JPH01268615A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JPH01268615A JPH01268615A JP9754188A JP9754188A JPH01268615A JP H01268615 A JPH01268615 A JP H01268615A JP 9754188 A JP9754188 A JP 9754188A JP 9754188 A JP9754188 A JP 9754188A JP H01268615 A JPH01268615 A JP H01268615A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- cosmetic
- ammonia
- methyltrialkoxysilane
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 claims abstract description 8
- 238000009826 distribution Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 18
- 239000007864 aqueous solution Substances 0.000 abstract description 15
- 150000001412 amines Chemical class 0.000 abstract description 13
- 229910021529 ammonia Inorganic materials 0.000 abstract description 13
- 238000003756 stirring Methods 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 11
- 238000006482 condensation reaction Methods 0.000 abstract description 9
- 239000003960 organic solvent Substances 0.000 abstract description 9
- 239000006210 lotion Substances 0.000 abstract description 6
- 239000000243 solution Substances 0.000 abstract description 6
- 239000006071 cream Substances 0.000 abstract description 5
- 239000003599 detergent Substances 0.000 abstract description 2
- 238000009472 formulation Methods 0.000 abstract description 2
- 238000005201 scrubbing Methods 0.000 abstract description 2
- 239000003906 humectant Substances 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 12
- 230000003020 moisturizing effect Effects 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 229940060184 oil ingredients Drugs 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 238000003786 synthesis reaction Methods 0.000 description 12
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 10
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 9
- -1 polyoxyethylene Polymers 0.000 description 9
- 239000012670 alkaline solution Substances 0.000 description 8
- 230000007062 hydrolysis Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 125000001309 chloro group Chemical group Cl* 0.000 description 5
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229940032094 squalane Drugs 0.000 description 5
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 229940105132 myristate Drugs 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000001166 anti-perspirative effect Effects 0.000 description 3
- 239000003213 antiperspirant Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229940119170 jojoba wax Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 2
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- NNCOOIBIVIODKO-UHFFFAOYSA-N aluminum;hypochlorous acid Chemical compound [Al].ClO NNCOOIBIVIODKO-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000005055 methyl trichlorosilane Substances 0.000 description 2
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 229940073665 octyldodecyl myristate Drugs 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 2
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229960003500 triclosan Drugs 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- QNURTFDBHAQRSI-OAHLLOKOSA-N (4r)-3-[4-[[2-[(3-iodophenyl)methyl]-3-oxocyclohexen-1-yl]amino]phenyl]-4-methyl-4,5-dihydro-1h-pyridazin-6-one Chemical compound C[C@@H]1CC(=O)NN=C1C(C=C1)=CC=C1NC(CCCC1=O)=C1CC1=CC=CC(I)=C1 QNURTFDBHAQRSI-OAHLLOKOSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 description 1
- 229930064664 L-arginine Natural products 0.000 description 1
- 235000014852 L-arginine Nutrition 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000013040 bath agent Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は化粧料、更に詳細には？リメチルシルセスキオ
キサン粉末を含有する。感触効果および皮膚保湿効果を
向上せしめた化粧料に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to cosmetics, more specifically? Contains remethylsilsesquioxane powder. This invention relates to cosmetics with improved tactile effects and skin moisturizing effects.
従来より、クリーム、乳液等の化粧料には、適用後にし
っとりとし九コクのある感触を付与し、しかも十分な保
湿効果を持たせるために、各種油成分やグリセリン、ピ
ロリドンカルボン酸ナトリウム等の保湿剤が比較的多量
に配合されてい友。Conventionally, cosmetics such as creams and emulsions have been formulated with moisturizing ingredients such as various oil ingredients, glycerin, and sodium pyrrolidone carboxylate in order to give them a moist and rich feel after application and to have a sufficient moisturizing effect. It contains a relatively large amount of the agent.
しかしながら、しっとりとしたコクのある使用感を強調
し、保湿効果全高めようとすると、塗布時の油性感やべ
たつき感が増し、皮膚への十分な保湿効果と良好な使用
感全同時に満足させることは困難であった。However, if you try to emphasize a moist and rich feeling and fully enhance the moisturizing effect, the oily and sticky feeling when applied will increase, making it difficult to satisfy both a sufficient moisturizing effect and a good feeling on the skin at the same time. was difficult.
本発明者らは斯かる実情に鑑み、優れた使用感を有し、
しかも皮膚に十分な保湿効果を与える化粧料を得るべく
鋭意ω（究會行った結果、？リメチルシルセスキオキサ
ン粉末金配合すれば、塗布時の油性感υよびべたつき感
が著しく抑制され、さらつとした滑らかな感触を持ち、
しかも皮膚保湿効果に優れた化粧料が得られること金兄
い出［７１本発明全完成した。In view of such actual circumstances, the present inventors have an excellent usability,
In addition, we conducted extensive research to obtain cosmetics that have sufficient moisturizing effects on the skin, and found that if ?limethylsilsesquioxane powder is added, the oiliness and stickiness during application can be significantly suppressed. Has a silky smooth feel,
Moreover, it is possible to obtain cosmetics with excellent skin moisturizing effects.[71] The present invention has been fully completed.
すなわち、不発１３ｔＪｒｉポリメチルシルセスキオキ
サン粉末を含有することを特徴とする化粧料を提供する
ものである。That is, the present invention provides a cosmetic material containing unexploded 13tJri polymethylsilsesquioxane powder.
本発明に用いられる？リメチルシルセスキオキサン粉末
はシロキサン結合が三次元的にのびた網状構造で、ケイ
素原子に１個のメチル基が結合した無機と有機の中間的
構造含有するものである。Is it used in the present invention? Limethylsilsesquioxane powder has a network structure in which siloxane bonds extend three-dimensionally, and contains an intermediate structure between an inorganic and an organic structure in which one methyl group is bonded to a silicon atom.
ぼりメチルシルセスキオキサン粉末の粒子の形は真球状
であり、平均粒子径は０１〜１０μｍ、特に０５〜５μ
ｎｌのものが好ましく。The shape of the particles of Bori methyl silsesquioxane powder is perfectly spherical, and the average particle diameter is 01 to 10 μm, especially 05 to 5 μm.
nl is preferred.
さらには粒度分布が平均粒子径の±３０％の範囲である
ものが好ましい。Furthermore, it is preferable that the particle size distribution is within the range of ±30% of the average particle diameter.
？リメチルシルセスキオキサンは、平均粒径２μ−の真
球状粒子から成シ、真比重Ｌ３、カサ比重Ｑ３５．比表
面積１５〜３０ ｃｎ” ／ ｆ 。? Limethylsilsesquioxane is composed of truly spherical particles with an average particle size of 2 μm, true specific gravity L3, and bulk specific gravity Q35. Specific surface area 15-30 cn”/f.
