performed using ink with a metallic luster on a printing plate having a fine embossed shape, and method (2) is a method in which the surface of the sheet is embossed using a fine embossing plate. Method (2) is a method of embossing the sheet surface using a laser.
〈発明が解決しようとする課題〉
■の方法では、他の方法と比べて形成されるエンボス（
凸形）がシャープでない為、意匠効果としては、不充分
であった。■の方法では表面にオーバーコートをしたも
のはほとんどなく、又オーバーコードした物はコート樹
脂の溶剤及び乾燥時の熱等によりエンボスのシャープさ
が損なわれていた。■の方法ではエンボス形状が最もシ
ャープであっても、生産性が悪く量産には適した方法で
はなかった。又後加工で加熱加工を行なうとほとんどエ
ンボスが消えてしまっていた。<Problem to be solved by the invention> In method (2), the emboss (
Since the convex shape was not sharp, the design effect was insufficient. In method (2), there were almost no overcoated surfaces, and the sharpness of the embossment was lost due to the solvent of the coating resin and the heat during drying. Even though the embossed shape was the sharpest in method (2), the productivity was poor and it was not suitable for mass production. Furthermore, when heat processing was performed in post-processing, most of the embossments disappeared.
〈課題を解決するための手段〉
この課題を解決するため、本発明は、金属光沢を有する
熱可塑性樹脂シートの表面をエンボス加工して深さ０．
１〜２０μの凹凸を設け、この凹部に透明な無溶剤タイ
プの硬化型樹脂を充填硬化させ、で成る化粧シートを提
供する。<Means for Solving the Problem> In order to solve this problem, the present invention embosses the surface of a thermoplastic resin sheet with metallic luster to a depth of 0.
A decorative sheet is provided by providing irregularities of 1 to 20 μm and filling and curing a transparent solvent-free curable resin in the recesses.
また、本発明は、その凹凸による模様が複数の平行な条
模様の集合した縞模様が更に複数個集合したもので、隣
り合った縞模様の条模様の条方向が異なるように組合わ
された模様である前記化粧シートを提供する。In addition, the present invention provides a pattern in which the pattern formed by the unevenness is a combination of a plurality of striped patterns in which a plurality of parallel striped patterns are assembled, and the striped patterns of adjacent striped patterns are combined so that the striped directions are different. The above-mentioned decorative sheet is provided.
〈実施例〉
以下、本発明を図面を参照して説明する。図面の第１図
は化粧シートの断面図、第２図は凹凸による物理的模様
を示す平面図である。<Example> The present invention will be described below with reference to the drawings. FIG. 1 of the drawings is a cross-sectional view of the decorative sheet, and FIG. 2 is a plan view showing a physical pattern due to unevenness.
第１図において、（１）は金属光沢を有する熱可塑性樹
脂シートを示し、表面に濶さ。、１〜２０μの凹凸（２
）が形成されている。この凹凸面は硬化Ｆ ＬＭ Ｊｌ
ａ（３）が被覆されており、凹部はこの樹脂（３）が充
填されている。In FIG. 1, (1) shows a thermoplastic resin sheet with metallic luster, and the surface is covered with water. , unevenness of 1 to 20μ (2
) is formed. This uneven surface is hardened F LM Jl
a(3) is coated, and the recess is filled with this resin (3).
本発明において、金属光沢を有する熱可塑性樹脂シート
（１）は光を反射するためのもので、凹凸（２）の形成
される面が金属光沢を有していれば良い。In the present invention, the thermoplastic resin sheet (1) with metallic luster is for reflecting light, and it is sufficient that the surface on which the unevenness (2) is formed has metallic luster.
具体的には、例えば金属光沢を有する粉末を練込んで厚
さ０．０５〜０．２胴に製膜した熱可塑性樹脂シートで
ある。金属光沢を有する粉末としては、アルミニウム、
銅、金、スズ、銀等の粉末又は雲母粉末が例示できる。Specifically, it is a thermoplastic resin sheet formed into a film having a thickness of 0.05 to 0.2 mm by kneading powder with metallic luster, for example. Examples of powders with metallic luster include aluminum,
Examples include powders of copper, gold, tin, silver, etc., and mica powders.