アマニ油吸油量７５ｄ／ １００ ｆの白色微粉末であ
る「トスノ♀−ル１２０」および平均粒径４μｍの粒子
からなり、真北ｋ ’−３ｓ カサ比重Ｑ１７．比表
面積２０〜３０ ｎ＋” ／ Ｖ 、 ７７二油吸油量
８４ ａｔ ／ １００ ｆ／の白色微粉末である［ト
スノ９−ル２４０」とし、て東芝シリコーン株式会社よ
り販売されているが、特願昭６ｌ−２２ｊ５２０号に記
載されている以下の方法に従っても合成することができ
る。It consists of "Tosnol 120", which is a white fine powder with a linseed oil absorption of 75 d/100 f, and particles with an average particle size of 4 μm, and has a true north k'-3s bulk specific gravity Q17. It is a white fine powder with a specific surface area of 20 to 30 n+"/V and an oil absorption of 84 at/100 f/, and is sold by Toshiba Silicone Co., Ltd. as "Tosunol 240", but a patent application has been filed. It can also be synthesized according to the following method described in Sho 6l-22j520.
すなわち、メチルトリアルコキシシランおよび／′また
はその部分加水分解縮合物またはメチルトリアルコキシ
シランおよび／またはその部分加水分解縮合物と有機溶
剤との混合液を上層にし、アンモニアまたはアミンの水
溶液および／またはアンモニアまたはアミンと有機溶剤
との混合液全下層に１−て、これらの界面でメチルトリ
アルコキシシランおよび／ま九はその部分加水分解縮合
物を加水分解・縮合させて１粒子の形状が各々独立した
ほぼ真球状であり１粒度分布が平均粒子径の±３０％の
範囲である？リメチルシルセスキオキサン粉末を製造す
ることができる。That is, methyltrialkoxysilane and/or a partially hydrolyzed condensate thereof or a mixture of methyltrialkoxysilane and/or a partially hydrolyzed condensate thereof and an organic solvent is formed as an upper layer, and ammonia or an aqueous solution of amine and/or ammonia Alternatively, in the entire lower layer of the mixed solution of amine and organic solvent, methyltrialkoxysilane and/or methyltrialkoxysilane hydrolyzes and condenses its partially hydrolyzed condensate at these interfaces, so that the shape of each particle becomes independent. It is almost perfectly spherical and the particle size distribution is within ±30% of the average particle diameter? Limethylsilsesquioxane powder can be produced.
本方法における原料のメチルトリアルコキシシランおよ
びその部分加水分解縮合物は。The raw materials used in this method are methyltrialkoxysilane and its partially hydrolyzed condensate.
例えば公知の方法によりメチルトリクロロシランを適当
なアルコールでアルコキシ化したものが用いられる。こ
のメチルトリアルコキシシランは、アルコキシ化反応に
使用するアルコールの種類によシ、メチルトリメトギシ
シラン、メチルトリエトキシシラン、メチルトリクロロ
シラン、メチルトリプトキシシラン等が得られ、またメ
チルトリアルコキジシランを完全に加水分解するのに要
する理論量より少量の水を存在させることにより得られ
る、メチルトリアルコキシシランの部分加水分解縮合物
を用いてもよい。これらのメチルトリアルコキシシラン
のうち、生産効率からメチルトリメトキシシランを用い
ることが好ましい。For example, methyltrichlorosilane alkoxylated with a suitable alcohol by a known method may be used. Depending on the type of alcohol used in the alkoxylation reaction, methyltrialkoxysilane can be obtained such as methyltrimethoxysilane, methyltriethoxysilane, methyltrichlorosilane, methyltriptoxysilane, etc. Partially hydrolyzed condensates of methyltrialkoxysilanes obtained by the presence of a smaller amount of water than the theoretical amount required for complete hydrolysis may also be used. Among these methyltrialkoxysilanes, methyltrimethoxysilane is preferably used from the viewpoint of production efficiency.
本方法においては、アルコキシ化反応によって得られた
メチルトリアルコキシシランまたはその部分加水分解縮
合物中に副生する塩化水素または未反応のメチルクロロ
ンランとして存在する塩素原子の量は、特に限定される
ものではない。In this method, the amount of chlorine atoms present as by-product hydrogen chloride or unreacted methylchlorane in the methyltrialkoxysilane or its partially hydrolyzed condensate obtained by the alkoxylation reaction is particularly limited. It's not a thing.
本方法におけるアンモニアまたはアミン類は、メチルト
リアルコキシシラン中に残存する塩素原子の中和剤であ
り、かつメチルトリアルコキシシランの加水分解・縮合
反応の触媒である。このアミン類としては、モノメチル
アミン、ジメチルアミン、モノエチルアミン、ゾエチル
アミン、エチレンシアミン等が例示される。Ammonia or amines in this method are a neutralizing agent for the chlorine atoms remaining in methyltrialkoxysilane, and a catalyst for the hydrolysis/condensation reaction of methyltrialkoxysilane. Examples of the amines include monomethylamine, dimethylamine, monoethylamine, zoethylamine, and ethylenecyamine.
本方法に用いるアンモニアまたはアミン類としては、毒
性が少なく、除去が容易で、しかも安価なことからアン
モニアが有利であり、一般に市販されているアンモニア
水溶液（濃度２８％）全使用することもできる。As the ammonia or amines used in this method, ammonia is advantageous because it has low toxicity, is easy to remove, and is inexpensive, and any commercially available ammonia aqueous solution (concentration 28%) can also be used.
これらのアンモニアおよびアミン類の使用量は、メチル
トリアルコキシシランまたはその部分加水分解縮合物中
に存在する塩素原子を中和するのに充分な量に触媒量を
加えた量で必るが、除去等の点で必要最小限にとどめる
べきである。しかし、アンモニアおよびアミン類の使用
量が少なすぎると、アルコキシシラン類の加水分解、さ
らには縮合反応が進行せず目的物が得られない。The amount of ammonia and amines used must be an amount sufficient to neutralize the chlorine atoms present in methyltrialkoxysilane or its partially hydrolyzed condensate, plus a catalytic amount. It should be kept to the minimum necessary. However, if the amounts of ammonia and amines used are too small, the hydrolysis of the alkoxysilanes and further the condensation reaction will not proceed, making it impossible to obtain the desired product.
アンモニアまたはアミン類は、水溶液または水と有機溶
剤との混合池の水溶液として用いられる。この有機溶剤
としては、メタノール、エタノール、７°ロビルアルコ
一ル％ ｎ−ブタノール、 １ａｏ−ブタノールのよ
うなアルコール類；ジメチルケト／、メチルエチルケト
ン、アセトンのよりなケトン類；脂肪族炭化水素系溶剤
；トルエン、キシレンのような芳香族炭化水素系溶剤等
が例示される。トルエン、キシレンのような芳香族炭化
水素系溶剤を使用する場合は、メチルトリアルコキシシ
ランおよび／またはその部分加水分解縮合物と均一に混
合して用いる。Ammonia or amines are used as an aqueous solution or a mixed solution of water and an organic solvent. Examples of the organic solvent include alcohols such as methanol, ethanol, 7° lobil alcohol% n-butanol, and 1ao-butanol; ketones such as dimethyl ketone, methyl ethyl ketone, and acetone; aliphatic hydrocarbon solvents; toluene, Examples include aromatic hydrocarbon solvents such as xylene. When an aromatic hydrocarbon solvent such as toluene or xylene is used, it is mixed uniformly with methyltrialkoxysilane and/or its partially hydrolyzed condensate.
有機溶剤の配合量は特に規制されないが、水と有機溶剤
の合計量の１００重量部に対し２０重量部以下であるこ
とが好ましい。Although the amount of the organic solvent is not particularly limited, it is preferably 20 parts by weight or less based on 100 parts by weight of the total amount of water and organic solvent.
アンモニアおよびアミ／類の水溶液の使用量は、メチル
トリアルコキシシランまたはその部分加水分解縮合物の
アルコキシ基、もしくは未反応のクロロ７ランの塩素原
子を加水分解するのに必要な理論量の２倍以上の水を含
む量があればよい。特に上記アミン類の水浴液の使用量
に上限はない。しかし、水溶液の使用量が多くなると１
反応工程上不利であり、反応時間も長くなる。逆にあま
り使用量が少なくなりすぎると、副生するアルコールに
より加水分解反応が阻害されて反応時間が長くかかり、
またほぼ真球状である本発明の目的物は得られない。The amount of ammonia and aqueous solution used is twice the theoretical amount required to hydrolyze the alkoxy group of methyltrialkoxysilane or its partially hydrolyzed condensate, or the chlorine atom of unreacted chloro7rane. It suffices if the amount contains more than the amount of water. In particular, there is no upper limit to the amount of the above-mentioned amine water bath solution used. However, when the amount of aqueous solution used increases, 1
This is disadvantageous in terms of the reaction process, and the reaction time becomes longer. On the other hand, if the amount used is too small, the hydrolysis reaction will be inhibited by the alcohol by-product and the reaction time will take longer.
Moreover, the object of the present invention, which is approximately perfectly spherical, cannot be obtained.
本方法におけるほぼ真球状の？リメチル／ルセスキオキ
サン粉末を得るための加水分解・縮合反応は、以下のよ
うにして行なう。Almost spherical in this method? The hydrolysis/condensation reaction to obtain the remethyl/lusesquioxane powder is carried out as follows.
すなわち、攪拌羽根のついた容器中に、アンモニアまた
はアミン類の水浴液あるいはアンモニアまたはアミン類
の水と有機浴剤との混合液（以下アルカリ溶液と記す。That is, a water bath solution of ammonia or amines or a mixed solution of ammonia or amines water and an organic bath agent (hereinafter referred to as an alkaline solution) is placed in a container equipped with a stirring blade.
）とメチルトリアルコキシシランおよび／またはその部
分加水分解縮合物とを、下層にアルカリ溶液層、上層が
メチルトリアルコキシシランおよび／またはその部分加
水分解縮合物層の２層状態となるように仕込む。次いで
、この２層の溶液を適度な攪拌速度で攪拌しながら界面
でメチルトリアルコキシシランとアルカリ溶液との加水
分解・縮合反応を徐々に行なう。) and methyltrialkoxysilane and/or its partially hydrolyzed condensate are prepared in a two-layered state, with the lower layer being an alkaline solution layer and the upper layer being methyltrialkoxysilane and/or its partially hydrolyzed condensate layer. Next, the two-layer solution is stirred at an appropriate stirring speed to gradually carry out a hydrolysis/condensation reaction between the methyltrialkoxysilane and the alkaline solution at the interface.
反応が進行するにつれ、球状粒子が生成され。As the reaction progresses, spherical particles are produced.
下層のアルカリ溶液層に移行し、下層は乳白色に変化す
る。It moves to the lower alkaline solution layer, and the lower layer turns milky white.
この反応における攪拌条件は、攪拌羽根の形状、アルカ
リ溶液の組成などにより変わるが、目的物が真球状であ
り、かつ粒度分布の狭い粒子を得る丸めには、２〜ｉ
ｏ ｏ ｒ−ｐ、ｍ程度の速度で行なうことが好ましく
、さらに好ましくは５〜５０ ｒ、ｐ、ｔｏである。攪
拌速度が大きすぎると、反応前のメチルトリアルコキシ
シランおよび／またはその部分加水分解縮合物が、アル
カリ溶液中に巻き込まれ、アルカリ溶液中で加水分解・
縮合反応が急速に起こるため、粒子が癒着してしまう。The stirring conditions for this reaction vary depending on the shape of the stirring blade, the composition of the alkaline solution, etc., but for rounding to obtain particles that are perfectly spherical and have a narrow particle size distribution,
It is preferable to carry out the reaction at a speed of about 100 m, more preferably 5 to 50 m. If the stirring speed is too high, the methyltrialkoxysilane and/or its partially hydrolyzed condensate before reaction will be dragged into the alkaline solution and will be hydrolyzed and condensed in the alkaline solution.
Since the condensation reaction occurs rapidly, the particles stick together.
また攪拌速度が小さすぎると、界面反応によって生成す
る粒子が、下層のアルカリ溶液中で分散しに＜＜、沈降
して凝集し塊状になってしまう。In addition, if the stirring speed is too low, the particles generated by the interfacial reaction will not be dispersed in the alkaline solution in the lower layer, but will settle and coagulate into lumps.
また、この加水分解・縮合反応のｍ度Ｆｉ特に規制され
ないが、メチルトリアルコキシシランの沸点以下になる
ように調整すべきである。例えばメチルトリメトキシシ
ランの場合は、５０℃以下で行なうことが好ましい。Further, the m degree Fi of this hydrolysis/condensation reaction is not particularly limited, but should be adjusted to be equal to or lower than the boiling point of methyltrialkoxysilane. For example, in the case of methyltrimethoxysilane, it is preferable to carry out the treatment at 50°C or lower.
上記条件により、上層のメチルトリアルコキシシランの
層が消失するまで反応を行ない。Under the above conditions, the reaction is carried out until the upper layer of methyltrialkoxysilane disappears.