熱可塑性樹脂としてはポリ塩化ビニル、アクリル樹脂、
ポリエチレン、ポリプロピレン、ウレタン、エチレン−
酢酸ビニル共重合体等が例示できる。Thermoplastic resins include polyvinyl chloride, acrylic resin,
Polyethylene, polypropylene, urethane, ethylene-
Examples include vinyl acetate copolymers.
また、金属光沢を有する熱可塑性樹脂シート（１）の例
としては、熱可塑性樹脂シートの表面に金属光沢を有す
る粉末を含むインキで印刷したものや、金属を蒸着した
ものがある。かかる場合に用いられる熱可塑性樹脂と金
属光沢を有する粉末は上述ノモノト同一で良い、′？着
金金属してはアルミニウム、銅、スズ等が例示できる。Further, examples of the thermoplastic resin sheet (1) having metallic luster include those printed with ink containing powder having metallic luster on the surface of the thermoplastic resin sheet, and those having metal vapor-deposited on the surface of the thermoplastic resin sheet. The thermoplastic resin and powder with metallic luster used in such cases may be the same as those mentioned above. Examples of the deposited metal include aluminum, copper, and tin.
凹凸（２）は、上記金属光沢を有する熱可塑性樹脂シー
トの表面を加熱軟化してエンボス版で押圧することによ
り形成できる。この凹凸（２）は、光の反射方向をユン
トロールして、視覚的な模様を形成するもので、凹凸（
２）そのものの物理的模様が視覚的模様となるのではな
い。この理由から、凹凸（２）の深さは０．１〜２０μ
の極めて浅いものに限られる。The unevenness (2) can be formed by heating and softening the surface of the thermoplastic resin sheet having metallic luster and pressing it with an embossing plate. This unevenness (2) is to untroll the direction of light reflection and form a visual pattern.
2) The physical pattern itself does not become the visual pattern. For this reason, the depth of the unevenness (2) is 0.1 to 20μ.
limited to extremely shallow areas.
この深さの凹凸（２）は、凹凸の物理的模様が肉眼で判
別できないからである。The reason for the unevenness (2) having this depth is that the physical pattern of the unevenness cannot be discerned with the naked eye.
凹凸（２）の物理的模様は、複数の平行な条模様の集合
した縞模様が更に複数個集合したもので、隣り合った縞
模様の条模様の条方向が異なるように組合わされた模様
であることが望ましい。（第２図）、平行な条模様から
の反射光の干渉により、光沢又は明暗の相異が引き立っ
て、興趣溢れる視覚的模様が構成できるがらである。The physical pattern of unevenness (2) is a combination of multiple parallel striped patterns, and the adjacent striped patterns are combined in different directions. It is desirable that there be. (Fig. 2), the interference of reflected light from the parallel striped patterns brings out the difference in gloss or brightness, creating an interesting visual pattern.
硬化型樹脂（３）は透明なことが必要である。視覚的模
様は金属光沢面からの反射光により構成されるからであ
る。無色透明である必要はなく、有色透明又は半透明で
あっても良い。The curable resin (3) needs to be transparent. This is because the visual pattern is composed of light reflected from the metallic shiny surface. It does not have to be colorless and transparent, and may be colored and transparent or translucent.
また、硬化型樹脂（３）は無溶剤タイプであるこ七を要
する。溶剤タイプの硬化型樹脂は溶剤が熱可塑性樹脂を
犯し、また乾燥時又は硬化時の熱により凹凸が消失する
と共に、ン容剤の揮散により硬化型樹脂皮膜が不均一と
なり、光の反射を乱すからである。Further, the curable resin (3) requires a solvent-free type. In the case of solvent-based curable resins, the solvent damages the thermoplastic resin, and the unevenness disappears due to the heat during drying or curing, and the curable resin film becomes uneven due to volatilization of the solvent, which disrupts light reflection. It is from.
このような硬化型樹脂（３）としては、二液硬化型、あ
るいは電子線や紫外線等の放射線で硬化するアクリル系
、ウレタン系、エポキシ系、ポリエステル系の硬化型樹
脂が例示できる。中でも放射線で硬化する樹脂が望まし
い。加熱することなく速やかに硬化するからである。Examples of such curable resins (3) include two-component curable resins, and acrylic, urethane, epoxy, and polyester curable resins that are cured by radiation such as electron beams and ultraviolet rays. Among these, resins that are cured by radiation are desirable. This is because it hardens quickly without heating.