さらに攪拌を続ける。この攪拌の時間および温度は、そ
の製造量等により変わるが、１〜１０時間程時間表当で
あり、また必要に応じて約５０℃程度に昇温してもよい
。Continue stirring. The time and temperature of this stirring will vary depending on the amount of production, etc., but will typically take about 1 to 10 hours, and the temperature may be raised to about 50° C. if necessary.
次いで、デイスノＱ−ゾヨンを金網全通して抜き取り、
遠心分離法あるいは遠心濾過法等により脱水を行ない、
得られたペースト状物ｆｒ、１００〜２２０℃で加熱乾
燥後、シェツトミル粉砕機などを用いて解砕を行なうこ
とにより、少なくとも９６％以上のものがほぼ真球状で
、接触帯電量が−２００〜−２０００μＣ／ｖである？
リメチルシルセスキオキサン粉末が得られる。Next, pass the Daysno Q-Zoyon through the wire mesh and pull it out.
Dehydrate by centrifugal separation method or centrifugal filtration method,
The obtained paste material fr is heated and dried at 100 to 220°C, and then crushed using a shet mill or the like, so that at least 96% of the material is almost perfectly spherical and has a contact charge of -200 to 200°C. -2000μC/v?
Limethylsilsesquioxane powder is obtained.
本発明化粧料におけるポリメチルシルセスキオキサン粉
末の配合量は、剤型に応じて変えることができるが、化
粧料中に０１〜３゜重量％、特に０１〜１５重量係配合
されることが好ましい。The amount of polymethylsilsesquioxane powder blended in the cosmetic composition of the present invention can be varied depending on the dosage form, but it is preferably blended in the cosmetic composition in an amount of 01 to 3% by weight, particularly 01 to 15% by weight. preferable.
本発明において、化粧料とは、皮膚化粧料。In the present invention, cosmetics refer to skin cosmetics.
毛髪化粧料のみならず、外用医薬品などの使用時に感触
が問題とされる、皮膚に外用される全ての製品を包含す
る。また、剤型も、クリーム、乳液等の水中油型（０／
Ｗ）％ 油中水ｆｊｌＣＷ１０）のエマルションから、
口紅。It includes not only hair cosmetics but also all products that are used externally on the skin, such as external medicines, where texture is a problem when used. In addition, the dosage form is also oil-in-water type (0/
From an emulsion of W)% water in oil fjlCW10),
lipstick.
チック等の油性固型化粧料、化粧水等のローションまで
種々の形態を選択することができ。You can choose from a variety of forms, from oil-based solid cosmetics such as TICK to lotions such as lotion.
更には皮膚洗浄剤とすればスクラブ効果も期待できる。Furthermore, if used as a skin cleansing agent, it can also be expected to have a scrubbing effect.
本発明の化粧料の調製に当り、好適に用いられる油とし
ては１例えば流動ノｑラフイン、ノＱラフインワックス
、セレシン、スクワラン等の炭化水素：密ロウ、鯨ロウ
、カルナバロウなどのワックス類；オリーブ油、椿油、
ホホバ油、ラノリンなどの天然動植物油脂；シリコーン
油、脂肪酸、高級アルコールおよびこれらを反応して得
られるエステル油等が挙げられる。In the preparation of the cosmetics of the present invention, oils that are preferably used include: 1. Hydrocarbons such as liquid No-Q rough-in wax, No-Q rough-in wax, ceresin, and squalane; Waxes such as beeswax, spermaceti wax, and carnauba wax; olive oil, camellia oil,
Examples include natural animal and vegetable oils and fats such as jojoba oil and lanolin; silicone oils, fatty acids, higher alcohols, and ester oils obtained by reacting these.
また、界面活性剤としては、ポリオキシエチレンアルキ
ルエーテル％ぼりオキシエチレ７ 脂肪酸エステル、？
リオキシエチレンソルビタン脂肪酸エステル、？リオキ
シエチレンソルビトール脂肪酸エステル、？リオキシエ
チレン硬化ヒマシ油アルキル硫酸エステル、？リオキシ
エチレンアルキル硫酸エステル、アルキルリン酸エステ
ル、？リオキシエチレンアルキルリン酸エステル、脂肪
酸アルカリ金属塩、ソルビタン脂肪酸エステル、グリセ
リン脂肪酸エステル等が用いられる。In addition, as a surfactant, polyoxyethylene alkyl ether% oxyethylene 7 fatty acid ester, ?
Lioxyethylene sorbitan fatty acid ester? Lyoxyethylene sorbitol fatty acid ester? Lioxyethylene hydrogenated castor oil alkyl sulfate,? Lyoxyethylene alkyl sulfate, alkyl phosphate, ? Lyoxyethylene alkyl phosphate ester, fatty acid alkali metal salt, sorbitan fatty acid ester, glycerin fatty acid ester, etc. are used.
また１本発明化粧料をエマルションとする場合には更に
各種任意成分を配合することができ１例えば粘度調整剤
として破りビニルアルコール、カルボキシビニルポリマ
ー、カルゴキシメチルセルロース、／リビニルピロリド
ン、ヒドロキシエチルセルロース、メチルセルロースな
どの高分子化合物；ゼラチン。In addition, when the cosmetic composition of the present invention is made into an emulsion, various optional ingredients can be further added.1 For example, as a viscosity modifier, broken vinyl alcohol, carboxyvinyl polymer, carboxymethylcellulose, /vinylpyrrolidone, hydroxyethylcellulose, methylcellulose Polymer compounds such as gelatin.
タラカントガムなどの天然ガム類；エタノール、イソゾ
ロノＱノール等のアルコールＭ が。Natural gums such as taracanth gum; Alcohol M such as ethanol and isozorono Q-nol.
保湿剤としてはグロビレングリコール、グリセリン、１
．３−ブチレングリコール、ゾノロピレンクリコール、
ソルビトール、乳酸、乳酸ナトリウム、ピロリドンカル
ボン酸ナトリウム等が、さらに防腐剤としては、Ｑラオ
キシ安息香酸エステル、安息香酸、安息香酸ナトリウム
、ソルビン酸、ソルビン酸カリウム、フェノキシエタノ
ール等がそれぞれ挙げられる。As a moisturizer, globylene glycol, glycerin, 1
．． 3-butylene glycol, zonolopylene glycol,
Examples of preservatives include sorbitol, lactic acid, sodium lactate, sodium pyrrolidone carboxylate, etc., and further examples of preservatives include Q-laoxybenzoate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, and phenoxyethanol.
本発明に用いられる？リメチルシルセスキオキサン粉末
は耐熱性、耐溶剤性に優れ、かつ凝集性が少なくて分散
性に優れているので、これを含有する本発明の化粧料は
、塗布時の油性感、べたつきがなく、さらつとした滑ら
かな感触を有し、しかも皮膚保湿効果に優れたものであ
る。Is it used in the present invention? Limethylsilsesquioxane powder has excellent heat resistance and solvent resistance, as well as low agglomeration and excellent dispersibility, so the cosmetic composition of the present invention containing it has no oily feel or stickiness when applied. It has a silky smooth feel and has an excellent skin moisturizing effect.
以下に本発明の実施例を示し、本発明を更に詳細に説明
するが、本発明はこれらの実施例によって限定されるも
のではない。EXAMPLES The present invention will be described in more detail below with reference to Examples, but the present invention is not limited to these Examples.
尚、併せて？リメチルシルセスキオキサン粉末の製造法
を合成例として示す０合成例中の部はすべて重量部を示
す。In addition, together? All parts in 0 Synthesis Examples, which show a method for producing remethylsilsesquioxane powder as a synthesis example, indicate parts by weight.
参考例１
水と２８％の濃度のアンモニア水浴液を第１表に示す割
合で容器内で攪拌１−、アンモニア水溶ｉＡ１〜Ａ４を
得た。なお、表中の配合量を示す数字は部を表わす。（
以下同じ。）第１表
合成例１
温度計、還流器および攪拌機のついた４つロフラスコに
アンモニア水溶液Ａ ｌ’ｔ ４０００部とり＠ １
００ ｒ、ｐ、ｍで１０分間攪拌して均一なアンモニア
水溶液にした。このアンモニア水溶液に、塩素原子換算
量で１ｏ ｐｐｍのメチルトリメトキシシラン６００部
を、５ ｒ、ｐ、ｒｎで攪拌機を回しながらアンモニア
水溶液中に混ざらないようにすみやかに加え、上層にメ
チルトリメトキシンラン層、下層にアンモニア水溶液層
の２層状態になるようにした０次いで攪拌機の攪拌速度
を２ Ｏｒ、ｐ、ｒｎにして２層状態を保ちながらメチ
ルトリメトキシシランとアンモニア水溶液との界面にお
いて加水分解・縮合反応を進行させた。反応が進むにつ
れ１反応物は下層に徐々に沈降し、下層は反応物が浮遊
して白濁し、上層のメチルトリメトキシンラン層は、徐
々に層が薄くなり、約３時間で目視で消失した。さらに
温度ヲ５０〜６０℃に保ち、同条件で３時間攪拌を行っ
た後ｓ２５℃に冷却した。次いで析出した生成物ｔｌｏ
Ｏメツシュの金網で濾過後、遠心分離により脱水してケ
ーギ状にし、このケーキ層を２００℃の乾燥器中で乾燥
させた。これをラボノエットを用いて解砕して、白色粉
末を得た。Reference Example 1 Water and ammonia water bath solution having a concentration of 28% were stirred in a container at the ratio shown in Table 1 to obtain ammonia water solutions iA1 to A4. Note that the numbers indicating the blending amounts in the table represent parts. (
same as below. ) Table 1 Synthesis Example 1 4000 parts of ammonia aqueous solution A l't was placed in a four-bottle flask equipped with a thermometer, reflux device, and stirrer @ 1
The mixture was stirred at 00 r, p, m for 10 minutes to form a homogeneous ammonia aqueous solution. To this ammonia aqueous solution, 600 parts of methyltrimethoxysilane of 10 ppm in terms of chlorine atom was quickly added while rotating the stirrer at 5 r, p, rn so as not to mix into the ammonia aqueous solution, and methyltrimethoxysilane was added to the upper layer. Next, the stirring speed of the stirrer was set to 2 Or, p, rn to form a two-layer state with an ammonia aqueous solution layer in the lower layer. Hydrolysis was carried out at the interface between methyltrimethoxysilane and ammonia aqueous solution while maintaining a two-layer state.・Condensation reaction proceeded. As the reaction progressed, one reactant gradually settled to the lower layer, and the lower layer became cloudy due to floating reactants, and the upper methyltrimethoxine layer gradually became thinner and disappeared visually in about 3 hours. . Further, the temperature was maintained at 50 to 60°C, and the mixture was stirred for 3 hours under the same conditions, and then cooled to 25°C. Then the precipitated product tlo
After filtering through an O-mesh wire mesh, it was dehydrated by centrifugation to form a cage, and this cake layer was dried in a dryer at 200°C. This was crushed using Labo Noet to obtain a white powder.
このようにして得た破りメチルシルセスギオギサン粉末
を、電子顕微鏡で観察したところ１粒子径のＸ軸とＹ軸
の比が１．０〜１．２であるほぼ真球状であり、平均粒
子径が約１．９μｍ（１７〜２．１μｍ）のものであっ
た。また接触帯電量を接触帯電量測定器（東芝ケミカル
■製）にてブローオフ法により測定したところ、その結
果は一１０００μＣ／ ｙであった０
合成例２〜５
第２表に示す配合および反応時の攪拌速度以外は合成例
１と同−東件で、メチルトリメトキシシランの加水分解
・縮合反応を行ない、第２表に示す？リメチルシルセス
キオキサン粉末を得た。When the broken methylsilsesgiogisan powder thus obtained was observed with an electron microscope, it was found to be almost perfectly spherical with a ratio of 1.0 to 1.2 between the X axis and the Y axis of one particle size, and the average The particle size was about 1.9 μm (17-2.1 μm). In addition, the contact charge amount was measured by the blow-off method using a contact charge amount measuring device (manufactured by Toshiba Chemical ■), and the result was -1000 μC/y0 Synthesis Examples 2 to 5 The formulation and reaction time shown in Table 2 The hydrolysis/condensation reaction of methyltrimethoxysilane was carried out in the same manner as in Synthesis Example 1 except for the stirring speed, and the results are shown in Table 2. Limethylsilsesquioxane powder was obtained.
以下余白
第２表
合成例６〜８
第３表に示す量のＡ２のアンモニア水溶液と有機溶剤を
合成例１で用いたフラスコにとり１００ ｒ、ｐ、＋ｎ
で１０分間攪拌して均一にした後１合成例１と同様にし
てメチルトリメトキシシラン６００部を加え、攪拌速度
を１５ｒ、ｐ、ｍ とする以外は合成例１と同一条件で
反応させ、第３表に示すそれぞれほぼ真球状の？リメチ
ルシルセスキオキサン粉末を得た。Below is a blank space in Table 2 Synthesis Examples 6 to 8 The amounts of ammonia aqueous solution A2 and organic solvent shown in Table 3 were placed in the flask used in Synthesis Example 1 and 100 r, p, +n
After stirring for 10 minutes to make it homogeneous, add 600 parts of methyltrimethoxysilane in the same manner as in Synthesis Example 1. Each of the nearly perfectly spherical shapes shown in Table 3? Limethylsilsesquioxane powder was obtained.