く試験例１〉
アルミニウム粉末を練り込んで製膜した厚ざ０゜２ ｍ
ｍのポリ塩化ビニルシートの表面に、常法により、深さ
１〜１０μの凹凸をエンボスした。凹凸の物理的形状は
第２図に示す通りである。Test Example 1> A film with a thickness of 0°2 m made by kneading aluminum powder
Irregularities with a depth of 1 to 10 μm were embossed on the surface of a polyvinyl chloride sheet of 1.0 m by a conventional method. The physical shape of the unevenness is as shown in FIG.
この凹凸面に反応性アクリル系紫外線硬化型樹脂を３０
ｇ／ｒｒｉ均一に塗布し、２０ｃ＋ｎの距離から、１０
０Ｈの水銀灯にて、２０秒間、２５０〜４００ ｎｍの
紫外線を１１１α射して硬化させた。なお、硬化型樹脂
は重合性モノアクリレート、モノメタクリレート、メタ
クリレート、光増感剤を主成分とするものである。30% of reactive acrylic ultraviolet curable resin is applied to this uneven surface.
g/rri uniformly applied, from a distance of 20c+n, 10
It was cured by irradiating 111α ultraviolet rays of 250 to 400 nm for 20 seconds using an 0H mercury lamp. The main components of the curable resin are polymerizable monoacrylate, monomethacrylate, methacrylate, and photosensitizer.
得られた化粧シートは、見本として添付するものであり
、縞模様毎に光沢もしくは明暗が異なり、興１１ ？ｍ
れる視覚的模様を形成している。The obtained decorative sheet is attached as a sample, and each striped pattern has a different luster or brightness. m
It forms a visual pattern.
く試験例２〉
厚さ０．１ ｍｍのポリ塩化ビニルシートの表面に、塩
化ビニル−酢酸ビニル共重合体をバインダーとし、アル
ミニウム粉末を混合したインキで全面で印１１１シた。Test Example 2> The surface of a polyvinyl chloride sheet with a thickness of 0.1 mm was marked with 111 marks on the entire surface with an ink containing vinyl chloride-vinyl acetate copolymer as a binder and aluminum powder mixed therein.
この印刷面を、常法により、深さ１〜１０μの凹凸をエ
ンボスした。凹凸の物理的形状は第２図に示す通りであ
る。This printed surface was embossed with concavities and convexities having a depth of 1 to 10 microns by a conventional method. The physical shape of the unevenness is as shown in FIG.
この凹凸面に、試験例１と同じ硬化型樹脂を１０ｇ／ボ
塗布し、試験例１と同様に紫外線照射して硬化させた。The same curable resin as in Test Example 1 was applied to this uneven surface at 10 g/bottom, and was cured by irradiation with ultraviolet rays in the same manner as in Test Example 1.
〈 ３式 験 例 ３ 〉
厚さ０．１５ｍｍの硬質ポリ塩化ビニルシートの表面に
アルミニウムを突管した後、この蒸着面を、常法により
、深さ０．１〜１μの凹凸をエンボスした。<Type 3 Experimental Example 3> After aluminum was protruded on the surface of a hard polyvinyl chloride sheet with a thickness of 0.15 mm, irregularities with a depth of 0.1 to 1 μm were embossed on the vapor-deposited surface by a conventional method.
凹凸の物理的形状は第２図の通りである。The physical shape of the unevenness is shown in FIG.
この凹凸面に反応性アクリル系電子線硬化型樹脂を５ｇ
／ｒｆ塗布し、次いて１−１０１−１Ｏの電子線を照射
して硬化した。5g of reactive acrylic electron beam curable resin is applied to this uneven surface.
/rf coating, and then irradiated with a 1-101-1O electron beam to cure.
〈効果〉 請求項１の発明は以下の効果を有する。<effect> The invention of claim 1 has the following effects.
（１）極めて浅い凹凸であるため、凹凸の物理的模様が
視覚的模様とならず、視覚的模様は光沢又は明暗の相異
により形成されるため、興趣ある模様が得られる。(1) Since the unevenness is extremely shallow, the physical pattern of the unevenness does not become a visual pattern, and the visual pattern is formed by gloss or differences in brightness and darkness, so an interesting pattern can be obtained.