合成例９
有機溶剤としてトルエンをあらかじめメチルトリメトキ
シシランと混合して用いた以外は１合成例６と同一条件
で反応させ、第３表に示す＃１ぼ真球状の、３ｆ １Ｊ
メチルシルセスキオキサン粉末を得た。Synthesis Example 9 The reaction was carried out under the same conditions as in Synthesis Example 6 except that toluene was mixed with methyltrimethoxysilane in advance as an organic solvent, and 3f 1J of #1 approximately spherical shape shown in Table 3 was obtained.
Methylsilsesquioxane powder was obtained.
第３表
実施例１（化粧水）
エタノール ３ＧＯ（重量％）グリ
セリン ５０
破りエチレングリコール１５０Ｑ ４Ｑ？リオキ
シエチレンオレイルエーテル（２０に、０．） １
．０？リオキシエチレン硬化ヒマシ油（ａｏｇ、ｏ、）
Ｑ５真球状ポリメチルシルセスキオキサン粉末（
合成例２）ａＯ香料 α２
精製水 バランスく製造法〉
精製水にグリセリン 、１５リエチレングリコール１５
００を加え、室温下で溶解する。−方、エタノールに？
リオキシエチレンオレイルエーテル、？リオキシエチレ
ン硬化ヒマシ油、香料を同様に室温下で溶解した後、真
球状ポリメチルシルセスキオキサン粉末を加え湿潤分散
させる。次いで前述の精製水溶液を加えて可溶体を行な
うことにより１本発明の化粧水を調製した。Table 3 Example 1 (Lotion) Ethanol 3GO (wt%) Glycerin 50 Broken ethylene glycol 150Q 4Q? Lyoxyethylene oleyl ether (20 to 0.) 1
．． 0? Lioxyethylene hydrogenated castor oil (aog, o,)
Q5 true spherical polymethylsilsesquioxane powder (
Synthesis example 2) aO fragrance α2 Purified water Balanced production method> Purified water with glycerin, 15 lye ethylene glycol 15
00 and dissolve at room temperature. -How about ethanol?
Lyoxyethylene oleyl ether? After similarly dissolving lyoxyethylene hydrogenated castor oil and fragrance at room temperature, spherical polymethylsilsesquioxane powder is added and wet-dispersed. Next, the above-mentioned purified aqueous solution was added to perform solubilization, thereby preparing a lotion of the present invention.
得られた本発明の化粧水け、感触向上効果および皮膚保
湿効果に優れた化粧料でろＺ＋だ。The resulting cosmetic product of the present invention is called Ro Z+, which has excellent lotion removal, texture improvement effects, and skin moisturizing effects.
実施例２（乳液）
く油相成分〉
セタノール １．０（重量％）ス
クワラン ａＯオリーブ油
ａＯホホバ油
２０ＰＯＥ叫硬化ヒマシ油 ＬＯモノ
ステアリン酸ンルビタン ＬＯ真球状？リメ
チルシル七スキオキサン粉末 ０５（合成例１）
ブチルノ９ラベン ０゜１く水相成分
〉
メチルノＱラベン ０１グリセリン
２．０
１．３−ブチレングリコール ２．０エタノー
ル ａＯ香料 ０１
精製水 バランスく製造法〉
上記水相成分を混合し、加熱溶解して水相部を、７０℃
に保つ。上記油相成分も同様に７０℃で加熱混合し、こ
の水相部に上記の油相部を加えてそれらを乳化機にて乳
化する。Example 2 (Emulsion) Oil phase components> Setanol 1.0 (wt%) Squalane aO Olive oil
aO jojoba oil
20POE Hardened Castor Oil LO Rubitan Monostearate LO True Spherical? Limethylsil-7-squioxane powder 05 (Synthesis example 1) Butyl-9-laben 0゜1 water phase component> Methyl-Q-laben 01 Glycerin
2.0 1.3-Butylene glycol 2.0 Ethanol aO fragrance 01 Purified water Balanced production method> The above aqueous phase components are mixed and dissolved by heating, and the aqueous phase is heated to 70°C.
Keep it. The above-mentioned oil phase components are similarly heated and mixed at 70°C, and the above-mentioned oil phase is added to this aqueous phase and emulsified using an emulsifier.
乳化物を熱交換機にて終温３０℃まで冷却した後充填を
行うことにより、本発明の乳液を調製した。The emulsion of the present invention was prepared by cooling the emulsion to a final temperature of 30°C using a heat exchanger and then filling the mixture.
得られた本発明の乳液は、感触向上効果および皮膚保湿
効果に優れた化粧料であった。The obtained emulsion of the present invention was a cosmetic with excellent texture-improving effects and skin moisturizing effects.
実施例３（クリーム）
く油相成分〉
ステアリンｉ１！２．０（重量％）
セタノール １．０コレス
テロール １．０スクワラン
ＩＱＯホホバ油
ＩＱＯオリーブ油
１０．０セナルリン酸
ｏ５モノステアリン酸ノルビタン
２．０ブｔルノ髪ラベン ｏｌく
水相成分〉
メチルノ髪うベン ｏ２グリセリン
ｉａ。Example 3 (cream) Oil phase ingredients> Stearin i1!2.0 (wt%) Setanol 1.0 Cholesterol 1.0 Squalane
IQO jojoba oil
IQO olive oil
10.0 senal phosphate
o5 norbitan monostearate
2.0 Butruno Hair Ruben O2 Water Phase Ingredients> Methyl Hair Ruben O2 Glycerin
ia.
香料 ＱＩ
Ｌ−アルギニン α３精製水
バランスく製造法〉
上記組成の油相成分及び水相成分を用い。Fragrance QI L-arginine α3 purified water
Balanced production method> Using the oil phase component and water phase component of the above composition.
実施例２と同様の方法によりクリームを調製した。A cream was prepared in the same manner as in Example 2.
得られた本発明のクリームは、感触向上効果および皮膚
保湿効果に優れた化粧料であった０
実施例４（エアゾール制汗剤）
トリクロサン ０．０１（重
量％）アルミニウムヒドロキシクロライド
１．５メルク １．
０ミリスチン酸イソノロビル ２．０香料
α２
く製造法〉
トリクロサン、アルミニウムヒドロキシクロライド、タ
ルク、真球状ポリメチルンルセスキオキサン粉末、ミリ
スチン酸イングロピル、香料を混合分散したものをエア
ゾール用缶に詰めた後、噴射剤全充填することにより。The obtained cream of the present invention was a cosmetic with excellent texture-improving effects and skin moisturizing effects.Example 4 (aerosol antiperspirant) Triclosan 0.01 (wt%) Aluminum hydroxychloride
1.5 Merck 1.
0 Isonorovir myristate 2.0 Fragrance α2 Production method> After mixing and dispersing triclosan, aluminum hydroxychloride, talc, spherical polymethylnlucesquioxane powder, ingropil myristate, and fragrance into an aerosol can, By fully filling the propellant.
本発明のエアゾール制汗剤を調製した。An aerosol antiperspirant of the present invention was prepared.
得られた本発明のエアゾール制汗剤は、感触向上効果に
得れた化粧料であった。The resulting aerosol antiperspirant of the present invention was a cosmetic with a feel-improving effect.
実施例５（油性ファンデーション）
スクワラン ３ａＯ（重ｆ
！に％）ミリスチン酸オクチルドデシル
ａＯマイクロクリスタリンワックス ａ
Ｏ酸化チタン １°８カオリン
ａＯメルク
５０着色顔料
１５０香料 Ｑ２
く製造法〉
着色顔料を混合する。一方、スクワラン。Example 5 (Oil-based foundation) Squalane 3aO (heavy f
! %) Octyldodecyl myristate
aO microcrystalline wax a
O titanium oxide 1°8 kaolin aO Merck
50 colored pigments
150 Fragrance Q2 Production method> Mix color pigments. On the other hand, squalane.
ミリスチン酸オクチルドデシル、マイクロクリスタリン
ワックスを混合し、加熱溶解した後、真球状？リメチル
シルセスキオキサン粉末を加え７０℃に保つ。この基剤
成分に酸化チタン、カオリン、タルク、着色顔料を加え
。After mixing octyldodecyl myristate and microcrystalline wax and heating and melting it, it becomes a perfect sphere? Add remethylsilsesquioxane powder and maintain at 70°C. Titanium oxide, kaolin, talc, and color pigments are added to this base ingredient.
ロールミルで練る。練ったものを加熱して溶かし、調色
し死後、脱泡し香料を加え、容器に流し込み冷却１−て
成型することにより１本発明の油性ファンデーションｔ
ｌ−調製した。Knead with a roll mill. The oil-based foundation of the present invention is prepared by heating and melting the kneaded product, toning the color, defoaming, adding fragrance, pouring into a container, cooling, and molding.
l-prepared.
得られた本発明の油性７アンデーンヨンは、感触向上効
果および皮膚保湿効果に優れた化粧料であった。The obtained oil-based 7-andane gelatin of the present invention was a cosmetic with excellent texture-improving effects and skin moisturizing effects.
実施例６（ブラッシング剤）
ミリスチン酸イングロビル １．０
（３ｉｆｉＬ％）塩化ステアリルトリメチルアンモニウ
ム ００５香料 α１
エタノール ２ａＯ噴射剤Ｃ
フロン１２：フロン１１＝１：１） バランスく製
造法〉
ミリスチン酸イングロビル、塩化ステアリルトリメチル
アンモニウム、真球状献すメチルシルセスキオキサン粉
末、香料、エタノールを混合分散し九ものをエアゾール
用缶に詰めた後、噴射剤を充填することにより１本発明
のブラッシング剤１を調製した。Example 6 (Brushing agent) Inglovir myristate 1.0
(3ifiL%) Stearyltrimethylammonium chloride 005 Fragrance α1 Ethanol 2aO Propellant C
Freon 12: Freon 11 = 1:1) Balanced manufacturing method> Mix and disperse inglovir myristate, stearyltrimethylammonium chloride, spherical methylsilsesquioxane powder, fragrance, and ethanol, and pack the nine ingredients into an aerosol can. After that, the brushing agent 1 of the present invention was prepared by filling with a propellant.
得られた本発明のブラッシング剤は、感触向上効果に優
れた化粧料であった。The resulting brushing agent of the present invention was a cosmetic with an excellent feel-improving effect.
以上that's all
Claims (1)
を特徴とする化粧料。 ２、ポリメチルシルセスキオキサン粉末の粒子が平均粒
子径０．１〜１０μｍの真球状であり、粒度分布が平均
粒子径の±３０％の範囲である、特許請求の範囲第１項
記載の化粧料。 ３、ポリメチルシルセスキオキサン粉末の含有量が０．
１〜３０重量％である、特許請求の範囲第１項記載の化
粧料。[Claims] 1. A cosmetic characterized by containing polymethylsilsesquioxane powder. 2. The polymethylsilsesquioxane powder particles are perfectly spherical with an average particle diameter of 0.1 to 10 μm, and the particle size distribution is within ±30% of the average particle diameter. Cosmetics. 3. The content of polymethylsilsesquioxane powder is 0.