（２）硬化型樹脂が無溶剤タイプであるため、凹凸が消
失することなく、また均一な皮膜となって、上記視覚的
模様を充分に生かせる。(2) Since the curable resin is a solvent-free type, the unevenness does not disappear and a uniform film is formed, making full use of the above-mentioned visual pattern.
（３）凹凸表面に硬化型樹脂が存在するため、表面がｔ
η染から防止でき、耐熱性耐候性等に優れる。(3) Due to the presence of curable resin on the uneven surface, the surface becomes t
It can prevent η staining and has excellent heat resistance and weather resistance.
また、請求項２の発明は、以上に加えて、以下の効果を
存する。In addition to the above, the invention of claim 2 has the following effects.
（４）反射光同士の干渉により上記視覚的模様が一層引
き立つ。(4) The above-mentioned visual pattern becomes more attractive due to the interference between the reflected lights.
図面は本発明の実施例を示し、第１図は化粧シートの断
面図、第２図は凹凸による物理的模様を示す平面図であ
る。
（１１・・・金属光沢を有する熱可塑性樹脂シート（２
）・・・凹凸 （３）・・・硬化型Ｈ］脂特 許
出 願 人
凸版印刷株式会社
代表者 鈴木和夫
岩２図The drawings show an embodiment of the present invention, and FIG. 1 is a cross-sectional view of a decorative sheet, and FIG. 2 is a plan view showing a physical pattern due to unevenness. (11... Thermoplastic resin sheet with metallic luster (2
)...Irregularities (3)...Curing type H] Resin patent application Toppan Printing Co., Ltd. Representative Kazuo Suzuki Figure 2
Claims (1)
ボス加工して深さ０．１〜２０μの凹凸を設け、この凹
部に透明な無溶剤タイプの硬化型樹脂を充填硬化させて
成る化粧シート。 ２、凹凸による模様が複数の平行な条模様の集合した縞
模様が更に複数個集合したもので、隣り合った縞模様の
条模様の条方向が異なるように組合わされた模様である
ことを特徴とする請求項１記載の化粧シート。[Claims] 1. The surface of a thermoplastic resin sheet with metallic luster is embossed to form irregularities with a depth of 0.1 to 20 μm, and the recesses are filled with a transparent solvent-free curable resin and cured. A decorative sheet made of 2. The uneven pattern is a combination of a plurality of parallel striped patterns, and the adjacent striped patterns are combined in different directions. The decorative sheet according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10615388A JPH01275138A (en) | 1988-04-28 | 1988-04-28 | Decoration sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10615388A JPH01275138A (en) | 1988-04-28 | 1988-04-28 | Decoration sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01275138A true JPH01275138A (en) | 1989-11-02 |
Family
ID=14426377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10615388A Pending JPH01275138A (en) | 1988-04-28 | 1988-04-28 | Decoration sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01275138A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002004234A1 (en) * | 2000-07-10 | 2002-01-17 | De La Rue International Limited | Method of providing an image on a substrate, and an ink for use therein |
| JP2008307734A (en) * | 2007-06-13 | 2008-12-25 | Fukuvi Chem Ind Co Ltd | Method of manufacturing design sheet, and design sheet |
| JP2011084015A (en) * | 2009-10-19 | 2011-04-28 | Toppan Cosmo Inc | Decorative sheet with internal uneven pattern |
| JP2011093096A (en) * | 2009-10-27 | 2011-05-12 | Toppan Cosmo Inc | Decorative sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6248597B2 (en) * | 1981-02-17 | 1987-10-14 | Fuji Xerox Co Ltd |
-
1988
- 1988-04-28 JP JP10615388A patent/JPH01275138A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6248597B2 (en) * | 1981-02-17 | 1987-10-14 | Fuji Xerox Co Ltd |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002004234A1 (en) * | 2000-07-10 | 2002-01-17 | De La Rue International Limited | Method of providing an image on a substrate, and an ink for use therein |
| JP2008307734A (en) * | 2007-06-13 | 2008-12-25 | Fukuvi Chem Ind Co Ltd | Method of manufacturing design sheet, and design sheet |
| JP2011084015A (en) * | 2009-10-19 | 2011-04-28 | Toppan Cosmo Inc | Decorative sheet with internal uneven pattern |
| JP2011093096A (en) * | 2009-10-27 | 2011-05-12 | Toppan Cosmo Inc | Decorative sheet |
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