The cosmetic composition according to claim 1, which contains 1 to 30% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9754188A JPH01268615A (en) | 1988-04-20 | 1988-04-20 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9754188A JPH01268615A (en) | 1988-04-20 | 1988-04-20 | Cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01268615A true JPH01268615A (en) | 1989-10-26 |
Family
ID=14195103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9754188A Pending JPH01268615A (en) | 1988-04-20 | 1988-04-20 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01268615A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0240314A (en) * | 1988-07-28 | 1990-02-09 | Toshiba Silicone Co Ltd | Manicure |
| JPH04230311A (en) * | 1990-07-06 | 1992-08-19 | Dow Corning Corp | Hair fixing agent |
| JPH04230312A (en) * | 1990-07-06 | 1992-08-19 | Dow Corning Corp | Method for treating hair |
| JPH0539215A (en) * | 1991-08-02 | 1993-02-19 | Toshiba Silicone Co Ltd | Antiperspirant composition |
| JPH0543420A (en) * | 1991-08-16 | 1993-02-23 | Kao Corp | Cosmetic |
| JPH05139932A (en) * | 1991-11-12 | 1993-06-08 | Kao Corp | Hair cosmetic |
| JPH05148120A (en) * | 1991-11-12 | 1993-06-15 | Shiseido Co Ltd | Cosmetic |
| JPH05310533A (en) * | 1992-05-08 | 1993-11-22 | Toshiba Silicone Co Ltd | Hair cosmetic |
| JPH07267843A (en) * | 1994-03-31 | 1995-10-17 | Shiseido Co Ltd | Two-layer type cosmetic |
| FR2720644A1 (en) * | 1994-06-06 | 1995-12-08 | Oreal | Water-in-oil emulsion without surfactant. |
| JPH07330536A (en) * | 1994-06-02 | 1995-12-19 | Shiseido Co Ltd | Cosmetic |
| JPH08291023A (en) * | 1995-04-18 | 1996-11-05 | Kanebo Ltd | Aerosol composition |
| JPH0948723A (en) * | 1995-06-01 | 1997-02-18 | Shiseido Co Ltd | Milky lotion like powdery cosmetic material |
| JPH10139624A (en) * | 1996-09-13 | 1998-05-26 | Shin Etsu Chem Co Ltd | Production of cosmetic |
| JPH1112132A (en) * | 1997-06-24 | 1999-01-19 | Kose Corp | Cosmetic for eyelash |
| JPH11335254A (en) * | 1998-05-20 | 1999-12-07 | Shin Etsu Chem Co Ltd | Aerosol composition |
| JP2000063674A (en) * | 1998-08-26 | 2000-02-29 | Shin Etsu Chem Co Ltd | Cured silicone powder and cosmetic containing same |
| JP2000505095A (en) * | 1996-08-23 | 2000-04-25 | 花王株式会社 | Aqueous skin cosmetics |
| FR2787798A1 (en) * | 1998-12-25 | 2000-06-30 | Seiwa Kasei Co Ltd | Polysiloxane particles useful in cosmetics are obtained by copolymerizing silanol-functionalized hydrophilic substance with hydrolyzable silicon compound |
| JP2001139451A (en) * | 1999-11-17 | 2001-05-22 | Lion Corp | Gelatinous cosmetic |
| KR100376087B1 (en) * | 2000-12-28 | 2003-03-15 | 주식회사 태평양 | Emulsifier-free finely cosmetic compositions of the water-in-oil type and a method of preparing thereof |
| JP2005068162A (en) * | 1996-08-23 | 2005-03-17 | Kao Corp | Aqueous skin cosmetic |
| JP2015143206A (en) * | 2013-12-27 | 2015-08-06 | ライオン株式会社 | Powder-containing cosmetic composition |
| JP2018016586A (en) * | 2016-07-28 | 2018-02-01 | 花王株式会社 | Water-in-oil emulsified cosmetics |
| JP2018199653A (en) * | 2017-05-29 | 2018-12-20 | 東色ピグメント株式会社 | Cosmetic |
| JP2019099741A (en) * | 2017-12-06 | 2019-06-24 | 株式会社日本触媒 | Dispersoid and resin composition |
| JP2020164458A (en) * | 2019-03-29 | 2020-10-08 | 花王株式会社 | Oil-in-water emulsion cosmetic |
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Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0240314A (en) * | 1988-07-28 | 1990-02-09 | Toshiba Silicone Co Ltd | Manicure |
| JPH04230311A (en) * | 1990-07-06 | 1992-08-19 | Dow Corning Corp | Hair fixing agent |
| JPH04230312A (en) * | 1990-07-06 | 1992-08-19 | Dow Corning Corp | Method for treating hair |
| JPH0539215A (en) * | 1991-08-02 | 1993-02-19 | Toshiba Silicone Co Ltd | Antiperspirant composition |
| JPH0543420A (en) * | 1991-08-16 | 1993-02-23 | Kao Corp | Cosmetic |
| JPH05139932A (en) * | 1991-11-12 | 1993-06-08 | Kao Corp | Hair cosmetic |
| JPH05148120A (en) * | 1991-11-12 | 1993-06-15 | Shiseido Co Ltd | Cosmetic |
| JPH05310533A (en) * | 1992-05-08 | 1993-11-22 | Toshiba Silicone Co Ltd | Hair cosmetic |
| JPH07267843A (en) * | 1994-03-31 | 1995-10-17 | Shiseido Co Ltd | Two-layer type cosmetic |
| JPH07330536A (en) * | 1994-06-02 | 1995-12-19 | Shiseido Co Ltd | Cosmetic |
| US5643555A (en) * | 1994-06-06 | 1997-07-01 | L'oreal | Surfactant-free water-in-oil emulsion |
| EP0686391A1 (en) * | 1994-06-06 | 1995-12-13 | L'oreal | Surfactant-free water-in-oil emulsion |
| FR2720644A1 (en) * | 1994-06-06 | 1995-12-08 | Oreal | Water-in-oil emulsion without surfactant. |
| JPH08291023A (en) * | 1995-04-18 | 1996-11-05 | Kanebo Ltd | Aerosol composition |
| JPH0948723A (en) * | 1995-06-01 | 1997-02-18 | Shiseido Co Ltd | Milky lotion like powdery cosmetic material |
| JP2005068162A (en) * | 1996-08-23 | 2005-03-17 | Kao Corp | Aqueous skin cosmetic |
| JP2000505095A (en) * | 1996-08-23 | 2000-04-25 | 花王株式会社 | Aqueous skin cosmetics |
| JPH10139624A (en) * | 1996-09-13 | 1998-05-26 | Shin Etsu Chem Co Ltd | Production of cosmetic |
| JPH1112132A (en) * | 1997-06-24 | 1999-01-19 | Kose Corp | Cosmetic for eyelash |
| JPH11335254A (en) * | 1998-05-20 | 1999-12-07 | Shin Etsu Chem Co Ltd | Aerosol composition |
| JP2000063674A (en) * | 1998-08-26 | 2000-02-29 | Shin Etsu Chem Co Ltd | Cured silicone powder and cosmetic containing same |
| FR2787798A1 (en) * | 1998-12-25 | 2000-06-30 | Seiwa Kasei Co Ltd | Polysiloxane particles useful in cosmetics are obtained by copolymerizing silanol-functionalized hydrophilic substance with hydrolyzable silicon compound |
| JP2001139451A (en) * | 1999-11-17 | 2001-05-22 | Lion Corp | Gelatinous cosmetic |
| KR100376087B1 (en) * | 2000-12-28 | 2003-03-15 | 주식회사 태평양 | Emulsifier-free finely cosmetic compositions of the water-in-oil type and a method of preparing thereof |
| JP2015143206A (en) * | 2013-12-27 | 2015-08-06 | ライオン株式会社 | Powder-containing cosmetic composition |
| JP2018016586A (en) * | 2016-07-28 | 2018-02-01 | 花王株式会社 | Water-in-oil emulsified cosmetics |
| JP2018199653A (en) * | 2017-05-29 | 2018-12-20 | 東色ピグメント株式会社 | Cosmetic |
| JP2019099741A (en) * | 2017-12-06 | 2019-06-24 | 株式会社日本触媒 | Dispersoid and resin composition |
| JP2020164458A (en) * | 2019-03-29 | 2020-10-08 | 花王株式会社 | Oil-in-water emulsion cosmetic |
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